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WO2017036923A1 - Composition de soin cutané - Google Patents

Composition de soin cutané Download PDF

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Publication number
WO2017036923A1
WO2017036923A1 PCT/EP2016/070107 EP2016070107W WO2017036923A1 WO 2017036923 A1 WO2017036923 A1 WO 2017036923A1 EP 2016070107 W EP2016070107 W EP 2016070107W WO 2017036923 A1 WO2017036923 A1 WO 2017036923A1
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mono
cosmetic composition
alkyl
formula
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PCT/EP2016/070107
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German (de)
English (en)
Inventor
Ira Hartmann
Soraya Heinen
Marianne Waldmann-Laue
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication of WO2017036923A1 publication Critical patent/WO2017036923A1/fr
Anticipated expiration legal-status Critical
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention relates to skin cleansing and skin care cosmetic compositions.
  • surface-active cleaning agents for example aqueous surfactant solutions
  • aqueous surfactant solutions are used for cleaning the skin.
  • These cleaning agents remove dirt particles and at the same time have a degreasing effect, but are only of limited use for the removal of very stubborn impurities, dead skin dander, sebaceous secretions and make-up.
  • there is a risk of excessive defatting which may contribute to further drying out of the skin in dry skin, or, in the case of very greasy skin, which may additionally stimulate excessive sebum production in an undesirable manner.
  • peeling refers to a cosmetic or dermatological treatment that removes surface layers of the skin over a wide area.
  • the removal of the upper layer of the skin can be mechanical, such as mineral or vegetal abrasives or chemical.
  • the chemical (exfoliative) exfoliation is based on the effect of different Substance groups, among its prominent representatives, for example, the fruit acids, lipo-hydroxy acid (2-hydroxy-5-octanoylbenzoeklare, LHA), the trichloroacetic acids (TCA), phenolic compounds and tretinoin (vitamin A acid) count.
  • Chemical peeling agents are often only with great difficulty in the amount necessary for a sufficient effect incorporated into cosmetic carriers in a way that long-term stable compositions with pleasant, especially skin-friendly properties guaranteed.
  • the object of the present invention was therefore to provide a composition for cosmetic skin cleansing and skin care, which contains at least one chemical peeling agent, in storage-stable form, that is both chemically and physically stable, and by good cosmetic properties, in particular a good skin compatibility distinguished.
  • cosmetic compositions which, in addition to a chemical peeling agent, an alkyl phosphate and a mono- or diacylglyceride further contain an alkylglucoside, solve the above-mentioned objects.
  • German patent applications DE 10 2008 063 307 A1 and DE 10 2008 063 288A1 describe cosmetic compositions containing cetyl phosphate and palm oil glycerides.
  • German patent applications DE 198 16 664 A1 and DE 10 2013 209 895 A1 describe cosmetic compositions based on mechanical peeling agents.
  • a first subject of this application is an aqueous cosmetic composition containing:
  • At least one anionic oil-in-water emulsifier selected from the salts of C 12-2o-alkyl phosphate, in particular from the salts of cetyl phosphate,
  • At least one C 1-4 -mono- or diacylglyceride preferably at least one C 16-16 mono- or diacylglyceride, more preferably selected from hardened palm oil glycerides
  • at least one alkyl glucoside having a linear or branched alkyl or alkenyl radical with 14 up to 30 carbon atoms and a mono-, di- or triglucoside radical
  • d) at least one chemical peeling agent at least one chemical peeling agent.
  • the cosmetic compositions according to the invention are aqueous, ie comprise an aqueous carrier.
  • the composition according to the invention is preferably viscous-liquid.
  • Preferred cosmetic compositions are characterized by a water content of 30 to 92% by weight, preferably 45 to 90% by weight, in particular 50 to 85% by weight, based on their total weight.
  • the pH composition is preferably in the range of 4.5 to 7.0, preferably 5.0 to 6.0, and more preferably about 5.5.
  • the compositions according to the invention may further contain from 1 to 40% by weight, preferably from 2 to 30 and in particular from 3 to 20% by weight, of at least one alcohol, based on their total weight.
  • Preferred alcohols are glycol, 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, pentylene glycols, 1 , 2-hexanediol, 1, 6-hexanediol, 1, 2,6-hexanetriol, 1, 2-octanediol, 1, 8-octanediol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol, polyethylene glycol and mixtures of the aforementioned substances ,
