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WO2017038436A1 - Steel wire for mechanical structure parts - Google Patents

Steel wire for mechanical structure parts Download PDF

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Publication number
WO2017038436A1
WO2017038436A1 PCT/JP2016/073770 JP2016073770W WO2017038436A1 WO 2017038436 A1 WO2017038436 A1 WO 2017038436A1 JP 2016073770 W JP2016073770 W JP 2016073770W WO 2017038436 A1 WO2017038436 A1 WO 2017038436A1
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WO
WIPO (PCT)
Prior art keywords
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cementite
steel wire
steel
average
Prior art date
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Ceased
Application number
PCT/JP2016/073770
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French (fr)
Japanese (ja)
Inventor
雄基 佐々木
琢哉 高知
政道 千葉
昌之 坂田
昌吾 村上
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Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
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Filing date
Publication date
Priority claimed from JP2016124960A external-priority patent/JP2017048459A/en
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Publication of WO2017038436A1 publication Critical patent/WO2017038436A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/32Soft annealing, e.g. spheroidising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires

Definitions

  • the present invention relates to a steel wire used as a material for machine structural parts. More specifically, the wire rod manufactured by temper rolling is subjected to spheroidizing annealing and then cold-worked, so the deformation resistance during cold working is low, crack resistance is good, and cold workability is good.
  • the present invention relates to a steel wire useful as a material for machine structural parts.
  • a "wire” is used for the meaning of a rolled wire, and points out the linear steel material cooled to room temperature after hot rolling.
  • the “steel wire” refers to a linear steel material obtained by subjecting the rolled wire material to a tempering treatment such as spheroidizing annealing.
  • spheroidizing annealing is usually applied to hot rolled wire rods such as carbon steel and alloy steel for the purpose of imparting cold workability.
  • hot rolled wire rods such as carbon steel and alloy steel
  • the strength is adjusted to obtain a machine structural part.
  • the life of the mold can be improved by lowering the deformation resistance of the steel wire.
  • the yield improvement of various components can be expected by improving the crack resistance of the steel wire.
  • the metal structure is substantially composed of ferrite grains and spherical carbides, and the ferrite grains have an average particle size of 15 ⁇ m or more, and the spherical carbides have an average particle size of 0.1. 8 ⁇ m or less, the maximum particle size is 4.0 ⁇ m or less, and the number per 1 mm 2 is 0.5 ⁇ 10 6 ⁇ C% to 5.0 ⁇ 10 6 ⁇ C%.
  • a steel wire technique in which the maximum distance between spherical carbides having a particle size of 0.1 ⁇ m or more is 10 ⁇ m or less is disclosed.
  • the average particle diameter of ferrite in the region from the surface to 20% of the cross-sectional radius, is 3 to 15 ⁇ m, the average particle diameter is 0.3 to 0.6 ⁇ m, and the average aspect ratio is 2. 5 or less spherical cementite is contained at a number density of 7 ⁇ 10 5 pieces / mm 2 or less, and the value obtained by dividing the standard deviation of the area ratio of cementite by the average area ratio of cementite is 0.25 or less.
  • the average particle diameter of ferrite In the inner region from 75% of the radius to the center, the average particle diameter of ferrite is 20 ⁇ m or more, and the steel wire rod / steel bar has excellent cold workability and contains spherical cementite having an average particle diameter of 0.3 ⁇ m or more.
  • Patent Document 3 includes a ferrite structure having an average particle diameter of 15 ⁇ m or less, and spherical cementite having an average aspect ratio of 3 or less and an average particle diameter of 0.6 ⁇ m or less, and the number of the spherical cementite is 1 mm.
  • a technique of steel wire rods having a cold workability of 1.0 ⁇ 10 6 ⁇ C content (%) or more per 2 is disclosed.
  • An object of the present invention is to provide a steel wire for machine structural parts capable of reducing deformation resistance during cold working, improving crack resistance, and exhibiting excellent cold workability.
  • the steel wire for machine structural parts according to the embodiment of the present invention that has solved the above problems is in mass%, C: 0.3 to 0.6%, Si: 0.05 to 0.5%, Mn: 0.2 to 1.7%, P: more than 0%, 0.03% or less, S: 0.001 to 0.05%, Al: 0.01 to 0.1%, and N: 0 to 0.015 %,
  • the balance is composed of iron and inevitable impurities, the steel microstructure is composed of ferrite and cementite, the balance is composed of impurities, and the average equivalent circle diameter of the bcc-Fe crystal grains is 15 ⁇ m or less,
  • the main point is that the number of cementite per 25 ⁇ m 2 satisfies 2.0 ⁇ 10 ⁇ [C%] or less. However, [C%] indicates the C content in mass%.
  • the steel wire further comprises, in mass%, Cr: more than 0%, 0.5% or less, Cu: more than 0%, 0.25% or less, Ni: more than 0%, 0 0.5% or less, Mo: more than 0%, 0.25% or less, and B: more than 0%, containing 0.01% or less, and satisfying the following formula (X) To do. [Cr%] + [Cu%] + [Ni%] + [Mo%] ⁇ 0.75 (X) However, [Cr%], [Cu%], [Ni%], and [Mo%] respectively indicate the contents of Cr, Cu, Ni, and Mo expressed in mass%.
  • the number ratio of cementite having an aspect ratio of 3.0 or less in the metal structure is 70% or more with respect to the total cementite number.
  • the chemical composition is appropriately adjusted, the steel microstructure contains ferrite and cementite, and the balance is made of impurities, and bcc (body-centered cubic) : Body-centered cubic lattice)-by controlling the average equivalent circle diameter of Fe crystal grains (hereinafter sometimes simply referred to as "bcc-Fe average grain diameter") to be small and reducing the number of cementite per 25 ⁇ m 2 Further, it is possible to provide a steel wire that realizes an improvement in crack resistance as well as a reduction in deformation resistance.
  • the present inventors have studied from various angles in order to realize a steel wire that has both improved deformation resistance and reduced deformation resistance during cold working. As a result, it was found that the ductility is improved and the crack resistance is improved by controlling the average particle size of bcc-Fe to be small during cold working. Further, the present inventors have found that as the number density of cementite is higher, the deformation resistance is increased by the dispersion strengthening mechanism, and further, macro cracks are formed by connecting the voids starting from the cementite.
  • the metal structure of a steel wire for machine structural parts according to an embodiment of the present invention (hereinafter sometimes simply referred to as “steel wire”) contains ferrite and cementite, and the balance is impurities.
  • the steel wire according to the embodiment of the present invention is obtained by spheroidizing and annealing a rolled wire, and changes to a spheroidized structure mainly composed of ferrite and cementite by spheroidizing annealing.
  • the steel metal structure contains ferrite and cementite, and the balance is made of impurities. As a result, the deformation resistance of the steel is reduced and the cold workability is improved.
  • a preferable total area ratio of ferrite and cementite with respect to the entire metal structure is 97% or more, more preferably 98% or more, and further preferably 99% or more.
  • the impurities include compounds such as AlN.
  • the compound can be tolerated as long as it does not adversely affect cold workability.
  • the preferred area ratio of the compound with respect to the total metal structure is less than about 3%.
  • a pearlite structure before spheroidizing annealing may be included as long as the cold workability is not adversely affected.
  • Average equivalent circle diameter of bcc-Fe crystal grains 15 ⁇ m or less
  • the average equivalent circle diameter (bcc-Fe average grain diameter) of bcc-Fe crystal grains of steel wire is 15 ⁇ m or less to improve ductility and during cold working Generation of cracks can be suppressed.
  • the bcc-Fe average particle diameter is preferably 13 ⁇ m or less, more preferably 11 ⁇ m or less.
  • the bcc-Fe average particle diameter is preferably 5 ⁇ m or more in consideration of production costs.
  • the standard for the size of the bcc-Fe crystal grains to be measured is not particularly limited, but the size that can be discriminated by the measurement method described later is the minimum size. Specifically, a size of 1 ⁇ m or more is a measurement target.
  • the circle equivalent diameter of a crystal grain means the diameter of the circle of the same area as each crystal grain.
  • the metal structure to be controlled by the above-described average bcc-Fe grain size is bcc-Fe crystal grains surrounded by a large-angle grain boundary in which the orientation difference between two adjacent crystal grains is larger than 15 °. This is because the effect on cold workability is small at the small-angle grain boundary where the orientation difference is 15 ° or less.
  • the above-mentioned “azimuth difference” is also called “deviation angle” or “bevel angle”, and the EBSP method (Electron BackScatter diffraction Pattern method) may be employed for measuring the orientation difference.
  • Number of cementite per 25 ⁇ m 2 2.0 ⁇ 10 ⁇ [C%] or less
  • the number of cementite per 25 ⁇ m 2 in the metal structure is 2.0 ⁇ 10 ⁇ [C %] Or less.
  • the number of cementite per 25 ⁇ m 2 is preferably 1.8 ⁇ 10 ⁇ [C%] or less, more preferably 1.6 ⁇ 10 ⁇ [C%] or less.
  • the number of cementite per 25 ⁇ m 2 is preferably 0.6 ⁇ 10 ⁇ [C%] or more in consideration of productivity.
  • size of the cementite used as a measuring object is not specifically limited, The size of the cementite which can be discriminate
  • the steel wire according to the embodiment of the present invention has a number ratio of cementite having an aspect ratio of 3.0 or less to the total number of cementites (hereinafter simply referred to as “aspect ratio”).
  • the ratio of the cementite with a ratio of 3.0 or less ”(sometimes referred to as“ the ratio of cementite ”) is preferably 70% or more.
  • the aspect ratio of cementite decreases, voids originating from the cementite become more difficult to generate. Therefore, macro cracks can be further suppressed by increasing the number ratio of cementite having a small aspect ratio.
  • the number ratio of cementite having an aspect ratio of 3.0 or less is more preferably 75% or more, still more preferably 80% or more, still more preferably 90% or more, and most preferably 100%.
  • size of the cementite used as a measuring object is not specifically limited. However, similarly to the above-described measurement of the number of cementites per 25 ⁇ m 2 , the size of the cementite that can be discriminated by the measurement method of the cementite ratio with an aspect ratio of 3.0 or less described later is the minimum size. Specifically, cementite having an equivalent circle diameter of 0.1 ⁇ m or more is a measurement target.
  • the aspect ratio of cementite is a value obtained by dividing the length of the major axis of the equivalent ellipse by the length of the minor axis of the equivalent ellipse when the cementite shape is an equivalent ellipse.
  • the equivalent ellipse is an ellipse having the same area as the target cementite and having the same moment of inertia as the target cementite.
  • Media Cybernetics, Inc. which will be described later. You may obtain
  • the embodiment of the present invention is intended for a steel wire used as a material for a machine structural component, and may have a normal chemical composition as a steel wire for a machine structural component.
  • the appropriate range of chemical components and the reasons for limiting the range are as follows.
  • “%” for the chemical component composition means mass%.
  • C 0.3 to 0.6%
  • the C content is preferably 0.32% or more, and more preferably 0.34% or more. However, if C is excessively contained, the strength is increased and the cold workability is lowered, so that it is necessary to be 0.6% or less.
  • the C content is preferably 0.55% or less, more preferably 0.50% or less.
  • Si 0.05 to 0.5% Si is useful as a deoxidizing element and an element for improving the strength of the final product by solid solution hardening.
  • the Si content was set to 0.05% or more.
  • the Si content is preferably 0.07% or more, and more preferably 0.10% or more.
  • the Si content is set to 0.5% or less.
  • the Si content is preferably 0.45% or less, more preferably 0.40% or less.
  • P more than 0% and 0.03% or less
  • P is an element inevitably contained in steel, causes segregation of grain boundaries in steel, and causes ductility deterioration. Therefore, the P content is set to 0.03% or less.
  • the P content is preferably 0.02% or less, more preferably 0.017% or less, and still more preferably 0.01% or less. The smaller the P content, the better. However, there may be a case where approximately 0.001% remains due to restrictions on the manufacturing process.
  • S 0.001 to 0.05%
  • S is an element inevitably contained in the steel, and is present as MnS in the steel and deteriorates ductility. Therefore, S is an element harmful to cold workability. Therefore, the S content is set to 0.05% or less.
  • the S content is preferably 0.04% or less, and more preferably 0.03% or less. However, since S has the effect
  • the S content is preferably 0.002% or more, and more preferably 0.003% or more.
  • Al 0.01 to 0.1%
  • Al is useful as a deoxidizing element and is useful for fixing solute N present in steel as AlN.
  • the Al content is determined to be 0.01% or more.
  • the Al content is preferably 0.013% or more, and more preferably 0.015% or more.
  • the Al content is determined to be 0.1% or less. Al content becomes like this. Preferably it is 0.090% or less, More preferably, it is 0.080% or less.
  • N 0 to 0.015%
  • N is an element inevitably contained in the steel.
  • the N content is set to 0.015% or less.
  • the N content is preferably 0.013% or less, and more preferably 0.010% or less.
  • the N content is preferably as low as possible, and is most preferably 0%, but it may remain about 0.001% due to restrictions on the manufacturing process.
  • the basic components of the steel wire according to the embodiment of the present invention are as described above, and the balance is substantially iron.
  • substantially iron means that the presence of trace components such as Sb and Zn, for example, other than iron, which does not inhibit the characteristics of the present invention, and that other than P, S, N, etc. It means that inevitable impurities such as O and H may be included.
  • the following elements may be selectively contained as necessary. Depending on the type of the selected arbitrary element (selected component), the characteristics of the steel wire are further improved. As described above, P, S, and N are elements inevitably contained (unavoidable impurities), but their composition ranges are separately defined as described above. For this reason, in the present specification, “inevitable impurities” included as the balance mean elements inevitably included except for elements whose composition range is separately defined.
  • Cr more than 0%, 0.5% or less
  • Cu more than 0%, 0.25% or less
  • Ni more than 0%, 0.25% or less
  • Mo more than 0%, 0.25% or less
  • B One or more selected from the group consisting of more than 0% and less than 0.01% Cr, Cu, Ni, Mo and B all increase the strength of the final product by improving the hardenability of the steel. It is an effective element. If necessary, these elements may be contained alone or in combination of two or more. Such effects increase as the content of these elements increases.
  • a preferable content for effectively exhibiting the above-described effect is such that the Cr content is 0.015% or more, more preferably 0.020% or more.
  • the preferable contents of Cu, Ni and Mo are all 0.02% or more, more preferably 0.05% or more.
  • the preferable content of B is 0.0003% or more, more preferably 0.0005% or more.
  • the Cr content is preferably 0.5% or less, and the Cu, Ni and Mo contents are preferably 0.25% or less.
  • a more preferable content of Cr is 0.45% or less, and further preferably 0.40% or less.
  • the more preferable contents of Cu, Ni and Mo are all 0.22% or less, more preferably 0.20% or less.
  • the B content is preferably 0.01% or less.
  • a more preferable content of B is 0.007% or less, more preferably 0.005% or less.
  • the steel wire according to the embodiment of the present invention may contain Ti in a range of more than 0% and 0.1% or less, if necessary. Since Ti forms a compound with N, solid solution N can be reduced by containing Ti. Therefore, the steel wire can be made softer.
  • the content of Ti is preferably 0.01% or more, more preferably 0.02% or more. On the other hand, if the Ti content is excessive, the hardness of the steel wire may increase due to the compound formed. Therefore, the preferable Ti content is 0.1% or less, more preferably 0.08% or less, and still more preferably 0.05% or less.
  • the steel wire according to the embodiment of the present invention is obtained by spheroidizing and annealing a rolled wire. Therefore, in order to appropriately control the metal structure after spheroidizing annealing as described above, it is preferable to appropriately control the spheroidizing annealing conditions described later. However, in order to ensure the above-described structure form by spheroidizing annealing, it is preferable to further appropriately control the production conditions (that is, rolling conditions) of the rolled wire rod. By controlling the rolling conditions, the microstructure of the rolled wire can be in a state where the bcc-Fe average particle diameter can be easily reduced and the number density of cementite can be easily reduced after spheroidizing annealing.
  • the finish rolling temperature at the time of hot rolling the steel that satisfies the above-described component composition it is preferable to adjust the finish rolling temperature at the time of hot rolling the steel that satisfies the above-described component composition, and to appropriately adjust the cooling rate and the temperature range with three subsequent cooling rates. .
  • the metal structure before spheroidizing annealing has pearlite and ferrite as the main phase, the crystal grains are refined, and the proeutectoid ferrite crystal grains are equiaxed.
  • the average lamellar interval can be set to a predetermined value or less.
  • the rolling wire manufacturing conditions for this are as follows: (a) finish rolling at 800 ° C. or more and 1000 ° C.
  • first cooling with an average cooling rate of 7 ° C./sec or more (b) first cooling with an average cooling rate of 7 ° C./sec or more, and (c) average cooling rate of 1 Second cooling at a rate of not less than 5 ° C / second and not more than 5 ° C / second, and (d) a third cooling having an average cooling rate faster than that of the second cooling and not less than 5 ° C / second in this order,
  • the end of the first cooling and the start of the second cooling are performed within a range of 700 to 750 ° C.
  • the end of the second cooling and the start of the third cooling are performed within a range of 600 to 650 ° C.
  • the third The end of cooling is preferably set to 500 ° C. or lower.
  • the finish rolling temperature is preferably 1000 ° C. or less.
  • the finish rolling temperature is more preferably 970 ° C. or less, and further preferably 940 ° C. or less.
  • the number ratio of cementite having an aspect ratio of 3.0 or less after spheroidizing annealing is further increased by performing finish rolling at 970 ° C. or less, which is a more preferable finish rolling temperature, and performing spheroidizing annealing under appropriate conditions described later. It tends to be higher.
  • the finish rolling temperature is more preferably 830 ° C. or higher, and further preferably 860 ° C. or higher.
  • the first cooling starts from 800 ° C. or more and 1000 ° C. or less, which is the finish rolling temperature, and ends in the temperature range of 700 to 750 ° C.
  • the average cooling rate in the first cooling is preferably 7 ° C./second or more.
  • the average cooling rate of the first cooling is more preferably 10 ° C./second or more, and further preferably 20 ° C./second or more.
  • the average lamellar spacing of the pearlite of the rolled wire rod is made as narrow as possible, the cementite is easily dissolved during spheroidizing annealing, and no spherical cementite nuclei are left in the grains ( That is, the number density of spherical cementite nuclei remaining in the grains is reduced).
  • the third cooling starts from a temperature range of 600 to 650 ° C. and ends at 500 ° C. or less.
  • the third cooling is faster than the second cooling and at an average cooling rate of 5 ° C./second or more.
  • the average cooling rate of the third cooling is more preferably 10 ° C./second or more, and further preferably 20 ° C./second or more.
  • the upper limit of the average cooling rate of the third cooling is not particularly limited, but is preferably 200 ° C./second or less as a practical range.
  • the cooling rate may be changed as long as the average cooling rate is 5 ° C./second or more.
  • finish temperature of 3rd cooling is not specifically limited, For example, it is 200 degreeC or more.
  • the average cooling rate of cooling is often slower than the average cooling rate of the third cooling.
  • the area reduction rate at that time may be, for example, 30% or less.
  • the area reduction rate is preferably 30% or less.
  • the lower limit of the area reduction rate is not particularly limited, but the effect is preferably obtained by setting it to 2% or more.
  • a spheroidizing annealing condition to be applied to a rolled wire manufactured under the preferable conditions as described above for example, when heating from room temperature to 740 ° C. in an atmospheric furnace as SA1 described later, at least from 500 ° C. to 740 ° C. Is heated at an average heating rate of 50 ° C / hour or more, then heated to 750 ° C at an average heating rate of 2 to 5 ° C / hour, held at 750 ° C for 10 to 60 minutes, and then at an average cooling rate of 20 ° C / hour or more. It is preferably cooled to 720 ° C., cooled to 700 ° C.
  • the spheroidizing annealing condition used in the embodiment of the present invention is not limited to this.
  • the average heating rate from at least 500 ° C. to 740 ° C. is set to 50 ° C./hour or more, thereby suppressing the grain growth of the metal structure.
  • the average heating rate at this time is more preferably 60 ° C./hour or more.
  • the average heating rate is preferably 200 ° C./hour or less, more preferably 150 ° C./hour or less.
  • the holding time at this time is more preferably 20 minutes or more and 50 minutes or less.
  • the average cooling rate at this time is more preferably 30 ° C./hour or more.
  • the average cooling rate is preferably 100 ° C./hour or less.
  • the average cooling rate at this time is more preferably 4 ° C./hour or more and 6 ° C./hour or less.
  • the average cooling rate at this time is more preferably 9 ° C./hour or more and 11 ° C./hour or less.
  • normal cooling such as cooling may be performed to cool to room temperature.
  • the average cooling rate for cooling is often slower than the average cooling rate from 700 ° C to 640 ° C.
  • Embodiments of the present invention are not limited by the following examples, and can be implemented with appropriate modifications within a range that can be adapted to the gist described above. It is included in the technical scope of the embodiment.
  • this annealing condition is abbreviated as “SA1”.
  • (B) Repeat SA1 five times. Note that the second and subsequent heating of SA2 (that is, the heating during the annealing of the second to fifth SA1 conditions in the annealing of SA2 that repeats SA1 five times) started at 640 ° C. Hereinafter, this annealing condition is abbreviated as “SA2”.
  • (C) When heating from room temperature to 710 ° C., heating from room temperature to 500 ° C.
  • this annealing condition is abbreviated as “SA3”.
  • the annealing conditions SA1 and SA2 are preferable annealing conditions of the embodiment of the present invention, and the annealing condition SA3 is an example in which the heating temperature (holding temperature) is low and not properly controlled.
  • the cross section (that is, in the radial direction of the wire)
  • the resin was embedded so that the cut cross-section could be observed, and the cut surface was mirror-polished with emery paper and diamond buff.
  • the position of D / 4 was measured in the radial direction from the outer peripheral surface of the steel wire.
  • the bcc-Fe crystal grain diameter was measured using an EBSP analyzer and an FE-SEM. As an analysis tool, OIM software of TSL Solutions Inc. was used. When the crystal grain difference is defined as a boundary where the crystal orientation difference (also referred to as “bevel”) exceeds 15 °, that is, a large-angle grain boundary, and the area of the bcc-Fe crystal grain is converted into a circle The average value of the diameters, that is, the average equivalent circle diameter was calculated. The measurement area at this time was 200 ⁇ m ⁇ 400 ⁇ m, and the measurement step was 1.0 ⁇ m. Measurement points having a confidence index (Confidence Index) indicating the reliability of the measurement direction of 0.1 or less were deleted (ie, excluded) from the analysis target.
  • Confidence Index Confidence Index
  • cementite ratio with an aspect ratio of 3.0 or less In measuring the cementite ratio with an aspect ratio of 3.0 or less, the measurement was performed based on the photograph taken in (3) above. Specifically, the aspect ratios of all cementites in the five photographs were measured by image analysis, and the average value of the ratios of the number of cementites having an aspect ratio of 3.0 or less to the total number of cementites in the five visual fields was determined. The total cementite and the cementite with an aspect ratio of 3.0 or less were targeted for those in which the entire cementite was shown in the photograph, and those that were not partially visible in the photograph. From the average value, a cementite ratio with an aspect ratio of 3.0 or less was calculated. The minimum equivalent circle diameter of the cementite to be measured was 0.1 ⁇ m.
  • Target deformation resistance 400 ⁇ Ceq + 430 (1)
  • Ceq [C%] + 0.2 ⁇ [Si%] + 0.2 ⁇ [Mn%]
  • [C%] and [Mn%] are C, Si and Mn, respectively. Content (mass%) is shown.
  • the crack occurrence rate was measured by performing a cold forging test with a processing rate of 60% under the same conditions as in (5) above, and observing the surface of each sample with a stereomicroscope at a magnification of 20 times. It was performed 5 times and the presence or absence of surface cracks was measured. Then, the “number of samples having surface cracks” was divided by 5 to obtain the average. The target crack generation rate for all steel types was 20% or less.
  • test no. 1, 2, 4 to 8, 10, 11, 13 to 16, 18 to 20, 22 to 25, 37, 38, 40, and 41 are examples that satisfy all of the requirements defined in the embodiments of the present invention. It can be seen that both a reduction in deformation resistance and an improvement in crack resistance are achieved. Although not shown in Table 3, test no. FE-SEM observation of the metal structures 1 to 36 confirms that all contain ferrite and cementite in a total ratio of 99 area% or more.
  • test No. which performed both SA1 and SA2 annealing conditions. 1 and 2 (steel type A), test no. 7 and 8 (steel type E), test no. 10 and 11 (steel type F), test no. 15 and 16 (steel type I), test no. 19 and 20 (steel grade K), test no. 24 and 25 (steel grade N), and test no. Focusing on 37 and 38 (steel type V), in any case, when annealing SA2 was repeated 5 times compared to SA1, at least one of deformation resistance and crack generation rate was further reduced.
  • test no. 11 (steel type F) is an example in which the number ratio of cementite having an aspect ratio of 3.0 or less satisfies the preferable requirements of the embodiment of the present invention. Therefore, the test No. in which the number ratio of cementite is not properly controlled. Compared to 10 (steel type F), the crack generation rate was further reduced.
  • Test No. 3 is an example in which spheroidizing annealing was performed using SA3 whose conditions were not appropriate using steel type A in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.
  • Test No. No. 9 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using steel type E in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance does not reach the target value.
  • Test No. No. 12 is an example in which spheroidizing annealing was performed with SA3 whose conditions were not appropriate using the steel type F in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.
  • Test No. No. 17 is an example in which spheroidizing annealing was performed using SA3 whose conditions were not appropriate using steel type I in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.
  • Test No. No. 21 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using the steel type K shown in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance does not reach the target value.
  • Test No. No. 26 is an example in which spheroidizing annealing was performed with SA3 whose conditions were not appropriate using the steel type N in Tables 1 and 2. Therefore, the number of cementite per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.
  • Test No. 27 is an example using the steel type O of Tables 1 and 2 with an excessive Mn content. For this reason, appropriate hot rolling and spheroidizing annealing of SA1 were performed, but the deformation resistance did not reach the target value.
  • Test No. No. 28 is an example using the steel type O in Tables 1 and 2 with an excessive Mn content. Therefore, although appropriate hot rolling and spheroidizing annealing of SA2 were performed, the deformation resistance did not reach the target value.
  • Test No. 29 is an example using the steel type P in Tables 1 and 2 with an excessive Cr content. For this reason, appropriate hot rolling and spheroidizing annealing of SA1 were performed, but the deformation resistance did not reach the target value.
  • Test No. 30 is an example using the steel type P of Tables 1 and 2 with an excessive Cr content. Therefore, although appropriate hot rolling and spheroidizing annealing of SA2 were performed, the deformation resistance did not reach the target value.
  • Test No. 31 is an example using the steel types Q of Tables 1 and 2 having a high finish rolling temperature at the time of rolling wire production. For this reason, appropriate spheroidizing annealing of SA1 was performed, but the average bcc-Fe particle diameter was coarser than the specified value, and the crack generation rate did not reach the target value.
  • Test No. 32 is an example using the steel types R of Tables 1 and 2 in which the cooling rate of the first cooling during the production of the rolled wire rod is slow and the cooling rate of the third cooling is slow. Therefore, although appropriate spheroidizing annealing of SA1 was performed, the average particle diameter of bcc-Fe was coarser than the specified value, and the number of cementites per 25 ⁇ m 2 was larger than the specified value. The target value has not been reached.
  • Test No. 33 is an example using the steel types S of Tables 1 and 2 in which the cooling rate of the second cooling during the production of the rolled wire rod is fast and the cooling rate of the third cooling is the same as the cooling rate of the second cooling. Therefore, although appropriate SA1 spheroidizing annealing was performed, the number of cementite per 25 ⁇ m 2 was larger than the specified value, and the deformation resistance did not reach the target value.
  • Test No. 34 is an example using the steel types T of Tables 1 and 2 having a high finish rolling temperature during the production of the rolled wire rod. Therefore, appropriate spheroidizing annealing of SA1 was performed, but the bcc-Fe average particle diameter was coarser than the specified value, and the crack generation rate did not reach the target value.
  • Test No. No. 35 uses the steel type U of Tables 1 and 2 that has a high finish rolling temperature at the time of rolling wire production, a high cooling rate of the second cooling, and does not perform the third cooling. This is an example. Therefore, the average particle diameter of bcc-Fe is coarser than the specified value, fine cementite is uniformly dispersed, the number of cementites per 25 ⁇ m 2 is larger than the specified value, and the deformation resistance and crack occurrence rate are the target values. Not reached.
  • Test No. No. 36 uses the steel type U of Tables 1 and 2 that has a high finish rolling temperature during the production of the rolled wire, the second cooling rate is high, and the third cooling is not performed, and the spheroidizing annealing is performed with SA5 where the conditions are not appropriate.
  • SA5 the spheroidizing annealing
  • Test No. 39 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using steel type V in Table 1.
  • the number of cementites around 25 ⁇ m 2 is larger than the predetermined value, and the deformation resistance does not reach the target value.
  • Steel wires for machine structural parts are various machine structural parts such as automobile parts and construction machine parts manufactured by cold working such as cold forging, cold forging and cold rolling. It is suitably used for the material.
  • these mechanical structural parts include bolts, screws, nuts, sockets, ball joints, inner tubes, torsion bars, clutch cases, cages, housings, hubs, covers, cases, washers, tappets, saddles, bulgs, Inner case, clutch, sleeve, outer race, sprocket, core, stator, anvil, spider, rocker arm, body, flange, drum, fitting, connector, pulley, metal fitting, yoke, base, valve lifter, spark plug, pinion gear, steering Examples include mechanical parts such as shafts and common rails, and electrical parts.
  • a steel wire according to an embodiment of the present invention is industrially useful as a steel wire for a high-strength mechanical structural component that is preferably used as a material for the mechanical structural component.
  • Excellent cold workability can be exhibited by low deformation resistance at room temperature and by suppressing cracking of the material.
  • Aspect 1 % By mass C: 0.3 to 0.6%, Si: 0.05 to 0.5%, Mn: 0.2 to 1.7%, P: more than 0%, 0.03% or less, S: 0.001 to 0.05%, Al: 0.01 to 0.1% and N: 0 to 0.015%, respectively, the balance consisting of iron and inevitable impurities,
  • the metallographic structure of the steel contains ferrite and cementite, the balance is made of impurities, the average equivalent circle diameter of the bcc-Fe crystal grains is 15 ⁇ m or less, and the number of cementite per 25 ⁇ m 2 is 2.0 ⁇ 10 ⁇ [C %] Steel wires for machine structural parts that are less than the number.
  • [C%] indicates the C content in mass%.
  • -Aspect 2 Furthermore, in mass%, Cr: more than 0%, 0.5% or less, Cu: more than 0%, 0.25% or less, Ni: more than 0%, 0.25% or less, It is described in the aspect 1 which contains 1 or more types selected from the group which consists of Mo: more than 0%, 0.25% or less and B: more than 0%, 0.01% or less, and satisfy
  • the present application includes a Japanese patent application with a filing date of September 3, 2015, Japanese Patent Application No. 2015-173962, and a Japanese patent application with a filing date of June 23, 2016, Japanese Patent Application No. 2016- Japanese Patent Application No. 2015-173962 and Japanese Patent Application No. 2016-124960 are incorporated herein by reference with a priority claim based on No. 124960.

