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WO2018074439A1 - Produit cosmétique - Google Patents

Produit cosmétique Download PDF

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Publication number
WO2018074439A1
WO2018074439A1 PCT/JP2017/037444 JP2017037444W WO2018074439A1 WO 2018074439 A1 WO2018074439 A1 WO 2018074439A1 JP 2017037444 W JP2017037444 W JP 2017037444W WO 2018074439 A1 WO2018074439 A1 WO 2018074439A1
Authority
WO
WIPO (PCT)
Prior art keywords
component
mass
less
cosmetic
polyoxyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2017/037444
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English (en)
Japanese (ja)
Inventor
堀住　輝男
青崎　泰輔
千賀 竹原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to CN201780063862.0A priority Critical patent/CN109843254B/zh
Priority to MYPI2019001919A priority patent/MY188643A/en
Publication of WO2018074439A1 publication Critical patent/WO2018074439A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362—Polycarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin

Definitions

  • the present invention relates to cosmetics, particularly skin cosmetics.
  • Deodorant cosmetics are used as cosmetics to control the stickiness and smell of sebum and sweat and to give a refreshing feeling.
  • Such deodorant cosmetics contain various metal salts that are antiperspirants and bactericidal components. And the technique which improves a feeling of use etc. in addition to an antiperspirant action and a bactericidal action is reported.
  • powdered solid cosmetics containing powder in addition to antiperspirant ingredients and bactericidal ingredients (Patent Document 1), cosmetics containing ferulic acid and a bactericidal agent (Patent Document 2), artepilin C and a bactericidal agent Cosmetics (Patent Document 3), plant extracts such as geranium, cosmetics containing a bactericide and a cationic surfactant (Patent Document 4), benzyl glyceryl ether, isopropylmethylphenol and polyhydric alcohol and / or Deodorant stick (Patent Document 6), antibacterial component, cyclodeodorant composition (Patent Document 5) for external application of skin containing nonionic surfactant, silicone gel, polyhydric alcohol fatty acid ester powder, solidifying agent and deodorant component Dextrin-based compound, external composition for skin containing solid wax (Patent Document 7), aluminum compound and phenol A system fungicide, an aldehyde perfume, antipers
  • Patent Document 1 JP 2010-77094 (Patent Document 2) JP 2010-116376 (Patent Document 3) JP 2011-126862 (Patent Document 4) JP 2012-51845 (Patent Document 3) Document 5) Japanese Patent Application Laid-Open No. 2012-219046 (Patent Document 6) Japanese Patent Application Laid-Open No. 2015-3891 (Patent Document 7) Japanese Patent Application Laid-Open No. 2016-88925 (Patent Document 8) Japanese Patent Application Laid-Open No. 2016-113447
  • the present invention provides a cosmetic containing the following components (A) to (D).
  • (A) Isopropylmethylphenol 0.01% by mass or more and 0.2% by mass or less
  • (B) Carboxylic acid or salt thereof 0.1% by mass or more and 3% by mass or less
  • (D) Nonionic surfactant of HLB 10-13 0.005 mass% or more and 1 mass% or less
  • the conventional deodorant cosmetics have not been sufficient in the persistence of antiperspirant action and bactericidal action, the feeling of use, particularly the persistence on the skin of the bactericides necessary for the expression of deodorizing effects and long-term storage stability. Therefore, the present invention is to provide a cosmetic that is excellent in not only the feeling of use such as stickiness and coolness and the bactericidal effect, but also the persistence of the bactericidal component on the skin and the long-term storage stability of the bactericidal component.
  • the cosmetic of the present invention a sufficient amount of isopropylmethylphenol, which is a bactericidal component, remains on the skin even after sweating, the bactericidal effect is sustained, there is no stickiness, a cool feeling is good, and a long-term storage stability is also good. Therefore, the cosmetic of the present invention is useful as a skin cosmetic, particularly as a deodorant cosmetic.
  • Component (A) of the cosmetic of the present invention is isopropylmethylphenol.
  • Isopropyl methylphenol has a strong bactericidal action and is blended in the cosmetic of the present invention as a bactericidal component and a deodorizing component.
  • the content of the component (A) is 0.01% by mass or more in the total amount of the cosmetic from the viewpoint of obtaining a sufficient bactericidal effect, the viewpoint of persistence on the skin, the viewpoint of long-term storage stability, and the feeling of use. .2% by mass or less, preferably 0.02% by mass or more, more preferably 0.05% by mass or more, and from the viewpoint of long-term storage stability, preferably 0.15% by mass or less. More preferably, it is 0.10 mass% or less.
  • the range of preferable content of a component (A) is 0.02 mass% or more and 0.15 mass% or less, More preferably, it is 0.05 mass% or more and 0.10 mass% or less.
  • Component (B) is a carboxylic acid or a salt thereof.
  • the component (B) is blended for decreasing the pH of the skin and expressing the deodorizing effect by suppressing the growth of bacteria and maintaining the deodorizing effect, the stability of the cosmetics, and reducing stickiness.
  • the carboxylic acid or a salt thereof preferably includes an organic carboxylic acid having 1 to 8 carbon atoms or a salt thereof, more preferably an organic carboxylic acid having 3 to 8 carbon atoms or a salt thereof.
