WO2017140243A1 - Multi-stage treatmetn method and device for biomedical wastes and recycling method of treated wastes - Google Patents

Abstract

A multi-stage treatment method and device for biomedical wastes and a recycling method of the treated wastes. The multi-stage treatment method comprises the following steps: (1) carrying out the first stage of disinfection treatment on biomedical wastes using a hyperoxide disinfectant with concentration of 0.1-0.5% while comminuting the biomedical wastes; (2) carrying out the second stage of disinfection treatment on the biomedical wastes having residual hyperoxide disinfectant after the first stage of disinfection treatment, wherein the second stage of disinfection treatment refers to steam sterilizing heat treatment or disinfection using a high-concentration hyperoxide disinfectant with concentration of 5-20%. The method has the advantages of good sterilizing effect and short sterilizing time; the recycled product can be applied to decoration, isolation, building materials, containers and can be used as an alternative of cement.

Description

Multi-stage processing method and equipment for biomedical waste and recycling method after treatment Technical field

The invention belongs to the field of biological/medical waste treatment and recycling, and particularly relates to a multi-stage processing method and equipment for biomedical waste and a recycling method after treatment.

Background technique

Biomedical waste (BMW) consists of solids, liquids, sharps, and laboratory waste. They are potentially infectious and dangerous, such as bacteria, viruses, and other microorganisms. Biomedical waste must be properly disposed of to protect public health and to protect groups of medical and health workers who need frequent exposure to biomedical waste for work reasons.

Biomedical waste is one of the most difficult to treat in heterogeneous waste because it contains pathogenic microorganisms, is mixed with a wide variety of materials, and is not allowed to be sorted by law. Handling non-homogeneous waste without sorting is a difficult, costly and long-standing issue.

Biomedical waste must be sterilized prior to any recycling. Special equipment is required to achieve the required microbial killing effects, such as various bacteria, viruses, fungi and bacterial spores. However, for recycling purposes, all waste needs to be thoroughly sterilized before being exposed to the environment and to the population. In addition, in order to meet the regulatory requirements for the treatment of biomedical waste into an “unrecognizable” state, and to expose the waste to the thermal and chemical disinfection media as fully as possible, it is necessary to pulverize the biological waste in advance. For recycling, this process is very important because people are afraid of products made from recycled materials from medical waste. In order to protect the public and health care workers, health workers and other people who are frequently exposed to the occupational hazards of biomedical waste, BMW must be properly managed.

The State Regulatory Oversight of Medical Waste Treatment Technologies, developed by the National and Regional Alternative Treatment Technology Association (STAATT), is used by most of the world's regulatory agencies, which stipulates limited medical care. The microbial killing efficiency of waste. STAATT-III takes into account the limitations of available biomedical waste disinfection techniques and specifies that the killing efficiency for viruses, bacteria and fungal spores is divided into six orders of magnitude. However, more and more countries have turned the disinfection standard for medical waste into “complete disinfection”, which is not possible with the treatment technology of existing chemical disinfectants, mainly due to the existing chemical disinfection technology. Basic restrictions.

The biomedical waste treatment methods currently used are mainly divided into three categories: incineration, thermal disinfection and chemical disinfection. The incineration method treats biomedical waste directly through high-temperature incineration. This method is more thorough, but it produces toxic gases such as dioxins, which pollutes the air and the environment, and consumes more energy. Common thermal disinfection techniques generally It is steam sterilization, that is, steam is introduced under high pressure to heat the waste to 121-140 ° C; steam sterilization is a simple and effective method to treat biological waste, but it consumes a lot of energy and disinfects the enclosed space in the garbage. It may not be effective, and there are significant limitations to crushing the trash after heating; in addition, steam sterilization usually produces an unpleasant odor. Other thermal disinfection techniques include dry heat sterilization, which also produces toxic gases such as dioxins and high energy consumption. In summary, these techniques are not particularly satisfactory, as these methods generally leave a pungent odor, blood, bacterial growth media, and even body tissue. Residues of these organic components can cause the re-growth of pathogenic microorganisms after treatment, and the waste will become unstable during recycling and reuse. The organic components will continue to degrade.

In general, the use of chemical disinfection technology to treat biomedical waste is rare, mainly because of the limited effectiveness of chemical disinfection, the potential toxicity of disinfectant, the possibility of emitting toxic gases, and the potential for water when draining used disinfectant. It is necessary to carry out effective pulverization before the disinfection and disinfection to make the waste and the disinfectant fully contact. Conventional conventional chemical disinfectants usually include hypochlorous acid, glutaraldehyde, quaternary amines and hydrogen peroxide. Hypochlorous acid is not commonly used because disinfection with hypochlorous acid requires higher concentrations and longer disinfection times, as well as toxic chlorine in the sterilization process. Glutaraldehyde is used as a chemostat culture rather than a disinfectant; the disinfection effect of quaternary amines does not meet regulatory requirements. Disinfectants using quaternary amines combined with glutaraldehyde, such as SteriCid and ViroCid, provide only 2-3 orders of magnitude of bacterial disinfection efficiency and do not meet STAATT requirements, which is considered an international standard for disinfection efficiency. . In addition, volatile vapors of glutaraldehyde and hypochlorous acid are toxic, and carcinogens are easily formed when reacted with oxygen.

The low concentration of hydrogen peroxide solution is very low in disinfection efficiency and can only provide 3-4 orders of magnitude disinfection. The method of reacting hydrogen peroxide with acetic acid with or without a catalyst to increase the disinfecting effect of hydrogen peroxide has been intensively studied and even patented. When hydrogen peroxide is reacted with acetic acid and sulfuric acid is used as an activator, the active substance peracetic acid is formed, which is the disinfecting products Kickstart and Kenocid produced by the Belgian company CidLines, which contain peracetic acid, hydrogen peroxide and acetic acid, and may also contain other A component such as sulfuric acid is added as a catalyst for producing peracetic acid. The disinfection efficiency reported by Cidlines is 2% disinfectant, which can achieve 5 orders of magnitude disinfection efficiency for various bacteria and 2-4 orders of magnitude for fungi and spores. Disinfection efficiency does not meet the STAATT standard. In 2008, China Engineering Journal published an article on the use of sulfuric acid to promote the reaction of hydrogen peroxide with acetic acid to form peracetic acid, entitled "Experiment and Modeling of Peracetic Acid with Hydrogen Peroxide and Acetic Acid" (Zhao Xuebing, Zhang Ting, Zhou Yujie) , Andy Lau. "Preparation of Peracetic Acid from Acetic Acid and Hydrogen Peroxide: Exploration and Modeling." Chinese Journal of Process Engineering, February 2008, Vol. 8, No. 1, pp. 35-41, which clearly indicates the temperature for enhancement The effect of peracetic acid disinfection. In addition, higher temperatures promote the decomposition of hydrogen peroxide into water and oxygen, which may form ozone when exposed to air at elevated temperatures. This is an unstable but potent disinfectant that is sterilized in biomedical waste. The application has been registered (US5087419) and has been produced and sold (Qzonator NG-3000, Ozonator Industries Ltd.). The formation of ozone is very advantageous and safe for sterilization, because it degrades when it encounters steam, and thus it is strongly disinfected in the high-pressure steam sterilization process while degrading itself into harmless oxygen, so it is not discharged at the end of disinfection. Two Chinese patents, CN 101828551 and CN 103704264, disclose the preparation of peracetic acid by the use of hydrogen peroxide and acetic acid under the catalysis of sulfuric acid, and also disclose the use of hydrogen peroxide-acetic acid-sulfuric acid solution to mix detergents and surface active agents. Method of the agent. These patents disclose the use of low concentrations of the above solutions for use in home, hospital and industry, but do not mention the use of such solutions for the disinfection of medical waste. Moreover, the 2015 results of the Anhalt University of Applied Sciences show that hydrogen peroxide is synergistically disinfected with glutaraldehyde and/or quaternary ammonium compounds, but it significantly affects the disinfectant within 24 hours. Stability, mainly due to the reaction of hydrogen peroxide with other components.

Disinfection with high concentrations of disinfectant has never been patented because of the high cost of the disinfectant and environmental impact. Due to the chemical nature of hydrogen peroxide, the use of high concentrations of hydrogen peroxide in open systems is dangerous. High concentrations of hydrogen peroxide react with detergents and surfactants. Disinfection with high concentrations of peroxides while pulverizing is not possible. Yes, and these substances are necessary in the disinfection process, and the regulations stipulate that biomedical devices must be comminuted while disinfecting, and can not be pulverized and then sterilized.

The recycling of biomedical waste after sterilization and disinfection is an issue of great concern from an environmental point of view. Medical waste is often infectious, and the main mode now is long-term degradation in landfills after sterilization. Despite medical disuse Many parts of the material are recyclable, but these substances are not recycled because they are contaminated by sources of infection and by concerns about contamination of medical waste. This has resulted in the waste of billions of dollars worth of material that could have been recycled and the use of valuable landfill space.

The recycling of biomedical waste after treatment has attracted wide interest in environmental protection and profit creation. The recycling process can be used for biomedical waste and may later be extended to various heterogeneous wastes such as domestic/municipal waste.

Waste is divided into sortable waste and non-sortable waste. The prior art has complicated recycling operations for sortable waste, and there is no effective way to recycle non-sortable waste. .

Summary of the invention

In order to overcome the shortcomings and deficiencies of the prior art, the primary object of the present invention is to provide a multi-stage processing method for biomedical waste, which has reasonable process steps, convenient operation and good synergistic effect.

Another object of the present invention is to provide an apparatus for implementing the above-described multi-stage processing method of biomedical waste.

It is still another object of the present invention to provide a method for recycling biomedical waste treated by the above method.

The object of the present invention is achieved by the following technical solution: a multi-stage processing method for biomedical waste, comprising the following steps:

(1) While pulverizing the biological medical waste, the first-stage disinfection treatment of the biological medical waste is carried out by using a general concentration of the peroxide disinfectant; the mass concentration of the general concentration peroxide disinfectant is 0.1-0.5%;

(2) performing the second-stage disinfection treatment on the garbage disposal material with the remaining peroxide disinfectant after the first-stage disinfection treatment, and the second-stage disinfection treatment is steam sterilization heat treatment or high concentration peroxidation Disinfection; the high-concentration peroxide disinfection is carried out by using a high-concentration peroxide disinfectant with a mass concentration of 5%-20%.

The second stage of disinfection is performed for a short period of 3 to 10 minutes in a mixed reactor containing a high concentration of peroxide disinfectant or in a high pressure steam sterilizer.

The general concentration peroxide disinfectant and the high concentration peroxide disinfectant are all based on hydrogen peroxide, and the disinfectant prepared by mixing the activator and the stabilizer in advance, and then mixed with the preparation, Before use, the disinfectant is configured as a mother liquor to a different concentration and then contacted with the biomedical waste to be treated for disinfection.

The disinfectant is prepared from the following raw materials: 50% by mass of hydrogen peroxide, 1-5% by mass of activator, 2-10% by mass of stabilizer, mass fraction 0.5-2% The formulation, the rest is water.

The stabilizer comprises acetic acid and peracetic acid.

The activator is any chemical or substance capable of enriching the disinfectant with a peracetic acid compound having the highest activity, and includes at least one of sulfuric acid, anhydrous acetic acid, and iron powder.

The formulation is one or more of an anionic detergent, a nonionic detergent, and a cationic detergent.

The formulation comprises one or more of the following quaternary ammonium compounds: alkyl dimethyl benzyl ammonium chloride, octyl-mercapto-dimethyl ammonium chloride, octyl-decyl-dimethyl ammonium bromide Di-decyl-dimethylammonium chloride and dinonyl-dimethylammonium bromide.

The formulation further contains one or more of the following components: a silicone-free lubricating oil, an isopropanol, and an emulsifier; the emulsifier is preferably a mineral oil; the mineral oil comprises the following components: polysorbate and / or oleic acid polyethylene glycol glyceride.

The steam sterilization heat treatment in the step (2) is to perform high-temperature steam on the garbage disposal material after the first-stage disinfection treatment and the disinfectant liquid remaining on the garbage disposal material at 120 to 150 ° C; in the process, the disinfectant liquid The peroxide disinfecting substance is enhanced by the heating activity, resulting in a more thorough disinfecting effect.

The high concentration peroxide disinfection in the step (ii) is carried out in a mixing reactor in which a high concentration peroxide disinfectant is used for disinfection and agitation is used to force the chemical to be thoroughly mixed with the waste treatment so that The pulverized waste treatment is fully exposed to the disinfectant and achieves final disinfection within 3 to 10 minutes.

The general concentration peroxide disinfectant and the high concentration peroxide disinfectant contain viscous polysaccharides, and the effective disinfecting components are adhered to the pulverized waste particles, and the waste particles are bonded together to form a polymer. It does not separate during transport while maintaining a continuous disinfecting effect.

