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WO2017156608A1 - Sunscreen product and method for applying a sunscreen product to the skin - Google Patents

Sunscreen product and method for applying a sunscreen product to the skin Download PDF

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Publication number
WO2017156608A1
WO2017156608A1 PCT/BR2017/050053 BR2017050053W WO2017156608A1 WO 2017156608 A1 WO2017156608 A1 WO 2017156608A1 BR 2017050053 W BR2017050053 W BR 2017050053W WO 2017156608 A1 WO2017156608 A1 WO 2017156608A1
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Prior art keywords
vitamin
sunscreen
skin
product
sun protection
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PCT/BR2017/050053
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French (fr)
Portuguese (pt)
Inventor
Luiz Francisco Pianowski
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/59Compounds containing 9, 10- seco- cyclopenta[a]hydrophenanthrene ring systems
    • A61K31/5939,10-Secocholestane derivatives, e.g. cholecalciferol, i.e. vitamin D3
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11Encapsulated compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20Polycyclic condensed hydrocarbons
    • C07C15/27Polycyclic condensed hydrocarbons containing three rings
    • C07C15/30Phenanthrenes

Definitions

  • the present invention relates generally to products providing sunscreen, additionally containing vitamin D3.
  • the present invention relates to topical formulations of any nature, particularly cosmetic, dermatological or dermocosmetic, which provide sunscreen and additionally contain vitamin D3, particularly in the form of nanoparticles.
  • Vitamin D is an essential fat soluble steroid hormone for the human body and its absence can provide a number of complications. Vitamin D is known to control 270 genes, including cells in the cardiovascular system. The main source of vitamin production is through sun exposure, because type B ultraviolet rays (UVB) are able to activate the synthesis of this substance. Some foods, especially fatty fish, are sources of vitamin D, but the sun is responsible for 80 to 90% of the vitamin the body receives. It can also be produced in the laboratory and given as a supplement when there is a deficiency and for the prevention and treatment of a variety of diseases.
  • UVB type B ultraviolet rays
  • Vitamin D is necessary for the maintenance of bone tissue, it also influences considerably in the immune system, being interesting for the treatment of autoimmune diseases such as rheumatoid arthritis and multiple sclerosis, and in the process of cell differentiation, the lack of this nutrient favors 17 types of cancer.
  • This substance also acts on hormone secretion and several chronic noncommunicable diseases, among them the metabolic syndrome that has type 2 diabetes as one of its components.
  • Vitamin consumption is essential for pregnant women, lack of it can lead to miscarriages in the first trimester. At the end of pregnancy, nutrient deficiency favors preeclampsia and increases the chances of the child being autistic.
  • Vitamin D besides being obtained exogenously, also has endogenous synthesis. It needs to be metabolized to 1,25 (OH) 2 D3, which is its active form and acts similar to steroid hormones. It comes from two sources: present in natural sources ingested and synthesized in the skin. Ingestion vitamin D comes in two forms: D2 (calciferol), synthesized in plants from the precursor ergosterol and D3 (cholecalciferol), from non-plant foods. Both undergo the same metabolization process to become active.
  • Skin vitamin D3 is produced from 7-dihydrocholesterol (pro-vitamin D3), the immediate precursor of cholesterol. By solar radiation (ultraviolet B), it is transformed into pre-vitamin D3, which undergoes heat-induced isomerization for a few hours, forming vitamin D3.
  • the present invention overcomes the above problem by means of sunscreen products, characterized in that it contains one or more sunscreens as well as vitamin D3 in microencapsulated form.
  • sunscreen products is indicative of topical products, encompassing both those intended solely to provide sunscreen and products not specifically intended for that purpose, but which understand how Additional benefit ingredient is a sunscreen agent, for example anti-aging products, facial or body care products, makeup, suntan lotions, skin moisturizers, insect repellents, topical medicines, etc.
  • vitamin D3 encompasses both vitamin D3 (cholecalciferol) itself, as well as precursors and metabolites of vitamin D3, which provide the aforementioned benefits.
