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WO2017052161A1 - Composition à base d'une formulation transparente pour les cheveux - Google Patents

Composition à base d'une formulation transparente pour les cheveux Download PDF

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Publication number
WO2017052161A1
WO2017052161A1 PCT/KR2016/010481 KR2016010481W WO2017052161A1 WO 2017052161 A1 WO2017052161 A1 WO 2017052161A1 KR 2016010481 W KR2016010481 W KR 2016010481W WO 2017052161 A1 WO2017052161 A1 WO 2017052161A1
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WO
WIPO (PCT)
Prior art keywords
hair
composition
weight
less
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2016/010481
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English (en)
Korean (ko)
Inventor
배우리
강병하
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
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Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Priority to CN201680054897.3A priority Critical patent/CN108024934A/zh
Priority to HK18107953.0A priority patent/HK1249012A1/zh
Publication of WO2017052161A1 publication Critical patent/WO2017052161A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair

Definitions

  • the present specification relates to a transparent formulation composition for hair comprising polyquaternium-73 (PQ-73).
  • Shampoo a hair cleaner, makes hair clean by removing contaminants and sebum from the hair and scalp, but the shampoo process removes the moisturizing ingredients of the sebum and hair, making the hair soft and dry, making the hair tangled and difficult to handle.
  • a hair conditioning agent in the case of a general opaque shampoo to increase the flexibility of the hair by including a hair conditioning agent, in the case of a transparent shampoo there is a constraint that the formulation becomes opaque when using a conventional hair conditioner.
  • Transparent shampoos are preferred as infant or child shampoos with a clean and mild image, and offer aesthetic benefits with a beautiful appearance, but the product performance is also unsatisfactory because the formulation is opaque due to the limited amount of conditioning ingredients to be added when using conventional hair conditioners.
  • the problem is that there is a lack of air bubbles and a lack of function as a shampoo.
  • Adult hair is damaged by contamination, frequent perm, hair dry, dyeing, and combing, so it needs a hair cleanser that has a certain level of conditioning effect. have.
  • One aspect of the present invention is to provide a composition for hair in a transparent formulation.
  • One aspect of the present invention is to provide a hair composition of a transparent formulation comprising a polyquaternium-73 (PQ-73) as a cationic polymer as a hair composition.
  • PQ-73 polyquaternium-73
  • One aspect of the present invention is to provide a composition for hair of a transparent formulation having excellent foaming force, excellent conditioning effect, excellent hair glossiness enhancing effect.
  • One aspect of the present invention is to provide a composition for hair of a transparent formulation further comprises a surfactant in the composition.
  • One aspect of the present invention is to provide a composition for hair in a transparent formulation excellent in foaming, excellent in the conditioning effect, excellent hair shine enhancement effect.
  • One aspect of the present invention provides a composition for hair in a transparent formulation comprising polyquaternium-73 (PQ-73).
  • compositions for hair in a transparent dosage form wherein the composition further comprises a surfactant.
  • the surfactant may be at least one surfactant selected from the group consisting of sodium laureth sulfate, sodium lauroyl sarcosinate, and cocamidopropyl betaine. Can be.
  • composition for hair of the transparent formulation of the polyquaternium-73 is 0.01 to 5% by weight based on the total composition.
  • Another aspect of the present invention provides a composition for hair in a transparent formulation wherein the surfactant is 1 to 30% by weight based on the total composition, preferably the surfactant is 10 to 20% by weight relative to the total composition To provide.
  • compositions for hair in a transparent formulation comprising the polyquaternium-73 and the surfactant in a weight ratio of 1:20 to 40.
  • the surfactant comprises sodium laureth sulfate, sodium lauroyl sarcosinate and cocamidopropyl betaine, for the whole composition
  • the sodium laureth sulfate is 5 to 10% by weight