After the second stage of disinfection treatment as described in step (2), the resulting sterile waste treatment is separated from the disinfectant, and the separated disinfectant is reused.

After the second stage of the disinfection treatment described in the step (2), the obtained aseptic waste treatment is separated from the disinfectant, and the separated garbage treatment is compressed by an extruder and the residual disinfectant is retained therein. Extrusion is repeated. The separated garbage treatment can be used for subsequent recycling.

An apparatus for implementing the multi-stage processing method of the above biomedical waste, comprising: one or more of the following devices:

a reaction chamber for receiving garbage, equipped with a lid to prevent the leakage of microorganisms;

Drug dispenser

Pulverizer, with or without filter;

Reaction cell

Enhanced sterilizer, including a high pressure steam sterilizer or a mixing reactor;

The reaction chamber is provided with a medicament dispenser, a pulverizer and a reaction tank for pulverizing and disinfecting the biomedical waste; the medicament dispenser is connected to the reaction tank, and the pulverizer is disposed in the reaction tank; the sterilizer is The reaction tanks are connected, and the treatment materials which have been subjected to the disinfection treatment of the general concentration of the peroxide disinfectant in the reaction tank are subjected to steam sterilization heat treatment or disinfected by using a high concentration peroxide disinfectant.

The above equipment is also equipped with a controller to control the relevant devices:

(1) Controlling the feeder of the reaction chamber to control the garbage entering the reaction chamber;

(2) Control the pulverizer to control the crushing of garbage;

(3) manipulating the medicament dispenser to control the dispensing of the corresponding medicament on the garbage;

(4) Control the enhanced sterilizer, control the corresponding device to perform steam sterilization heat treatment on the treated object and/or use high concentration peroxide disinfection treatment.

The above apparatus further includes a solid-liquid separator for separating the treated garbage and the disinfectant, and recycling and recycling the disinfectant. Correspondingly, the controller controls the solid-liquid separator to control the separated garbage and the disinfectant. The solid-liquid separator comprises a first-stage solid-liquid separator and a second-stage solid-liquid separator, wherein the first-stage solid-liquid separator is used for taking the crushed garbage after the first-stage disinfection treatment and sending it to the second stage of disinfection. The second-stage solid-liquid separator is used to separate the treated waste and send it to the extruder, and the separated disinfectant can be recycled and reused to reduce the consumption of chemicals and water, and to eliminate waste water. emission.

The apparatus may further include an extruder coupled to the extruder for compressing the treated waste, extruding the disinfectant and minimizing the volume of the treated waste.

The above device also includes an online analyzer for tracking the success of the sterilization process. Correspondingly, the controller controls the online analyzer to control the operation of the corresponding device through feedback from the online analyzer. The online analyzer contains electrically connected detectors and filters; the detector is used to automatically sample the disinfected liquid at the end of the sterilization process and measure its aerobic level, and Provides readings and documentation of disinfection effects based on pre-determined oxygen demand thresholds; filters are used to collect bacteria from the disinfectant for analysis of bacterial survival after disinfection; cleaning from filter residue to remove residual chemical disinfection Peroxide disinfectant, the residual particles on the filter net into the suspension, and mixed into the medium, and then use the oxygen electrode or any other method to analyze the oxygen content of the suspension for oxygen consumption analysis; due to controller and online analysis Connected, if the online analyzer feedback oxygen consumption exceeds the threshold, the controller will control to stop the operation of the entire device.

In the above apparatus, for the mixing reactor, the controller can adjust the concentration of the high concentration peroxide disinfectant according to the physical and chemical signals fed back from the sensors installed in the mixing reactor; and coordinate the mixing reaction The operation of the pulverizer and the pulverizer evacuates the material in the mixing reactor to the solid-liquid separator to separate the sterilizing liquid from the pulverized solid residue that has been sterilized.

In the above apparatus, for the high-pressure steam sterilizer, the first-stage sterilized garbage disposal material and the disinfectant liquid remaining on the garbage disposal material are steam-sterilized together, thereby combining the peroxide sterilization and steam sterilization processes. .

The medicament dispenser comprises: a first dispenser connected to a container containing hydrogen peroxide, a stabilizer and an activator; a second dispenser connected to the container containing the formulation, the controller being operable to provide the first dispenser Hydrogen peroxide and manipulation of the second dispenser provides the formulation.

A method for recycling processed biomedical waste includes the following steps:

(1) removing organic components in the heterogeneous solid waste by degradation or washing;

(2) pulverizing the waste;

(3) washing the waste to remove any remaining active chemical, acid, alkali, disinfectant or detergent;

(4) adding more than one fibrous substance to the waste;

(5) adding more than one type of stickies to the waste;

(6) adding more than one hydrophilic polymer to the waste;

(7) adding more than one hydrophobic polymer to the waste;

(8) further grinding to obtain a waste mixture;

(9) Pour the waste mixture into the mold, let it stand for stability and then make the final drying and curing;

The heterogeneous solid waste in the step (1) is the above-mentioned separated garbage disposal product (that is, after the second-stage sterilization treatment described in the step (2), the obtained aseptic garbage disposal material is removed from the disinfectant liquid. Separated and separated from the garbage disposal).

The step (1) further includes disinfecting the waste.

The method of disinfection is a chemical disinfection method.

The method of sterilization is heat sterilization.

The organic matter degrading agent used for the degradation in the step (1) and the disinfectant used in the disinfection are the same chemical substance.

The process of degradation and disinfection described in step (1) is completed simultaneously at the same stage.

The degradation and disinfection described in the step (1), and the pulverization process in the step (2) are simultaneously performed at the same stage.

The step (2) further includes the step of subjecting the pulverized waste to a heat sterilization treatment.

The disinfectant used in the chemical sterilization method is selected from the following materials and is still active during the washing as described in the step (3): a cationic detergent, a nonionic detergent, and an anionic detergent.

The disinfectant used in the chemical disinfection method is more than one of organic degradation agents, including hypochlorous acid, hydrogen peroxide, sulfuric acid, sodium hydroxide, or any other acid or alkali that chemically degrades or rinses organic components. .

The heterogeneous solid waste is pulverized into small particles having a particle size of less than 5 cm to ensure all surfaces of the waste and the disinfectant Can be fully contacted.

The sterilization process is carried out in a mixing reactor.

The fibrous material in the step (4) is a natural fiber derived from plants and/or mammals, and/or a synthetic fiber, including one of cellulose, wool, lignin, flax, synthetic fiber, glass fiber and mineral wool. More than one species.

The glue of the step (5) is a polysaccharide, a resin, a silica gel or the like.

The hydrophilic polymer in the step (6) is water-soluble, and during the final drying and curing as described in the step (9), polymerization occurs due to loss of moisture in the mixture over time; the hydrophilicity The polymer is preferably polyacrylic acid, polyethylene glycol or polyamine.

The hydrophobic polymer in the step (7) is a polymer dissolved in an organic solvent, and is polymerized and solidified as the organic solvent is volatilized during the final drying and curing as described in the step (9); the hydrophobic polymerization The material is preferably polyethylene, polypropylene, polystyrene or hydrophobic polyacrylate.

The hydrophilic polymer and the hydrophobic polymer undergo physical or chemical separation over time.

The hydrophobic polymer provides a waterproof layer for products made from heterogeneous solid waste recycling materials.

A flame retardant compound is added to the non-homogeneous solid waste recycling material to prevent the product from burning in case of fire.

The grinding in the step (8) is to grind the waste into particles having an average particle diameter of less than 5 mm.

The washing in the step (3) is washing with water or detergent.

The solution used in the washing in the step (3) is subjected to solid-liquid separation after use and the washed residue is removed by catalytic oxidation or other methods to purify the water therein.

When the fibrous material is a fiber from recycled paper, the paper fibers are dissolved in water prior to addition to the solid waste mixture.

The drying and curing described in the step (9) are at normal temperature or under heating.

The heterogeneous solid waste recovery material is stored in a sealed container for use.

Non-homogeneous solid waste recycling materials are made into insulation and sound insulation products.

Heterogeneous solid waste recycling materials are made into building materials, walls, wall coverings, containers, floors and other panels, as well as cement substitutes.

The principle of action of the present invention is that the present invention discloses a method and apparatus for treating biological waste (BMW). The method and apparatus can perform the combination and sequential disinfection of several methods of crushing, peroxide disinfecting and heat disinfecting of BMW. Mixing of different types of disinfectants produces synergistic effects, while sequential disinfection processes achieve up to 100% sterilization. BMW will be comminuted and peroxide sterilized after entering the unit. Peroxide disinfection is a disinfectant mixture that is a disinfectant solution that has anti-virus properties and does not produce harmful gases and water pollution. For example, hydrogen peroxide can be chemically decomposed into oxygen and water, or react with organic matter to form carbon dioxide and water. , or ozone is produced in a steam boiler and reacts with steam to regenerate hydrogen peroxide. Due to the chemical nature of the solution, the peroxide-sterilized BMW can be further sterilized by thermal disinfection, such as steam sterilization (autoclaving). The autoclave can be used as an integral part of the equipment or as a separate unit. The combination of chemical disinfection methods and thermal disinfection methods has not been applied to date because the disinfectant used is unstable under heating conditions, forming chlorine, bromine and its oxides, and other disinfecting components such as glutaraldehyde may Oxidation to carcinogens or gasification, becoming an inhalable toxic gas.

Hydrogen peroxide disinfectant is widely used in the medical industry for its safety. However, its disinfection efficiency is relatively low, requiring high concentration and long time. However, hydrogen peroxide reacts with acetic acid to form peracetic acid, which is a very effective disinfectant. The reaction of hydrogen peroxide with acetic acid to form peracetic acid is chemically balanced, and a small amount of peracetic acid can be produced under standard conditions. Add catalysts such as sulfuric acid and anhydrous B Acid, it will effectively accelerate the production of peracetic acid, thus enhancing the disinfection effect. Therefore, the disinfectant using hydrogen peroxide, acetic acid, peracetic acid and catalyst components is finally adopted, which is mainly considered to be environmentally friendly, stable and non-toxic after heating, can be effectively disinfected under the action of a catalyst, and can be quickly prepared. However, since such a disinfectant has a large surface tension, in order to achieve a good disinfecting effect, it is necessary to add a surfactant and apply pulverization and pressurization as needed. Activated hydrogen peroxide (ie, hydrogen peroxide reacts with acetic acid under the action of a catalyst to form peracetic acid) as a disinfecting solution, combined with pulverizing, mixing, and disinfecting steam that can penetrate into the interior of biomedical waste under high temperature and high pressure, is effective and Environmentally friendly medical bio-waste treatment technology.

The combination of the three functions of pulverization, peroxide sterilization and heat sterilization is compared with the treatment method combining one of pulverization and peroxide sterilization or heat sterilization, and the three-function treatment is combined. The technology has a synergistic and enhanced disinfection effect. The peroxide disinfection first reduces the microbial survival, the steam disinfection simultaneously enhances the active substance in the disinfectant, and completes the complete killing of the microorganism in the second stage.

In addition, the same sterilization effect can be achieved by using a sterilizing method of pulverization, general concentration of peroxygen sterilization, and a mixed reactor equipped with a high concentration of peroxide disinfectant, as compared with heat sterilization.

The present invention has the following advantages and effects over the prior art:

First, the disinfection and sterilization effect is good; the method and equipment for the treatment of biomedical waste, has a very good sterilization and disinfection effect, the specific performance has the following aspects:

1. A method of combining pulverization with a general concentration of a peroxide disinfectant, and a combination of heat sterilization and high-concentration disinfectant disinfection, in combination with pulverization and peroxide sterilization or pulverization and heat sterilization. Compared with a treatment method, the multi-functional treatment technology has the synergistic effect of strengthening disinfection. The first stage of peroxide disinfection first reduces the microbial survival, and the steam disinfection or high-concentration disinfectant disinfection simultaneously enhances the disinfectant. The active substance in the second stage completes the complete killing of the microorganisms; thus the disinfection effect is very good, and it can fully meet the disinfection efficiency of 6 orders of magnitude developed by the National and Regional Alternative Treatment Technology Association (STAATT).

2, using this program for disinfection, the second stage of high-concentration peroxide disinfection process takes only 3-10 minutes. Moreover, the second-stage high-concentration disinfection is also a continuation of the first-stage disinfection, so the first-stage time is flexibly controlled according to the time required for the crushing process. In this way, the two-stage overall disinfection process can still be controlled within 5-10 minutes. Other existing technologies generally require more than 30 minutes for the same disinfection effect. Therefore, in comparison, the use of this scheme can greatly save operating time, fully improve processing efficiency, significantly promote production volume, and has very good economic benefits.

3. The present invention first pulverizes in a low concentration peroxide disinfectant, and then uses a high concentration disinfectant in the mixing reactor for enhanced treatment, thereby achieving a higher speed and more efficient processing result than the existing treatment method. The method can effectively shorten the disinfection time, the consumption of the disinfectant is small, and there is no sewage discharge; the method enables the surfactant and the detergent to act on the waste before being disinfected with high concentration hydrogen peroxide, and at the same time obtains the required The anti-virus effect overcomes the problem that only a high concentration of hydrogen peroxide reacts with detergents and surfactants, and it is not feasible and dangerous to use high concentration peroxide disinfection while pulverizing.