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Abstract

Provided is a steel wire for mechanical structure parts, which is reduced in deformation resistance during cold working, has improved cracking resistance, and can exhibit excellent cold workability. The steel wire for mechanical structure parts according to the present invention comprises, in % by mass, 0.3 to 0.6% of C, 0.05 to 0.5% of Si, 0.2 to 1.7% of Mn, more than 0% and 0.03% or less of P, 0.001 to 0.05% of S, 0.01 to 0.1% of Al, 0 to 0.015% of N, and a remainder made up by iron and unavoidable impurities. In the steel wire, the metallic structure of the steel contains ferrite and cementite, with the remainder made up by impurities. In the steel wire, the average equivalent circle diameter of bcc-Fe crystal grains is 15 μm or less and the number of cementite grains per 25 μm2 is 2.0 × 10 × [C%] or less.

Description

機械構造部品用鋼線Steel wire for machine structural parts

 本発明は、機械構造部品の素材として用いられる鋼線に関する。より詳細には、調質圧延により製造した線材に球状化焼鈍を施した後、冷間加工する際に、冷間加工時の変形抵抗が低く、耐割れ性が良好であり、冷間加工性に優れた、機械構造部品用の素材として有用な鋼線に関する。尚、本明細書において、「線材」とは、圧延線材の意味で用い、熱間圧延後、室温まで冷却した線状の鋼材を指す。また「鋼線」とは、上記圧延線材に球状化焼鈍等の調質処理が施された、線状の鋼材を指す。 The present invention relates to a steel wire used as a material for machine structural parts. More specifically, the wire rod manufactured by temper rolling is subjected to spheroidizing annealing and then cold-worked, so the deformation resistance during cold working is low, crack resistance is good, and cold workability is good. The present invention relates to a steel wire useful as a material for machine structural parts. In addition, in this specification, a "wire" is used for the meaning of a rolled wire, and points out the linear steel material cooled to room temperature after hot rolling. The “steel wire” refers to a linear steel material obtained by subjecting the rolled wire material to a tempering treatment such as spheroidizing annealing.

