WO2018076083A1 - Composition déodorante anti-transpirantes de masquage - Google Patents
Composition déodorante anti-transpirantes de masquage Download PDFInfo
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- WO2018076083A1 WO2018076083A1 PCT/BR2016/050274 BR2016050274W WO2018076083A1 WO 2018076083 A1 WO2018076083 A1 WO 2018076083A1 BR 2016050274 W BR2016050274 W BR 2016050274W WO 2018076083 A1 WO2018076083 A1 WO 2018076083A1
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- antiperspirant
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0254—Platelets; Flakes
- A61K8/0258—Layered structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
Definitions
- the present invention relates to a method and composition for controlling body odor and masking skin imperfection of the localized areas of the body such as the underarm, comprising at least one masking micas having a high and low refractive index, at least one antiperspirant agent, at least one fatty compound, optionally, at least one silicone, optionally, at least one surfactant, optionally, at least one solvent, and optionally, at least one propellant.
- Sweating though a natural bodily function, results in the formation of wet patches on human skin or clothing. Moreover, the sweat secreted from sweat glands has a tendency to form a malodorous odor due to its interaction with the many microorganisms which reside on the underarm skin surface. These two phenomena are deemed to be undesirable in many societies.
- antiperspirant products possess active ingredients which inhibit/suppress sweating, whereas deodorant products possess ingredients that mask the malodors caused by sweat. Many products address both phenomena simultaneously.
- the present invention relates to a deodorant antiperspirant composition
- a deodorant antiperspirant composition comprising:
- beige/silver masking mica composition comprising mica, titanium dioxide and iron oxide, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consists of:
- mica has an average particle size less than 25 microns; b. an antiperspirant agents selected from one or more antiperspirant actives;
- the present invention relates to a deodorant antiperspirant roll-on composition
- a deodorant antiperspirant roll-on composition comprising:
- beige/silver masking micas composition a. from 0.03% to 0.25% by weight of beige/silver masking micas composition, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consists of:
- mica has an average particle size less than 25 microns; b. from 0.01 % to 40% by weight of one or more antiperspirant agents selected from one or more antiperspirant actives and the combination thereof;
- the present invention relates to an anhydrous deodorant antiperspirant aerosol composition
- anhydrous deodorant antiperspirant aerosol composition comprising:
- beige/silver masking micas composition a. from 0.13% to 0.43% by weight of beige/silver masking micas composition, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consist of:
- the mica has an average particle size less than 25 microns; b. from 0.01 % to 40% by weight of one or more antiperspirant agents selected from one or more antiperspirant actives and the combination thereof; c. from 0.1 % to 10% by weight of one or more fatty compound comprising:
- the present invention relates to a deodorant antiperspirant soft-solid composition
- a deodorant antiperspirant soft-solid composition comprising:
- beige/silver masking micas composition a. from 0.05% to 0.49% by weight of beige/silver masking micas composition, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consist of:
- mica has an average particle size less than 25 microns; b. from 0.01 % to 40% by weight of one or more antiperspirant agents selected from one or more antiperspirant actives and the combination thereof;
- the present invention relates to a deodorant antiperspirant stick composition
- a deodorant antiperspirant stick composition comprising:
- beige/silver masking micas composition a. from 0.10% to 1 .00% by weight of beige/silver masking micas composition, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consist of:
- mica has an average particle size less than 25 microns; b. from 0.01 % to 40% by weight of one or more antiperspirant agents selected from one or more antiperspirant actives and the combination thereof;
- the present invention is also directed to the method for masking skin imperfection and reducing fabric transfer, comprising applying a composition to the skin area in need of such an application a deodorant antiperspirant composition comprising:
- beige/silver masking mica composition comprising mica, titanium dioxide and iron oxide, wherein beige is the base color, and silver is the reflection color, wherein the beige/silver masking mica composition consists of:
- mica has an average particle size less than 25 microns; b. an antiperspirant agents selected from one or more antiperspirant actives;
- the present invention is also directed to a process for suppressing sweat and odor from forming on human skin involving applying the above-disclosed composition onto a surface of the human skin.
- composition according to the invention may be place in a dispensing means and applied in form of cream, for example a roll-on, soft-solid.
- the composition according to the invention may also be place in a dispensing means and applied by spraying, for example an aerosol spray.
- the composition according to the invention may also be place in a dispensing means and applied in form of a stick.
- the above-described composition not only controls perspiration and body odor, but also masks the skin imperfection in broad range of (both dark and light) skin tones by covering contrast between bright areas such as skin ridges and dark areas, also by blurring the appearance of imperfection. Additionally, the composition also reduces the transference of a deodorant antiperspirant to both light and dark fabrics.
- Figure 1 Roll-on antiperspirant deodorant for masking skin imperfection and improve skin tone matching
- FIG. 3 Aerosol antiperspirant deodorant for masking skin imperfection and improve skin tone matching
- FIG. 4 Aerosol antiperspirant deodorant to reduces the fabric transfer on both light and dark color fabrics
- One or more as used herein means at least one and thus includes individual components as well as mixtures/combinations.
- Cosmetically acceptable means that the item in question is compatible with any keratinous substrate.
- cosmetically acceptable carrier means a carrier that is compatible with any keratinous substrate.
- compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful.
- the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
- the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
- ranges provided are meant to include every specific range within, and combination of subranges between, the given ranges.
- a range from 1 -5 includes specifically 1 , 2, 3, 4 and 5, as well as subranges such as 2- 5, 3-5, 2-3, 2-4, 1 -4, etc.
- a range of ratios is meant to include every specific ratio within, and combination of subranges between, the given ranges.
- Polymers include homopolymers and copolymers formed from at least two different types of monomers.
- Anhydrous means a composition containing less than 2% by weight of water, or less than 0.5% water, not being water-added at the preparation of the composition, but the corresponding residual water provided by the ingredients blends.
- Aerosol propellant refers to and includes, for example, conventional propellants such as liquefied gases, usually naturally occurring hydrocarbons such as propane or butane, pentane, iso-pentane, and the like and compressed gases, such as, carbon dioxide, nitrogen, and air. Lacking a propellant with reference to the compositions hereof means essentially free of a propellant, such that any amounts that may be present are trace and insufficient to confer conventional benefits or properties associated with propellants used for aerosolizing or foaming.
- conventional propellants such as liquefied gases, usually naturally occurring hydrocarbons such as propane or butane, pentane, iso-pentane, and the like and compressed gases, such as, carbon dioxide, nitrogen, and air.
- deodorant means any substance capable of reducing, masking, or absorbing human body odors, in particular underarm odors.
- pigment means any colored and/or iridescent mineral or organic particles that are insoluble in the liquid hydrophilic phase, which are intended to color and/or add iridescence to the composition.
- antiperspirant means any substance capable of reducing flow of sweat.
- mica composition means a pigment comprising at least one type core composed of mica, and at least one coat containing including at least titanium dioxide and iron oxide.
- the expression “masking” means cover contrast between bright areas such as skin ridges and dark areas, and reducing skin imperfection and fabric transfer by blurring the appearance of imperfection by providing soft focus effect.
- coverage means masking skin imperfection and matching skin tone with surrounding area of underarm.