  • Nanoparticles are known to man in the art, defined as solid colloidal particles typically sized from 10 to 1000 nanometers, in which chemical compounds are dissolved, captured, encapsulated, or to which they are chemically bonded or adsorbed into a polymer matrix. They are synonymous with nanocapsules, typically defined as vesicular systems consisting of a membrane of synthetic or natural polymers encapsulating a liquid or solid in its central cavity.
  • Typical examples of nanoparticles / nanocapsules are liposomes.
  • synthetic polymers used for nanocapsulation are polylactides (PLA), polyglycolides (PGA), poly (lactam co-glycolides) (PLGA), polyanhydrides, polyalkylcyanoacrylates, polycaprolactone, polyglutamic acid, polymeric acid, polyvinylpyrrolidone, polymethylmethacrylate, polymethylmethacrylate, polymethylmethacrylate , polyacrylamide, polyethylene glycol, polymethacrylic acid, polystyrene sulfonate, polyallylamine hydrochloride, etc.
  • Sun protection agents are intended to absorb or reflect ultraviolet (UV) radiation from the sun on skin or hair exposed to sunlight.
  • UV radiation ultraviolet
  • the use of products containing such agents helps to protect against a number of deleterious effects of radiation such as sunburn, wrinkles, loss of elasticity, photodermatitis and cancer.
  • sunscreen agents contained in sunscreen products that chemically absorb UV radiation are: aminobenzoic acid, avobenzone, benzophenone, cinnamate, cinoxate, dioxibenzone, ensulizole, ethylhexyl p-methoxycinnamate, octyl salicylate, menthyl anthranilate, homosalate, meradimate, octisalate, octinoxate, octocrene, PABA (p-aminobenzoic acid), sulisobenzone and trolamine salicylate.
  • sunscreen agents contained in sunscreen products that physically block UV radiation includes the following metal oxides: iron, titanium, cerium, zinc, aluminum and zirconium.
  • UV-A and IR (infrared) radiation are co-responsible for premature skin aging, including loss of skin elasticity and wrinkles, and specific additives to block / absorb such radiation in sun protection products are known.
  • the sunscreen products of the invention are characterized in that they comprise at least one sunscreen agent, nanoparticulate vitamin D3 and at least one vehicle for topical application.
  • Sunscreen products according to the invention which permit topical application are of any nature known to the man of the art, such as water-in-oil or oil-in-water emulsions, ointments, ointments, cream, gel, spray, or any other fit for purpose.
  • the vitamin D3 nanocapsule (or nanoparticle) contained in the formulation of the sunscreen products of the invention can release vitamin D3 by rupture under pressure, with time passing, by reaction with chemicals contained in the human body, or by any other effect.
  • Sunscreen products of the invention are known per se and may contain one or more components of various active agents, surfactants, emollients, skin conditioners, stabilizers, antioxidants, humectants, buffering agents, thickeners, preservatives, chelating agents, emulsifiers , dyes, etc.
  • sunscreen products are cosmetic compositions.
  • Such compositions and ways of preparing them are known in the art, exemplified in the publication “Sunscreens: Development: Evaluation, and Regulatory Aspects”, Lowe, N.J. et al., Mareei Dekker, 2nd edition, 1997.
  • the invention in another aspect, relates to the process of applying the sunscreen product to the skin, characterized by bringing an effective amount of said product into contact with the skin.
  • An effective amount is that which enables the effects of sunscreen and vitamin D3 administration to be achieved.
  • “Putting ... this product in contact with the skin” means any form suitable for the purpose, for example using applicators, for example spray applicators, brushes, sponges or the like, or with one's own hands. by pouring product and spreading it on the skin with rubbing or massaging activity.
  • an effective amount of the purpose composition is to apply to the skin amounts between 1 mg / cm 2 and 3 mg / cm 2 .
  • the part of the body to which the sun protection product of the The invention may be any depending on the purpose. The larger the area of skin to which the product is applied, the more likely it is to administer vitamin D3 to the body.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Medicinal Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Cosmetics (AREA)

Abstract

The present invention generally relates to sunscreen products additionally containing vitamin D3. In particular, the present invention relates to topical formulations of any nature, particularly cosmetic, dermatological or dermocosmetic formulations that provide protection against solar radiation and in addition contain vitamin D3, especially in the form of nanoparticles.

