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WO2018090884A1 - Articles en polyester présentant un aspect métallique ou nacré simulé - Google Patents

Articles en polyester présentant un aspect métallique ou nacré simulé Download PDF

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Publication number
WO2018090884A1
WO2018090884A1 PCT/CN2017/110675 CN2017110675W WO2018090884A1 WO 2018090884 A1 WO2018090884 A1 WO 2018090884A1 CN 2017110675 W CN2017110675 W CN 2017110675W WO 2018090884 A1 WO2018090884 A1 WO 2018090884A1
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WO
WIPO (PCT)
Prior art keywords
plastic article
article
metallic
pearlescent
polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2017/110675
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English (en)
Inventor
Julynn ZHU
Mengge Liu
Wenyu Shang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Polyone Shanghai China
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Polyone Shanghai China
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Filing date
Publication date
Application filed by Polyone Shanghai China filed Critical Polyone Shanghai China
Publication of WO2018090884A1 publication Critical patent/WO2018090884A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Definitions

  • This invention relates to use of a polymer and colorant combination to simulate metallic or pearlescent appearance in a colored polyester article.
  • Plastic has taken the place of other materials in a variety of industries. In the packaging industry, plastic has replaced glass to minimize breakage, reduce weight, and reduce energy consumed in manufacturing and transport. In other industries, plastic has replaced metal to minimize corrosion, reduce weight, and provide color-in-bulk products.
  • Attracting consumers to purchase individually-sized or family-sized containers includes branding and trade dress.
  • the color of the container is the color of the container.
  • such color may need to co-exist with translucency, transparency, or other special effects for the bottle, such as metallic or pearlescent appearance.
  • Thermoplastic resins are used for the production of consumer products. Ranging from the clear, plastic, large soft drink bottles to the miniature colored cosmetic vials, polyethylene terephthalate (PET, one type of the class of polymers called polyesters) as a resin has been frequently used because of its low cost and ability to be compounded with colorants. Most importantly, polyesters such as PET can be formed into products by conventional blow-molding techniques. Molded products made by the blow-molding techniques take the shape and outer texture according to the mold used.
  • PET polyethylene terephthalate
  • Films have previously included polyolefins in transparent polyesters to impart translucency or opacity, including such as disclosed in U.S. Pat. No. 4,368,295 (Newton et al. ) . But Newton et al. did not address use of polyesters and polyolefins in colored polymeric films.
  • U.S. Pat. No. 8,575,296 has disclosed a polyester article made to appear lustrously metallic or pearlescent by the addition of polymethylpentene and non-metallic, non-pearlescent colorant; and optionally other functional additives.
  • the colorant could be one or more pigments, one or more dyes, or combinations thereof.
  • a stretch blow molded plastic article, such as a bottle, using the polymethylpentene in the polyester could simulate the appearance of a metallic surface or a pearlescent luster even though non-metallic and non-pearlescent colorants are used.
  • Metallic colorants can be supplied in the form of concentrates formulated to give a brushed-metal look to thermoplastic parts. These concentrates (also called “masterbatches” ) , upon blending into the thermoplastic resin, allow the plastic article to duplicate the look of brushed metals such as aluminum, bronze, copper, gold or antique brass. Custom metal color matches also can be formulated, depending on the colorant combination employed.
  • the concentrates are supplied in a pelletized, non-dusting form tailored to a specific resin system.
  • a typical dilution or “letdown” ratio for a metallic colorant concentrate ranges from about 100: 1 to about 10: 1 and preferably about 25: 1 (4%) , which varies with the desired effect.
  • Typical applications for metallic effect plastic articles include packaging, personal care, toys, sporting goods, and transportation.
  • Pearlescent colorants can be supplied in the form concentrates formulated to give a lustrous effect varying from a satin to a sparkling sheen using pearlescent or iridescent pigments.
  • the pearlescent colorant concentrates can be formulated in a range of hues and are compatible with most thermoplastic resins. Effects range from satin to sparkle. The strongest pearlescent effects are seen in pastel colors.
  • pearlescent colorant concentrates are supplied in pelletized, non-dusting form, tailored to suit a specific resin system. Again, a typical letdown ratio ranges from about 100: 1 to about 10: 1 and preferably about 25: 1 (4%) , which varies with the desired effect.
  • Pearlescent effect plastic articles can have the same or different uses as metallic effect plastic articles.
  • the colorant which provides the special effect can be viewed by a customer as costly because conventional colorants used to produce metallic or pearlescent appearance are higher in specific gravity and have a tendency to produce unsightly flow-lines due to the flake geometry of the conventional metallic or pearlescent colorant material. Furthermore, when subjected to shear stresses the conventional metallic or pearlescent colorant materials can bend or break, thus changing the overall surface appearance of the thermoplastic article in its final shape. In addition, many of the conventional metallic or pearlescent colorant materials are not able to produce a highly uniform pearl-like appearance –the flakes produce a grain-like appearance which may be undesirable to the customer.
  • the present invention solves the problem in the art by using polylactic acid (PLA) as a component or carrier for color concentrates for polyester articles, in order to simulate metallic or pearlescent effects in the coloration of a polyester article when the polyester article is produced by stretch blow molding or other stress formation process.
  • PLA polylactic acid
  • the interaction of PLA in polyester results in increasing translucency toward opacity.
  • increasing translucency toward opacity is accompanied by a simulation by the non-metallic, non-pearlescent colorants of the brushed metal appearance of a metallic colorant concentrate or the lustrous appearance of a pearlescent colorant concentrate, or both.