Second, it has better environmental protection effect; the method and equipment of the invention are more in line with environmental protection requirements, and the specific performance is as follows:

1. The invention mainly uses hydrogen peroxide as a main component for disinfection, hydrogen peroxide can be decomposed into water and oxygen, and ozone may be generated when it is in contact with air at a high temperature, and ozone formation is very favorable and safe for sterilization. Because it will degrade when it encounters steam; therefore, this technology does not produce substances that have obvious pollution to the environment, and has no adverse effect on air and water resources, completely avoiding the existing sterilization and disinfection methods often produce toxic and harmful The problem of material pollution of the environment, and thus the solution of the invention is relatively friendly to the environment, and is very environmentally friendly.

2. The invention can also recycle and recycle the disinfectant, and can fully utilize the disinfectant while reducing emissions, save raw material resources, reduce material loss, save energy and reduce consumption, and also have good environmental protection effects.

Third, the degree of intelligence is high; the program uses the controller to control the related devices, and uses the online analyzer to monitor the relevant parameters in the device and the relevant concentration of the disinfectant, which can achieve intelligent control with high degree of automation. It is beneficial to reduce the labor intensity of the operator, improve production efficiency, promote production quality, and ensure the stability and safety of the operation effect.

4. The device of the invention has various forms, adopts modular structure, is easy to assemble and install, and can be flexibly selected according to different production conditions, and can meet the production requirements of different occasions.

5. The recycling process of the present invention has the following advantages:

1. The recycling method of the present invention uses a solution capable of rapidly reacting with an organic substance and simultaneously disinfecting the waste to erode the waste to degrade or wash away the organic components in the waste; thereafter, the reaction solution is removed from the solid Separated and reused to reduce environmental pollution. The solids from which the organics have been removed are further comminuted and then finally sterilized and recycled. The method realizes recycling and recycling non-homogeneous solid waste without sorting, and has wide application range, simple and effective, and high efficiency, saving manpower and material resources.

2. The purpose of adding fibrous substances is to physically bond the pulverized waste particles together; the purpose of adding the adhesive is to further enhance the adhesion of the waste particles; the purpose of adding the hydrophilic polymer is to make the waste The particles and other water-soluble additives polymerize to better bond; the purpose of adding the hydrophobic polymer is to stabilize the mixture in water and provide a waterproof layer for products made from heterogeneous solid waste recycling materials.

3. The recycling method can also be applied to the recycling of ordinary sanitation solid waste.

DRAWINGS

Figure 1A is a schematic view showing the structure of the apparatus of the present invention.

Figure 1B is a conceptual diagram of the medicament dispenser of the apparatus of Figure 1A.

Figure 1C is a schematic view showing the structure of the sterilization reaction chamber of the apparatus shown in Figure 1A.

FIG. 1D is a schematic structural view of the medicament dispenser shown in FIG. 1B.

Fig. 1E is a conceptual diagram of the pulverizer shown in Fig. 1A.

Fig. 1F is a schematic view showing the structure of the high pressure steam sterilizer shown in Fig. 1A.

2 is a conceptual illustration (according to an embodiment) of a bio-waste processor incorporating a high pressure steam sterilizer, a mixing reactor, and a pulverizer.

Figure 3A is a conceptual illustration (according to an embodiment) of a method for assessing disinfection efficiency based on the oxygen demand of viable bacteria.

Fig. 3B is a schematic view showing the structure of the apparatus for evaluating the disinfection efficiency according to the oxygen demand of the viable bacteria shown in Fig. 3A.

FIG. 3C is an operational flowchart of the method of evaluating sterilization efficiency according to FIGS. 3A and 3B.

4 is a flow chart showing the operation of the method of processing biological waste according to FIGS. 1 and 3.

Fig. 5A is a schematic structural view of a main part of a biomedical waste disposal system according to an embodiment of a biological waste disposal apparatus.

Figure 5B is a flow chart showing the operation of the system of Figure 5A for processing biomedical waste.

Figure 6a shows a hydrogen peroxide disinfectant with a mass concentration of 0.5% mixed with different kinds of chemicals (including two quaternary amines Galsept50 and Septol, and a mixture of glutaraldehyde and quaternary amines SterCid). Efficiency impact map; The data is based on samples collected after 1 hour and 24 hours after mixing the organic disinfecting product with hydrogen peroxide.

Figure 6b is a data plot of various disinfectants and their disinfection levels, including quaternary ammonium (QA) commercial products, high temperature steam sterilizers (using 121 ° C or 135 ° C), mass concentrations of 0.5% and 5% activation Hydrogen peroxide (AHPO), sterilization efficiency was determined by analysis of the survival rate of B. subtilis spores.

Figure 7 is a diagram illustrating the process of treating heterogeneous solid waste in accordance with an application example of the present invention.

Figure 7a is a diagram showing the solid-liquid separation process after degrading organic components in a solid waste mixture.

Figure 8 is a chart of recycled product composition, wherein 1 is a hydrophobic layer, 2 is a hydrophilic polymer, 3 is a fibrous material, and 4 is a waste particle.

Figure 9 is a cross-sectional view of a recycled product showing a waterproof layer of recycled material according to an application example of the present invention; wherein 1 is a fibrous material, 2 is a hydrophobic layer, 3 is air, and 4 is waste particles. .

Figure 10 illustrates a tile made of recycled material utilizing the waterproofing technique of the present invention; wherein 1 is a fiber and 2 is a hydrophobic layer.

Figure 11 is a photograph of the tile of Figure 10 after removal of the waterproof layer, with 1 being waste particles and 2 being fibers.

Figure 12 illustrates a barrier layer on a finished product made using the heterogeneous waste recycling material of the present invention; the finished product is produced by coagulation at the treatment site.

Figure 13 shows a picture of a packaging film made using the present invention for recycling non-homogeneous waste technology.

detailed description

The present invention will be further described in detail below with reference to the embodiments and drawings, but the embodiments of the present invention are not limited thereto.

Specific examples are shown by the associated figures. The dimensions and functions of the components shown in the figures are only accurate and convenient, not actual.

1A is a schematic view of the structure of the apparatus of the present invention, including a reaction chamber 100, a controller 110, and an enhanced sterilizer 108. The reaction chamber 100 is used to treat waste to make it suitable for subsequent enhanced sterilization (steam sterilization heat treatment using a high pressure steam sterilizer or high concentration peroxide disinfectant disinfection of a mixed reactor). The reaction chamber 100 is provided with a medicament dispenser 106, a pulverizer 104 and a reaction tank 102 for receiving biomedical waste or biological waste to be treated. The controller 110 can control the pulverizer 104 to pulverize the waste, and can also control the medicament dispenser 106 to dispense disinfectant (including hydrogen peroxide, a stabilizer and an activator, and a formulation) to the waste. Within 6 hours (or 7, 8, 9, 10, 11, 12, 13 hours) after mixing hydrogen peroxide with the formulation, it can be used for the erosion of waste to achieve the purpose of disinfecting the waste. Optionally, the waste is comminuted and peroxide sterilized in the reaction tank 102. The first stage of disinfection treatment in the reaction tank 102, that is, the general concentration of the peroxide disinfectant disinfected pulverized waste ("post-treated garbage") can be carried out by the enhanced sterilizer 108 (including a high pressure steam sterilizer or a mixed reactor). The second stage of disinfection treatment, such as steam sterilization heat treatment using a high pressure steam sterilizer or high concentration peroxide disinfectant disinfection of the mixing reactor. Optionally, the controller 110 can operate the enhanced sterilizer 108 (when the high-pressure steam sterilizer is used), and adds high temperature and high pressure to the first-stage sterilized garbage disposal material and the disinfectant liquid remaining on the garbage disposal product. Thermal disinfection is carried out in high temperature steam containing hydrogen peroxide at ~150 °C. During this process, the peroxide disinfectant in the disinfectant is enhanced by the heating activity, resulting in a more thorough disinfection effect. Optionally, the controller 110 can manipulate the enhanced sterilizer 108 (when mixing the reactor) to further perform high-concentration peroxide disinfection on the first-stage sterilized garbage disposal material and the disinfectant liquid remaining on the garbage disposal material. Disinfecting in a mixed reactor with a high concentration of peroxide disinfectant and using agitation to force the chemical to be thoroughly mixed with the waste treatment to fully expose the pulverized waste treatment to the disinfectant and within 3 to 10 minutes The final disinfection. Each of the above optional combinations corresponds to a separate embodiment of the present invention.

Optionally, the pulverizer 104 can include one or more comminuting components, such as a pre-shredder 104a and a final pulverizer 104b.

Optionally, the autoclave is a stand-alone unit or any of the existing steam sterilizers. Alternatively, a steam sterilization heat treatment process can also be carried out in the reaction cell 102.

Optionally, it is also possible to control only the heating temperature at 90-100 degrees Celsius, since the disinfectant vapor can penetrate better into the interior of the pulverized material at this temperature, and it is obviously also energy-saving when using a lower temperature.

The controller 110 can regulate the operation of any of the components in the reaction chamber 100, such as the medicament dispenser 106, the pulverizer 104, and the like. Additionally or alternatively, the operation of any component can also be controlled by a timer. For example, controller 110 can operate a timer to time the operation of various components in reaction chamber 100. One or more sensors can provide feedback signals to controller 110 to effect control of the various components.

Optionally, the controller 110 can control a barcode scanner to use a container equipped with a barcode. In a non-limiting embodiment, the bar coded container used may be an original barrel of a hydrogen peroxide producer or an original barrel of a formulation manufacturer.

Optionally, the reaction cell 102 can also be divided into multiple sub-bins. In a non-limiting embodiment, the pulverization of the waste can be carried out in the first sub-tank, and the peroxide disinfection of the waste can be carried out in the second sub-tank, also as an option, the steam sterilization heat treatment can be Conducted in three sub-bins.

Optionally, controller 110 manipulates shredder 104 for comminution prior to peroxide sterilization. The comminution can fully expose all surfaces hidden in the waste disinfectant entering the peroxide sterilization process, so that the waste is in full contact with the disinfectant. In a non-limiting embodiment, the pulverized waste consists of particles having a size between 0.5 and 1 inch. In a non-limiting embodiment, the particles are spherical and the measured size is a radius. Optionally, controller 110 can simultaneously control shredder 104 and medicament dispenser 106. Optionally, the controller 110 may first manipulate the medicament dispenser 106 to dispense hydrogen peroxide, a stabilizer, an activator, and a formulation to the waste, and then operate the shredder 104 for comminution. Optionally, the powder medicament dispenser 106 mixes the hydrogen peroxide, the stabilizer, the activator, and the formulation together to form a disinfecting solution and mixes it with the waste. In a non-limiting embodiment, the sterilization process begins when the waste begins to partially comminute and is carried out along with the comminution process. Alternatively, the controller 110 can also operate the shredder 104 to begin operation prior to dispensing the medicament.

The peroxide disinfectant solution used for waste disinfection and its residual parts are not toxic during steam sterilization and can not affect the normal operation of the autoclave.

Optionally, the controller 110 can operate the heater to heat the reaction cell 102 to create suitable temperature conditions (60-100 ° C) for heat sterilization of the waste, so that the disinfectant vapor can better penetrate into the void of the waste, and the temperature The higher the disinfection effect, the better.

Optionally, in the second stage of disinfection treatment using a high concentration of peroxide disinfectant, then the second stage disinfection treatment can also add viscous material to the waste; optionally, in the second stage of disinfection treatment The steam sterilization heat treatment is used, and then the viscous substance is added to the waste after the first stage of the disinfection treatment; the viscous substance is, for example, a glue or a polysaccharide component, and the waste particles are bonded together to make it It is not easy to separate during transportation or landfill.

The general concentration of peroxide disinfectant used in the first stage of disinfection treatment, and the high concentration of peroxide disinfectant used in the second stage of disinfection treatment are based on hydrogen peroxide and pre-mixed with activator and stabilizer. The preparation, and then the disinfectant formed after mixing with the preparation, is disposed in the mother liquor at different concentrations before use, and is then contacted with the biomedical waste to be treated for disinfection. The mass concentration of the general concentration peroxide disinfectant is 0.1-0.5%; the mass concentration of the high concentration peroxide disinfectant is 5%-20%.

In a non-limiting embodiment, the disinfecting solution contains hydrogen peroxide, which is further enhanced at high temperatures. In another unrestricted In a sexual embodiment, the disinfectant is a peroxide to which a stabilizer is added. In another non-limiting embodiment, the disinfectant is prepared from the following ratio of raw materials: 50% by mass of hydrogen peroxide, 1-5% by mass of activator, 2-10% by mass of stabilizer The formulation with a mass fraction of 0.5-2%, the remainder being water. The stabilizer is acetic acid and peracetic acid; the activator is any chemical or substance capable of enriching the disinfectant with the highest activity peracetic acid compound, and contains at least one of sulfuric acid, anhydrous acetic acid and iron powder.

