WO2017207025A1 - Method for producing plastically deformed metal particles - Google Patents

Abstract

The present invention relates to a method for producing plastically deformed metal particles using an auxiliary agent. The present invention also relates to metal particles, which have been ground using such an auxiliary agent, and to metal particle compositions containing them. The present invention further relates to the use of the above-mentioned metal particles and metal particle compositions.

Description

 Process for the production of plastically deformed metal particles

The present invention relates to a method for producing plastically deformed metal particles. Furthermore, the present invention relates plastically deformed

Metal particles with a specific superficial coating and

 Metal particle compositions containing plastically deformed metal particles obtained by means of a specific grinding. In addition, the present concerns

Invention, the use of the aforementioned metal particles and

Metal particle compositions.

One use of aluminum particles is the production of cellular concrete, as described in US 8409345 B1. However, the large-scale production of aerated concrete poses major challenges to the used here

Starting materials and auxiliaries. On the one hand, the costs must be kept low in order to provide a low-cost product. On the other hand, a stable process must be ensured, since only the disposal of faulty batches brings a lot of effort and additional costs.

Despite the age of this procedure, specific problems are still subject to further development. For example, in JP 201 1256094 A, the problem of cracking in aerated concrete parts of greater thickness to be solved or at least reduced.

Another development already established on the market is plastically deformed aluminum particles. These particles, as sold by the company Eckart, allow for the production of aerated concrete, a more even and complete Abreagieren the active metal.

Other technical applications are still the subject of further research. For example, WO 2013/01421 1 A2 deals with the provision of an improved metal particle material for coating processes such as

Flame spraying or non-thermal plasma spraying.

However, in other areas in which, for example, the optical effect of the aluminum pigments is of importance, it is still the task to provide products with further improved properties. Thus, for example, in WO 2009/156149 A1, the provision of an optimized Metallic effect pigment composition are described, which should provide optical properties comparable to those of PVD pigments. At the same time, however, it is the task to reduce the amount of solvent and a more constant

To ensure processing quality.

The plastic deformation of metal particles and their use in various fields such as for the production of cellular concrete or in aqueous paint systems are thus already known. However, there is still a need for metal particles which have improved water wettability and by means of a

simplified method can be produced.

Surprisingly, it has been shown that it is possible to provide metal particle compositions with excellent incorporability into aqueous systems in a one-step process. This is achieved by a method for producing plastically deformed metal particles, wherein metal particles are ground using at least one polyalkylene glycol,

the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol,

at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molar mass of the at least one polyalkylene glycol is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions. Standard conditions are conditions defined by IUPAC (25 ° C, 1 bar). The term "solid" refers to the state of aggregation, that is to say that, in contrast to a gas or a liquid, the substance in question does not deform indefinitely, but is dimensionally stable.

For example, a vessel such as a 100 ml beaker (5 cm outside diameter) can be filled with a corresponding substance without settling under

Standard conditions, for example, within the next hour, the substance of the shape of the vessel adapts and fills completely. The plastic deformation of the

Metal particles are advantageously carried out by means of known grinding methods. Examples of devices used for this purpose are ball mills and stirred ball mills. Such grinding steps can also be a

Crush the particles cause, so that fragments of the starting particles arise. However, the inventive method is accompanied by a plastic deformation of the particles at least in one spatial direction, so that the

According to the invention obtained metal particles have at least one spatial axis, which is smaller by at least the factor 5 than the longest spatial axis perpendicular thereto. Preferably, the invention has plastically deformed

Metal particles at least one spatial axis, which is smaller by at least a factor of 5 than two mutually perpendicular and spatial axes. The terms "ethylene glycol unit" and "propylene glycol unit" include the structures familiar to the skilled worker in the context of the polyalkylene glycols ((-CH ₂ -CH ₂ -O-) and (- C (H) (CH ₃ ) -CH ₂ -O-) ) Understood. However, the foregoing structures or subsequent performances of these structural units do not imply orientation of the units (for example, (-C (H) (CH ₃ ) -CH ₂ -O-), (-O-C (H) (CH ₃ ) -CH ₂ -)

(-CH ₂ -C (H) (CH ₃ ) -O-), (-O-CH ₂ -C (H) (CH ₃ ) -)), unless explicitly stated.

Unless otherwise specified, the term "average molecular weight" of a polymer in the present invention means the weight average molecular weight The determination of this weight average molecular weight can be determined by methods familiar to one skilled in the art or combinations of such methods Methods using light scattering proved to be very advantageous, such as multi-angle light scattering.

Corresponding measuring devices are available, for example, from Wyatt Technology Corporation, USA. This can be combined, for example, with other methods such as GPC (gel permeation chromatography), in particular if a mixture of different polymers is present. Corresponding devices are sold, for example, by the company Malvern Instruments Ltd, England, under the name Omnisec. Preferred developments of the method according to the invention can be found, for example, in aspects 1 to 21 and claims 1 to 9.

Furthermore, the present invention relates to metal particles, wherein the metal particles were plastically deformed using at least one polyalkylene glycol,

the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol,

at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions. Preferred developments of the metal particles according to the invention can be found, for example, in aspects 22 to 32 and claims 10 to 12.

Furthermore, the present invention relates to metal particle compositions comprising metal particles, wherein the metal particles were prepared by the method according to the invention. Preferably by means of the method according to the invention as described in one of claims 1 to 9 or one of aspects 1 to 21.

Furthermore, the present invention relates to metal particles, which according to the

have been prepared according to the invention. Preferably, in this case a variant of the method according to any one of claims 2 to 9 or one of the aspects 2 to 21 was used.

Furthermore, the present invention relates to the use of the metal particles according to the invention for hydrogen evolution, in a cosmetic, in a plastic or in a coating agent. Be particularly advantageous

Metal particles of the invention, in particular the inventive

Aluminum particles, proved to hydrogen evolution. Preferred developments of the uses according to the invention can be found, for example, in one of the aspects 38 to 39 or claim 15.

Furthermore, the present invention relates to a coating composition comprising the metal particles according to the invention or the inventive

Metal particle compositions. In particular, coating compositions are preferably comprising the metal particles according to any one of claims 10 to 12 or any of aspects 22 to 32, the metal particle compositions according to claim 13 or any of aspects 33 to 36 or metal particles, which by means of the method according to one of claims 1 to 9 or a Aspects 1 to 21 were made.