 自動車用部品および建設機械部品等の各種機械構造部品を製造するにあたっては、通常、炭素鋼および合金鋼等の熱間圧延線材に、冷間加工性を付与する目的で球状化焼鈍が施される。そして、球状化焼鈍後の圧延線材、即ち鋼線に対して冷間加工を行い、その後切削加工などの機械加工を施すことによって所定の形状に成形し、さらに焼入れ焼戻し処理を行って最終的な強度調整が行われて、機械構造部品とされる。 When manufacturing various machine structural parts such as automobile parts and construction machine parts, spheroidizing annealing is usually applied to hot rolled wire rods such as carbon steel and alloy steel for the purpose of imparting cold workability. . And it cold-processes with respect to the rolling wire after spheroidizing annealing, ie, a steel wire, and after that, it forms into a predetermined shape by giving machining, such as cutting, and also performs quenching and tempering processing, and is final. The strength is adjusted to obtain a machine structural part.

 冷間加工において、鋼線の変形抵抗を下げることで、金型寿命の向上を期待することができる。また鋼線の耐割れ性を向上させることで、各種部品の歩留り向上を期待することができる。 In cold working, the life of the mold can be improved by lowering the deformation resistance of the steel wire. Moreover, the yield improvement of various components can be expected by improving the crack resistance of the steel wire.

 これまでにも、鋼線の冷間加工性を向上させる技術として、様々な方法が提案されている。こうした技術として、例えば特許文献1には、金属組織が実質的にフェライト粒と球状炭化物から構成され、前記フェライト粒は、平均粒径が15μm以上であり、前記球状炭化物は平均粒径が0.8μm以下で、且つ最大粒径を4.0μm以下で、且つ1mm当たりの個数が0.5×10×C%~5.0×10×C%個であり、前記球状炭化物のうち、粒径が0.1μm以上の球状炭化物間の最大距離が10μm以下である鋼線の技術が開示されている。 So far, various methods have been proposed as techniques for improving the cold workability of steel wires. As such a technique, for example, in Patent Document 1, the metal structure is substantially composed of ferrite grains and spherical carbides, and the ferrite grains have an average particle size of 15 μm or more, and the spherical carbides have an average particle size of 0.1. 8 μm or less, the maximum particle size is 4.0 μm or less, and the number per 1 mm 2 is 0.5 × 10 6 × C% to 5.0 × 10 6 × C%. A steel wire technique in which the maximum distance between spherical carbides having a particle size of 0.1 μm or more is 10 μm or less is disclosed.

 また特許文献2には、表面から断面半径の20%までの領域は、フェライトの平均粒径が3~15μmであり、平均粒子径が0.3~0.6μmで且つ平均アスペクト比が2.5以下の球状セメンタイトを7×10個/mm以下の個数密度で含有し、セメンタイトの面積率の標準偏差をセメンタイトの平均面積率で除した値が0.25以下であり、中心から断面半径の75%から中心までの内部領域においては、フェライトの平均粒径が20μm以上であり、平均粒子径が0.3μm以上の球状セメンタイトを含有する冷間加工性に優れた鋼線材・棒鋼の技術が開示されている。 In Patent Document 2, in the region from the surface to 20% of the cross-sectional radius, the average particle diameter of ferrite is 3 to 15 μm, the average particle diameter is 0.3 to 0.6 μm, and the average aspect ratio is 2. 5 or less spherical cementite is contained at a number density of 7 × 10 5 pieces / mm 2 or less, and the value obtained by dividing the standard deviation of the area ratio of cementite by the average area ratio of cementite is 0.25 or less. In the inner region from 75% of the radius to the center, the average particle diameter of ferrite is 20 μm or more, and the steel wire rod / steel bar has excellent cold workability and contains spherical cementite having an average particle diameter of 0.3 μm or more. Technology is disclosed.

 更に、特許文献3には、平均粒径が15μm以下のフェライト組織と、平均アスペクト比が3以下であり、かつ平均粒子径が0.6μm以下の球状セメンタイトからなり、前記球状セメンタイトの個数が1mm当り1.0×10×C含有量(%)個以上である冷間加工性に優れた鋼線材の技術が開示されている。 Further, Patent Document 3 includes a ferrite structure having an average particle diameter of 15 μm or less, and spherical cementite having an average aspect ratio of 3 or less and an average particle diameter of 0.6 μm or less, and the number of the spherical cementite is 1 mm. A technique of steel wire rods having a cold workability of 1.0 × 10 6 × C content (%) or more per 2 is disclosed.

特許第5026626号公報Japanese Patent No. 5026626 特開2013-234349号公報JP 2013-234349 A 特許第5407178号公報Japanese Patent No. 5407178

 本発明の目的は、冷間加工時における変形抵抗の低減と共に、耐割れ性の向上を図り、優れた冷間加工性を発揮できる機械構造部品用鋼線を提供することにある。 An object of the present invention is to provide a steel wire for machine structural parts capable of reducing deformation resistance during cold working, improving crack resistance, and exhibiting excellent cold workability.

 上記課題を解決し得た本発明の実施形態に係る機械構造部品用鋼線は、質量%で、C:0.3~0.6%、Si:0.05~0.5%、Mn:0.2~1.7%、P:0%超、0.03%以下、S:0.001~0.05%、Al:0.01~0.1%およびN:0~0.015%を夫々含有し、残部が鉄および不可避不純物からなり、鋼の金属組織が、フェライトおよびセメンタイトを含有し、残部が不純物からなり、bcc-Fe結晶粒の平均円相当直径が15μm以下であり、25μm当たりのセメンタイト個数が2.0×10×[C%]個以下を満たすところに要旨を有する。
 ただし、[C%]は、質量%でCの含有量を示す。
The steel wire for machine structural parts according to the embodiment of the present invention that has solved the above problems is in mass%, C: 0.3 to 0.6%, Si: 0.05 to 0.5%, Mn: 0.2 to 1.7%, P: more than 0%, 0.03% or less, S: 0.001 to 0.05%, Al: 0.01 to 0.1%, and N: 0 to 0.015 %, The balance is composed of iron and inevitable impurities, the steel microstructure is composed of ferrite and cementite, the balance is composed of impurities, and the average equivalent circle diameter of the bcc-Fe crystal grains is 15 μm or less, The main point is that the number of cementite per 25 μm 2 satisfies 2.0 × 10 × [C%] or less.
However, [C%] indicates the C content in mass%.

 本発明の好ましい実施形態において、上記鋼線は、更に、質量%で、Cr:0%超、0.5%以下、Cu:0%超、0.25%以下、Ni:0%超、0.25%以下、Mo:0%超、0.25%以下およびB:0%超、0.01%以下よりなる群から選択される1種以上を含有し、かつ下記式(X)を満足する。
 [Cr%]+[Cu%]+[Ni%]+[Mo%]≦0.75   (X)
 ただし、[Cr%]、[Cu%]、[Ni%]および[Mo%]は、それぞれ、質量%で示したCr、Cu、NiおよびMoの含有量を示す。
In a preferred embodiment of the present invention, the steel wire further comprises, in mass%, Cr: more than 0%, 0.5% or less, Cu: more than 0%, 0.25% or less, Ni: more than 0%, 0 0.5% or less, Mo: more than 0%, 0.25% or less, and B: more than 0%, containing 0.01% or less, and satisfying the following formula (X) To do.
[Cr%] + [Cu%] + [Ni%] + [Mo%] ≦ 0.75 (X)
However, [Cr%], [Cu%], [Ni%], and [Mo%] respectively indicate the contents of Cr, Cu, Ni, and Mo expressed in mass%.

 本発明の好ましい実施形態において、上記鋼線は、更に、質量%で、Ti:0%超、0.1%以下、を含有する。 In a preferred embodiment of the present invention, the steel wire further contains, by mass%, Ti: more than 0% and 0.1% or less.

 本発明の好ましい実施形態において、上記鋼線は、前記金属組織におけるアスペクト比が3.0以下のセメンタイトの数割合が、全セメンタイト数に対して70%以上である。 In a preferred embodiment of the present invention, in the steel wire, the number ratio of cementite having an aspect ratio of 3.0 or less in the metal structure is 70% or more with respect to the total cementite number.

 本発明の実施形態に係る機械構造部品用鋼線は、化学成分組成を適切に調整すると共に、鋼の金属組織が、フェライトおよびセメンタイトを含有し、残部が不純物からなり、bcc(body-centerd cubic:体心立方格子)-Fe結晶粒の平均円相当直径(以下、単に「bcc-Fe平均粒径」と呼ぶことがある)を小さく制御し、25μm当たりのセメンタイトの個数を少なくすることによって、変形抵抗の低減と共に耐割れ性の向上を実現した鋼線を提供することができる。本発明の実施形態に係る機械構造部品用鋼線は、変形抵抗が低減されているため、金型などの塑性加工用冶工具の磨耗および破壊を抑制できる。また、本発明の実施形態に係る機械構造部品用鋼線は、耐割れ性に優れているため、圧造加工時の割れ発生も抑制でき、冷間加工性に優れた特性を発揮する。 In the steel wire for machine structural parts according to the embodiment of the present invention, the chemical composition is appropriately adjusted, the steel microstructure contains ferrite and cementite, and the balance is made of impurities, and bcc (body-centered cubic) : Body-centered cubic lattice)-by controlling the average equivalent circle diameter of Fe crystal grains (hereinafter sometimes simply referred to as "bcc-Fe average grain diameter") to be small and reducing the number of cementite per 25 μm 2 Further, it is possible to provide a steel wire that realizes an improvement in crack resistance as well as a reduction in deformation resistance. Since the deformation resistance of the steel wire for machine structural parts according to the embodiment of the present invention is reduced, wear and breakage of a plastic working tool such as a die can be suppressed. Moreover, since the steel wire for machine structural components according to the embodiment of the present invention is excellent in crack resistance, it is possible to suppress the occurrence of cracking during forging and to exhibit characteristics excellent in cold workability.

 本発明者らは、冷間加工時の変形抵抗の低減と共に耐割れ性の向上を兼備した鋼線を実現するため、様々な角度から検討した。その結果、冷間加工時において、bcc-Fe平均粒径を小さく制御することによって延性が向上し、耐割れ性が向上することを見出した。また、セメンタイトの数密度が高いほど分散強化機構によって変形抵抗が増加すること、更にセメンタイト起点のボイドの連結によってマクロな割れが形成されることを見出した。すなわち、セメンタイトの数密度を低く制御すれば、セメンタイト粒子間の平均距離が拡大してセメンタイト起点のボイドが連結し難くなるため、冷間加工時の変形抵抗を低減でき、且つ、マクロな割れを抑制できるとの着想が得られた。よって、変形抵抗低減と耐割れ性向上の両立を図るためには、bcc-Fe平均粒径を小さく制御した上で、セメンタイトの数密度を適切な範囲に制御することが重要であるとの知見の下、検討した結果、本発明を完成した。 The present inventors have studied from various angles in order to realize a steel wire that has both improved deformation resistance and reduced deformation resistance during cold working. As a result, it was found that the ductility is improved and the crack resistance is improved by controlling the average particle size of bcc-Fe to be small during cold working. Further, the present inventors have found that as the number density of cementite is higher, the deformation resistance is increased by the dispersion strengthening mechanism, and further, macro cracks are formed by connecting the voids starting from the cementite. In other words, if the number density of cementite is controlled to be low, the average distance between the cementite particles is expanded and the voids of the cementite origin are difficult to connect, so the deformation resistance during cold working can be reduced, and macro cracks can occur. The idea that it can be suppressed was obtained. Therefore, in order to achieve both reduction of deformation resistance and improvement of crack resistance, it is important to control the number density of cementite within an appropriate range while controlling the bcc-Fe average particle size small. As a result of the examination, the present invention was completed.

 以下、本発明の実施形態で規定する各要件について説明する。 Hereinafter, each requirement prescribed | regulated by embodiment of this invention is demonstrated.

 本発明の実施形態に係る機械構造部品用鋼線(以下、単に「鋼線」と呼ぶことがある)の金属組織は、フェライトおよびセメンタイトを含有し、残部は不純物である。前述したとおり、本発明の実施形態に係る鋼線は圧延線材を球状化焼鈍して得られるものであり、球状化焼鈍によりフェライト・セメンタイト主体の球状化組織に変化する。鋼の金属組織が、フェライトおよびセメンタイトを含有し、残部が不純物からなり、その結果、鋼の変形抵抗が低減されて冷間加工性が向上する。全金属組織に対するフェライトとセメンタイトの好ましい合計面積率は97%以上であり、より好ましくは98%以上、更に好ましくは99%以上である。上記不純物としてAlN等の化合物が挙げられる。上記化合物は、冷間加工性に悪影響を及ぼさない範囲で許容することができ、例えば全金属組織に対する上記化合物の好ましい面積率は約3%未満である。上記化合物の他、冷間加工性に悪影響を及ぼさない限度において、球状化焼鈍前のパーライト組織が含まれていてもよい。 The metal structure of a steel wire for machine structural parts according to an embodiment of the present invention (hereinafter sometimes simply referred to as “steel wire”) contains ferrite and cementite, and the balance is impurities. As described above, the steel wire according to the embodiment of the present invention is obtained by spheroidizing and annealing a rolled wire, and changes to a spheroidized structure mainly composed of ferrite and cementite by spheroidizing annealing. The steel metal structure contains ferrite and cementite, and the balance is made of impurities. As a result, the deformation resistance of the steel is reduced and the cold workability is improved. A preferable total area ratio of ferrite and cementite with respect to the entire metal structure is 97% or more, more preferably 98% or more, and further preferably 99% or more. Examples of the impurities include compounds such as AlN. The compound can be tolerated as long as it does not adversely affect cold workability. For example, the preferred area ratio of the compound with respect to the total metal structure is less than about 3%. In addition to the above compounds, a pearlite structure before spheroidizing annealing may be included as long as the cold workability is not adversely affected.

 bcc-Fe結晶粒の平均円相当直径:15μm以下
 鋼線のbcc-Fe結晶粒の平均円相当直径(bcc-Fe平均粒径)を15μm以下とすることで延性を向上させ、冷間加工時の割れ発生を抑制することができる。bcc-Fe平均粒径は、好ましくは13μm以下であり、より好ましくは11μm以下である。なお、bcc-Fe平均粒径は、製造コストを考慮すると5μm以上であることが好ましい。尚、測定対象であるbcc-Fe結晶粒の大きさの基準は特に限定されないが、後述する測定方法によって判別できるサイズが最小サイズとなる。具体的には、1μm以上のサイズが測定対象である。尚、結晶粒の円相当直径とは、各結晶粒と同一面積の円の直径を意味する。
Average equivalent circle diameter of bcc-Fe crystal grains: 15 μm or less The average equivalent circle diameter (bcc-Fe average grain diameter) of bcc-Fe crystal grains of steel wire is 15 μm or less to improve ductility and during cold working Generation of cracks can be suppressed. The bcc-Fe average particle diameter is preferably 13 μm or less, more preferably 11 μm or less. The bcc-Fe average particle diameter is preferably 5 μm or more in consideration of production costs. The standard for the size of the bcc-Fe crystal grains to be measured is not particularly limited, but the size that can be discriminated by the measurement method described later is the minimum size. Specifically, a size of 1 μm or more is a measurement target. In addition, the circle equivalent diameter of a crystal grain means the diameter of the circle of the same area as each crystal grain.

 前記したbcc-Fe平均粒径の制御の対象となる金属組織は、隣り合う2つの結晶粒の方位差が15°よりも大きい大角粒界で囲まれたbcc-Fe結晶粒である。これは前記方位差が15°以下の小角粒界では、冷間加工性に及ぼす影響が小さいからである。なお、前記した「方位差」は、「ずれ角」もしくは「斜角」とも呼ばれているものであり、方位差の測定にはEBSP法(Electron BackScatter diffraction Pattern法)を採用すればよい。 The metal structure to be controlled by the above-described average bcc-Fe grain size is bcc-Fe crystal grains surrounded by a large-angle grain boundary in which the orientation difference between two adjacent crystal grains is larger than 15 °. This is because the effect on cold workability is small at the small-angle grain boundary where the orientation difference is 15 ° or less. The above-mentioned “azimuth difference” is also called “deviation angle” or “bevel angle”, and the EBSP method (Electron BackScatter diffraction Pattern method) may be employed for measuring the orientation difference.

