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WO2017114298A1 - 一种环保型耐油密封胶 - Google Patents

一种环保型耐油密封胶 Download PDF

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Publication number
WO2017114298A1
WO2017114298A1 PCT/CN2016/111675 CN2016111675W WO2017114298A1 WO 2017114298 A1 WO2017114298 A1 WO 2017114298A1 CN 2016111675 W CN2016111675 W CN 2016111675W WO 2017114298 A1 WO2017114298 A1 WO 2017114298A1
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parts
oil
resistant sealant
plasticizer
paraffin
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PCT/CN2016/111675
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French (fr)
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李栋军
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Definitions

  • the present invention relates to an environmentally friendly oil resistant sealant.
  • sealants have been used in joint sealing of building structures and have gradually become the main material.
  • sealant is not only used in construction, civil engineering, and bridges, but also widely used in many engineering fields such as container, ship, electrical, and aerospace.
  • Sealant can be used to fill the configuration gap to provide a good sealing effect, with anti-leakage, waterproof, anti-vibration and sound insulation, heat insulation and so on.
  • the traditional sealant has the defects of poor oil resistance and tearing, and it will cause certain pollution to the environment, which does not meet the current requirements. .
  • the problem to be solved by the present invention is to provide an environmentally-friendly oil-resistant sealant, which has good acid and alkali resistance, oil resistance, stable bonding, flexibility, and simple preparation process. Poisonous, non-corrosive, no pollution to the environment.
  • the technical solution of the present invention is an environmentally-friendly oil-resistant sealant which is made of the following raw materials by weight: 8-15 parts of ethylene glycol, 6-14 parts of talcum powder, 8-15 parts of phenyl silicone oil, 12-24 parts of diethyl methoxysiloxy group, 15-30 parts of carbon black, 12-20 parts of plasticizer, 15-24 parts of nano calcium carbonate, 0.8-tackifying resin 1.7 parts, 20-32 parts of flame retardant filler, 1.5-4 parts of water scavenger, 2-7 parts of heat stabilizer, 0.8-1.8 parts of glass fiber, 0.8-1.5 parts of magnesium dimethacrylate, 1.5-2.5 parts of paraffin, Diacetyl peroxide 0.5-3. 2 parts, epoxy resin 4-6 parts.
  • an environmentally-friendly oil-resistant sealant made of the following parts by weight: 12 parts of ethylene glycol, 10 parts of talc, 11 parts of phenyl silicone oil, diethyl methoxysilicon oxide 18 parts, 23 parts carbon black, 16 parts plasticizer, 19 parts of nano calcium carbonate, 1.3 parts of tackifying resin, 26 parts of flame retardant filler, 2.9 parts of moisture scavenger, heat 4.5 parts of stabilizer, 1.3 parts of glass fiber, 1 part of magnesium dimethacrylate, 2 parts of paraffin, 2.3 parts of diacetyl peroxide, and 5 parts of epoxy resin.
  • the beneficial effect of the invention is that the environment-friendly oil-resistant sealant of the invention has good acid and alkali resistance, oil resistance, stable bonding, elasticity, simple preparation process, non-toxic, non-corrosive, no environment Pollution.
  • An environmentally friendly oil-resistant sealant made of the following parts by weight: 12 parts of ethylene glycol, 10 parts of talc, 11 parts of phenyl silicone oil, 18 parts of diethyl methoxysiloxy 23 parts of carbon black, 16 parts of plasticizer, 19 parts of nano calcium carbonate, 1.3 parts of tackifying resin, 26 parts of flame retardant filler, 2.9 parts of water scavenger, 4.5 parts of heat stabilizer, 1.3 parts of glass fiber, dimethyl 1 part of magnesium acrylate, 2 parts of paraffin, 2.3 parts of diacetyl peroxide, and 5 parts of epoxy resin.
  • An environmentally-friendly oil-resistant sealant made of the following parts by weight: 8 parts of ethylene glycol, 6 parts of talc, 8 parts of phenyl silicone oil, 12 parts of diethyl methoxysiloxy , 15 parts of carbon black, 12 parts of plasticizer, 15 parts of nano calcium carbonate, 0.8 parts of tackifying resin, 20 parts of flame retardant filler, 1.5 parts of water scavenger, 2 parts of heat stabilizer, 0.8 parts of glass fiber, dimethyl 0.8 parts of magnesium acrylate, 1.5 parts of paraffin, 0.5 parts of diacetyl peroxide, and 4 parts of epoxy resin.
  • An environmentally friendly oil-resistant sealant made of the following parts by weight: 15 parts of ethylene glycol, 14 parts of talc, 15 parts of phenyl silicone oil, 24 parts of diethyl methoxysiloxy 30 parts of carbon black, 20 parts of plasticizer, 24 parts of nano calcium carbonate, 1.7 parts of tackifying resin, 32 parts of flame retardant filler, 4 parts of moisture scavenger, 7 parts of heat stabilizer, 1.8 parts of glass fiber, dimethyl 1.5 parts of magnesium acrylate, 2.5 parts of paraffin, 3.2 parts of diacetyl peroxide, and 6 parts of epoxy resin.
  • Example 3 Example 3
  • An environmentally friendly oil-resistant sealant made of the following parts by weight of raw materials: 12 parts of ethylene glycol, 10 parts of talc, 11 parts of phenyl silicone oil, 18 parts of diethyl methoxysiloxy 23 parts of carbon black, 16 parts of plasticizer, 19 parts of nano calcium carbonate, 1.3 parts of tackifying resin, 26 parts of flame retardant filler, 2.9 parts of water scavenger, 4.5 parts of heat stabilizer, 1.3 parts of glass fiber, dimethyl 1 part of magnesium acrylate, 2 parts of paraffin, 2.3 parts of diacetyl peroxide, and 5 parts of epoxy resin.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Sealing Material Composition (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