Furthermore, the present invention relates to a coating comprising

Inventive metal particles and / or inventive

Metal particle compositions. Furthermore, the present invention relates to an article comprising

Inventive metal particles or metal particle compositions according to the invention. Particularly preferred in this case are the metal particles, as in one of Claims 10 to 12 or any of aspects 22 to 32, and metal particle compositions as described in claim 13 or any one of aspects 33 to 36. Surprisingly, it has been shown that by means of the invention

 Method are obtained directly in a one-step process plastically deformed metal particles with excellent water wettability. Such improved water wettability results in improved dispersibility in water and is important, for example, in applications such as aerated concrete. In particular, for a field of work such as aerated concrete, it is of great importance with as few steps as possible to get into the aqueous aerated concrete einarbeitbare particles.

The term "aspect ratio" for the purposes of the present invention denotes the ratio of mean particle diameter (d ₅₀ ) to average particle thickness (h ₅₀ ). The term "d ₅₀ " or else "d ₅ o value" denotes the value at which 50% of the particles in the cumulative frequency distribution have a diameter which is equal to or less than this value

Particle size analyzer HELOS of the company Sympatec GmbH, Clausthal-Zellerfeld, Germany performed. The dispersion of a dry powder can take place here with a dispersion unit of the Rodos T4.1 type at a primary pressure of, for example, 4 bar. Alternatively, the size distribution curve of the particles can be measured, for example, using a device from Quantachrome (device: Cilas 1064) in accordance with the manufacturer's instructions. For this purpose, 1, 5 g of the powdery coating material are dispersed in about 100 ml of ethanol, 300 seconds in an ultrasonic bath (device: Sonorex IK 52, Fa. Bandelin) treated and then by means of a Pasteur pipette in the

 Sample preparation cell of the measuring device and measured several times. From the individual measurement results, the resulting averages are formed. The evaluation of the scattered light signals is carried out according to the Fraunhofer method. The term "alloy" for the purposes of the present invention means that the corresponding specified metal constitutes at least 50% by weight, more preferably at least 70% by weight, even more preferably at least 80% by weight, of the alloy, based in each case on The thickness of the particles can be determined, for example, by means of SEM as follows: The platelet-shaped particles according to the invention are first of all treated with acetone

washed and then dried. A common in electron microscopy resin, for example TEMPFIX (Gerhard Neubauer Chemikalien, D-48031 Münster, Germany), is applied to a sample plate and heated on a hot plate until softening. Subsequently, the sample tray is removed from the hot plate and the particles are sprinkled on the softened resin. As a result of the cooling, the resin solidifies again and the scattered particles can - due to the interplay between adhesion and gravity - be prepared almost vertically and fixed on the sample tray. As a result, the particles are in the

Good electron microscope to measure laterally. When measuring the thickness, the azimuthal angle α of the particle is estimated to be a plane normal to the surface and considered in the thickness evaluation according to the formula h _e ff = h _meas / cosa. Of the h _eff values, the relative frequencies make the

Sum distribution curve created. About 100 particles, preferably 100 particles, are counted.

Of course, it must be understood that the total sum of the weight percent of all components, for example, the metal particle composition, the metal particles, the polyalkylene glycols, or the like, must always be 100% by weight in total. Necessarily, the sum of the individual constituents can never exceed 100% by weight, based on their total weight, nor can the sum of the individual weights of all constituents be less than 100% by weight. Furthermore, constituents which do not necessarily constitute a final list of all constituents may naturally represent less than 100% by weight in total.

If the abovementioned method variant can not be used, the thicknesses of the particles can also be counted, for example, by means of cross sections of painted samples. However, this method should only work for a very good plane-parallel

Orientation of the particles are applied. Otherwise, the particles may be oriented in cross-section with an azimuthal angle of inclination, which, however, is not recognizable to the observer. This leads systematically to the measurement of higher thicknesses. Unless otherwise specified, it is particularly preferred in the present invention that "substantially" at least 95%, preferably at least 99%, means. As far as a material feature is concerned, such as the amount of a constituent, this means wt%.

According to the invention, the term "polymers" also encompasses oligomers Preferably, the polymers according to the invention, such as, for example, cellulose derivatives, polysaccharides, polyvinyls, polyacrylates and polyethylene glycols have at least 10 monomer units, more preferably at least 20 monomer units, even more preferably at least 60 monomer units. is understood within the meaning of the present invention, a small-sized, solid form of a substance. The average particle size (d ₅₀ ) of the powders according to the invention is preferably at most 150 μm, more preferably at most 123 μm, even more preferably at most 110 μm. The determination of this size of the powder is preferably carried out by means of a device from the company. Quantachrome (device: Cilas 1064) according to the manufacturer. For this purpose, 1, 5 g of powdered

 Coating material dispersed in about 100 ml of ethanol and then added using a Pasteur pipette in the sample preparation cell of the meter and measured several times. In particular, no dispersion takes place in an ultrasonic bath and no addition of dispersing additives. From the individual

Measurement results, the resulting averages are formed. The evaluation of the scattered light signals is carried out according to the Fraunhofer method. Here, a reference value for typical applications such as the aerated concrete is obtained, which draws an inference to the particle or agglomerate size of the metal particles in the

Aerated concrete allows. In particular, it has proved to be advantageous if the pastes according to the invention have the above upper limits of the average particle size under the aforementioned measurement conditions.

The invention relates to a method for producing plastically deformed metal particles, wherein metal particles are ground using at least one polyalkylene glycol,

the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol,

at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions. This was done by means of a very simple procedure Metal particles obtained, for example, which were very suitable for applications such as aerated concrete. In addition to procedural advantages and benefits were observed in the product obtained. In particular, the metal particles obtained therewith had excellent dispersibility in aqueous systems. This is particularly advantageous in applications such as aerated concrete, in which a uniform distribution of the metal particles, in particular aluminum particles, in the aerated concrete mass should be as simple and reliable as possible. As local

Concentrations of the metal particles, for example in aerated concrete to

Weak points, good dispersion is essential. Thus, in this field of application, the metal particles according to the invention make it possible, for example, to accelerate production, to increase the consistency of product quality, to simplify equipment and work-related costs, etc. However, less price-driven fields of application also benefit, for example, from improved dispersibility. Thus, hydrophilic coating compositions appear to be better absorbed in subsequent processing steps, so that, for example, certain known coatings can be applied to simple or novel coatings in the first place, or a better intermediate adhesion in certain coatings can be achieved. Surprisingly, a uniform distribution to the metal particles was achieved by means of simple standard methods for milling with the solid polyalkylene glycols according to the invention. Even small amounts of uneven application should have led to a partial segregation in view of the large number of particles, which was not observed. In addition, it was expected that at least the increasing hardness of high molecular weight polyalkylene glycols would complicate the plastic deformation, for example in a ball mill, or possibly an uneven distribution of the polyalkylene glycols would be observed. However, preliminary tests indicate that any deterioration in milling may be minimal. Furthermore, corresponding particles appear to have a further improved settling behavior. Without it being understood as limiting the invention, it is believed that this is due to the formation of a gel layer around the particles due to the greater increase in viscosity. Although the inventive method for a wide range of