 25μm当たりのセメンタイト個数:2.0×10×[C%]個以下
 本発明の実施形態に係る鋼線は、前記金属組織における25μm当たりのセメンタイトの個数が2.0×10×[C%]個以下を満足する。25μm当たりのセメンタイトの個数を上記の範囲に制御することで、変形抵抗を低減させることができる。更には上記範囲に制御することにより、セメンタイト起点の割れ発生を抑制できる場合がある。25μm当たりのセメンタイトの個数は、好ましくは1.8×10×[C%]個以下であり、より好ましくは1.6×10×[C%]個以下である。なお、25μm当たりのセメンタイトの個数は、生産性を考慮すると、0.6×10×[C%]個以上であることが好ましい。尚、測定対象となるセメンタイトの大きさの基準は特に限定されないが、後述する25μm当たりのセメンタイトの個数の測定方法によって判別できるセメンタイトのサイズが最小サイズとなる。具体的には、円相当直径が0.1μm以上であるセメンタイトが測定対象である。
Number of cementite per 25 μm 2 : 2.0 × 10 × [C%] or less In the steel wire according to the embodiment of the present invention, the number of cementite per 25 μm 2 in the metal structure is 2.0 × 10 × [C %] Or less. By controlling the number of cementites per 25 μm 2 within the above range, the deformation resistance can be reduced. Furthermore, by controlling to the above range, the occurrence of cracks at the cementite starting point may be suppressed. The number of cementite per 25 μm 2 is preferably 1.8 × 10 × [C%] or less, more preferably 1.6 × 10 × [C%] or less. The number of cementite per 25 μm 2 is preferably 0.6 × 10 × [C%] or more in consideration of productivity. In addition, although the reference | standard of the magnitude | size of the cementite used as a measuring object is not specifically limited, The size of the cementite which can be discriminate | determined with the measuring method of the number of cementite per 25 micrometers 2 mentioned later becomes the minimum size. Specifically, cementite having an equivalent circle diameter of 0.1 μm or more is a measurement target.

 アスペクト比が3.0以下のセメンタイトの数割合:70%以上
 本発明の実施形態に係る鋼線は、全セメンタイト数に対する、アスペクト比が3.0以下のセメンタイトの数割合(以下、単に「アスペクト比3.0以下のセメンタイト割合」と呼ぶことがある)が70%以上であることが好ましい。セメンタイトのアスペクト比が小さくなる程、セメンタイト起点のボイドが一層生成し難くなる。そのため、アスペクト比の小さいセメンタイトの数割合を増加させることによって、マクロな割れを一層抑制することができる。アスペクト比3.0以下のセメンタイトの数割合は、より好ましくは75%以上であり、更に好ましくは80%以上、更により好ましくは90%以上、最も好ましくは100%である。尚、測定対象となるセメンタイトの大きさの基準は特に限定されない。しかしながら、前述の25μm当たりのセメンタイトの個数の測定と同様、後述するアスペクト比3.0以下のセメンタイト割合の測定方法によって判別できるセメンタイトのサイズが最小サイズとなる。具体的には、円相当直径が0.1μm以上であるセメンタイトが測定対象である。
 なお、セメンタイトのアスペクト比とは、セメンタイト形状を相当楕円とした際の、当該相当楕円の長軸の長さを、当該相当楕円の短軸の長さで除した値である。なお、相当楕円とは、対象とするセメンタイトと同面積であり、かつ対象とするセメンタイトと慣性モーメントが等しい楕円である。例えば、後述するMediaCybernetics,Inc.製「Image-Pro Plus」(商品名)を用いた画像解析によって求めてもよい。
Number ratio of cementite having an aspect ratio of 3.0 or less: 70% or more The steel wire according to the embodiment of the present invention has a number ratio of cementite having an aspect ratio of 3.0 or less to the total number of cementites (hereinafter simply referred to as “aspect ratio”). The ratio of the cementite with a ratio of 3.0 or less ”(sometimes referred to as“ the ratio of cementite ”) is preferably 70% or more. As the aspect ratio of cementite decreases, voids originating from the cementite become more difficult to generate. Therefore, macro cracks can be further suppressed by increasing the number ratio of cementite having a small aspect ratio. The number ratio of cementite having an aspect ratio of 3.0 or less is more preferably 75% or more, still more preferably 80% or more, still more preferably 90% or more, and most preferably 100%. In addition, the reference | standard of the magnitude | size of the cementite used as a measuring object is not specifically limited. However, similarly to the above-described measurement of the number of cementites per 25 μm 2 , the size of the cementite that can be discriminated by the measurement method of the cementite ratio with an aspect ratio of 3.0 or less described later is the minimum size. Specifically, cementite having an equivalent circle diameter of 0.1 μm or more is a measurement target.
The aspect ratio of cementite is a value obtained by dividing the length of the major axis of the equivalent ellipse by the length of the minor axis of the equivalent ellipse when the cementite shape is an equivalent ellipse. The equivalent ellipse is an ellipse having the same area as the target cementite and having the same moment of inertia as the target cementite. For example, Media Cybernetics, Inc., which will be described later. You may obtain | require by the image analysis using "Image-Pro Plus" (brand name) made from a product.

 次に、本発明の実施形態に係る鋼線の化学成分組成について説明する。本発明の実施形態は、機械構造部品の素材に用いる鋼線を対象とするものであり、機械構造部品用鋼線として通常の化学成分組成を有していればよい。化学成分の適切な範囲およびその範囲限定理由は下記の通りである。尚、本明細書では、化学成分組成について「%」とは、質量%を意味する。 Next, the chemical component composition of the steel wire according to the embodiment of the present invention will be described. The embodiment of the present invention is intended for a steel wire used as a material for a machine structural component, and may have a normal chemical composition as a steel wire for a machine structural component. The appropriate range of chemical components and the reasons for limiting the range are as follows. In the present specification, “%” for the chemical component composition means mass%.

 C:0.3~0.6%
 Cは、鋼の強度、即ち最終製品の強度を確保する上で有用な元素である。こうした効果を有効に発揮させるためには、C含有量は0.3%以上とする必要がある。C含有量は、好ましくは0.32%以上であり、より好ましくは0.34%以上である。しかしながら、Cが過剰に含有されると強度が高くなって冷間加工性が低下するので、0.6%以下とする必要がある。C含有量は、好ましくは0.55%以下であり、より好ましくは0.50%以下である。
C: 0.3 to 0.6%
C is an element useful for ensuring the strength of the steel, that is, the strength of the final product. In order to exhibit such an effect effectively, the C content needs to be 0.3% or more. The C content is preferably 0.32% or more, and more preferably 0.34% or more. However, if C is excessively contained, the strength is increased and the cold workability is lowered, so that it is necessary to be 0.6% or less. The C content is preferably 0.55% or less, more preferably 0.50% or less.

 Si:0.05~0.5%
 Siは、脱酸元素、および固溶体硬化による最終製品の強度向上元素として有用である。このような効果を有効に発揮させるため、Si含有量を0.05%以上と定めた。Si含有量は、好ましくは0.07%以上であり、より好ましくは0.10%以上である。一方、Siが過剰に含有されると硬度が過度に上昇して冷間加工性を劣化させる。そこでSi含有量を0.5%以下と定めた。Si含有量は、好ましくは0.45%以下であり、より好ましくは0.40%以下である。
Si: 0.05 to 0.5%
Si is useful as a deoxidizing element and an element for improving the strength of the final product by solid solution hardening. In order to effectively exhibit such an effect, the Si content was set to 0.05% or more. The Si content is preferably 0.07% or more, and more preferably 0.10% or more. On the other hand, when Si is contained excessively, the hardness is excessively increased and the cold workability is deteriorated. Therefore, the Si content is set to 0.5% or less. The Si content is preferably 0.45% or less, more preferably 0.40% or less.

 Mn:0.2~1.7%
 Mnは、焼入れ性の向上を通じて、最終製品の強度を増加させるのに有効な元素である。このような効果を有効に発揮させるため、Mn含有量を0.2%以上と定めた。Mn含有量は、好ましくは0.3%以上であり、より好ましくは0.4%以上である。一方、Mnが過剰に含有されると硬度が上昇して冷間加工性を劣化させる。そこでMn含有量を1.7%以下と定めた。Mn含有量は、好ましくは1.5%以下であり、より好ましくは1.3%以下である。
Mn: 0.2 to 1.7%
Mn is an effective element for increasing the strength of the final product through improvement of hardenability. In order to effectively exhibit such an effect, the Mn content is set to 0.2% or more. The Mn content is preferably 0.3% or more, and more preferably 0.4% or more. On the other hand, when Mn is contained excessively, the hardness is increased and the cold workability is deteriorated. Therefore, the Mn content is set to 1.7% or less. The Mn content is preferably 1.5% or less, and more preferably 1.3% or less.

 P:0%超、0.03%以下
 Pは、鋼中に不可避的に含まれる元素であり、鋼中で粒界偏析を起こし、延性の劣化の原因となる。そこで、P含有量は0.03%以下と定めた。P含有量は、好ましくは0.02%以下であり、より好ましくは0.017%以下、更に好ましくは0.01%以下である。P含有量は少なければ少ない程好ましいが、製造工程上の制約などにより0.001%程度残存してしまう場合もある。
P: more than 0% and 0.03% or less P is an element inevitably contained in steel, causes segregation of grain boundaries in steel, and causes ductility deterioration. Therefore, the P content is set to 0.03% or less. The P content is preferably 0.02% or less, more preferably 0.017% or less, and still more preferably 0.01% or less. The smaller the P content, the better. However, there may be a case where approximately 0.001% remains due to restrictions on the manufacturing process.

 S:0.001~0.05%
 Sは、鋼中に不可避的に含まれる元素であり、鋼中でMnSとして存在し延性を劣化させるので、冷間加工性に有害な元素である。そこでS含有量を0.05%以下と定めた。S含有量は、好ましくは0.04%以下であり、より好ましくは0.03%以下である。但し、Sは被削性を向上させる作用を有するので、0.001%以上含有させる。S含有量は、好ましくは0.002%以上であり、より好ましくは0.003%以上である。
S: 0.001 to 0.05%
S is an element inevitably contained in the steel, and is present as MnS in the steel and deteriorates ductility. Therefore, S is an element harmful to cold workability. Therefore, the S content is set to 0.05% or less. The S content is preferably 0.04% or less, and more preferably 0.03% or less. However, since S has the effect | action which improves a machinability, it is made to contain 0.001% or more. The S content is preferably 0.002% or more, and more preferably 0.003% or more.

 Al:0.01~0.1%
 Alは、脱酸元素として有用であると共に、鋼中に存在する固溶NをAlNとして固定するのに有用である。こうした効果を有効に発揮させるため、Al含有量を0.01%以上と定めた。Al含有量は、好ましくは0.013%以上であり、より好ましくは0.015%以上である。しかしながら、Al含有量が過剰になると、Alが過剰に生成し、冷間加工性を劣化させる。そこでAl含有量を0.1%以下と定めた。Al含有量は、好ましくは0.090%以下であり、より好ましくは0.080%以下である。
Al: 0.01 to 0.1%
Al is useful as a deoxidizing element and is useful for fixing solute N present in steel as AlN. In order to exhibit such an effect effectively, the Al content is determined to be 0.01% or more. The Al content is preferably 0.013% or more, and more preferably 0.015% or more. However, when the Al content is excessive, Al 2 O 3 is excessively generated and the cold workability is deteriorated. Therefore, the Al content is determined to be 0.1% or less. Al content becomes like this. Preferably it is 0.090% or less, More preferably, it is 0.080% or less.

 N:0~0.015%
 Nは、鋼中に不可避的に含まれる元素であり、鋼中に固溶Nが含まれると、歪み時効による硬度上昇、延性低下を招き、冷間加工性を劣化させる。そこでN含有量を0.015%以下と定めた。N含有量は、好ましくは0.013%以下であり、より好ましくは0.010%以下である。N含有量は少なければ少ない程好ましく、0%であることが最も好ましいが、製造工程上の制約などにより0.001%程度残存する場合もある。
N: 0 to 0.015%
N is an element inevitably contained in the steel. When solid solution N is contained in the steel, the hardness increases due to strain aging and the ductility decreases, and the cold workability deteriorates. Therefore, the N content is set to 0.015% or less. The N content is preferably 0.013% or less, and more preferably 0.010% or less. The N content is preferably as low as possible, and is most preferably 0%, but it may remain about 0.001% due to restrictions on the manufacturing process.

 本発明の実施形態に係る鋼線の基本成分は上記の通りであり、残部は実質的に鉄である。尚、「実質的に鉄」とは、鉄以外にも本発明の特性を阻害しない程度の、例えばSb、Zn等の微量成分の存在を許容し得ること、およびP、S、N以外の例えばO、H等の不可避不純物も含み得ることを意味する。更に本発明の実施形態では、必要に応じて以下の元素を選択的に含有してもよい。選択された任意元素(選択成分)の種類に応じて、鋼線の特性が更に改善される。
 尚、上述のように、P、SおよびNは、不可避的に含まれる元素(不可避不純物)であるが、その組成範囲について上記のように別途規定している。このため、本明細書において、残部として含まれる「不可避不純物」は、別途その組成範囲が規定されている元素を除いた不可避的に含まれる元素を意味する。
The basic components of the steel wire according to the embodiment of the present invention are as described above, and the balance is substantially iron. In addition, “substantially iron” means that the presence of trace components such as Sb and Zn, for example, other than iron, which does not inhibit the characteristics of the present invention, and that other than P, S, N, etc. It means that inevitable impurities such as O and H may be included. Furthermore, in the embodiment of the present invention, the following elements may be selectively contained as necessary. Depending on the type of the selected arbitrary element (selected component), the characteristics of the steel wire are further improved.
As described above, P, S, and N are elements inevitably contained (unavoidable impurities), but their composition ranges are separately defined as described above. For this reason, in the present specification, “inevitable impurities” included as the balance mean elements inevitably included except for elements whose composition range is separately defined.

 Cr:0%超、0.5%以下、Cu:0%超、0.25%以下、Ni:0%超、0.25%以下、Mo:0%超、0.25%以下およびB:0%超、0.01%以下よりなる群から選択される1種以上
 Cr、Cu、Ni、MoおよびBは、いずれも鋼材の焼入れ性を向上させることによって最終製品の強度を増加させるのに有効な元素である。必要によって、それらの元素を単独でまたは2種以上で含有してもよい。このような効果は、これら元素の含有量が増加するに従って大きくなる。前記した効果を有効に発揮させるための好ましい含有量は、Cr量が0.015%以上、より好ましくは0.020%以上である。Cu量、Ni量およびMo量の好ましい含有量は、いずれも0.02%以上、より好ましくは0.05%以上である。B量の好ましい含有量は、0.0003%以上、より好ましくは0.0005%以上である。
Cr: more than 0%, 0.5% or less, Cu: more than 0%, 0.25% or less, Ni: more than 0%, 0.25% or less, Mo: more than 0%, 0.25% or less and B: One or more selected from the group consisting of more than 0% and less than 0.01% Cr, Cu, Ni, Mo and B all increase the strength of the final product by improving the hardenability of the steel. It is an effective element. If necessary, these elements may be contained alone or in combination of two or more. Such effects increase as the content of these elements increases. A preferable content for effectively exhibiting the above-described effect is such that the Cr content is 0.015% or more, more preferably 0.020% or more. The preferable contents of Cu, Ni and Mo are all 0.02% or more, more preferably 0.05% or more. The preferable content of B is 0.0003% or more, more preferably 0.0005% or more.

 しかしながら、Cr、Cu、NiおよびMoの含有量が過剰になると、強度が高くなり過ぎて冷間加工性を劣化させるおそれがある。そこで、Cr含有量は0.5%以下が好ましく、Cu、NiおよびMo含有量はいずれも0.25%以下が好ましい。Crのより好ましい含有量は0.45%以下、更に好ましくは0.40%以下である。Cu、NiおよびMoのより好ましい含有量は、いずれも0.22%以下、更に好ましくは0.20%以下である。 However, if the contents of Cr, Cu, Ni and Mo are excessive, the strength becomes too high and the cold workability may be deteriorated. Therefore, the Cr content is preferably 0.5% or less, and the Cu, Ni and Mo contents are preferably 0.25% or less. A more preferable content of Cr is 0.45% or less, and further preferably 0.40% or less. The more preferable contents of Cu, Ni and Mo are all 0.22% or less, more preferably 0.20% or less.

 また、Bの含有量が過剰になると、靭性を劣化させるおそれがある。そこで、B含有量は0.01%以下が好ましい。Bのより好ましい含有量は、0.007%以下、更に好ましくは0.005%以下である。 Also, if the B content is excessive, the toughness may be deteriorated. Therefore, the B content is preferably 0.01% or less. A more preferable content of B is 0.007% or less, more preferably 0.005% or less.