Description

PRODUTO DE PROTEÇÃO SOLAR E PROCESSO DE SOLAR PROTECTION PRODUCT AND

APLICAÇÃO DE PRODUTO DE PROTEÇÃO SOLAR À PELE APPLICATION OF SKIN SOLAR PROTECTION PRODUCT

A presente invenção refere-se na sua generalidade a produtos que propiciam proteção solar, adicionalmente contendo vitamina D3.  The present invention relates generally to products providing sunscreen, additionally containing vitamin D3.

De forma particular, a presente invenção refere-se a formulações tópicas de qualquer natureza, particularmente cosméticas, dermatológicas ou dermocosméticas, que propiciam proteção solar e que adicionalmente contêm vitamina D3, particularmente sob forma de nanopartículas.  In particular, the present invention relates to topical formulations of any nature, particularly cosmetic, dermatological or dermocosmetic, which provide sunscreen and additionally contain vitamin D3, particularly in the form of nanoparticles.

ANTECEDENTES DA TECNOLOGIA TECHNOLOGY BACKGROUND

A vitamina D é um hormônio esteroide lipossolúvel essencial para o corpo humano e sua ausência pode proporcionar uma série de complicações. Sabe-se que a vitamina D controla 270 genes, inclusive células do sistema cardiovascular. A principal fonte de produção da vitamina se dá por meio da exposição solar, pois os raios ultravioletas do tipo B (UVB) são capazes de ativar a síntese dessa substância. Alguns alimentos, especialmente peixes gordos, são fontes de vitamina D, mas é o sol o responsável por 80 a 90% da vitamina que o corpo recebe. Ela também pode ser produzida em laboratório e ser administrada na forma de suplemento, quando há a deficiência e para a prevenção e tratamento de uma série de doenças.  Vitamin D is an essential fat soluble steroid hormone for the human body and its absence can provide a number of complications. Vitamin D is known to control 270 genes, including cells in the cardiovascular system. The main source of vitamin production is through sun exposure, because type B ultraviolet rays (UVB) are able to activate the synthesis of this substance. Some foods, especially fatty fish, are sources of vitamin D, but the sun is responsible for 80 to 90% of the vitamin the body receives. It can also be produced in the laboratory and given as a supplement when there is a deficiency and for the prevention and treatment of a variety of diseases.

A vitamina D é necessária para a manutenção do tecido ósseo, ela também influencia consideravelmente no sistema imunológico, sendo interessante para o tratamento de doenças autoimunes, como a artrite reumatóide e a esclerose múltipla, e no processo de diferenciação celular, a falta deste nutriente favorece 17 tipos de câncer.  Vitamin D is necessary for the maintenance of bone tissue, it also influences considerably in the immune system, being interesting for the treatment of autoimmune diseases such as rheumatoid arthritis and multiple sclerosis, and in the process of cell differentiation, the lack of this nutrient favors 17 types of cancer.

Esta substância ainda age na secreção hormonal e em diversas doenças crónicas não transmissíveis, entre elas a síndrome metabólica que tem como um dos componentes o diabetes tipo 2.  This substance also acts on hormone secretion and several chronic noncommunicable diseases, among them the metabolic syndrome that has type 2 diabetes as one of its components.

O consumo da vitamina é essencial para as gestantes, a falta dela pode levar a abortos no primeiro trimestre. Já no final da gravidez, a carência do nutriente favorece a pré-eclâmpsia e aumenta as chances da criança ser autista.  Vitamin consumption is essential for pregnant women, lack of it can lead to miscarriages in the first trimester. At the end of pregnancy, nutrient deficiency favors preeclampsia and increases the chances of the child being autistic.