  • carboxylic acid of component (B) examples include monocarboxylic acids such as acetic acid, propionic acid and caprylic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid and fumaric acid; glycolic acid And hydroxycarboxylic acids such as lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid and citric acid; aromatic carboxylic acids such as benzoic acid, salicylic acid and phthalic acid; and acidic amino acids such as glutamic acid and aspartic acid.
  • monocarboxylic acids such as acetic acid, propionic acid and caprylic acid
  • dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid and fumaric acid
  • glycolic acid And hydroxycarboxylic acids such as lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric
  • the counter ion constituting the salt include alkali metals such as sodium and potassium; alkaline earth metals such as calcium and magnesium; ammonium; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine; arginine, Examples include cations derived from basic amino acids such as lysine.
  • the salt is preferably an alkali metal salt, more preferably a sodium salt.
  • the component (B) the viewpoint of leaving the component (A) on the skin, the expression of the deodorizing effect by inhibiting the growth of bacteria and the sustainability of the deodorizing effect, the long-term stability of the component (A), and the stickiness From the viewpoint of reducing feeling, it is preferably one or more selected from the group consisting of dicarboxylic acids, hydroxycarboxylic acids and salts thereof, more preferably citric acid, succinic acid, adipic acid and salts thereof. It is 1 type, or 2 or more types selected from the group which consists of. Furthermore, citric acid that can maintain the pH of the skin at 5 or less is particularly preferable in order to exhibit a deodorizing effect and maintain the effect.
  • the content of the component (B) is the viewpoint of leaving the component (A) on the skin, the expression of the deodorizing effect by inhibiting the growth of bacteria and the sustainability of the deodorizing effect, the viewpoint of the long-term stability of the component (A), From the viewpoint of reducing stickiness, it is 0.1% by mass or more and 3% by mass or less, preferably 0.2% by mass or more, more preferably 0.5% by mass or more in the total amount of the cosmetic. Preferably it is 2.8 mass% or less, More preferably, it is 2.5 mass% or less.
  • the specific range of the preferable content of the component (B) is preferably 0.2% by mass or more and 2.8% by mass or less, and more preferably 0.5% by mass or more and 2.5% by mass or less.
  • Component (C) is 1,3-butylene glycol.
  • Component (C) contributes to the action of leaving component (A) on the skin, the long-term storage stability of component (A), bactericidal performance, cool feeling, and reduction in stickiness.
  • the content of the component (C) is in the total amount of the cosmetic from the viewpoint of obtaining a sufficient bactericidal effect, the viewpoint of persistence on the skin, the viewpoint of long-term storage stability, the viewpoint of reducing stickiness, and the viewpoint of coolness.
  • component (C) is 0.5% by mass or more and 8% by mass or less, more preferably 1.0% by mass or more and 5% by mass or less, and further preferably 1.2% by mass or more. 3% by mass or less.
  • the content ratio (A / C) of the component (A) to the component (C) in the cosmetic of the present invention is a viewpoint that a sufficient amount of the component (A) remains on the skin and a viewpoint of long-term storage stability of the component (A)
  • 0.005 or more is preferable, 0.010 or more is more preferable, and 0.02 or more is more preferable.
  • 0.03 or more is more preferable, 0.04 or more is further more preferable, 0.6 or less is preferable, 0.4 or less is more preferable, 0.2 or less is further preferable, and 0.1 or less is even more preferable.
  • the specific A / C range is preferably 0.005 or more and 0.6 or less, more preferably 0.010 or more and 0.5 or less, further preferably 0.01 or more and 0.4 or less, and 0.02 or more and 0 or less. .4 or less is more preferable, 0.03 or more and 0.2 or less is more preferable, and 0.04 or more and 0.1 or less is even more preferable.
  • Component (D) is a nonionic surfactant having an HLB of 10 to 13.
  • Component (D) is a nonionic surfactant having an HLB of 10 to 13. From the viewpoint of improving the emulsion stability in the component (A) agent, suppressing adsorption to the container, and improving long-term storage stability. Those having HLB 11 to 13 are more preferable, and those having HLB 12 to 13 are more preferable.
  • the HLB value is an index indicating a hydrophilic-lipophilic balance. In the present invention, a value calculated by the following equation by Oda and Teramura et al. Is used.
  • the HLB value is the HLB of each nonionic surfactant before blending.
  • Component (D) is preferably polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether having an alkyl group or alkenyl group having 10 to 18 carbon atoms (hereinafter also referred to as polyoxyethylene alkyl ether in the present invention).
  • the carbon number indicates the carbon number of the alkyl group or alkenyl group constituting the polyoxyethylene alkyl ether in the present invention, and improves the emulsion stability in the component (A) agent, suppresses adsorption to the container, and stabilizes long-term storage.
  • 10 to 16 carbon atoms are preferable, and 12 to 14 carbon atoms are more preferable.
  • the polyoxyethylene alkyl ether having an alkyl group having the above carbon number is preferable.
  • polyoxyethylene lauryl ether (carbon number 12), polyoxyethylene myristyl ether (carbon number 14), polyoxyethylene cetyl ether (carbon number 16), polyoxyethylene oleyl ether (carbon number 18), etc.
  • Polyoxyethylene lauryl ether is preferable.