 [Cr%]+[Cu%]+[Ni%]+[Mo%]≦0.75
 本発明の実施形態に係る鋼線は、Cr、Cu、NiおよびMoの1種以上を上述した範囲で含有する場合、下記式(X)を満足することが好ましい。
 [Cr%]+[Cu%]+[Ni%]+[Mo%]≦0.75   (X)
 ここで、[Cr%]、[Cu%]、[Ni%]および[Mo%]は、それぞれ、質量%で示したCr、Cu、NiおよびMoの含有量を示す。
 Cr、Cu、NiおよびMoの合計含有量が上記式(X)を満たすことにより、鋼線の強度が高くなり過ぎることを抑制し、冷間加工性を向上することができる。
[Cr%] + [Cu%] + [Ni%] + [Mo%] ≦ 0.75
When the steel wire which concerns on embodiment of this invention contains 1 or more types of Cr, Cu, Ni, and Mo in the range mentioned above, it is preferable that the following formula (X) is satisfied.
[Cr%] + [Cu%] + [Ni%] + [Mo%] ≦ 0.75 (X)
Here, [Cr%], [Cu%], [Ni%], and [Mo%] respectively indicate the contents of Cr, Cu, Ni, and Mo expressed in mass%.
When the total content of Cr, Cu, Ni and Mo satisfies the above formula (X), it is possible to suppress the strength of the steel wire from becoming too high and improve the cold workability.

 Ti:0%超、0.1%以下
 本発明の実施形態に係る鋼線は、必要に応じて、0%超、0.1%以下の範囲でTiを含有してよい。TiはNと化合物を形成するので、Tiを含有することで固溶Nを低減することができる。そのため、鋼線をより軟質にすることができる。Tiの含有量は、好ましくは0.01%以上、より好ましくは0.02%以上である。一方、Tiの含有量が過剰になると、形成される化合物により、鋼線の硬さが増加するおそれがある。そのため、好ましいTi含有量は0.1%以下であり、より好ましくは0.08%以下、さらに好ましくは0.05%以下である。
Ti: More than 0%, 0.1% or less The steel wire according to the embodiment of the present invention may contain Ti in a range of more than 0% and 0.1% or less, if necessary. Since Ti forms a compound with N, solid solution N can be reduced by containing Ti. Therefore, the steel wire can be made softer. The content of Ti is preferably 0.01% or more, more preferably 0.02% or more. On the other hand, if the Ti content is excessive, the hardness of the steel wire may increase due to the compound formed. Therefore, the preferable Ti content is 0.1% or less, more preferably 0.08% or less, and still more preferably 0.05% or less.

 次に、上述した本発明の実施形態に係る鋼線を製造する方法について説明する。繰返し述べるように本発明の実施形態に係る鋼線は、圧延線材を球状化焼鈍して得られるものである。そのため、球状化焼鈍後の金属組織を上記のように適切に制御するためには、後述する球状化焼鈍条件を適切に制御することが好ましい。但し、球状化焼鈍によって上記の組織形態を確保するためには、更に圧延線材の製造条件(すなわち、圧延条件)も適切に制御することが好ましい。圧延条件の制御により、圧延線材における組織形態を、球状化焼鈍後にbcc-Fe平均粒径を小さくしやすく、且つ、セメンタイトの数密度が低減しやすい状態となるようにすることができる。 Next, a method for manufacturing the steel wire according to the embodiment of the present invention described above will be described. As described repeatedly, the steel wire according to the embodiment of the present invention is obtained by spheroidizing and annealing a rolled wire. Therefore, in order to appropriately control the metal structure after spheroidizing annealing as described above, it is preferable to appropriately control the spheroidizing annealing conditions described later. However, in order to ensure the above-described structure form by spheroidizing annealing, it is preferable to further appropriately control the production conditions (that is, rolling conditions) of the rolled wire rod. By controlling the rolling conditions, the microstructure of the rolled wire can be in a state where the bcc-Fe average particle diameter can be easily reduced and the number density of cementite can be easily reduced after spheroidizing annealing.

 具体的には、上記した成分組成を満足する鋼を、熱間圧延する際の仕上げ圧延温度を調整すると共に、その後の冷却速度を3段階として冷却速度と温度範囲を適切に調整することが好ましい。こうした条件で圧延線材を製造することによって、球状化焼鈍前の金属組織を、パーライトとフェライトを主相とすると共に、結晶粒を微細化させ、且つ初析フェライト結晶粒を等軸化し、パーライトの平均ラメラー間隔を所定以下とすることができる。このような金属組織を有する圧延線材に対し、後述する条件で球状化焼鈍を行うことによって、bcc-Fe平均粒径が適切な範囲に制御され、且つセメンタイトの数密度が適切な範囲に制御された鋼線が得られる。このための圧延線材製造条件は、(a)800℃以上、1000℃以下で仕上げ圧延し、(b)平均冷却速度が7℃/秒以上の第1冷却と、(c)平均冷却速度が1℃/秒以上、5℃/秒以下の第2冷却と、(d)平均冷却速度が前記第2冷却よりも速くかつ5℃/秒以上である第3冷却とを、この順で行い、前記第1冷却の終了と前記第2冷却の開始を700~750℃の範囲内で行い、前記第2冷却の終了と前記第3冷却の開始を600~650℃の範囲内で行い、前記第3冷却の終了を500℃以下にすることが好ましい。 Specifically, it is preferable to adjust the finish rolling temperature at the time of hot rolling the steel that satisfies the above-described component composition, and to appropriately adjust the cooling rate and the temperature range with three subsequent cooling rates. . By producing a rolled wire rod under these conditions, the metal structure before spheroidizing annealing has pearlite and ferrite as the main phase, the crystal grains are refined, and the proeutectoid ferrite crystal grains are equiaxed. The average lamellar interval can be set to a predetermined value or less. By subjecting a rolled wire having such a metal structure to spheroidizing annealing under the conditions described later, the bcc-Fe average particle diameter is controlled to an appropriate range, and the number density of cementite is controlled to an appropriate range. Steel wire is obtained. The rolling wire manufacturing conditions for this are as follows: (a) finish rolling at 800 ° C. or more and 1000 ° C. or less, (b) first cooling with an average cooling rate of 7 ° C./sec or more, and (c) average cooling rate of 1 Second cooling at a rate of not less than 5 ° C / second and not more than 5 ° C / second, and (d) a third cooling having an average cooling rate faster than that of the second cooling and not less than 5 ° C / second in this order, The end of the first cooling and the start of the second cooling are performed within a range of 700 to 750 ° C., the end of the second cooling and the start of the third cooling are performed within a range of 600 to 650 ° C., and the third The end of cooling is preferably set to 500 ° C. or lower.

 以下、工程順に詳しく説明する。 Hereinafter, detailed description will be given in the order of steps.

 まず、熱間圧延時の加熱温度は、生産性、圧延品質を考慮すると800℃以上、1100℃以下が好ましい。 First, the heating temperature during hot rolling is preferably 800 ° C. or higher and 1100 ° C. or lower in consideration of productivity and rolling quality.

(a)仕上げ圧延温度:800℃以上、1000℃以下
 圧延線材の金属組織の結晶粒を微細化させ、球状化焼鈍後の鋼線のbcc-Fe平均粒径を小さくするためには、特に仕上げ圧延温度の上限を適切に制御することが好ましい。仕上げ圧延温度が1000℃を超えると、鋼線のbcc-Fe平均粒径を小さくすることが困難となる。また、仕上げ圧延温度が1000℃を超えると、球状化焼鈍後にアスペクト比の大きなセメンタイトが析出し易くなる場合がある。そのため、仕上げ圧延温度は1000℃以下であることが好ましい。仕上げ圧延温度は、より好ましくは970℃以下であり、更に好ましくは940℃以下である。尚、より好ましい仕上げ圧延温度である970℃以下で仕上げ圧延し、後述する適切な条件の球状化焼鈍をすることにより、球状化焼鈍後のアスペクト比が3.0以下のセメンタイトの数割合を一層高くできる傾向にある。但し、仕上げ圧延温度が800℃未満となると、圧延機の負荷が高くなりすぎる上に、球状化焼鈍後の耐割れ性向上効果もほぼ飽和するため、800℃以上とすることが好ましい。仕上げ圧延温度は、より好ましくは830℃以上であり、更に好ましくは860℃以上である。
(A) Finishing rolling temperature: 800 ° C. or higher and 1000 ° C. or lower In order to refine the crystal grains of the metal structure of the rolled wire rod and reduce the bcc-Fe average grain size of the steel wire after spheroidizing annealing, it is especially finished. It is preferable to appropriately control the upper limit of the rolling temperature. When the finish rolling temperature exceeds 1000 ° C., it becomes difficult to reduce the bcc-Fe average particle diameter of the steel wire. On the other hand, when the finish rolling temperature exceeds 1000 ° C., cementite having a large aspect ratio may be easily precipitated after spheroidizing annealing. Therefore, the finish rolling temperature is preferably 1000 ° C. or less. The finish rolling temperature is more preferably 970 ° C. or less, and further preferably 940 ° C. or less. The number ratio of cementite having an aspect ratio of 3.0 or less after spheroidizing annealing is further increased by performing finish rolling at 970 ° C. or less, which is a more preferable finish rolling temperature, and performing spheroidizing annealing under appropriate conditions described later. It tends to be higher. However, when the finish rolling temperature is less than 800 ° C., the load on the rolling mill becomes too high and the effect of improving crack resistance after spheroidizing annealing is almost saturated. The finish rolling temperature is more preferably 830 ° C. or higher, and further preferably 860 ° C. or higher.

(b)第1冷却
 第1冷却は、仕上げ圧延温度である800℃以上、1000℃以下から開始し、700~750℃の温度範囲で終了する。第1冷却において、冷却速度が遅くなると圧延線材の金属組織の結晶粒が粗大化して、球状化焼鈍後の鋼線のbcc-Fe平均粒径が大きくなるおそれがある。そこで、第1冷却における平均冷却速度を7℃/秒以上とすることが好ましい。第1冷却の平均冷却速度はより好ましくは10℃/秒以上であり、更に好ましくは20℃/秒以上である。第1冷却の平均冷却速度の上限は特に限定されないが、現実的な範囲として200℃/秒以下であることが好ましい。尚、第1冷却における冷却では、平均冷却速度が7℃/秒以上である限り、冷却速度を変化させてもよい。
(B) First cooling The first cooling starts from 800 ° C. or more and 1000 ° C. or less, which is the finish rolling temperature, and ends in the temperature range of 700 to 750 ° C. In the first cooling, when the cooling rate is slow, the crystal grains of the metal structure of the rolled wire are coarsened, and the bcc-Fe average particle diameter of the steel wire after spheroidizing annealing may be increased. Therefore, the average cooling rate in the first cooling is preferably 7 ° C./second or more. The average cooling rate of the first cooling is more preferably 10 ° C./second or more, and further preferably 20 ° C./second or more. The upper limit of the average cooling rate of the first cooling is not particularly limited, but is preferably 200 ° C./second or less as a realistic range. In the cooling in the first cooling, the cooling rate may be changed as long as the average cooling rate is 7 ° C./second or more.

(c)第2冷却
 第2冷却は、700~750℃の温度範囲から開始し、600~650℃の温度範囲で終了する。球状化焼鈍後の鋼線のセメンタイトの数密度を低くするためには、第2冷却において、5℃/秒以下の平均冷却速度で徐冷することが好ましい。これにより、圧延線材のパーライトの平均ラメラー間隔をできるだけ狭くし、球状化焼鈍時にセメンタイトを溶解させやすくして、球状化焼鈍後の鋼線のセメンタイトの数密度を低くすることができる。第2冷却の平均冷却速度はより好ましくは4℃/秒以下であり、更に好ましくは3.5℃/秒以下である。一方、第2冷却における平均冷却速度が遅すぎると、bcc-Fe結晶粒が粗大化して、大角粒界で囲まれたbcc-Fe平均粒径が大きくなり過ぎるおそれがある。そこで、第2冷却における平均冷却速度は1℃/秒以上とするのが好ましい。第2冷却の平均冷却速度は、より好ましくは2℃/秒以上であり、更に好ましくは2.5℃/秒以上である。尚、第2冷却における冷却では、平均冷却速度が1℃/秒以上、5℃/秒以下である限り、冷却速度を変化させてもよい。
(C) Second cooling The second cooling starts from a temperature range of 700 to 750 ° C. and ends in a temperature range of 600 to 650 ° C. In order to reduce the number density of cementite in the steel wire after spheroidizing annealing, it is preferable to perform slow cooling at an average cooling rate of 5 ° C./second or less in the second cooling. Thereby, the average lamellar interval of the pearlite of a rolled wire rod can be made as narrow as possible, and the cementite can be easily dissolved during spheroidizing annealing, and the number density of cementite in the steel wire after spheroidizing annealing can be lowered. The average cooling rate of the second cooling is more preferably 4 ° C./second or less, and further preferably 3.5 ° C./second or less. On the other hand, if the average cooling rate in the second cooling is too slow, the bcc-Fe crystal grains are coarsened, and the average bcc-Fe grain size surrounded by the large-angle grain boundaries may be too large. Therefore, the average cooling rate in the second cooling is preferably 1 ° C./second or more. The average cooling rate of the second cooling is more preferably 2 ° C./second or more, and further preferably 2.5 ° C./second or more. In the cooling in the second cooling, the cooling rate may be changed as long as the average cooling rate is 1 ° C./second or more and 5 ° C./second or less.

(d)第3冷却
 この第3冷却では、圧延線材のパーライトの平均ラメラー間隔をできるだけ狭くし、球状化焼鈍時にセメンタイトを溶解させやすくし、粒内に球状セメンタイトの核を残さないようにする(すなわち、粒内に残存する球状セメンタイトの核の数密度を少なくする)。第3冷却は、600~650℃の温度範囲から開始し、500℃以下で終了する。圧延線材のパーライトの平均ラメラー間隔を狭くするためには第3冷却において、第2冷却よりも速く、且つ5℃/秒以上の平均冷却速度で冷却することが好ましい。5℃/秒より遅い冷却であると圧延線材のパーライトの平均ラメラー間隔を狭くし難くなる。第3冷却の平均冷却速度はより好ましくは10℃/秒以上であり、更に好ましくは20℃/秒以上である。尚、第3冷却の平均冷却速度の上限は特に限定されないが、現実的な範囲として200℃/秒以下であることが好ましい。また、第3冷却では、平均冷却速度が5℃/秒以上である限り、冷却速度を変化させてもよい。第3冷却の終了温度の下限は特に限定されないが、例えば200℃以上である。
(D) Third Cooling In this third cooling, the average lamellar spacing of the pearlite of the rolled wire rod is made as narrow as possible, the cementite is easily dissolved during spheroidizing annealing, and no spherical cementite nuclei are left in the grains ( That is, the number density of spherical cementite nuclei remaining in the grains is reduced). The third cooling starts from a temperature range of 600 to 650 ° C. and ends at 500 ° C. or less. In order to reduce the average lamellar spacing of the pearlite of the rolled wire rod, it is preferable that the third cooling is faster than the second cooling and at an average cooling rate of 5 ° C./second or more. Cooling slower than 5 ° C./second makes it difficult to narrow the average lamellar spacing of the pearlite of the rolled wire rod. The average cooling rate of the third cooling is more preferably 10 ° C./second or more, and further preferably 20 ° C./second or more. The upper limit of the average cooling rate of the third cooling is not particularly limited, but is preferably 200 ° C./second or less as a practical range. In the third cooling, the cooling rate may be changed as long as the average cooling rate is 5 ° C./second or more. Although the minimum of the completion | finish temperature of 3rd cooling is not specifically limited, For example, it is 200 degreeC or more.

 第3冷却を行った後は、放冷などの通常の冷却を行って室温まで冷却すればよい。一般には、放冷の平均冷却速度は、第3冷却の平均冷却速度より遅くなることが多い。 After the third cooling, normal cooling such as cooling is performed to cool to room temperature. In general, the average cooling rate of cooling is often slower than the average cooling rate of the third cooling.

 室温まで冷却した後は、必要に応じて更に室温で伸線加工を行ってもよく、その際の減面率は例えば30%以下とすればよい。伸線すると、鋼中の炭化物が破壊され、その後の球状化焼鈍で炭化物の凝集を促進できるため、球状化焼鈍の時間の短縮および、セメンタイトの球状化促進に有効である。但し、伸線加工の減面率が30%を超えると、焼鈍後の強度が高くなり冷間加工性を劣化させるおそれがあるので、伸線加工の減面率は30%以下が好ましい。尚、減面率の下限は特に限定されないが、好ましくは2%以上とすることで効果が得られる。 After cooling to room temperature, wire drawing may be performed at room temperature as necessary, and the area reduction rate at that time may be, for example, 30% or less. When the wire is drawn, the carbides in the steel are destroyed, and the agglomeration of the carbides can be promoted by the subsequent spheroidizing annealing. However, if the area reduction ratio of the wire drawing process exceeds 30%, the strength after annealing increases and the cold workability may be deteriorated. Therefore, the area reduction ratio of the wire drawing process is preferably 30% or less. The lower limit of the area reduction rate is not particularly limited, but the effect is preferably obtained by setting it to 2% or more.

