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WO2017013193A1 - Acier léger deformable de construction présentant des propriétés mécaniques améliorées et procédé de fabrication de produit semi-fini à partir de cet acier - Google Patents

Acier léger deformable de construction présentant des propriétés mécaniques améliorées et procédé de fabrication de produit semi-fini à partir de cet acier Download PDF

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Publication number
WO2017013193A1
WO2017013193A1 PCT/EP2016/067347 EP2016067347W WO2017013193A1 WO 2017013193 A1 WO2017013193 A1 WO 2017013193A1 EP 2016067347 W EP2016067347 W EP 2016067347W WO 2017013193 A1 WO2017013193 A1 WO 2017013193A1
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WO
WIPO (PCT)
Prior art keywords
max
steel
elements
mpa
tensile strength
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2016/067347
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German (de)
English (en)
Inventor
Peter PALZER
Zacharias Georgeou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Salzgitter Flachstahl GmbH
Original Assignee
Salzgitter Flachstahl GmbH
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Filing date
Publication date
Application filed by Salzgitter Flachstahl GmbH filed Critical Salzgitter Flachstahl GmbH
Priority to EP16750113.9A priority Critical patent/EP3325678B1/fr
Priority to US15/746,317 priority patent/US20180216207A1/en
Priority to RU2018105926A priority patent/RU2691436C1/ru
Priority to KR1020187003165A priority patent/KR102096190B1/ko
Publication of WO2017013193A1 publication Critical patent/WO2017013193A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0231Warm rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273Final recrystallisation annealing