  • polyoxyethylene lauryl ether (5EO) HLB: 10.6
  • polyoxyethylene lauryl ether (6EO) HLB: 11.5)
  • polyoxyethylene lauryl ether 7E.O.
  • polyoxyethylene lauryl ether 8E.O.
  • HLB: 12.9 polyoxyethylene lauryl ether
  • improvement of emulsification stability in the component (A) agent Polyoxyethylene lauryl ether (7E.O.) (HLB: 12.2), poly, from the viewpoint of suppressing adsorption to the container and improving long-term storage stability, from the viewpoint of reducing stickiness, from the viewpoint of coolness, and from the viewpoint of bactericidal performance
  • Oxyethylene lauryl ether (6E.O.) HLB: 11.5)
  • polyoxyethylene lauryl ether (6E.O.) HLB: 11.5) is more preferred.
  • the number of moles of ethylene oxide added to the polyoxyethylene alkyl ether in the present invention is improved in emulsification stability in the component (A) agent, reduced in adsorption to the container and improved in long-term storage stability, reduced in stickiness, From the viewpoint of coolness and the viewpoint of bactericidal performance, 3 or more and 9 or less are preferable, 4 or more and 8 or less are more preferable, and 5 or more and 7 or less are more preferable.
  • the content of component (D) is the improvement of emulsification stability in the agent of component (A), the viewpoint of suppression of adsorption to the container and the improvement of long-term storage stability, the viewpoint of stickiness reduction, the viewpoint of cool feeling, the sterilization performance
  • the total amount of the cosmetic is preferably 0.005% by mass or more, more preferably 0.006% by mass or more, further preferably 0.008% by mass or more, and still more preferably 0.01% by mass.
  • 1.0 mass% or less is preferable, 0.8 mass% or less is more preferable, and 0.5 mass% or less is still more preferable.
  • it is 0.005% by mass or more and 1% by mass or less, preferably 0.006% by mass or more and 1% by mass or less, more preferably 0.008% by mass or more and 0.8% by mass or less. More preferably, it is 0.01 mass% or more and 0.5 mass% or less.
  • the cosmetic of the present invention has a component (E) HLB value of 4 to 7, and a glyceryl group that is liquid at 25 ° C. It is preferable to contain the nonionic surfactant which has.
  • the liquid state at 25 ° C. means that the viscosity at 25 ° C. is 100,000 mPa ⁇ s or less.
  • nonionic surfactants include those having a branched alkyl group or alkenyl group having 8 to 22 carbon atoms and bonded to a glyceryl group via an ether bond or an ester bond, or bonded via an alkylene oxide group. preferable.
  • Nonionic surfactants having a glyceryl group and having an HLB value of 4-7 in component (E) and having a glyceryl group include, for example, alkyl glyceryl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glyceryl. 1 type (s) or 2 or more types chosen from ether fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, etc. are preferable.
  • alkyl glyceryl ethers and glycerin fatty acid esters are preferable, and further one selected from alkyl glyceryl ethers. Or 2 or more types are preferable.
  • component (E) examples include isostearyl glyceryl ether (HLB5.4), 2-ethylhexyl glyceryl ether (HLB7), glyceryl monoisostearate (HLB6), monoisostearic acid (degree of polymerization 2) polyglyceryl (HLB5).
  • isostearyl glyceryl ether 2-ethylhexyl glyceryl ether, and glyceryl monoisostearate are preferable from the viewpoint of improving the persistence of the component (A) on the skin and cooling, and isostearyl glyceryl from the viewpoint of feeling of use. Ether is preferred.
  • the content of the component (E) is preferably 0.01 to 1% by mass, more preferably 0.01 to 0.8% by mass in the total amount of the cosmetic from the viewpoint of improving the persistence on the skin and the cool feeling. More preferably, it is 0.01 to 0.5% by mass.
  • the content mass ratio (D / E) of the component (D) and the component (E) in the cosmetic of the present invention is preferably 1 or more from the viewpoint of the persistence of the component (A) on the skin and long-term storage stability, Moreover, 100 or less is preferable, 80 or less is preferable and 60 or less is more preferable.
  • the preferred range of D / E is preferably 1 to 100, more preferably 1 to 80, and even more preferably 1 to 60.
  • the cosmetics of the present invention have an excellent bactericidal effect and excellent persistence of the component (A) on the skin, as well as a feeling of use such as no stickiness, and a cool feeling.
  • the content of the component (A) is maintained even after long-term storage in a resin container such as polyethylene. Therefore, the cosmetic of the present invention is useful as a skin cosmetic (including scalp), and particularly useful as a deodorant cosmetic.
  • the cosmetics of the present invention include bactericides other than component (A), antiperspirants, powders, fats and oils, waxes, silicones, hydrocarbon oils, higher fatty acids, higher alcohols, and synthetic esters.
  • Oil, other surfactants, polymer compounds, antioxidants, dyes, emulsion stabilizers, pH adjusters, astringents, preservatives, UV absorbers, chelating agents, moisturizers, thickeners, cooling agents, anti Inflammatory agents, amino acids, vitamin agents, various plant extracts, water and the like can be contained.