- the cosmetic composition according to the present invention comprises at least one beige interferential pigment, such as a pearlescent pigment or nacre, with an average particle size of less than 25 pm can effectively reduce the visibility of skin imperfections, such as pores, and spots, especially reduce the visibility of spots, to provide superior concealing cosmetic effects, with natural effects.
- beige interferential pigment such as a pearlescent pigment or nacre
- mica composition means a pigment that is capable of producing a color by an interference phenomenon, e.g., between the light reflected by a single layer or a plurality of layers with different refractive indices, in particular a succession of layers of high and low refractive indices.
- the mica composition herein referred as "pigment” may have a multilayer structure which is intended to denote either a structure formed from a substrate covered with a single layer or a structure formed from a substrate covered with at least two or even more consecutive layers.
- a mica composition may include more than four layers of different refractive indices.
- the layers of pigment may optionally surround a core, which may present an optionally plate-like shape.
- the pigment may be in the form of a plate, with an aspect ratio of from 1 to 200, preferably from 5 to 100, and more preferably from 10 to 50.
- the pigment according to the present invention has an average particle size of less than 30 ⁇ .
- the average particle size may be measured as a volume average particle size, with a laser granulometer, for instance the Mastersizer 2000® machine from Malvern and/or the BI90+® machine from Brookhaven Instrument Corporation.
- the pigment be a composite powder comprising at least one plate type core, preferably composed of mica, talc, alumina, silica, barium sulfate, boron nitride, bismuth oxychloride, synthetic fluorphlogopite or a mixture thereof, and at least one coating including at least one metal oxide, preferably titanium dioxide, iron oxide, or a mixture thereof.
- the beige pigment according to the invention comprises at least one plate type core composed of mica, and at least one coating including at least titanium dioxide and iron oxide.
- Nacres are examples of mica composition pigments.
- nacres mean colored particles of any form, which may optionally be iridescent, as produced in the shells of certain mollusks, or which are synthesized, and which exhibit a "pearlescent” coloring effect by optical interference.
- nacre pigments such as mica titanium dioxide coated with iron oxide, mica titanium dioxide coated with chromium oxide, mica titanium dioxide coated with an organic colorant, in particular of the type mentioned above, and nacre pigments based on bismuth oxychloride. They may also be particles of mica on the surface of which at least two successive layers of metal oxides and/or organic coloring substances have been superimposed.
- the mica composition pigment such as a pearlescent pigment, has a beige color.
- the beige pigment used according to the present invention may preferably be characterized by:a beige base color with 50 ⁇ L * ⁇ 100, 15 ⁇ C * ⁇ 35 and 30 ⁇ h ⁇ 90 under the CLE. L * C * h color system, on white background; and
- the beige interferential pigment used according to the present invention may be characterized by:a beige base color with 70 ⁇ L * ⁇ 90, 15 ⁇ C * ⁇ 30 and 40 ⁇ h ⁇ 80 under the CLE. L * C * h color system, on white background; and
- the color of the pigment can be measured with a colorimeter such as a Nikon Minolta CM-700d colorimeter (standard illuminant D65/10 0 ) under the conditions that the white or black background is covered with 0.2 mg/cm 2 of powder (interferential pigment), and the measured color can be characterized using the CLE.
- L * C * h color system where "L * " stands for lightness, "C * " stands for saturation, and "h” stands for hue.
- pigments preferably pearlescent pigments or nacres
- the pigment such as a pearlescent pigment or nacre can show its base color once applied on bright areas of the skin such as skin ridges and its reflection color once applied on dark areas of the skin such as spots.
- the interferential pigment with a beige base color and a desaturated reflection color can provide a natural color coverage while brightening up spots and decreasing their visibility.
- the masking mica composition may be present in a deodorant antiperspirant composition according to the present invention in an amount ranging from 0.02% to 1 .0%, preferably from 0.03% to 0.80% by weight relative to the total weight of the composition.
- the masking mica composition may be present in a deodorant antiperspirant according to the present invention in an amount of 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.10, 0.1 1 , 0.12, 0.13, 0.14, 0.15, 0.16, 0.17, 0.18, 0.19, 0.20, 0.21 , 0.22, 0.23, 0.24, 0.25, 0.26, 0.27, 0.28, 0.29, 0.30, 0.31 , 0.32, 0.33, 0.34, 0.35, 0.36, 0.37, 0.38, 0.39, 0.40, 0.41 , 0.42, 0.43, 0.44, 0.45, 0.46, 0.47, 0.48, 0.49, 0.50, 0.51 , 0.52, 0.53, 0.54, 0.55, 0.56, 0.57, 0.58, 0.59, 0.60, 0.61 , 0.62, 0.63, 0.64, 0.65, 0.66, 0.67, 0.68, 0.69, 0.70, 0.71 , 0.72, 0.73, 0.74, 0.75,
- the masking mica composition may be present in a deodorant antiperspirant roll-on composition according to the present invention in an amount ranging from 0.03% to 0.25%, preferably from 0.06% to 0.23% and more preferably from 0.08% to 0.20% by weight relative to the total weight of the composition.
- the masking mica composition may be present in a deodorant antiperspirant roll-on composition according to the present invention in an amount of 0.06, 0.07, 0.08, 0.09, 0.10, 0.1 1 , 0.12, 0.13, 0.14, 0.15, 0.16, 0.17, 0.18, 0.19, 0.20, 0.21 , 0.22, 0.23.
- the masking mica composition may be present in a deodorant antiperspirant aerosol composition according to the present invention in an amount ranging from 0.13% to 0.43%, preferably from 0.15% to 0.35% and more preferably from 0.17% to 0.30% by weight relative to the total weight of the composition.
- the masking mica composition may be present in a deodorant antiperspirant aerosol composition according to the present invention in an amount of 0.15, 0.16, 0.17, 0.18, 0.19, 0.20, 0.21 , 0.22, 0.23, 0.24, 0.25, 0.26, 0.27, 0.28, 0.29, 0.30, 0.31 , 0.32, 0.33, 0.34, 0.35.
- the masking mica composition may be present in a deodorant antiperspirant soft-solid composition according to the present invention in an amount ranging from 0.05% to 0.49%, preferably from 0.15% to 0.47% and more preferably from 0.25% to 0.45% by weight relative to the total weight of the composition.
- the masking mica composition may be present in a deodorant antiperspirant soft-solid composition according to the present invention in an amount of 0.15, 0.16, 0.17, 0.18, 0.19, 0.20, 0.21 , 0.22, 0.23, 0.24, 0.25, 0.26, 0.27, 0.28, 0.29, 0.30, 0.31 , 0.32, 0.33, 0.34, 0.35, 0.36, 0.37, 0.38, 0.39, 0.40, 0.41 , 0.42, 0.43, 0.44, 0.45, 0.46, 0.47.
- the masking mica composition may be present in a deodorant antiperspirant stick composition according to the present invention in an amount ranging from 0.10% to 1 .0%, preferably from 0.20% to 0.90% and more preferably from 0.30% to 0.80% by weight relative to the total weight of the composition.