Metal particles are used, however, it has proved to be particularly advantageous for the provision of very inexpensive metal particles, as they For example, in the production of aerated concrete are required. Surprisingly, even simple coatings are not suitable for achieving this

required properties, so that in further embodiments, the metal particles used are preferably at least 90 wt .-%, more preferably at least 95 wt .-%, even more preferably at least 99 wt .-%, uncoated metal particles, each based on the Total weight of metal particles. In particular, it is preferred that all metal particles used are uncoated. The term "uncoated" in the sense of the present invention means that the corresponding particles do not have at least substantially enveloping coating, preferably enveloping, coating around the particle, In particular, in the field of metal pigments, it is often preferred to apply highly cross-crosslinked, at least substantially enveloping coatings To provide high protection against external influences or improved compatibility with the

provide surrounding medium. Examples of such coatings are metal oxide coatings and polymer coatings. Of course you can

uncoated particles still include substances such as grinding aids such as stearic acid or oleic acid on the surface thereof.

Furthermore, it has been found that it is particularly advantageous for functional applications such as aerated concrete if the metal particles produced by the process have at least a certain aspect ratio. At further

In embodiments, it is preferred that the plastically deformed metal particles have an aspect ratio of at least 10, more preferably at least 20, even more preferably at least 50.

Furthermore, the properties can be further advantageously changed by the addition of additives. In further embodiments, a mixture of

Grind metal particles and at least one polyalkylene glycol, wherein the

The total weight of the metal particles and the at least one polyalkylene glycol is at most 99.8% by weight, more preferably at most 99% by weight, even more preferably at least 94% by weight, based in each case on the total weight of the

Mixture.

In particular, for uses such as aerated concrete, it has proven to be advantageous in a further step to apply retardants to the Foaming behavior of the metal particles to control. In further embodiments, the method according to the invention therefore comprises a

subsequent step of applying a retarder to the plastically deformed metal particles. Examples of such delay means are

Phosphoric acid compounds such as phosphoric acids, phosphoric acid esters and

Phosphates.

The process according to the invention for metal particles of specific metals has proved to be particularly advantageous. In further embodiments, the metal of the metal particles is selected from the group consisting of aluminum, copper, iron, zinc, tin, titanium, chromium, silver, gold, vanadium, nickel, magnesium, alloys of the foregoing such as brass and steel, and mixtures thereof, more preferably selected from the group consisting of aluminum, copper, iron, zinc, silver, alloys thereof, such as brass and steel and mixtures thereof, even more preferably from the group consisting of aluminum, iron, alloys thereof and mixtures thereof.

In particular, it is preferable that aluminum particles are used. Examples of advantageous alloy constituents are silicon and boron.

Further, however, it may be preferable not to use high molecular weight polyalkylene glycols. Despite the very low amount of polyalkylene glycol seem

orienting attempts at influencing the surrounding system

especially with regard to the viscosity. Although this could be for

Areas of application such as aerated concrete may offer benefits but may require adaptation of specific formulations. In further embodiments, it is preferred that the average molecular weight of the at least one polyalkylene glycol is at most 53,000, more preferably at most 17,000, more preferably at most 13,000, more preferably at most 9,000, more preferably at most 8,000, even more preferably at most 4750. Allow these polyalkylene glycols

For example, the provision of a modular system which offers optimal usability and interchangeability in a large number of formulations.

In particular, in further embodiments, it is preferred that the average molecular weight of the at least one polyalkylene glycol is in the range of 1000 to 17000, more preferably in the range of 1300 to 13000, even more preferably in the range of 1400 to 9000, even more preferably in the range of 2900 to 4750, lies. In further embodiments of the present invention, it is further preferred that a mixture of metal particles and at least one polyalkylene glycol is ground, the total weight of the metal particles and the at least one polyalkylene glycol being at least 60% by weight, more preferably at least

68 wt .-%, more preferably at least 74 wt .-%, in each case based on the total weight of the mixture. In further embodiments, the mixture consists of metal particles and the at least one polyalkylene glycol.

In further embodiments, it is preferred that the at least one

Polyalkylene glycol has a structure according to formula (I)

R ¹ - (O-alk) _n -O-R ¹ (I), wherein the R ^{1 are} independently selected from the group consisting of H, C1-C4 aliphatic groups and (meth) acrylate groups,

the alk are independently selected from ethylene units and

Propylene units, and

the weight average of n is at least 30. The term "ethylene units" is understood to mean -CH ₂ -CH ₂ units according to the invention. The term "propylene units" is understood according to the invention to mean -CH ₂ -C (H) (CH ₃ ) - or -C (H) (CH ₃ ) - CH ₂ units understood. The mass mean of n is understood as the chain length averaged for a polyalkylene glycol, which can be calculated from the average molecular weight. If various polyalkylene glycols are present, they are previously separated by methods such as GPC. Further, it is preferable that the aliphatic groups are selected from the group of the alkyl groups and alkenyl groups, more preferably from the group of the alkyl groups and allyl groups, still more preferably from the group of the alkyl groups.

In particular, it is preferred that the R ^{1 are} unsubstituted and besides H

for example, be selected from unsubstituted aliphatic groups and unsubstituted (meth) acrylate groups. The term "(meth) acrylate groups" is understood to mean methacrylate groups and acrylate groups.

The (meth) acrylate functionality appears to offer advantages in incorporation into certain polymer-containing systems. For many other applications, however, it is advantageous that no such reactive group is present. At further

It is therefore preferred for embodiments that the R ^{1 are} independently selected from the group consisting of H and unsubstituted C 1 -C 4 aliphatic groups, more preferably from the group consisting of H and unsubstituted C1-C4 alkyl groups.

Without it being understood as a limitation of the invention, it is further assumed that advantageously a free binding site for binding to the metal particles should be present. In certain of the above

It is therefore preferred for embodiments that at least one R ^{1 of} the at least one polyalkylene glycol is H. Preferably, both R ^{1 are} H. In further embodiments, it is preferred that the weight average of n is at least 60, more preferably at least 70, even more preferably at least 75.

According to further embodiments, it is preferred that the weight average of n is at most 200, more preferably at most 160, even more preferably at most 140.

In particular, it is preferred in certain of the foregoing embodiments that the weight average of n is in the range of 60 to 200, more preferably in the range of 70 to 160, even more preferably in the range of 75 to 140.