的化学平衡取决于各成分的浓度与反应条件。因此，在合适的条件下添加乙酸和过氧乙酸可使过氧化氢更加稳定，成为本发明方法和设备中使用的消毒液。Generally, hydrogen peroxide and acetic acid can be chemically reacted, and hydrogen peroxide and acetic acid can form peracetic acid and water. chemical reaction

The chemical equilibrium depends on the concentration of each component and the reaction conditions. Thus, the addition of acetic acid and peroxyacetic acid under suitable conditions can make hydrogen peroxide more stable and become the disinfectant used in the method and apparatus of the present invention.

Adding 1-2% by mass of sulfuric acid as an activator for the reaction of hydrogen peroxide with acetic acid (Zhao Xuebing, Zhang Ting, Zhou Yujie, Liu Dehua. "Preparation of Peracetic Acid from Acetic Acid and Hydrogen Peroxide: Exploration and Modeling". Process Engineering Journal, February 2008, Vol. 8, No. 1, pp. 35-41). As an option, 1-2% anhydrous acetic acid may also be added to the mixture as an activator instead of sulfuric acid. As an option, iron powder can also be used as a catalyst and has the same function.

Optionally, the disinfecting effect of hydrogen peroxide can be enhanced by suitable reaction conditions, such as a suitable temperature. In a non-limiting embodiment, a suitable temperature for peroxide sterilization with hydrogen peroxide can be 60-70 degrees Celsius, or 50-150 degrees Celsius. Each of the above cases corresponds to a separate embodiment of the present invention.

Optionally, the disinfecting activity of the peroxide solution can be further enhanced by the addition of one or more formulations. In a non-limiting embodiment, the formulation may be one or more of an anionic detergent, a nonionic detergent, and a cationic detergent. In another non-limiting embodiment, the formulation may contain one or more surfactants having antibacterial activity, such as quaternary ammonium compounds. In another non-limiting embodiment, the formulation may contain one or more of the following chemical constituents: alkyl dimethyl benzyl ammonium chloride (C ₁₇ H ₃ 0ClN), octyl decyl dimethyl chloride Ammonium (C ₂₀ H ₄₄ ClN), octyldecyl dimethylammonium bromide (C ₂₀ H ₄₄ BrN), dimercaptodimethylammonium chloride (C ₂₂ H ₄₈ ClN), and dioctyl dimethyl Ammonium bromide (C ₁₈ H ₄₀ BrN).

In addition, the formulation may also contain materials known in other fields to protect the components of the reaction chamber 100 that are in contact with the hydrogen peroxide solution (such as mechanical components, components of the reaction cell 102 and the pulverizer 104) from hydrogen peroxide corrosion. Or to reduce the coefficient of friction between the parts. Optionally, a lubricating oil, such as a silicone-free lubricating oil, may be added to protect the components of the reaction chamber 100 that are in contact with the hydrogen peroxide. Also, in order to better fuse the lubricating oil and the aqueous disinfecting solution, an alcohol such as isopropyl alcohol and mineral oil may be added. In a non-limiting embodiment, the mineral oil comprises one or more of polysorbate (TWEEN) and oleic acid polyethylene glycol glyceride. As an alternative, more emulsifiers which are capable of promoting the fusion of lubricating oils with aqueous solutions are described in the World Patent No. WO 2003/074027, which is incorporated herein by reference.

In a non-limiting embodiment, the disinfecting solution may comprise hydrogen peroxide as well as stabilizers (including peracetic acid and acetic acid), activators (one of sulfuric acid, anhydrous acetic acid, and iron powder). The formulation may comprise one or more of the following: alkyl dimethyl benzyl ammonium chloride, octyl decyl dimethyl ammonium chloride, octyl decyl dimethyl ammonium bromide, dimercapto dimethyl Ammonium chloride and dimercaptodimethylammonium bromide, and may also contain more than one of the following: silicone-free lubricants, alcohols (such as isopropanol) and mineral oils (such as polysorbates) Oleic acid polyethylene glycol glyceride).

Mixing the disinfectant with the formulation will result in an active disinfectant. Generally, the activity of the disinfectant decays with time, and therefore, the disinfectant has a defined time limit based on the minimum activity requirement for the disinfecting component hydrogen peroxide in the disinfectant. The attenuation of the activity may also occur due to a chemical reaction between the disinfectant and the formulation in a state where it is not mixed with the waste. In a non-limiting embodiment, the activity of the disinfectant is attenuated from 100% to 50% within 24 hours of mixing. Therefore, the disinfectant can be used or reused within 1 hour after mixing. As an option, the disinfectant can be used in an aqueous environment.

Figure 6a shows a hydrogen peroxide disinfectant with a mass concentration of 0.5% and different types of chemicals (including two quaternary amines Galsept50 (a spectral disinfectant containing four quaternary ammonium compounds, no Chinese translation) and Septal (Ubidiacil, also known as chlorhexidine, scientific name chlorhexidine), and a mixture of glutaraldehyde and quaternary amines SterCid mixed with disinfection efficiency; data based on organic disinfection products Samples collected after 1 hour and 24 hours after mixing with hydrogen peroxide. This figure shows the necessity of mixing hydrogen peroxide with detergents, surfactants and organic disinfectants in a short time before use. The mixture of hydrogen and quaternary amines and/or glutaraldehyde exhibits a synergistic effect over the use of activated hydrogen peroxide solution within 1 hour after mixing, and the disinfection effect in 5 minutes reaches 6 orders of magnitude, but After 24 hours of mixing, the effect was significantly reduced, and hydrogen peroxide alone was not used. Figure 6a fully demonstrates that the disinfecting activity of the peroxide solution can be further enhanced by the addition of one or more formulations.

Figure 6b is a data plot of various disinfectants and their disinfection levels, including quaternary ammonium (QA) commercial products with a mass concentration of 0.5%, high temperature steam sterilizer (using AC121 ° C or AC 135 ° C), mass concentration 0.5% And 5% activated hydrogen peroxide (AHPO), the sterilization efficiency was determined by the survival analysis of B. subtilis spores. It is shown that two or more stages of sequential disinfection are required to achieve complete sterilization and inactivation. Different stages of disinfectant can be used in both stages, or disinfectant can be used in the second stage using moderate thermal steam sterilization in the first stage, or disinfectant in the first stage and thermal disinfection in the second stage in the second stage. In all cases, complete inactivation was not achieved after the first stage, and after the second stage, all test samples were completely inactivated. The need for a sequential disinfection phase is due to the limitation of the use of high-concentration disinfectants during the first phase, because of the high concentration of activated hydrogen peroxide, plus the addition of detergents, lubricants and surfactants, to shredding The machine poses a threat of damage. On the other hand, sequential treatment significantly shortens the sterilization process and achieves a complete inactivation effect, which is achieved when using a single disinfection method, whether using chemical disinfectants or using moderately hot steam. Can not reach.

Optionally, in the first stage of disinfection, in order to effectively disinfect the biomedical waste, the waste should be immersed in the disinfectant for at least 1 minute, or at least 2 minutes, or at least 3 minutes, or at least 4 minutes, or at least 6 minutes, or at least 7 minutes, or at least 8 minutes, or at least 9 minutes, or at least 10 minutes, each of the above cases corresponds to a separate embodiment of the invention. Optionally, one or more sensors can provide information feedback to controller 110 to control the various components. In a non-limiting embodiment, the sensor can provide pressure, temperature, concentration level, flow rate, level of disinfectant activity, or other data associated with each component to controller 110. Controller 110 can use these data to control the various components to operate as required. The controller 110 can receive data from any of the sensors and output control signals to coordinate the operation of the various components via various standard wired/wireless forms such as USB, Bluetooth or WIFI.

Optionally, controller 110 may include one or more controllers containing one or more computing instructions to perform control functions. As an option, the user can set the duration and timing of the different components through the user interface. For example, the user may choose a longer smash time. In addition, the user can also set a suitable disinfection time limit for a specific type of waste, such as 5 minutes, 10 minutes, etc., to save energy.

FIG. 1B is a conceptual schematic diagram of the medicament dispenser 106 of FIG. 1A. The medicament dispenser 106 includes a first dispenser 106a coupled to a container 106b containing hydrogen peroxide, a stabilizer, and an activator; a second dispenser 106c coupled to the container 106d containing the formulation, the controller being operable to operate the first dispense A hydrogen peroxide is supplied and the second dispenser is manipulated to provide a formulation.

Optionally, the first dispenser 106a and the second dispenser 106c may be electronic dispensers or electromechanical dispensers. The operation of the first dispenser 106a and the second dispenser 106c is at least partially controlled by the controller 110 or entirely mechanically controlled.

Optionally, the first distributor 106a and the second distributor 106c are fitted with one or more valves, such as check valves or may be controlled The electric valve controlled by the device 110.

Optionally, one or more pumps are responsible for pumping the disinfectant and formulation from the container 106b and the container 106d into the respective medicament dispenser. As an option, the pump can be controlled by the controller 110.

Optionally, the first dispenser 106a and the second dispenser 106c may dispense the disinfectant and formulation directly into the reaction cell 102, or may first mix the formulation with the disinfectant prior to dispensing into the reaction cell 102.

Optionally, the medicament dispenser 106 can be provided with an additional medicament container and an additional dispenser.

Figure 1C is an embodiment of the reaction cell 102 of Figure 1A. The reaction cell 102 can be provided with a lid 112 that covers the waste feed hopper 114. The waste enters the hopper 114 through the inlet 116, and then the baffle 118 opens, and the waste enters the reaction tank 102. The baffle 118 is controlled by the controller 110. Optionally, the controller 110 receives feedback signals from various sensors, such as whether the shredder 104 is ready. Optionally, the reaction cell 102 is equipped with one or more screens, such as screens 120 and/or screens 122, to prevent the passage of waste having particles larger than a predetermined value while dividing the reaction tank 102 into different areas. Optionally, screen 120 and screen 122 are used to screen for waste particles of different sizes. Optionally, the screen can prevent the passage of solids, thereby separating the solids from the liquid. The pulverized waste may pass through the screen 120 but may not pass through the screen 122 and may be discharged through the outlet 124 on the reaction tank 102. Optionally, the pulverized peroxide-sterilized waste, after being discharged through outlet 124, may be sent directly or indirectly to enhanced sterilizer 108, such as through a conveyor. Optionally, the screen 122 located below the screen 120 prevents waste from passing, thereby separating the solid and the liquid, and the separation liquid contains a disinfectant which can be discharged from the reaction tank 102 through the outlet 126 and reused as a disinfectant. Or directly discharged from the reaction chamber 100. Optionally, the outlet 126 can be fitted with a valve 126a (e.g., a one-way valve, pressure valve, etc.) to regulate the discharge of the solution containing the disinfecting component. Optionally, valve 126b can be controlled by controller 110.

FIG. 1D is an embodiment of the medicament dispenser 106 of FIG. 1A. The controller 110 can manipulate the medicament dispenser 106, which is coupled to the container 128, which mixes the disinfectant and the formulation to produce a peroxide disinfectant. The container 128 is made of a corrosion resistant metal to resist corrosion of the metal by the disinfecting solution, formulation, and mixtures thereof. Container 128 receives the disinfectant from container 106b and the formulation from container 106d through inlet 130. Optionally, the disinfectant and formulation are separately pumped into the container 128 by one or more pumps. Alternatively or additionally, the containers 106b and 106d may each be fitted with a valve to control the flow of disinfectant and formulation into the container 128 through the dispensers 106a and 106c. The sterilizing solution flows out of the container 128 through the outlet 132. Optionally, the controller 110 can operate the pump 134 to dispense the disinfecting solution from the container 128 and manipulate one or more liquid outlets 136, such as dispensers, to dispense the disinfecting solution onto the waste in the reaction cell 102. Alternatively, the disinfecting solution can enter the reaction cell 102 through an inlet. As an option, the container 128 can be fitted with an inlet 136 for returning the disinfectant used in the reaction cell 102 to the container 128 for reuse via the outlet 126, which is provided with a valve 126a. Optionally, the disinfecting solution refluxed into the container 128 can be adjusted to a predetermined level of activity by adding the disinfecting solution stored in the container 106b thereto through the dispenser 106a and adding the stored therein to the container 106d through the dispenser 106c. preparation. Optionally, the level of activity of the disinfecting solution is regulated by controller 110. Optionally, one or more sensors can measure various parameters of the disinfecting solution, such as pH, conductance, concentration of components in the disinfecting solution, and the like, and provide a feedback signal to controller 110 to control medicament dispenser 106a. And the work of 106c.