一种环保型耐油密封胶,其由以下重量份数的原料制成:乙二醇8-15份,滑石粉6-14份,苯基硅油8-15份,二乙基甲氧基硅氧基12-24份,炭黑15-30份,增塑剂12-20份,纳米碳酸钙15-24份,增粘树脂0.8-1.7份,阻燃填料20-32份,水分清除剂1.5-4份,热稳定剂2-7份,玻璃纤维0.8-1.8份,二甲基丙烯酸镁0.8-1.5份,石蜡1.5-2.5份,过氧化二乙酰0.5-3.2份,环氧树脂4-6份。本发明的有益效果是,本发明的环保型耐油密封胶,具有很好的耐酸碱、耐油性能,粘接稳定,有弹性,制备工艺简单,无毒、无腐蚀,对环境没有污染。

Description

说明书 发明名称:一种环保型耐油密封胶
技术领域
[0001] 本发明涉及一种环保型耐油密封胶。
背景技术
[0002] 七十年代以后, 密封胶已幵始用于建筑结构接缝密封, 逐渐成为主体材料。 随 着密封胶的发展, 密封胶不但被用于建筑、 土木、 桥梁, 而且也广泛的应用于 集装箱、 船舶、 电气、 航天等众多工程领域。 密封胶可以用来填充构形间隙、 以起到很好密封作用, 具有防泄漏、 防水、 防振动及隔音、 隔热等作用。 随着 市场需求量的增加, 对密封胶的性能的要求也越来越高, 传统的密封胶存在耐 油性差、 易撕裂的缺陷, 而且会对环境造成一定的污染, 不符合现在的使用要 求。
技术问题
[0003] 针对现有技术的不足, 本发明要解决的问题是, 提供一种环保型耐油密封胶, 具有很好的耐酸碱、 耐油性能, 粘接稳定, 有弹性, 制备工艺简单, 无毒、 无 腐蚀, 对环境没有污染。
问题的解决方案
技术解决方案
[0004] 为解决上述技术问题, 本发明的技术方案是, 一种环保型耐油密封胶, 其由以 下重量份数的原料制成: 乙二醇 8-15份, 滑石粉 6-14份, 苯基硅油 8-15份, 二乙 基甲氧基硅氧基 12-24份, 炭黑 15-30份, 增塑剂 12-20份, 纳米碳酸钙 15-24份, 增粘树脂 0.8-1.7份, 阻燃填料 20-32份, 水分清除剂 1.5-4份, 热稳定剂 2-7份, 玻 璃纤维 0.8-1.8份, 二甲基丙烯酸镁 0.8-1.5份, 石蜡 1.5-2.5份, 过氧化二乙酰 0.5-3. 2份, 环氧树脂 4-6份。
[0005] 优化的, 一种环保型耐油密封胶, 其由以下重量份数的原料制成: 乙二醇 12份 , 滑石粉 10份, 苯基硅油 11份, 二乙基甲氧基硅氧基 18份, 炭黑 23份, 增塑剂 1 6份, 纳米碳酸钙 19份, 增粘树脂 1.3份, 阻燃填料 26份, 水分清除剂 2.9份, 热 稳定剂 4.5份, 玻璃纤维 1.3份, 二甲基丙烯酸镁 1份, 石蜡 2份, 过氧化二乙酰 2.3 份, 环氧树脂 5份。
发明的有益效果
有益效果
[0006] 本发明的有益效果是, 本发明的环保型耐油密封胶, 具有很好的耐酸碱、 耐油 性能, 粘接稳定, 有弹性, 制备工艺简单, 无毒、 无腐蚀, 对环境没有污染。 实施该发明的最佳实施例
本发明的最佳实施方式
[0007] 一种环保型耐油密封胶, 其由以下重量份数的原料制成: 乙二醇 12份, 滑石粉 10份, 苯基硅油 11份, 二乙基甲氧基硅氧基 18份, 炭黑 23份, 增塑剂 16份, 纳 米碳酸钙 19份, 增粘树脂 1.3份, 阻燃填料 26份, 水分清除剂 2.9份, 热稳定剂 4.5 份, 玻璃纤维 1.3份, 二甲基丙烯酸镁 1份, 石蜡 2份, 过氧化二乙酰 2.3份, 环氧 树脂 5份。
本发明的实施方式
[0008] 实施例 1
[0009] 一种环保型耐油密封胶, 其由以下重量份数的原料制成: 乙二醇 8份, 滑石粉 6 份, 苯基硅油 8份, 二乙基甲氧基硅氧基 12份, 炭黑 15份, 增塑剂 12份, 纳米碳 酸钙 15份, 增粘树脂 0.8份, 阻燃填料 20份, 水分清除剂 1.5份, 热稳定剂 2份, 玻璃纤维 0.8份, 二甲基丙烯酸镁 0.8份, 石蜡 1.5份, 过氧化二乙酰 0.5份, 环氧 树脂 4份。
[0010] 实施例 2
[0011] 一种环保型耐油密封胶, 其由以下重量份数的原料制成: 乙二醇 15份, 滑石粉 14份, 苯基硅油 15份, 二乙基甲氧基硅氧基 24份, 炭黑 30份, 增塑剂 20份, 纳 米碳酸钙 24份, 增粘树脂 1.7份, 阻燃填料 32份, 水分清除剂 4份, 热稳定剂 7份 , 玻璃纤维 1.8份, 二甲基丙烯酸镁 1.5份, 石蜡 2.5份, 过氧化二乙酰 3.2份, 环 氧树脂 6份。 [0012] 实施例 3
[0013] 一种环保型耐油密封胶, 其由以下重量份数的原料制成: 乙二醇 12份, 滑石粉 10份, 苯基硅油 11份, 二乙基甲氧基硅氧基 18份, 炭黑 23份, 增塑剂 16份, 纳 米碳酸钙 19份, 增粘树脂 1.3份, 阻燃填料 26份, 水分清除剂 2.9份, 热稳定剂 4.5 份, 玻璃纤维 1.3份, 二甲基丙烯酸镁 1份, 石蜡 2份, 过氧化二乙酰 2.3份, 环氧 树脂 5份。