  • Bactericides other than component (A) include benzalkonium chloride, triclosan, piroctone olamine, benzethonium chloride, alkyltrimethylammonium chloride, cetyltrimethylammonium bromide, triclocarban, salicylic acid, paraben, chlorhexidine or a salt thereof, lysozyme Or a salt thereof, acrinol, ethanol, gluconic acid, alkyldiaminoglycine or a salt thereof, popidone iodine, potassium iodide, iodine, cresol, photosensitizer 101, photosensitizer 201, phenoxyethanol, 1,2-pentanediol, halocarban, Examples include 3,4,4-trichlorocarbanilide, triethyl citrate, resorcin, phenol, sorbic acid, hexachlorophene, silver-supported zeolite, and silver
  • Antiperspirants include: chlorohydroxyaluminum, zinc oxide, zinc phenolsulfonate, aluminum chloride, potassium aluminum sulfate, aluminum sulfate, aluminum acetate, allantochlorohydroxyaluminum, aluminum zirconium octachlorohydrate, aluminum zirconium tetrachlorohydrate, Examples include aluminum zirconium trichlorohydrate and zirconium chlorohydrate.
  • the antiperspirant there is no problem whether or not the antiperspirant is blended, but it is more preferable not to blend it from the viewpoint of the persistence of the component (A) on the skin and the feeling of use.
  • the dosage form of the cosmetic of the present invention is not particularly limited, and examples thereof include creams, roll-on types, mists, lotions, aerosols, sprays, sticks, emulsions, gels, sheet-like forms impregnated with nonwoven fabrics, and the like.
  • the form of cream, roll-on type, spray type, mist or lotion is more preferable from the viewpoint of enhancing the persistence of component (A) on the skin.
  • the melting point as component (F) Is an oily component at 60 ° C. or higher, polyether-modified silicone as component (G), organic powder as component (H), inorganic powder as component (I), antioxidant as component (J) and component (K)
  • polyether-modified silicone as component (G) organic powder as component (H)
  • inorganic powder as component (I) antioxidant as component (J)
  • component (K) One or more selected from poly (N-acylalkylenimine) -bonded silicone polymers can be contained.
  • the oily component having a melting point of component (F) of 60 ° C. or higher is a solid component having a melting point of 60 ° C. or higher and a solid at room temperature (25 ° C.), preferably having a melting point of 60 to 110 ° C.
  • fusing point is a thing measured by the quasi-drug raw material specification I (General test method, 70. Melting
  • oily components are those used in normal skin external preparations, and include solid oils such as hydrocarbons, waxes, esters, silicones, animal waxes, vegetable waxes, mineral waxes, synthetic waxes, and the like. It is selected from waxes and mixtures thereof.
  • solid oils such as hydrocarbons, waxes, esters, silicones, animal waxes, vegetable waxes, mineral waxes, synthetic waxes, and the like. It is selected from waxes and mixtures thereof.
  • paraffin, ceresin, synthetic hydrocarbon wax, Fischer-Tropsch wax, microcrystalline wax, polyethylene wax, ethylene propylene copolymer, candelilla wax, beeswax, carnauba wax and the like can be used.
  • hydrocarbons are preferable, and ceresin (melting point: 72 to 76 ° C.), microcrystalline wax (melting point: 60 to 85 ° C.), polyethylene wax (melting point: 75 to 105 ° C.), paraffin wax (melting point: 70 to 78 ° C.) )
  • ceresin melting point: 72 to 76 ° C.
  • microcrystalline wax melting point: 60 to 85 ° C.
  • polyethylene wax melting point: 75 to 105 ° C.
  • paraffin wax melting point: 70 to 78 ° C.
  • the content of the component (F) is preferably 0.5 to 10% by mass, more preferably 0.5 to 8% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use.
  • 1 to 6% by mass is more preferable.
  • the polyether-modified silicone of component (G) may be a dimethylpolysiloxane having a polyoxyethylene group or a polyoxypropylene group, and examples thereof include those represented by the following formula (1) or (2). These may be used alone or in combination of two or more.
  • R 1 represents — (CH 2 ) 3 —O— (C 2 H 4 O) p — (C 3 H 6 O) q —A
  • A represents a hydrogen atom or a carbon number
  • R 2 each independently represents a methyl group or — (CH 2 ) 3 —O— (C 2 H 4 O) s — (C 3 H 6 O) t —B
  • B represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, and s and t are Each independently represents an integer of 0 to 50, and s + t ⁇ 1)
  • m represents an integer of 1 to 2000
  • n represents an integer of 0 to 1000, provided that n is 0
  • at least one of R 2 is — (CH 2 ) 3 —O— (C 2 H 4 O) s —
  • G examples of commercially available components include KF6011, KF6012, KF6013, KF6015, KF6016, KF6017, KF6028 (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.
  • the content of the component (G) is preferably 0.01 to 10% by mass, preferably 0.05 to 5% by mass in the total amount of the cosmetic from the viewpoint of improving the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.1 to 3% by mass is even more preferable.
  • component (H) organic powder may be used singly or in combination of two or more.
  • the shape may be any of a spherical shape, a needle shape, and a plate shape. Further, it may be treated with alumina, silica, zinc or the like, or treated with silicone or the like.
  • organic powder examples include lauroyl lysine, methylpolysiloxane network polymer, cross-linked methylpolysiloxane, polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoro Examples thereof include ethylene powder and crosslinked resin powder.
