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WO2017120989A1 - Matière première destinée à la préparation d'un panneau décoratif nacré présentant des motifs en trois dimensions, et procédé de préparation d'un panneau décoratif - Google Patents

Matière première destinée à la préparation d'un panneau décoratif nacré présentant des motifs en trois dimensions, et procédé de préparation d'un panneau décoratif Download PDF

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Publication number
WO2017120989A1
WO2017120989A1 PCT/CN2016/072704 CN2016072704W WO2017120989A1 WO 2017120989 A1 WO2017120989 A1 WO 2017120989A1 CN 2016072704 W CN2016072704 W CN 2016072704W WO 2017120989 A1 WO2017120989 A1 WO 2017120989A1
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WIPO (PCT)
Prior art keywords
decorative board
preparing
dimensional
raw material
pearlescent
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Ceased
Application number
PCT/CN2016/072704
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English (en)
Chinese (zh)
Inventor
陈礼根
陈理军
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Individual
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C08K7/20—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/18—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of organic plastics with or without reinforcements or filling materials or with an outer layer of organic plastics with or without reinforcements or filling materials; plastic tiles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0812—Aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

Definitions

  • the invention mainly relates to a method for manufacturing a three-dimensional pearlescent decorative board, and the three-dimensional pearlescent decorative board produced is mainly used for decoration.
  • the decorative plates containing pearlescent materials used as decorative rooms are mostly paint coating finishes, Polaroid plates, pvc veneers, pet veneers, uv plates, artificial stone, quartz stone, etc., but the disadvantage of this decorative plate is that Their colors are uniform and uniform, the pattern is a printed pattern or with some pearl powder as a decoration, there is no three-dimensional pearlescent layer pattern effect, lack of three-dimensional effect, can not meet the user's unique design requirements for the decorative surface.
  • the object of the present invention is to solve a method for manufacturing a three-dimensional pearlescent decorative panel having a good stereoscopic effect.
  • the present invention discloses a raw material for preparing a three-dimensional pearlescent decorative board, which is composed of the following weight percentage materials.
  • Liquid polymeric resin 30-90%
  • Reflective particles 1-30%
  • the rheology aid in the auxiliaries is from 0.1 to 5%.
  • the filler and the pigment respectively comprise two or more substances of different specific gravity, the pigment being selected from a color masterbatch or a color paste, the filler being selected from the group consisting of calcium carbonate, aluminum hydroxide, and hydroxide. , calcium silicate, aluminum oxide or silicon dioxide.
  • the reflective particles include one or a combination of pearl powder, shell powder, pvc particle powder, glass microbead powder, aluminum silver paste, copper gold powder, and the like.
  • the liquid polymer resin is one of methyl methacrylate, crystal resin, polymer resin, acrylic resin, epoxy resin, and polyurethane resin.
  • Another aspect of the present invention provides a method for preparing a three-dimensional pearlescent decorative board, comprising the following steps,
  • the pouring viscosity of the liquid polymeric resin is controlled to be from 10 to 2000 centipoise.
  • the rest time is 30-120 minutes.
  • the invention has the advantages that the single-casting method can prepare the decorative board with good three-dimensional feeling, and at the same time, the pigments and fillers with different specific gravity can be used, and the layers can be layered and lowered when standing, forming a layered pattern; Rheological additives, the establishment of three-dimensional structure, the formation of pseudoplasticity and thixotropic fluidity, the thixotropic flow of the active region of the liquid polymer resin during the patterning process, changing the arrangement of pearlescence to produce pearlescent accumulation to form a pattern, surrounded by patterns The effect of refraction.
  • Example 1 Preparation The raw material of the three-dimensional pearlescent decorative board is composed of the following weight percentage materials.
  • Methyl methacrylate 50%;
  • Aluminum silver paste 5%;
  • Example 2 Preparation The raw material of the three-dimensional pearlescent decorative board is composed of the following weight percentage materials.
  • Shell powder 8%;
  • Rheology additive 0.5%
  • Example 3 The raw material of the three-dimensional pearlescent decorative board was composed of the following weight percentage materials:
  • Polyurethane resin 90%;
  • Aluminum silver paste 1%
  • Shell powder 1%
  • Rheology additive 0.5%
  • Example 4 Preparation The raw material of the three-dimensional pearlescent decorative board is composed of the following weight percentage materials.
  • Epoxy resin 62%
  • Example 5 Preparation The raw material of the three-dimensional pearlescent decorative board is composed of the following weight percentage materials.
  • Polyurethane resin 35%
  • the color masterbatch or color paste in all of the above embodiments is selected from two or more substances having different specific gravities, and the rheological additive is selected as a rheological additive commonly used in the market, and is well known to those skilled in the art, and others.
  • the auxiliary agent mainly includes a curing agent, a promoter, a coupling agent, a leveling agent, an antifoaming agent, a flame retardant, a diluent, etc., and is also a process well known to those skilled in the art.
  • Embodiment 6 Method for preparing three-dimensional pearlescent decorative board
  • liquid polymer resin containing the reflective particles, the rheological assistant, the filler and the pigment is uniformly coated on the backing plate; the liquid polymer resin has a casting viscosity of 100 cps;
  • the pouring viscosity of the liquid polymer resin can be generally controlled at 10 to 2000 centipoise; the standing time can be generally set to 30 to 120 minutes, and the mold can be used in the liquid after standing and layering.
  • Geometrical lines, geometric patterns, wavy lines, irregular lines and patterns are formed on the polymer resin.
  • the pattern is a uniform layered arrangement of the original reflective particles by external force, so that the reflective particles are unevenly stacked and arranged, so that the extruded protrusions are Part of the reflective particles will accumulate, giving a strong three-dimensional sense.
  • the decorative board prepared by the preparation of the invention can be attached to a wall board, a ceiling, a material such as a MDF, a multi-layer board, a plastic board, an acrylic board, an aluminum board, an aluminum honeycomb board, a pvc board, a phenolic fire board or a floor.
  • a material such as a MDF, a multi-layer board, a plastic board, an acrylic board, an aluminum board, an aluminum honeycomb board, a pvc board, a phenolic fire board or a floor.
  • the surface of the door, cabinet, floor, exhibition, furniture decoration, etc. is decorated.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