- the masking mica composition may be present in a deodorant antiperspirant stick composition according to the present invention in an amount of 0.20, 0.21 , 0.22, 0.23, 0.24, 0.25, 0.26, 0.27, 0.28, 0.29, 0.30, 0.31 , 0.32, 0.33, 0.34, 0.35, 0.36, 0.37, 0.38, 0.39 0.40, 0.41 , 0.42, 0.43, 0.44, 0.45, 0.46, 0.47, 0.48, 0.49, 0.50, 0.51 , 0.52, 0.53, 0.54, 0.55, 0.56, 0.57, 0.58, 0.59, 0.60, 0.61 , 0.62, 0.63, 0.64, 0.65, 0.66, 0.67, 0.68, 0.69, 0.70, 0.71 , 0.72, 0.73, 0.74, 0.75, 0.76, 0.77, 0.78, 0.79, 0.80, 0.81 , 0.82, 0.83, 0.84, 0.85, 0.86, 0.87, 0.89, 0.90.
- antiperspirant ingredient means any substance capable of reducing the flow of sweat.
- the antiperspirant ingredients which can be used according to the invention are preferably chosen from aluminium and/or zirconium salts, complexes of zirconium chlorohydrate and of aluminium chlorohydrate with an amino acid, and mixtures thereof.
- Non-limiting examples of aluminum salts useful in the invention include, for example, aluminium chlorohydrate in the activated or nonactivated form, aluminium chlorohydrex, the aluminium chlorohydrex polyethylene glycol complex, the aluminium chlorohydrex propylene glycol complex, aluminium dichlorohydrate, the aluminium dichlorohydrex polyethylene glycol complex, the aluminium dichlorohydrex propylene glycol complex, aluminium sesquichlorohydrate, the aluminium sesquichlorohydrex polyethylene glycol complex, the aluminium sesquichlorohydrex propylene glycol complex, aluminium sulphate buffered by sodium aluminium lactate, and mixtures thereof.
- Non-limiting examples of complexes of zirconium chlorohydrate and aluminium chlorohydrate with an amino include, for example, aluminium zirconium octachlorohydrate, aluminium zirconium pentachlorohydrate, aluminium zirconium tetrachlorohydrate, aluminium zirconium trichlorohydrate, and mixtures thereof.
- ZAG zirconium chlorohydrate and of aluminium chlorohydrate with an amino acid
- ZAG when the amino acid is glycine
- the ZAG complexes usually exhibit an Al/Zr quotient ranging from about 1 .67 to 12.5 and a Metal/CI quotient ranging from about 0.73 to 1 .93.
- Non-limiting examples of these complexes include, for example, aluminium zirconium octachlorohydrex glycine, aluminium zirconium pentachlorohydrex glycine, aluminium zirconium tetrachloro- hydrex glycine aluminium zirconium trichlorohydrex glycine complexes, and mixtures thereof.
- the antiperspirant ingredient is aluminium chlorohydrate, in particular the product sold by SummitReheis under the name REACH 103, aluminum zirconium pentachlorohydrate, in particular the product sold by SummitReheis under the name REACH AZ-7373, aluminum zirconium tetrachlorohydrex GLY (INCI name), in particular the product sold by SummitReheis under the name REACH AZP-908, and mixtures thereof.
- the antiperspirant actives may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 40% by weight, preferably in an amount of from about 1 % to 35% by weight, and most preferably 5% to 30% by weight, based on the total weight of the composition.
- the antiperspirant actives may be present in a deodorant antiperspirant composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the antiperspirant actives may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 40% by weight, preferably in an amount of from about 5% to 30% by weight, and most preferably 10% to 20% by weight, based on the total weight of the composition.
- the antiperspirant actives may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20.
- the antiperspirant actives may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 40% by weight, preferably in an amount of from about 1 % to 30% by weight, and most preferably 5% to 25% by weight, based on the total weight of the composition.
- the antiperspirant actives may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25.
- the antiperspirant actives may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 40% by weight, preferably in an amount of from about 1 % to 35% by weight, and most preferably 5% to 30% by weight, based on the total weight of the composition.
- the antiperspirant actives may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the antiperspirant actives may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 40% by weight, preferably in an amount of from about 1 % to 35% by weight, and most preferably 5% to 30% by weight, based on the total weight of the composition.
- the antiperspirant actives may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- PLANT-DERIVED OIL PLANT-DERIVED OIL
- the fatty compound of the present invention optionally may contains at least one plant-derived oil having a melting point from 10°C to 40°C, such as from about 12°C to 38°C, preferably from about 16°C to 32°C.
- Plant-derived oils are those typically extracted from a relevant part of the plant such as the seed, fruit or leave, although equivalents which can be synthetically manufactured may be employed as well.
- Suitable plant derived oils include, but are not limited to, elaeis guineensis (palm) oil, cocos nucifera (coconut) oil, babassu (orbignya olifera seed) oil, safflower oil, palm kernel oil, cottonseed oil, linseed oil, almond oil, castor oil, corn oil, olive oil, rapeseed oil, sesame oil, wheat germ oil, peach stone oil and the liquid fractions of coconut oil, pracaxi oil (known by the INCI name pentaclethra macroloba seed oil), andiroba oil (known by the INCI name carapa guaianensis seed oil), pataua oil (known by the INCI name oenocarpus bataua fruit oil), and buriti oil (known by the INCI name ma
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 2% to 30% by weight, based on the total weight of the composition.
- the plant-derived oil according to the present invention includes elaeis guineensis (palm) oil, cocos nucifera (coconut) oil.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 7%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the plant-derived oil according to the present invention is elaeis guineensis (palm) oil.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the plant-derived oil according to the present invention is cocos nucifera (coconut) oil.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 3% to 7% by weight, based on the total weight of the composition.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 10% to 30% by weight, based on the total weight of the composition.
- the fatty compound in form of Plant-derived oils may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the fatty compound of the present invention optionally may contain at least one fatty acid ester containing 7 to 31 carbon atoms.
- suitable fatty acid esters containing 7 to 31 carbon atoms for use in the present invention include, but are not limited to, dicaprylyl carbonate, 2-ethylhexyl isononanoate, isononyl isononanoate, isopropyl palmitate, myristyl palmitate, C12-C15 alkyl benzoate, and isodecyl isononate.
- the fatty compound in form of ester may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 2% to 30% by weight, based on the total weight of the composition.
- the ester according to the present invention includes isononyl isononanoate, isopropyl palmitate, caprylic/capric triglyceride.
- the fatty compound in form of ester may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 7%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of ester may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the fatty compound in form of ester may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of ester may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the ester according to the present invention is isononyl isononanoate.
- the fatty compound in form of ester may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 3% to 7% by weight, based on the total weight of the composition.
- the fatty compound in form of ester may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7.
- the ester according to the present invention is caprylic/capric triglyceride.
- the fatty compound in form of ester may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 10% to 30% by weight, based on the total weight of the composition.
- the fatty compound in form of ester may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the ester according to the present invention is isopropyl palmitate.
- VOLATILE HYDROCARBON OIL VOLATILE HYDROCARBON OIL
- the fatty compound of the present invention optionally may contain one or more volatile hydrocarbon oil.
- hydrocarbon is intended to mean oil comprising carbon and hydrogen atoms.