Surprisingly, it has been shown that it is advantageous to use polyalkylene glycols having a specific melting point. According to further embodiments, the at least one polyalkylene glycol has a melting point or lower limit of the melting point range of at least 35 ° C, more preferably at least 42 ° C, even more preferably at least 51 ° C. The pressure has only a minimal influence on the melting point, but the measurement is preferably carried out at 1, 013 bar.

Further, in further embodiments, it is preferred that the at least one polyalkylene glycol has a melting point or upper limit of the melting point range of at most 75 ° C, more preferably at most 70 ° C, even more preferably at most 68 ° C.

In particular, in further embodiments it is preferred that the at least one polyalkylene glycol has a melting point or melting point range in one

Range of 35 ° C to 75 ° C, more preferably in a range of 42 ° C to 70 ° C, even more preferably in a range of 51 ° C to 68 ° C. Furthermore, in applications such as aerated concrete, it has proved advantageous at least in certain compositions if the water solubility of the at least one polyalkylene glycol is at least 300 g / l, more preferably at least 370 g / l, even more preferably at least 420 g / l.

Furthermore, it has proven advantageous in further embodiments of the present invention if the at least one polyalkylene glycol has a defined HLB value. Preferably, in these embodiments, the HLB value of the at least one polyalkylene glycol is in the range of 16 to 24, more preferably in the range of 16.3 to 22.1, even more preferably in the range of 16.5 to 19.8.

Although theoretically not used according to the invention polyalkylene glycols can be added whose average molecular weight is at least 1000 and wherein at least 50 mol% of the alkylene glycol units are propylene glycol units.

However, the proportion of such polyalkylene glycols is preferably at most 10 wt .-%, more preferably at most 5 wt .-%, even more preferably at most 1 wt .-%, based on the mass of the metal particles. In particular, by the subsequent addition of polyalkylene glycols with a higher proportion of propylene glycol units, a broader spectrum of applications seems to be explicable. Without it being to be understood as limiting the invention, it is assumed that the various polyalkylene glycols with higher and lower content of ethylene glycol units mediate compatibility with one another and the polyalkylene glycols with a low proportion of ethylene glycol units in turn impart compatibility to non-polar media. However, for many applications, such as aerated concrete, such a change in compatibility is not required or undesirable. In further embodiments, it is therefore preferred that the ratio of polyalkylene glycols having an average molecular weight of at least 1000 and more than 50 mol% of propylene glycol units as

 Alkylenglykoleinheiten to polyalkylene glycols having an average molecular weight of at least 1000 and at least 50 mol% ethylene glycol units as

Alkylene glycol units at most 1: 1, more preferably at most 0.5: 1, even more preferably at most 0.1: 1, even more preferably at most 0.01: 1.

Furthermore, it has proved advantageous for many fields of application if the alkylene glycol units of the at least one polyalkylene glycol are at least 60 molar %, more preferably at least 75 mole%, even more preferably at least 92 mole%, of ethylene glycol units are, based on the total moles of alkylene glycol units. In particular, for applications such as aerated concrete hereby seem particularly good results to be achieved. These are preferably pure polyethylene glycols.

The term "polyalkylene glycol" / "polyethylene glycol" / "polypropylene glycol" refers to polymers of corresponding monomers, the end groups optionally being able to be substituted The term "polyalkylene glycol" encompasses the polyethylene glycols and polypropylene glycols, as well as copolymers of ethylene glycol and propylene glycol.

An important group of the copolymers of ethylene glycol and propylene glycol are the block polymers, in particular diblock polymers and triblock polymers. For certain applications, however, it has proven to be advantageous to touch the powder obtained by grinding, for example, to prevent the formation of dust during further processing or to allow feeding of the metal particles in a continuous process by means of simple pumping technology. In further embodiments, it is preferred that the metal particles produced according to the invention are in the form of a paste. In this case, it has typically proven advantageous to use alkylene glycols or polymers thereof having an average molecular weight of up to 550. These under standard conditions liquid compounds proved to be particularly advantageous. An example of this is diethylene glycol. For specific applications, for example when a particularly uniform foaming of the aerated concrete is desired or for optical applications, it is preferred in further embodiments that the plastically deformed

Metal particles are platelet-shaped. For the purposes of the present invention, the term "platelet-shaped" means that corresponding particles have an aspect ratio of at least 10. Particles having an aspect ratio of less than 10 are referred to as "non-platelet-shaped" in the context of the present invention. In further embodiments, the metal of the metal particles becomes at least

90% by weight selected from the group consisting of aluminum, copper, iron, zinc, tin, titanium, chromium, silver, gold, vanadium, nickel, magnesium, alloys of the foregoing such as brass and steel and mixtures thereof, more preferably from the group consisting of aluminum, copper, iron, zinc, silver, alloys of the foregoing such as brass and steel, and mixtures thereof, more preferably from the group consisting of aluminum, iron, alloys the foregoing and mixtures thereof. In particular, it is preferable that aluminum particles are used. Examples of advantageous alloy constituents are silicon and boron.

Preferably, the metal of the metal particles is selected from at least 95% by weight, more preferably at least 99% by weight, even more preferably completely, from the aforementioned groups.

In further embodiments, the metal of the metal particles comprises at most 5 wt%, more preferably at most 2 wt%, more preferably at most 1 wt%, metals selected from the group consisting of silver, palladium, platinum, gold, Mixtures thereof and alloys thereof.

In further embodiments, the metal particles are preferably selected from uncoated metal particles and coated metal particles, wherein the amount of coating of the coated metal particles is at most 15 wt .-%, preferably at most 12 wt .-%, more preferably at most 10 wt .-%, based on the total weight of the coated metal particles.

Furthermore, it has been shown that in other embodiments, the metal particles according to the invention preferably have a certain minimum amount of the at least one polyalkylene glycol. In this case, it is preferred that the amount of the at least one polyalkylene glycol is at least 1% by weight, more preferably at least 1.2% by weight, even more preferably at least 1.5% by weight, in each case based on the weight of the Metal particles, which also optionally present as a result of the milling existing decomposition products of at least one

Polyalkylene glycols are included.

Furthermore, over a certain amount, typically no sufficiently improved properties were observed that justified the additional cost and reduction of the active metal. In further embodiments, the amount of the at least one polyalkylene glycol is therefore preferably at most 5.7% by weight, more preferably at most 4.6% by weight, even more preferably at most 3.3% by weight, based in each case on the weight of Metal particles, whereby also possibly due the milling of existing decomposition products of at least one

Polyalkylene glycols are included.

In further embodiments, the amount of at least one

Polyalkylene glycol in the range of 1 wt .-% to 5.7 wt .-%, more preferably in the range of 1, 2 wt .-% to 4.6 wt .-%, even more preferably in the range of 1, 5 wt. % to 3.3% by weight, based in each case on the weight of the metal particles, wherein any decomposition products of the at least one polyalkylene glycol which may also be present as a result of the milling are also included.

