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WO2017064569A1 - Lead free on-glass connection element - Google Patents

Lead free on-glass connection element Download PDF

Info

Publication number
WO2017064569A1
WO2017064569A1 PCT/IB2016/001963 IB2016001963W WO2017064569A1 WO 2017064569 A1 WO2017064569 A1 WO 2017064569A1 IB 2016001963 W IB2016001963 W IB 2016001963W WO 2017064569 A1 WO2017064569 A1 WO 2017064569A1
Authority
WO
WIPO (PCT)
Prior art keywords
connection element
glass
free electrical
solder connection
hybrid lead
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2016/001963
Other languages
French (fr)
Inventor
Thomas Reul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fractal Technologies GmbH
Original Assignee
Fractal Technologies GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fractal Technologies GmbH filed Critical Fractal Technologies GmbH
Priority to CN201690001233.6U priority Critical patent/CN209352794U/en
Publication of WO2017064569A1 publication Critical patent/WO2017064569A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • B23K35/0227Rods, wires
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/02Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
    • B23K35/0222Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in soldering, brazing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/302Cu as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3033Ni as the principal constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3053Fe as the principal constituent

Definitions

  • the invention comprises of a hybrid lead-free electrical glass solder connection element which can be soldered or bonded to appropriate contact surfaces of
  • windowpanes glass panels or composite windowpanes.
  • this lead-free electrical glass solder connection element has the advantage of reducing the mechanical tensions incurred at the interfaces between the connection element and the glass which are caused by the different thermal expansion coefficients of the materials used, with simultaneously high electrical conductivity.
  • Conventional lead-free electrical glass solder connection elements comprise either of copper or brass materials and feature a high to extremely-high electrical conductivity corresponding to the material, but also a relatively high thermal expansion coefficient compared to glass, which then causes increased mechanical tension at the interface between the connection element and the glass.
  • Relief is provided in particular by means of indium or bismuth-based solders which, thanks to their special material characteristics, compensate for tensions between the connection element and the glass, or, in the case of bismuth, display inverse expansion behaviour on cooling, which however requires compromises to be made in the temperature application range, as these melt in a lower temperature range (approx. 110°C to 150°C) than the conventional plumbiferous alloys (approx. 180°C to 250°C).
  • solder connection elements comprise of a combination of steel and copper materials or steel and brass materials (in which the steel section preferably contacts the glass as a bridge due to the lower thermal expansion coefficient compared to copper or brass) or are completely manufactured from steel.
  • the current is conducted to the bridge via a flat plug contact, normally a reed, either by means of a flexible braid or a wire.
  • a flat plug contact normally a reed, either by means of a flexible braid or a wire.
  • solder alloys especially low-expansion steels are used and are combined with a multitude of solder alloys, but they have the major disadvantage inherent in steels of multiple increases in the specific electrical resistance value (a factor of 6 to 40 and more) compared to copper or brass.
  • hybrid lead-free electrical solder connection elements can be designed in two versions.
  • Version 1 consists of a bridge and an electrically functional element; in the simplest case, a conductor with a plug contact which is attached to this bridge.
  • Version 2 consists of a bridge and an electrically functional element; in the simplest case, a conductor and a screw contact.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)

Abstract

A hybrid lead-free electrical glass solder connection element which, due to its special design, can be soldered to glass. The connection element minimises the mechanical tensions incurred at the interface between the connection element and the glass due to the combination of materials used, with simultaneously more electrical conductivity than is inherent in the material contacting the glass.

Description

LEAD FREE ON-GLASS CONNECTION ELEMENT
CROSS-REFERENCE TO RELATED APPLICATION
This application claims the benefit of priority under Article 8 of the Patent Cooperation Treaty to German Utility Model Application No. 20 2015 007 098.1, having a filing date of October 10, 2015, the entire disclosure of which is hereby incorporated herein by reference.
DESCRIPTION
The invention comprises of a hybrid lead-free electrical glass solder connection element which can be soldered or bonded to appropriate contact surfaces of
windowpanes, glass panels or composite windowpanes.
The special feature of this lead-free electrical glass solder connection element is that, in contrast to the connections currently in use, it has the advantage of reducing the mechanical tensions incurred at the interfaces between the connection element and the glass which are caused by the different thermal expansion coefficients of the materials used, with simultaneously high electrical conductivity.
Conventional lead-free electrical glass solder connection elements comprise either of copper or brass materials and feature a high to extremely-high electrical conductivity corresponding to the material, but also a relatively high thermal expansion coefficient compared to glass, which then causes increased mechanical tension at the interface between the connection element and the glass. Relief is provided in particular by means of indium or bismuth-based solders which, thanks to their special material characteristics, compensate for tensions between the connection element and the glass, or, in the case of bismuth, display inverse expansion behaviour on cooling, which however requires compromises to be made in the temperature application range, as these melt in a lower temperature range (approx. 110°C to 150°C) than the conventional plumbiferous alloys (approx. 180°C to 250°C). Other conventional lead-free electrical glass solder connection elements, on the other hand, comprise of a combination of steel and copper materials or steel and brass materials (in which the steel section preferably contacts the glass as a bridge due to the lower thermal expansion coefficient compared to copper or brass) or are completely manufactured from steel. The current is conducted to the bridge via a flat plug contact, normally a reed, either by means of a flexible braid or a wire. In this process, especially low-expansion steels are used and are combined with a multitude of solder alloys, but they have the major disadvantage inherent in steels of multiple increases in the specific electrical resistance value (a factor of 6 to 40 and more) compared to copper or brass. This is especially disadvantageous if the glass connections should conduct high electrical capacities onto the windowpane or the composite windowpane-, for example as is usually required for heating panels. Coating of the steels with strongly electrically-conductive materials, for example silver, also does not help significantly, because although the coatings can increase the electrical conductivity somewhat, the required economic efficiency would not permit sufficiently-large cross-sections, and also the application of thicker layers of silver would counteract the advantages of the steel with regard to the thermal expansion coefficients.
Typically, hybrid lead-free electrical solder connection elements can be designed in two versions.
Version 1 consists of a bridge and an electrically functional element; in the simplest case, a conductor with a plug contact which is attached to this bridge.
Version 2 consists of a bridge and an electrically functional element; in the simplest case, a conductor and a screw contact.
Key for Figure 3.)
Lead-free hybrid solder connection, schematic
1- Bridge
2- Conductor with optional insulation
3- Plug contact Key for Figure 2.)
Bridge of hybrid solder connection from the side 1- Solder deposit with optional flux
2- Electrically strongly-conductive material, preferably copper or brass
3- Low-expansion steel alloy
4- Optional surface coating, such as silver, nickel or similar Key for Figure 3.)
Version 1 hybrid lead-free electrical glass solder connection
1 - Solder contact, preferably designed as a bridge
2 - Conductor
3 - Electrical functional unit (e.g. solenoid, filter, electronics)
4 - Plug
Key for Figure 4.)
Version 2 hybrid lead-free electrical glass solder connection
1 - Solder contact, preferably designed as a bridge
2 - Conductor
3 - Electrical functional unit (e.g. solenoid, filter, electronics)
4 - Screw connection