FIG. 1E is an embodiment of the shredder 104 of FIG. 1A. The pulverizer 104 is installed in the reaction tank 102. The controller 110 controls the pulverizer 104 to pulverize the waste inside the reaction tank 102. Optionally, the pulverizer 104 can include one or more comminutions Components such as pre-shredder 104a and final shredder 104b. For example, the waste may first be comminuted by the pre-shredder 104a to break up the outer box, the net and other large waste bodies to form waste having a particle size of 10 to 50 cm (length). The waste particles are then further comminuted by a pulverizer 104b to control the particle size to 0.5-1 inch. The controller 110 can manipulate the pre-shredder 104a and the final shredder 104b to operate simultaneously or sequentially. Alternatively, after the pre-pulverizer 104a is pulverized, the waste enters 104b for final pulverization. Alternatively, the pre-shredder 104a may be replaced by a pressure bar capable of breaking the waste to improve the feeding effect of the pulverizer 104b. Optionally, a pulverizer, such as a high speed pulverizer, may be additionally added below the screen 120 in Figure 1C. The controller 110 can manipulate the new pulverizer to further pulverize the waste passing through the screen 120 to reduce the waste particle size to less than 1 inch. In addition, the new pulverizer can mix the pulverized waste with the sterilizing solution before opening the valve 126 in FIG. 1C and releasing the sterilizing solution in the reaction cell 102.

Figure 1F is an embodiment of the enhanced sterilizer 108 of Figure 1A when it is a high pressure steam sterilizer. After the chemically treated pulverized waste enters the autoclave, the controller operates the heater 140 to heat the waste to a temperature sufficient to sterilize (120-150 degrees Celsius). Alternatively, the steam may also be provided by an external source of steam, such as a steam generator. Optionally, the autoclave may be coupled to the reaction cell 102 via a conveyor 138, either directly or indirectly. Alternatively, the autoclave can be used as a stand-alone unit that is not connected to the reaction chamber 100. Optionally, any component of the autoclave, such as heater 140, is controlled by controller 110.

Figure 2 shows an apparatus 200 for treating waste based on another embodiment. Apparatus 200 is very similar to reaction chamber 100 of Figure 1A, except that the treated waste is thermally sterilized in silo 202 (corresponding to reaction cell 102 in Figure 1A above). Apparatus 200 includes a controller 210 that, in response to controller 110, controls the operation of all of the components in apparatus 200. The silo 202 is fitted with a lid 212. When the lid 212 is opened or partially opened, the waste enters the device through the inlet 216. Optionally, the inlet 216 can also be used to remove pulverized waste that has been subjected to peroxide sterilization and heat sterilization. The controller 210 can manipulate the medicament dispenser 206a connected to the container 206b to deliver the disinfectant contained in the bin 202 through the inlet 236 into the 206b, or manipulate the medicament dispenser 206c connected to the container 206d to pass through the inlet into the silo 202. 236 was injected into the formulation contained in 206d. The disinfectant and the formulation are combined to produce a peroxide disinfecting solution that is sterilized while the pulverizer 204 (controlled by controller 210) is operating. Optionally, the controller 210 can operate the heater 240 to heat the bin 202 to provide a suitable temperature environment (eg, 60-70 ° C) for sterilization. Accordingly, controller 210 opens valve 226a to allow peroxide-containing disinfecting solution to exit bin 28 through outlet 226. Optionally, the discharged liquid can be reused as a disinfecting solution or directly discharged from the apparatus 200. The controller must first operate the piston 242a prior to thermal sterilization. The 242a piston is depressed to assist in the discharge of the liquid and also to pressurize the comminuted and sterilized waste, thereby reducing the volume filled by steam after heat sterilization. In addition, the controller 210 can also operate the heater 240 to heat the silo 202 to the temperature required for thermal disinfection (eg, 121-140 degrees Celsius).

Figure 3A is a conceptual diagram showing an inline analyzer 360 for assessing the sterilization efficiency of the reaction chamber 100 and apparatus 200 shown in Figures 1A and 2 during operation. For ease of explanation, FIG. 3A will be explained with the controller 110 of FIGS. 1A-F, but the same applies to the controller 210 of FIG. The controller 110 operates the detector 360 to extract a liquid sample from the enhanced sterilizer 108 (such as a high pressure steam sterilizer or a mixing reactor) and detect its oxygen demand (due to surviving bacteria) to reflect the bactericidal effect of the system. . The controller 110 controls the opening valve 364 to input a sample into the cylindrical container 366 through the inlet 362. Next, the sample is filtered through a rotating filter 368 (such as a 0.22 micron filter, 0.45 micron filter, etc.) to remove microorganisms (such as bacteria). Etc.) Separation from the disinfectant solution to obtain concentrated microorganisms. After filtration, the filter was rinsed with distilled water to remove residual disinfectant (hydrogen peroxide). Controller 110 opens valve 372 to allow water to flow from inlet 370 and out of outlet 374. Subsequently, the controller 110 closes the valve 376, rotates the filter to a vertical state, and opens the valve 372 to provide a bacterial growth medium into the cylindrical container 366 through the inlet 370. As an option, the cylindrical container 366 is also equipped with a breathing vent to remove excess air therein. Next, the controller 110 rotates the filter 368 such that the bacteria captured on the filter 368 fall into the growth medium in the cylindrical container 366 and are homogenized. Optionally, the controller controls the rotation of the filter 368 by manipulating the motor with the shifting actuator. The oxygen content in the growth medium is measured by an oxygen electrode. The controller takes oxygen content data and analyzes the oxygen consumption based on the measurement results. Oxygen consumption means that microbes survive, so the disinfection process fails, and if the oxygen content remains the same, it means the disinfection process is successful. Optionally, the controller 110 provides the user with an indication of the success or failure of the sterilization process. Optionally, the controller 110 provides a signal to the reaction chamber 100 to effect real-time adjustment of the sterilization process as appropriate. In a non-limiting embodiment, the module 360 is coupled to the device 200 and will automatically stop the operation of the comminution and disinfection apparatus when a disinfection failure is detected. After a preset time (1-5 minutes), controller 110 opens valve 376 to discharge the growth medium through outlet 374 and adjusts filter 368 to a horizontal position.

3B and 3C are diagrams of examples of the line analyzer 360 shown in Fig. 3A. Detection is controlled by controller 110 or an autonomous controller. When the sterilization process in the autoclave or mixing reactor 108 is completed, the mixture of solid and liquid is discharged to the solid-liquid separator shown in FIG. Upon discharge, valve 364 opens and a sample of the discharged liquid (step 420) flows into cylindrical container 366 through a conduit connected by inlet 362. At this stage the filter 368 is in a horizontal state, the liquid sample passes through the filter 368 (step 422), the bacteria in the sample are collected onto the filter screen, and the liquid is discharged through the open valve 376 through the outlet 374. A vacuum pump can be connected to the outlet 374 if it is desired to ensure that sufficient liquid sample flows through the filter. When sampling is complete, valve 364 is closed and valve 372 is opened to allow water in distilled water irrigation 382 to flow into cylindrical vessel 366. The cylindrical container and filter are rinsed with distilled water to remove residual disinfectant (step 424). Controller 110 closes valve 376 and motor 380 rotates the filter to a vertical position. At this stage, controller 110 opens valve 370 to fill the growth medium in container 384 with cylindrical container 366 (step 428), and excess air is expelled through vent tube 386. When the cylindrical container 366 is filled with the growth medium, the motor 380 rotates the filter 368 to cause the bacteria to fall into the growth medium and homogenize (step 430). While rotating the filter, the oxygen electrode 388 analyzes the oxygen level of the growth medium in the cylindrical vessel 366, and the controller 110 calculates a change in oxygen content by a setting algorithm (step 432). If the oxygen content analysis indicates a decrease in oxygen content (step 440), the controller 110 will stop the operation of the pulverizer.

4 is a flow chart of the method of processing biowaste shown in FIGS. 1A, 1B, 2, and 3. Optionally, the waste is loaded into a silo (step 400). The activated hydrogen peroxide, stabilizer and formulation are dispensed onto the waste. Hydrogen peroxide, the formulation is mixed to form a disinfecting solution and needs to be 6 hours after its formation (or 7, 8, 9, 10, 11 Within 12, 13 hours) for disinfection with contact with garbage. Optionally, the activity can be sustained for a longer period of time by the addition of hydrogen peroxide, a stabilizer and a formulation to the disinfecting solution. In a non-limiting embodiment, hydrogen peroxide, a stabilizer, and a formulation can be pumped into device 200 by a pump. In a non-limiting embodiment, the activated peroxide and stabilizer are dispensed by a first medicament dispenser and the stabilizer is dispensed by a second medicament dispenser. In another non-limiting embodiment, the dispensing of peroxides, stabilizers, and formulations is controlled by the controller through one or more valves and one or more pumps. The activated peroxide, one or more stabilizers, and the formulation can be dispensed into the silo at the same time, or the peroxide, one or more stabilizers, and the formulation are first mixed and then sprayed to the feedstock. In the warehouse. In a non-limiting embodiment, the stabilizer may contain peracetic acid, acetic acid. In a non-limiting embodiment, the formulation may be non-ionic A surface activator, a cationic surfactant, or an anionic surfactant, or a detergent. In another non-limiting embodiment, the formulation may contain one or more known surfactants or detergents having antibacterial activity. In another non-limiting embodiment, the formulation may contain one or more surfactants such as quaternary ammonium compounds having antibacterial activity. In another non-limiting embodiment, the formulation may comprise one or more selected from the group consisting of alkyl dimethyl benzyl ammonium chloride, octyl decyl dimethyl chloride Ammonium, octyldecyl dimethyl ammonium bromide, dimercaptodimethylammonium chloride and dimercaptodimethylammonium bromide. In addition, the formulation may also contain other known suitable ingredients, such as silicone-free lubricating oils. In addition, in order to better fuse the lubricating oil and the disinfecting liquid, an alcohol such as isopropyl alcohol and mineral oil may be added. In a non-limiting embodiment, the mineral oil may comprise one or more of polysorbate (TWEEN) and oleic acid polyethylene glycol glyceride.

The waste is mixed with the disinfecting solution while being pulverized, thereby facilitating sufficient contact of the waste with the disinfecting solution (step 404). In a non-limiting embodiment, in the first stage of sterilization, in order to effectively disinfect the biomedical waste, the waste should be immersed in the disinfectant for at least 1 minute, or at least 2 minutes, or at least 3 minutes, or at least 4 Minutes, or at least 6 minutes, or at least 7 minutes, or at least 8 minutes, or at least 9 minutes, or at least 10 minutes, or at least 11 minutes, or at least 12 minutes, or at least 15 minutes. Each possibility represents a separate embodiment of the invention. Optionally, the comminution of the waste and the disinfection of the peroxide are done in a single silo.

After comminution and disinfection (step 404), the sterilized mixed solution will be returned to step 402 for reuse to reduce disinfectant consumption and environmental emissions; the treated waste will enter a high pressure steam sterilizer for final steam sterilization. Or enter the mixing reactor to contact the high concentration disinfectant for 3-5 minutes (step 406). Optionally, in order to cope with excessive bacterial concentrations or excessive organic constituents, the duration of the sterilization can be as long as 15 minutes.

Optionally, after the waste is pulverized and peroxide sterilized (step 405 or 406), the disinfecting solution can be sampled and analyzed by the inline analyzer 360 to analyze the oxygen demand and be compared with a threshold to detect the disinfecting effect of the disinfecting solution. (Step 407). In a non-limiting embodiment, when the oxygen demand does not exceed the threshold, the disinfectant activity is considered to be up to standard and the system flow continues to operate. Optionally, after the test result of the determining step 408 is passed, the disinfectant is returned to the solid-liquid separation (step 410) and reused. Optionally, the treated comminuted waste will enter the extruder and be extruded (step 412), and the sterilizing liquid will return to step 406 so that no liquid is discharged and the solids are available for recycling.

Figures 5A and 5B are detailed conceptual illustrations of an example of an apparatus (in Figure 1A) for treating waste and for subsequent thermal disinfection or mixing reactor sterilization. In the first stage, the waste is loaded by a manual or mechanical feeder 502, while the lid 112 is opened at the time of feeding and closed immediately after the loading to prevent biofouling. The waste is then mixed with a pre-mixed, water-diluted low concentration disinfectant that is pumped into the silo 114 by a dispenser (106 in Figure 1D). The push rod 504 pushes the waste into the pre-shredder 104a, and the pre-pulverized waste is mixed with the low-concentration disinfectant and sent to the pulverizer 104b, which is equipped with a sieve to ensure that only enough small waste particles can enter the subsequent Autoclave sterilization or mixing reactor disinfection (108/202/510). Conveyor 138 acts as a solid-liquid separator, the liquid will return to the general concentration of peroxide disinfectant container and returned to the sterilization process for reuse (step 405, Figure 4), while the solid enters the enhanced sterilizer (high pressure) Steam sterilizer or mixing reactor) (108/202/510). A high concentration of disinfectant combined with hydrogen peroxide with an activator and stabilizer, or optionally a viscous material, pumped into an enhanced sterilizer (high pressure steam sterilizer or mixing reactor) (108/202/510) It can be processed by mixing or heat treatment for up to 15 minutes. The substance in the enhanced sterilizer (108/202/510) is then discharged into the solid-liquid separator 506, the liquid is returned to the high-concentration peroxide disinfectant container (as shown in step 410 of Figure 4), and the liquid sample is pumped into the pump. On-line analysis system (as shown in Figures 3A, 3B and 3C), solid feed extrusion The machine extrudes the residual disinfectant, and the extruded disinfectant is returned to the high-concentration disinfectant container, and the solid can be recycled according to the method shown in FIG. 7 later. If the analysis of the online analytical system shown in Figure 3 is a failure, the disinfecting solution needs to be replaced and the solids will be returned to the feeder 502.