Definitions

  • the invention relates to a deformable lightweight structural steel with improved
  • the invention relates to a process for the production of semi-finished products from this steel.
  • semi-finished product is understood below to mean hot or cold strip produced from this steel or an intermediate or end product made therefrom, such as, for example, pipes.
  • lightweight steels which are characterized by a low specific weight while high strength and toughness and have a high ductility and thus are of great interest to the vehicle.
  • the high proportion of alloying constituents (Si, Al) having a specific gravity far below the specific gravity of iron achieves a weight reduction advantageous to the automobile industry while retaining the previous design construction.
  • the deformable lightweight structural steel known from the published patent application DE 10 2004 061 284 A1 has, for example, the following alloy composition (in% by weight): C 0.04 to ⁇ 1.0, Al 0.05 to ⁇ 4.0, Si 0, 05 to ⁇ 6.0, Mn 9.0 to ⁇ 18.0, the remainder being iron including conventional steel accompanying elements.
  • alloy composition in% by weight: C 0.04 to ⁇ 1.0, Al 0.05 to ⁇ 4.0, Si 0, 05 to ⁇ 6.0, Mn 9.0 to ⁇ 18.0, the remainder being iron including conventional steel accompanying elements.
  • Requirement Cr, Cu, Ti, Zr, V and Nb are added.
  • This lightweight steel has a partially stabilized ⁇ -mixed crystal structure with defined stacking fault energy with a z. T. multiple TRIP effect, which is the stress or strain-induced conversion of a face-centered ⁇ -mixed crystal (austenite) in an ⁇ -martensite (hexagonal closest packing) and then upon further deformation into a body-centered ⁇ -martensite and retained austenite.
  • TRIP Transformation Induced Plasticity
  • TWIP winning Induced Plasticity
  • WO 201 1/154153 A1 discloses an austenitic steel which is said to have outstanding resistance to delayed cracking.
  • the steel contains, in addition to iron and impurities in wt .-%: 0.5 to 0.8 C, 10 to 17 Mn, at least 1, 0 AI, at most 0.5 Si, at most 0.020 S, at most 0.050 P, 50 to 200 ppm N and 0.050 to 0.25 V.
  • WO 2009/142362 A1 discloses a steel alloy for a high-strength cold-rolled steel sheet, which should also have improved resistance to delayed cracking.
  • the steel contains, in addition to iron and impurities in wt .-%: 0.05 to 0.3 C, 0.3 to 1.6 Si, 4.0 to 7.0 Mn, 0.5 to 2.0 AI, 0 , 01 to 0.1 Cr, 0.02 to 0.1 Ni, 0.005 to 0.03 Ti, 5 to 30 ppm B, 0.01 to 0.03 Sb and 0.008 or less S.
  • EP 2 128 293 A1 discloses a lightweight structural steel with improved elongation, comprising iron and impurities in wt.%: 0.2 to 0.8 C, 2 to 10 Mn, 0.2 or less P , at most 0.015 S, 3.0 to 15 Al, at most 0.01 N and a ratio Mn / Al of 0.4 to 1.0.
  • a roll gap of a rolling mill during the production of the steel strip is selectively varied.
  • the object of the invention is to provide a lightweight steel of the generic type, while maintaining very good mechanical properties
  • This object is based on the preamble in connection with the
  • the deformable lightweight steel with TRIP is provided. According to the teachings of the invention, the deformable lightweight steel with TRIP and
  • TWIP properties the following elements in% by weight:
  • antimony causes the carbides to grow slower and thus finer and less precipitated. This will be
  • Alloying concepts result in improved mechanical properties and significant improvement with respect to avoiding delayed hydrogen-induced cracking (delayed fracture) and hydrogen embrittlement.
  • the evaluation of the mechanical properties is based on the product of tensile strength and elongation at break, which is a measure of the performance of the material.
  • the product or semifinished product produced from the alloy according to the invention by deformation which may be, for example, hot strip, cold strip, flexibly rolled hot or cold strip, a pipe or a body component, is therefore advantageously heat-treated at 480 to 770 ° C for 1 minute to 48 hours, for example, in a bell annealer with predominantly long annealing times or in a continuous annealing with predominantly short annealing times.
  • the timing of the annealing can therefore be flexibly adapted to the production process.
  • An annealing of the end product in addition to an already performed annealing of the semifinished product can lead to a further improvement of the material properties.
  • Annealing temperature 480 to 770 ° C
  • annealing time 1 minute to 48 hours.
  • Annealing temperature 480 to 770 ° C
  • annealing time 1 minute to 48 hours.
  • the annealing is preferably carried out at temperatures of 670 to 770 ° C at annealing times of 1 minute to 12 hours, as lower temperatures and longer annealing times lead to lower tensile strength and elongation at break.
  • a continuous annealing is preferably used for hot-rolled strip, cold strip and flexibly rolled strips for short annealing times, and preferably for long annealing times a crown annealing.
  • other annealing devices can be used with the given parameters, such as a muffle furnace.
  • Manganese-containing steels are possible, which have a better tensile strength and elongation at break than non-Sb-alloyed higher manganese-containing steels with the same chemical composition.
  • antimony also significantly improves the behavior towards hydrogen (delayed cracking and hydrogen embrittlement).
  • the reason for the improvement in the material properties is that antimony inhibits the diffusion of carbon and aluminum.
  • antimony lowers the interfacial energy, resulting in a finer distribution of the carbides.
  • the reduced carbon diffusion thus delays the local accumulation of carbon at the grain boundaries and in the microstructure and, in conjunction with aluminum, the formation of kappa carbides or in particular with V, Nb, Mo, Cr, W, Zr and Ti, the formation of local larger carbides.
  • the homogeneity of the material is thereby improved with the described positive effects on the mechanical properties and the resistance to delayed cracking and hydrogen embrittlement.
  • the precipitation of finely divided carbides leads to grain refining in the microstructure, which leads to an improvement in the behavior with respect to hydrogen-related negative effects (delayed cracking,
  • antimony For antimony to be effective, at least levels of 30 ppm are necessary. However, antimony contents of more than 0.8 wt.% Embrittle the material and should therefore be avoided. Optimal, the maximum content of antimony is 0.5 wt .-%.
  • Precipitated carbides improve the utilization of the corresponding alloying elements, potentially allowing a reduction in the amount of addition. Furthermore, due to the reduced carbon diffusion and the reduced grain growth due to the addition of antimony, the process window for the heat treatments necessary according to the invention is increased, that is, the steel is less sensitive to the resulting mechanical properties
  • AI Improves the strength and elongation properties, lowers the specific gravity, and influences the conversion behavior of the invention Alloys. Al contents of more than 15% by weight deteriorate the
  • Ca Used to modify non-metallic oxide inclusions, which can lead to inhomogeneities and unwanted material failure.
  • Mn Stabilizes austenite, increases strength and toughness, and allows for deformation-induced martensite and / or twinning in the
  • Mo acts as a strong carbide former and increases strength. Contents of Mo exceeding 2% by weight deteriorate the elongation properties, and therefore a maximum content of 2% by weight is determined.
  • Nb + V Grain-refining, in particular through the formation of carbides, which simultaneously improves the strength, toughness and elongation properties. Contents of over 1 wt .-% bring no further advantages.
  • Ni Stabilizes austenite and improves elongation properties, especially at low application temperatures. More than the addition of 5 wt .-% Ni brings no further advantage.
  • Si hinders carbon diffusion, reduces specific gravity and increases strength and elongation and toughness properties. Furthermore, an improvement in cold rollability by alloying Si could be observed.
  • Elongation properties which is why a maximum content of 2 wt .-% is set.
  • W acts as a carbide former and increases strength and heat resistance. Content W of more than 1 wt% deteriorate the elongation properties, therefore, a maximum content of 1 wt .-% is determined.
  • Zr acts as a carbide former and improves strength. Contents of Zr of more than 0.3% by weight deteriorate the elongation properties, therefore, a maximum content of 0.3% by weight is set.
  • Heat treatment parameters (see Table 1 to 4) a product of tensile strength and elongation at break of at least 20,000 MPa% and a tensile strength of at least 800 MPa.
  • the product of tensile strength and elongation at break is a measure of the material's performance during forming.
  • An alloy according to claim 4 comprises a product of tensile strength
  • An alloy according to claim 5 comprises finely divided kappa-carbide precipitates and a product of tensile strength and elongation at break of at least 30,000 MPa% and a yield strength of at least 700 MPa and a tensile strength of at least 800 MPa.
  • Table 1 lists the alloy compositions tested. With otherwise approximately the same chemical composition, the content of Sb and additions of Nb were varied.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