  • the sodium lauroyl salcosinate is 5 to 10% by weight
  • the cocamidopropyl betaine is 0.1 to 5% by weight to provide a composition for hair in a transparent formulation.
  • the surfactant includes sodium laureth sulfate, cocamidopropyl betaine, and sodium lauroyl sarcosinate
  • the polyquaternium -73, Sodium Laureth Sulfate, Cocamidopropyl Betaine, and Sodium Lauroyl Salcosinate provide a composition for hair in a transparent formulation comprising a weight ratio of 1: 10 to 20: 10 to 20: 1 to 7.
  • the polyquaternium-73, sodium laureth sulfate, cocamidopropyl betaine and sodium lauroyl salcosinate may be included in a weight ratio of 1:12 to 16:12 to 16: 3 to 5.
  • composition for the hair composition of the transparent formulation is a cleaning composition.
  • composition according to one aspect of the present invention has the effect of providing a transparent formulation.
  • composition according to one aspect of the present invention when using the composition according to one aspect of the present invention as a transparent shampoo has the effect of providing a clean and gentle image, has the effect of providing a beautiful appearance.
  • the hair softness at the time of rinsing has an excellent effect.
  • composition according to one aspect of the present invention When the composition according to one aspect of the present invention is applied to hair, hair softness in the wet state has an excellent effect.
  • composition according to one aspect of the present invention When the composition according to one aspect of the present invention is applied to hair, hair softness after drying has an excellent effect.
  • composition according to one aspect of the present invention When the composition according to one aspect of the present invention is applied to hair, the conditioning effect is excellent.
  • composition according to one aspect of the present invention When the composition according to one aspect of the present invention is applied to hair, light has less scattering in the hair and has the effect of increasing hair clarity.
  • composition according to one aspect of the invention When applying the composition according to one aspect of the invention to the hair has the effect of increasing the gloss of the hair.
  • composition according to one aspect of the present invention When the composition according to one aspect of the present invention is applied to hair, the foaming force and the amount of foam have an excellent effect.
  • composition according to one aspect of the present invention provides a clear formulation to provide a beautiful appearance and clean and gentle image, and at the same time, when applied to the hair shows an excellent effect on the conditioning effect and hair glossiness.
  • Figure 2 is a photograph when the present invention Comparative Example and Example 4 applied to normal hair and dyed hair.
  • FIG. 3 shows comparative examples of the present specification and Examples 1 to 4 showing data evaluated by each panelist in terms of amount of foam, softness during rinsing, softness in wet state, softness after drying, and hair shine. will be.
  • One aspect of the present invention provides a composition for hair in a transparent formulation comprising polyquaternium-73 (PQ-73) as the cationic polymer.
  • PQ-73 polyquaternium-73
  • One aspect of the invention is a method for hair cleansing, the method comprising applying a composition of a clear formulation comprising polyquaternium-73 (PQ-73) as a cationic polymer to a subject in need thereof Provide a method.
  • PQ-73 polyquaternium-73
  • polyquaternium-73 (PQ-73) as a cationic polymer in preparing a composition of a clear formulation for hair cleaning.
  • the cationic polymer is a conditioning agent, and generally Called polyquaternium, it provides improved conditioning effects and at the same time enables the formulation to be transparent.
  • Poly quaternium-73 is a polymeric quaternary ammonium salt consisting of monomers of propyltrimonium chloride acrylamide, ethyltrimonium chloride methacrylate and dimethylacrylamide.
  • the composition provides a composition for hair of a transparent formulation further comprises a surfactant.
  • the surfactant may be at least one surfactant selected from the group consisting of sodium laureth sulfate, sodium lauroyl sarcosinate, and cocamidopropyl betaine. Can be.
  • the surfactant may include any one or more of sodium laureth sulfate and sodium lauroyl sarcosinate as an anionic surfactant.
  • the surfactant may include cocamidopropyl betaine as an amphoteric surfactant.