- volatile hydrocarbon oil is intended to mean a hydrocarbon that is capable of evaporating on contact with the skin or the keratin fibers in less than one hour, at ambient temperature and atmospheric pressure.
- the volatile hydrocarbons of the invention are volatile cosmetic oils which are liquid at ambient temperature and which have a non-zero vapor pressure, at ambient temperature and atmospheric pressure, ranging in particular from 0.13 Pa to 40 000 Pa (10 -3 to 300 immHg), in particular ranging from 1 .3 Pa to 13 000 Pa (0.01 to 100 immHg) and more particularly ranging from 1 .3 Pa to 1300 Pa (0.01 to 10 mmHg).
- volatile hydrocarbons mention may be made of straight- chain hydrocarbons containing from 8 to 16 carbon atoms, for example, dodecane and hexadecane, and branched-chain hydrocarbons containing from 8 to 16 carbon atoms, for example, isododecane, isodecane, isohexadecane, and Cs-Ci6 isoalkanes of petroleum origin (also known as isoparaffins) known under the INCI names C1 1 -13 isoparaffin and C8-9 isoparaffin sold under the tradename ISOPARTM by ExxonMobil.
- straight- chain hydrocarbons containing from 8 to 16 carbon atoms for example, dodecane and hexadecane
- branched-chain hydrocarbons containing from 8 to 16 carbon atoms for example, isododecane, isodecane, isohexadecane, and Cs-Ci6 isoalkanes of petroleum origin (also known as iso
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 2% to 30% by weight, based on the total weight of the composition.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 7%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 3% to 7% by weight, based on the total weight of the composition.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 10% to 30% by weight, based on the total weight of the composition.
- the fatty compound in form of volatile hydrocarbon oil may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the fatty compound of the present invention optionally may contain at least one wax.
- a wax is defined as a fatty compound substantially in the form of a solid at ambient temperature (20-25°C) under atmospheric pressure (760 immHg), and has a melting point generally of 35°C or more.
- the wax is a fatty alcohol.
- a fatty alcohol is defined as any saturated or unsaturated, linear or branched C8-C30 fatty alcohol, which is optionally substituted, in particular with one or more hydroxyl groups (in particular 1 to 4). If they are unsaturated, these compounds may comprise one to three conjugated or non- conjugated carbon-carbon double bonds.
- fatty alcohols are unsaturated and/or branched.
- C8-C30 fatty alcohols C12-C22 fatty alcohols, for example, are used.
- cetyl alcohol, stearyl alcohol or a mixture thereof (e.g., cetearyl alcohol), as well as myristyl alcohol can be used as a solid fatty material.
- the waxes are those generally used in cosmetics and dermatology.
- the waxes may be of natural origin, for instance beeswax, carnauba wax, candelilla wax, ouricoury wax, Japan wax, cork fiber wax or sugar cane wax, paraffin wax, lignite wax, microcrystalline waxes, lanolin wax, montan wax, ozokerites and hydrogenated oils, for instance hydrogenated jojoba oil.
- the waxes also may be of synthetic origin, for instance polyethylene waxes derived from the polymerization of ethylene, waxes obtained by Fischer- Tropsch synthesis, esters of fatty acids and of glycerides that are solid at 40 Q C.
- Waxes of synthetic origin are preferable as they are more uniform and provide greater reproducibility than waxes of natural origin. Moreover, the waxes are preferably not silicone waxes.
- the fatty compound in form of wax may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 2% to 30% by weight, based on the total weight of the composition.
- the wax according to the present invention includes beeswax, ozokerite.
- the fatty compound in form of wax may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 7%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of wax may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the fatty compound in form of wax may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 2% to 6% by weight, based on the total weight of the composition.
- the fatty compound in form of wax may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 2, 3, 4, 5, 6.
- the fatty compound in form of wax may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 1 % to 8%, and more preferably from about 3% to 7% by weight, based on the total weight of the composition.
- the fatty compound in form of wax may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7.
- the wax according to the present invention is beeswax.
- the fatty compound in form of wax may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 40%, preferably from about 1 % to 35%, and more preferably from about 10% to 30% by weight, based on the total weight of the composition.
- the fatty compound in form of wax may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28, 29, 30.
- the wax according to the present invention is ozokerite.
- the deodorant antiperspirant compositions of the present invention optionally may contain one or more non-volatile silicone oil.
- non-volatile oil means oil that remains on the skin or the keratin fiber at room temperature and atmospheric pressure for at least several hours, and that especially has a vapor pressure of less than 10 3 immHg (0.13 Pa).
- silicon oil means an oil comprising in its structure carbon atoms and at least one silicon atom.
- Non-limiting examples of non-volatile silicone oils useful in the invention include, for example, polydimethylsiloxanes (PDMS), polydimethylsiloxanes comprising alkyl or alkoxy groups that are pendent and/or at the end of a silicone chain, these groups each containing from 2 to 24 carbon atoms, phenyl silicones, for instance phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl trisiloxanes and 2-phenylethyl trimethylsiloxysilicates, dimethicones or phenyltrimethicones with a viscosity range of 25 to 350 cSt, and mixtures thereof.
- PDMS polydimethylsiloxanes
- phenyl silicones for instance phenyl trimethicones, phenyl dimeth
- the non-volatile silicone oil is dimethicone (INCI name) having a viscosity of 100 cSt sold by Wacker under the name BELSIL® DM 100.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 35%, preferably from about 0.1 % to 30% by weight, based on the total weight of the composition.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 6%, and more preferably from about 2% to 5% by weight, based on the total weight of the composition.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 5%, preferably from about 0.1 % to 3%, and more preferably from about 0.3% to 2.5% by weight, based on the total weight of the composition.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1 .0, 1 .2, 1 .3, 1 .4, 1 .5, 1 .6, 1 .7, 1 .8, 1 .9, 2.0, 2.1 , 2.2, 2.3, 2.4, 2.5.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 3% to 15%, and more preferably from about 7% to 12% by weight, based on the total weight of the composition.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 7, 8, 9, 10, 1 1 , 12.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 35%, preferably from about 5% to 32%, and more preferably from about 10% to 28% by weight, based on the total weight of the composition.
- the silicone in form of non-volatile oil may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28.
- SILICONE ELASTOMER 10 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28.
- the cosmetic compositions of the present invention optionally may contain at least one silicone elastomer.
- silicone elastomer means a supple, deformable organopolysiloxane with viscoelastic properties and especially with the consistency of a sponge or a supple sphere. Its modulus of elasticity is such that this material withstands deformation, has a limited ability to extend and to contract, and is capable of regaining its original shape after stretching.
- the silicone elastomer is more particularly a crosslinked organopolysiloxane elastomer.
- the organopolysiloxane elastomer may be obtained by crosslinking addition reaction of diorganopolysiloxane containing at least one hydrogen bonded to silicon and of diorganopolysiloxane containing ethylenically unsaturated groups bonded to silicon, especially in the presence of a platinum catalyst; or by dehydrogenation crosslinking condensation reaction between a diorganopolysiloxane containing hydroxyl end groups and a diorganopolysiloxane containing at least one hydrogen bonded to silicon, especially in the presence of an organotin; or by crosslinking condensation reaction of a diorganopolysiloxane containing hydroxyl end groups and of a hydrolysable organopolysilane; or by thermal crosslinking of organopolysiloxane, especially in the presence of an organoperoxide catalyst
- the silicone elastomer is advantageously a non-emulsifying elastomer.
