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WO2017030176A1 - Système de projection et procédé de fabrication d'écran d'image intermédiaire de système de projection - Google Patents

Système de projection et procédé de fabrication d'écran d'image intermédiaire de système de projection Download PDF

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Publication number
WO2017030176A1
WO2017030176A1 PCT/JP2016/074163 JP2016074163W WO2017030176A1 WO 2017030176 A1 WO2017030176 A1 WO 2017030176A1 JP 2016074163 W JP2016074163 W JP 2016074163W WO 2017030176 A1 WO2017030176 A1 WO 2017030176A1
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WIPO (PCT)
Prior art keywords
liquid crystal
layer
light
cholesteric liquid
intermediate image
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Ceased
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PCT/JP2016/074163
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English (en)
Japanese (ja)
Inventor
市橋　光芳
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Fujifilm Corp
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Fujifilm Corp
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Priority to JP2017535567A priority Critical patent/JP6580143B2/ja
Publication of WO2017030176A1 publication Critical patent/WO2017030176A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/01—Head-up displays
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B21/00—Projectors or projection-type viewers; Accessories therefor
    • G03B21/14—Details
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B21/00—Projectors or projection-type viewers; Accessories therefor
    • G03B21/54—Accessories
    • G03B21/56—Projection screens
    • G03B21/60—Projection screens characterised by the nature of the surface

Definitions

  • the present invention relates to a projection system. More particularly, the present invention relates to a projection system including a drawing device and an intermediate image screen. The invention also relates to a method for producing an intermediate image screen of a projection system.
  • Patent Document 1 describes a head-up display system configured to form an image that is a real image on an intermediate image screen and project the image onto a windshield or a combiner. The projected image is displayed as a virtual image at the same time as the front scenery on the front glass or combiner as viewed from the observer.
  • Patent Document 1 describes a configuration in which an image is formed on an intermediate image screen and transmitted or reflected.
  • the reflection type configuration is easy to design so that sunlight is not easily incident on the drawing device, particularly when applied to a head-up display system for a vehicle, and the deterioration of the drawing device can be prevented. This is preferable because it is possible.
  • a reflection screen for normal use is applied as it is, for example, it is possible to give a virtual image having luminance and resolution that can be used in a head-up display system. It is difficult to develop materials that can be used practically.
  • An object of the present invention is to provide a projection system that provides a projected image with high brightness and high resolution.
  • an object of the present invention is to provide a projection system that provides a high-luminance and high-resolution projection image using a reflective intermediate image screen.
  • Another object of the present invention is to provide an intermediate image screen manufacturing method applicable to the projection system.
  • the present inventor has intensively studied to solve the above problems, and found that a high-luminance and high-resolution projection image can be obtained by using a layer in which a specific cholesteric liquid crystal phase is fixed as an intermediate image screen. Based on the above, further studies were made and the present invention was completed.
  • the present invention provides the following [1] to [17].
  • [1] including a drawing device and an intermediate image screen;
  • the drawing device forms an image on the intermediate image screen;
  • a projection system in which a projection image is displayed with light derived from reflected light from the intermediate image screen,
  • the intermediate image screen includes a layer in which a cholesteric liquid crystal phase is fixed;
  • the projection system, wherein the intermediate image screen has diffuse reflectivity in a wavelength region where the layer in which the cholesteric liquid crystal phase is fixed exhibits selective reflection.
  • the cholesteric liquid crystal phase has a helical axis inclined on at least one surface of the layer to which the cholesteric liquid crystal phase is fixed, The inclination of the spiral axis changes in the plane,
  • the intermediate image screen has a layer in which a cholesteric liquid crystal phase having a central wavelength of selective reflection is fixed in a red light wavelength region, and a layer in which a cholesteric liquid crystal phase having a central wavelength of selective reflection is fixed in a wavelength region of green light. And a layer in which a cholesteric liquid crystal phase having a central wavelength of selective reflection is fixed in the wavelength range of blue light, according to any one of [1] to [3].
  • the intermediate image screen has two layers having different spiral senses as a layer in which a cholesteric liquid crystal phase having a central wavelength of selective reflection is fixed in the wavelength range of red light, and has a central wavelength of selective reflection in the wavelength range of green light.
  • the writing device according to any one of [1] to [5], including a wave plate that emits linearly polarized light and converts linearly polarized light into circularly polarized light between the drawing device and the intermediate image screen. Projection system.
  • the projection image position adjusting optical element is one selected from the group consisting of a concave mirror, a Fresnel lens, a Fresnel reflection mirror, a convex lens, and a concave lens.
  • a wave plate for converting circularly polarized light into linearly polarized light is included in an optical path of light derived from reflected light from the intermediate image screen between the intermediate image screen and the projection image display member.
  • the projection image display member includes a layer in which a cholesteric liquid crystal phase is fixed, and at least one of the center wavelengths of substantial selective reflection exhibited by the projection image display member is substantially selected by the intermediate image screen.
  • the projection system according to any one of [8] to [11], which is the same as at least one of the central wavelengths of reflection.
  • a method for producing an intermediate image screen of a projection system Applying a liquid crystal composition containing a polymerizable liquid crystal compound to the surface of the isotropic resin layer, and forming a layer in which the cholesteric liquid crystal phase is fixed by curing the liquid crystal composition;
  • the isotropic resin layer is a hardened layer of a non-liquid crystalline polymerizable composition containing a (meth) acrylate monomer, gelatin, or a urethane monomer, or polyimide, polyvinyl alcohol, polyester, polyarylate, polyamideimide, polyetherimide Manufacturing method which is a resin layer containing a polymer selected from polyamide, and modified polyamide.
  • a projection system using a reflective intermediate image screen that gives a projected image with high brightness and high resolution.
  • the projection system of the present invention is particularly suitable for use in a projection system such as a head-up display, a head-mounted display, or the like that displays a projected image as a virtual image and simultaneously displays a front landscape.
  • FIG. 6 is a side view showing the arrangement of each member used in Example 3.
  • the angle for example, an angle such as “90 °”
  • the relationship thereof for example, “orthogonal”, “parallel”, “intersection at 45 °”, etc.
  • the range of allowable error is included.
  • the angle is within the range of strict angle ⁇ 10 °, and the error from the strict angle is preferably 5 ° or less, and more preferably 3 ° or less.
  • a numerical value, numerical range, and qualitative expression for example, an expression such as “identical”, etc.
  • a numerical value, numerical range It shall be interpreted as indicating properties. For example, when the wavelength is “same”, an error range of 3 nm or less, 5 nm or less, 7 nm or less, or 10 nm or less may be included.
  • (meth) acrylate is used to mean “one or both of acrylate and methacrylate”.
  • screen image means an image drawn on an intermediate image screen
  • projection image means an image projected by the projection system of the present invention.
  • the projected image is displayed on a projected image display member or displayed as a virtual image by the projected image display member.
  • the image may be called a real image.
  • Both the image and the projected image may be a single color image, a multicolor image of two or more colors, or a full color image.
  • “selective” for circularly polarized light means that the amount of light of either the right circularly polarized component or the left circularly polarized component of light is greater than that of the other circularly polarized component.
  • the degree of circular polarization of light is preferably 0.3 or more, more preferably 0.6 or more, and even more preferably 0.8 or more. More preferably, it is substantially 1.0. Table In / (I R + I L)
  • sense for circularly polarized light means right circularly polarized light or left circularly polarized light.
  • the sense of circularly polarized light is right-handed circularly polarized light when the electric field vector tip turns clockwise as time increases when viewed as the light travels toward you, and left when it turns counterclockwise. Defined as being circularly polarized.
  • the term “sense” is sometimes used for the twist direction of the spiral of the cholesteric liquid crystal.
  • the twist direction (sense) of the spiral of the cholesteric liquid crystal is right, it reflects right circularly polarized light and transmits left circularly polarized light.
  • the sense When the sense is left, it reflects left circularly polarized light and transmits right circularly polarized light.
  • light means visible light (natural light) unless otherwise specified.
  • Visible light is light having a wavelength that can be seen by the human eye among electromagnetic waves, and usually indicates light having a wavelength range of 380 nm to 780 nm.
  • the measurement of the light intensity required in connection with the calculation of the light transmittance may be performed by using, for example, a normal visible spectrum meter and measuring the reference as air.
  • “diffuse reflectance” or “regular reflectance” is a value calculated based on values measured using a spectrophotometer and an integrating sphere unit.
  • regular reflectance is based on a value measured using an integrating sphere unit, it may be a measured value at an incident angle of 5 °, for example, for convenience of measurement.
  • the diffuse reflectance is a value that can be calculated by subtracting the regular reflectance from the total reflectance (measured value of all angles of the integrating sphere).
  • haze means a value measured using a haze meter NDH-2000 manufactured by Nippon Denshoku Industries Co., Ltd.
  • the spectral haze is obtained by measuring the total light transmission spectrum and the diffuse transmission spectrum by attaching an integrating sphere unit to a spectrophotometer UV-3100PC manufactured by Shimadzu Corporation. It means a value obtained by calculating (diffuse transmittance / total transmittance).
  • the spectral haze spectrum shows a change according to the wavelength of the spectral haze.
  • the term “reflected light” or “transmitted light” is used to mean scattered light and diffracted light.