Claims

权利要求书
[权利要求 1] 一种环保型耐油密封胶, 其特征在于: 其由以下重量份数的原料制成
: 乙二醇 8-15份, 滑石粉 6-14份, 苯基硅油 8-15份, 二乙基甲氧基硅 氧基 12-24份, 炭黑 15-30份, 增塑剂 12-20份, 纳米碳酸钙 15-24份, 增粘树脂 0.8-1.7份, 阻燃填料 20-32份, 水分清除剂 1.5-4份, 热稳定 剂 2-7份, 玻璃纤维 0.8-1.8份, 二甲基丙烯酸镁 0.8-1.5份, 石蜡 1.5-2.5 份, 过氧化二乙酰 0.5-3.2份, 环氧树脂 4-6份。
[权利要求 2] 根据权利要求 1所述的环保型耐油密封胶, 其特征在于: 其由以下重 量份数的原料制成: 乙二醇 12份, 滑石粉 10份, 苯基硅油 11份, 二乙 基甲氧基硅氧基 18份, 炭黑 23份, 增塑剂 16份, 纳米碳酸钙 19份, 增 粘树脂 1.3份, 阻燃填料 26份, 水分清除剂 2.9份, 热稳定剂 4.5份, 玻 璃纤维 1.3份, 二甲基丙烯酸镁 1份, 石蜡 2份, 过氧化二乙酰 2.3份, 环氧树脂 5份。
PCT/CN2016/111675 2015-12-30 2016-12-23 一种环保型耐油密封胶 Ceased WO2017114298A1 (zh)

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CN105567154A (zh) * 2015-12-30 2016-05-11 李栋军 一种环保型耐油密封胶

Citations (3)

* Cited by examiner, † Cited by third party
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WO2009038020A1 (ja) * 2007-09-19 2009-03-26 Toray Industries, Inc. 電子部品用接着剤組成物およびそれを用いた電子部品用接着剤シート
CN102086365A (zh) * 2010-12-27 2011-06-08 东莞市腾威电子材料技术有限公司 一种胶黏剂及其制备方法和在集成线路板灌封中的应用
CN105567154A (zh) * 2015-12-30 2016-05-11 李栋军 一种环保型耐油密封胶

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CN104610904B (zh) * 2015-01-23 2017-11-17 朱小英 一种防水汽电子器件密封胶的制备方法
CN104610903B (zh) * 2015-01-23 2017-10-31 朱小英 一种防水汽电子器件密封胶

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Publication number Priority date Publication date Assignee Title
WO2009038020A1 (ja) * 2007-09-19 2009-03-26 Toray Industries, Inc. 電子部品用接着剤組成物およびそれを用いた電子部品用接着剤シート
CN102086365A (zh) * 2010-12-27 2011-06-08 东莞市腾威电子材料技术有限公司 一种胶黏剂及其制备方法和在集成线路板灌封中的应用
CN105567154A (zh) * 2015-12-30 2016-05-11 李栋军 一种环保型耐油密封胶

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