  • the chromaticity and the brightness of the resulting molded polyester container using concentrates of the present invention have dramatically different values as one tilts the container in the presence of a light source at a constant angle.
  • non-metallic, non-pearlescent colorant means a conventional dye or pigment which is not formed of, or derived from, metal, mica, or glass.
  • a conventional, non-metallic, non-pearlescent colorant can replace more expensive and more dispersion-difficult metallic colorants or pearlescent colorants, if one employs PLA as a carrier for the colorant being employed in a polyester plastic article. It is believed with current costs that the combination of PLA and non-metallic, non-pearlescent colorant is less expensive than the use of a metallic or pearlescent colorant.
  • One aspect of the invention is a plastic article, comprising (a) a matrix of polyester and (b) polylactic acid dispersed throughout the matrix, and optionally, (c) at least one non-metallic, non-pearlescent colorant dispersed throughout the matrix, wherein surfaces of the article have a brightness and chromaticity which simulates the appearance of metallic pigment or pearlescent pigment throughout the matrix because the brightness and chromaticity values change as the angle of the surface of the article changes relative to a constant light source.
  • Another aspect of the invention is a method of making the plastic article described above, comprising the steps of (a) mixing the matrix and the concentrate into a mixture; and (b) forming under stress the mixture into the plastic article, wherein the differences in brightness and chromaticity are a function of the amount of polylactic acid in the mixture.
  • Fig. 1 is a composite photo of Examples 3 and 4, Examples 5 and 6, and Example 7.
  • Any aromatic polyester is a candidate for use in the present invention.
  • the formation of a polyester from a monool or a polyol and an acid or its ester encompasses many different suitable types of polyesters for use in this invention.
  • the monomeric units can be formed reactions of either aliphatic moieties, aromatic moieties, or both.
  • the polyester is transparent or semi-transparent in order to accentuate the effect of the stress forming event.
  • Non-limiting examples of polyesters include terephthalates, 1, 4 butylene glycol, terephthalate glycols, copolyesters of terephthalic acid residues, 2, 2, 4, 4-tetramethyl-1, 3-cyclobutanediol, and 1, 4-cyclohexanedimethanol, etc., or combinations, derivatives, thereof.
  • the linear polyesters may be produced by condensing one or more dicarboxylic acids or a lower alkyl diester thereof, e.g., dimethylterephthalate, terephthalic acid, isophthalic acid, phthalic acid, 2, 5-, 2, 6-, or 2, 7-naphthalene dicarboxylic acid, succinic acid, sebacic acid, adipic acid, azelaic acid, bibenzoic acid and hexahydroterephthalic acid, or bis-p-carboxyphenoxyethane, with one or more glycols, e.g., ethylene glycol, pentyl glycol, and 1, 4-cyclohexanedimethanol.
  • dicarboxylic acids or a lower alkyl diester thereof e.g., dimethylterephthalate, terephthalic acid, isophthalic acid, phthalic acid, 2, 5-, 2, 6-, or 2, 7-naphthalene dicarboxylic acid, succinic acid
  • PET polyethylene terephthalate
  • PBT polybutylene terephthalate
  • PLA is an aliphatic monomer having has a formula I:
  • n is high enough (e.g., at least 30) for the polymer to have a number average molecular weight higher than the number average molecular weight of an oligomer.
  • the monomeric unit can homopolymerize or copolymerize.
  • PLA has a melting point of about 170-180°C and is nearly transparent with a low specific gravity of about 1.25 g/cm 3 . The reported haze is less than 2.5%with a transmittance of 90%.
  • PLA has a refractive index of 1.46.
  • PLA is used in consumer packaging because PLA is an environmental friendly material. For that reason, PLA has been used as a carrier in color concentrate products, but not intentionally for use with polyester for metallic or pearlescent simulation appearance purposes.
  • PLA is commercially available as Revode 190 brand grade from HISUN in China, among others located by searching the internet.
  • a colorant can be a pigment, a dye, a combination of pigments, a combination of dyes, a combination of pigments and dye, a combination of pigment and dyes, or a combination of pigments and dyes.
  • the choice of colorants depends on the ultimate color desired by the designer for the plastic article.
  • Colorants are commercially available from a number of sources well known to those skilled in the art.
  • Commercially available pigments are well known to those skilled in the art and include organic and inorganic colorant chemistries.
  • Commercially available dyes are well known to those skilled in the art and include all organic chemistries.
  • Commercial sources for pigments and dyes include multinational companies such as BASF, Bayer, Color-Chem International, Sun Chemical, Zhuhai Skyhigh Chemicals, and others identified at Internet Web Sites such as www. colorpro. com/info/vendors/colorant. html and dir. yahoo. com/Business_and_Economy/Business_to_Business/Chemicals_and_Allied_Products/Pigments_and_Dyes/
  • Table 1 lists 8 commercially available pigment colorants in a variety of primary and secondary colors, 5 chromatics, 2 blacks, and 1 white.
  • Table 2 shows 14 commercially available dyes.
  • Colorants for this invention can include colorants intended for transparent or translucent plastic polyester articles and colorants intended for opaque plastic articles.
  • the colorant itself, when used, in this invention determines the color of the metal or pearl which is simulated by the interaction of the PLA with the polyester.
  • the more convenient method of manufacture is to assemble the colorant and PLA as a concentrate to be added into the polyester matrix, it is certainly contemplated that each ingredient can be added separately.
  • the amount of PLA in the polyester affects the change in brightness and chromaticity of the colorants as the wall thickness of the polyester article changes from a preform to a final article.
  • the simulated metallic or pearlescent surface appearance can be achieved using this invention, whether by compounding all ingredients together or compounding a concentrate of colorant and PLA into polyester.
  • the concentration of colorant into a carrier is significant because of the relative cost of the colorant ingredient (s) and the need for that color to consistently and precisely mix and disperse into the carrier and then to consistently and precisely dilute into the plastic resin and other compound ingredients during "letdown" of the concentrate in mixing equipment prior to formation of the preform embryonic bottles or other articles.
  • Letdown ratios depend on the concentration of colorant in the color concentrate and whether the final molded product is intended to be opaque, translucent, or transparent.