Controllers 110 and/or 210 may include one or more software and hardware modules that perform control, calculation, information reception, and/or delivery functions.

The following examples are methods for recycling the solids obtained after the multi-stage treatment and solid-liquid separation of the biomedical waste in the above examples (hereinafter referred to as "non-homogeneous waste"):

Some application examples of the present invention are described herein by way of example only. In the case where detailed drawings are incorporated by reference, it is emphasized that the examples presented herein are merely examples and are intended to explain the practical application of the invention. Accordingly, the description accompanying the drawings may enable those skilled in the art to clearly understand how the invention is applied.

The present invention discloses a method of recovering heterogeneous waste. The technology disclosed herein is used to recover waste after disinfecting and degrading organic matter.

Optionally, the method comprises: pulverization, chemical degradation or rinsing of the organic components, and the waste is sterilized or degraded and pulverized sequentially or simultaneously. The methods disclosed herein protect the environment and reduce the landfill of waste.

Optionally, the method is chemically sterilized with a chemical component to remove residual organic components from the waste by physical or chemical means.

Optionally, the waste can be chemically degraded to remove residual organic components from the waste.

Optionally, the organic matter is degraded or washed away from other materials in the waste.

Optionally, after sterilization and degradation of the organic components and rinsing, the waste slag will be washed with water or a neutral liquid to remove residual organics and/or degradation fluids and/or disinfectants therein.

Optionally, the organic component-removing waste is mixed with fibrous materials such as cellulose, wool and synthetic fibers.

Optionally, the solid mixture is further mixed with the stickies and the hydrophilic polymer and further ground and stirred evenly.

Optionally, the mixture will mix with the flame retardant material prior to grinding to render it non-flammable.

Optionally, a hydrophobic polymer can be added to the mixture to form a water repellent layer on the surface of the recovered product product.

Optionally, the mixture is added to the mold of the final product and dried and cured. Optionally, heating may or may not be performed.

Optionally, the final treatment of the product includes such processes as painting, cutting, coating, and the like.

Further details and application examples of the invention are described below.

The use of "recycled" and "recycled" in this specification and its accompanying statements refers to the disposal of used waste materials and the use of new products.

As used herein, "sterilization" refers to any process by which a transferable substance (such as a fungus, a bacterium, a virus, a spore) can be killed or removed from a surface, device, object or drug. This term includes the process of completely killing one or more deliverables, as well as the process by which the level of deliverables can be significantly reduced compared to before treatment. In some application examples, the killable ratio of the deliverable material should be at least 50%, 60%, 70%, 80%, 90%, 99%, 99.99%, or even 100%. The term "sterilization" shall mean complete sterilization and partial sterilization processes such as heat sterilization.

Non-homogeneous waste, such as medical waste, may contain mixtures of various substances such as metals, glass and plastics; Materials from different sources, including but not limited to: needles, syringes, pipes, bottles, petri dishes, textiles, cartoon boxes, paper and other such materials.

7 is a flow diagram of a method for recovering heterogeneous waste containing various materials based on some embodiments, based on some embodiments. The present invention provides a more detailed study of waste materials by some embodiments, some embodiments comprising at least 1% organic components, while in some embodiments at least 10%, and still other embodiments comprising at least 30%, and then At least 50% organic ingredients.

The recovery process depicted in Figure 7 may include a step 502 of adding heterogeneous solid waste mixed from various materials, including biologically infected waste, medical waste, domestic waste, or any non-homogenous waste. The waste is then comminuted and optionally sterilized while comminuting. In some applications, the waste is also ground. In some embodiments, the heterogeneous waste is produced by a medical procedure.

As used herein, "medical process" means any medical device, material, container, laboratory procedure, including but not limited to: medical waste containers, liquid-free equipment and liquid-circuit equipment, medical waste containers (eg, sharp-object containers) , pathogenic waste containers, RCRA containers and chemotherapy containers), syringes, catheters, petri dishes, dialysis equipment, rinse syringes, urine cups, vials, sterilization wraps and liquid collection tubes.

In some application examples, the term "medical waste" refers to mixed medical waste including, but not limited to, one or more plastics, injection molded parts, rubber, glass, metal, paper, textiles, and blood. Examples of other medical waste include, but are not limited to, sharp objects containers (containing plastic, one or more glasses, metals, rubber).

The method illustrated in Figure 7 includes a step 504 of pulverizing the heterogeneous waste. The heterogeneous waste is pulverized into fine particles (hereinafter referred to as "granules"). In some applications, the pulverized waste is subjected to further grinding and agitation.

The waste particles can be pulverized into small sizes such as 1 cm, 2 cm, 3 cm, 4 cm or 5 cm in the longitudinal direction, including values between them. In other non-limiting examples, the comminuted waste comprises particles having a size of 5 cm. In other non-limiting examples, the particles are spherical and the measured size is the radius of the particles.

Optionally, comminution and grinding can be accomplished by a suitable mill in conjunction with a bowler, storage bin, screw feeder. It is to be understood that the particle sizes listed above are for illustrative purposes only and are not intended to limit the scope of the invention. The comminuted material can be returned to the container and continue to be ground to a smaller size while circulating in the system.

The method depicted in Figure 7 includes disinfecting the waste prior to or simultaneously with the comminution. Disinfection can be sterilized by heat, steam or chemical. When using chemical disinfection, the particles should be small enough to allow the disinfectant to fully contact all surfaces, cavities, and voids of the waste.

The method of Figure 7 includes a step 506 of degrading organic matter in the pulverized waste (also referred to as "treatment"). In some applications, these organics are non-particulate organics. In some applications, the organic matter is a particulate organic matter. In some applications, the organic matter is in a liquid state, such as blood and culture fluid.

As used herein, the term "degradation" and its associated state of time may be the degradation of an organic component by an oxidant or reaction consuming material (step 505). For example, aliphatic hydrocarbons are oxidized to the corresponding alcohols, whether mono- or polyhydric, aldehyde, carbonic, or the like, and eventually become carbon dioxide. The aromatic hydrocarbons can also be oxidized to the corresponding alcohols, either mono or diol, acetic acid, etc., and ultimately to carbon dioxide, carbonic acid, or the like.

In some applications, the degradation reaction is an oxidation reaction. In some applications, the oxidative degradation process is biodegradable and the organic components are degraded by microorganisms.

Degradation of organic matter can be accomplished by chemical agents, at least 50%, 60%, 70%, 80%, 90%, 95% of the degradable waste Or 99% organic ingredients (called "organic waste"). Optionally, the degradation process can be completed in a short time, such as 30 minutes or less, or 10 minutes or less.

In some applications, degradation of the degradable polymer can be accomplished by hydrolysis or aminolysis. The term "degradation" can refer to the extremes of the hydrolysis or aminolysis process.

The degradation process can be achieved by using an alkaline solution comprising at least one of ammonium hydroxide, an alkaline ethanol solution, a basic amine solution and derivatives thereof, and the alkaline solution itself can be degraded.

Degradation of organic matter can be achieved by heating the organic component and then using an oxidizing device or process.

The pulverization, sterilization and rinsing of the pulverized waste should be carried out at the same time, such as in a mother liquor, to enhance the efficiency and effectiveness of the disinfection. There are currently known suitable disinfectants in the industry.

Disinfection solutions disinfect medical waste while degrading organic matter.

The terms "disinfecting solution", "disinfectant", "disinfecting water" are used interchangeably herein.

In some applications, disinfectants can also be used to degrade organic waste.

In some application examples, the action of spraying the disinfectant and the degrading agent to the waste is controlled by a control mechanism, such as by controlling one or more valves or pumps.

In some applications, the disinfectant can be nonionic, and/or cationic, and/or ionic, and/or detergent. In some non-limiting application examples, the disinfectant may contain one or more surfactants and/or detergents known in the art to have antimicrobial activity. In some non-limiting application examples, the disinfectant may contain one or more surfactants having antibacterial activity such as quaternary ammonium compounds.

In some non-limiting application examples, a suitable disinfectant consists of one or more of the following: hypochlorous acid or hydrogen peroxide or sulfuric acid or any other acid or sodium hydroxide or any, any of which may be Combination of species or multiples.

In some application examples, the waste is mixed with the disinfecting solution (step 503) while being comminuted to promote sufficient contact of the waste with the disinfecting solution. In a non-limiting example, the comminution and chemical disinfection of the waste can be carried out simultaneously. In a non-limiting example, the waste is comminuted in an environment in contact with the disinfecting solution for at least 1 minute, or at least 2 minutes, or at least 3 minutes, or at least 4 minutes, or at least 5 minutes, or at least 6 minutes, or at least 7 minutes. , or at least 8 minutes, or at least 9 minutes, or at least 10 minutes, or at least 11 minutes, or at least 12 minutes, or at least 15 minutes. Each possibility represents a separate embodiment of the invention

As an alternative or in addition, the pulverized waste is thermally sterilized. Optionally, the chemically sterilized pulverized waste is thermally sterilized with the container (interior compartment). Optionally, chemically sterilized waste is also steam sterilized.

The method depicted in Figure 7 may also include steps 508 and 510 for rinsing and solid-liquid separation of the waste, as shown in Figure 7a. In some application examples, the separating step includes washing the pulverized waste with a rinsing solution to remove organic and/or chemical residues and/or solvent and/or detergent residues and/or blood and/or any liquid. In some application examples, the rinsing step includes rinsing the waste with a neutral liquid to render the participating liquid neutral.

In some applications, the liquid discharged from the comminution mechanism is returned for further sterilization and removal of organic components.

Optionally, solid-liquid separation is carried out using different densities of the different components of the mixture (solid and liquid). In this way, the comminuted particles can be collected and the residual organic matter can be separated from the waste and further processed if needed or discarded directly.

Optionally, the liquid separated in the solid needs to be evaporated to pass through a catalytic converter to evaporate any organic components in the rinse.

The method depicted in Figure 7 may include a step 512 of adding a polymer additive (fibrous material and stickies additive) to the pulverized solid waste. Optionally, the fibrous material is derived from natural fibers of plants and/or mammals, including more than one of cellulose, wool, lignin and flax; or may be derived from synthetic fibers, including one of glass fibers and mineral wool. Above; optionally, the fibrous material may be derived from the cellulose extracted from the recycled paper, and the waste paper is first mixed with water (step 507), the cellulose is dissolved, and then the solid-liquid separation (step 509) is performed to remove the water. Paper fibers; paper fibers need to be dissolved in water before being added to the solid waste mixture. The paper fibers are added to the stickies, such as polyvinyl acetate, at the time of use, and optionally, a flame retardant compound may also be added (step 511).

Step 512 can be performed after or at the same time as the separation step 510.

The method described in Figure 7 may include the step of adding a crosslinking agent to the pulverized waste.

Optionally, the recycled material derived from the heterogeneous waste is added to a fibrous material, which is physically bonded together by physical methods as described below. In some applications, some comminuted waste particles are chemically combined. In some application examples, the comminuted waste particles are physically combined, such as wrapped within the material.

Optionally, the recycled material derived from the heterogeneous waste incorporates a glue additive (also referred to as a binder) such as a glue that can bond the different materials together.

Optionally, the stickies may be the following viscous additives: 1. rubber-based viscous additives; 2. silicon-based viscous additives; 3. acetic acid-based polyethylene viscous additives; 4. (a) terminally unsaturated ethylene The base monomer and (b) one or both of the components containing the aqueous acrylic binder, a copolymer formed with vinyl acetate.

Some stickies are inherently tacky, while others can be tacky by adding viscous ingredients. The term "sticky" may refer to a stickies that are inherently tacky or that are tacky by the addition of tacky ingredients.

In some applications, the fibrous material is paper; in some applications, the fibrous material is a polyester or a compound containing a polyester. In some applications, the fibrous material is nylon or a compound containing nylon; in some applications, the fibrous material is an acrylic resin or a compound containing an acrylic resin.

Steps 512 and 514 may include a step of removing residual liquid from the solid mixture.

The term "additive" refers to a substance that can be added to another material without affecting its original function.