  • the polarization state of each wavelength of light can be measured using a spectral radiance meter or a spectrometer equipped with a circularly polarizing plate.
  • the intensity of the light measured through the right circular polarizing plate I R corresponds to I L.
  • ordinary light sources such as incandescent light bulbs, mercury lamps, fluorescent lamps, and LEDs emit almost natural light, but the characteristic of creating the polarization of the measurement object mounted on them is, for example, a polarization phase difference analysis manufactured by AXOMETRICS. It can be measured using an apparatus AxoScan or the like.
  • the polarization state can also be measured by attaching a circularly polarizing plate to an illuminometer or optical spectrum meter.
  • the ratio can be measured by attaching a right circular polarized light transmission plate, measuring the right circular polarized light amount, attaching a left circular polarized light transmission plate, and measuring the left circular polarized light amount.
  • the front phase difference is a value measured using an AxoScan manufactured by AXOMETRICS.
  • the measurement wavelength is 550 nm.
  • the front phase difference is a value measured with KOBRA 21ADH or WR (manufactured by Oji Scientific Instruments Co., Ltd.) by injecting light in the visible light wavelength region such as the central wavelength of selective reflection of the cholesteric liquid crystal layer in the film normal direction. It can also be used.
  • the wavelength selection filter can be exchanged manually, or the measurement value can be converted by a program or the like.
  • the birefringence ( ⁇ n) of a liquid crystal compound is the same as that described in p. It is a value measured according to the method described in 214. Specifically, by injecting a liquid crystal compound into a wedge-shaped cell that has been subjected to parallel alignment surface treatment, and measuring the interval between interference fringes using a polarizing microscope that can be observed with light having a wavelength of 550 nm by attaching an interference filter. ⁇ n at 60 ° C. can be obtained.
  • the “projection system” means a system including at least an image projection unit capable of projecting an image, and further includes a projection image display member for displaying a projection image projected by the image projection unit. May be included. In this combination, the image projection unit and the projection image display member may be separated from each other, or may be configured integrally.
  • the image projection unit includes a drawing device and an intermediate image screen. In the image projection unit, the drawing device and the intermediate image screen may be separated or may be integrated.
  • the drawing device and the intermediate image screen are arranged so that light emitted from the drawing device can be incident on the intermediate image screen.
  • the drawing device may draw an image on a part of the intermediate image screen or may draw the entire image, but 80% or more, preferably 90% or more, more preferably substantially, of the total area of the intermediate image screen. It is preferable that the image is drawn on the whole.
  • the projection system include a head-up display system and a head-mounted display system, and an image projection unit used in the head-up display system or the head-mounted display system; an image projection unit used in the see-through display system and the see-through display system; Examples thereof include an image projection unit used in the system and the like.
  • the head-up display system reference can be made to JP2013-79930A and International Publication WO2005 / 124431.
  • the projection system includes a drawing device.
  • the drawing device is a device that emits light that can draw an image using light from a light source.
  • the drawing device means a device including a light source, and further including a light modulator, a laser intensity modulating unit, a light deflecting unit for drawing, or the like.
  • a light source is not specifically limited, A laser light source, LED (light emitting diode), a discharge tube, etc. can be used. Of these, LEDs or laser light sources are preferred.
  • the LED is preferably used in combination with an LCOS (Liquid Crystal on Silicon) method or a DLP (registered trademark) method described later.
  • the laser light source can efficiently use the light emitted with excellent directivity, the energy use efficiency is high. Note that in a configuration with high energy use efficiency or light efficiency, the heat dissipating mechanism may be relatively small, so that noise derived from the heat dissipating mechanism is reduced, contributing to downsizing of the projection system.
  • the laser light source is not particularly limited, and a commercially available semiconductor laser that can irradiate light of a desired wavelength can be selected and used as appropriate.
  • the drawing method can be selected according to the light source to be used and the application, and is not particularly limited.
  • Examples of the drawing method include a liquid crystal display (LCD) method using liquid crystal, a liquid crystal on silicon (LCOS) method, a digital light processing (DLP) method, and a scanning method using a laser.
  • LCD liquid crystal display
  • LCOS liquid crystal on silicon
  • DLP digital light processing
  • the DLP system is a display system using DMD (Digital Micromirror Device), and is drawn by arranging micromirrors for the number of pixels, and light is emitted from a projection lens.
  • the scanning method is a method in which a light beam is scanned on a screen and an image is contrasted using an afterimage of an eye. For example, the descriptions in JP-A-7-270711 and JP-A-2013-228664 can be referred to.
  • laser light of each color for example, red light, green light, and blue light
  • laser light of each color whose luminance is modulated is bundled into one light beam by a multiplexing optical system or a condenser lens, and the light beam is deflected. It may be scanned by the means and drawn on the intermediate image screen.
  • the luminance modulation of laser light of each color may be performed directly as a change in intensity of the light source, or may be performed by an external modulator.
  • the light deflection means include a galvanometer mirror, a combination of a galvanometer mirror and a polygon mirror, or MEMS (microelectromechanical system).
  • MEMS is preferable.
  • the scanning method include a random scan method and a raster scan method, but it is preferable to use a raster scan method.
  • the laser beam can be driven by a resonance frequency in the horizontal direction and a sawtooth wave in the vertical direction, for example. Since the scanning system does not require a projection lens, the apparatus can be easily downsized.
  • the outgoing light from the drawing device may be polarized light (linearly polarized light) or natural light (non-polarized light).
  • polarized light linearly polarized light
  • natural light non-polarized light
  • the emitted light is essentially polarized.
  • the polarization directions (transmission axis directions) of the polarization of the plurality of lights are the same or orthogonal to each other. It is preferable.
  • the drawing device may be installed inside the housing and configured as a projector.
  • the housing is preferably formed of a light shielding material.
  • the intermediate image screen may be integrated with the drawing device to form a projector. At this time, the intermediate image screen may be inside the housing.
  • the projector in which the drawing device and the intermediate image screen are integrated may further include a projected image position adjusting optical element and / or a wave plate described later.
  • a drawing device, an intermediate image screen, and a projection image position adjusting optical element and / or a wave plate may be included inside the housing.
  • the projection system of the present invention includes an intermediate image screen.
  • an “intermediate image screen” is a member that is distinguished from a projection image display member, and is a screen on which an image is drawn. That is, the light emitted from the drawing device is not yet visible as an image, but the drawing device forms a visible image on the intermediate image screen by this light.
  • the intermediate image screen in the projection system of the present invention is a reflective intermediate image screen in which a projected image is formed by light derived from reflected light from the intermediate image screen.
  • the surface of the reflective intermediate image screen that receives and reflects light from the drawing device is referred to as a “reflective surface”.
  • light derived from the reflected light from the intermediate image screen means reflected light from the intermediate image screen; light reflected or transmitted from the projection image position adjusting optical element by the reflected light from the intermediate image screen; Light reflected from the image screen is transmitted through the wave plate; Light reflected from the intermediate image screen is reflected or transmitted through the projection position adjusting optical element; Light transmitted through the wavelength plate; Reflected light from the intermediate image screen is reflected The light transmitted through the wave plate means the light reflected or transmitted through the projection image position adjusting optical element.
  • the intermediate image screen includes a layer with a fixed cholesteric liquid crystal phase.
  • a layer in which a cholesteric liquid crystal phase is fixed may be referred to as a cholesteric liquid crystal layer or a liquid crystal layer.
  • the intermediate image screen includes a diffusely reflective cholesteric liquid crystal layer, the intermediate image screen has diffuse reflectivity with respect to light in a wavelength region in which the cholesteric liquid crystal layer exhibits selective reflection.
  • the cholesteric liquid crystal layer is twisted and oriented so as to have a helical axis in a direction substantially perpendicular to the layer surface, and exhibits selective reflection in the direction of the helical axis. It is considered not.
  • the present inventor has found that a high-luminance image can be formed and a high-luminance projected image can be obtained by using a cholesteric liquid crystal layer with diffuse reflection as an intermediate image screen.
  • a projection image display member In general, in a projection system, there may be a problem that light from a light source is reflected on a projection image display member together with a projection image.
  • an intermediate image screen using a diffusely reflective cholesteric liquid crystal layer may cause such a problem. Reflection can also be prevented.
  • the reflective surface of the intermediate image screen may be further matted, and a wedge-shaped base material is provided on the reflective surface so that the surface reflection light and the cholesteric liquid crystal layer The reflected light may be separated.
  • the diffuse reflectance of at least one surface of the intermediate image screen is preferably 25% or more at the central wavelength of selective reflection of the cholesteric liquid crystal layer included in the intermediate image screen. Furthermore, it may be 35% or more, 60% or more, 80% or more, 95% or less, 90% or less, and the like.
  • the intermediate image screen includes a plurality of cholesteric liquid crystal layers, the above may be satisfied at the center wavelength of at least one selective reflection of the included cholesteric liquid crystal layer, and preferably two or more of the included cholesteric liquid crystal layers, more preferably It is preferable that the above is satisfied in each of the light in the wavelength range in which all exhibit selective reflection.
  • the diffuse reflectance of the reflecting surface of the intermediate image screen preferably satisfies the above.
