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WO2016194595A1 - Composition nettoyante pour les cheveux - Google Patents

Composition nettoyante pour les cheveux Download PDF

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Publication number
WO2016194595A1
WO2016194595A1 PCT/JP2016/064476 JP2016064476W WO2016194595A1 WO 2016194595 A1 WO2016194595 A1 WO 2016194595A1 JP 2016064476 W JP2016064476 W JP 2016064476W WO 2016194595 A1 WO2016194595 A1 WO 2016194595A1
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WO
WIPO (PCT)
Prior art keywords
mass
scalp
content
hair
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2016/064476
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English (en)
Japanese (ja)
Inventor
泉 大石
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Lion Corp
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Lion Corp
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Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to MYPI2017704220A priority Critical patent/MY185250A/en
Priority to KR1020177030288A priority patent/KR102539780B1/ko
Publication of WO2016194595A1 publication Critical patent/WO2016194595A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a hair cleaning composition.
  • a hair cleansing composition that is excellent in foaming, fine foam, and smooth hair during rinsing, can improve the flexibility of the scalp, and can increase the moisture content of the scalp. ing.
  • the present invention provides a hair cleansing composition that is excellent in foaming, fineness of foam, and smoothness of hair during rinsing, can improve the flexibility of the scalp, and can increase the moisture content of the scalp.
  • the purpose is to provide.
  • This invention is based on the said knowledge by this inventor, and as a means for solving the said subject, it is as follows. ⁇ 1> (A) polyoxyethylene alkyl ether sulfate, (B) an amphoteric surfactant, (C) N-acyl amino acid ester, (D) polyoxyethylene hydrogenated castor oil having an average addition mole number of ethylene oxide of 5 to 30, and (E) a cationic polymer, The content (mass%) of the (C) N-acyl amino acid ester and the content (mass%) of the polyoxyethylene hydrogenated castor oil in which the average added mole number of the ethylene oxide (D) is 5 to 30 A hair cleansing composition having a mass ratio (D / C) of 1 to 12.5.
  • the content of the (C) N-acyl amino acid ester is 0.08% by mass to 1% by mass
  • the content of the polyoxyethylene alkyl ether sulfate (A) is 12% by mass to 20% by mass
  • the content of the cationic polymer (E) is 0.1% by mass to 1% by mass
  • the hair cleansing composition according to any one of ⁇ 1> to ⁇ 2>, wherein the mass ratio (D / C) is 3 to 9.
  • the (B) amphoteric surfactant is at least one selected from alkylbetaine amphoteric surfactants, amidobetaine amphoteric surfactants, and imidazolinium betaine amphoteric surfactants,
  • the hair cleansing composition according to any one of ⁇ 1> to ⁇ 3>, wherein the content of the (B) amphoteric surfactant is 1% by mass to 20% by mass.
  • the present invention it is possible to solve the above-mentioned problems and achieve the above-mentioned object, and it is excellent in foaming, fineness of foam, and smoothness of hair during rinsing, and improves the flexibility of the scalp. It is possible to provide a hair cleansing composition that can increase the amount of water in the scalp.
  • the hair cleansing composition of the present invention has an average addition mole number of (A) polyoxyethylene alkyl ether sulfate, (B) amphoteric surfactant, (C) N-acyl amino acid ester, and (D) ethylene oxide. 30 to 30 polyoxyethylene hydrogenated castor oil and (E) a cationic polymer, and further contains other components as necessary.
  • polyoxyethylene alkyl ether sulfate Polyoxyethylene alkyl ether sulfate> The polyoxyethylene alkyl ether sulfate of component (A) is contained to improve foaming, fineness of foam, smoothness of hair at the time of rinsing, flexibility of scalp, and moisture content of scalp. Yes.
  • the number of carbon atoms in the alkyl group portion of the polyoxyethylene alkyl ether sulfate of component (A) is preferably 10 to 24, more preferably 12 to 14 from the viewpoint of good foaming.
  • the average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (A) (hereinafter sometimes referred to as “EO”) is preferably 1 to 3 from the viewpoint of good foaming. ⁇ 3 are more preferred.
  • EO average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (A)
  • EO average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (A)
  • EO average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (A)
  • EO average added mole number of ethylene oxide of the polyoxyethylene alkyl ether sulfate of the component (
  • the polyoxyethylene alkyl ether sulfate as the component (A) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include compounds represented by the following general formula (a).