In further embodiments, it is preferred that the metal particles according to the invention consist essentially of elemental metal, at least one

Polyalkylene glycol and optionally present as a result of grinding

There are decomposition products of at least one polyalkylene glycol.

Preferably, the metal particles of the invention consist of at least 90% by weight, more preferably at least 95% by weight, even more preferably at least 98% by weight, of elemental metal, at least one polyalkylene glycol and optionally decomposition products of the at least existing as a result of the milling a polyalkylene glycol, wherein the at least one polyalkylene glycols is selected from polyalkylene glycols in which at least 50 mol% of the

Alkylene glycol units are ethylene glycol units,

the average molecular weight of the polyalkylene glycols is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions.

In further embodiments, it is preferred that the metal of the metal particles is selected from the group consisting of aluminum, copper, iron, zinc, tin, titanium, chromium, silver, gold, vanadium, nickel, magnesium, alloys of the foregoing such as brass and steel and mixtures thereof, more preferably selected from the group consisting of aluminum, copper, iron, zinc, silver, alloys thereof, such as brass and steel and mixtures thereof, even more preferably from the group consisting of aluminum, iron, alloys thereof and mixtures thereof.

In particular, it is preferable that aluminum particles are used. Examples of advantageous alloy constituents are silicon and boron. In further embodiments, the metal particles preferably have one

Aspect ratio of at least 10, more preferably at least 20, even more preferably at least 50. Furthermore, the present invention relates to metal particles by means of

A process according to the invention, in particular as described in one of claims 2 to 9 or one of aspects 2 to 21.

Furthermore, the present invention relates to a metal particle composition comprising the metal particles according to the invention.

Surprisingly, it has been shown that even very small amount of

Polyalkylene glycol are sufficient to, for example, an excellent

To achieve dispersibility in aerated concrete masses. At further

In embodiments, it is preferred that the amount of the at least one

 Polyalkylene glycol is at least 0.6 wt .-%, more preferably at least 0.8 wt .-%, even more preferably at least 1, 0 wt .-%, in each case based on the weight of the metal particles. If at least partial decomposition of the

Polyalkylene glycol has occurred, the aforementioned indication refers to the weight comprising the decomposition products.

Furthermore, it was found that with large amounts of polyalkylene glycol no essential improvement of the properties could be achieved. In addition, in addition to an increase in costs, this led to a reduction in the active metal content. In further embodiments, it is therefore preferred that the amount of the at least one polyalkylene glycol is at most 5.2% by weight, more preferably at most 4.1% by weight, even more preferably at most 3.0% by weight, respectively based on the weight of the metal particles. Such compositions are for example

Paint formulations and the production of aerated concrete advantageous.

Furthermore, it may be preferred to apply further polyalkylene glycol, for example by means of polishing. These additional alkylene glycols can serve, for example, as binders in order to produce granules or shaped bodies from the metal particles according to the invention. In further embodiments, the amount of the at least one polyalkylene glycol is at most 12 wt%, more preferably at most 7.0 wt%, even more preferably at most 5.7 wt%, each based on the weight of the metal particles. Such metal particles provide for Although applications such as aerated concrete the advantage of easier handling, but the additional cost of the additional polyalkylene glycol are typically prove undesirable. These forms are particularly advantageous for example

Uses such as the production of masterbatches or use in

Coating processes such as flame spraying, high-speed flame spraying, thermal plasma spraying, non-thermal plasma spraying and cold gas spraying.

In particular, in further embodiments, it is preferred that the amount of the at least one polyalkylene glycol be in the range of 0.8% to 5.2% by weight, more preferably in the range of 1.0% to 4.1% Wt .-%, even more preferably in

Range from 1, 2 wt .-% to 3.0 wt .-%, in each case based on the weight of the metal particles.

Without it being understood as limiting the invention, the results obtained indicate that as uniform and as thin as possible

Coatings of the polyalkylene glycol are preferred. At further

In embodiments, it is preferred that the average layer thickness of the at least one polyalkylene glycol on the surface is at most 15 nm, more preferably at most 12 nm, even more preferably at most 10 nm.

Furthermore, highly concentrated metal particle compositions could be obtained by means of the metal particles according to the invention. In further embodiments, it is preferred that the total weight of the metal particles and the at least one polyalkylene glycol is at least 90% by weight, more preferably at least 93% by weight, even more preferably at least 97% by weight, based in each case on

Total weight of metal particle composition without solvent. In further embodiments, the metal particle composition consists of metal particles and the at least one polyalkylene glycol and optionally solvents. The solvents serve to pasting the metal particles in order in particular to facilitate the processing. Preferably, the amount of solvent is at most 15% by weight, more preferably at most 10% by weight, even more preferably at most 7% by weight, based on the total weight of

Metal particle composition. Furthermore, it may be advantageous for other applications in essence

use solvent-free metal particle compositions. For example, certain advantages have been found in applications such as incorporation into Plastics. In further embodiments, it is therefore preferable if the solvent content of the metal particle compositions is at most 7% by weight, more preferably at most 5% by weight, even more preferably at most 2% by weight, based on the total weight of the metal particle composition.

Preferred forms of the metal particle compositions according to the invention are powders and pastes.

Powders are preferably substantially solvent-free metal particle compositions. For example, such powders have less than 5 wt%, more preferably less than 2 wt%, even more preferably less than 1 wt%,

Solvent, based on the total weight of

Metal particle composition. Pastes are typically obtained by pasting powders with solvents. An advantage here is the reduction or even avoidance of one

Dusting during handling, wherein the metal particle content should not be reduced too much. Preferably, the solvent content of the pastes is at most 40% by weight, more preferably at most 35% by weight, even more preferably at most 32% by weight. Particularly effective pastes were at a

 Solvent content of at least 15 wt .-%, more preferably at least 18 wt%, even more preferably at least 22 wt .-%, obtained.

Furthermore, the present invention relates to a coating agent or cosmetic comprising the metal particles according to the invention. Examples of coating compositions are wet paints, powder coatings, coil coating paints and inks such as printing inks and inks.

Examples of printing inks, such as flexo, gravure and screen inks, powder coatings, coil coating paints, solvent-based inks and water-based inks.

The use of the metal particles according to the invention in water-based systems is particularly advantageous.

However, the increased water wettability also simplifies, for example, the

Application of protective layers in coating system with hydrophilic

Solvents as in common sol-gel systems. Hereby generated

Protective layers not only stabilize the metal particles, but can for example, the affinity for coating agents based on organic

Increase solvents.