 上記のような好ましい条件で製造された圧延線材に施す球状化焼鈍条件として、例えば後記するSA1のように、大気炉にて、室温から740℃まで加熱する際に、少なくとも500℃から740℃までは平均加熱速度50℃/時以上で加熱し、その後平均加熱速度2~5℃/時で750℃まで加熱し、750℃で10~60分保持した後、平均冷却速度20℃/時以上で720℃まで冷却し、平均冷却速度3~7℃/時で700℃まで冷却し、平均冷却速度8~12℃/時で640℃まで冷却し、その後放冷することが好ましい。但し、本発明の実施形態に用いられる球状化焼鈍条件は、これに限定されない。 As a spheroidizing annealing condition to be applied to a rolled wire manufactured under the preferable conditions as described above, for example, when heating from room temperature to 740 ° C. in an atmospheric furnace as SA1 described later, at least from 500 ° C. to 740 ° C. Is heated at an average heating rate of 50 ° C / hour or more, then heated to 750 ° C at an average heating rate of 2 to 5 ° C / hour, held at 750 ° C for 10 to 60 minutes, and then at an average cooling rate of 20 ° C / hour or more. It is preferably cooled to 720 ° C., cooled to 700 ° C. at an average cooling rate of 3 to 7 ° C./hour, cooled to 640 ° C. at an average cooling rate of 8 to 12 ° C./hour, and then allowed to cool. However, the spheroidizing annealing condition used in the embodiment of the present invention is not limited to this.

 上記の球状化焼鈍条件において、室温から740℃まで加熱する際に、少なくとも500℃から740℃までの平均加熱速度を50℃/時以上とすることで、金属組織の粒成長を抑制する。このときの平均加熱速度は、より好ましくは60℃/時以上である。しかしながら、平均加熱速度が速すぎると圧延線材の温度追従が困難となるため、200℃/時以下とすることが好ましく、より好ましくは150℃/時以下である。 In the above spheroidizing annealing condition, when heating from room temperature to 740 ° C., the average heating rate from at least 500 ° C. to 740 ° C. is set to 50 ° C./hour or more, thereby suppressing the grain growth of the metal structure. The average heating rate at this time is more preferably 60 ° C./hour or more. However, if the average heating rate is too high, it becomes difficult to follow the temperature of the rolled wire, and therefore it is preferably 200 ° C./hour or less, more preferably 150 ° C./hour or less.

 またA1点直上の740℃から750℃までの平均加熱速度を2~5℃/時に制御することにより、金属組織の粒成長を極力抑えながら、パーライト組織中のセメンタイトの分解・固溶を十分に行うことができる。平均加熱速度が5℃/時よりも速い場合は、パーライト組織中のセメンタイトの分解・固溶に十分な時間の確保が難しく、平均加熱速度が2℃/時よりも遅い場合は、740℃から750℃までの加熱時間が長くなり、金属組織の粒成長を抑制することが困難となる。このときの平均加熱速度は、より好ましくは3℃/時以上、4℃/時以下である。 In addition, by controlling the average heating rate from 740 ° C to 750 ° C immediately above the A1 point at 2-5 ° C / hour, the decomposition and solid solution of cementite in the pearlite structure is sufficiently suppressed while suppressing the grain growth of the metal structure as much as possible. It can be carried out. When the average heating rate is higher than 5 ° C / hour, it is difficult to secure a sufficient time for decomposition and solid solution of cementite in the pearlite structure, and from 740 ° C when the average heating rate is lower than 2 ° C / hour. The heating time up to 750 ° C. becomes longer, and it becomes difficult to suppress the grain growth of the metal structure. The average heating rate at this time is more preferably 3 ° C./hour or more and 4 ° C./hour or less.

 750℃では、10~60分保持することが好ましい。この保持温度が10分よりも短くなると、パーライト組織中のセメンタイトの分解・固溶が不十分であり、60分よりも長くなると、金属組織の粒成長を抑制することが困難となる。このときの保持時間は、より好ましくは20分以上、50分以下である。 It is preferable to hold at 750 ° C. for 10 to 60 minutes. When this holding temperature is shorter than 10 minutes, decomposition and solid solution of cementite in the pearlite structure is insufficient, and when it is longer than 60 minutes, it becomes difficult to suppress grain growth of the metal structure. The holding time at this time is more preferably 20 minutes or more and 50 minutes or less.

 上記のような保持を行なった後、720℃までの好ましい平均冷却速度を20℃/時以上とすることで、金属組織の粒成長を抑制できる。このときの平均冷却速度は、より好ましくは30℃/時以上であるが、平均冷却速度が速すぎると圧延線材の温度追従が困難となるため、100℃/時以下とすることが好ましい。 After holding as described above, by setting the preferable average cooling rate up to 720 ° C. to 20 ° C./hour or more, grain growth of the metal structure can be suppressed. The average cooling rate at this time is more preferably 30 ° C./hour or more. However, if the average cooling rate is too high, it becomes difficult to follow the temperature of the rolled wire, and therefore it is preferably 100 ° C./hour or less.

 その後、720℃から700℃までの平均冷却速度を3~7℃/時に制御することにより、再析出するセメンタイトの数を制御し、セメンタイトを粗大化させることができる。平均冷却速度が3℃/時よりも遅い場合は、金属組織の粒成長の抑制が困難となり、平均冷却度が7℃/時よりも速い場合は、再析出するセメンタイトの数が多くなる。このときの平均冷却速度は、より好ましくは4℃/時以上、6℃/時以下である。 Thereafter, by controlling the average cooling rate from 720 ° C. to 700 ° C. at 3 to 7 ° C./hour, the number of re-deposited cementite can be controlled and the cementite can be coarsened. When the average cooling rate is slower than 3 ° C./hour, it is difficult to suppress the grain growth of the metal structure, and when the average cooling rate is higher than 7 ° C./hour, the number of cementite to be reprecipitated increases. The average cooling rate at this time is more preferably 4 ° C./hour or more and 6 ° C./hour or less.

 その後、700℃から640℃までの平均冷却速度を8~12℃/時に制御することにより、パーライト組織のようなアスペクト比の大きなセメンタイトの析出を抑制することができる。平均冷却速度が8℃/時よりも遅い場合は、金属組織の粒成長の抑制が困難となり、平均冷却度が12℃/時よりも速い場合は、パーライト組織のようなアスペクト比の大きなセメンタイトが多く再析出する。このときの平均冷却速度は、より好ましくは9℃/時以上、11℃/時以下である。 Thereafter, by controlling the average cooling rate from 700 ° C. to 640 ° C. at 8 to 12 ° C./hour, precipitation of cementite having a large aspect ratio such as a pearlite structure can be suppressed. When the average cooling rate is lower than 8 ° C./hour, it is difficult to suppress the grain growth of the metal structure, and when the average cooling rate is higher than 12 ° C./hour, cementite with a large aspect ratio such as a pearlite structure is formed. Reprecipitates a lot. The average cooling rate at this time is more preferably 9 ° C./hour or more and 11 ° C./hour or less.

 640℃まで冷却を行った後は、放冷などの通常の冷却を行って室温まで冷却すればよい。一般には、放冷の平均冷却速度は、700℃から640℃までの平均冷却速度より遅くなることが多い。 After cooling to 640 ° C., normal cooling such as cooling may be performed to cool to room temperature. In general, the average cooling rate for cooling is often slower than the average cooling rate from 700 ° C to 640 ° C.

 上記のような球状化焼鈍は、複数回繰り返し行ってもよい。こうした繰り返しを行うことによって、セメンタイトの個々のアスペクト比が小さくなり、セメンタイトの数密度が低くなる。このときの繰り返し回数については、少なくとも3回以上であることが好ましい。過度に繰り返してもセメンタイトの数密度があまり変化しなくなるので、10回以下であることが好ましい。尚、球状化焼鈍を複数回繰り返すに際して、上記の好ましい条件の範囲内で、同じ条件で繰り返してもよく、異なる条件で繰り返してもよい。 The spheroidizing annealing as described above may be repeated a plurality of times. By performing such repetition, the individual aspect ratio of cementite becomes small, and the number density of cementite becomes low. The number of repetitions at this time is preferably at least 3 times. Since the number density of cementite does not change so much even if it is excessively repeated, it is preferably 10 times or less. When the spheroidizing annealing is repeated a plurality of times, it may be repeated under the same conditions or within different conditions within the range of the above preferable conditions.

 以下、実施例を挙げて本発明の実施形態をより具体的に説明する。本発明の実施形態は以下の実施例によって制限を受けるものではなく、前記、後記の趣旨に適合し得る範囲で適当に変更を加えて実施することも勿論可能であり、それらはいずれも本発明の実施形態の技術的範囲に包含される。 Hereinafter, embodiments of the present invention will be described more specifically with reference to examples. Embodiments of the present invention are not limited by the following examples, and can be implemented with appropriate modifications within a range that can be adapted to the gist described above. It is included in the technical scope of the embodiment.

 下記表1に示す化学成分組成の鋼を用い、下記表2に示す各種加工条件にて圧延を行い、φ17.0mmの線材を作製した。なお、鋼種A~TおよびV~Xは、「第3冷却」の終了温度を450℃とし、その後、室温まで放冷した。 Using steel having the chemical composition shown in Table 1 below, rolling was performed under various processing conditions shown in Table 2 below to produce a wire having a diameter of 17.0 mm. For steel types A to T and V to X, the end temperature of “third cooling” was set to 450 ° C., and then allowed to cool to room temperature.

 鋼種O、Pは化学成分組成が規定値から外れる比較例である。また、鋼種Q、R、S、T、Uは、本発明の実施形態における適切な製造条件で圧延線材を製造しなかった例である。即ち、鋼種Q、T、Uは、仕上げ圧延温度が高い条件で圧延線材を製造した例であり、鋼種S、Uは、第2冷却速度が速い条件で圧延線材を製造した例であり、鋼種Rは、第1冷却速度および第3冷却速度が遅い条件で圧延線材を製造した例である。
 また、鋼種B、E、H、I、K、L、P、Q、VおよびWは、Cr、Cu、Ni、MoおよびBのいずれかを1種以上含有する例である。下記表1に示すように、これらの鋼種のうち、Pを除く全ての鋼種は、[Cr%]+[Cu%]+[Ni%]+[Mo%]が0.75質量%以下であり、上述の式(X)を満たしている。鋼種Pでは、[Cr%]+[Cu%]+[Ni%]+[Mo%]が0.75質量%を超えており、式(X)を満たさない。
Steel types O and P are comparative examples in which the chemical composition deviates from the specified value. Steel types Q, R, S, T, and U are examples in which a rolled wire was not manufactured under appropriate manufacturing conditions in the embodiment of the present invention. That is, steel types Q, T, and U are examples in which rolled wire rods are manufactured under conditions with a high finish rolling temperature, and steel types S and U are examples in which rolled wire rods are manufactured under conditions where the second cooling rate is high. R is an example in which a rolled wire was manufactured under conditions where the first cooling rate and the third cooling rate were slow.
Steel types B, E, H, I, K, L, P, Q, V, and W are examples containing at least one of Cr, Cu, Ni, Mo, and B. As shown in Table 1 below, among these steel types, all the steel types except P have [Cr%] + [Cu%] + [Ni%] + [Mo%] of 0.75 mass% or less. The above-described formula (X) is satisfied. In the steel type P, [Cr%] + [Cu%] + [Ni%] + [Mo%] exceeds 0.75 mass% and does not satisfy the formula (X).

 鋼種Uでは、550℃まで第2冷却を行った後、580℃で120秒保持する保持工程を行い、その後、室温まで放冷し、減面率40%の伸線加工工程を行った。 In steel type U, after the second cooling to 550 ° C., a holding step of holding at 580 ° C. for 120 seconds was performed, and then the mixture was allowed to cool to room temperature, and a wire drawing step with a surface reduction rate of 40% was performed.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

 次に、鋼種Uを除いた夫々の圧延線材に対し、大気炉にて、下記(a)から(c)のいずれかの球状化焼鈍を行った。
(a)室温から740℃まで加熱するに際し、室温から500℃までを平均加熱速度100℃/時で、500℃から740℃までを平均加熱速度80℃/時で加熱した後、平均加熱温度4℃/時で750℃まで加熱し、750℃で30分保持した後、平均冷却速度30℃/時で720℃まで冷却し、次いで平均冷却速度5℃/時で700℃まで冷却し、平均冷却速度10℃/時で640℃まで冷却した後、放冷する。以下、この焼鈍条件を「SA1」と略記する。
(b)上記SA1を5回繰り返す。尚、SA2の2回目以降の加熱(すなわち、SA1を5回繰り返すSA2の焼鈍において、2~5回目のSA1条件の焼鈍の際の加熱)は、640℃から開始した。以下、この焼鈍条件を「SA2」と略記する。
(c)室温から710℃まで加熱するに際し、室温から500℃までを平均加熱速度100℃/時で、500℃から710℃までを平均加熱速度80℃/時で加熱し、710℃で5時間保持した後、平均冷却速度10℃/時で640℃まで冷却し、その後放冷する。以下、この焼鈍条件を「SA3」と略記する。
 ここで、上記焼鈍条件SA1、SA2は本発明の実施形態の好ましい焼鈍条件であり、上記焼鈍条件SA3は加熱温度(保持温度)が低く、適切に制御されていない例である。
Next, spheroidizing annealing of any of the following (a) to (c) was performed on each rolled wire rod excluding the steel type U in an atmospheric furnace.
(A) When heating from room temperature to 740 ° C., after heating from room temperature to 500 ° C. at an average heating rate of 100 ° C./hour and from 500 ° C. to 740 ° C. at an average heating rate of 80 ° C./hour, an average heating temperature of 4 After heating to 750 ° C./hour and holding at 750 ° C. for 30 minutes, cooling to 720 ° C. at an average cooling rate of 30 ° C./hour, then cooling to 700 ° C. at an average cooling rate of 5 ° C./hour, average cooling After cooling to 640 ° C. at a rate of 10 ° C./hour, it is allowed to cool. Hereinafter, this annealing condition is abbreviated as “SA1”.
(B) Repeat SA1 five times. Note that the second and subsequent heating of SA2 (that is, the heating during the annealing of the second to fifth SA1 conditions in the annealing of SA2 that repeats SA1 five times) started at 640 ° C. Hereinafter, this annealing condition is abbreviated as “SA2”.
(C) When heating from room temperature to 710 ° C., heating from room temperature to 500 ° C. at an average heating rate of 100 ° C./hour, heating from 500 ° C. to 710 ° C. at an average heating rate of 80 ° C./hour, and 710 ° C. for 5 hours After being held, it is cooled to 640 ° C. at an average cooling rate of 10 ° C./hour, and then allowed to cool. Hereinafter, this annealing condition is abbreviated as “SA3”.
Here, the annealing conditions SA1 and SA2 are preferable annealing conditions of the embodiment of the present invention, and the annealing condition SA3 is an example in which the heating temperature (holding temperature) is low and not properly controlled.

 尚、鋼種Uに対しては、大気炉にて、下記(d)または(e)のいずれかの球状化焼鈍を行った。
(d)平均加熱速度80℃/時で室温から680℃まで加熱し、680℃で5時間保持した後、平均冷却速度10℃/時で640℃まで冷却し、その後放冷する。以下、この焼鈍条件を「SA4」と略記する。
(e)平均加熱速度80℃/時で室温から700℃まで加熱し、700℃で5時間保持した後、平均冷却速度10℃/時で640℃まで冷却し、その後放冷する。以下、この焼鈍条件を「SA5」と略記する。
 ここで、上記焼鈍条件SA4、SA5は、加熱温度(保持温度)が低く、適切に制御されていない例である。
The steel type U was subjected to spheroidizing annealing of either (d) or (e) below in an atmospheric furnace.
(D) Heat from room temperature to 680 ° C. at an average heating rate of 80 ° C./hour, hold at 680 ° C. for 5 hours, cool to 640 ° C. at an average cooling rate of 10 ° C./hour, and then cool. Hereinafter, this annealing condition is abbreviated as “SA4”.
(E) Heat from room temperature to 700 ° C. at an average heating rate of 80 ° C./hour, hold at 700 ° C. for 5 hours, cool to 640 ° C. at an average cooling rate of 10 ° C./hour, and then cool. Hereinafter, this annealing condition is abbreviated as “SA5”.
Here, the annealing conditions SA4 and SA5 are examples in which the heating temperature (holding temperature) is low and not properly controlled.