L'invention concerne un acier léger déformable de construction, présentant des propriétés mécaniques améliorées et une résistance élevée à la formation retardée de fissures induite par l'hydrogène et à la fragilisation due à l'hydrogène, comprenant les éléments suivants (en pourcentage en poids) : C 0,02 à ≤1,0 ; Mn 3 à 30 ; Si ≤4 ; P au maximum 0,1 ; S au maximum 0,1 ; N au maximum 0,03 ; Sb 0,003 à 0,8, en particulier de manière avantageuse jusqu'à 0,5, ainsi qu'au moins un ou plusieurs des éléments formant des carbures suivants dans les teneurs indiquées (en pourcentage en poids) : Al ≤15 ; Cr > 0,1 à 8 ; Mo 0,05 à 2 ; Ti 0,01 à 2 ; V 0,005 à 1 ; Nb 0,00 à 1 ; W 0,005 à 1 ; Zr 0,001 à 0,3 ; le reste étant du fer, y compris des éléments habituels d'accompagnement de l'acier, avec addition éventuelle des éléments suivants en pourcentage en poids : au maximum 5 de Ni, au maximum 10 de Co, au maximum 0,005 de Ca, au maximum 0,01 de B et 0,05 à 2 de Cu. L'invention concerne également un procédé de fabrication dudit acier léger de construction.
PCT/EP2016/067347 2015-07-22 2016-07-20 Acier léger deformable de construction présentant des propriétés mécaniques améliorées et procédé de fabrication de produit semi-fini à partir de cet acier Ceased WO2017013193A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP16750113.9A EP3325678B1 (fr) 2015-07-22 2016-07-20 Acier léger deformable de construction présentant des propriétés mécaniques améliorées et procédé de fabrication de produit semi-fini à partir de cet acier
US15/746,317 US20180216207A1 (en) 2015-07-22 2016-07-20 Formable lightweight steel having improved mechanical properties and method for producing semi-finished products from said steel
RU2018105926A RU2691436C1 (ru) 2015-07-22 2016-07-20 Формуемая легковесная сталь с улучшенными механическими свойствами и способ производства полуфабрикатов из указанной стали
KR1020187003165A KR102096190B1 (ko) 2015-07-22 2016-07-20 향상된 기계적 물성을 갖는 성형 가능한 경량 강 및 상기 강으로부터 반제품을 제조하기 위한 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015111866.1A DE102015111866A1 (de) 2015-07-22 2015-07-22 Umformbarer Leichtbaustahl mit verbesserten mechanischen Eigenschaften und Verfahren zur Herstellung von Halbzeug aus diesem Stahl
DE102015111866.1 2015-07-22