  • the polyquaternium-73 may provide a composition for hair in a transparent formulation of 0.01 to 5% by weight based on the total composition.
  • the polyquaternium-73 is 0.01% by weight, 0.05% by weight, 0.10% by weight, 0.15% by weight, 0.20% by weight, 0.25% by weight, 0.30% by weight, 0.35% by weight based on the total composition.
  • the polyquaternium-73 is less than 5% by weight, 4.5% by weight, 4.0% by weight, 3.5% by weight, 3% by weight, 2.5% by weight, 2.0% by weight, 1.5% by weight based on the total composition. % Or less, 1.0% or less, 0.9% or less, 0.8% or less, 0.7% or less, 0.6% or less, 0.59% or less, 0.58% or less, 0.57% or less, 0.56% or less, or 0.55% or less It may be up to 0.54% by weight, up to 0.53% by weight, up to 0.52% by weight, up to 0.51% by weight or up to 0.50% by weight.
  • the surfactant is 0.1 to 30% by weight based on the total composition, preferably the surfactant is 10 to 20% by weight relative to the total composition To provide.
  • the surfactant is 0.1% by weight, 0.5% by weight, 1% by weight, 1.5% by weight, 1.6% by weight, 1.7% by weight, 1.8% by weight, 1.9% by weight, At least 2 wt%, at least 2.1 wt%, at least 2.2 wt%, at least 2.3 wt%, at least 2.4 wt%, at least 2.5 wt%, at least 3 wt%, at least 4 wt%, at least 5 wt%, at least 6 wt%, At least 6.5%, at least 6.6%, at least 6.7%, at least 6.8%, at least 6.9%, at least 7%, at least 7.1%, at least 7.2%, at least 7.3%, at least 7.4%, 7.5% by weight, 8% by weight, 9% by weight, 10%
  • the surfactant is 30% by weight, 25% by weight, 20% by weight, 19% by weight, 18% by weight, 17% by weight, 16.9% by weight, 16.8% by weight, 16.7 wt% or less, 16.6 wt% or less, 16.5 wt% or less, 16.4 wt% or less, 16.3 wt% or less, 16.2 wt% or less, 16.1 wt% or less, 16 wt% or less, 13 wt% or less, 10 wt% or less, 9 wt% or less, 8 wt% or less, 7.9 wt% or less, 7.8 wt% or less, 7.7 wt% or less, 7.6 wt% or less, 7.5 wt% or less, 7.4 wt% or less, 7.3 wt% or less, 7.2 wt% or less, It can be 7.1 wt% or less, 7 wt% or less, 5 wt% or less, 3 wt% or less
  • the content of the surfactant is in the above range, it is excellent in the foaming force, excellent in the conditioning effect and softness when applied to the hair, it is excellent in the hair shiny effect.
  • Another aspect of the invention provides a composition for hair of a transparent formulation comprising the polyquaternium-73 and the surfactant in a weight ratio of 1:20 to 40.
  • the weight ratio of the polyquaternium-73 and the surfactant is 1:20 or more, 1:21 or more, 1:22 or more, 1:23 or more, 1:24 or more, 1:25 or more, 1:26 or more, 1:27 or more, 1:28 or more, 1:29 or more, 1:30 or more, 1:31 or more, 1: 31.2 or more, 1: 31.4 or more, 1: 31.6 or more, 1: 31.8 or more, 1:32 or more, 1: 32.2 or greater, 1: 32.6 or greater, or 1:33 or greater.
  • the weight ratio of the polyquaternium-73 and the surfactant is 1:40 or less, 1:39 or less, 1:38 or less, 1:37 or less, 1:36 or less, 1:35 or less, 1:34 or less, 1:33 or less, 1: 32.8 or less, 1: 32.6 or less, 1: 32.4 or less, 1: 32.2 or less, 1:32 or less, 1: 31.8 or less, 1: 31.6 or less, or 1:30 or less.
  • the weight ratio of the polyquaternium-73 and the surfactant is in the above range, it is excellent in the foaming force, excellent in the conditioning effect and softness when applied to the hair, it is excellent in the hair shiny effect.
  • the surfactant includes sodium laureth sulfate, cocamidopropyl betaine, and sodium lauroyl sarcosinate.
  • the sodium laureth sulfate is 5 to 10% by weight
  • the cocamidopropyl betaine is 5 to 10% by weight
  • the sodium lauroyl salcosinate is 0.1 to 5% by weight to provide a hair composition.
  • the surfactant includes sodium laureth sulfate, cocamidopropyl betaine, and sodium lauroyl sarcosinate
  • the polyquaternium -73, Sodium Laureth Sulfate, Cocamidopropyl Betaine, and Sodium Lauroyl Salcosinate provide a composition for hair in a transparent formulation comprising a weight ratio of 1: 10 to 20: 10 to 20: 1 to 7.
  • the polyquaternium-73, sodium laureth sulfate, cocamidopropyl betaine and sodium lauroyl salcosinate may be in a weight ratio of 1:12 to 16:12 to 16: 3 to 5.
  • the surfactant comprises sodium laureth sulfate, cocamidopropyl betaine and sodium lauroyl sarcosinate, polyquaternium-73 and
  • the weight ratio of sodium laureth sulfate and the weight ratio of polyquaternium-73 and cocamidopropyl betaine are 1:10 or more, 1:11 or more, 1:12 or more, 1:13 or more, 1: 13.2 or more, 1: 13.4 Or greater than 1: 13.6, greater than or equal to 1: 13.8, greater than or equal to 1:14, or greater than or equal to 1:15, and the weight ratio of polyquaternium-73 to sodium laureth sulfate and polyquaternium-73 to cocamidopropyl betaine.