  • the organic powder of the component (H) is more preferably one or more selected from a crosslinked resin powder, a methylpolysiloxane network polymer, and a crosslinked methylpolysiloxane.
  • the methylpolysiloxane network polymer and the crosslinked methylpolysiloxane are already commercially available as cosmetic raw materials and can be used without any limitation. Among them, those having a spherical shape and a particle size in the range of 0.09 to 30.0 ⁇ m are preferable, and more preferably 0.2 to 15 ⁇ m.
  • the average particle diameter is an average particle diameter when the powder is monodispersed, and is a volume average particle diameter of the particle diameter measured by a static light scattering method.
  • the methylsiloxane network polymer is a solid obtained by emulsion polymerization of methyltrimethoxysiloxane in an alkaline aqueous solution, and specific examples include Tospearl series (Tospearl 145A, etc.) manufactured by GE Toshiba Silicone.
  • the crosslinked methylpolysiloxane is obtained by polymerizing dimethoxydimethylsiloxane with a small amount of methyltrimethoxysiloxane, and has a crosslinked structure of methyltrimethoxysiloxane inside. This can be produced by emulsion polymerization in the same manner as the methylsiloxane network polymer.
  • the Toray Fill series manufactured by Toray Dow Corning Silicone (Trefill E506W, Trefil E505C, Trefil E506C, Trefill E505W). Etc.). These may be used alone or in combination, and those dispersed in various solvents and those previously mixed with other components can be used without any problem. These include, for example, Trefil E507 solution, BY29-119 and BY29-122.
  • X-52-1139K and X-52-1139G manufactured by Shin-Etsu Chemical Co., Ltd., which are silicone resin / rubber composite powders, may also be mentioned.
  • Tospearl series which is a methylsiloxane network polymer is particularly preferable in terms of smoothness.
  • crosslinked resin powder examples include a crosslinked (meth) acrylic ester resin powder described in JP-A-2006-225338.
  • the content of the organic powder of component (H) is preferably 1 to 40% by mass, and preferably 3 to 30% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 5 to 20% by mass is even more preferable.
  • Inorganic powders of component (I) include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, Muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silica, porous silica, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, silica Examples include strontium acid and metal tungstate.
  • the inorganic powder of the component (I) preferably contains silicic anhydride from the viewpoint of the persistence of the component (A) on the skin.
  • the content of the inorganic powder of component (I) is 0.1 to 20% by mass in the total amount of the cosmetic from the viewpoint of imparting the persistence of the component (A) on the skin and a smooth use feeling.
  • it is 0.5 to 15% by mass, more preferably 1 to 10% by mass.
  • dibutylhydroxytoluene (BHT) As an antioxidant of component (J), dibutylhydroxytoluene (BHT); butylhydroxyanisole; vitamin E such as ⁇ tocopherol and its derivatives; thiotaurine, evening primrose extract, ⁇ -carotene, catechin compound, flavonoid compound, polyphenol compound Etc. can be illustrated.
  • the catechin compound can be used as a green tea extract or the like.
  • dibutylhydroxytoluene (BHT) or ⁇ tocopherol is preferable from the viewpoint of improving the feeling in use.
  • These antioxidants may be used individually by 1 type, and may combine 2 or more types.
  • the content of the component (J) is 0.001% by mass or more, particularly 0.005% by mass or more, and 1% by mass or less from the viewpoint of reducing stickiness after application from the viewpoint of preventing oxidation.
  • the content is preferably 0.5% by mass or less.
  • the poly (N-acylalkylenimine) -bonded silicone-based polymer of component (K) is represented by the following formula (I) via an alkylene group containing a hetero atom at least one of the terminal or side chain silicon atoms of the organopolysiloxane segment.
  • Examples thereof include silicone-based polymers formed by bonding poly (N-acylalkylenimines) composed of repeating units represented by 3).
  • R 3 represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, a cycloalkyl group, an aralkyl group or an aryl group, and l represents a number of 2 or 3)
  • silicone polymers include poly (N-formylethyleneimine) modified silicone, poly (N-acetylethyleneimine) modified silicone, poly (N-propionylethyleneimine) modified silicone, poly (Nn-octa). Noylethyleneimine) modified silicone, poly (Nn-dodecanoylethyleneimine) modified silicone, poly (N-formylpropyleneimine) modified silicone, poly (N-acetylethyleneimine) modified silicone, poly (N-acetylpropyleneimine) ) Modified silicone, poly (N-propionylpropyleneimine) modified silicone, poly (Nn-octanoylpropyleneimine) modified silicone, poly (Nn-dodecanoylpropyleneimine) modified silicone, and the like.
  • the content of the component (K) is preferably 0.1 to 10% by mass, preferably 0.2 to 8% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.5 to 6% by mass is even more preferable.
  • the cosmetic of the present invention can be a roll-on type cosmetic.
  • the roll-on type is a cosmetic obtained by filling a roll-on container with a cosmetic composition, and is applied by applying a roll to an application site.
  • a lower alcohol having 2 to 4 carbon atoms as the component (L)
  • the component (M) is selected from the group consisting of sorbitan monooleate, sorbitan trioleate, sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate.