 上記の球状化焼鈍を行った後の鋼線について、(1)フェライトとセメンタイトの合計面積率、(2)金属組織のbcc-Fe平均粒径、(3)25μm当たりのセメンタイトの個数、(4)アスペクト比3.0以下のセメンタイト割合、(5)冷間加工時の変形抵抗、(6)冷間加工時の割れ発生率を、下記の方法によって測定した。 For the steel wire after the spheroidizing annealing, (1) the total area ratio of ferrite and cementite, (2) the bcc-Fe average particle diameter of the metal structure, (3) the number of cementite per 25 μm 2 , ( 4) The ratio of cementite having an aspect ratio of 3.0 or less, (5) deformation resistance during cold working, and (6) crack occurrence rate during cold working were measured by the following methods.

 尚、球状化焼鈍後の鋼線のフェライトとセメンタイトの合計面積率、bcc-Fe結晶粒径、セメンタイトの数密度、およびセメンタイトの数割合の測定に当たっては、横断面(すなわち、線材の径方向に切断した断面)が観察できるように樹脂埋めし、エメリー紙、ダイヤモンドバフによって切断面を鏡面研磨した。鋼線の直径Dに対し、鋼線の外周面から径方向にD/4の位置を測定した。 In measuring the total area ratio of ferrite and cementite, bcc-Fe crystal grain size, number density of cementite, and number ratio of cementite in the steel wire after spheroidizing annealing, the cross section (that is, in the radial direction of the wire) The resin was embedded so that the cut cross-section could be observed, and the cut surface was mirror-polished with emery paper and diamond buff. With respect to the diameter D of the steel wire, the position of D / 4 was measured in the radial direction from the outer peripheral surface of the steel wire.

(1)フェライトとセメンタイトの合計面積率の測定
 フェライトとセメンタイトの合計面積率の測定は、ピクラールエッチングによってセメンタイトを出現させ、FE-SEM(Field-Emission ScanningElectron Microscope、電界放出型走査電子顕微鏡)にて組織観察を行い、倍率2000倍にて60μm×45μmの領域を5視野撮影した。それらの写真上に、縦方向、横方向に3μm毎のメッシュ線を入れ、フェライトもしくはセメンタイト上に存在するメッシュ線の交点の数を測定した。フェライトもしくはセメンタイト上に存在するメッシュ線の交点の数を、すべてのメッシュ線の交点の数で割った値をフェライトとセメンタイトの合計面積率として算出した。
(1) Measurement of the total area ratio of ferrite and cementite The measurement of the total area ratio of ferrite and cementite was performed by making cementite appear by picral etching, and using FE-SEM (Field-Emission Scanning Electron Microscope, field emission scanning electron microscope). The tissue was observed, and a 60 μm × 45 μm region was photographed at 5 magnifications at a magnification of 2000 times. On these photographs, mesh lines every 3 μm were put in the vertical direction and the horizontal direction, and the number of intersections of the mesh lines existing on the ferrite or cementite was measured. A value obtained by dividing the number of intersections of mesh lines existing on ferrite or cementite by the number of intersections of all mesh lines was calculated as the total area ratio of ferrite and cementite.

(2)bcc-Fe平均粒径の測定
 bcc-Fe結晶粒径の測定は、EBSP解析装置およびFE-SEMを用いて測定した。解析ツールには、株式会社TSLソリューションズのOIMソフトウェアを用いた。結晶方位差(これを「斜角」とも呼ぶ)が15°を超える境界、即ち大角粒界を結晶粒界として「結晶粒」を定義し、bcc-Fe結晶粒の面積を円に換算したときの直径の平均値、即ち平均円相当直径を算出した。このときの測定領域は200μm×400μm、測定ステップは1.0μm間隔とした。測定方位の信頼性を示すコンフィデンス・インデックス(Confidence Index)が0.1以下の測定点は解析対象から削除(すなわち、除外)した。
(2) Measurement of bcc-Fe average particle diameter The bcc-Fe crystal grain diameter was measured using an EBSP analyzer and an FE-SEM. As an analysis tool, OIM software of TSL Solutions Inc. was used. When the crystal grain difference is defined as a boundary where the crystal orientation difference (also referred to as “bevel”) exceeds 15 °, that is, a large-angle grain boundary, and the area of the bcc-Fe crystal grain is converted into a circle The average value of the diameters, that is, the average equivalent circle diameter was calculated. The measurement area at this time was 200 μm × 400 μm, and the measurement step was 1.0 μm. Measurement points having a confidence index (Confidence Index) indicating the reliability of the measurement direction of 0.1 or less were deleted (ie, excluded) from the analysis target.

(3)25μm当たりのセメンタイトの個数
 25μm当たりのセメンタイトの個数の測定においては、ピクラールエッチングによってセメンタイトを出現させ、FE-SEMにて組織観察を行い、倍率4000倍にて29μm×22μmの領域を5視野撮影した。それらの写真を元に、画像解析(MediaCybernetics,Inc.製「Image-Pro Plus」(商品名))によって、写真内の全セメンタイトの個数を測定し、5視野における、セメンタイトの個数の平均値を求めた。写真内にセメンタイトの全体が写っているものを1個、セメンタイトの一部が写真内に写っていないものを0.5個として、セメンタイトの個数を測定した。その平均値から、単位面積を25μmとし、セメンタイトの数密度を算出した。測定するセメンタイトの最小の円相当直径は0.1μmとした。
(3) Number of cementite per 25 μm 2 In the measurement of the number of cementite per 25 μm 2 , cementite appeared by picral etching, and the structure was observed with FE-SEM, and 29 μm × 22 μm at a magnification of 4000 times. The field was photographed with 5 fields of view. Based on these photographs, the number of all cementite in the photograph was measured by image analysis (“Image-Pro Plus” (trade name) manufactured by Media Cybernetics, Inc.), and the average value of the number of cementite in the five fields of view was determined. Asked. The number of cementite was measured with one piece showing the entire cementite in the photo and 0.5 piece containing no cementite in the photo. From the average value, the unit area was 25 μm 2 and the number density of cementite was calculated. The minimum equivalent circle diameter of the cementite to be measured was 0.1 μm.

(4)アスペクト比3.0以下のセメンタイト割合
 アスペクト比3.0以下のセメンタイト割合の測定においては、上記(3)で撮影した写真を元に測定を行った。具体的には、画像解析によって、5つの写真内の全セメンタイトのアスペクト比を測定し、5視野における、全セメンタイト数に対する、アスペクト比3.0以下のセメンタイト数の割合の平均値を求めた。全セメンタイト及びアスペクト比3.0以下のセメンタイトは、写真内にセメンタイトの全体が写っているものを対象とし、セメンタイトの一部が写真内に写っていないものは対象としなかった。その平均値から、アスペクト比3.0以下のセメンタイト割合を算出した。測定するセメンタイトの最小の円相当直径は0.1μmとした。
(4) Cementite ratio with an aspect ratio of 3.0 or less In measuring the cementite ratio with an aspect ratio of 3.0 or less, the measurement was performed based on the photograph taken in (3) above. Specifically, the aspect ratios of all cementites in the five photographs were measured by image analysis, and the average value of the ratios of the number of cementites having an aspect ratio of 3.0 or less to the total number of cementites in the five visual fields was determined. The total cementite and the cementite with an aspect ratio of 3.0 or less were targeted for those in which the entire cementite was shown in the photograph, and those that were not partially visible in the photograph. From the average value, a cementite ratio with an aspect ratio of 3.0 or less was calculated. The minimum equivalent circle diameter of the cementite to be measured was 0.1 μm.

(5)変形抵抗の測定
 鋼線から、φ10.0mm×15.0mmの冷間鍛造試験用サンプルを作製し、鍛造プレスを用い、室温にて、ひずみ速度5/秒~10/秒で、加工率60%の冷間鍛造試験を5回ずつ行った。変形抵抗の測定は、60%加工率の冷間鍛造試験から得られた加工率-変形抵抗のデータから、40%加工時の変形抵抗を5回測定し、5回の平均値を求めた。尚、C、Si及びMn含有量によって、求められる変形抵抗が異なるため、目標とする変形抵抗(表3内では「目標変形抵抗」と記載。)を下記式(1)とした。
 目標変形抵抗=400×Ceq+430 ・・・(1)
 ただし、Ceq=[C%]+0.2×[Si%]+0.2×[Mn%]であり、[C%]、[Si%]及び[Mn%]は、それぞれC、Si及びMnの含有量(質量%)を示す。
(5) Measurement of deformation resistance A sample for cold forging test of φ10.0 mm x 15.0 mm was prepared from a steel wire and processed at a strain rate of 5 / sec to 10 / sec at room temperature using a forging press. A cold forging test at a rate of 60% was performed five times. The deformation resistance was measured by measuring the deformation resistance at 40% processing 5 times from the data of the processing rate-deformation resistance obtained from the cold forging test at the 60% processing rate, and obtaining the average value of 5 times. Since the required deformation resistance differs depending on the contents of C, Si and Mn, the target deformation resistance (described as “target deformation resistance” in Table 3) was defined by the following formula (1).
Target deformation resistance = 400 × Ceq + 430 (1)
However, Ceq = [C%] + 0.2 × [Si%] + 0.2 × [Mn%], and [C%], [Si%] and [Mn%] are C, Si and Mn, respectively. Content (mass%) is shown.

(6)割れ発生率の測定
 割れ発生率の測定は、上記(5)と同じ条件で加工率60%の冷間鍛造試験後、夫々のサンプルについて、実体顕微鏡にて倍率20倍で表面観察を5回行い、表面割れの有無を測定した。そして、「表面割れを有するサンプル数」を5で除すことにより、その平均を求めた。全ての鋼種における目標とする割れ発生率は、20%以下とした。
(6) Measurement of crack occurrence rate The crack occurrence rate was measured by performing a cold forging test with a processing rate of 60% under the same conditions as in (5) above, and observing the surface of each sample with a stereomicroscope at a magnification of 20 times. It was performed 5 times and the presence or absence of surface cracks was measured. Then, the “number of samples having surface cracks” was divided by 5 to obtain the average. The target crack generation rate for all steel types was 20% or less.

 これらの結果を、球状化焼鈍条件と共に下記表3に示す。尚、表3の総合評価の欄には、変形抵抗の低減および耐割れ性向上のいずれも良好である例は「OK」と表示し、変形抵抗の低減および耐割れ性向上の少なくともいずれかが劣化している例は「NG」と表示した。 These results are shown in Table 3 below together with the spheroidizing annealing conditions. In the overall evaluation column of Table 3, an example in which both the reduction in deformation resistance and the improvement in crack resistance are good is indicated as “OK”, and at least one of the reduction in deformation resistance and the improvement in crack resistance is indicated. An example of deterioration is indicated as “NG”.

Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

 表3の結果より、次のように考察できる。 From the results in Table 3, it can be considered as follows.

 まず、表3の試験No.1、2、4~8、10、11、13~16、18~20、22~25、37、38、40および41は、本発明の実施形態で規定する要件の全てを満足する実施例であり、変形抵抗の低減および耐割れ性向上が共に達成されていることが分かる。なお、表3には記載していないが、試験No.1~36における金属組織をFE-SEM観察すると、全てフェライトとセメンタイトを合計で99面積%以上の比率で含有していることを確認している。 First, test no. 1, 2, 4 to 8, 10, 11, 13 to 16, 18 to 20, 22 to 25, 37, 38, 40, and 41 are examples that satisfy all of the requirements defined in the embodiments of the present invention. It can be seen that both a reduction in deformation resistance and an improvement in crack resistance are achieved. Although not shown in Table 3, test no. FE-SEM observation of the metal structures 1 to 36 confirms that all contain ferrite and cementite in a total ratio of 99 area% or more.

 ここで、SA1、SA2の焼鈍条件の両方を行った試験No.1および2(鋼種A)、試験No.7および8(鋼種E)、試験No.10および11(鋼種F)、試験No.15および16(鋼種I)、試験No.19および20(鋼種K)、試験No.24および25(鋼種N)、ならびに試験No.37および38(鋼種V)に着目すると、いずれの場合もSA1と比べてSA1を5回繰り返すSA2の焼鈍を行うと、変形抵抗および割れ発生率の少なくとも一方がより低減した。 Here, the test No. which performed both SA1 and SA2 annealing conditions. 1 and 2 (steel type A), test no. 7 and 8 (steel type E), test no. 10 and 11 (steel type F), test no. 15 and 16 (steel type I), test no. 19 and 20 (steel grade K), test no. 24 and 25 (steel grade N), and test no. Focusing on 37 and 38 (steel type V), in any case, when annealing SA2 was repeated 5 times compared to SA1, at least one of deformation resistance and crack generation rate was further reduced.

 このうち、試験No.11(鋼種F)は、更にアスペクト比が3.0以下のセメンタイトの数割合が本発明の実施形態の好ましい要件を満足する例である。そのため、セメンタイトの数割合が適切に制御されていない試験No.10(鋼種F)に比べて、割れ発生率が一層低減した。 Of these, test no. 11 (steel type F) is an example in which the number ratio of cementite having an aspect ratio of 3.0 or less satisfies the preferable requirements of the embodiment of the present invention. Therefore, the test No. in which the number ratio of cementite is not properly controlled. Compared to 10 (steel type F), the crack generation rate was further reduced.

 これに対し、試験No.3、9、12、17、21、26~36および39は、本発明の実施形態で規定する要件のいずれかを欠く比較例であり、変形抵抗、割れ発生率のいずれか、または両方が目標値に達していないことが分かる。 In contrast, test no. 3, 9, 12, 17, 21, 26 to 36 and 39 are comparative examples lacking any of the requirements defined in the embodiments of the present invention, and target is either deformation resistance, crack generation rate, or both. It can be seen that the value has not been reached.

 試験No.3は、表1および2の鋼種Aを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗、および割れ発生率が目標値に達していない。 Test No. 3 is an example in which spheroidizing annealing was performed using SA3 whose conditions were not appropriate using steel type A in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.

 試験No.9は、表1および2の鋼種Eを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗が目標値に達していない。 Test No. No. 9 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using steel type E in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance does not reach the target value.

 試験No.12は、表1および2の鋼種Fを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗、および割れ発生率が目標値に達していない。 Test No. No. 12 is an example in which spheroidizing annealing was performed with SA3 whose conditions were not appropriate using the steel type F in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.

 試験No.17は、表1および2の鋼種Iを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗、および割れ発生率が目標値に達していない。 Test No. No. 17 is an example in which spheroidizing annealing was performed using SA3 whose conditions were not appropriate using steel type I in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.

 試験No.21は、表1および2の鋼種Kを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗が目標値に達していない。 Test No. No. 21 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using the steel type K shown in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance does not reach the target value.

 試験No.26は、表1および2の鋼種Nを用い、条件が適切でないSA3で球状化焼鈍を行った例である。そのため、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗、および割れ発生率が目標値に達していない。 Test No. No. 26 is an example in which spheroidizing annealing was performed with SA3 whose conditions were not appropriate using the steel type N in Tables 1 and 2. Therefore, the number of cementite per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate do not reach the target values.

 試験No.27は、Mn含有量が過剰な表1および2の鋼種Oを用いた例である。そのため、適切な熱間圧延およびSA1の球状化焼鈍を行ったが、変形抵抗が目標値に達していない。 Test No. 27 is an example using the steel type O of Tables 1 and 2 with an excessive Mn content. For this reason, appropriate hot rolling and spheroidizing annealing of SA1 were performed, but the deformation resistance did not reach the target value.

 試験No.28は、Mn含有量が過剰な表1および2の鋼種Oを用いた例である。そのため、適切な熱間圧延およびSA2の球状化焼鈍を行ったが、変形抵抗が目標値に達していない。 Test No. No. 28 is an example using the steel type O in Tables 1 and 2 with an excessive Mn content. Therefore, although appropriate hot rolling and spheroidizing annealing of SA2 were performed, the deformation resistance did not reach the target value.

 試験No.29は、Cr含有量が過剰な表1および2の鋼種Pを用いた例である。そのため、適切な熱間圧延およびSA1の球状化焼鈍を行ったが、変形抵抗が目標値に達していない。 Test No. 29 is an example using the steel type P in Tables 1 and 2 with an excessive Cr content. For this reason, appropriate hot rolling and spheroidizing annealing of SA1 were performed, but the deformation resistance did not reach the target value.

 試験No.30は、Cr含有量が過剰な表1および2の鋼種Pを用いた例である。そのため、適切な熱間圧延およびSA2の球状化焼鈍を行ったが、変形抵抗が目標値に達していない。 Test No. 30 is an example using the steel type P of Tables 1 and 2 with an excessive Cr content. Therefore, although appropriate hot rolling and spheroidizing annealing of SA2 were performed, the deformation resistance did not reach the target value.

 試験No.31は、圧延線材製造時の仕上げ圧延温度の高い表1および2の鋼種Qを用いた例である。そのため、適切なSA1の球状化焼鈍を行ったが、bcc-Fe平均粒径が規定値より粗大で、割れ発生率が目標値に達していない。 Test No. 31 is an example using the steel types Q of Tables 1 and 2 having a high finish rolling temperature at the time of rolling wire production. For this reason, appropriate spheroidizing annealing of SA1 was performed, but the average bcc-Fe particle diameter was coarser than the specified value, and the crack generation rate did not reach the target value.