  • compositions of the invention contain as alcohol 1, 2-propylene glycol, glycerol, 1, 3-butylene glycol, 1, 6-hexanediol, diglycerol, triglycerol, dipropylene glycol and / or tripropylene glycol, in particular glycerol, 1, 6-hexanediol and dipropylene glycol.
  • compositions of the invention comprise as a first essential ingredient at least one C 12-2o alkyl phosphate.
  • the salts of C 12-2o-alkyl phosphate, in particular the salts of cetyl phosphate, based on the total weight of the composition in amounts of 0.05 to 3 , 0 wt .-%, preferably 0.1 to 1, 5 wt .-% and in particular 0.1 to 1, 0 wt .-% are included.
  • the salts of C 12-2 o -alkyl phosphates may be present, for example, as alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolamine or glucammonium salt. Preference is given to the corresponding sodium, potassium, alkanolamine, trialkylammonium, triethanolamine, 2-amino-1-butanol, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1 , 3-propanediol, 2-amino-2-ethyl-1, 3-propanediol or tris (hydroxymethyl) aminomethane salts, and salts of the basic amino acids ornithine, lysine, arginine and / or histidine. Particularly preferred are the potassium salts of said C12-20 alkyl phosphates.
  • the group of salts of C 12-2o-alkyl phosphates include the salts of phosphoric acid C 12-2 monoalkyl esters and the salts of phosphoric acid C 12-2 o dialkyl esters.
  • Salts of C 12-2 o -alkyl phosphates which are preferred according to the invention are selected from the monoesters of phosphoric acid with lauryl alcohol, tridecyl alcohol, isotridecyl alcohol, myristyl alcohol, pentadecyl alcohol, cetyl alcohol, palmityl alcohol, isocetyl alcohol, isostearyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, linoleyl alcohol, linolenyl alcohol, Nonadecyl alcohol, arachyl alcohol, gadoleyl alcohol or arachidonic alcohol, as the alkali, alkaline earth, ammonium, alkylammonium, alkanolamine or glucammonium, preferably the corresponding sodium, potassium, alkanolamine, trialkylammonium, triethanolamine, 2-amino 1-butanol, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl
  • C 12-28 -alkyl phosphates are selected from the diesters of phosphoric acid with lauryl alcohol, tridecyl alcohol, isotridecyl alcohol, myristyl alcohol, pentadecyl alcohol, cetyl alcohol, palmityl alcohol, isocetyl alcohol, isostearyl alcohol, stearyl alcohol, oleyl alcohol, elaidyl alcohol, linoleyl alcohol, linolenyl alcohol, nonadecyl alcohol, arachyl alcohol, Gadoleyl alcohol or arachidonic alcohol which is in the form of an alkali, alkaline earth, ammonium, alkylammonium, alkanolamine or glucammonium salt, preferably the corresponding sodium, potassium, alkanolamine, trialkylammonium, triethanolamine, 2-amino-1-butanol, 2-amino-2-methyl-1-propanol, 2-amino-2
  • mixtures of mono-C 12-2o-alkyl phosphates and di-C 12-2o-alkyl phosphates are particularly preferred.
  • mixtures of dipotassium monocetyl phosphate and potassium dicetyl phosphate are particularly preferred.
  • the compositions according to the invention comprise at least one C 16-2 mono-or diacylglyceride.
  • the proportion of the Ci4-2o mono- or diacylglyceride, preferably the Ci6-is-mono- or diacylglyceride, particularly preferably the cured palm oil glyceride in the total weight of the composition is preferably 0.01 to 3.0 wt .-%, preferably 0.02 to 1, 5 wt .-% and in particular 0.05 to 0.8 wt .-%.
  • Corresponding compositions have a particularly good chemical and physical stability and good cosmetic properties.
  • Ci4-2o mono- or Diacylglyceride are selected from Monomyristoylglycerid, Monopalmitoylglycerid, Monostearoylglycerid, monoarachinoylglyceride, Dimyristoylglycerid, Dipalmitoylglycerid, Distearoylglycerid, Diarachinoylglycerid and mixtures of two or more than Meherer compounds thereof.
  • Further inventively preferred Ci4-2o mono- or diacylglycerides are glycerides cured, that is, hydrogenated, preferably fully hydrogenated, fatty acids of natural oils.
  • Particularly preferred C 16 -is mono- or diacylglycerides are selected from the group of hardened palm oil glycerides (INCI: Hydrogenated Palm Glycerides).
  • the properties of the cosmetic compositions can also be advantageously influenced by the weight ratio of these two essential constituents.
  • Cosmetic composition in which the salts of C 12-2 o -alkyl phosphate and the ci4-2o-mono- and C 14-20- Diacylglycerides in a weight ratio of 3 to 1 to 1 to 1, 5, preferably from 2.5 to 1 to 1 to 1, are characterized by a high storage stability.
  • Particularly preferred are those cosmetic compositions in which the salts of cetyl phosphate and the hardened palm oil glycerides are present in a weight ratio of 3: 1 to 1: 1.5, more preferably 2.5: 1 to 1: 1.