A vitamina D, além de ser obtida exogenamente, tem também síntese endógena. Necessita ser metabolizada até 1 ,25(OH)2D3, que é sua forma ativa e age similarmente aos hormônios esteroides. Origina-se de duas fontes: presente em fontes naturais na ingesta e a sintetizada na pele. A vitamina D da ingesta apresenta-se sob duas formas: D2 (calciferol), sintetizada em plantas a partir do precursor ergosterol e a D3 (colecalciferol), dos alimentos não vegetais. Ambas sofrem o mesmo processo de metabolização para se tornarem ativas. Vitamin D, besides being obtained exogenously, also has endogenous synthesis. It needs to be metabolized to 1,25 (OH) 2 D3, which is its active form and acts similar to steroid hormones. It comes from two sources: present in natural sources ingested and synthesized in the skin. Ingestion vitamin D comes in two forms: D2 (calciferol), synthesized in plants from the precursor ergosterol and D3 (cholecalciferol), from non-plant foods. Both undergo the same metabolization process to become active.

A vitamina D3 da pele é produzida a partir do 7-diidrocolesterol (pró-vitamina D3), precursor imediato do colesterol. Por ação da radiação solar (ultravioleta B), é transformada em pré-vitamina D3, que sofre uma isomerização induzida pelo calor, durante algumas horas, formando-se a vitamina D3.  Skin vitamin D3 is produced from 7-dihydrocholesterol (pro-vitamin D3), the immediate precursor of cholesterol. By solar radiation (ultraviolet B), it is transformed into pre-vitamin D3, which undergoes heat-induced isomerization for a few hours, forming vitamin D3.

Entretanto, com a conscientização dos danos que a exposição constante aos raios solares proporciona é cada vez mais comum o uso de produtos que propiciam proteção solar, tanto aqueles especificamente para esse uso quanto produtos voltados a outras finalidades que contém, adicionalmente, filtros solares. Em consequência, vem se constatando um déficit de vitamina D na população devido à diminuição ou mesmo bloqueio completo da ativação da vitamina pelo sol devido ao uso produtos que propiciam proteção solar.  However, with the awareness of the damage that constant exposure to sunlight provides, it is increasingly common to use products that provide sun protection, both specifically for this use and products intended for other purposes that additionally contains sunscreens. As a result, there has been a vitamin D deficit in the population due to the decrease or even complete blocking of vitamin activation by the sun due to the use of products that provide sun protection.

Dessa forma surgiu a necessidade de um protetor solar contemplando a nanotecnologia para liberação constante e controlada de vitamina D3, minimizando assim, o déficit proporcionado pelo bloqueio dos raios solares.  Thus came the need for a sunscreen contemplating nanotechnology for constant and controlled release of vitamin D3, thus minimizing the deficit provided by blocking the sun's rays.

DESCRIÇÃO DA INVENÇÃO  DESCRIPTION OF THE INVENTION

A presente invenção vem superar o problema acima mencionado por meio de produtos de proteção solar, caracterizados pelo fato de conter um ou mais filtros solares, assim como vitamina D3 sob forma microencapsulada.  The present invention overcomes the above problem by means of sunscreen products, characterized in that it contains one or more sunscreens as well as vitamin D3 in microencapsulated form.

Conforme sentido aqui empregado, a expressão "produtos de proteção solar" é indicativa de produtos tópicos, englobando tanto aqueles que visam unicamente proporcionar proteção solar quanto produtos não especificamente voltados à a essa finalidade, mas que compreendem como ingrediente de benefício adicional um agente protetor solar, por exemplo, produtos antienvelhecimento, produtos de tratamento facial ou corporal, maquiagem, bronzeadores, hidratantes para pele, repelentes de insetos, medicamentos tópicos, etc. As used herein, the term "sunscreen products" is indicative of topical products, encompassing both those intended solely to provide sunscreen and products not specifically intended for that purpose, but which understand how Additional benefit ingredient is a sunscreen agent, for example anti-aging products, facial or body care products, makeup, suntan lotions, skin moisturizers, insect repellents, topical medicines, etc.