  • One or two or more types, trimethylsiloxysilicic acid as component (O), and poly (N-acylalkylenimine) -bonded silicone polymer as component (K) can be contained. .
  • the lower alcohol having 2 to 4 carbon atoms of the component (L) ethanol is preferable.
  • the content of the lower alcohol having 2 to 4 carbon atoms in the component (L) is preferably 20 to 80% by mass, and more preferably 40 to 80% by mass from the viewpoints of feeling upon use and cooling.
  • the persistence of the component (A) on the skin can be improved.
  • a water-soluble polymer any of natural polymers, semi-synthetic polymers, and synthetic polymers can be used.
  • natural polymers include xanthan gum, carrageenan, alginic acid and the like.
  • semi-synthetic polysaccharide polymers include modified polysaccharides such as hydroxycellulose, hydroxypropylcellulose, sodium carboxymethylcellulose, methylcellulose, hydroxymethylcellulose, and cationized cellulose.
  • Synthetic polymers include carbomers (cross-linked polyacrylic acid), polyacrylic acid, sodium polyacrylate, acrylic polymers such as acrylic acid / alkyl methacrylate copolymers; polyvinyl pyrrolidone, polyvinyl alcohol, cationized polyvinyl pyrrolidone, and the like. It is done. Of these, carbomer, acrylic acid / alkyl methacrylate copolymer, hydroxypropylcellulose, and sodium carboxymethylcellulose are preferred.
  • Examples of commercially available carbomers include carbopol 910, carbopol 934, carbopol 940, carbopol 941, carbopol 980, carbopol 981 (and above, manufactured by Lubrizol Advanced Materials, Inc.), etc., and acrylic acid / methacrylic acid.
  • Examples of commercially available acid alkyl copolymers include Carbopol 1382, Carbopol ETD2020, PEMULEN TR-1, and PEMULEN TR-2 (from Lubrizol Advanced Materials, Inc.).
  • HPC-M, HPC-H manufactured by Nippon Soda Co., Ltd.
  • commercially available products of sodium carboxymethylcellulose include CMC Daicel (Daicel Chemical Industries). Company, Ltd.), and the like.
  • Component (M) can be used alone or in combination of two or more, and the content is 0.01 mass in the total amount of the cosmetic from the viewpoint of the persistence of component (A) on the skin and the feeling of use. % Or more is preferable, 0.05 mass% or more is more preferable, 5 mass% or less is preferable, and 3 mass% or less is more preferable. In addition, the content of the component (M) is preferably 0.01 to 5% by mass and more preferably 0.05 to 3% by mass in the total amount of the cosmetic.
  • component (N) one or more selected from the group consisting of sorbitan monooleate, sorbitan trioleate, sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate are included. This improves the persistence of the component (A) on the skin and the feeling of use.
  • the content of the component (N) is preferably 0.01 to 3% by mass, and preferably 0.03 to 1% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. More preferred is 0.05 to 0.5% by mass.
  • the trimethylsiloxysilicic acid of component (O) is not limited as long as it is usually used in cosmetics. Any compound can be used, and is a compound having a crosslinked structure with a siloxane structure as the main skeleton, [(CH 3) 3 SiO 1/2] X [ SiO 2] represented by the Y (X is 1 ⁇ 3, Y is 0.5 to 8) are preferred.
  • the trimethylsiloxysilicic acid has a weight average molecular weight of preferably 1000 to 10,000, more preferably 2000 to 9000, more preferably 3000 to 6000, from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Are more preferred. Further, the property may be any of liquid, gum, paste, solid, etc.
  • the solvent for diluting or dispersing the component (O) is preferably one or more selected from dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and isododecane, and includes volatile dimethylpolysiloxane, deca More preferred is methylcyclopentasiloxane. Volatile means that it has a flash point of 35 to 90 ° C.
  • KF-7312T, KF-7312J, KF-7312K (manufactured by Shin-Etsu Chemical Co., Ltd.) or the like previously dissolved in a solvent can be preferably used.
  • the content of the component (O) is preferably 0.005 to 2% by mass, and preferably 0.008 to 1% by mass in the total amount of the cosmetic from the viewpoint of the persistence of the component (A) on the skin and the feeling of use. Is more preferable, and 0.01 to 0.5% by mass is even more preferable.
  • the content of the poly (N-acylalkylenimine) -bonded silicone polymer of component (K) is the total amount of cosmetics in terms of the persistence of component (A) on the skin and the feeling of use. Further, it is preferably 0.3 to 5% by mass, more preferably 0.4 to 4% by mass, and still more preferably 0.5 to 3% by mass.
  • the cosmetic of the present invention is in the form of mist, spray or lotion, in addition to the component (A), component (B), component (C), component (D) and component (E), the component ( P) as polyoxyethylene polyoxypropylene decyl tetradecyl ether (for example PPG-6 decyl tetradeces-30), polyether modified silicone as component (G), and ethanol as component (L) More than seeds can be included.
  • polyoxyethylene polyoxypropylene decyl tetradecyl ether for example PPG-6 decyl tetradeces-30
  • polyether modified silicone for example PPG-6 decyl tetradeces-30
  • component (G) More than seeds can be included.
