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WO2017036578A1 - Composition pour micro-lubrification et son utilisation - Google Patents

Composition pour micro-lubrification et son utilisation Download PDF

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Publication number
WO2017036578A1
WO2017036578A1 PCT/EP2016/001394 EP2016001394W WO2017036578A1 WO 2017036578 A1 WO2017036578 A1 WO 2017036578A1 EP 2016001394 W EP2016001394 W EP 2016001394W WO 2017036578 A1 WO2017036578 A1 WO 2017036578A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
alcohol
lubricant composition
aliphatic
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2016/001394
Other languages
German (de)
English (en)
Inventor
Thomas Frank
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuchs SE
Original Assignee
Fuchs Petrolub SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP15002409.9A external-priority patent/EP3130653B1/fr
Priority claimed from DE202015005833.7U external-priority patent/DE202015005833U1/de
Priority to US15/751,900 priority Critical patent/US20180237712A1/en
Priority to KR1020187006975A priority patent/KR102057954B1/ko
Priority to JP2018526999A priority patent/JP2018523748A/ja
Priority to CN201680055295.XA priority patent/CN108138072B/zh
Priority to SG11201801166TA priority patent/SG11201801166TA/en
Priority to PH1/2018/500308A priority patent/PH12018500308B1/en
Priority to RU2019100454A priority patent/RU2019100454A/ru
Priority to MYPI2018000202A priority patent/MY184087A/en
Application filed by Fuchs Petrolub SE filed Critical Fuchs Petrolub SE
Priority to MX2018001855A priority patent/MX2018001855A/es
Priority to HK18113750.3A priority patent/HK1254738B/zh
Priority to CA2995517A priority patent/CA2995517C/fr
Priority to AU2016316437A priority patent/AU2016316437B2/en
Publication of WO2017036578A1 publication Critical patent/WO2017036578A1/fr
Priority to IL257424A priority patent/IL257424A/en
Anticipated expiration legal-status Critical
Priority to ZA2018/01649A priority patent/ZA201801649B/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/10—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M105/12—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/041—Mixtures of base-materials and additives the additives being macromolecular compounds only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/0215—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/22—Degreasing properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/24—Emulsion properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