- non-emulsifying defines organopolysiloxane elastomers not containing any hydrophilic chains, and in particular not containing any polyoxyalkylene units (especially polyoxyethylene or polyoxypropylene) or any polyglyceryl units.
- the composition comprises an organopolysiloxane elastomer free of polyoxyalkylene units and of polyglyceryl units.
- Non-emulsifying elastomers are described especially in patents EP 242 219, EP 285 886 and EP 765 656 and in patent application JP-A-61 -194009.
- the silicone elastomer is generally in the form of a gel, a paste or a powder, but advantageously in the form of a gel in which the silicone elastomer is dispersed in a linear silicone oil (dimethicone) or cyclic silicone oil (e.g.: cyclopentasiloxane), advantageously in a linear silicone oil.
- a linear silicone oil dimethicone
- cyclic silicone oil e.g.: cyclopentasiloxane
- a gel of silicone elastomer dispersed in a silicone oil chosen from a non-exhaustive list comprising cyclopentadimethylsiloxane, dimethicones, dimethylsiloxanes, methyl trimethicone, phenyl methicone, phenyl dimethicone, phenyl trimethicone and cyclomethicone, preferably a linear silicone oil chosen from polydimethylsiloxanes (PDMS) or dimethicones with a viscosity at 25°C ranging from 1 to 500 cSt, optionally modified with optionally fluorinated aliphatic groups, or with functional groups such as hydroxyl, thiol and/or amine groups.
- a silicone oil chosen from a non-exhaustive list comprising cyclopentadimethylsiloxane, dimethicones, dimethylsiloxanes, methyl trimethicone, phenyl methicone, phen
- the composition according to the invention comprises at least one crosslinked silicone elastomer having the INCI name "dimethicone crosspolymer” or “dimethicone (and) dimethicone crosspolymer”, with preferably a dimethicone having a viscosity ranging from 1 to 100 cSt, in particular from 1 to 10 cSt at 25°C, such as the mixture of polydimethylsiloxane crosslinked with hexadiene/polydimethylsiloxane (16% by weight) in dimethicone (5 cSt) sold under the name DC 9041 Dow Corning or the mixture of polydimethylsiloxane crosslinked with hexadiene/polydimethylsiloxane (16% by weight) in dimethicone (2 cSt) sold under the name Dow Corning EL-9240 ® silicone elastomer blend Dow Corning.
- Dow Corning EL-9240 ® silicone elastomer blend Dow Corning
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 35%, preferably from about 0.1 % to 30% by weight, based on the total weight of the composition.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 8%, preferably from about 1 % to 6%, and more preferably from about 2% to 5% by weight, based on the total weight of the composition.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 2, 3, 4, 5.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 5%, preferably from about 0.1 % to 3%, and more preferably from about 0.3% to 2.5% by weight, based on the total weight of the composition.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9, 1 .0, 1 .2, 1 .3, 1 .4, 1 .5, 1 .6, 1 .7, 1 .8, 1 .9, 2.0, 2.1 , 2.2, 2.3, 2.4, 2.5.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 3% to 15%, and more preferably from about 7% to 12% by weight, based on the total weight of the composition.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 7, 8, 9, 10, 1 1 , 12.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 35%, preferably from about 5% to 32%, and more preferably from about 10% to 28% by weight, based on the total weight of the composition.
- the silicone in form of silicone elastomer may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 10, 1 1 , 12, 13, 14, 15, 16, 17, 18, 19, 20, 21 , 22, 23, 24, 25, 26, 27, 28.
- the surfactants of the present invention may optionally contain one or more surfactant chosen from oxyalkylenated fatty acid ester of glycerol.
- the oxyalkylene chain of the oxyalkylenated fatty acid esters of glycerol is preferably an oxyethylene chain.
- it may contain, for example, from 1 to 150 oxyalkylene and especially oxyethylene groups, and preferably from 2 to 100 oxyalkylene and especially oxyethylene groups.
- composition may also contain one or more other nonionic emulsifying surfactants.
- the surfactant or the mixture of surfactants preferably has an HLB (hydrophilic-lipophilic balance) ranging from 5 to 20 and preferably from 8 to 18, and it should be soluble in the oily phase.
- HLB hydrophilic-lipophilic balance
- Surfactants with an HLB of greater than 20 may also be used, provided that one or more other surfactants are added thereto such that the HLB of the mixture ranges from 5 to 15.
- Examples of oxyalkylenated fatty acid esters of glycerol that may be mentioned more particularly include (INCI name) PEG-20 glyceryl triisostearate, PEG-7 glyceryl cocoate, and mixtures thereof.
- PEG-20 glyceryl triisostearate such as those sold by the company Nihon Emulsion under the tradename Emalex Gwis-320EX.
- nonionic surfactants examples include oxyalkylenated fatty acid ester of sorbitan, esters of fatty acids and of polyols; oxyalkylenated or non-oxyalkylenated ethers of fatty alcohols and of polyols, and mixtures thereof.
- Surfactants of this type that may be mentioned more particularly include:
- sorbitan such as (INCI name) Polysorbate 20, Polysorbate 65, Polysorbate 85, PEG-5 sorbitan isostearate, PEG-20 sorbitan triisostearate, PEG-20 sorbitan isostearate, PEG-40 sorbitan septaoleate, PEG-20 sorbitan tetraoleate and PEG-20 sorbitan trioleate;
- Triisostearate Polyglyceryl-10 Diisostearate, Polyglyceryl-6 Isostearate, Polyglyceryl-3 Diisostearate, Polyglyceryl-10 Trioleate or Polyglyceryl-10 Trilaurate;
- - fatty acid esters of polyethylene glycol such as (INCI name) PEG-8 Stearate, PEG-6 Oleate, PEG-6 Isostearate, PEG-12 Isostearate, PEG-12 Diisostearate, PEG-8 Isostearate, PEG-8 Diisostearate or PEG-10 Isostearate;
- - oxyalkylenated especially oxyethylenated and/or oxypropylenated, more particularly oxyethylenated, fatty alkyl ethers, for instance ceteareth-12 and ceteareth-20 (INCI name), and also mixtures containing them, for instance the mixture sold under the name Emulgade CM by the company Cognis (mixture of cetearyl isononanoate, ceteareth-20, cetearyl alcohol, glyceryl stearate, glycerol, ceteareth-12 and cetyl palmitate);
- the surfactant may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 15%, and more preferably from about 1 .5% to 14.5% by weight, based on the total weight of the composition.
- the surfactant according to the present invention includes cetearyl alcohol, glyceryl stearate, PEG-100 stearate, PEG-8 distearate.
- the surfactant may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 0.5% to 8%, and more preferably from about 1 % to 5% by weight, based on the total weight of the composition.
- the surfactant may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 1 , 2, 3, 4, 5.
- the surfactant according to the present invention is cetearyl alcohol.
- the surfactant may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 5%, preferably from about 1 % to 4%, and more preferably from about 1 .3% to 3.5% by weight, based on the total weight of the composition.