  • R 1 O (CH 2 CH 2 O) m SO 3 M 1 ⁇ formula (a) (In the general formula (a), R 1 represents an alkyl group, M 1 represents an alkali metal, ammonium, or alkanolamine, and m represents an integer of 1 to 3)
  • Examples of the (A) component polyoxyethylene alkyl ether sulfate include polyoxyethylene capryl ether sulfate (EO: 1 to 3), polyoxyethylene lauryl ether sulfate (EO: 1 to 3), polyoxyethylene Examples include ethylene myristyl ether sulfate (EO: 1 to 3), polyoxyethylene palmityl ether sulfate (EO: 1 to 3), and polyoxyethylene stearyl ether sulfate (EO: 1 to 3). These may be used alone or in combination of two or more.
  • polyoxyethylene lauryl ether sulfate (EO: 1 to 3) is preferable and polyoxyethylene lauryl ether ammonium sulfate (EO: 2) is more preferable from the viewpoint of good foaming and fineness of the foam.
  • polyoxyethylene alkyl ether sulfate of the component (A) a commercially available product may be used, or an appropriately synthesized product may be used.
  • the commercially available product include trade name: EMAL 170J (polyoxyethylene lauryl ether sodium sulfate (EO: 1), manufactured by Kao Corporation), trade name: Sinoline SPE-1250 (polyoxyethylene lauryl ether sodium sulfate (EO) : 2), manufactured by Shin Nippon Rika Co., Ltd.), trade name: Teikapol NE1270 (polyoxyethylene lauryl ether ammonium sulfate (EO: 3), manufactured by Teika Co., Ltd.), and the like. These may be used alone or in combination of two or more.
  • Sinoline SPE-1250 sodium polyoxyethylene lauryl ether sulfate (EO: 2), manufactured by Shin Nippon Rika Co., Ltd.
  • EO sodium polyoxyethylene lauryl ether sulfate
  • the content of the polyoxyethylene alkyl ether sulfate of the component (A) from the viewpoint of good foaming, fine foam, smooth hair during rinsing, scalp flexibility, and scalp moisture content, 5% by mass to 25% by mass is preferable and 12% by mass to 20% by mass is more preferable based on the total amount of the hair cleaning composition.
  • the content is less than 5% by mass, the foaming and fineness of the foam may be insufficient.
  • the content exceeds 25% by mass, the smoothness of the hair during rinsing and the flexibility of the scalp. And the amount of water in the scalp may be insufficient.
  • the coacervate with (E) component since the coacervate with (E) component is not formed, the smoothness of the hair at the time of a rinse becomes inadequate.
  • the (B) component amphoteric surfactant is contained in order to improve the fineness of foam, the flexibility of the scalp, and the moisture content of the scalp.
  • amphoteric surfactant of the component (B) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include betaine amphoteric surfactants, aminopropionic acid amphoteric surfactants, and amino acid amphoteric surfactants. Surfactant etc. are mentioned. These may be used individually by 1 type and may use 2 or more types together. Among these, betaine amphoteric surfactants are preferable.
  • betaine amphoteric surfactants examples include alkylbetaine amphoteric surfactants, amide betaine amphoteric surfactants, sulfobetaine amphoteric surfactants, phosphobetaine surfactants, and imidazolinium betaine amphoteric interfaces. An active agent etc. are mentioned. These may be used individually by 1 type and may use 2 or more types together. Among these, alkylbetaine amphoteric surfactants, amidobetaine amphoteric surfactants, and imidazolinium betaine amphoteric surfactants are preferred, and amide betaine amphoteric surfactants are more preferred from the viewpoint of fineness of foam. .
  • alkylbetaine amphoteric surfactant examples include alkyldimethylaminoacetic acid betaine.
  • alkyldimethylaminoacetic acid betaine examples include lauryldimethylaminoacetic acid betaine, myristyldimethylaminoacetic acid betaine, and stearyldimethylaminoacetic acid betaine. These may be used individually by 1 type and may use 2 or more types together. Among these, lauryldimethylaminoacetic acid betaine is preferable.
  • amidobetaine amphoteric surfactant examples include alkylamidopropylbetaine.
  • alkylamidopropyl betaine examples include coconut oil fatty acid amidopropyl betaine (cocamidopropyl betaine), lauric acid amidopropyl betaine, and isostearamidopropyl betaine. These may be used individually by 1 type and may use 2 or more types together. Among these, lauric acid amidopropyl betaine and coconut oil fatty acid amidopropyl betaine are preferable.
  • sulfobetaine amphoteric surfactants examples include hydroxysulfobetaine amphoteric surfactants and amide sulfobetaine amphoteric surfactants.
  • hydroxysulfobetaine amphoteric surfactants examples include coconut oil fatty acid dimethylaminohydroxysulfobetaine, lauryldimethylaminohydroxysulfobetaine, and laurylhydroxysulfobetaine. These may be used individually by 1 type and may use 2 or more types together.
  • amidosulfobetaine-based amphoteric surfactant examples include dodecylaminomethyldimethylsulfopropylbetaine and octadecylaminomethyldimethylsulfopropylbetaine. These may be used individually by 1 type and may use 2 or more types together.
