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WO2018005201A8 - Complexes quinolinyldiamido de métaux de transition, leur production et leur utilisation - Google Patents

Complexes quinolinyldiamido de métaux de transition, leur production et leur utilisation Download PDF

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Publication number
WO2018005201A8
WO2018005201A8 PCT/US2017/038606 US2017038606W WO2018005201A8 WO 2018005201 A8 WO2018005201 A8 WO 2018005201A8 US 2017038606 W US2017038606 W US 2017038606W WO 2018005201 A8 WO2018005201 A8 WO 2018005201A8
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
metal complexes
production
quinolinyldiamido transition
quinolinyldiamido
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2017/038606
Other languages
English (en)
Other versions
WO2018005201A1 (fr
Inventor
John R. Hagadorn
Patrick J. PALAFOX
Peijun Jiang
Yaohua GAO
Xin Chen
Georgy P. GORYUNOV
Mikhail I Sharikov
Dmitry V. Uborsky
Alexander Z. Voskoboynikov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to CN201780046978.3A priority Critical patent/CN109563110B/zh
Priority to JP2018568410A priority patent/JP2019527679A/ja
Priority to EP17820955.7A priority patent/EP3478694B9/fr
Priority to BR112018077480-4A priority patent/BR112018077480A2/pt
Priority to SG11201811335UA priority patent/SG11201811335UA/en
Priority to KR1020187038128A priority patent/KR20190003835A/ko
Priority to CA3029544A priority patent/CA3029544C/fr
Publication of WO2018005201A1 publication Critical patent/WO2018005201A1/fr
Publication of WO2018005201A8 publication Critical patent/WO2018005201A8/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/64086—Neutral ligand
    • C08F4/64089—NNN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/6411—Monoanionic ligand
    • C08F4/64113—NNN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicinal Preparation (AREA)

Abstract

L'invention concerne des complexes de métaux de transition quinolinyldiamido, utilisables dans la polymérisation des alcènes pour produire des polyoléfines multimodales.
PCT/US2017/038606 2016-06-30 2017-06-21 Complexes quinolinyldiamido de métaux de transition, leur production et leur utilisation Ceased WO2018005201A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN201780046978.3A CN109563110B (zh) 2016-06-30 2017-06-21 喹啉基二氨基过渡金属络合物，其生产和用途
JP2018568410A JP2019527679A (ja) 2016-06-30 2017-06-21 キノリニルジアミド遷移金属錯体、生成物およびその使用
EP17820955.7A EP3478694B9 (fr) 2016-06-30 2017-06-21 Complexes quinolinyldiamido de métaux de transition, leur production et leur utilisation
BR112018077480-4A BR112018077480A2 (pt) 2016-06-30 2017-06-21 complexos de metais de transição quinolinildiamido, sua produção e sua utilização
SG11201811335UA SG11201811335UA (en) 2016-06-30 2017-06-21 Quinolinyldiamido transition metal complexes, production and use thereof
KR1020187038128A KR20190003835A (ko) 2016-06-30 2017-06-21 퀴놀리닐디아미도 전이 금속 착물, 제조 및 이의 용도
CA3029544A CA3029544C (fr) 2016-06-30 2017-06-21 Complexes quinolinyldiamido de metaux de transition, leur production et leur utilisation

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201662357033P 2016-06-30 2016-06-30
US62/357,033 2016-06-30
EP16185512 2016-08-24
EP16185512.7 2016-08-24

Publications (2)

Publication Number Publication Date
WO2018005201A1 WO2018005201A1 (fr) 2018-01-04
WO2018005201A8 true WO2018005201A8 (fr) 2018-07-12

Family

ID=56799356

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2017/038606 Ceased WO2018005201A1 (fr) 2016-06-30 2017-06-21 Complexes quinolinyldiamido de métaux de transition, leur production et leur utilisation

Country Status (3)