Ainda conforme sentido aqui empregado, a expressão "vitamina D3" engloba tanto a vitamina D3 (colecalciferol) propriamente dita, quanto precursores e metabolitos da vitamina D3, que propiciam os benefícios já mencionados mais atrás.  Still as used herein, the term "vitamin D3" encompasses both vitamin D3 (cholecalciferol) itself, as well as precursors and metabolites of vitamin D3, which provide the aforementioned benefits.

Nanopartículas são conhecidas do homem da técnica, definidas como partículas coloidais sólidas de tamanhos tipicamente entre 10 a 1000 nanômetros, nas quais compostos químicos são dissolvidos, capturados, encapsulados, ou às quais estão quimicamente ligados ou adsorvidos em uma matriz polimérica. São sinónimos de nanocápsulas, tipicamente definidas como sistemas vesiculares consistindo de uma membrana de polímeros sintéticos ou naturais, que encapsula um líquido ou sólido na sua cavidade central.  Nanoparticles are known to man in the art, defined as solid colloidal particles typically sized from 10 to 1000 nanometers, in which chemical compounds are dissolved, captured, encapsulated, or to which they are chemically bonded or adsorbed into a polymer matrix. They are synonymous with nanocapsules, typically defined as vesicular systems consisting of a membrane of synthetic or natural polymers encapsulating a liquid or solid in its central cavity.

Exemplos típicos de nanopartículas/nanocápsulas são os lipossomas. Exemplos de polímeros sintéticos usados para nanoencapsulação são polilactídeos (PLA), poliglicolídeos (PGA), poli (lactídeos co-glicolídeos) (PLGA), polianidridos, polialquilcianoacrilatos, policaprolactona, ácido poliglutâmico, ácido polimálico, polivinilpirrolidona, polimetilmetacrilato, álcool polivinílico, ácido poliacrílico, poliacrilamida, polietileno glicol, ácido polimetacrílico, poliestireno sulfonato, polialilamina cloridrato, etc.  Typical examples of nanoparticles / nanocapsules are liposomes. Examples of synthetic polymers used for nanocapsulation are polylactides (PLA), polyglycolides (PGA), poly (lactam co-glycolides) (PLGA), polyanhydrides, polyalkylcyanoacrylates, polycaprolactone, polyglutamic acid, polymeric acid, polyvinylpyrrolidone, polymethylmethacrylate, polymethylmethacrylate, polymethylmethacrylate , polyacrylamide, polyethylene glycol, polymethacrylic acid, polystyrene sulfonate, polyallylamine hydrochloride, etc.

O conhecimento da nanotecnologia adequado à presente invenção pode ser exemplificado pelas publicações abaixo:  Knowledge of nanotechnology suitable for the present invention can be exemplified by the publications below:

- MOGHIMI, S.M.; HUNTER, A.C.; MURRAY, J.C. Nanomedicine: current status and future prospects. The FASEB J., v.19, p.31 1 -330, 2005.  MOGHIMI, S.M .; HUNTER, A.C .; MURRAY, J.C. Nanomedicine: current status and future prospects. The FASEB J., v.19, p.31-130, 2005.

- KOTHASAMU, P. et al. Nanocapsules: The Weapons for Novel Drug Delivery Systems. Biolmpacts, 2012, 2(2), 71 -81 .  - KOTHASAMU, P. et al. Nanocapsules: The Weapons for Novel Drug Delivery Systems. Biolmpacts, 2012, 2 (2), 71-81.