The stickiness additive is a filling material or material, including but not limited to: polysaccharide, resin, silica gel, acrylic acid, which can make the waste particles stick together to form a stable solid form, thus forming an ideal material, such as: Sexual container.

The term "fiber" or "fibrous material" includes, but is not limited to, the following species: microcrystalline cellulose, microbial cellulose, cellulose extracted from marine or other invertebrates, mechanically prepared wood pulp, chemically dissolved pulp, Protozoa (plant fibers that form stems and skins) and cellulose rayon. The cellulosic material can be further chemically derivatized, for example, by carboxylation, oxidation, sulfation or esterification.

In some application examples, the additive (the additive here refers to all substances added to the waste except the disinfectant and the organic degradation agent) is the concentration in the waste mixture before the final pouring into the mold (%w/ w) 0.1%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9% or 10%, including values in between.

In some applications, the term "filler" refers to a particular substance, typically a natural mineral, that can be added to a solid particle (such as fiber pulp) to provide specific properties.

In some application examples, the term "crosslinking substance" or "crosslinking agent" may allow a multifunctional, such as a double acting substance, to promote covalent interaction between the chain of compounds by reacting with a substance in the polymer. Connect to achieve cross-linking. In some should In the examples, the cross-linking agent refers to a radical component; in some applications, the radical component (also referred to as a generating agent or forming agent) is an organic or inorganic substance.

In some applications, the crosslinking agent is one or more of the following free radical species: an organic peroxide and an azo initiator.

Examples of other non-limiting organic peroxides for use in the invention include benzoyl peroxide, acetyl peroxide, lauroyl peroxide, tert-butyl perbenzoate, sodium peroxide, sodium sulfate, alkali acetyl , and alkaline earth metal peroxides.

Other free radical forming agents include, but are not limited to, azo compounds such as isobutyronitrile.

In some application examples, a crosslinking agent refers to a bonding agent. The bonding agent may be selected from the group consisting of thermoplastics, unsaturated acids, acid anhydrides, polyols, polyether polyols, isocyanates, and mixtures thereof.

In some applications, the crosslinking agent (e.g., organic peroxide) comprises 0.01%, 0.05%, 0.1%, 0.2%, 0.5%, or 1% by weight of the total weight of the solid mixture, including values in between.

Optionally, the method described in Figure 7 may include a step of adding a hydrophilic polymer to the mixed waste (step 513), mixing the waste with the hydrophilic polymer (step 514). The hydrophilic polymer is water-soluble, and during the final drying and curing as described in step (9), polymerization occurs due to loss of moisture in the mixture over time; optionally, the hydrophilic polymer is polymerized. Acrylic acid, polyvinyl alcohol or polyamine.

Optionally, the method described in Figure 13 may include a step of adding a hydrophobic polymer to the mixed waste (step 515). The mixture can then be ground and homogenized (step 516). The hydrophobic polymer is a polymer dissolved in an organic solvent, and is polymerized and solidified as the organic solvent is volatilized during the final drying and curing as described in the step (9); optionally, the hydrophobic polymer is polyethylene. , polypropylene, polystyrene or hydrophobic polyacrylate. If no hydrophobic polymer is added, the recovered material after drying may form a thinner layer of material, similar to a film, which can be used for coverage. This cover film can be completely recycled through process 512. Other examples of recycling medical waste to make films include, but are not limited to, the examples shown in FIG.

The method described in Figure 7 may also include introducing the ground waste into a mold (518) for further drying and curing. Prior to the drying step 522, the mixture needs to be allowed to stand to stabilize (step 520), so that the hydrophobic polymer separates from the hydrophobic component and forms a water repellent protective layer (Fig. 8, Fig. 9, Fig. 10 and Fig. 11). ), the recycled product can be kept stable when it is in contact with water.

The method described in Figure 7 may include an alternative step of storing the ground waste in a closed container that can be used as a filler or cover, similar to cement, without the use of a mold. An example of a thermal insulation material used to cover recycled pipes is shown in Figure 12.

In step 518, depicted in Figure 7, the solid mixture is introduced into a preformed mold.

The method depicted in Figure 7 may include the step 520 of placing the mixture in a preformed mold for hours or days until the hydrophobic polymer separates from the hydrophobic mixture and polymerizes to form a water repellent layer (Fig. 9), covering On the surface, the waste is not visible. Waste particles and fibrous materials can only be seen by removing the hydrophobic layer.

Step 522 may include a step of drying the mixed solids. In some applications, drying can be accelerated by heating the solid to above 40 °C.

Figure 7 may include a step 518 of pouring the mixture into a previously designed mold (hereinafter referred to as "product molding"). In some application examples, solids are formed by patterns drawn on a particular surface. In some application examples, the solid is formed by application to a particular surface; in some application examples, the solid is formed by cutting into the desired shape size.

In some application examples, articles made from recycled materials will also be provided.

In some application examples, these items are used for applications such as filling and segregation (Figs. 10 and 12). For example, the use of recycled waste is based on waste components such as plastics, textiles, and cellulose. The composition of the waste may have cold/hot properties that make it a barrier material. (eg as insulation)

In some application examples, the barrier layer is used in building parts such as walls, pipes, roofs and floors (Figure 10).

In some application examples, the item is a container.

Examples of such articles include, but are not limited to, food packaging and containers, beverage packaging and containers, medical device packaging, agricultural product packaging and containers (agrochemicals), packaging and containers for blood or other biological samples, and various other uses. Packaging and containers.

Other example items include, but are not limited to, containers, storage tanks, pipe walls, rubber seals, piping systems, filling machinery, silos, pumps, valves, and separation devices.

Figure 8 and Figure 13 are now described:

Figure 8 shows a chart of recycled product composition, where 1 is a hydrophobic layer, 2 is a hydrophilic polymer, 3 is a fibrous material, and 4 is a waste particle.

Figure 9 is a microscopic view of a waterproof layer produced by the method of the present invention, showing in detail a waterproof layer; the hydrophilic polymer used in the process of recycling waste is polyethylene glycol; hydrophobicity used The polymer is a hydrophobic polyacrylate; the fibrous materials used are mineral wool (rock wool), synthetic fibers (nylon), paper fibers and cotton fibers; the adhesive used is a resin.

Figure 10 shows a waterproof, thermal and acoustic insulation material made with heterogeneous waste recycling technology.

Figure 11 shows the structure under the waterproof layer of the separator made of recycled medical waste.

Figure 12 shows the insulating material overlaid on the pipe made with the stored mixed material without the use of a mold.

Figure 13 shows a packaging film material made from recycled medical waste.

Other exemplary articles include the filler material (particle board) of the door, and the surface material of the door.

In some applications, these articles have an identifiable hydrophobic or superhydrophobic surface.

In some applications, these items have fire, antistatic, and UV protection properties.

In some application examples, there is also a cast material in the article. In some applications, the cast materials include cement, gypsum, non-thermosetting synthetic resins, and materials such as soft polyurethane materials.

Existing inventions may be a system, method, and/or a computer program product. The computer program product may include a storage medium written with a computer program that directs the computer to operate in accordance with the above inventive method.

The computer storage medium can be a physical object that can store information, can store instructions, and can be used by an instruction executor. The computer storage medium can be, but is not limited to, an electronic storage device, a magnetic disk storage device, an optical disk storage device, an electromagnetic storage device, a semiconductor storage device, or a combination of other various forms. Examples of more detailed but not fully integrated computer storage devices are as follows: portable computer floppy disk, hard disk, random access memory (RAM), read only memory (ROM), electrically erasable programmable read only memory (EEPROM or flash), static Random access memory (SRAM), portable compact disk read only memory (CD-ROM), digital versatile disk (DVD), memory stick, floppy disk, mechanical cipher such as punched cards or using sculpt and its internal raised structure to record commands Information slot, as well as any suitable combination of the above. The computer readable storage medium referred to herein should not be considered as a transient signal, such as radio waves or other freely propagating electromagnetic waves, electromagnetic waves propagating through waveguides or other transmission media (eg, optical pulses through fiber optic cables) or through wires. electric signal.

The computer readable program instructions described herein can be downloaded and then loaded into a respective computing/processing device, the download source including the calculations A machine readable storage medium, or an external computer, or an external storage device over a network, such as the Internet, a local area network, a wide area network, and a wireless network. The network used may include copper transmission cables, optical transmission fibers, wireless transmissions, routers, firewalls, switches, gateway computers, and/or edge servers. A network adapter card or network interface in each computing/processor receives computer readable program instructions from the network and transmits the computer readable program instructions to a computer readable storage medium within the respective computing/processor.

Computer readable program instructions for performing the operations of the present invention may be assembly instructions, instruction set architecture (ISA) instructions, machine instructions, machine attached instructions, microcode, firmware instructions, state setting data, or by one or Source code or object code written in any combination of multiple programming languages, including object oriented programming languages such as Java, Smalltalk, C++, etc., and conventional procedural programming languages such as the C programming language or similar programming languages. The computer readable program instructions may be executed in whole or in part on a user's computer, or as a stand-alone software package, partly on a user's computer and partly on a remote computer, or entirely on a remote computer or server. In the latter case, the remote computer can be connected to the user's computer through any type of network, including a local area network (LAN) or a wide area network (WAN), or connected to an external computer (eg, using an internet service provider over the Internet). In some embodiments, electronic circuitry (including, for example, a programmable logic circuit PLC, a field programmable gate array FPGA, or a programmable logic array PLA) can be implemented by creating personalized electronic circuitry using state information of computer readable program instructions Computer readable instructions to perform the operations of the present invention.

The description of the various aspects of the invention has been made in accordance with the flowchart illustrations and drawings of the method, apparatus (system), and computer program product used in accordance with the embodiments of the invention. Each of the blocks in the flowcharts and block diagrams, as well as the combinations of the blocks in the flowcharts and block diagrams, can be implemented by computer readable program instructions.

The computer readable program instructions can be provided to a general purpose computer, a special purpose computer, or other programmable data processor to make the processor of the machine, and the instructions executed by the computer or other programmable data processor processor are created for implementation A device or block diagram or a device for the function/behavior specified in the tile. The computer readable program instructions can also be stored in a computer readable storage medium, which can be a computer, a programmable data processing device, and/or other device having a particular function, such that the computer readable storage medium carries the implementation The flowcharts and block diagrams and the instructions specified in the blocks therein guide the device to operate in a specific manner.

The computer readable program instructions can also be loaded into a computer to perform a series of operational steps on the computer, or loaded into other programmable data processing devices or other devices to create a process that can be implemented by the computer so that the computer, other Instructions executed on a programming device, or other device, implement a flowchart or block diagram or the functions and behaviors specified by the blocks therein.

The flowcharts and block diagrams in the figures illustrate the architecture, functionality, and operation of the systems, methods, and computer program products of the present invention in implementation, in accordance with various embodiments. In this regard, each block in the flowchart or block diagrams may represent a module, a portion or a portion of an instruction (including one or more executable instructions for performing certain logical functions). In some instances, the functions noted in the blocks may not be performed in the order noted. For example, two blocks of consecutive numbers may actually be executed simultaneously, or even in reverse order, depending on the specific function. Each of the flowcharts and the blocks in the block diagrams, or a combination thereof, may be implemented by a dedicated hardware system that performs a particular function or action, or a combination of special purpose hardware and computer instructions.

The description of the various embodiments of the present invention is intended to be illustrative and not restrictive Numerous modifications and changes can be made without departing from the scope and spirit of the described embodiments. The terminology is chosen to be a better understanding of the principles of the embodiments of the present invention, and the practical application and technical improvements of the prior art, or to enable a person of ordinary skill in the art to understand the embodiments of the present invention well. .

Unless otherwise expressly stated, the term "substantially" used herein to describe the state or related features of certain aspects of the embodiments of the present invention, The terms "about" and "an" are understood to mean that these states or features may remain within the scope of the intended application. Unless otherwise stated, "or" in the description or the claims is to be understood as a non-exclusive "or", including at least one of the

It should be noted that “one” in this document means “one or more”. The industry average should know that the singular form also includes the plural unless otherwise stated. Therefore, "a" and "at least one" are used herein to be equivalent and interchangeable.

To better understand the scope of this article and to limit the scope of the content, all quantitative numbers, percentages or scores in this document, as well as other values in this description and statement, should be used unless otherwise stated. The word "about" is modified. Therefore, all numbers and parameters in the following specifications and accompanying claims are approximate, and may vary depending on the desired performance, unless otherwise stated. At a minimum, each numerical parameter should still be within the same order of magnitude as it is reported and should be roughly consistent with the number of treatments obtained by the usual trade-offs.

In the description and claims of this patent application, all verbs "including", "comprising", "having" and variations thereof mean that the object of the verb is not necessarily a complete list of (parts, elements or other parts). Other terms should also be understood in accordance with what is known in the industry.