  • the intermediate image screen preferably includes two or more diffusely reflective cholesteric liquid crystal layers, and more preferably includes three or more layers.
  • the intermediate image screen may include layers such as an isotropic resin layer, a support, an adhesive layer, and a substrate in addition to the diffusely reflective cholesteric liquid crystal layer.
  • the intermediate image screen includes a cholesteric liquid crystal layer and a substrate, the cholesteric liquid crystal layer side is preferably a reflective surface.
  • the projection system of the present invention may further include a projection image display member.
  • projection image display member is a member that is distinguished from the intermediate image screen, and means a member for displaying a projection image.
  • the projected image display member is a half mirror that displays the projected image as a virtual image that appears above the projected image display member when viewed by the observer, even if it is a screen that displays the projected image on the surface as a real image. May be.
  • the projected image may be anything as long as the projected image projected with reflected light or transmitted light, preferably reflected light, can be displayed in a visible manner. Examples of the projection image display member include a projection screen and a projection image display half mirror.
  • the Brewster angle is used so that p-polarized light is incident on the projection image display member in the projection system of the present invention. It is also preferable to reduce the double image by making the reflected light from the surface of the projection image display member close to zero. That is, the incident light for displaying the projected image on the projected image display member is configured to be p-polarized light, and the incident light is 45 ° with respect to the normal of the incident light incident surface of the projected image display member. It is also preferable to set the angle to ⁇ 70 °.
  • p-polarized light means polarized light that oscillates in a direction parallel to the light incident surface.
  • the incident surface means a surface that is perpendicular to the reflection surface (such as the surface of the projection image display member) and includes the incident light beam and the reflected light beam.
  • the vibration plane of the electric field vector is parallel to the incident plane.
  • the intermediate image screen since the cholesteric liquid crystal layer is used for the intermediate image screen, when the sense of the cholesteric liquid crystal layer exhibiting selective reflection in a specific wavelength region is either the right or the left, the intermediate image screen The reflected light from the light becomes circularly polarized light.
  • a wave plate for converting circularly polarized light into linearly polarized light is provided between the intermediate image screen and the projected image display member so as to adjust the azimuth so that p polarized light is incident on the projected image display member. .
  • the projected image display member is a projection screen that displays a projected image on the surface
  • the screen is scattered and reflected with respect to the projection light wavelength in order to display the projected image on the screen.
  • a screen in which a diffusion layer formed by mixing fine particles with a binder and coating on a transparent medium is formed on the light incident side of the screen, or a screen including a diffuse reflective cholesteric liquid crystal layer.
  • a screen including a diffusely reflective cholesteric liquid crystal layer is used, and one of the center wavelengths of substantial selective reflection exhibited by the projection image display screen is one of the center wavelengths of substantial selective reflection exhibited by the intermediate image screen.
  • all of the substantial selective reflection center wavelengths indicated by the projected image display half mirror are the same as any of the substantial selective reflection center wavelengths indicated by the intermediate image screen.
  • a method for manufacturing a screen including a diffusely reflective cholesteric liquid crystal layer will be described later.
  • the projected image display half mirror is capable of displaying the projected image as a virtual image so that the projected image can be viewed visually, and information on the opposite side of the projected image display half mirror from the same surface on which the projected image is displayed or It means an optical member that can observe a landscape at the same time. That is, the projected image display half mirror can achieve a function as an optical path combiner that displays the ambient light and the image light in a superimposed manner.
  • a projection image display half mirror with high selective reflectivity for each selected wavelength band for example, a projection image display half mirror including a cholesteric liquid crystal layer and DBEF (registered trademark) (manufactured by 3M) is used. A half mirror etc. are mentioned.
  • a projection image display half mirror including a cholesteric liquid crystal layer is used, and one of the center wavelengths of substantial selective reflection indicated by the half mirror for projection image display and one of the center wavelengths of substantial selective reflection indicated by the intermediate image screen.
  • a projected image (virtual image) with high light utilization efficiency and high brightness.
  • all of the substantial selective reflection center wavelengths indicated by the projected image display half mirror are the same as any of the substantial selective reflection center wavelengths indicated by the intermediate image screen.
  • a method for manufacturing a projection image display half mirror including a cholesteric liquid crystal layer will be described later.
  • projected video display half mirrors include a head-up display system (HUD) combiner, windshield glass, a reflective screen for a see-through display, and a reflective mirror for a head-mounted display.
  • the combiner can be integrated with an image projection unit including a drawing device and an intermediate image screen to constitute a head-up display device.
  • FIG. 26 Japanese Patent Application Laid-Open No. 2014-21391.
  • the windshield glass is a half mirror for displaying a projected image
  • double images can be reduced with a windshield glass made of laminated glass having a wedge-shaped cross section as described in JP 2011-505330 A.
  • the half mirror film including the cholesteric liquid crystal layer may be adhered to the incident light incident surface of the windshield glass or included in the intermediate layer of the windshield glass including the laminated glass.
  • the emitted light from the drawing device may be reflected by the intermediate image screen and further projected onto the projection image display member via the projection image position adjusting optical element.
  • the adjusting optical element may also be inside the housing.
  • the projected image position adjusting optical element can be provided for adjusting the direction of the projection light and adjusting the size of the projected image. Examples of the projection image position adjusting optical element include a concave mirror, a Frennel lens, a Frennel reflection mirror, a convex lens, and a concave lens.
  • the positions of the intermediate image screen and the projected image position adjusting optical element may be adjusted so that the projected image is displayed at a desired position in a desired size. Even if these position adjustments are performed appropriately, for example, when the projected image is enlarged using a concave mirror, aberrations such as distortion may occur in the projected image. In such a case, distortion can be eliminated by designing the intermediate image screen to have a curved surface such as a concave surface. In the projection system of the present invention, since the cholesteric liquid crystal layer is used for the intermediate image screen, it can be easily formed into a curved surface.
  • a wave plate for converting linearly polarized light into circularly polarized light is included between the drawing device and the intermediate image screen. This is because, by converting linearly polarized light into circularly polarized light having a sense that matches the sense of selectively polarized circularly polarized light based on the cholesteric liquid crystal layer in the intermediate image screen, it is possible to project with high light utilization efficiency.
  • an intermediate image screen using a cholesteric liquid crystal layer can be configured so that the sense of reflected circularly polarized light is different for each wavelength range of red, green, and blue light.
  • a design suitable for the drawing device can be performed.
  • An example of a wave plate that converts linearly polarized light into circularly polarized light is a retardation plate that functions as a quarter wave plate.
  • the quarter-wave plate include a one-quarter-type quarter-wave retardation plate, a broadband quarter-wave retardation plate in which a quarter-wave retardation plate and a half-wave retardation plate are stacked, and the like.
  • the front phase difference of the former 1 ⁇ 4 wavelength phase difference plate may be a length of 1 ⁇ 4 of the projection light wavelength.
  • the wavelength of 450 nm is 112.5 nm ⁇ 10 nm, preferably 112.5 nm ⁇ 5 nm, more preferably 112.5 nm, and 530 nm.
  • the plate is most preferable as the former quarter-wave retardation plate, a retardation plate having a small retardation wavelength dispersion or a forward dispersion retardation plate can also be used.
  • the reverse dispersion means a property that the absolute value of the phase difference becomes larger as the wavelength becomes longer, and the forward dispersion means a property that the absolute value of the phase difference becomes larger as the wavelength becomes shorter.
  • the latter laminated type quarter-wave retardation plate is formed by laminating a quarter-wave retardation plate and a half-wave retardation plate at an angle of about 60 ° with respect to the slow axis.
  • the retardation plate side By arranging the retardation plate side on the incident side of linearly polarized light and crossing the slow axis of the half-wave retardation plate at 15 ° or 75 ° with respect to the polarization plane of the incident linearly polarized light, It converts to circularly polarized light. Since the reverse dispersion of the phase difference is good, it can be suitably used.
  • the quarter-wave retardation plate may be a commercially available product using a birefringent material such as quartz, or may be formed by arranging and fixing a polymerizable liquid crystal compound or a polymer liquid crystal compound.
  • the type of liquid crystal compound used for this formation is not particularly limited.
  • an optically anisotropic layer obtained by forming a low-molecular liquid crystal compound in a nematic alignment in a liquid crystal state and then fixing by photocrosslinking or thermal cross-linking, or a polymer liquid crystal compound in a nematic alignment in a liquid crystal state and then cooling Accordingly, an optically anisotropic layer obtained by fixing the orientation can also be used.
  • a wave plate that converts linearly polarized light into circularly polarized light can also be used as a wave plate that converts circularly polarized light into linearly polarized light.
  • the reflected circularly polarized light is converted into linearly polarized light, and the projection image display member is Then, it may be incident as p-polarized light.
  • the intermediate image screen in the projection system of the present invention includes a cholesteric liquid crystal layer.
  • the projected image display member may include a cholesteric liquid crystal layer.
  • the cholesteric liquid crystal phase selectively reflects circularly polarized light of either right circularly polarized light or left circularly polarized light in a specific wavelength region and selectively transmits circularly polarized light of the other sense. It is known to show.
  • the cholesteric liquid crystal layer may be a layer in which the orientation of the liquid crystal compound in the cholesteric liquid crystal phase is maintained.