La présente invention concerne une matière première de préparation d'un panneau décoratif nacré présentant des motifs en trois dimensions, et un procédé de préparation du panneau décoratif. La matière première pour le panneau décoratif comprend des substances ayant les pourcentages suivants en poids : de 30 à 90 % d'une résine polymère liquide, de 1 à 10 % d'un pigment, de 1 à 50 % d'une charge, de 1 à 30 % de particules réfléchissantes, de 1 à 50 % d'autres additifs. La charge et le pigment comprennent chacun deux ou plusieurs substances présentant des poids spécifiques différents. À l'aide du procédé de préparation, le panneau décoratif nacré présentant des motifs en trois dimensions peut être produit en utilisant une approche de coulée en une fois.
PCT/CN2016/072704 2016-01-12 2016-01-29 Matière première destinée à la préparation d'un panneau décoratif nacré présentant des motifs en trois dimensions, et procédé de préparation d'un panneau décoratif Ceased WO2017120989A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610016649.1 2016-01-12
CN201610016649.1A CN105504627B (zh) 2016-01-12 2016-01-12 用于制备立体花纹珠光装饰板的原料及其制造方法

Publications (1)

Publication Number Publication Date
WO2017120989A1 true WO2017120989A1 (fr) 2017-07-20

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Country Link
CN (1) CN105504627B (fr)
WO (1) WO2017120989A1 (fr)

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CN106349533A (zh) * 2016-08-31 2017-01-25 芜湖恒信汽车内饰制造有限公司 汽车立柱饰板用环保材料
CN106280040A (zh) * 2016-08-31 2017-01-04 芜湖恒信汽车内饰制造有限公司 汽车立柱饰板用环保材料的制备方法
CN106544930B (zh) * 2016-10-20 2019-01-04 金建德 商业会所建筑内饰的夜光银浆丝绸装饰材料的制作工艺
CN107298820A (zh) * 2017-06-29 2017-10-27 合肥达户电线电缆科技有限公司 一种环保装饰材料及其生产工艺
CN107163715A (zh) * 2017-07-20 2017-09-15 合肥安力电力工程有限公司 一种内墙用的阻燃装饰板及其制备方法
CN111847987A (zh) * 2020-08-04 2020-10-30 广东原创新材料科技有限公司 一种通体珠光人造石及其制备方法

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CN102922814A (zh) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 花纹人造石板及其制备方法
CN103774816A (zh) * 2014-01-08 2014-05-07 珠海市佳伟力环保科技有限公司 一种辐射固化彩色装饰板

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CN100376638C (zh) * 2004-10-26 2008-03-26 Sk化研株式会社 装饰性涂装材料以及装饰性建材
CN100540293C (zh) * 2006-03-30 2009-09-16 刘建锋 亚克力珠光板及其制备方法
CN201208874Y (zh) * 2008-04-23 2009-03-18 黄玉明 紫外光固化印花装饰板
CN103289341A (zh) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 一种增强型聚碳酸酯复合材料
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Publication number Priority date Publication date Assignee Title
CN1363475A (zh) * 2001-11-15 2002-08-14 郭旭清 人造仿天然石雕装饰件
CN101143538A (zh) * 2007-09-12 2008-03-19 廖笑玲 一种树脂发花装饰面板的制作方法
CN101623974A (zh) * 2009-07-29 2010-01-13 金华市海日家居用品有限公司 装饰板的浮雕装饰方法
CN102922814A (zh) * 2012-11-22 2013-02-13 昆山市大金机械设备厂 花纹人造石板及其制备方法
CN103774816A (zh) * 2014-01-08 2014-05-07 珠海市佳伟力环保科技有限公司 一种辐射固化彩色装饰板

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CN105504627A (zh) 2016-04-20

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