 試験No.32は、圧延線材製造時の第1冷却の冷却速度が遅く、第3冷却の冷却速度が遅い表1および2の鋼種Rを用いた例である。そのため、適切なSA1の球状化焼鈍を行ったが、bcc-Fe平均粒径が規定値より粗大で、かつ25μm当たりのセメンタイトの個数が規定値より多くなり、変形抵抗、および割れ発生率が目標値に達していない。 Test No. 32 is an example using the steel types R of Tables 1 and 2 in which the cooling rate of the first cooling during the production of the rolled wire rod is slow and the cooling rate of the third cooling is slow. Therefore, although appropriate spheroidizing annealing of SA1 was performed, the average particle diameter of bcc-Fe was coarser than the specified value, and the number of cementites per 25 μm 2 was larger than the specified value. The target value has not been reached.

 試験No.33は、圧延線材製造時の第2冷却の冷却速度が速く、第3冷却の冷却速度が第2冷却の冷却速度と同じ表1および2の鋼種Sを用いた例である。そのため、適切なSA1の球状化焼鈍を行ったが、25μm当たりのセメンタイトの個数が規定値より多く、変形抵抗が目標値に達していない。 Test No. 33 is an example using the steel types S of Tables 1 and 2 in which the cooling rate of the second cooling during the production of the rolled wire rod is fast and the cooling rate of the third cooling is the same as the cooling rate of the second cooling. Therefore, although appropriate SA1 spheroidizing annealing was performed, the number of cementite per 25 μm 2 was larger than the specified value, and the deformation resistance did not reach the target value.

 試験No.34は、圧延線材製造時の仕上げ圧延温度の高い表1および2の鋼種Tを用いた例である。そのため、適切なSA1の球状化焼鈍を行ったが、bcc-Fe平均粒径が規定値より粗大となり、割れ発生率が目標値に達していない。 Test No. 34 is an example using the steel types T of Tables 1 and 2 having a high finish rolling temperature during the production of the rolled wire rod. Therefore, appropriate spheroidizing annealing of SA1 was performed, but the bcc-Fe average particle diameter was coarser than the specified value, and the crack generation rate did not reach the target value.

 試験No.35は、圧延線材製造時の仕上げ圧延温度が高く、第2冷却の冷却速度が速く、第3冷却を行わなかった表1および2の鋼種Uを用い、条件が適切でないSA4で球状化焼鈍を行った例である。そのため、bcc-Fe平均粒径が規定値より粗大で、微細なセメンタイトが均一に分散し、25μm当たりのセメンタイトの個数が規定値より多くなっており、変形抵抗、および割れ発生率が目標値に達していない。 Test No. No. 35 uses the steel type U of Tables 1 and 2 that has a high finish rolling temperature at the time of rolling wire production, a high cooling rate of the second cooling, and does not perform the third cooling. This is an example. Therefore, the average particle diameter of bcc-Fe is coarser than the specified value, fine cementite is uniformly dispersed, the number of cementites per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate are the target values. Not reached.

 試験No.36は、圧延線材製造時の仕上げ圧延温度が高く、第2冷却の冷却速度が速く、第3冷却を行わなかった表1および2の鋼種Uを用い、条件が適切でないSA5で球状化焼鈍を行った例である。そのため、bcc-Fe平均粒径が規定値より粗大で、微細なセメンタイトが均一に分散し、25μm当たりのセメンタイトの個数が規定値より多くなっており、変形抵抗、および割れ発生率が目標値に達していない。 Test No. No. 36 uses the steel type U of Tables 1 and 2 that has a high finish rolling temperature during the production of the rolled wire, the second cooling rate is high, and the third cooling is not performed, and the spheroidizing annealing is performed with SA5 where the conditions are not appropriate. This is an example. Therefore, the average particle diameter of bcc-Fe is coarser than the specified value, fine cementite is uniformly dispersed, the number of cementites per 25 μm 2 is larger than the specified value, and the deformation resistance and crack occurrence rate are the target values. Not reached.

 試験No.39は、表1およびの鋼種Vを用い、条件が適切でないSA3で球状化焼鈍を行った例である。25μm辺りのセメンタイトの個数が既定値より多く、変形抵抗が目標値に達していない。 Test No. No. 39 is an example in which spheroidizing annealing was performed using SA3 whose conditions are not appropriate using steel type V in Table 1. The number of cementites around 25 μm 2 is larger than the predetermined value, and the deformation resistance does not reach the target value.

 本発明の実施形態に係る機械構造部品用鋼線は、冷間鍛造、冷間圧造および冷間転造等の冷間加工によって製造される自動車用部品および建設機械用部品等の各種機械構造部品の素材に好適に用いられる。こうした機械構造部品として、具体的には、ボルト、ねじ、ナット、ソケット、ボールジョイント、インナーチューブ、トーションバー、クラッチケース、ケージ、ハウジング、ハブ、カバー、ケース、受座金、タペット、サドル、バルグ、インナーケース、クラッチ、スリーブ、アウターレース、スプロケット、コア、ステータ、アンビル、スパイダー、ロッカーアーム、ボディー、フランジ、ドラム、継手、コネクタ、プーリ、金具、ヨーク、口金、バルブリフター、スパークプラグ、ピニオンギヤ、ステアリングシャフトおよびコモンレール等の機械部品、電装部品等が挙げられる。本発明の実施形態に係る鋼線は、上記の機械構造部品の素材として好適に用いられる高強度機械構造部品用鋼線として産業上有用であり、上記の各種機械構造用部品を製造するときの室温における変形抵抗が低く、且つ素材の割れが抑制されることで優れた冷間加工性を発揮することができる。 Steel wires for machine structural parts according to embodiments of the present invention are various machine structural parts such as automobile parts and construction machine parts manufactured by cold working such as cold forging, cold forging and cold rolling. It is suitably used for the material. Specifically, these mechanical structural parts include bolts, screws, nuts, sockets, ball joints, inner tubes, torsion bars, clutch cases, cages, housings, hubs, covers, cases, washers, tappets, saddles, bulgs, Inner case, clutch, sleeve, outer race, sprocket, core, stator, anvil, spider, rocker arm, body, flange, drum, fitting, connector, pulley, metal fitting, yoke, base, valve lifter, spark plug, pinion gear, steering Examples include mechanical parts such as shafts and common rails, and electrical parts. A steel wire according to an embodiment of the present invention is industrially useful as a steel wire for a high-strength mechanical structural component that is preferably used as a material for the mechanical structural component. When manufacturing the various mechanical structural components described above, Excellent cold workability can be exhibited by low deformation resistance at room temperature and by suppressing cracking of the material.

 本明細書の開示は、以下の態様を含む。
・態様1:
 質量%で、
 C :0.3~0.6%、
 Si:0.05~0.5%、
 Mn:0.2~1.7%、
 P :0%超、0.03%以下、
 S :0.001~0.05%、
 Al:0.01~0.1%および
 N :0~0.015%を夫々含有し、残部が鉄および不可避不純物からなり、
 鋼の金属組織が、フェライトおよびセメンタイトを含有し、残部が不純物からなり、bcc-Fe結晶粒の平均円相当直径が15μm以下であり、25μm当たりのセメンタイト個数が2.0×10×[C%]個以下である機械構造部品用鋼線。
 ただし、[C%]は、質量%でCの含有量を示す。
・態様2:
 更に、質量%で、
 Cr:0%超、0.5%以下、
 Cu:0%超、0.25%以下、
 Ni:0%超、0.25%以下、
 Mo:0%超、0.25%以下および
 B :0%超、0.01%以下よりなる群から選択される1種以上を含有し、かつ
 下記式(X)を満足する態様1に記載の機械構造部品用鋼線。
 [Cr%]+[Cu%]+[Ni%]+[Mo%]≦0.75   (X)
 ただし、[Cr%]、[Cu%]、[Ni%]および[Mo%]は、それぞれ、質量%で示したCr、Cu、NiおよびMoの含有量を示す。
・態様3:
 更に、質量%で、
 Ti:0%超、0.1%以下、を含有する、態様1または2に記載の機械構造部品用鋼線。
・態様4:
 前記金属組織におけるアスペクト比が3.0以下のセメンタイトの数割合が、全セメンタイト数に対して70%以上である態様1~3のいずれかに記載の機械構造部品用鋼線。
The disclosure of this specification includes the following aspects.
Aspect 1:
% By mass
C: 0.3 to 0.6%,
Si: 0.05 to 0.5%,
Mn: 0.2 to 1.7%,
P: more than 0%, 0.03% or less,
S: 0.001 to 0.05%,
Al: 0.01 to 0.1% and N: 0 to 0.015%, respectively, the balance consisting of iron and inevitable impurities,
The metallographic structure of the steel contains ferrite and cementite, the balance is made of impurities, the average equivalent circle diameter of the bcc-Fe crystal grains is 15 μm or less, and the number of cementite per 25 μm 2 is 2.0 × 10 × [C %] Steel wires for machine structural parts that are less than the number.
However, [C%] indicates the C content in mass%.
-Aspect 2:
Furthermore, in mass%,
Cr: more than 0%, 0.5% or less,
Cu: more than 0%, 0.25% or less,
Ni: more than 0%, 0.25% or less,
It is described in the aspect 1 which contains 1 or more types selected from the group which consists of Mo: more than 0%, 0.25% or less and B: more than 0%, 0.01% or less, and satisfy | fills following formula (X). Steel wire for machine structural parts.
[Cr%] + [Cu%] + [Ni%] + [Mo%] ≦ 0.75 (X)
However, [Cr%], [Cu%], [Ni%], and [Mo%] respectively indicate the contents of Cr, Cu, Ni, and Mo expressed in mass%.
Aspect 3:
Furthermore, in mass%,
The steel wire for machine structural parts according to aspect 1 or 2, containing Ti: more than 0% and 0.1% or less.
Aspect 4:
The steel wire for machine structural parts according to any one of aspects 1 to 3, wherein the number ratio of cementite having an aspect ratio of 3.0 or less in the metal structure is 70% or more with respect to the total cementite number.

 本出願は、出願日が2015年9月3日である日本国特許出願、特願第2015-173962号および、出願日が2016年6月23日である日本国特許出願、特願第2016-124960号を基礎出願とする優先権主張を伴い、特願第2015-173962号および特願第2016-124960号は、参照することにより本明細書に取り込まれる。 The present application includes a Japanese patent application with a filing date of September 3, 2015, Japanese Patent Application No. 2015-173962, and a Japanese patent application with a filing date of June 23, 2016, Japanese Patent Application No. 2016- Japanese Patent Application No. 2015-173962 and Japanese Patent Application No. 2016-124960 are incorporated herein by reference with a priority claim based on No. 124960.

Claims (5)

 質量%で、
 C :0.3~0.6%、
 Si:0.05~0.5%、
 Mn:0.2~1.7%、
 P :0%超、0.03%以下、
 S :0.001~0.05%、
 Al:0.01~0.1%および
 N :0~0.015%を夫々含有し、残部が鉄および不可避不純物からなり、
 鋼の金属組織が、フェライトおよびセメンタイトを含有し、残部が不純物からなり、bcc-Fe結晶粒の平均円相当直径が15μm以下であり、25μm当たりのセメンタイト個数が2.0×10×[C%]個以下である機械構造部品用鋼線。
 ただし、[C%]は、質量%でCの含有量を示す。
% By mass
C: 0.3 to 0.6%,
Si: 0.05 to 0.5%,
Mn: 0.2 to 1.7%,
P: more than 0%, 0.03% or less,
S: 0.001 to 0.05%,
Al: 0.01 to 0.1% and N: 0 to 0.015%, respectively, the balance consisting of iron and inevitable impurities,
The metallographic structure of the steel contains ferrite and cementite, the balance is made of impurities, the average equivalent circle diameter of the bcc-Fe crystal grains is 15 μm or less, and the number of cementite per 25 μm 2 is 2.0 × 10 × [C %] Steel wires for machine structural parts that are less than the number.
However, [C%] indicates the C content in mass%.
 更に、質量%で、
 Cr:0%超、0.5%以下、
 Cu:0%超、0.25%以下、
 Ni:0%超、0.25%以下、
 Mo:0%超、0.25%以下および
 B :0%超、0.01%以下よりなる群から選択される1種以上を含有し、かつ
 下記式(X)を満足する請求項1に記載の機械構造部品用鋼線。
 [Cr%]+[Cu%]+[Ni%]+[Mo%]≦0.75   (X)
 ただし、[Cr%]、[Cu%]、[Ni%]および[Mo%]は、それぞれ、質量%で示したCr、Cu、NiおよびMoの含有量を示す。
Furthermore, in mass%,
Cr: more than 0%, 0.5% or less,
Cu: more than 0%, 0.25% or less,
Ni: more than 0%, 0.25% or less,
The element according to claim 1, which contains at least one selected from the group consisting of Mo: more than 0% and 0.25% or less and B: more than 0% and 0.01% or less, and satisfies the following formula (X). Steel wire for machine structural parts as described.
[Cr%] + [Cu%] + [Ni%] + [Mo%] ≦ 0.75 (X)
However, [Cr%], [Cu%], [Ni%], and [Mo%] respectively indicate the contents of Cr, Cu, Ni, and Mo expressed in mass%.
 更に、質量%で、
 Ti:0%超、0.1%以下、を含有する、請求項1または2に記載の機械構造部品用鋼線。
Furthermore, in mass%,
The steel wire for machine structural parts according to claim 1 or 2, containing Ti: more than 0% and 0.1% or less.
 前記金属組織におけるアスペクト比が3.0以下のセメンタイトの数割合が、全セメンタイト数に対して70%以上である請求項1または2に記載の機械構造部品用鋼線。 The steel wire for machine structural parts according to claim 1 or 2, wherein the number ratio of cementite having an aspect ratio of 3.0 or less in the metal structure is 70% or more with respect to the total cementite number.  前記金属組織におけるアスペクト比が3.0以下のセメンタイトの数割合が、全セメンタイト数に対して70%以上である請求項3に記載の機械構造部品用鋼線。 The steel wire for machine structural parts according to claim 3, wherein the number ratio of cementite having an aspect ratio of 3.0 or less in the metal structure is 70% or more with respect to the total cementite number.
PCT/JP2016/073770 2015-09-03 2016-08-12 Steel wire for mechanical structure parts Ceased WO2017038436A1 (en)

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Cited By (2)

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JP2021509151A (en) * 2017-12-26 2021-03-18 ポスコPosco Wire rods for cold heading, processed products using them, and their manufacturing methods
CN112522632A (en) * 2020-12-09 2021-03-19 苏州莱特复合材料有限公司 Powder metallurgy wear-resistant stator and production process thereof

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JP2009275250A (en) * 2008-05-13 2009-11-26 Nippon Steel Corp Steel wire rod excellent in cold-workability, and producing method thereof
WO2011108459A1 (en) * 2010-03-02 2011-09-09 新日本製鐵株式会社 Steel wire with excellent cold forging characteristics and manufacturing process thereof
JP2012140674A (en) * 2010-12-28 2012-07-26 Kobe Steel Ltd Steel excellent in cold forgeability, and method of manufacturing the same
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JP2001011575A (en) * 1999-06-30 2001-01-16 Nippon Steel Corp Bar and steel wire for machine structure with excellent cold workability and method for producing the same
JP2009275250A (en) * 2008-05-13 2009-11-26 Nippon Steel Corp Steel wire rod excellent in cold-workability, and producing method thereof
WO2011108459A1 (en) * 2010-03-02 2011-09-09 新日本製鐵株式会社 Steel wire with excellent cold forging characteristics and manufacturing process thereof
JP2012140674A (en) * 2010-12-28 2012-07-26 Kobe Steel Ltd Steel excellent in cold forgeability, and method of manufacturing the same
WO2015194411A1 (en) * 2014-06-16 2015-12-23 株式会社神戸製鋼所 Steel for mechanical structure for cold working, and method for producing same

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* Cited by examiner, † Cited by third party
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JP2021509151A (en) * 2017-12-26 2021-03-18 ポスコPosco Wire rods for cold heading, processed products using them, and their manufacturing methods
US11441202B2 (en) 2017-12-26 2022-09-13 Posco Wire rod for cold heading, processed product using same, and manufacturing method therefor
JP7300451B2 (en) 2017-12-26 2023-06-29 ポスコ カンパニー リミテッド Wire rod for cold heading, processed product using the same, and manufacturing method thereof
CN112522632A (en) * 2020-12-09 2021-03-19 苏州莱特复合材料有限公司 Powder metallurgy wear-resistant stator and production process thereof

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