- the surfactant may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 1 .3, 1 .4, 1 .5, 1 .6, 1 .7, 1 .8, 1 .9, 2.0, 2.1 , 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1 , 3.2, 3.3, 3.4, 3.5.
- the surfactant may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 15%, preferably from about 1 % to 12%, and more preferably from about 3% to 9% by weight, based on the total weight of the composition.
- the surfactant may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7, 8, 9.
- the surfactant according to the present invention is cetearyl alcohol, glyceryl stearate, PEG-100 stearate.
- the surfactant may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 18%, and more preferably from about 5% to 15% by weight, based on the total weight of the composition.
- the surfactant may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15.
- the surfactant according to the present invention is PEG-8 distearate.
- the surfactants of the present invention may optionally contain one or more lower alkyl ether of polypropylene glycols ("PPG alkyl ethers").
- PPG alkyl ethers are liquid, water-insoluble propoxylated fatty alcohols, having the molecular formula of RO(CH2CHOCH 3 )n; wherein "R” is a straight-chained or branched C4 to C22 alkyl group; and "n” is in the range between 4 and about 50.
- PPG alkyl ethers mention may be made of PPG-12 butyl ether, PPG-14 butyl ether, PPG-15 butyl ether, PPG-16 butyl ether, PPG-17 butyl ether, PPG-18 butyl ether, and PPG-20 butyl ether.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 15%, and more preferably from about 1 .5% to 14.5% by weight, based on the total weight of the composition.
- the surfactant in form of PPG alkyl ethers according to the present invention is PPG-14 butyl ether.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 0.5% to 8%, and more preferably from about 1 % to 5% by weight, based on the total weight of the composition.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 1 , 2, 3, 4, 5.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 5%, preferably from about 1 % to 4%, and more preferably from about 1 .3% to 3.5% by weight, based on the total weight of the composition.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 1 .3, 1 .4, 1 .5, 1 .6, 1 .7, 1 .8, 1 .9, 2.0, 2.1 , 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1 , 3.2, 3.3, 3.4, 3.5.
- the surfactant in form of PPG alkyl ethers according to the present invention is PPG-14 butyl ether.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 15%, preferably from about 1 % to 12%, and more preferably from about 3% to 9% by weight, based on the total weight of the composition.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7, 8, 9.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 18%, and more preferably from about 5% to 15% by weight, based on the total weight of the composition.
- the surfactant in form of PPG alkyl ethers may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15.
- the surfactant in form of PPG alkyl ethers according to the present invention is PPG-14 butyl ether.
- An essential constituent of the oil-in-water emulsions of the present invention is a mixture of non-ionic emulsifiers forming an emulsifier system.
- Such an emulsifier system conveniently has a weighted average HLB value in the region of from about 4 to about 15 and particularly from about 6 to 9.
- An especially desired weighted average HLB value is from about 6 to 6.29.
- Such a weighted average HLB value can be obtained by using a combination of at least two emulsifiers, a first (lower) HLB emulsifier having an HLB value in the range of from about 3 to 8, and in particular from about 4 to 6 and a second (higher) HLB emulsifier having an HLB value in the range of from about 10 to 19 and especially from about 14 to 16.
- the weighted average HLB value is obtained by varying the weight average of the low and high HLB values of the constituent emulsifiers.
- the weighted average HLB value is obtained by calculating the weighted average of the individual HLB values.
- the non-ionic emulsifiers may be chosen from ethoxylated non-ionic surfactants and propoxylated non-ionic surfactants.
- composition of the present invention is its ability to impart a pleasant feeling of moisturizing which is perceived by the end user upon application to their skin.
- This tactile feeling is directly related to liquid crystals which are formed in the composition based on the selection and association of the constituents of the oil system and emulsifier system.
- the ratio by weight of the oil system to the emulsifier system be in the range of about 10:1 to 2:1 , such as about 7:1 to 2:1 , and about 3:1 to 4.7:1 . It has been found that by using the above- disclosed oil and emulsifier systems, in the disclosed amounts, liquid crystals are formed within the composition which yield the desired moisturizing tactile properties observed by the end user.
- the aqueous phase of the said emulsions comprises water and generally other water-soluble or water-miscible solvents.
- the water-soluble or water- miscible solvents comprise short-chain, for example C1 -C4, monoalcohols, such as ethanol or isopropanol; or diols or polyols, such as ethylene glycol, 1 ,2-propylene glycol, 1 ,3-butylene glycol, hexylene glycol, diethylene glycol, dipropylene glycol, 2- ethoxyethanol, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether and sorbitol.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 15%, and more preferably from about 1 .5% to 14.5% by weight, based on the total weight of the composition.
- the surfactant in form of emulsifier according to the present invention include steareth-2, steareth-20.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 0.01 % to 10%, preferably from about 0.5% to 8%, and more preferably from about 1 % to 5% by weight, based on the total weight of the composition.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 1 , 2, 3, 4, 5.
- the surfactant in form of emulsifier according to the present invention include steareth-2, steareth-20.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.01 % to 5%, preferably from about 1 % to 4%, and more preferably from about 1 .3% to 3.5% by weight, based on the total weight of the composition.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 1 .3, 1 .4, 1 .5, 1 .6, 1 .7, 1 .8, 1 .9, 2.0, 2.1 , 2.2, 2.3, 2.4, 2.5, 2.6, 2.7, 2.8, 2.9, 3.0, 3.1 , 3.2, 3.3, 3.4, 3.5.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 0.01 % to 15%, preferably from about 1 % to 12%, and more preferably from about 3% to 9% by weight, based on the total weight of the composition.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 3, 4, 5, 6, 7, 8, 9.
- the surfactant in form of emulsifier according to the present invention include steareth-2, steareth-20.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 18%, and more preferably from about 5% to 15% by weight, based on the total weight of the composition.
- the surfactant in form of emulsifier may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15.
- the surfactant in form of emulsifier according to the present invention is PPG-14 butyl ether.
- the cosmetic compositions of the present invention optionally may contain one or more solvent.
- the solvent of the composition typically comprises water although it is possible to include co-solvents which are miscible with the water.
- the solvent consists essentially of water.
- the solvent can be any solvent known or otherwise effective in solubilizing or helping to maintain solubilization of the antiperspirant actives described herein, and which is otherwise suitable for topical application to the skin.
- the solvent can therefore be used to solubilize the antiperspirant active during formulation, or may be added to the composition separate from the solubilized antiperspirant active component with the effect of maintaining or further solubilizing the antiperspirant active in the finished product.
- concentration of the selected solvent will vary depending upon the particular formulation selected, e.g., active concentration selected.
- Suitable solvents for solubilizing the antiperspirant active include water, short chain monohydric alcohols (e.g., C1 -C10) such as ethanol, and polyols capable of solubilizing or helping to solubilize the antiperspirant active in the composition.
- the polyols for use in the antiperspirant composition of the present invention preferably have 2 or more hydroxyl groups with 2 of the hydroxyl groups attached to the a and ⁇ carbons of the polyol.
- the polyols preferably have from about 3 to about 8 carbon atoms, and preferably have either 2 or 3 hydroxyl groups in total.