Definitions

  • This invention relates to a lubricant composition for minimal quantity lubrication in metal working and the use of the lubricant composition therefor.
  • the cooling lubricants used in wet processing primarily provide cooling, lubrication and chip evacuation, but at the same time have an influence on non-productive times in the production process by collecting, processing or disposing of the cooling lubricants, and thus also for the costs of their purchasing, processing and disposal , Furthermore, environmental and health protection must be taken into account.
  • the minimum quantity lubrication (MQL) or minimal quantity cooling lubrication (MMKS) forms a middle ground between wet machining and dry machining.
  • the minimum quantity lubrication offers a significant reduction in the supply and disposal technology for the cooling lubricant compared to wet processing, which enables longer service life and reduced process time. Furthermore, follow-up processes for cleaning the workpieces and also the tool can be reduced. Since minimum quantity lubrication means loss lubrication, only new, ie non-recycled or recycled lubricant is used so that biocides, fungicides and other additives can be dispensed with. However, there are increased demands on the lubricant, which must be matched to the workpiece material, machine parameters and tool material in order to achieve optimum results.
  • Water-miscible metalworking fluids that can be cleaned with water are considered unsuitable for minimum quantity lubrication because they do not have the required lubrication or flash point.
  • WO 91/06619 describes heating the workpiece so that the lubricant evaporates.
  • a lubricant composition according to the invention for minimal quantity lubrication in metalworking is composed to a major proportion of an aliphatic Cie-24 alcohol to which a small proportion of emulsifier is added, so that the
  • Lubricant is emulsifiable with water. In this way not only the workpiece, but also the tool and the processing space (eg machine interior) can be easily removed from the residues of the lubricant composition according to the invention by emulsification with water. However, care must be taken that the lubricant composition can not come into contact with water during storage and supply to the tool.
  • a preferred emulsifier may be a fatty alcohol polyalkylene glycol ether contained in the composition at 0.05 to 5% by weight, based on the total weight of the composition.
  • the emulsifier may be a glycolic acid alkoxylate alkyl ether, the proportion of which in the composition ranges from 0.05 to 5% by weight, based on the total weight of the composition.
  • mixtures of fatty alcohol-polyalkylene glycol ethers and glycolic acid alkethoxylate alkyl ethers are used as emulsifier with a weight fraction of 0.05 to 5 wt .-%, based on the total weight of the composition.
  • the aliphatic Cie-24 alcohol is then in each case in a 100% of the composition complementary proportion.
  • the fatty alcohol polyalkylene glycol ether has the formula (I)
  • R 1 is an aliphatic, branched or linear Cie- alkyl or alkenyl radical.
  • R * may be a hydroxyl group.
  • the variables x and y can be 0 to 10, provided that the sum x + y is from 1 to 10.
  • the weight fraction of the fatty alcohol polyalkylene glycol ether may be from 1 to 5% by weight, with lower proportions, e.g. B. 1 wt .-%, are particularly preferred.
  • the lubricant composition with 1% by weight of fatty alcohol-polyalkylene glycol ether has a suitable emulsifier balance with sufficiently good emulsifying properties, without negatively influencing the separation behavior in the cleaning system (demulsifying behavior). While too low an emulsifier concentration results in less cleanability of tool, workpiece and machine room, too high concentrations prevent the oil separation in the cleaning system.
  • the glycolic acid alkoxylate alkyl ether alternative to the fatty alcohol polyalkylene glycol ether
  • R 2 is an aliphatic, branched or linear C 6-2 o alkyl or alkenyl radical.
  • glycolic acid alkoxylate alkyl ether is preferably a glycolic acid ethoxylate alkyl ether.
  • Exemplary glycolic acid alkoxylate alkyl ethers are poly (oxy-1,2-ethanediyl), a- (carboxymethyl) -o-hydroxy, Cio-w and Ci 2 -o-unsaturated alkyl ethers (eg CAS No. 68954-89-2 ), Poly (oxy-1,2-ethanediyl), ⁇ - (carboxymethyl) - (yo-hydroxy, C16-18 and cis-unsaturated alkyl ethers (CAS No. 227310-69-2), poly (oxy-1, 2-ethanediyl), a- (carboxymethyl) -u) -hydroxy-octyloxy- (CAS No.
  • the C16-24 aliphatic alcohol used in the lubricant composition of the present invention may be a branched alcohol, preferably a Guerbet alcohol (long-chain, ⁇ -position to the primary OH group alkyl-substituted alcohol), such as.
  • a Guerbet alcohol long-chain, ⁇ -position to the primary OH group alkyl-substituted alcohol
  • 2-hexyl-1-decanol or 2-octyl-1-dodecanol can preferably be used.
  • Such alcohols can be used at lower application temperatures because of the lower pour point and lower tendency to stick due to complete saturation than is possible with natural linear alcohols.
  • a lubricant composition designed according to the invention can thus consist of only two components, the basic C 16-24-alcohol and the emulsifier. In a further embodiment of the invention, however, it may also be provided that the lubricant composition additionally contains from 0.05 to 5% by weight, based on the total weight of the composition, of fatty acid alkanolamide or alkoxylated fatty acid alkanolamide of the formula (III)
  • R 3 is - (CO) -NR '- (CH 2 ) 2-0 - [(CH 2 CH 2 O) x- (CH 2 CH (CH 3) O) y ] -R "(III) wherein R 3 is an aliphatic, linear or branched C5-23 alkyl or alkenyl radical and R ', R "are independently hydrogen or an aliphatic, linear or branched, substituted or unsubstituted alkyl or alkenyl radical, x and y can each be selected from 0 to 10, so that as above pure ethoxylated, purely propoxylated and mixed ethoxylated and propoxylated compounds are included, in which case the sum x + y can be from 0 (not alkoxylated) to 10.
  • a lubricant composition of the present invention may further comprise at least one performance additive selected from a group consisting of
  • sulfurized compounds such as sulfurized olefins, sulfurized esters, sulfurized triglycerides and sulfurized natural ester oils,
  • sulfurized olefins such as di-tert-dodecyl polysulfides (EC No. 270-335-7), e.g. Di-ferf-dodecyl-trisulfide or di-te / f-dodecyl-pentasulfide,
  • esters such as fatty acids, vegetable oil, methyl esters, sulfurized (EC No. 276-337-4),
  • sulfurized triglycerides / sulfurized natural ester oils e.g.
  • sulphurised rapeseed oil sulphurised lard oil, sulphurised castor oil etc.
  • pure fatty acids e.g. Oleic acid or the like having chain lengths in the range of C12-24
  • ethoxylated natural oils such as e.g. Castor ethoxylate with 1 to 10 ethylene oxide units
  • KOH saponified rapeseed oil
  • a proportion of each performance additive based on the total weight of the composition is a maximum of 15 wt .-%, wherein the proportion of the sum of the performance additives based on the total weight of the composition does not exceed 30 wt .-%.
  • a lubricant composition according to the invention can thus be used for minimum quantity lubrication in metalworking, with residues of the lubricant composition remaining on surfaces of the workpiece and the tool being washable with water.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)