  • the polymerizable liquid crystal compound is placed in the orientation state of the cholesteric liquid crystal phase and then irradiated with ultraviolet rays.
  • Any layer may be used as long as it is polymerized and cured by heating or the like to form a layer having no fluidity, and at the same time, the layer is changed to a state in which the orientation is not changed by an external field or an external force.
  • the polymerizable liquid crystal compound may be polymerized by a curing reaction and may no longer have liquid crystallinity.
  • the selective reflection center wavelength and the half width of the cholesteric liquid crystal layer can be obtained as follows. When the transmission spectrum of the light reflection layer (measured from the normal direction of the cholesteric liquid crystal layer) is measured using a spectrophotometer UV3150 (Shimadzu Corporation), a reduction peak in transmittance is observed in the selective reflection band.
  • the wavelength value on the short wavelength side is selected from the two wavelengths that have a transmittance of half the peak height (transmittance between the lowest transmittance and the transmittance before the decrease). If ⁇ 1 (nm) and the wavelength value on the long wave side are ⁇ 2 (nm), the center wavelength and the half-value width of selective reflection can be expressed by the following equations.
  • the center wavelength of selective reflection means the center wavelength when measured from the normal direction of the cholesteric liquid crystal layer.
  • the center wavelength of selective reflection can be adjusted by adjusting the pitch of the helical structure.
  • the center wavelength ⁇ can be adjusted in order to selectively reflect either the right circularly polarized light or the left circularly polarized light with respect to light of a desired wavelength by adjusting the n value and the P value.
  • the central wavelength of selective reflection when a light ray passes at an angle of ⁇ 2 with respect to the normal direction of the cholesteric liquid crystal layer (the helical axis direction of the cholesteric liquid crystal layer) is ⁇ d .
  • ⁇ d is expressed by the following equation.
  • ⁇ d n 2 ⁇ P ⁇ cos ⁇ 2
  • the wavelength ⁇ d determined according to ⁇ 2 in consideration of the arrangement of the intermediate image screen and the projection image display member in the projection system and the light incident direction is referred to as “substantially selective reflection center wavelength”.
  • the pitch of the cholesteric liquid crystal phase depends on the type of chiral agent used together with the polymerizable liquid crystal compound or the concentration of the chiral agent, a desired pitch can be obtained by adjusting these.
  • a desired pitch can be obtained by adjusting these.
  • the intermediate image screen and the projection image display member are respectively a cholesteric liquid crystal layer having a central wavelength of selective reflection in the red light wavelength region, a cholesteric liquid crystal layer having a central wavelength of selective reflection in the green light wavelength region, and blue It is preferable to include a cholesteric liquid crystal layer having a central wavelength of selective reflection in the wavelength region of light.
  • the reflective layer is, for example, a cholesteric liquid crystal layer having a central wavelength of selective reflection in 400 nm to 500 nm, a cholesteric liquid crystal layer having a central wavelength of selective reflection in 500 nm to 580 nm, and a cholesteric liquid crystal having a central wavelength of selective reflection in 580 nm to 700 nm. It is preferable to include a layer.
  • each of the plurality of layers is a diffuse reflective cholesteric liquid crystal layer.
  • a bright image with high light utilization efficiency can be formed by adjusting the center wavelength of selective reflection of the cholesteric liquid crystal layer used in the intermediate image screen according to the wavelength range of the emitted light of the drawing device.
  • the central wavelength of selective reflection of the cholesteric liquid crystal layer used in the projection image display member By adjusting the central wavelength of selective reflection of the cholesteric liquid crystal layer used in the projection image display member according to the wavelength range of light incident as light derived from the reflected light of the intermediate image screen, the light utilization efficiency is high and the luminance is high. Projected images can be displayed.
  • the center wavelength of substantial selective reflection of the cholesteric liquid crystal layer used in the intermediate image screen is preferably the same as the center wavelength of substantial selective reflection of the cholesteric liquid crystal layer used in the projection image display member.
  • each cholesteric liquid crystal layer a cholesteric liquid crystal layer whose spiral sense is either right or left is used.
  • the sense of reflected circularly polarized light in the cholesteric liquid crystal layer coincides with the sense of a spiral.
  • the spiral senses of the plurality of cholesteric liquid crystal layers may all be the same or different. That is, either the right or left sense cholesteric liquid crystal layer may be included, or both the right and left sense cholesteric liquid crystal layers may be included.
  • the intermediate image screen When the light incident on the intermediate image screen from the drawing device is linearly polarized light or natural light (non-polarized light), the intermediate image screen has both right and left for each wavelength range of incident light from the drawing device. Inclusion of the sense cholesteric liquid crystal layer enables efficient reflection of incident light. On the other hand, when the light emitted from the drawing device enters the intermediate image screen via the wave plate, the incident light becomes circularly polarized light, so that either one of the senses is detected for each wavelength region of the incident light from the drawing device. It only needs to include a cholesteric liquid crystal layer.
  • the spiral sense of each cholesteric liquid crystal layer may be determined according to the sense of incident circularly polarized light at the selective reflection wavelength of each cholesteric liquid crystal layer. Specifically, a cholesteric liquid crystal layer having a spiral sense that reflects circularly polarized light of the sense obtained by being emitted from the drawing device and transmitted through the wavelength plate may be selected and used for each selected wavelength range.
  • the projection image display member may reflect the circularly polarized light of only one sense or the circularly polarized light of both right and left senses for each selective reflection wavelength range.
  • the projected image display half mirror preferably reflects circularly polarized light of only one of the senses for each selective reflection wavelength region.
  • the spiral sense of the cholesteric liquid crystal layer having the central wavelength of selective reflection in the light wavelength range is the center wavelength of selective reflection in the wavelength range of blue light and the cholesteric liquid crystal layer having the central wavelength of selective reflection in the wavelength range of red light.
  • the incident light may be reflected in each wavelength region.
  • ⁇ n can be adjusted by adjusting the kind of the polymerizable liquid crystal compound and the mixing ratio thereof, or by controlling the temperature at the time of fixing the alignment.
  • a plurality of cholesteric liquid crystal layers having the same pitch P and the same spiral sense may be stacked. By laminating cholesteric liquid crystal layers having the same pitch P and the same spiral sense, the circularly polarized light selectivity can be increased at a specific wavelength.
  • the wavelength range of selective reflection of the cholesteric liquid crystal layer is limited, the color purity of each color is high in an image of an intermediate image screen including a plurality of cholesteric liquid crystal layers having central wavelengths of selective reflection in different wavelength ranges. Therefore, an image having a color reproduction range wider than the color reproduction range of the drawing device itself, and thus a projected image can be obtained. Also, in projection systems such as head-up displays, external light such as sunlight enters from the exit of the projection light and enters (collects) the intermediate image screen, which degrades the drawing device by the reflected or transmitted light. May end up.
  • a cholesteric liquid crystal layer is used for the intermediate image screen, and the cholesteric liquid crystal layer has a limited selective reflection band showing reflection as described above, so that the amount of reflected light to the drawing device is reduced. Can be reduced.
  • cholesteric liquid crystal layer ⁇ Method for producing cholesteric liquid crystal layer>
  • the material used for forming the cholesteric liquid crystal layer include a liquid crystal composition containing a polymerizable liquid crystal compound and a chiral agent (optically active compound). If necessary, apply the above liquid crystal composition, which is further mixed with a surfactant or a polymerization initiator and dissolved in a solvent, to a support, an isotropic resin layer alignment film, a lower cholesteric liquid crystal layer, etc. After ripening the cholesteric alignment, it can be fixed by curing the liquid crystal composition to form a cholesteric liquid crystal layer.
  • the polymerizable liquid crystal compound may be a rod-like liquid crystal compound or a disk-like liquid crystal compound, but is preferably a rod-like liquid crystal compound.
  • Examples of the rod-like polymerizable liquid crystal compound forming the cholesteric liquid crystal layer include a rod-like nematic liquid crystal compound.
  • rod-like nematic liquid crystal compounds examples include azomethines, azoxys, cyanobiphenyls, cyanophenyl esters, benzoic acid esters, cyclohexanecarboxylic acid phenyl esters, cyanophenylcyclohexanes, cyano-substituted phenylpyrimidines, alkoxy-substituted phenylpyrimidines.
  • Phenyldioxanes, tolanes and alkenylcyclohexylbenzonitriles are preferably used. Not only low-molecular liquid crystal compounds but also high-molecular liquid crystal compounds can be used.
  • the polymerizable liquid crystal compound can be obtained by introducing a polymerizable group into the liquid crystal compound.
  • the polymerizable group include an unsaturated polymerizable group, an epoxy group, and an aziridinyl group, preferably an unsaturated polymerizable group, and particularly preferably an ethylenically unsaturated polymerizable group.
  • the polymerizable group can be introduced into the molecule of the liquid crystal compound by various methods.
  • the number of polymerizable groups possessed by the polymerizable liquid crystal compound is preferably 1 to 6, more preferably 1 to 3. Examples of polymerizable liquid crystal compounds are described in Makromol. Chem. 190, 2255 (1989), Advanced Materials 5, 107 (1993), US Pat. No.
  • the addition amount of the polymerizable liquid crystal compound in the liquid crystal composition is preferably 80 to 99.9% by mass with respect to the solid content mass (mass excluding the solvent) of the liquid crystal composition, and is preferably 85 to 99. It is more preferably 5% by mass, particularly preferably 90 to 99% by mass.