Claims

WE CLAIM:
1. A hybrid lead-free electrical glass solder connection element which, due to its special design, can be soldered to glass, characterised in that the connection element minimises the mechanical tensions incurred at the interface between the connection element and the glass due to the combination of materials used, with simultaneously more electrical conductivity than is inherent in the material contacting the glass.
2. The hybrid lead-free electrical glass solder connection element according to claim 1, characterised in that the area of the material contacting the glass being made from a low- expansion material which has a bore made from a strongly electrically conductive material.
3. The hybrid lead-free electrical glass solder connection element according to claim 1, characterised in that the outer side of the glass contact area is preferably made from a low-expansion material and the inner area features a strongly electrically conductive bore preferably made from copper.
4. The hybrid lead-free electrical glass solder connection element according to claim 1, characterised in that the connection element can be electromagnetically picked up and deposited.
5. The hybrid lead-free electrical glass solder connection element according to claim 1, characterised in that the connection element can be surface-finished.
6. The hybrid lead-free electrical glass solder connection element according to claim 1, characterised in that the connection element can be combined with solder alloys containing indium and a surface finishing, preferably made from nickel.
PCT/IB2016/001963 2015-10-10 2016-10-10 Lead free on-glass connection element Ceased WO2017064569A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201690001233.6U CN209352794U (en) 2015-10-10 2016-10-10 The unleaded electric glass solder connections of mixed type

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE202015007098.1U DE202015007098U1 (en) 2015-10-10 2015-10-10 Hybrid-Electric Unleaded-glass-solder connection element
DE202015007098.1 2015-10-10

Publications (1)

Publication Number Publication Date
WO2017064569A1 true WO2017064569A1 (en) 2017-04-20

Family

ID=58010499

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2016/001963 Ceased WO2017064569A1 (en) 2015-10-10 2016-10-10 Lead free on-glass connection element

Country Status (3)

Country Link
CN (1) CN209352794U (en)
DE (1) DE202015007098U1 (en)
WO (1) WO2017064569A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3696916B1 (en) 2017-11-07 2022-07-13 Central Glass Company, Limited Car window glass assembly

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004068643A1 (en) * 2003-01-30 2004-08-12 Pilkington Plc Vehicular glazing panel
US20070036670A1 (en) * 2005-08-12 2007-02-15 John Pereira Solder composition
WO2007110610A1 (en) * 2006-03-24 2007-10-04 Pilkington Group Limited Electrical connector
WO2009074264A2 (en) * 2007-12-11 2009-06-18 Saint-Gobain Glass France Solder connection element
US20140182932A1 (en) * 2011-05-10 2014-07-03 Saint-Gobain Glass France Disk having an electric connecting element
US20150236438A1 (en) * 2012-08-24 2015-08-20 Saint-Gobain Glass France Pane having an electrical connection element
US20150264800A1 (en) * 2012-09-14 2015-09-17 Saint-Gobain Glass France Pane having an electrical connection element

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004068643A1 (en) * 2003-01-30 2004-08-12 Pilkington Plc Vehicular glazing panel
US20070036670A1 (en) * 2005-08-12 2007-02-15 John Pereira Solder composition
WO2007110610A1 (en) * 2006-03-24 2007-10-04 Pilkington Group Limited Electrical connector
WO2009074264A2 (en) * 2007-12-11 2009-06-18 Saint-Gobain Glass France Solder connection element
US20140182932A1 (en) * 2011-05-10 2014-07-03 Saint-Gobain Glass France Disk having an electric connecting element
US20150236438A1 (en) * 2012-08-24 2015-08-20 Saint-Gobain Glass France Pane having an electrical connection element
US20150264800A1 (en) * 2012-09-14 2015-09-17 Saint-Gobain Glass France Pane having an electrical connection element

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3696916B1 (en) 2017-11-07 2022-07-13 Central Glass Company, Limited Car window glass assembly

Also Published As

Publication number Publication date
DE202015007098U1 (en) 2017-01-24
CN209352794U (en) 2019-09-06

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