Examples of cosmetics are body powder, face powder, pressed and loose powder, face makeup, powder cream, cream makeup, emulsion makeup, wax makeup, foundation, mousse makeup, cheek rouge, eye make-up such as eye shadow, mascara, eyeliner, liquid eyeliner, eyebrow pencil, lip balm, lipstick, lip gloss, lip Liner, hair styling compositions such as hair spray, hair mousse, hair gel, hair wax, hair mascara, permanent or semi-permanent hair colors, temporary hair colors, skin care compositions such as lotions, gels, emulsions and

Nail polish compositions.

Furthermore, the present invention relates to the use of the metal particles according to the invention for hydrogen evolution, in a cosmetic, in a plastic or in a coating agent.

A particularly advantageous application of the metal particles according to the invention is the use of the metal particles according to the invention, preferably aluminum particles, for hydrogen evolution. This can, for example, in the production of

Used aerated concrete.

Furthermore, the metal particles according to the invention can be used for example in

Coating agents are incorporated. Examples of such coating compositions are wet paints, powder coatings and inks such as printing inks and inks.

Furthermore, the present invention relates to an article produced using the metal particles according to the invention or coated with a coating agent comprising the metal particles according to the invention. In particular, further preferred embodiments are

Autoclaved aerated using the metal particles of the invention.

In further embodiments, the article is a coated article comprising a coating agent comprising the metal particles according to the invention. The coating compositions according to the invention can be used for coating a wide variety of articles. Examples are car bodies, facade elements, printed matter, such as printed films, paper, cardboard, plastic moldings, etc ..

Furthermore, the metal particles according to the invention can also be incorporated in a plastic material. In this case, the metal particle-containing plastic material can be brought directly into the desired shape or subsequently by means of

machining steps are transformed.

According to one aspect of the invention, the present invention preferably relates to a method for producing plastically deformed metal particles, wherein metal particles are ground using at least one polyalkylene glycol,

the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol,

at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions. According to one aspect, the present invention relates to a process according to aspect 1, wherein the at least one polyalkylene glycol has a structure according to formula (I)

R ¹ - (O-alk) _n -O-R ¹ (I), wherein the R ^{1 are} independently selected from the group consisting of H, C1-C4 aliphatic groups and (meth) acrylate groups,

the alk are independently selected from ethylene units and propylene units, and

the weight average of n is at least 30. In particular, it is preferred that the aliphatic groups are selected from the group of alkyl groups and alkenyl groups, more preferably from the group of alkyl groups and allyl groups, still more preferably from the group of alkyl groups.

In one aspect, the present invention relates to a process according to any of aspects 1 to 2, wherein at least one R ^{1 of} the at least one polyalkylene glycol is H. Preferably both R ^{1 are} H. According to one aspect, the present invention relates to a method according to any of aspects 1 to 3, wherein the weight average of n is at least 60, more preferably at least 70, even more preferably at least 75.

According to an aspect 5, the present invention relates to a method according to any of aspects 1 to 4, wherein the weight average of n is at most 200, more preferably at most 160, even more preferably at most 140. According to one aspect of the invention, the present invention relates to a process according to any of aspects 1 to 5, wherein preferably the average molecular weight of the at least one polyalkylene glycol is at most 53,000, more preferably at most 17,000, more preferably at most 13,000, more preferably at most 9,000, more preferably at most 8,000, even more preferably at most 4750.

According to one aspect, the present invention relates to a method according to any of aspects 1 to 6, wherein preferably the water solubility of the at least one polyalkylene glycol is at least 300 g / l, more preferably at least 370 g / l, even more preferably at least 420 g / l ,

According to an aspect 8, the present invention relates to a method according to one of the aspects 1 to 7, wherein preferably the HLB value of the at least one

Polyalkylene glycol in the range of 8 to 24, more preferably in the range of 9.3 to 22.1, even more preferably in the range of 10.2 to 19.8.

According to one aspect 9, the present invention relates to a process according to any one of aspects 1 to 8, wherein the amount of the at least one polyalkylene glycol is at least 0.9% by weight, more preferably at least 1.0% by weight, even more preferably at least 1 , 2 wt .-%, in each case based on the weight of the metal particles.

According to one aspect, the present invention relates to a method according to any of aspects 1 to 9, wherein the amount of the at least one polyalkylene glycol is at most 5.7% by weight, more preferably at most 4.6% by weight, even more preferably at most 3 , 3 wt .-%, in each case based on the weight of the metal particles. According to one aspect of the invention, the present invention relates to a process according to any one of aspects 1 to 10, wherein the amount of the at least one polyalkylene glycol ranges from 0.9% by weight to 5.7% by weight, more preferably in the range of 1, 0 wt .-% to 4.6 wt .-%, more preferably in the range of 1, 2 wt .-% to 3.3 wt .-%, in each case based on the weight of the metal particles.

According to one aspect 12, the present invention relates to a process according to any of aspects 1 to 11, wherein preferably the alkylene glycol units of the at least one polyalkylene glycol are at least 60 mole%, more preferably at least 75 mole%, even more preferably at least 92 mole -%, ethylene glycol units, based on the total molar amount of the alkylene glycol units. In particular, it is preferred that the at least one polyalkylene glycol from the group of

Polyethylene glycols is selected. According to one aspect, the present invention relates to a method according to any of aspects 1 to 12, wherein preferably a mixture comprising metal particles and at least one polyalkylene glycol is ground, wherein the total weight of the metal particles and the at least one polyalkylene glycol is at least 60% by weight, more preferred at least 68 wt .-%, more preferably at least 74 wt .-%, in each case based on the total weight of the mixture. At further

 Embodiments consists of the mixture of metal particles and the at least one polyalkylene glycol.

According to one aspect 14, the present invention relates to a method according to any of aspects 1 to 13, wherein preferably a mixture comprising metal particles and at least one polyalkylene glycol is ground, the total weight of the metal particles and the at least one polyalkylene glycol being at most 99.8% by weight, more preferably at most 99% by weight, more preferably at least 94% by weight, in each case based on the total weight of the mixture.

According to one aspect, the present invention relates to a process according to any of aspects 1 to 14, wherein preferably the at least one polyalkylene glycol has a melting point or lower limit of the melting point range of at least 35 ° C, more preferably at least 42 ° C, even more preferably at least 51 ° C, has. According to an aspect 16, the present invention relates to a method according to any of aspects 1 to 15, wherein preferably the at least one polyalkylene glycol has a melting point or upper limit of the melting point range of at most 75 ° C, more preferably at most 70 ° C, even more preferably at most 68 ° C, has.