  • Each weight ratio is 1:20 or less, 1:19 or less, 1:18 or less, 1:17 or less, 1:16 or less, 1:15 or less, 1: 14.8 or less, 1: 14.6 or less, 1: 14.4 or less, 1 : 14.2 or less, 1:14 or less, 1: 13.8 or less, 1: 13.6 or less, 1: 13.4 or less, or 1:13 or less.
  • the weight ratio of polyquaternium-73 and sodium lauroyl salcosinate is 1: 1 or more, 1: 2 or more, 1: 3 or more, 1: 3.2 or more, 1: 3.4 or more, 1: 3.6 or more, 1: 3.8 or more, 1: 4.0 or more, 1: 4.2 or more, 1: 4.4 or more, 1: 4.6 or more, or 1: 5 or more.
  • the weight ratio of polyquaternium-73 and sodium lauroyl salcosinate is 1: 7 or less, 1: 6 or less, 1: 5 or less, 1: 4.8 or less, 1: 4.6 or less, 1: 4.4 or less, 1: 4.2 or less, 1: 4 or less, 1: 3.8 or less, 1: 3.6 or less, or 1: 3.4 or less.
  • the shampoo composition according to the present invention may further contain additives such as preservatives, thickeners, viscosity adjusters, pH adjusters, flavorings, dyes, conditioning agents that can be used as a component of the shampoo composition.
  • preservative sodium benzoate, phenoxyethanol and the like can be used.
  • thickener and viscosity modifier include carbomer, hydroxypropylmethylcellulose, hydroxymethylcellulose, sodium chloride, ammonium chloride and the like.
  • Citric acid, sodium hydroxide, triethanolamine, etc. are mentioned as a pH adjuster.
  • the dyes include water-soluble tar pigments.
  • additional conditioning agents include animal and vegetable extracts, proteins and protein variants.
  • Example 2 Example 3
  • Example 4 Purified water 81.80 81.80 81.80 81.80 81.80 81.80 81.80 81.80 Polyquaternium-10 0.50 - - - - Polyquaternium-73 - 0.50 0.50 0.50 0.50 Sodium citrate 0.20 0.20 0.20 0.20 0.20 Sodium laureth sulfate 7.00 16.00 - - 7.00 Cocamidopropyl betaine 7.00 - 16.00 - 7.00 Sodium Lauroyl Sarcosinate 2.00 - - 16.00 2.00 fragrance 1.00 1.00 1.00 1.00 1.00 Sodium benzoate 0.50 0.50 0.50 0.50 0.50 Unit (% by weight) 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00
  • the composition of the present invention In order to measure the hair softness at the time of rinsing the composition of the present invention, it is immersed in a 10% dilution solution of the Comparative Examples and Examples 1 to 3 for 3 minutes and then mounted on a combine machine (water) in a shower machine while rinsing hair The force taken during combing was measured and the results are shown in Table 2 below.
  • the Combing test is a general test method performed in the art, and means that the higher the value of the force required when combing the hair, the poor the conditioning effect.
  • Example 4 As a result of the experiment, compared to the comparative example using PQ-10, the case of Examples 1 to 4 using PQ-73 has a small force when combing, it was confirmed that the softness in dry hair is better. In particular, in Example 4, the softness in the dry hair was the best.
  • composition of the present invention When the composition of the present invention is applied, normal hair and dyed hair tress are prepared to compare the shine in hair.
  • the compositions of Comparative Example and Example 4 above were used five times in each tress. 30 °C, 40% relative humidity) was incubated in a constant temperature room for one day and completely dried. Dried hair is shown in FIG. 2. The hair was fixed to a gloss measurement device and the results of measuring the gloss are shown in Table 4 below as Luster Values.
  • the Luster Value was excellent in both the dyed hair and the normal hair during the treatment of Example 4 compared to the comparative example, and the dyed hair and the normal hair treated in Example 4 had less light scattering and excellent hair clarity as shown in FIG.
  • the composition of the present invention it was confirmed that the gloss of the hair is enhanced.
  • Example 2 Example 3
  • Example 4 Amount of foam 4.57 6.86 6.14 5.57 7.29 Soft when rinsing 3.71 4.00 7.29 6.86 8.14 Softness in wet conditions 4.43 4.71 7.00 6.43 7.86 Softness after drying 4.14 4.86 6.57 6.71 8.00 Hair shine 4.86 5.29 5.29 6.14 6.86
  • Example 1 to 4 are superior to the comparative example, 2) in rinsing, soft in wet and soft after drying, Examples 1 to 4 were superior to the comparative example, and 3) Examples 1 to 4 were superior to the comparative example even in hair shine. In particular, Example 4 showed the best in all of the above evaluation items.