  • a wavelength range of selective reflection is obtained by forming a cholesteric liquid crystal phase using a low ⁇ n polymerizable liquid crystal compound and fixing it. Narrow cholesteric liquid crystal layer can be obtained.
  • a cholesteric liquid crystal layer having a narrow selective reflection wavelength range the color purity is further improved, and thus an image with a wider color reproduction range can be obtained.
  • a cholesteric liquid crystal layer having a narrow selective reflection wavelength region it is possible to further prevent the drawing device from being deteriorated due to the above-described light collection.
  • Examples of the low ⁇ n polymerizable liquid crystal compound include compounds represented by the following formula (I) in addition to the compounds described in International Publication WO2015 / 115390.
  • A represents a phenylene group which may have a substituent or a trans-1,4-cyclohexylene group which may have a substituent
  • L is a single bond, —CH 2 O—, —OCH 2 —, — (CH 2 ) 2 OC ( ⁇ O) —, —C ( ⁇ O) O (CH 2 ) 2 —, —C ( ⁇ O) O Selected from the group consisting of —, —OC ( ⁇ O) —, —OC ( ⁇ O) O—, —CH ⁇ CH—C ( ⁇ O) O—, and —OC ( ⁇ O) —CH ⁇ CH—.
  • a linking group m represents an integer of 3 to 12
  • Sp 1 and Sp 2 are each independently one or more of a single bond, a linear or branched alkylene group having 1 to 20 carbon atoms, and a linear or branched alkylene group having 1 to 20 carbon atoms.
  • CH 2 — is —O—, —S—, —NH—, —N (CH 3 ) —, —C ( ⁇ O) —, —OC ( ⁇ O) —, or —C ( ⁇ O) O—.
  • the compound represented by the formula (I) includes, as A, a trans-1,4-cyclohexylene group which contains at least one phenylene group which may have a substituent and may have a substituent. It is preferable to include at least one.
  • Preferred examples of the compound represented by the formula (I) include compounds represented by the following formula (II-2).
  • a 1 and A 2 each independently represent a phenylene group which may have a substituent or a trans-1,4-cyclohexylene group which may have a substituent.
  • each of the above substituents is independently 1 to 4 substituents selected from the group consisting of an alkyl group, an alkoxy group, and —C ( ⁇ O) —X 3 —Sp 3 —Q 3.
  • R 1 and R 2 each independently represents a group selected from the group consisting of a hydrogen atom, an alkyl group, an alkoxy group, and a group represented by —C ( ⁇ O) —X 3 —Sp 3 —Q 3 .
  • X 3 represents a single bond, —O—, —S—, or —N (Sp 4 -Q 4 ) —, or represents a nitrogen atom that forms a ring structure with Q 3 and Sp 3.
  • X 3 is preferably a single bond or —O—.
  • Sp 3 and Sp 4 each independently represent one or more of a single bond, a linear or branched alkylene group having 1 to 20 carbon atoms, and a linear or branched alkylene group having 1 to 20 carbon atoms.
  • CH 2 — is —O—, —S—, —NH—, —N (CH 3 ) —, —C ( ⁇ O) —, —OC ( ⁇ O) —, or —C ( ⁇ O) O—.
  • a linking group selected from the group consisting of substituted groups is shown.
  • Q 3 and Q 4 are each independently a hydrogen atom, a cycloalkyl group, or a cycloalkyl group in which one or more —CH 2 — is —O—, —S—, —NH—, —N (CH 3 ) —, —C ( ⁇ O) —, —OC ( ⁇ O) —, or a group substituted with —C ( ⁇ O) O—, or a group represented by Formulas Q-1 to Q-5 Any polymerizable group selected from the group consisting of:
  • R 1 and R 2 are preferably —C ( ⁇ O) —X 3 —Sp 3 —Q 3 .
  • R 1 and R 2 are preferably the same as each other.
  • the bonding position of each of R 1 and R 2 to the phenylene group is not particularly limited.
  • L 1 and L 2 are a single bond, —CH 2 O—, —OCH 2 —, — (CH 2 ) 2 OC ( ⁇ O) —, —C ( ⁇ O) O (CH 2 ) 2 —, — C ( ⁇ O) O—, —OC ( ⁇ O) —, —OC ( ⁇ O) O—, —CH ⁇ CH—C ( ⁇ O) O—, —OC ( ⁇ O) —CH ⁇ CH—,
  • a linking group selected from the group consisting of: N1 and n2 each independently represent an integer of 0 to 9, and n1 + n2 is 9 or less.
  • Formula (II-2) is a phenylene group which may have a substituent and a trans-1,4-cyclohexylene group which may have a substituent (preferably unsubstituted trans-1,4- A structure in which (cyclohexylene groups) are alternately arranged is also preferable.
  • the chiral agent has a function of inducing a helical structure of a cholesteric liquid crystal phase.
  • the chiral compound may be selected according to the purpose because the helical sense or helical pitch induced by the compound is different.
  • limiting in particular as a chiral agent A well-known compound can be used.
  • Examples of chiral agents include liquid crystal device handbook (Chapter 3, Section 4-3, TN, chiral agent for STN, 199 pages, edited by Japan Society for the Promotion of Science, 142th Committee, 1989), JP-A 2003-287623, Examples thereof include compounds described in JP-A No. 2002-302487, JP-A No. 2002-80478, JP-A No. 2002-80851, JP-A No. 2010-181852 or JP-A No. 2014-034581.
  • a chiral agent generally contains an asymmetric carbon atom, but an axially asymmetric compound or a planar asymmetric compound containing no asymmetric carbon atom can also be used as the chiral agent.
  • the axial asymmetric compound or the planar asymmetric compound include binaphthyl, helicene, paracyclophane, and derivatives thereof.
  • the chiral agent may have a polymerizable group. When both the chiral agent and the liquid crystal compound have a polymerizable group, they are derived from the repeating unit derived from the polymerizable liquid crystal compound and the chiral agent by a polymerization reaction between the polymerizable chiral agent and the polymerizable liquid crystal compound.
  • the polymerizable group possessed by the polymerizable chiral agent is preferably the same group as the polymerizable group possessed by the polymerizable liquid crystal compound. Therefore, the polymerizable group of the chiral agent is also preferably an unsaturated polymerizable group, an epoxy group or an aziridinyl group, more preferably an unsaturated polymerizable group, and an ethylenically unsaturated polymerizable group. Particularly preferred.
  • the chiral agent may be a liquid crystal compound.
  • an isosorbide derivative As the chiral agent, an isosorbide derivative, an isomannide derivative, or a binaphthyl derivative can be preferably used.
  • an isosorbide derivative a commercial product such as LC-756 manufactured by BASF may be used.
  • the content of the chiral agent in the liquid crystal composition is preferably 0.01 mol% to 200 mol%, more preferably 1 mol% to 30 mol%, based on the amount of the polymerizable liquid crystal compound.
  • the liquid crystal composition preferably contains a polymerization initiator.
  • the polymerization initiator to be used is preferably a photopolymerization initiator that can start the polymerization reaction by ultraviolet irradiation.
  • photopolymerization initiators include ⁇ -carbonyl compounds (described in US Pat. Nos. 2,367,661 and 2,367,670), acyloin ether (described in US Pat. No. 2,448,828), ⁇ -hydrocarbon substituted aromatics.
  • Group acyloin compounds described in US Pat. No. 2,722,512
  • polynuclear quinone compounds described in US Pat.
  • acyl phosphine oxide compound As the polymerization initiator, it is also preferable to use an acyl phosphine oxide compound or an oxime compound.
  • acylphosphine oxide compound for example, IRGACURE819 (compound name: bis (2,4,6-trimethylbenzoyl) -phenylphosphine oxide) manufactured by BASF Japan Ltd. can be used.
  • oxime compounds examples include IRGACURE OXE01 (manufactured by BASF), IRGACURE OXE02 (manufactured by BASF), TR-PBG-304 (manufactured by Changzhou Strong Electronic New Materials Co., Ltd.), Adeka Arcles NCI-831, Adeka Arcles NCI-930 Commercial products such as (ADEKA) and Adeka Arcles NCI-831 (ADEKA) can be used. Only one type of polymerization initiator may be used, or two or more types may be used in combination.
  • the content of the photopolymerization initiator in the liquid crystal composition is preferably 0.1 to 20% by mass, and preferably 0.5 to 5% by mass with respect to the content of the polymerizable liquid crystal compound. Further preferred.
  • the liquid crystal composition may optionally contain a crosslinking agent in order to improve the film strength after curing and improve the durability.
  • a crosslinking agent one that can be cured by ultraviolet rays, heat, moisture, or the like can be suitably used.
  • polyfunctional acrylate compounds such as a trimethylol propane tri (meth) acrylate and pentaerythritol tri (meth) acrylate
  • Glycidyl (meth) acrylate Epoxy compounds such as ethylene glycol diglycidyl ether; aziridine compounds such as 2,2-bishydroxymethylbutanol-tris [3- (1-aziridinyl) propionate], 4,4-bis (ethyleneiminocarbonylamino) diphenylmethane; hexa Isocyanate compounds such as methylene diisocyanate and biuret type isocyanate; polyoxazoline compounds having an oxazoline group in the side chain; vinyltrimethoxysilane, N- (2-aminoethyl) 3-aminopropylto Alkoxysilane compounds such as methoxy silane.