- the antiperspirant compositions of the present invention may be aqueous or anhydrous, and therefore the solvent for the antiperspirant active may be aqueous or anhydrous. Both the antiperspirant composition and the solvent are preferably anhydrous.
- the solvent may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 0.01 % to 85%, preferably from about 1 % to 75%.
- the solvent according to the present invention include water, propylene carbonate, isododecane, caprylyl glycol.
- the solvent may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount of from about 30% to 85%, preferably from about 35% to 80%, and more preferably from about 40% to 75% by weight, based on the total weight of the composition.
- the solvent may be present in a deodorant antiperspirant roll-on composition according to the invention in an amount ranging of 40, 41 , 42, 43, 44, 45, 46, 47, 48, 49, 50, 51 , 52, 53, 54, 55, 56, 57, 58, 59, 60, 61 , 62, 63,64, 65, 66, 67, 68, 69, 70, 71 , 72, 73, 74, 75.
- the solvent according to the present invention is water.
- the solvent may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 0.1 % to 8%, preferably from about 1 % to 7%, and more preferably from about 2% to 5% by weight, based on the total weight of the composition.
- the solvent may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 1 , 2, 3, 4, 5, 6, 7.
- the solvent according to the present invention is propylene carbonate, isododecane.
- the solvent may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount of from about 20% to 80%, preferably from about 30% to 70%, and more preferably from about 35% to 65% by weight, based on the total weight of the composition.
- the solvent may be present in a deodorant antiperspirant soft-solid composition according to the invention in an amount ranging of 30, 31 , 32, 33, 34, 35, 36, 37, 38, 39, 40, 41 , 42, 43, 44, 45, 46, 47, 48, 49, 50, 51 , 52, 53, 54, 55, 56, 57, 58, 59, 60, 61 , 62, 63, 64, 65, 66, 67, 68, 69, 70.
- the solvent according to the present invention is water, caprylyl glycol.
- Propellants generally used in products of this type and that are well known to those skilled in the art are, for example, dimethyl ether (DME), volatile hydrocarbons such as n-butane, propane, isobutane and mixtures thereof, carbon dioxide gas, nitrous oxide, nitrogen, or compressed air.
- DME dimethyl ether
- volatile hydrocarbons such as n-butane, propane, isobutane and mixtures thereof
- carbon dioxide gas such as n-butane, propane, isobutane and mixtures thereof
- nitrogen nitrous oxide
- compressed air compressed air
- the compositions as defined previously and the propellant(s) may be in the same compartment or in different compartments in the aerosol container.
- the dispensing means which forms a part of the aerosol device, is generally composed of a dispensing valve controlled by a dispensing head, itself comprising a nozzle via which the aerosol composition is vaporized.
- the container comprising the pressurized composition can be opaque or transparent. It can be made of glass, of polymer or of metal, optionally covered with a protective lacquer layer.
- the propellant may be present in a deodorant antiperspirant composition according to the invention in an amount of from about 1 % to 95%, preferably from about 45% to 90% by weight, based on the total weight of the composition.
- the propellant according to the present invention includes isobutene, butane, propane.
- the propellant may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount of from about 40% to 95%, preferably from about 45% to 90% by weight, based on the total weight of the composition.
- the propellant may be present in a deodorant antiperspirant aerosol composition according to the invention in an amount ranging of 45, 46, 47, 48, 49, 50, 51 , 52, 53, 54, 55, 56, 57, 58, 59, 60, 61 , 62, 63, 64, 65, 66, 67, 68, 69, 70, 71 , 72, 73, 74, 75, 76, 77, 78, 79, 80, 81 , 82, 83, 84, 85, 86, 87, 88, 89, 90.
- the propellant according to the present invention includes isobutene, butane, propane.
- the cosmetic compositions of the present invention optionally may contain one or more thickening agent.
- the thickening agent of the composition typically comprises hydroxypropyl cellulose and its copolymer.
- distarch phosphates or of compounds rich in distarch phosphate in particular the distarch phosphate hydroxypropyl ethers having the INCI name: Hydroxypropyl Starch Phosphate, for instance the products sold under the trade names Farinex VA70 C or Farmal MS 689® from the company Avebe Stadex; the products sold under the trade names Structure BTC®, Structure HVS®, Structure XL® or Structure Zea® from National Starch (corn distarch phosphate).
- the thickening agent may be present in a deodorant antiperspirant soft- solid composition according to the invention in an amount of from about 0.01 % to 6%, preferably from about 1 % to 4% by weight, based on the total weight of the composition.
- the thickening agent may be present in a deodorant antiperspirant soft- solid composition according to the invention in an amount ranging of 1 , 2, 3. 4.
- the cosmetic compositions of the present invention optionally may contain one or more solidifying agent.
- the solidifying agent must be effective to solidify the composition, which means that it will cause a semi-solid or solid to be formed at room temperature.
- Waxes are suitable solidifying agents.
- High melting point waxes which have a melting point ranging from 65°-1 10° C. are good solifying agents. Waxes falling into this category include hydrogenated castor oil, paraffin, synthetic wax, ceresin, beeswax, spermaceti, carnauba, candelilla, montan wax, and other Fisher Tropsch waxes such as microcrystalline waxes and mixtures thereof.
- Low melting point waxes which have a melting point of 37° to 65° C. are also good solidifying agents.
- Such waxes include fatty alcohols, fatty acids, fatty acid esters, and fatty acid amides having fatty chains from 8 to 30 carbons, and mixtures thereof.
- the solidifying agent may be present in a deodorant antiperspirant stick composition according to the invention in an amount of from about 0.01 % to 20%, preferably from about 1 % to 18%, more preferably from about 5% to 15% by weight, based on the total weight of the composition.
- the thickening agent may be present in a deodorant antiperspirant stick composition according to the invention in an amount ranging of 1 , 2, 3. 4, 5, 6, 7, 8, 9, 10, 1 1 , 12, 13, 14, 15.
- compositions according to the invention may additionally comprise cosmetic adjuvants chosen from fragrances, pigments, chelating agents, softeners, antioxidants, opacifiers, stabilizers, moisturizing agents, vitamins, bactericides, preservatives, polymers, thickening agents, or any other ingredient commonly used in cosmetics for this type of application.
- cosmetic adjuvants chosen from fragrances, pigments, chelating agents, softeners, antioxidants, opacifiers, stabilizers, moisturizing agents, vitamins, bactericides, preservatives, polymers, thickening agents, or any other ingredient commonly used in cosmetics for this type of application.
- composition ingredients serve to illustrate the invention without however exhibiting a limiting character.
- amounts of the composition ingredients are given as weight percentages relative to the total weight of the composition.
- the inventive mica combination of beige/silver and beige/gold mica combinations shows significant improvement in the masking of the dark stains and imperfections on underarm areas. Additionally, a beige/silver and beige/gold mica combination reduces the transference of an antiperspirant deodorant on fabrics of both light and dark colors.
- Example II, Example III and Example IV optimizes the masking of the dark stains and imperfections on underarm areas.
- the formula has unique dry sensorial, that consumers appreciated. Additionally, the formula shows a very good adherence to the skin which helps to enhance the contact of the active to the skin and reduces the fabric transfer.