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Abstract

La présente invention concerne une composition pour les cheveux de formulation transparente comprenant du polyquaternium-73. La composition peut en outre comprendre un tensioactif en plus du polyquaternium-73, le tensioactif étant au moins un tensioactif sélectionné au sein du groupe constitué du laureth sulfate de sodium, du sarcosinate de lauroyle de sodium et de la bétaïne de cocamidopropyle. La composition selon un aspect de la présente invention concerne une formulation transparente et présente d'excellents effets en termes de capacité à former de la mousse, de conditionnement, et d'intensification de l'éclat des cheveux.
PCT/KR2016/010481 2015-09-23 2016-09-20 Composition à base d'une formulation transparente pour les cheveux Ceased WO2017052161A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201680054897.3A CN108024934A (zh) 2015-09-23 2016-09-20 用于毛发的透明制剂组合物
HK18107953.0A HK1249012A1 (zh) 2015-09-23 2016-09-20 用於毛发的透明制剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2015-0134738 2015-09-23
KR1020150134738A KR102418098B1 (ko) 2015-09-23 2015-09-23 모발용 투명 제형 조성물

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WO2017052161A1 true WO2017052161A1 (fr) 2017-03-30

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PCT/KR2016/010481 Ceased WO2017052161A1 (fr) 2015-09-23 2016-09-20 Composition à base d'une formulation transparente pour les cheveux

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KR (1) KR102418098B1 (fr)
CN (1) CN108024934A (fr)
HK (1) HK1249012A1 (fr)
TW (1) TWI725050B (fr)
WO (1) WO2017052161A1 (fr)

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US20190105245A1 (en) * 2017-10-10 2019-04-11 The Procter & Gamble Company Compact shampoo composition containing sulfate-free surfactants
US10799434B2 (en) 2016-10-21 2020-10-13 The Procter & Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
US10842720B2 (en) 2016-10-21 2020-11-24 The Procter And Gamble Company Dosage of foam comprising an anionic/zwitterionic surfactant mixture
US10888505B2 (en) 2016-10-21 2021-01-12 The Procter And Gamble Company Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space
US10912732B2 (en) 2017-12-20 2021-02-09 The Procter And Gamble Company Clear shampoo composition containing silicone polymers
CN112891240A (zh) * 2021-02-05 2021-06-04 纳爱斯浙江科技有限公司 一种兼具清洁力、泡沫体验和低牙齿磨损、低口腔黏膜刺激性的组合物
US11116703B2 (en) 2017-10-10 2021-09-14 The Procter And Gamble Company Compact shampoo composition containing sulfate-free surfactants
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US11129775B2 (en) 2017-10-10 2021-09-28 The Procter And Gamble Company Method of treating hair or skin with a personal care composition in a foam form
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US11154467B2 (en) 2016-10-21 2021-10-26 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair conditioning benefits
US11202740B2 (en) 2016-10-21 2021-12-21 The Procter And Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
US11224567B2 (en) 2017-06-06 2022-01-18 The Procter And Gamble Company Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel
US11291616B2 (en) 2015-04-23 2022-04-05 The Procter And Gamble Company Delivery of surfactant soluble anti-dandruff agent
US11318073B2 (en) 2018-06-29 2022-05-03 The Procter And Gamble Company Low surfactant aerosol antidandruff composition
US11446217B2 (en) 2016-03-03 2022-09-20 The Procter & Gamble Company Aerosol antidandruff composition
US11679073B2 (en) 2017-06-06 2023-06-20 The Procter & Gamble Company Hair compositions providing improved in-use wet feel
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
CN116507312A (zh) * 2020-12-02 2023-07-28 大阪有机化学工业株式会社 固体洗涤剂组合物
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11980679B2 (en) 2019-12-06 2024-05-14 The Procter & Gamble Company Sulfate free composition with enhanced deposition of scalp active
US11986543B2 (en) 2021-06-01 2024-05-21 The Procter & Gamble Company Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants
US12226505B2 (en) 2018-10-25 2025-02-18 The Procter & Gamble Company Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents
US12427099B2 (en) 2020-11-23 2025-09-30 The Procter & Gamble Company Personal care composition
US12458575B2 (en) 2021-12-09 2025-11-04 The Procter & Gamble Company Sulfate free personal cleansing composition comprising effective preservation

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