- MORA-HUERTAS CE, FESSI H, ELAISSARI A. Polymer-based nanocapsules for drug delivery. Int J Pharm. 2010 Jan 29;385(1 -2):1 13-42.  - MORA-HUERTAS CE, FESSI H, ELAISSARI A. Polymer-based nanocapsules for drug delivery. Int J Pharm. 2010 Jan 29; 385 (1-2): 11-42.

Agentes de proteção solar (englobando todos os diferentes nomes como "protetor solar", "filtro solar", "bloqueador solar", "anti solar", "fotoprotetor", etc.) visam absorver ou refletir a radiação ultravioleta (UV) do sol sobre a pele ou os cabelos expostos à luz solar. Em relação à pele, o uso de produtos contendo tais agentes ajuda a protegê-la contra uma série de efeitos deletérios da radiação, como queimaduras solares, rugas de envelhecimento precoce, perda de elasticidade, fotodermatite e câncer. Sun protection agents (encompassing all the different names such as "sunscreen", "sunscreen", "sunscreen", "anti sunscreen", "photoprotector", etc.) are intended to absorb or reflect ultraviolet (UV) radiation from the sun on skin or hair exposed to sunlight. With regard to the skin, the use of products containing such agents helps to protect against a number of deleterious effects of radiation such as sunburn, wrinkles, loss of elasticity, photodermatitis and cancer.

Os diferentes agentes de proteção solar têm diferentes maneiras de lidar com a luz solar para proporcionar "proteção solar", seja absorvendo quimicamente a radiação ultravioleta, seja bloqueando fisicamente a radiação ultravioleta.  Different sun protection agents have different ways of dealing with sunlight to provide "sun protection", either by chemically absorbing ultraviolet radiation or by physically blocking ultraviolet radiation.

Uma lista não limitante de agentes de proteção solar contidos em produtos de proteção solar que absorvem quimicamente a radiação UV é: ácido aminobenzoico, avobenzona, benzofenona, cinamatos, cinoxato, dioxibenzona, ensulizol, etilhexil p-metoxicinamato, octil salicilato, antranilato de mentila, homossalato, meradimato, octisalato, octinoxato, octocrileno, PABA (ácido p- aminobenzoico), sulisobenzona e salicilato de trolamina.  A non-limiting list of sunscreen agents contained in sunscreen products that chemically absorb UV radiation are: aminobenzoic acid, avobenzone, benzophenone, cinnamate, cinoxate, dioxibenzone, ensulizole, ethylhexyl p-methoxycinnamate, octyl salicylate, menthyl anthranilate, homosalate, meradimate, octisalate, octinoxate, octocrene, PABA (p-aminobenzoic acid), sulisobenzone and trolamine salicylate.

Uma lista não limitativa de agentes de proteção solar contidos em produtos de proteção solar que bloqueiam fisicamente a radiação UV compreende os seguintes óxidos metálicos: ferro, titânio, cério, zinco, alumínio e zircônio.  A non-limiting list of sunscreen agents contained in sunscreen products that physically block UV radiation includes the following metal oxides: iron, titanium, cerium, zinc, aluminum and zirconium.

Embora a maioria dos produtos de proteção solar proteja apenas contra raios UV-B, que causam queimaduras, a exposição à radiações UV-A e IV (infravermelho) são co-responsáveis pelo envelhecimento precoce da pele, incluindo a perda de elasticidade da pele e o aparecimento de rugas, e são conhecidos aditivos específicos para bloquear/absorver tais radiações em produtos de proteção solar.  While most sunscreen products only protect against sunburning UV-B rays, exposure to UV-A and IR (infrared) radiation is co-responsible for premature skin aging, including loss of skin elasticity and wrinkles, and specific additives to block / absorb such radiation in sun protection products are known.

Dentro de um aspecto, os produtos de proteção solar da invenção são caracterizados por compreender ao menos um agente de proteção solar, vitamina D3 sob forma de nanopartícula e ao menos um veículo para aplicação tópica.  In one aspect, the sunscreen products of the invention are characterized in that they comprise at least one sunscreen agent, nanoparticulate vitamin D3 and at least one vehicle for topical application.