For the sake of clarity, different embodiments have been used herein to describe some aspects of the invention, but in fact these aspects may also be provided in combination in the same embodiment. Conversely, in some aspects of the invention, the same embodiment is used herein for the sake of brevity of the description, but may be provided separately in different embodiments, or combined in other suitable manners, or as suitable in other embodiments. The sub-combination is provided. The specific features described herein in the various embodiments are not essential features of the embodiments used, unless the embodiments do not function without the features.

The above embodiments are preferred embodiments of the present invention, but the embodiments of the present invention are not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and combinations thereof may be made without departing from the spirit and scope of the invention. Simplifications should all be equivalent replacements and are included in the scope of the present invention.

Claims (50)

A multi-stage processing method for biomedical waste, comprising the steps of: (1) While pulverizing the biological medical waste, the first-stage disinfection treatment of the biological medical waste is carried out by using a general concentration of the peroxide disinfectant; the mass concentration of the general concentration peroxide disinfectant is 0.1-0.5%; (2) performing the second-stage disinfection treatment on the garbage disposal material with the remaining peroxide disinfectant after the first-stage disinfection treatment, and the second-stage disinfection treatment is steam sterilization heat treatment or high concentration peroxidation Disinfection; the high-concentration peroxide disinfection is carried out by using a high-concentration peroxide disinfectant with a mass concentration of 5%-20%. A multi-stage processing method for biomedical waste according to claim 1, wherein said second stage sterilization treatment is in a mixed reactor containing a high concentration of peroxide disinfectant or in a high pressure steam sterilizer Perform a short 3 to 10 minute disinfection. The multi-stage processing method for biomedical waste according to claim 1, wherein the general concentration peroxide disinfectant and the high concentration peroxide disinfectant are based on hydrogen peroxide and are mixed in advance. The disinfectant preparation of the activator and the stabilizer, and then the disinfectant formed after mixing with the preparation, is disposed in the mother liquor at different concentrations before use, and then contacted with the biomedical waste to be treated for disinfection. The multi-stage processing method for biomedical waste according to claim 3, wherein the disinfectant is prepared from the following raw materials: hydrogen peroxide having a mass fraction of 50%, and a mass fraction of 1-5%. The activator, a mass fraction of 2-10% stabilizer, a mass fraction of 0.5-2% of the formulation, and the remainder is water. The multi-stage processing method of biomedical waste according to claim 3, wherein the stabilizer comprises acetic acid and peracetic acid. The multi-stage processing method of biomedical waste according to claim 3, wherein the activator is any chemical or substance capable of enriching the disinfectant with a peracetic acid compound having the highest activity, and comprises sulfuric acid and anhydrous acetic acid. And more than one of iron powder. The multi-stage processing method for biomedical waste according to claim 3, wherein the formulation is one or more of an anionic detergent, a nonionic detergent, and a cationic detergent. The multi-stage processing method for biomedical waste according to claim 3, wherein the formulation comprises one or more of the following quaternary ammonium compounds: alkyldimethylbenzylammonium chloride, octyl-fluorenyl - dimethyl ammonium chloride, octyl-decyl-dimethylammonium bromide, dinonyl-dimethylammonium chloride and dinonyl-dimethylammonium bromide. The multi-stage processing method for biomedical waste according to claim 8, wherein the formulation further comprises one or more of the following components: a silicone-free lubricating oil, an isopropyl alcohol, and an emulsifier; Preferably, it is a mineral oil; the mineral oil comprises the following components: polysorbate and/or oleic acid polyethylene glycol glyceride. The multi-stage processing method for biomedical waste according to claim 1, wherein in the step (2), the steam sterilization heat treatment is the garbage disposal after the first stage sterilization treatment and remains on the garbage disposal material. The disinfectant is subjected to high temperature steam at 120 to 150 ° C; in this process, the peroxide disinfectant in the disinfectant is enhanced by the heating activity, resulting in a more thorough disinfection effect. The multi-stage processing method for biomedical waste according to claim 1, wherein the high concentration peroxide disinfection in the step (2) is performed in a mixing reactor, and a high concentration peroxide is used in the mixing reactor. The disinfectant is sterilized and agitation is used to force the chemical to be thoroughly mixed with the waste treatment to adequately expose the comminuted waste treatment to the disinfectant and achieve a final disinfection within 3 to 10 minutes. The multi-stage processing method for biomedical waste according to claim 1, wherein the general concentration peroxide disinfectant and the high concentration peroxide disinfectant contain a viscous substance polysaccharide, and the effective disinfecting component is adhered. On the pulverized waste particles, the waste particles are simultaneously bonded together to form a polymer; the continuous disinfection effect is maintained while it is not separated during transportation. The multi-stage processing method for biomedical waste according to claim 1, characterized in that after the second-stage sterilization treatment described in the step (2), the obtained aseptic garbage disposal material is separated from the disinfectant. The separated disinfectant is reused. The multi-stage processing method for biomedical waste according to claim 1, characterized in that after the second-stage sterilization treatment described in the step (2), the obtained aseptic garbage disposal material is separated from the disinfectant. The separated garbage disposal material is contracted by an extruder and the residual disinfectant therein is extruded and reused. An apparatus for implementing a multi-stage processing method for biomedical waste according to any one of claims 1 to 14, characterized by comprising: one or more of the following devices: a reaction chamber for receiving garbage, equipped with a lid to prevent the leakage of microorganisms; Drug dispenser Pulverizer, with or without filter; Reaction cell Enhanced sterilizer, including a high pressure steam sterilizer or a mixing reactor; The reaction chamber is provided with a medicament dispenser, a pulverizer and a reaction tank for pulverizing and disinfecting the biomedical waste; the medicament dispenser is connected to the reaction tank, and the pulverizer is disposed in the reaction tank; the sterilizer is The reaction tanks are connected, and the treatment materials which have been subjected to the disinfection treatment of the general concentration of the peroxide disinfectant in the reaction tank are subjected to steam sterilization heat treatment or disinfected by using a high concentration peroxide disinfectant. The apparatus of claim 15 further comprising: a controller for controlling the associated device: (1) Controlling the feeder of the reaction chamber to control the garbage entering the reaction chamber; (2) Control the pulverizer to control the crushing of garbage; (3) manipulating the medicament dispenser to control the dispensing of the corresponding medicament on the garbage; (4) Control the enhanced sterilizer, control the corresponding device to perform steam sterilization heat treatment on the treated object and/or use high concentration peroxide disinfection treatment. The apparatus according to claim 16, further comprising a solid-liquid separator for separating the treated garbage and the disinfectant, and recycling the disinfectant. The apparatus according to claim 17, wherein said controller controls said solid-liquid separator to control separation of the treated garbage and the disinfectant. The apparatus according to claim 16 further comprising an extruder, said reinforced sterilizer being coupled to the extruder for compressing the treated waste, extruding the disinfectant and minimizing the treatment The volume of post-garbage. The device of claim 16 further comprising an inline analyzer for tracking whether the sterilization process is successful. The apparatus according to claim 20, wherein: ???said controller controls the online analyzer to control operation of the corresponding device through feedback from the online analyzer; the online analyzer includes an electrically connected detector And a filter; the detector is used to automatically sample the disinfected liquid at the end of the sterilization process and measure its oxygen demand level, and provide a reading and documentation of the disinfection effect according to a predetermined oxygen demand threshold; the filter is used Collect bacteria from the disinfectant to analyze the bacterial survival after the disinfection process; wash and remove the remaining chemical disinfectant peroxide disinfectant from the residual particles of the filter, so that the residual particles on the filter net enter the suspension and mix into the medium. The oxygen consumption is analyzed using an oxygen electrode or any other method for analyzing the oxygen content of the suspension; when the online analyzer's feedback oxygen consumption exceeds the threshold, the controller controls the operation of the entire device. A method for recycling processed biomedical waste, comprising the steps of: (1) removing organic components in the heterogeneous solid waste by degradation or washing; (2) pulverizing the waste; (3) washing the waste to remove any remaining active chemical, acid, alkali, disinfectant or detergent; (4) adding more than one fibrous substance to the waste; (5) adding more than one type of stickies to the waste; (6) adding more than one hydrophilic polymer to the waste; (7) adding more than one hydrophobic polymer to the waste; (8) further grinding to obtain a waste mixture; (9) Pour the waste mixture into the mold, let it stand for stability and then make the final drying and curing; The heterogeneous solid waste according to the step (1) is the separated garbage treated product according to claim 14. A method for recycling biomedical waste after treatment according to claim 22, wherein said step (1) further comprises disinfecting said waste. A method for recycling biomedical waste after treatment according to claim 23, wherein: The method of disinfection is a chemical disinfection method. A method for recycling biomedical waste after treatment according to claim 23, wherein the method of disinfecting is heat sterilization. A method for recycling biomedical waste after treatment according to claim 22 or 23, wherein the organic degradation agent used in the degradation in step (1) and the disinfectant used in the disinfection are the same Chemical material. A method for recycling biomedical waste after treatment according to claim 22 or 23, wherein the step of degrading and disinfecting in step (1) is completed simultaneously at the same stage. A method for recycling treated biomedical waste according to claim 22 or 23, wherein the step (1) of the degradation and disinfection, and the step (2) of the pulverizing process are The same phase is completed at the same time. A method for recycling biomedical waste after treatment according to claim 22, wherein the step (2) further comprises the step of subjecting the pulverized waste to a heat sterilization treatment. A method for recycling biomedical waste after treatment according to claim 22 or 24, wherein the disinfectant used in the chemical disinfection method is selected from the following materials and is in the step (3) The washing process is still active: cationic detergents, nonionic detergents and anionic detergents. A method for recycling biomedical waste after treatment according to claim 22 or 24, wherein the disinfectant used in the chemical disinfection method is one or more of organic degradants, including Chloric acid, hydrogen peroxide, sulfuric acid, sodium hydroxide, or any other acid or base that chemically degrades or rinses organic components. The method for recycling biomedical waste according to claim 23, wherein the non-homogenous solid waste is pulverized into small particles having a particle diameter of less than 5 cm to ensure waste. All surfaces are in full contact with the disinfectant. A method for recycling treated biomedical waste according to claim 32, wherein the sterilization process is carried out in a mixing reactor. The method for recycling biomedical waste according to claim 1, wherein the fibrous material in step (4) is natural fiber derived from plants and/or mammals, and/or Synthetic fibers include one or more of cellulose, wool, lignin, flax, synthetic fiber, glass fiber, and mineral wool. The method for recycling biomedical waste according to claim 1, wherein the adherend in the step (5) is a polysaccharide, a resin, a silica gel or the like. The method for recycling biomedical waste according to claim 1, wherein the hydrophilic polymer in the step (6) is water-soluble, and is carried out in the step (9). During the final drying and curing process, polymerization occurs due to loss of moisture in the mixture over time. A method for recycling biomedical waste after treatment according to claim 36, wherein the hydrophilic polymer is polyacrylic acid, polyethylene glycol or polyamine. A method for recycling biomedical waste after treatment according to claim 1, wherein: The hydrophobic polymer described in the step (7) is a polymer dissolved in an organic solvent, and is polymerized and solidified as the organic solvent is volatilized during the final drying and solidification as described in the step (9). A method for recycling biomedical waste after treatment according to claim 38, wherein the hydrophobic polymer is polyethylene, polypropylene, polystyrene or hydrophobic polyacrylate. A method for recycling treated biomedical waste according to any one of claims 36 to 39, wherein the hydrophilic polymer and the hydrophobic polymer are physically or chemically formed over time Separation. A method for recycling biomedical waste after treatment according to claim 38 or claim 39, wherein the hydrophobic polymer provides a waterproof layer for a product made of a heterogeneous solid waste recycling material. A method for recycling biomedical waste after treatment according to claim 1, wherein a flame retardant compound is added to the non-homogenous solid waste recovery material to prevent the product from burning in the event of fire. A method for recycling biomedical waste after treatment according to claim 1, wherein the grinding in the step (8) is grinding the waste into particles having an average particle diameter of less than 5 mm. A method for recycling biomedical waste after treatment according to claim 1, wherein the washing in step (3) is washing with water or detergent. A method for recycling biomedical waste after treatment according to claim 44, wherein the solution used in the step (3) is solid-liquid separated after use and is subjected to catalytic oxidation or other methods. The rinsed residue is removed to purify the water therein. A method for recycling treated biomedical waste according to claim 34, wherein when said fibrous material is a fiber derived from recycled paper, the paper fiber is added to the solid waste mixture Dissolve first in water. A method for recycling biomedical waste according to claim 1, wherein the drying and curing in the step (9) are at normal temperature or under heating. A method for recycling biomedical waste after treatment according to claim 1, wherein the non-homogenous solid waste recovery material is stored in a sealed container for use. A method for recycling biomedical waste according to claim 1, wherein the non-homogenous solid waste recovery material is formed into a heat insulating and sound insulating product. The method for recycling biomedical waste according to claim 1, characterized in that the non-homogenous solid waste recycling material is made into building materials, walls, wall coverings, containers, floors and other boards. Noodles, as well as cement substitutes.

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