According to one aspect 17, the present invention relates to a method according to any of aspects 1 to 16, wherein preferably the at least one polyalkylene glycol has a melting point in a range of 35 ° C to 75 ° C, more preferably in a range of 42 ° C to 70 ° C, more preferably in a range of 51 ° C to 68 ° C, having.

According to one aspect, the present invention relates to a method according to any one of aspects 1 to 17, wherein preferably the metal particles to at least 90 wt .-%, more preferably at least 95 wt .-%, even more preferably at least

99 wt .-% uncoated metal particles are, in each case based on the total weight of the metal particles. In particular, it is preferred that all metal particles are uncoated. According to one aspect 19, the present invention relates to a method according to any one of aspects 1 to 18, wherein preferably the metal of the metal particles is selected from the group consisting of aluminum, copper, iron, zinc, tin, titanium, chromium, silver, gold, vanadium , Nickel, magnesium, alloys of the foregoing such as brass and steel, and mixtures thereof, more preferably selected from the group consisting of aluminum, copper, iron, zinc, silver, alloys thereof, such as

Brass and steel and mixtures thereof, more preferably from the group consisting of aluminum, iron, alloys thereof and mixtures thereof.

In particular, it is preferable that aluminum particles are used. According to one aspect, the present invention relates to a method according to any of aspects 1 to 19, wherein preferably the plastically deformed metal particles have an aspect ratio of at least 10, more preferably at least 20, even more preferably at least 50. According to one aspect 21, the present invention relates to a method according to any one of aspects 1 to 20, wherein preferably subsequently a retarder is applied to the plastically deformed metal particles. According to one aspect 22, the present invention relates to metal particles wherein the metal particles have been ground using at least one polyalkylene glycol, the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol,

at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000, preferably at least 1300, more preferably at least 1400, even more preferably at least 2900, and the at least one polyalkylene glycol is solid under standard conditions.

According to an aspect 23, the present invention relates to metal particles according to aspect 22, wherein preferably the average molecular weight of the at least one

Polyalkylene glycol is at most 53,000, more preferably at most 17,000, more preferably at most 13,000, more preferably at most 9,000, more preferably at most 8,000, even more preferably at most 4750.

According to one aspect, the present invention relates to metal particles according to one of the aspects 22 to 23, wherein preferably the average layer thickness of the at least one polyalkylene glycol on the surface is at most 15 nm, more preferably at most 12 nm, even more preferably at most 10 nm.

According to an aspect 25, the present invention relates to metal particles according to any one of aspects 22 to 24, wherein preferably the amount of at least one

Polyalkylene glycol is at least 0.6 wt .-%, more preferably at least 0.8 wt .-%, more preferably at least 1, 0 wt .-%, in each case based on the weight of the metal particles, wherein also optionally present as a result of grinding Decomposition products of at least one polyalkylene glycol are included.

According to one aspect, the present invention relates to metal particles according to any of aspects 22 to 25, wherein preferably the amount of the at least one

Polyalkylene glycols at most 12 wt .-%, more preferably at most 7.0 wt .-%, even more preferably at most 5.7 wt .-%, in each case based on the weight of the metal particles, wherein also optionally present as a result of grinding existing decomposition products of at least one polyalkylene glycol are included. According to an aspect 27, the present invention relates to metal particles according to any of aspects 22 to 26, wherein preferably the amount of the at least one

Polyalkylene glycol in the range of 0.6 wt .-% to 12 wt .-%, more preferably in the range of 0.8 wt .-% to 7.0 wt .-%, even more preferably in the range of

1, 0 wt .-% to 5.7 wt .-%, is, in each case based on the weight of the metal particles, wherein also optionally present as a result of the milling existing decomposition products of the at least one polyalkylene glycol.

According to an aspect 28, the present invention relates to metal particles according to any one of aspects 22 to 27, wherein preferably the metal particles to at least 90% by weight, more preferably at least 95 wt .-%, even more preferably at least 99 wt .-% uncoated Metal particles are, in each case based on the total weight of the metal particles. In particular, it is preferred that all metal particles are uncoated.

According to one aspect 29, the present invention relates to metal particles according to any one of aspects 22 to 28, wherein preferably the metal of the metal particles is selected from the group consisting of aluminum, copper, iron, zinc, tin, titanium, chromium, silver, gold, vanadium, Nickel, magnesium, alloys of the foregoing such as brass and steel and mixtures thereof, more preferably selected from the group consisting of aluminum, copper, iron, zinc, silver, alloys thereof such as brass and steel, and mixtures thereof, more preferably from the group consisting of Aluminum, iron, alloys thereof, and mixtures thereof.

In particular, it is preferable that aluminum particles are used.

According to one aspect, the present invention relates to metal particles according to any of aspects 22 to 29, wherein preferably the metal particles have an aspect ratio of at least 10, more preferably at least 20, even more preferably at least 50.

According to one aspect 31, the present invention relates to metal particles according to any one of aspects 22 to 30, wherein preferably the coated metal particles in the

Substantially consist of elemental metal and at least one polyalkylene glycol. Preferably, the coated metal particles consist of at least 90% by weight, more preferably at least 95% by weight, even more preferably at least 98% by weight, of elemental metal and at least one Polyalkylene glycol, wherein the polyalkylene glycols also comprise decomposition products resulting from the milling.

According to one aspect 32, the present invention relates to metal particles according to one of the aspects 22 to 31, wherein preferably the metal particles were produced by means of the method according to one of the aspects 1 to 21.

According to one aspect 33, the present invention relates to a metal particle composition comprising metal particles according to any of aspects 22 to 32.

According to one aspect 34, the present invention relates to a metal particle composition according to aspect 33, wherein preferably the metal particle composition is a powder or a paste, more preferably a powder. According to one aspect 35, the present invention relates to metal particle composition according to any one of aspects 33 to 34, wherein preferably the total weight of the metal particles and the at least one polyalkylene glycol is at least 90% by weight, more preferably at least 93% by weight, even more preferably at least 97% by weight .-%, is, in each case based on the total weight of the metal particle composition without solvent.

According to one aspect, the present invention relates to the metal particle composition according to any of aspects 33 to 35, wherein preferably the amount of solvent is at most 40% by weight, more preferably at most 35% by weight, even more preferably at most 32% by weight.

According to one aspect 37, the present invention relates to the use of metal particles according to any of aspects 22 to 32 for hydrogen evolution, wherein the metal is aluminum, zinc or mixtures thereof; in a cosmetic; in a plastic or in a coating agent.

According to one aspect 38, the present invention relates to the use according to aspect 37, wherein preferably aluminum particles are used for hydrogen evolution in the production of cellular concrete.

According to one aspect 39, the present invention relates to the use according to any of aspects 37 to 38, wherein preferably the coating agent is selected is from the group consisting of wet paints, powder coatings and inks such as printing inks and inks.