  • the content of the component (P) is preferably 0.05 to 2% by mass, more preferably 0.08 to 1% by mass, and more preferably 0.1% to 0.1% by mass in the total amount of the cosmetic from the viewpoint of coolness and long-term storage stability. More preferably, 0.5% by mass.
  • the content of component (G) is preferably 0.05 to 2% by mass in the total amount of cosmetics in terms of elongation to the skin, familiarity, and stability over time. 0.08 to 1.5% by mass is more preferable, and 0.1 to 1% by mass is even more preferable.
  • the cosmetic of the present invention is used in various forms as described above, the components (A) to (D) and other components are added, mixed, heated as necessary, and various forms. It can be manufactured by filling a container according to the above.
  • the present invention further discloses the following cosmetics with respect to the embodiment described above.
  • a cosmetic containing the following components (A) to (D).
  • (A) Isopropylmethylphenol 0.01% by mass or more and 0.2% by mass or less
  • (B) Carboxylic acid or salt thereof 0.1% by mass or more and 3% by mass or less
  • (C) 1,3-butylene glycol 0.1% by mass 10 mass% or less
  • (D) Nonionic surfactant of HLB 10-13 0.005 mass% or more and 1 mass% or less
  • component (A) is preferably 0.02% by mass or more, more preferably 0.05% by mass or more, and preferably 0.15% by mass or less in the total amount of the cosmetic.
  • Component (B) is preferably an organic carboxylic acid having 1 to 8 carbon atoms or a salt thereof, more preferably an organic carboxylic acid having 3 to 8 carbon atoms or a salt thereof ⁇ 1> or ⁇ 2> Cosmetics described.
  • the component (B) is one or more selected from monocarboxylic acids, dicarboxylic acids, hydroxycarboxylic acids, aromatic carboxylic acids, acidic amino acids and salts thereof.
  • the content of ⁇ 6> component (B) is preferably 0.2% by mass or more, more preferably 0.5% by mass or more, and preferably 2.8% by mass or more in the total amount of the cosmetic.
  • the content of ⁇ 7> component (C) is preferably 0.5% by mass or more, more preferably 1.0% by mass or more, and further preferably 1.2% by mass or more in the total amount of the cosmetic.
  • the cosmetic according to any one of ⁇ 1> to ⁇ 6>, which is preferably 8% by mass or less, more preferably 5% by mass or less.
  • the mass ratio (A / C) of the component (A) and the component (C) is preferably 0.005 or more, more preferably 0.010 or more, still more preferably 0.02 or more, and still more preferably 0. 0.03 or more, more preferably 0.4 or more, and preferably 0.6 or less, more preferably 0.4 or less, further preferably 0.2 or less, and further preferably 0.1 or less.
  • component (D) is preferably a nonionic surfactant of HLB11 to 13, more preferably a nonionic surfactant of HLB12 to 13.
  • component (D) is a polyoxyethylene alkyl ether or polyoxyethylene alkenyl ether having an alkyl group or alkenyl group having 10 to 18 carbon atoms, more preferably a polyoxyethylene alkyl ether having an alkyl group having 10 to 16 carbon atoms.
  • the content of ⁇ 11> component (D) is preferably 0.005% by mass or more and 0.8% by mass or less, more preferably 0.006% by mass or more and 1% by mass or less, in the total amount of the cosmetic.
  • ⁇ 12> The cosmetic according to any one of ⁇ 1> to ⁇ 11>, further comprising a nonionic surfactant having a component (E) HLB value of 4 to 7 and having a liquid glyceryl group at 25 ° C.
  • Component (E) is selected from alkyl glyceryl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glyceryl ether fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester and the like ⁇ 12> description which is 1 type, or 2 or more types, Preferably it is 1 type, or 2 or more types chosen from alkyl glyceryl ether and glycerol fatty acid ester, More preferably, it is 1 type, or 2 or more types chosen from alkyl glyceryl ether Cosmetics.
  • component (E) is preferably 0.01 to 1% by mass, more preferably 0.01 to 0.8% by mass, and still more preferably 0.01 to 0.5% by mass.
  • the mass ratio (D / E) of the component (D) and the component (E) is preferably 1 or more, preferably 100 or less, more preferably 80 or less, and even more preferably 60 or less.
  • ⁇ 16> The cosmetic according to any one of ⁇ 1> to ⁇ 15>, preferably a skin cosmetic, and more preferably a deodorant cosmetic.
  • a bactericidal agent other than component (A) preferably benzalkonium chloride, triclosan, piroctone olamine, benzethonium chloride, alkyltrimethylammonium chloride, cetyltrimethylammonium bromide, triclocarban, salicylic acid, paraben, Chlorhexidine or its salt, lysozyme or its salt, acrinol, ethanol, gluconic acid, alkyldiaminoglycine or its salt, popidone iodine, potassium iodide, iodine, cresol, photosensitizer 101, photosensitizer 201, phenoxyethanol, 1,2- Selected from pentanediol, halocarban, 3,4,4-trichlorocarbanilide, triethyl citrate, resorcin, phenol, sorbic acid, hexachlorophene, silver-supported
  • an antiperspirant preferably chlorohydroxyaluminum, zinc oxide, zinc phenolsulfonate, aluminum chloride, potassium aluminum sulfate, aluminum sulfate, aluminum acetate, chlorohydroxyaluminum, allantochlorohydroxyaluminum and zinc paraphenolsulfonate.