- Example II enhances the masking coverage on skin and provides homogenous skin tone for both dark and light prototypes. Additionally, Example II reduces the transference of roll-on antiperspirant deodorant to the fabric compared to Example III and Example IV.
- the inventive examples optimizes the masking of the dark stains and imperfections on underarm areas.
- the formula has a unique dry sensorial, that consumers appreciated. Additionally, the formula shows a very good adherence to the skin which helps to enhance the contact of the active to the skin and reduces the fabric transfer.
- Example III enhances the masking coverage on skin and optimizes the skin tone matching for both dark and light prototypes. Additionally, Example III reduces the transference of an aerosol antiperspirant deodorant to the fabric compared to Example II and Example IV.
- Example II optimizes masking of the dark stains and imperfections on underarm areas, while matching skin tone on both dark and light prototypes.
- the formula has unique dry sensorial, that consumers appreciated. Additionally, the formula shows a very good adherence to the skin which helps to enhance the contact of the active to the skin and reduces the fabric transfer. Moreover, compare to the benchmark Example I in the table, inventive Example II reduces the transference of a soft-solid antiperspirant deodorant on fabrics of both light and dark colors; while still enhancing the masking of the dark stains and imperfections on underarm areas.
- Example II optimizes masking of the dark stains and imperfections on underarm areas, while matching skin tone on both dark and light prototypes.
- the formula had unique dry sensorial, which was very appreciated by consumers. Additionally, the formula also shows a very good adherence to the skin which helped to enhance the contact of the active to the skin and reduce the fabric transfer. Moreover, compare to the benchmark Example I in the table, inventive Example II reduces the transference of a stick antiperspirant deodorant on fabrics of both light and dark colors; while still enhancing the masking of the dark stains and imperfections on underarm areas.
- Example II, III and IV provides an optimized skin tone matching on both dark and light prototypes.
- an Example II with a concentration of 0.1 % of beige/silver masking mica composition provides an enhanced masking of the dark stains and imperfections on underarm areas, compared to an Example III with a concentration of 0.2% and an Example IV with a concentration of 0.5% of beige/silver masking mica composition.
- Example II, III and IV reduces the stains transfer of a roll-on antiperspirant deodorant on fabrics of both light and dark colors. Moreover, an Example II with a concentration of 0.1 % of beige/silver masking mica composition lessens the fabric transfer, compared to an Example III with a concentration of 0.2% and an Example IV with a concentration of 0.5% of beige/silver masking mica composition; while still enhancing the masking of the dark stains and imperfections on underarm areas.
- Example II, III and IV provides an optimized skin tone matching on both dark and light prototypes.
- an Example III with a concentration of 0.2% of beige/silver masking mica composition provides an enhanced masking of the dark stains and imperfections on underarm areas, compared to an Example II with a concentration of 0.1 % and an Example IV with a concentration of 0.5% of beige/silver masking mica composition.
- Example II, III and IV reduces the stains transfer of aerosol antiperspirant deodorant on fabrics of both light and dark colors. Moreover, an Example III with a concentration of 0.2% of beige/silver masking mica composition lessens the fabric transfer, compared to an Example II with a concentration of 0.1 % and an Example IV with a concentration of 0.5% of beige/silver masking mica composition; while still enhancing the masking of the dark stains and imperfections on underarm areas.
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Abstract
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2016/050274 WO2018076083A1 (fr) | 2016-10-31 | 2016-10-31 | Composition déodorante anti-transpirantes de masquage |
| BR112019006327A BR112019006327A2 (pt) | 2016-10-31 | 2016-10-31 | composição antiperspirante desodorante, composição roll-on antiperspirante desodorante, composição aerossol antiperspirante desodorante anidra, composição sólida macia antiperspirante desodorante, composição em bastão antiperspirante desodorante e método para mascarar a imperfeição da pele e reduzir a transferência ao tecido |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2016/050274 WO2018076083A1 (fr) | 2016-10-31 | 2016-10-31 | Composition déodorante anti-transpirantes de masquage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2018076083A1 true WO2018076083A1 (fr) | 2018-05-03 |
Family
ID=57256009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/BR2016/050274 Ceased WO2018076083A1 (fr) | 2016-10-31 | 2016-10-31 | Composition déodorante anti-transpirantes de masquage |
Country Status (2)
| Country | Link |
|---|---|
| BR (1) | BR112019006327A2 (fr) |
| WO (1) | WO2018076083A1 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109655433A (zh) * | 2019-02-25 | 2019-04-19 | 鲁泰纺织股份有限公司 | 织物和服装在穿着过程中遮盖效果的直观测试方法 |
| GB2571400A (en) * | 2017-11-23 | 2019-08-28 | Henkel Kgaa | Cosmetic compositions with reduced oily or greasy feel on the skin |
| WO2020219576A1 (fr) * | 2019-04-22 | 2020-10-29 | Joban Beauty, Inc. | Produit cosmétique déodorant |
| WO2022047111A1 (fr) * | 2020-08-31 | 2022-03-03 | Colgate-Palmolive Company | Compositions de soins personnels |
| WO2022178598A1 (fr) * | 2021-02-26 | 2022-09-01 | L'oreal | Compositions cosmétiques en bâton, utilisation de la composition cosmétique en bâton et procédé de fabrication de la composition cosmétique en bâton |
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| WO2016005248A1 (fr) * | 2014-07-09 | 2016-01-14 | L'oreal | Poudre anhydre libre ou compacte a base de particules encapsulant un agent benefique |
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2016
- 2016-10-31 BR BR112019006327A patent/BR112019006327A2/pt active Search and Examination
- 2016-10-31 WO PCT/BR2016/050274 patent/WO2018076083A1/fr not_active Ceased
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|---|---|---|---|---|
| US3792068A (en) | 1971-04-02 | 1974-02-12 | Procter & Gamble | Dry powder aerosol antiperspirant composition incorporating dry powder antiperspirant active complex and process for its preparation |
| JPS61194009A (ja) | 1985-02-21 | 1986-08-28 | Toray Silicone Co Ltd | メ−クアツプ化粧料 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2571400A (en) * | 2017-11-23 | 2019-08-28 | Henkel Kgaa | Cosmetic compositions with reduced oily or greasy feel on the skin |
| US11147756B2 (en) | 2017-11-23 | 2021-10-19 | Henkel Ag & Co. Kgaa | Cosmetic compositions with reduced oily or greasy feel on the skin |
| GB2571400B (en) * | 2017-11-23 | 2022-05-11 | Henkel Kgaa | Cosmetic compositions with reduced oily or greasy feel on the skin |
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| CN109655433B (zh) * | 2019-02-25 | 2021-08-24 | 鲁泰纺织股份有限公司 | 织物和服装在穿着过程中遮盖效果的直观测试方法 |
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| WO2022047111A1 (fr) * | 2020-08-31 | 2022-03-03 | Colgate-Palmolive Company | Compositions de soins personnels |
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| WO2022178598A1 (fr) * | 2021-02-26 | 2022-09-01 | L'oreal | Compositions cosmétiques en bâton, utilisation de la composition cosmétique en bâton et procédé de fabrication de la composition cosmétique en bâton |
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| Publication number | Publication date |
|---|---|
| BR112019006327A2 (pt) | 2019-06-25 |
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