According to one aspect, the present invention relates to a coating agent comprising metal particles produced by the method according to any one of aspects 1 to 21, metal particles according to any one of aspects 22 to 32 or a metal particle composition according to any one of aspects 33 to 36, wherein preferably the coating agent is selected from the group consisting of wet paints, powder coatings and inks such as printing inks and inks.

According to one aspect 41, the present invention relates to a coating comprising metal particles produced by the method according to any one of aspects 1 to 21, metal particles according to any of aspects 22 to 32 or a metal particle composition according to any one of aspects 33 to 36.

According to one aspect, the present invention relates to an article produced using metal particles produced by the method according to any one of aspects 1 to 21, metal particles according to any of aspects 22 to 32 or a metal particle composition according to any one of aspects 33 to 36th

According to one aspect 43, the present invention relates to an article according to aspect 42, wherein the article is made of cellular concrete. Example 1 :

An aluminum grit having a d ₅₀ of 30 μm is prepared by dry milling using iron balls and 2% by weight of the grinding aid according to

in the table below, based on the weight of the metal particles.

Example of grinding aid

 Comparative Example 1 -1 oleic acid

 Comparative Example 1 -2 stearic acid

 Example 1 -3 Polyethylene glycol average molecular weight 1500

 Example 1 -4 Polyethylene glycol average molecular weight 3000

 Example 1 -5 Polyethylene glycol average molecular weight 4000

Example 1 -5 Polyethylene glycol average molecular weight 6000 Example 1 -6 Polyethylene glycol average molecular weight 8000

Example 1 -7 Polyethylene glycol average molecular weight 35,000

 Example 1 -8 Polyglycol M 4000 (polyethylene glycol monomethyl ether of average molecular weight in the range of 3500-4770)

 Example 1 -9 Polyethylene glycol allyl methyl ether average molecular weight 5000

Example 1 -10 Polyglycol MA 5000/50 (Polyethylene glycol monomethacrylate, average molecular weight 5000)

Example 2:

 Milling analogous to the grinding listed in Example 1 using polyethylene glycol with an average molecular weight of 3000.

The grinding worked well in the aforementioned cases. In Examples 2-5, however, individual observations indicated incipient agglomeration of the resulting particles. For some continuous process used in dry milling, this could possibly cause problems.

Use Example 1: Hydrogen Development To 2 l of water (40 ° C.), 2 kg of Dorsilite 1600 quartz flour, 200 g of cement and 1 kg of white fine lime and 2.5 g of metal particles are added and intensively mixed for 30 s before the mixture is transferred to the casting mold. Here, the height of the mixture is detected with respect to the time.

Example observation

 Comparative Example 1 -1 Metal particles float up, no real one

 volume growth

Comparative Example 1 -2 Metal particles float, no real volume growth

 Examples 1 -3 to 1 -10 Very similar behavior in these examples, metal particles appear to be evenly distributed, uniform

 Growth, slump very low to almost nonexistent

It was found that the metal particles according to the invention can be used directly for the production of aerated concrete. In addition to uniform growth of the test concrete, they offer a very low slump. Under slump is the

Height difference between maximum drive height and final height understood.

Use Example 2: Dispersibility in Water

The qualitative determination of the dispersibility in water was determined by means of the

tested in the following procedure. A spatula tip of the metal powder to be tested was placed in a 100 ml beaker containing 80 ml of water from a height of 1 cm above the water surface. Thereafter, the speed of the sinking of the powder, as well as its dispersibility was observed by stirring.

Example Observation on addition Observation on stirring

Comparative Example 1 -1 no drop in the water, no dispersing possible,

 Floats on Surface continues to float

 surface

 Comparative Example 1 -2 no drop in the water, no dispersing possible,

 Floats on Surface continues to float

 surface

 Examples 1 -3 to 1 -10 rapid decrease of the optically very good distribution in

 Metal powder and already water, at the water surface when sinking partial no formation of a

 Distribution in the water silver mirror

Claims

1 . Process for producing plastically deformed metal particles, wherein Metal particles are ground using at least one polyalkylene glycol, the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol, at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000 and the at least one polyalkylene glycol is solid under standard conditions. 2. The method according to claim 1, wherein the at least one polyalkylene glycol has a structure according to formula (I) R ¹ -(0-Alk) _n -0-R ¹ (I), wherein the R ¹ are independently selected from the group consisting from H, C1 -C4 aliphatic groups and (meth)acrylate groups, the alk are independently selected from ethylene units and propylene units, and the mass average of n is at least 30. 3. The method according to any one of claims 1 to 2, wherein at least one R ¹ of the at least one polyalkylene glycol is H. 4. The method according to any one of claims 1 to 3, wherein the mass average of n is in the range of 60 to 200. 5. The method according to any one of claims 1 to 4, wherein the average molecular weight of the at least one polyalkylene glycol is at most 53,000. 6. The method according to any one of claims 1 to 5, wherein the water solubility of the at least one polyalkylene glycol is at least 300 g/l. 7. The method according to any one of claims 1 to 6, wherein the HLB value of the at least one polyalkylene glycol is in the range of 8 to 24. 8. The method according to any one of claims 1 to 7, wherein the Alkylene glycol units of the at least one polyalkylene glycol are at least 60 mol% ethylene glycol units. 9. The method according to any one of claims 1 to 8, whereby a Retarding agent is applied to the metal particle powder. 10. Metal particles, the metal particles using at least one Polyalkylene glycol were ground, the alkylene glycol units of the at least one polyalkylene glycol are selected from ethylene glycol and propylene glycol, at least 50 mol% of the alkylene glycol units are ethylene glycol units, the average molecular weight of the at least one polyalkylene glycol is at least 1000 and the at least one polyalkylene glycol is solid under standard conditions. 1 1 . Metal particles according to claim 10, wherein the amount of the at least one polyalkylene glycol is in the range from 0.6% by weight to 5.7% by weight, based on the weight of the metal particles, with any decomposition products of the at least one present as a result of the grinding Polyalkylene glycol is included. 12. Metal particles according to one of claims 1 to 1 1, wherein the metal particles consist essentially of elemental metal, at least one polyalkylene glycol and any decomposition products of the at least one polyalkylene glycol present as a result of the grinding. 13. Metal particle composition comprising metal particles according to one of claims 10 to 12, wherein the metal particle composition is a powder or a paste. 14. Use of the metal particles according to one of claims 10 to 12 for gas evolution, wherein the metal is aluminum, zinc or mixtures thereof; in a cosmetic; in a plastic or in a coating agent. 15. Use according to claim 14, wherein aluminum particles are used for gas evolution in the production of aerated concrete.