  • a well-known catalyst can be used according to the reactivity of a crosslinking agent, and productivity can be improved in addition to membrane strength and durability improvement. These may be used individually by 1 type and may use 2 or more types together.
  • the content of the crosslinking agent is preferably 3% by mass to 20% by mass, and more preferably 5% by mass to 15% by mass. When the content of the crosslinking agent is less than 3% by mass, the effect of improving the crosslinking density may not be obtained. When the content exceeds 20% by mass, the stability of the cholesteric liquid crystal layer may be decreased.
  • alignment control agent horizontal alignment agent
  • an alignment control agent that contributes to stably or rapidly forming a cholesteric liquid crystal layer having a planar alignment
  • the alignment control agent include fluorine (meth) acrylate polymers described in paragraphs [0018] to [0043] of JP-A-2007-272185, and paragraphs [0031] to [0034] of JP-A-2012-203237.
  • 1 type may be used independently and 2 or more types may be used together.
  • the addition amount of the alignment control agent in the liquid crystal composition is preferably 0.01% by mass to 10% by mass, more preferably 0.01% by mass to 5% by mass with respect to the total mass of the polymerizable liquid crystal compound. 0.02% by mass to 1% by mass is particularly preferable.
  • the liquid crystal composition may contain at least one selected from a surfactant for adjusting the surface tension of the coating film to make the thickness uniform, and various additives such as a polymerizable monomer.
  • a polymerization inhibitor, an antioxidant, an ultraviolet absorber, a light stabilizer, a colorant, metal oxide fine particles, and the like may be added as long as the optical performance is not deteriorated. Can be added.
  • a cholesteric liquid crystal layer is prepared by preparing a liquid crystal composition in which a polymerizable liquid crystal compound and a polymerization initiator, a chiral agent added as necessary, a surfactant, and the like are dissolved in a solvent, a support, an alignment layer, or first.
  • the cholesteric liquid crystal layer is coated on the cholesteric liquid crystal layer and dried to obtain a coating film.
  • the coating film is irradiated with actinic rays to polymerize the cholesteric liquid crystal composition. Can be formed.
  • a laminated film including a plurality of cholesteric liquid crystal layers can be formed by repeatedly performing a manufacturing process of the cholesteric liquid crystal layer.
  • solvent there is no restriction
  • the organic solvent is not particularly limited and may be appropriately selected depending on the intended purpose. For example, ketones, alkyl halides, amides, sulfoxides, heterocyclic compounds, hydrocarbons, esters, ethers, etc. Is mentioned. These may be used individually by 1 type and may use 2 or more types together. Among these, ketones are particularly preferable in consideration of environmental load.
  • the method for applying the liquid crystal composition to the support, the alignment film, the underlying cholesteric liquid crystal layer, etc. is not particularly limited and can be appropriately selected according to the purpose.
  • a wire bar coating method, a curtain coating method examples include extrusion coating, direct gravure coating, reverse gravure coating, die coating, spin coating, dip coating, spray coating, and slide coating. It can also be carried out by transferring a liquid crystal composition separately coated on a support.
  • the liquid crystal molecules are aligned by heating the applied liquid crystal composition.
  • the heating temperature is preferably 200 ° C. or lower, and more preferably 130 ° C. or lower.
  • the aligned liquid crystal compound can be further polymerized to cure the liquid crystal composition.
  • the polymerization may be either thermal polymerization or photopolymerization utilizing light irradiation, but photopolymerization is preferred. It is preferable to use ultraviolet rays for light irradiation.
  • the irradiation energy is preferably 20mJ / cm 2 ⁇ 50J / cm 2, 100mJ / cm 2 ⁇ 1,500mJ / cm 2 is more preferable.
  • light irradiation may be performed under heating conditions or in a nitrogen atmosphere.
  • the irradiation ultraviolet wavelength is preferably 350 nm to 430 nm.
  • the polymerization reaction rate is preferably high from the viewpoint of stability, preferably 70% or more, and more preferably 80% or more.
  • the polymerization reaction rate can be determined by measuring the consumption ratio of the polymerizable functional group using an IR absorption spectrum.
  • the intermediate image screen includes a diffusely reflective cholesteric liquid crystal layer.
  • the projection screen may include a diffusely reflective cholesteric liquid crystal layer.
  • the diffuse reflectance of the diffusely reflective cholesteric liquid crystal layer is preferably 25% or more at the central wavelength of selective reflection of the cholesteric liquid crystal layer. Furthermore, it may be 30% or more, 35% or more, 40% or more, 47% or less, 45% or less, 42% or less, and the like.
  • the cholesteric liquid crystal layer included in the projected image display half mirror is preferably not diffusely reflective.
  • the diffuse reflectance is less than 10%, 5% or less at the central wavelength of selective reflection of the cholesteric liquid crystal layer, or 3% or less is preferable
  • the intermediate image screen Due to the diffusely reflective cholesteric liquid crystal layer, the intermediate image screen exhibits a maximum value in the spectral haze spectrum in the wavelength range showing selective reflection of the cholesteric liquid crystal layer. For example, when the intermediate image screen includes three cholesteric liquid crystal layers having different selective reflection center wavelengths, the intermediate image screen has three maximum values in the spectral haze spectrum.
  • the diffusely reflective cholesteric liquid crystal layer can be obtained by making the tilt angle of liquid crystal molecules small on at least one surface of the layer, preferably both surfaces of the layer, and making the in-plane orientation direction of the liquid crystal molecules random. That is, the diffuse reflectance of the cholesteric liquid crystal layer can be adjusted by adjusting the tilt angle and the in-plane orientation direction.
  • the liquid crystal alignment direction and tilt angle in the vicinity of the cholesteric liquid crystal layer surface may be confirmed by a transmission electron microscope (TEM) image or the like in the vicinity of the film surface in the cross section of the cholesteric liquid crystal layer.
  • TEM transmission electron microscope
  • the tilt angle and the in-plane orientation direction of the liquid crystal molecules on the surface of the cholesteric liquid crystal layer as described above, it is possible to realize a configuration having the inclination of the helical axis of the cholesteric liquid crystal phase on the outermost surface.
  • Having the inclination of the helical axis means that there is a position in a plane where the inclination of the helical axis described later is 2 ° or more. It is considered that the spiral axis of the cholesteric liquid crystal phase can be distributed with a slight undulation in the plane by the configuration having the inclination of the spiral axis of the cholesteric liquid crystal phase on the outermost surface. That is, a shift of the helical axis from the normal direction of the layer can be caused. Due to the deviation of the helical axis, a diffuse reflective layer is formed. Within this layer, there may be a plurality of alignment defects.
  • the inclination of the spiral axis on the outermost surface of the cholesteric liquid crystal layer can be obtained as follows.
  • a stripe pattern of a bright part and a dark part can be observed.
  • the stripe pattern is observed so that the bright part and the dark part are repeated in a direction substantially parallel to the layer surface.
  • a schematic diagram is shown in FIG. Two repetitions of this bright part and dark part (two bright parts and two dark parts) correspond to one pitch of the spiral.
  • the normal direction of the striped pattern is the spiral axis.
  • the inclination of the spiral axis of the outermost surface of the cholesteric liquid crystal layer can be obtained as an angle between the outermost surface 100 and the outermost surface on the same side as the line formed by the first dark portion (101 in FIG. 1).
  • the cholesteric liquid crystal layer By configuring the cholesteric liquid crystal layer so that the inclination of the outermost helical axis changes in the plane, it is possible to obtain a scattering layer having a high diffuse reflectance.
  • “the inclination of the spiral axis is changing” means, for example, a state in which an increase and a decrease in the straight line traveling direction are confirmed when the inclination of the spiral axis is measured at a constant interval on an arbitrary straight line on the surface. .
  • the increase and decrease are preferably repeated and the change is preferably continuous.
  • the outermost surface may be at least one of the cholesteric liquid crystal layers (the uppermost surface or the lowermost surface) or both (the uppermost surface and the lowermost surface), but preferably both.
  • the maximum value of the inclination of the helical axis may be 2 ° or more and 20 ° or less, and is preferably 5 ° or more and 20 ° or less.
  • the tilt angle means an angle formed by tilted liquid crystal molecules with a layer plane, and the maximum refractive index direction of the refractive index ellipsoid of the liquid crystal compound with respect to the layer plane is the maximum. Means the angle. Therefore, in the rod-like liquid crystal compound having positive optical anisotropy, the tilt angle means an angle formed by the major axis direction of the rod-like liquid crystal compound, that is, the director direction and the layer plane.
  • the in-plane orientation direction of the liquid crystal molecule means an orientation in a plane parallel to the layer in the direction of the maximum refractive index of the liquid crystal molecule.
  • the in-plane orientation azimuth is random when the liquid crystal molecules having an in-plane orientation azimuth different from the average azimuth of the in-plane liquid crystal compound molecules by 4 ° or more are 10% to 20% by TEM. It means a state that can be done.