Country Link
KR (1) KR20190003835A (fr)
SG (1) SG11201811335UA (fr)
WO (1) WO2018005201A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
WO2018160276A1 (fr) * 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Polymères produits par l'utilisation de complexes de métaux de transition quinolinyldiamido et d'agents de transfert de vinyle
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
WO2019147518A1 (fr) * 2018-01-29 2019-08-01 Exxonmobil Chemical Patents Inc. Lubrifiants solides de poly (alpha-oléfine) en forme de goupillon bimodal
US10807997B2 (en) * 2018-08-28 2020-10-20 Exxonmobil Chemical Patents Inc. Methods for making quinolinyldiamines
US11198745B2 (en) * 2018-11-29 2021-12-14 Exxonmobil Chemical Patents Inc. Poly(alpha-olefin)s and methods thereof
US12202920B2 (en) 2019-01-08 2025-01-21 ExxonMobil Engineering & Technology Company Olefin polymerization processes featuring in situ blending of an oil extension
EP4110835A1 (fr) * 2020-02-24 2023-01-04 ExxonMobil Chemical Patents Inc. Catalyseurs bases de lewis et procédés associés
WO2021262842A1 (fr) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS D'ÉTHYLÈNE, α-OLÉFINE, DIÈNE NON CONJUGUÉ, ET CYCLOALCÈNE ARYL-SUBSTITUÉ, PROCÉDÉ DE PRODUCTION, MÉLANGES ET ARTICLES OBTENUS À PARTIR DE CEUX-CI

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6455316B1 (en) 1998-08-13 2002-09-24 Symyx Technologies, Inc. Parallel reactor with internal sensing and method of using same
US6306658B1 (en) 1998-08-13 2001-10-23 Symyx Technologies Parallel reactor with internal sensing
US6147173A (en) 1998-11-13 2000-11-14 Univation Technologies, Llc Nitrogen-containing group 13 anionic complexes for olefin polymerization
EP1334139A2 (fr) 2000-11-07 2003-08-13 Symyx Technologies, Inc. Ligands de pyridylamine substitues, complexes, catalyseurs et procedes pour la polymerisation, et polymeres
US7247687B2 (en) 2002-07-17 2007-07-24 Exxonmobil Chemical Patents Inc. Late transition metal catalysts for olefin polymerization and oligomerization
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
ATE419282T1 (de) 2004-03-17 2009-01-15 Exxonmobil Chem Patents Inc Katalysatorzusammensetzung und verwendung davon
SG156614A1 (en) * 2005-09-15 2009-11-26 Dow Global Technologies Inc Catalytic olefin block copolymers via polymerizable shuttling agent
TW200728385A (en) 2005-12-09 2007-08-01 Dow Global Technologies Inc Processes of controlling molecular weight distribution in ethylene/alpha-olefin compositions
US7973116B2 (en) * 2008-07-25 2011-07-05 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
GB2463788B (en) 2008-09-29 2010-12-15 Amira Pharmaceuticals Inc Heteroaryl antagonists of prostaglandin D2 receptors
US8158733B2 (en) 2009-07-22 2012-04-17 Equistar Chemicals, Lp Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands
US8658556B2 (en) 2011-06-08 2014-02-25 Exxonmobil Chemical Patents Inc. Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith
WO2014123683A1 (fr) * 2013-02-06 2014-08-14 Exxonmobil Chemical Patents Inc. Procédé de contrôle du poids moléculaire des polyoléfines préparées à l'aide de systèmes de catalyseurs pyridyldiamido
US9290519B2 (en) * 2013-11-15 2016-03-22 Exxonmobil Chemical Patents Inc. Pyridyldiamido transition metal complexes, production and use thereof
KR102237823B1 (ko) * 2014-07-09 2021-04-08 삼성전자주식회사 유기금속 화합물 및 이를 포함한 유기 발광 소자

Also Published As

Publication number Publication date
KR20190003835A (ko) 2019-01-09
WO2018005201A1 (fr) 2018-01-04
SG11201811335UA (en) 2019-01-30

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