  • the dosage form is selected from a sheet form impregnated with cream, roll-on type, mist, lotion, aerosol, spray, stick, emulsion, gel, nonwoven fabric, etc., preferably cream, roll-on type, spray type,
  • the dosage form is cream, and the component (F) is an oily component having a melting point of 60 ° C.
  • component (G) polyether-modified silicone
  • component (H) organic powder component (I) inorganic powder
  • the dosage form is a roll-on type, and component (L) a lower alcohol having 2 to 4 carbon atoms, component (M) a water-soluble polymer, component (N) sorbitan monooleate, sorbitan trioleate, One or more selected from the group consisting of sorbitan monoisostearate, polyoxyethylene oleyl ether and polyoxyethylene glyceryl triisostearate, component (O) trimethylsiloxysilicic acid, and component (K) poly (N-acyl)
  • the cosmetic according to any one of ⁇ 1> to ⁇ 19>, which contains one or more selected from (alkyleneimine) -bonded silicone polymers.
  • the dosage form is mist, spray or lotion, and further component (P) polyoxyethylene polyoxypropylene decyl tetradecyl ether (eg PPG-6 decyl tetradeces-30), component (G) modified with polyether
  • P polyoxyethylene polyoxypropylene decyl tetradecyl ether
  • G modified with polyether
  • ⁇ 23> Use of the cosmetic according to any one of ⁇ 1> to ⁇ 19> as a deodorant.
  • % means mass%.
  • IPMP isopropylmethylphenol
  • a 100 g polyethylene container was filled with 80 g preparation, stored at 50 ° C. for one month, the amount of IPMP contained in the preparation was quantified, and the amount adsorbed on the container was evaluated.
  • AA is more than 95% compared to the initial AA If BB is over 93% BB If 90% or more remains If less than 90% DD
  • Production Example 1 A beaker was charged with 82 g of lauryl methacrylate, 3 g of methacrylic acid, 15 g of ethylene glycol dimethacrylate, and 2 g of lauroyl peroxide, and dissolved by stirring. To this, 400 g of ion-exchanged water in which 0.75 g of sodium N-stearoyl-N-methyltaurine (SMT) was dissolved was added and dispersed with a homomixer until the particle size became 2.2 ⁇ m. The dispersion of polymerized particles was neutralized by adding 3.9 g of 1N NaOH dropwise. The dispersion was poured into a four-necked flask and purged with nitrogen for 30 minutes while stirring.
  • SMT sodium N-stearoyl-N-methyltaurine
  • the temperature inside the flask was heated to 80 ° C. with an oil bath, polymerization was performed for 5 hours after reaching 80 ° C., and then cooled to room temperature.
  • the dispersion liquid of the polymerized particles was lyophilized and the particles were collected to obtain a resin powder A.
  • Sheet 4 g of a liquid composition having the following composition was impregnated by spraying onto 2 g of 100% cotton nonwoven fabric (basis weight 50 g / m 2 ) to produce a sheet-shaped cosmetic.
  • the impregnation rate of the liquid composition with respect to 100 parts by mass of the sheet base material is 200 parts by mass.

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  • Life Sciences & Earth Sciences (AREA)
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Abstract

L'invention concerne un produit cosmétique qui présente non seulement une excellente sensation à l'utilisation, par exemple en ce qui concerne la tenue et la sensation de fraîcheur, et un excellent effet bactéricide, mais également une excellente persistance sur la peau d'un composant bactéricide et une excellente stabilité du composant bactéricide lors d'un stockage sur le long terme. Le produit cosmétique contient les composants suivants, (A) à (D) : (A) de 0,01 % en masse à 0,2 % en masse d'isopropylméthylphénol ; (B) de 0,1 % en masse à 3 % en masse d'un acide carboxylique ou d'un sel de ce dernier ; (C) de 0,1 % en masse à 10 % en masse de 1,3-butylène glycol ; et (D) de 0,005 % en masse à 1 % en masse d'un tensioactif non ionique dont la HLB est comprise entre 10 et 13.
PCT/JP2017/037444 2016-10-18 2017-10-17 Produit cosmétique Ceased WO2018074439A1 (fr)

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JP7628405B2 (ja) * 2019-09-02 2025-02-10 ロート製薬株式会社 皮膚外用組成物、抗炎症成分又は抗菌成分の皮膚浸透性をコントロールする方法、及び抗炎症成分又は抗菌成分による皮膚刺激を低減する方法
JP2021116304A (ja) * 2020-01-22 2021-08-10 アース製薬株式会社 害虫忌避剤及び害虫忌避成分の感触を改善する方法
JP7557121B2 (ja) * 2020-07-16 2024-09-27 株式会社ピカソ美化学研究所 皮膚外用剤組成物
WO2022034911A1 (fr) * 2020-08-13 2022-02-17 花王株式会社 Composition pour préparation externe cutanée de type sans rinçage
JP2022072206A (ja) * 2020-10-29 2022-05-17 クラシエホームプロダクツ株式会社 皮膚化粧料及び油溶性有効成分の樹脂容器内壁吸着抑制方法
JP2022096800A (ja) * 2020-12-18 2022-06-30 ライオン株式会社 制汗剤組成物
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