  • the amount of PLA in the final molded product, as a function of plastic article (e.g., polyester part) wall thickness above about 0.01mm can range from about 0.5 to about 60 weight percent, and preferably from about 3 to about 10 weight percent for plastic article.
  • the mixing equipment used to make the color concentrate can be any suitable equipment already used in the art of mixing highly concentrated solids.
  • such equipment includes high speed Henschel mixers, ribbon blenders, shakers, and the like.
  • Mixing equipment can operate at mixing speeds ranging from about 10 rpm to about 10,000 rpm, and preferably from about 500 to about 8000 rpm. Mixing equipment can operate at temperatures ranging from about 25°C to about 100°C, and preferably from about 40°C to about 80°C.
  • additives to improve processing or performance of the concentrate of the present invention or the polyester compound, or both can be added according to preferences of those skilled in the art.
  • functional additives for polyester bottles can include anti-oxidants, anti-stats, acetaldehyde scavengers, oxygen scavengers, blowing agents, biocides, exfoliated nanoclays, thickeners, and the like, and combinations thereof.
  • minor amounts of such additives provide improvement of performance to the color concentrate during processing with the other ingredients in the polyester resin or in performance of the polyester molded article after manufacturing.
  • One skilled in the art without undue experimentation can determine the appropriate concentration.
  • the preparation of a colored plastic article does not involve merely color but also special effect features, such as Granite, Translucent, Fluorescents, Iridescents, Marbles, Metallics, Pearls, etc. With metallics and pearls already simulated by use of the PLA color concentrate in polyester, these other special effects can be added to create even more eye-catching effects for the plastic article in use or on sale.
  • Non-limiting examples of such additives are commercially available from PolyOne Corporation of Avon Lake, Ohio, USA (www. polyone. com) and marketed under the following brands: OnColor FX colorants, PolyOne colorants, etc.
  • Plastic articles exposed to natural sunlight are exposed to ultraviolet rays that can harm the color of the article. Therefore, for certain applications, it is customary but not required to include ultraviolet light stabilizers in the color concentrate.
  • This optional additive being included in the color concentrate adds value to that concentrate as a masterbatch in polymer compounding because the ultraviolet stabilizer also helps protect the polymer resin from adverse effects arising from exposure to the ultraviolet rays. Being included in a masterbatch as an additive makes the introduction of the stabilizer easier, due to better dispersion.
  • Table 3 shows acceptable, desirable, and preferable ranges of ingredients useful for polymeric articles of compounds containing PLA additives, all expressed in weight percent (wt. %) of the entire compound.
  • the compound can comprise, consist essentially of, or consist of these ingredients. Any number between the ends of the ranges is also contemplated as an end of a range, such that all possible combinations are contemplated within the possibilities of Table 1 as candidate compounds for use in this invention.
  • the polylactic acid can be delivered into the final compound via a masterbatch using a carrier.
  • the carrier can be entirely PLA or a mixture of PLA and polyester depending on the amount of total PLA desired in the polyester part wall thickness.
  • Concentrates of the present invention can be letdown into plastic resins and other ingredients useful for making molded or extruded articles.
  • the plastic resins can be any aromatic polyester, but especially PET.
  • the invention has particular applicability to plastic articles which are personal care or hygiene product containers, such as shampoo bottles, lotion containers, etc.
  • the method of making such plastic articles is via stretch blow molding.
  • Stretch blow molding is a subset of conventional blow molding, often used in making containers.
  • the final shape is achieved via one stage or two stages.
  • a “parison” is formed having some final dimensions (the “finish” such as the screw cap portion of the ultimate container) and nearly immediately then subjected to blow molding with a deliberate stretch of the non-final dimensions expanded to their intended shape.
  • the stretching occurs both in the axial direction of the parison and in the hoop or radial direction also.
  • a “preform” is formed via conventional injection molding and having some final dimensions (the “finish” such as the screw cap portion of the ultimate container) and the remainder having shrunken dimensions for convenience of transport and storage until final stress formation.
  • the preform is heated to an appropriate softening temperature and gas is used to deliberately stretch to its final intended shape.
  • the stretching occurs both in the axial direction of the preform and in the hoop or radial direction also.
  • polyester can be strengthened by stretch blow molding because the resulting strain is hardened into the plastic article after cooling. This strengthening in a container can assist in the storage of fluids having a high vapor pressure, such as carbonated soft drinks and the like.
  • the plastic article (of polyester and PLA which are both polymers having high clarity approaching transparency) becomes translucent or even opaque.
  • the ability of standard colorants to simulate metallic pigments or pearl pigments is totally unexpected but arises from the use of PLA and the effect of stress formation into final polyester article shape. Other embodiments appear in the examples.
  • Table 4 shows the formulations of the two masterbatches used in the compounds of the remaining examples, including the source of the raw materials.
  • Table 5 shows the formulations of the compounds and the test results.
  • Fig. 1 is a photographic lineup showing the metallic or pearlescent glossy appearance of Examples 3-7 in the shape of bottles and plaques.
  • PLA itself is a polyester and hence more able to obtain a more homogeneous and effective metallic or pearlescent appearance in injection blow molded bottles or injection plaques substituting for other polymer shapes.
  • the molded plastic article can be made by other molding techniques.
  • the molded plastic article can be used for any purpose imaginable. Any molded polyester article which utilizes a calculable wall thickness can benefit from the explanations in this invention to achieve any desired level of simulated metallic or pearlescent appearance.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