Publications (1)

Publication Number Publication Date
WO2017013193A1 true WO2017013193A1 (fr) 2017-01-26

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PCT/EP2016/067347 Ceased WO2017013193A1 (fr) 2015-07-22 2016-07-20 Acier léger deformable de construction présentant des propriétés mécaniques améliorées et procédé de fabrication de produit semi-fini à partir de cet acier

Country Status (6)

Country Link
US (1) US20180216207A1 (fr)
EP (1) EP3325678B1 (fr)
KR (1) KR102096190B1 (fr)
DE (1) DE102015111866A1 (fr)
RU (1) RU2691436C1 (fr)
WO (1) WO2017013193A1 (fr)

Cited By (1)

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CN107841691A (zh) * 2017-10-25 2018-03-27 河北工业大学 一种750MPa级超高强度Fe‑Mn‑Al‑C系轻质铸钢及其制备方法

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Publication number Priority date Publication date Assignee Title
DE102016117508B4 (de) 2016-09-16 2019-10-10 Salzgitter Flachstahl Gmbh Verfahren zur Herstellung eines Stahlflachprodukts aus einem mittelmanganhaltigen Stahl und ein derartiges Stahlflachprodukt
DE102017223633A1 (de) 2017-12-21 2019-06-27 Voestalpine Stahl Gmbh Kaltgewalztes Stahlflachprodukt mit metallischer Korrosionsschutzschicht und Verfahren zur Herstellung eines solchen
RU2721681C1 (ru) * 2019-12-23 2020-05-22 Федеральное Государственное Унитарное Предприятие "Центральный научно-исследовательский институт черной металлургии им. И.П. Бардина" (ФГУП "ЦНИИчермет им. И.П. Бардина") Способ производства холоднокатаного непрерывно отожженого листового проката из if-стали
CN111593263A (zh) * 2020-06-24 2020-08-28 安徽工业大学 一种高强度低密度钢的制备方法及高强度低密度钢
CN111607740A (zh) * 2020-06-24 2020-09-01 安徽工业大学 高强度低密度钢的制备方法及高强度低密度钢
CN114752867B (zh) * 2022-04-25 2022-10-11 燕山大学 一种高强韧轻质钢及其制备方法和应用

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EP2383353A2 (fr) * 2010-04-30 2011-11-02 ThyssenKrupp Steel Europe AG Acier à résistance élevée comprenant du Mn, produit plat en acier composé d'un tel acier et son procédé de fabrication
EP2778247A1 (fr) * 2011-11-07 2014-09-17 Posco Tôle d'acier pour un formage par pressage à chaud, élément de formage par pressage à chaud et procédé de fabrication associé

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KR20180033202A (ko) 2018-04-02
KR102096190B1 (ko) 2020-04-02
RU2691436C1 (ru) 2019-06-13

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