Abstract

La présente invention concerne une composition de micro-lubrification et son utilisation pour la micro-lubrification lors du travail des métaux. Cette composition présente 0,05 à 5 % en poids d'un émulsifiant, par rapport au poids total de la composition, et une proportion, complémentaire jusquà 100% de la composition, d'un alcool C16-24 aliphatique. Cet émulsifiant est sélectionné parmi des éthers de polyalkylèneglycol d'alcool gras ou des alkyléthers d'alcoxylate d'acide glycolique ou leurs mélanges.
PCT/EP2016/001394 2015-08-13 2016-08-15 Composition pour micro-lubrification et son utilisation Ceased WO2017036578A1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
CA2995517A CA2995517C (fr) 2015-08-13 2016-08-15 Composition pour micro-lubrification et son utilisation
AU2016316437A AU2016316437B2 (en) 2015-08-13 2016-08-15 Composition for minimum quantity lubrication, and use of same
MX2018001855A MX2018001855A (es) 2015-08-13 2016-08-15 Composicion para el engrase de cantidades minimas y su empleo.
JP2018526999A JP2018523748A (ja) 2015-08-13 2016-08-15 極微量油剤潤滑のための組成物及びその使用
CN201680055295.XA CN108138072B (zh) 2015-08-13 2016-08-15 用于进行最小量润滑的组合物及其用途
SG11201801166TA SG11201801166TA (en) 2015-08-13 2016-08-15 Composition for minimum quantity lubrication, and use of same
PH1/2018/500308A PH12018500308B1 (en) 2015-08-13 2016-08-15 Composition for minimum quantity lubrication, and use of same
RU2019100454A RU2019100454A (ru) 2015-08-13 2016-08-15 Состав для минимального количества смазки и его применение
MYPI2018000202A MY184087A (en) 2015-08-13 2016-08-15 Composition for minimum quantity lubrication, and use of same
US15/751,900 US20180237712A1 (en) 2015-08-13 2016-08-15 Composition for Minimum Quantity Lubrication, and Use of Same
KR1020187006975A KR102057954B1 (ko) 2015-08-13 2016-08-15 최소량 윤활용 조성물 및 이의 용도
HK18113750.3A HK1254738B (zh) 2015-08-13 2016-08-15 用於进行最小量润滑的组合物及其用途
IL257424A IL257424A (en) 2015-08-13 2018-02-08 A preparation for lubrication with a minimal amount and its use
ZA2018/01649A ZA201801649B (en) 2015-08-13 2018-03-09 Composition for minimum quantity lubrication, and use of same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP15002409.9 2015-08-13
DE202015005833.7 2015-08-13
EP15002409.9A EP3130653B1 (fr) 2015-08-13 2015-08-13 Composition destinee a la lubrification a quantites minimales et son utilisation
DE202015005833.7U DE202015005833U1 (de) 2015-08-13 2015-08-13 Zusammensetzung zur Minimalmengenschmierung und deren Verwendung

Publications (1)

Publication Number Publication Date
WO2017036578A1 true WO2017036578A1 (fr) 2017-03-09

Family

ID=57211465

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2016/001394 Ceased WO2017036578A1 (fr) 2015-08-13 2016-08-15 Composition pour micro-lubrification et son utilisation

Country Status (14)

Country Link
US (1) US20180237712A1 (fr)
JP (1) JP2018523748A (fr)
KR (1) KR102057954B1 (fr)
CN (1) CN108138072B (fr)
AU (1) AU2016316437B2 (fr)
CA (1) CA2995517C (fr)
IL (1) IL257424A (fr)
MX (1) MX2018001855A (fr)
MY (1) MY184087A (fr)
PH (1) PH12018500308B1 (fr)
RU (1) RU2019100454A (fr)
SG (1) SG11201801166TA (fr)
WO (1) WO2017036578A1 (fr)
ZA (1) ZA201801649B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7133422B2 (ja) * 2018-09-28 2022-09-08 ユシロ化学工業株式会社 ミスト加工用水溶性金属加工油剤組成物および金属加工方法
KR102732429B1 (ko) * 2022-07-08 2024-11-20 주식회사 한국타우 클린룸 내 디스플레이 생산장비 적용 불소 함유 그리스
KR102732428B1 (ko) * 2022-07-08 2024-11-20 주식회사 한국타우 클린룸 내 반도체 생산장비 적용 불소 함유 그리스

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EP1574560A1 (fr) * 2004-03-04 2005-09-14 Clariant GmbH Procédé sans solvant de préparation d' acides ether carboxyliques à faible teneur en sel
EP2397535A1 (fr) * 2009-02-10 2011-12-21 JX Nippon Oil & Energy Corporation Composition d'huile pour le travail de l'aluminium avec une quantité minimale de lubrification

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