Selon l'invention, un article en polyester est amené à présenter un aspect métallique ou nacré lustrés par l'addition de poly(acide lactique), éventuellement d'un colorant non métallique, non nacré ; et éventuellement d'autres additifs fonctionnels. Le colorant peut être un ou plusieurs pigments, un ou plusieurs colorants ou des combinaisons correspondantes. Un article en plastique, tel qu'une bouteille moulée par étirage-soufflage ou une plaque d'injection, faisant usage du poly(acide lactique) dans le polyester peut simuler l'aspect d'une surface métallique ou d'un lustre nacré, sans colorants métalliques ou nacrés.
PCT/CN2017/110675 2016-11-17 2017-11-13 Articles en polyester présentant un aspect métallique ou nacré simulé Ceased WO2018090884A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201611011209.3 2016-11-17
CN201611011209.3A CN108070225B (zh) 2016-11-17 2016-11-17 具有模拟金属或珠光外观的聚酯制品

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WO2018090884A1 true WO2018090884A1 (fr) 2018-05-24

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PCT/CN2017/110675 Ceased WO2018090884A1 (fr) 2016-11-17 2017-11-13 Articles en polyester présentant un aspect métallique ou nacré simulé

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CN111572138B (zh) * 2020-05-21 2022-03-08 厦门长塑实业有限公司 一种珠光聚酰胺薄膜及其制备方法
CN111838895B (zh) * 2020-08-11 2022-12-16 浙江伟星实业发展股份有限公司 一种铝质感纽扣及其制备方法
CN113584630A (zh) * 2021-09-02 2021-11-02 杭州卓普新材料科技有限公司 珠光3d打印材料及其制备方法

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CN102516789A (zh) * 2011-12-09 2012-06-27 上海锦湖日丽塑料有限公司 可用于温控指示的树脂组合物
CN105073879A (zh) * 2013-01-08 2015-11-18 瑞来斯实业公司 聚合物组合物及其制备方法

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Publication number Publication date
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CN108070225B (zh) 2022-02-08

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