  • compositions according to the invention comprise an alkylglucoside having a linear or branched alkyl or alkenyl radical having 14 to 30 carbon atoms and a mono-, di- or triglucoside radical, preferably a monoglycoside radical.
  • Suitable alkylglucosides correspond to the general formula RO- (Z) x , where R is a linear or branched C 3 - to C 30 -alkyl or alkenyl radical, preferably a linear C 2 - to C 20 -alkyl radical, Z is a sugar radical, such as glucose and x, - Indicator of the number of sugar units, which stands for a value of 1, 2 or 3.
  • compositions according to the invention are preferred in which the alkylglucoside has a linear alkyl radical having 16 to 18 carbon atoms and a monoglucoside radical.
  • alkylglucosides are the compounds with the INCI names Decyl Glucoside commercial product Plantaren 2000), lauryl glucoside (commercial product Plantacare 1200), Coco glucoside (commercial product Plantacare 818), caprylic / caprylyl glucoside (commercial product Oramix CG 1 10).
  • An inventively preferred alkyl glucoside carries the INCI name Cetearyl Glucoside (commercial product Tego Care CG 90).
  • the proportion by weight of the alkyl glucoside in the total weight of the composition is preferably from 0.05 to 9.0 wt .-%, preferably from 0, 1 to 4.0 wt .-% and in particular from 0.3 to 2.0 wt .-% ,
  • those cosmetic compositions are preferred which, based on their total weight
  • compositions at least one chemical peeling agent.
  • Particularly suitable for the chemical peel are fruit acids such as glycolic acid, 2-hydroxy-5-octanoylbenzoic acid (also lipohydroxy acid or LHA), trichloroacetic acids, vitamin A acid (tretinoin), glucosamine hydrochloride or specific plant extracts.
  • fruit acids such as glycolic acid, 2-hydroxy-5-octanoylbenzoic acid (also lipohydroxy acid or LHA), trichloroacetic acids, vitamin A acid (tretinoin), glucosamine hydrochloride or specific plant extracts.
  • Preferred cosmetic compositions contain a chemical peeling agent from the group of fruit acids and plant extracts.
  • a first group of preferred chemical peeling agents form the fruit acids, wherein fruit acid from the group of malic acid, citric acid and salicylic acid are particularly preferred.
  • Preferred cosmetic compositions are characterized in that at least one fruit acid, preferably at least one fruit acid from the group of malic acid, citric acid and salicylic acid, particularly preferably malic acid, is used as chemical peeling agent.
  • compositions with exfoliating action include the plant extracts with exfoliating action.
  • plant extracts from the group hydrolyzed Opuntia ficus indica extract, Bambusa vulgaris extract and Pisum sativum extract are particularly preferred.
  • the combination of different peeling active ingredients has been found.
  • the exfoliating action of the cosmetic compositions can be further increased.
  • chemical peeling active ingredient a combination of malic acid, hydrolyzed Opuntia ficus indica extract, Bambusa vulgaris extract, Pisum sativum extract and glucosamine hydrochloride.
  • the cosmetic compositions according to the invention are suitable for compounding a plurality of cosmetic peeling active ingredients.
  • Preferred cosmetic compositions contain
  • hydrophobically modified (meth) acrylic acid copolymers it is preferable to use copolymers based on
  • Preferred copolymers b) are based on at least one first monomer from the group of acrylic acid, methacrylic acid, C 1 -C 6 -alkylacrylic acid esters, C 1 -C 6 -alkyl methacrylic acid esters.
  • the acrylic acid esters and methacrylic acid esters are preferably esters of the respective acids with non-tertiary alkyl alcohols having alkyl radicals of 1 to 12 carbon atoms, in particular 2 to 4 carbon atoms.
  • Suitable monomers are ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, isobutyl acrylate, 2-methylbutyl acrylate, 2-ethylhexyl acrylate, n-octyl acrylate, isooctyl acrylate, isooctyl methacrylate, isononyl acrylate and isodecyl acrylate.
  • the group of hydrophobically modified second monomers refers to monomers which have a hydrophobic substructure.
  • preferred monomers can be attributed to the two following structural units:
  • an unsaturated acid preferably acrylic acid, methacrylic acid or itaconic acid
  • Cs-4oAlkylkette preferably a Cio soAlkylkette.
  • These two partial structures may optionally be supplemented by a third structural unit from the group of the polyoxyalkylene groups, preferably the polyethylene glycol groups, the polypropylene glycol groups or the polyethylene glycol / polypropylene glycol groups.
  • the second monomer used are, for example, C 1 -C 5 -alkyl acrylates, C 1 -C 4 -alkyl PEG acrylates, C 10 -C 30 -alkyl PEG-methacrylates or C 10 -Sialkyl PEG-itaconates.