Produtos de proteção solar segundo a invenção, que permitem aplicação tópica, são de qualquer natureza conhecida do homem da técnica, como emulsões água em óleo ou óleo em água, unguentos, pomadas, creme, gel, spray, ou qualquer outra adequada à finalidade. Sunscreen products according to the invention which permit topical application are of any nature known to the man of the art, such as water-in-oil or oil-in-water emulsions, ointments, ointments, cream, gel, spray, or any other fit for purpose.

A nanocápsula (ou nanopartícula) de vitamina D3 contida na formulação dos produtos de proteção solar da invenção pode liberar a vitamina D3 por ruptura sob pressão, com passagem do tempo, por reação com compostos químicos contidos no organismo humano, ou por qualquer outro efeito.  The vitamin D3 nanocapsule (or nanoparticle) contained in the formulation of the sunscreen products of the invention can release vitamin D3 by rupture under pressure, with time passing, by reaction with chemicals contained in the human body, or by any other effect.

Uma quantidade adequada de vitamina D3 contida nos produtos de proteção solar da invenção, sem excluir qualquer outra, é aquela que permite administrar de 0,1 a 1000 Ul/cm2 de pele (Ul= Unidades Internacionais). An adequate amount of vitamin D3 contained in the sunscreen products of the invention, without excluding any other, is that which allows 0.1 to 1000 IU / cm 2 of skin to be administered (IU = International Units).

Produtos de proteção solar da invenção são conhecidos per se, podendo conter um ou mais componentes dentre agentes ativos de naturezas variadas, tensoativos, emolientes, condicionadores de pele, estabilizantes, antioxidantes, umectantes, agentes de tamponamento, espessantes, preservantes, agentes quelantes, emulsificantes, corantes, etc.  Sunscreen products of the invention are known per se and may contain one or more components of various active agents, surfactants, emollients, skin conditioners, stabilizers, antioxidants, humectants, buffering agents, thickeners, preservatives, chelating agents, emulsifiers , dyes, etc.

Dentro de uma alternativa particular da invenção, produtos de proteção solar são composições cosméticas. Ditas composições e formas de prepará-las são conhecidas na técnica, exemplificadas na publicação "Sunscreens: Development: Evaluation, and Regulatory Aspects", Lowe, N. J. et al., Mareei Dekker, 2- edição, 1997.  Within a particular alternative of the invention, sunscreen products are cosmetic compositions. Such compositions and ways of preparing them are known in the art, exemplified in the publication "Sunscreens: Development: Evaluation, and Regulatory Aspects", Lowe, N.J. et al., Mareei Dekker, 2nd edition, 1997.

Dentro de outro aspecto, a invenção refere-se ao processo de aplicação do produto de proteção solar à pele, caracterizada por colocar uma quantidade eficaz do dito produto em contato com a pele. Entende-se por quantidade eficaz aquela que permite que se obtenham os efeitos de proteção solar e de administração de vitamina D3. Entende-se por "colocar... dito produto em contato com a pele", qualquer forma adequada à finalidade, por exemplo, com uso de aplicadores, por exemplo, aplicadores de spray, escovas, esponjas ou similares, ou com as próprias mãos, vertendo produto e espalhando-o sobre a pele com atividade de esfregar ou massagear. De forma particular, sem excluir qualquer outra, uma quantidade eficaz da composição para a finalidade é aplicar à pele quantidades entre 1 mg/cm2 e 3 mg/cm2. In another aspect, the invention relates to the process of applying the sunscreen product to the skin, characterized by bringing an effective amount of said product into contact with the skin. An effective amount is that which enables the effects of sunscreen and vitamin D3 administration to be achieved. "Putting ... this product in contact with the skin" means any form suitable for the purpose, for example using applicators, for example spray applicators, brushes, sponges or the like, or with one's own hands. by pouring product and spreading it on the skin with rubbing or massaging activity. Particularly, without excluding any other, an effective amount of the purpose composition is to apply to the skin amounts between 1 mg / cm 2 and 3 mg / cm 2 .