  • the term “liquid crystal molecule” means a molecule of a polymerizable liquid crystal compound in the liquid crystal composition, and when the polymerizable liquid crystal compound is polymerized by a curing reaction of the liquid crystal composition, the above-described polymerizable property. This means a partial structure corresponding to a liquid crystal compound molecule.
  • the tilt angle of the liquid crystal molecules on the lower layer side surface is preferably in the range of 0 ° to 20 °, more preferably in the range of 0 ° to 15 °. 0 ° to 10 ° is more preferable.
  • the density of orientation defects and the inclination angle distribution of the helical axis can be set within a preferable range.
  • the tilt angle (pretilt angle) of the liquid crystal molecules on the lower layer side surface is low as described above, preferably horizontal, and the alignment uniformity of the liquid crystal molecules
  • an orientation treatment such as rubbing on the surface of an isotropic resin layer or a substrate to be applied with the liquid crystal composition, which will be described later, or the surface of another cholesteric liquid crystal layer.
  • an isotropic resin layer is preferably used as a lower layer to which the liquid crystal composition is applied in the formation of at least one cholesteric liquid crystal layer.
  • the isotropic resin layer refers to a resin layer that is optically isotropic.
  • the isotropic resin layer may be included in the intermediate image screen, used only when forming the cholesteric liquid crystal layer, and may not be included in the intermediate image screen.
  • As the isotropic resin layer a layer made of a material that gives a low pretilt angle to the polymerizable liquid crystal compound molecules in the liquid crystal composition provided on the surface thereof can be preferably used.
  • the isotropic resin layer for example, a non-liquid crystalline polymerizable composition containing (meth) acrylate monomer, gelatin, urethane monomer and the like can be applied and cured.
  • a non-liquid crystalline polymerizable composition containing (meth) acrylate monomer, gelatin, urethane monomer and the like can be applied and cured.
  • an acrylic layer obtained by applying and curing a layer containing a (meth) acrylate monomer is isotropic in the plane. Therefore, if a liquid crystal layer is formed without rubbing the acrylic layer surface, the acrylic layer is in contact with the acrylic layer.
  • the in-plane orientation direction of the liquid crystal is random.
  • a cholesteric liquid crystal layer formed by applying a liquid crystal composition on the surface of the acrylic layer can be a layer having alignment defects.
  • a liquid crystal layer having alignment defects can be formed in the same manner.
  • the isotropic resin layer other resins such as polyimide (Nissan Chemical's polyimide varnish Sanever 130), polyvinyl alcohol, polyester, polyarylate, polyamideimide, polyetherimide, polyamide, modified polyamide, etc. may be used. Good.
  • the surface of the isotropic resin layer on which the liquid crystal composition is applied is rubbed (for example, the surface of the polymer layer is rubbed in a certain direction with paper or cloth). It is preferable not to do so.
  • the thickness of the isotropic resin layer is preferably 0.01 ⁇ m to 50 ⁇ m, and more preferably 0.05 ⁇ m to 20 ⁇ m.
  • An alignment film may be used as a lower layer to which a liquid crystal composition is applied when forming at least one cholesteric liquid crystal layer during the production of a projected image display half mirror.
  • the projected image display half mirror may or may not include an alignment film.
  • the alignment film is a layer having an organic compound, a rubbing treatment of a polymer (resin such as polyimide, polyvinyl alcohol, polyester, polyarylate, polyamide imide, polyether imide, polyamide, modified polyamide), oblique deposition of an inorganic compound, or a micro groove.
  • an organic compound for example, ⁇ -tricosanoic acid, dioctadecylmethylammonium chloride, methyl stearylate
  • LB film Langmuir-Blodgett method
  • an alignment film in which an alignment function is generated by application of an electric field, application of a magnetic field, or light irradiation is also known.
  • the alignment film made of a polymer is preferably subjected to a rubbing treatment, and then a composition for forming a liquid crystal layer is applied to the rubbing treatment surface.
  • the alignment film to be formed is particularly preferable.
  • the rubbing treatment can be performed by rubbing the surface of the polymer layer several times in a certain direction with paper or cloth.
  • the alignment film does not have to be peeled off together with the temporary support to form a layer constituting the projected image display half mirror.
  • the thickness of the alignment layer is preferably 0.01 ⁇ m to 5 ⁇ m, and more preferably 0.05 ⁇ m to 2 ⁇ m.
  • Each of the projected image display members including the intermediate image screen and the cholesteric liquid crystal layer may include a support.
  • the support is not particularly limited.
  • the support used for forming the cholesteric liquid crystal layer may be a temporary support that is peeled off after forming the cholesteric liquid crystal layer.
  • the support is a temporary support, it is not a layer constituting the projected image display member of the present invention, and there is no particular limitation on optical properties such as transparency and refraction.
  • the support temporary support
  • glass or the like may be used in addition to the plastic film.
  • the plastic film include polyester such as polyethylene terephthalate (PET), polycarbonate, acrylic resin, epoxy resin, polyurethane, polyamide, polyolefin, cellulose derivative, and silicone.
  • the support used for forming the cholesteric liquid crystal layer may be a temporary support that is peeled off after forming the cholesteric liquid crystal layer, and the cholesteric liquid crystal layer may be transferred to the substrate after forming the cholesteric liquid crystal layer.
  • a temporary support body you may use glass etc. other than said plastic film.
  • the thickness of the support may be about 5 ⁇ m to 1000 ⁇ m, preferably 10 ⁇ m to 250 ⁇ m, and more preferably 15 ⁇ m to 90 ⁇ m.
  • Each of the intermediate image screen and the projected image display member may include a base material as a support for the cholesteric liquid crystal layer.
  • the base material may also serve as the above isotropic resin layer.
  • the substrate is not particularly limited.
  • a plastic film can be used as the substrate. Examples of the plastic film include polyester such as polyethylene terephthalate (PET), polycarbonate, acrylic resin, epoxy resin, polyurethane, polyamide, polyolefin, cellulose derivative, and silicone.
  • the thickness of the substrate may be about 5 ⁇ m to 1000 ⁇ m, preferably 10 ⁇ m to 250 ⁇ m, and more preferably 15 ⁇ m to 90 ⁇ m.
  • the substrate may be curved.
  • a curved cholesteric liquid crystal layer can be formed by using a curved substrate.
  • the intermediate image screen and the projected image display member may each include an adhesive layer for bonding the respective layers.
  • the adhesive layer may be formed from an adhesive.
  • Adhesives include hot melt type, thermosetting type, photocuring type, reactive curing type, and pressure-sensitive adhesive type that does not require curing, from the viewpoint of curing method, and the materials are acrylate, urethane, urethane acrylate, epoxy , Epoxy acrylate, polyolefin, modified olefin, polypropylene, ethylene vinyl alcohol, vinyl chloride, chloroprene rubber, cyanoacrylate, polyamide, polyimide, polystyrene, polyvinyl butyral, etc. can do.
  • the photocuring type is preferable as the curing method, and from the viewpoint of optical transparency and heat resistance, it is preferable to use an acrylate, urethane acrylate, epoxy acrylate, or the like material.
  • the thickness of the adhesive layer may be 0.5 ⁇ m to 10 ⁇ m, preferably 1 ⁇ m to 5 ⁇ m.
  • the adhesive layer is preferably provided with a uniform thickness to reduce color unevenness and the like.
  • the manufacturing method of the intermediate image screen and the projection image display member is not particularly limited. For example, Applying a liquid crystal composition on a support; Curing the coating layer to form a cholesteric liquid crystal layer; The manufacturing method including adhere
  • An isotropic resin layer or an alignment film may be formed on the surface of the support on which the liquid crystal composition is applied. An isotropic resin layer may be used instead of the support.
  • attachment is performed on the surface on the opposite side to a support body, and the support body may be peeled after adhesion
  • a liquid crystal composition containing a polymerizable liquid crystal compound or the like is directly applied to the surface of the cholesteric liquid crystal layer previously formed on a support, etc.
  • the process may be repeated, and a separately prepared cholesteric liquid crystal layer or a laminate thereof may be laminated using an adhesive or the like, but the former is preferred. This is because the interference unevenness derived from the thickness unevenness of the adhesive layer is not observed.
  • the liquid crystal on the air interface side of the cholesteric liquid crystal layer formed earlier is formed by forming the next cholesteric liquid crystal layer so as to be in direct contact with the surface of the cholesteric liquid crystal layer formed earlier. This is because the orientation direction of the molecules matches the orientation direction of the liquid crystal molecules below the cholesteric liquid crystal layer formed thereon, and the polarization property of the laminate of the cholesteric liquid crystal layer is improved.
  • a cholesteric liquid crystalline coating solution Preparation of a cholesteric liquid crystalline coating solution; Compound 1, Compound 2, Fluorine Horizontal Alignment Agent 1, Fluorine Horizontal Alignment Agent 2, Chiral Agent, Polymerization Initiator, and Solvent are mixed and Right Sense Coating Solution (R) having the composition shown in Table 2 and Table 3 is mixed. And a left sense coating solution (L) were prepared.
  • the coating liquids (R-1) to (R-3) and (L-) were prepared by adjusting the amounts of the chiral agent LC-756 in the coating liquid (R) and the chiral agent chiral compound 1 in the coating liquid (L). 1) to (L-3) were prepared.