  • Preferred monomers are selected from the Cio-soAlkyl acrylates, Cio-soAlkyl PEG 20-25 acrylates, Cio-soAlkyl PEG 20-25 methacrylates or Cio soAlkyl PEG 20-25 itaconates.
  • Particularly preferred monomers are selected from the group of Cio soAlkyl acrylates, steareth-20 methacrylates, beheneth-25 methacrylates, steareth-20 itaconates, ceteth-20 itaconates, Palmeth-25 acrylates or Cio soAlkyl PEG-20 itaconates.
  • hydrophobically modified (meth) acrylic acid copolymers b) are preferred which
  • hydrophobically modified (meth) acrylic acid copolymers are selected from the group of compounds with the INCI name Acrylates / Cio-30-alkyl acrylate crosspolymer, as are available, for example, under the trade names Carbopol ETD 2020, Ultrez 21 or Pemulen TR1.
  • the proportion by weight of the hydrophobically modified (meth) acrylic acid copolymer in the total weight of the composition is preferably from 0.05 to 2.0% by weight, preferably from 0.1 to 1.2% by weight and in particular from 0.2 to 0, 8% by weight.
  • copolymers of 2-methyl-2 [(1-oxo-2-propenyl) amino] -1-propanesulfonic acid are preferably used
  • this copolymer is crosslinked.
  • Crosslinked copolymers of vinylpyrrolidone and 2-methyl-2 [(1-oxo-2-propenyl) -amino] -1-propanesulfonic acid are obtainable, for example, by copolymerization of the two monomers in the presence of ammonium hydroxide and a crosslinking agent.
  • the crosslinking can be carried out with the aid of multiply olefinically unsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallyl ether, polyallylpolyglyceryl ethers, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose.
  • multiply olefinically unsaturated compounds for example divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallyl ether, polyallylpolyglyceryl ethers, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose.
  • Methylenebisacrylamide is a preferred crosslink
  • a particularly suitable copolymer is the commercial product Aristoflex ® AVC (ex Clariant), which is in the form of the ammonium salt as a white powder.
  • the copolymer of 2-methyl-2 [(1-oxo-2-propenyl) amino] -1-propanesulfonic acid is preferably present in the compositions according to the invention in amounts of from 0.1 to 3.0% by weight, preferably from 0.2 to 2.0 wt .-% and in particular from 0.5 to 1, 5 wt .-%.
  • composition of some preferred cosmetic compositions can be seen from the following tables (% by weight based on the total weight of the cosmetic composition, unless stated otherwise).
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Peeling active ingredient in the form of a 0.01 to 4.0 0.05 to 3.0 0, 1 to 2.0 0.1 to 2.0 combination of fruit acid
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5 0.05 to 0.8 0.05 to 0.8 Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Peeling active ingredient in the form of a 0.01 to 4.0 0.05 to 3.0 0, 1 to 2.0 0.1 to 2.0 combination of fruit acid
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5 0.05 to 0.8 0.05 to 0.8
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • C 12-2o alkyl phosphate salt 0.05 to 3.0 0.1 to 1, 5 0, 1 to 1, 5 0.1 to 1, 0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5, 0.05 to 0.8 0.05 to 0.8
  • Ci6-i8 alkyl monoglucoside 0.05 to 9.0 0.1 to 4.0 0.1 to 4.0 0.3 to 2.0
  • Ci4-2o mono- or diacylglyceride 0.01, to 3.0 0.02 is 1, 5 0.05 to 0.8 0.05 to 0.8
  • Peeling active ingredient in the form of a 0.01 to 4.0 0.05 to 3.0 0, 1 to 2.0 0.1 to 2.0 combination of fruit acid
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5 0.05 to 0.8 0.05 to 0.8
  • Peeling agent in the form of a 0.01 to 4.0 0.05 to 3.0 0.1 to 2.0 0.1 to 2.0 combination of fruit acid
  • Ci6-i8-mono- and diacylglyceride 0.01, to 3.0 0.02 to 1.5 0.05 to 0.8 0.05 to 0.8
  • At least one monomer (b2) from the group of C10-30 alkyl acrylates can be attributed.
  • a combination of components a), b) and c) is particularly suitable for improving the physical and chemical stability of cosmetic peeling agents.
  • Another object of the present application is the use of a combination comprising
  • At least one anionic oil-in-water emulsifier selected from the salts of C 12-2o-alkyl phosphate, in particular from the salts of cetyl phosphate,
  • At least one C 1-4 -mono- or diacylglyceride preferably at least one C 16-18 mono- or diacylglyceride, more preferably selected from hardened palm oil glycerides
  • at least one alkylglucoside having a linear or branched alkyl or alkenyl radical with 14 to 30 carbon atoms and a mono-, di- or triglucoside radical, for improving the storage stability of a, at least one chemical peeling agent-containing cosmetic composition.
  • a third object of the present invention is finally a process for cosmetic skin care in which a cosmetic composition according to the invention is applied to the skin, in particular the facial skin.