A parte do corpo à qual se aplica o produto de proteção solar da invenção pode ser qualquer, dependendo da finalidade. Quanto maior a área de pele sobre a qual se aplica produto, maior a probabilidade de admin istrar vitamina D3 ao corpo. The part of the body to which the sun protection product of the The invention may be any depending on the purpose. The larger the area of skin to which the product is applied, the more likely it is to administer vitamin D3 to the body.

Com as informações aqui fornecidas, pode o homem da técnica realizar a invenção de formas diferentes, com função idêntica ou similar, com função idêntica ou similar àquelas descritas, sem no entanto fugir do escopo das reivindicações apresentadas a seguir.  With the information provided herein, the person skilled in the art may carry out the invention in different ways having identical or similar function, having identical or similar function to those described, without, however, departing from the scope of the claims set forth below.

Claims

REIVINDICAÇÕES 1 . Produto de proteção solar caracterizado pelo fato de compreender ao menos um agente de proteção solar, vitamina D3 sob forma de nanopartícula e ao menos um veículo para aplicação tópica.  1 . Sunscreen product comprising at least one sunscreen agent, vitamin D3 in nanoparticle form and at least one vehicle for topical application. 2. Produto de proteção solar de acordo com a reivindicação 1 caracterizado pelo fato de que a dita vitamina D3 é uma ou mais dentre entre colecalciferol, precursores e metabólitos da vitamina D3.  Sun protection product according to claim 1, characterized in that said vitamin D3 is one or more of cholecalciferol, precursors and metabolites of vitamin D3. 3. Produto de proteção solar de acordo com a reivindicação 1 caracterizado pelo fato de que nanopartículas são partículas coloidais sólidas de tamanhos entre 10 a 1000 nanometros, nas quais a vitamina D3 pode ser dissolvida, capturada, encapsulada, ou às quais está quimicamente ligada ou adsorvida em uma matriz polimérica.  Sunscreen according to claim 1, characterized in that nanoparticles are solid colloidal particles of size 10 to 1000 nanometers, in which vitamin D3 can be dissolved, captured, encapsulated, or chemically bonded or adsorbed on a polymer matrix. 4. Produto de proteção solar de acordo com a reivindicação 3 caracterizado pelo fato de que ditas partículas coloidais liberam vitamina D3 a elas associada por ruptura sob pressão, com passagem do tempo ou por reação com compostos químicos contidos no organismo humano.  Sunscreen according to Claim 3, characterized in that said colloidal particles release vitamin D3 associated with them by rupture under pressure, passing of time or by reaction with chemical compounds contained in the human organism. 5. Produto de proteção solar de acordo com a reivindicação 1 caracterizado pelo estar sob forma de emulsão água em óleo, emulsão óleo em água, unguento, pomada, creme, gel ou spray.  Sun protection product according to Claim 1, characterized in that it is in the form of a water-in-oil emulsion, oil-in-water emulsion, ointment, ointment, cream, gel or spray. 6. Produto de proteção solar de acordo com a reivindicação 1 caracterizado pelo fato de conter vitamina D3 em quantidade suficiente para administrar 0,1 a 1000 Ul/cm2 de pele. Sun protection product according to claim 1, characterized in that it contains sufficient vitamin D3 to deliver 0.1 to 1000 IU / cm 2 of skin. 7. Processo de aplicação de produto de proteção solar à pele de acordo com uma qualquer das reivindicações 1 a 6, caracterizado por colocar uma quantidade eficaz do dito produto em contato com a pele.  Method of applying sunscreen product to the skin according to any one of claims 1 to 6, characterized in that an effective amount of said product is contacted with the skin.
PCT/BR2017/050053 2016-03-15 2017-03-10 Sunscreen product and method for applying a sunscreen product to the skin Ceased WO2017156608A1 (en)

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