  • the coating liquid R-1 shown in Table 4 was applied on the acrylic layer formed above at room temperature so that the dry film thickness after drying was 5 ⁇ m.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C. for 2 minutes, and then irradiated with UV light at 30 ° C. with a fusion D bulb (lamp 90 mW / cm) at an output of 60% for 6 to 12 seconds.
  • a liquid crystal layer was obtained.
  • the coating liquid L-2 shown in Table 4 was applied onto the liquid crystal layer at room temperature so that the thickness of the dried film after drying was 5 ⁇ m.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C.
  • the coating liquid R-3 shown in Table 4 was applied onto this liquid crystal layer at room temperature so that the dry film thickness after drying was 5 ⁇ m.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C. for 2 minutes, and then irradiated with UV light at 30 ° C. with a fusion D bulb (lamp 90 mW / cm) at an output of 60% for 6 to 12 seconds.
  • a scattering type selective reflection film was obtained.
  • a 1 mm thick acrylic plate was prepared, and a curable UV curing adhesive Exp. U12034-6 was applied using a wire bar at room temperature so that the dry film thickness after drying was 5 ⁇ m.
  • the coated surface and the liquid crystal layer side of the scattering-type selective reflection film are bonded so that no air bubbles enter, and UV is applied at 30 ° C. with a fusion D bulb (lamp 90 mW / cm) at an output of 60% for 6 to 12 seconds. Irradiated. Thereafter, the PET film that was the support of the scattering type selective reflection film was peeled off to obtain an intermediate image screen SC-1.
  • a rubbing treatment is performed on a PET surface of Cosmo Shine A-4100 (thickness 100 ⁇ m) manufactured by Toyobo Co., Ltd., which has not been subjected to an easy adhesion treatment, and the thickness of the dry film after drying the coating solution R-1 shown in Table 4 becomes 5 ⁇ m. So that it was applied at room temperature.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C. for 2 minutes, and then irradiated with UV light at 30 ° C. with a fusion D bulb (lamp 90 mW / cm) at an output of 60% for 6 to 12 seconds.
  • a liquid crystal layer was obtained.
  • the coating liquid L-2 shown in Table 4 was applied onto the liquid crystal layer at room temperature so that the thickness of the dried film after drying was 5 ⁇ m.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C. for 2 minutes, and then irradiated with UV light at 30 ° C. with a fusion D bulb (lamp 90 mW / cm) at an output of 60% for 6 to 12 seconds.
  • a liquid crystal layer was obtained.
  • the coating liquid R-3 shown in Table 4 was applied onto this liquid crystal layer at room temperature so that the dry film thickness after drying was 5 ⁇ m.
  • the coating layer was dried at room temperature for 30 seconds, heated in an atmosphere of 85 ° C.
  • spectral haze evaluation of film The spectral haze of the film was measured by measuring the total light transmission spectrum and diffuse transmission spectrum by attaching an integrating sphere unit to a spectrophotometer UV-3100PC manufactured by Shimadzu Corporation. Ratio / total transmittance) was calculated and used as spectral haze.
  • the intermediate image screens SC-1 and SC-2 were all confirmed to have spectral haze peaks at 460 nm, 550 nm, and 640 nm.
  • the diffuse reflectance is measured by attaching an integrating sphere unit ISR-3100 to a spectrophotometer UV-3100PC manufactured by Shimadzu Corporation, and the intermediate image screen is placed on the sample window where the measurement light is perpendicularly incident on the liquid crystal layer surface side of the intermediate image screen.
  • BaSO 4 was used as a reference in the wavelength range of 350 nm to 800 nm.
  • SC-1 showed diffuse reflectance peaks at wavelengths of 460 nm, 550 nm, and 640 nm, and the diffuse reflectances at the respective peak wavelengths were 39%, 40%, and 40%.
  • SC-2 showed diffuse reflectance peaks at wavelengths of 460 nm, 550 nm, and 640 nm, and the diffuse reflectances at the respective peak wavelengths were 79%, 81%, and 80%.
  • the diffuse reflectance of the projected image display half mirror MR-1 was measured, but the diffuse reflectance was 2% or less at any wavelength, and a clear peak of diffuse reflectance could not be measured. .
  • Example 1 The brightness of the projected virtual image was measured with the optical arrangement shown in FIG. 2 simulating the configuration of the windshield type head-up display.
  • the equipment and materials used are as follows.
  • Drawing device Seiko Epson Corporation LCD-projector EB-W28
  • Luminance meter Spectral radiance meter CS-1000A manufactured by Konica Minolta Intermediate image screen: SC-1 produced above
  • Concave mirror Kasai Trading Co., Ltd.
  • the polarization state of the projection light of the drawing device was confirmed by observing the spectrum of the projection light while passing through the polarizing plate of the transmission polarization axis while opening the polarizing plate while displaying white.
  • green light is linearly polarized light having a vibration surface in the horizontal direction
  • blue light and red light are vertically polarized.
  • the quarter-wave retardation plate allows the drawing device to be installed horizontally so that the projection light is transmitted vertically, and its slow axis direction is 45 ° from the direction relative to the vertical direction of the drawing device.
  • a white solid image was formed by vertically incident light from the liquid crystal layer side of the intermediate image screen.
  • the angle of the glass plate was adjusted so that the projection light was incident and reflected at an angle of 60 ° with respect to the normal direction of the glass plate (windshield).
  • the magnification of the virtual image (projected image) in this optical arrangement was twice.
  • the measured luminance was 2903 cd / m 2 .
  • Example 2> The brightness of the white projection image was measured in the same manner as in Example 1 except that SC-2 produced above was used for the intermediate image screen, Benqi Japan MS521 was used for the drawing device, and a quarter-wave retardation plate was not used. did. The measured luminance was 2980 cd / m 2 . In addition, when the polarization state of this drawing device was confirmed using the polarizing plate, it was confirmed that it was natural light over a visible light region. ⁇ Comparative Example 2> The brightness of the white projection image was measured in the same manner as in Example 2 except that the projector screen PRS-K50K was used as the intermediate image screen. The measured luminance was 545 cd / m 2 .
  • Example 3 The brightness of the projected virtual image was measured with the optical arrangement shown in FIG. 3 simulating the structure of a combiner-type head-up display.
  • the equipment and materials used are as follows.
  • Drawing device Seiko Epson Corporation LCD-projector EB-W28
  • Luminance meter Spectral radiance meter CS-1000A manufactured by Konica Minolta Intermediate image screen: SC-1 produced above
  • Combiner MR-1 produced above 1/4 wavelength retardation plate: 1/4 wavelength plate MCR14N manufactured by Bikan Imaging
  • the quarter-wave retardation plate was disposed at the same position and slow axis orientation as in Example 1.
  • Example 3 The brightness of the white projection image was measured in the same manner as in Example 3, except that Sanwa Supply Co., Ltd. projector screen PRS-K50K was used as the intermediate image screen and the blue glass used in Example 1 was used as the combiner. The measured brightness was 530 cd / m 2 . Table 5 summarizes the results of Examples 1 to 3 and Comparative Examples 1 to 3.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polarising Elements (AREA)
  • Instrument Panels (AREA)
  • Overhead Projectors And Projection Screens (AREA)
  • Optical Filters (AREA)
  • Projection Apparatus (AREA)

Abstract

La présente invention concerne un système de projection comprenant un dispositif de dessin et un écran d'image intermédiaire. Le dispositif de dessin crée une image sur l'écran d'image intermédiaire. L'image projetée est affichée avec la lumière réfléchie par l'écran d'image intermédiaire. L'écran d'image intermédiaire comprend une couche dans laquelle est fixée une phase cristalline liquide cholestérique. L'écran d'image intermédiaire provoque une réflexion diffuse dans une région de longueurs d'onde dans laquelle la couche susmentionnée présente une réflexion sélective. Le système de projection selon la présente invention crée une image projetée ayant une luminance élevée et une haute résolution. La présente invention concerne un procédé de fabrication d'un écran d'image intermédiaire approprié pour le système de projection, le procédé consistant à former la couche comprenant la phase cristalline liquide cholestérique fixée par application et durcissement d'une composition de cristaux liquides contenant des composés cristallins liquides polymérisables sur la surface d'une couche de résine isotrope qui est une couche durcie d'une composition polymérisable cristalline non liquide contenant un monomère (méth)acrylate.
PCT/JP2016/074163 2015-08-20 2016-08-19 Système de projection et procédé de fabrication d'écran d'image intermédiaire de système de projection Ceased WO2017030176A1 (fr)

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JPWO2021060316A1 (fr) * 2019-09-25 2021-04-01
JP7345554B2 (ja) 2019-09-25 2023-09-15 富士フイルム株式会社 液晶回折素子、および、液晶回折素子の製造方法
WO2021060316A1 (fr) * 2019-09-25 2021-04-01 富士フイルム株式会社 Élément de diffraction à cristaux liquides et procédé de production d'un élément de diffraction à cristaux liquides
JP7293403B2 (ja) 2019-12-26 2023-06-19 富士フイルム株式会社 透明スクリーン
US11977306B2 (en) 2019-12-26 2024-05-07 Fujifilm Corporation Transparent screen
JPWO2021132113A1 (fr) * 2019-12-26 2021-07-01

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