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Abstract

Composition cosmétique aqueuse contenant : a) au moins un émulsifiant anionique huile-dans-l'eau choisi parmi les sels de phosphate d'alkyle C12-20, notamment parmi les sels de phosphate cétylique, b) au moins un monoglycéride C14-20 ou un diacylglycéride C₁₄₋₂₀, de préférence au moins un monoglycéride C16-18 ou un diacylglycéride C₁₆₋₁₈, de préférence encore choisi parmi des glycérides d'huile de palme durcis, c) au moins un glucoside d'alkyle présentant un radical alkyle ou alcényle linéaire ou ramifié ayant 14 à 30 atomes de carbone et un radical monoglucoside, diglucosside ou triglucoside, et d) au moins un principe actif de peeling chimique; et procédé de soin cosmétique pour la peau utilisant cette composition.
PCT/EP2016/070107 2015-08-31 2016-08-25 Composition de soin cutané Ceased WO2017036923A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015216603.1A DE102015216603A1 (de) 2015-08-31 2015-08-31 Zusammensetzung zur Hautpflege
DE102015216603.1 2015-08-31

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WO2017036923A1 true WO2017036923A1 (fr) 2017-03-09

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DE19816664A1 (de) * 1998-04-15 1999-10-21 Henkel Kgaa Mild abrasive Hautreinigungsmittel
WO2001076552A2 (fr) * 2000-04-11 2001-10-18 Noveon Ip Holdings Corp. Compositions tensioactives aqueuses stables
EP1621183A1 (fr) * 2004-07-26 2006-02-01 L'oreal Composition de nettoyage moussante
EP1759688A1 (fr) * 2005-09-05 2007-03-07 L'Oréal Procédé cosmétique de soin des peaux grasses et kit associé
CN104042482A (zh) * 2014-05-31 2014-09-17 青岛博泓海洋生物技术有限公司 一种去角质磨砂膏

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DE102008063307A1 (de) 2008-12-29 2010-07-01 Henkel Ag & Co. Kgaa Sonnenschutzzusammensetzungen
DE102008063288A1 (de) 2008-12-29 2010-07-01 Henkel Ag & Co. Kgaa Sonnenschutzzusammensetzungen
DE102013209895A1 (de) 2013-05-28 2014-12-04 Henkel Ag & Co. Kgaa Verfahren zur Herstellung eines kosmetischen Reinigungsmittels

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19816664A1 (de) * 1998-04-15 1999-10-21 Henkel Kgaa Mild abrasive Hautreinigungsmittel
WO2001076552A2 (fr) * 2000-04-11 2001-10-18 Noveon Ip Holdings Corp. Compositions tensioactives aqueuses stables
EP1621183A1 (fr) * 2004-07-26 2006-02-01 L'oreal Composition de nettoyage moussante
EP1759688A1 (fr) * 2005-09-05 2007-03-07 L'Oréal Procédé cosmétique de soin des peaux grasses et kit associé
CN104042482A (zh) * 2014-05-31 2014-09-17 青岛博泓海洋生物技术有限公司 一种去角质磨砂膏

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