  • Examples of the phosphobetaine surfactant include alkylhydroxyphosphobetaine.
  • Examples of the alkyl hydroxyphosphobetaine include lauryl hydroxyphosphobetaine, myristyl hydroxyphosphobetaine, stearyl hydroxyphosphobetaine, and the like. These may be used individually by 1 type and may use 2 or more types together.
  • imidazolinium betaine amphoteric surfactant examples include coconut oil alkyl-N-hydroxyethyl imidazolinium betaine, coconut oil alkyl-N-carboxyethyl-N-hydroxyethyl imidazolinium betaine, 2-alkyl- And N-carboxymethyl-N-hydroxyethylimidazolinium betaine. These may be used individually by 1 type and may use 2 or more types together. Among these, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine is preferable.
  • aminopropionic acid-based amphoteric surfactant examples include sodium laurylaminodipropionate and triethanolamine laurylaminodipropionate. These may be used individually by 1 type and may use 2 or more types together.
  • Examples of the amino acid-based amphoteric surfactant include alkylamino fatty acids or salts thereof.
  • alkylamino fatty acid include laurylamino fatty acid, stearylamino fatty acid, myristylamino fatty acid and the like. These may be used individually by 1 type and may use 2 or more types together.
  • Examples of the counter ion of the salt include alkali metal salts, ammonium salts, alkanolamine salts, and the like. Among these, alkali metal salts are preferable, sodium and potassium are more preferable, and sodium is particularly preferable.
  • amphoteric surfactant for the component (B) a commercially available product can be used.
  • the commercially available product include trade name: Enadicol L-30B (amidopropyl betaine laurate, manufactured by Otsuka Kogyo Co., Ltd.) ), Product name: Amhitoal 55AB (coconut oil fatty acid amidopropyl betaine solution), product name: Amhitoal 20Y-B (2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine) (above, manufactured by Kao Corporation) ), Amogen SH (Lauryldimethylaminoacetic acid betaine, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), and the like. These may be used individually by 1 type and may use 2 or more types together.
  • the content of the amphoteric surfactant of the component (B) is 1% by mass to 20% with respect to the total amount of the hair cleaning composition in terms of fineness of foam, flexibility of the scalp, and moisture content of the scalp. % By mass is preferable, and 3% by mass to 10% by mass is more preferable. When the content is less than 1% by mass, the fineness of the foam and the moisture content of the scalp may be insufficient. When the content exceeds 20% by mass, the flexibility of the scalp and the moisture content of the scalp are increased. It may be insufficient.
  • N-acyl amino acid ester > The N-acyl amino acid ester of component (C) is contained in order to improve foaming, fineness of foam, smoothness of hair upon rinsing, flexibility of scalp, and moisture content of scalp.
  • the N-acyl amino acid ester of the component (C) is an ester of an N-acyl amino acid and a higher alcohol.
  • the N-acyl amino acid is not particularly limited as long as it has an acyl group, and can be appropriately selected according to the purpose. Examples thereof include N-acyl acidic amino acids. Examples of the N-acyl acidic amino acid include N-acyl aspartic acid and N-acyl glutamic acid. These may be used individually by 1 type and may use 2 or more types together. Among these, N-acyl glutamic acid is preferable.
  • the structures of these amino acids may be optically active or racemic.
  • the acyl group is preferably an acyl group derived from a saturated or unsaturated fatty acid having 8 to 22 carbon atoms.
  • the acyl group is a fatty acid having a single composition such as lauric acid, palmitic acid, stearic acid, or oleic acid.
  • it may be a mixed fatty acid obtained from nature such as coconut oil fatty acid, beef tallow fatty acid, hardened beef tallow fatty acid, or an acyl group of fatty acids (including branched fatty acids) obtained by synthesis.
  • the higher alcohols are not particularly limited, and examples thereof include sterols, alkyl alcohols having 8 to 38 carbon atoms, and alkenyl alcohols having 8 to 38 carbon atoms. Among these, sterols, liquid higher alkyl alcohols having 8 to 30 carbon atoms, liquid higher alkenyl alcohols having 8 to 30 carbon atoms, and solid higher alkyl alcohols having 12 to 38 carbon atoms are preferable.
  • the N-acyl acidic amino acid ester of component (C) may be a monoester form or a diester form, and a diester form in which at least one of two ester forming residues is a sterol residue is preferable.
  • the sterol may be animal-derived or plant-derived, and examples thereof include cholesterol, phytosterol, and hydrogenated products thereof.
  • the liquid higher alkyl alcohol having 8 to 30 carbon atoms and the liquid higher alkenyl alcohol having 8 to 38 carbon atoms are natural or synthetic aliphatic alcohols having 8 to 30 carbon atoms and are liquid at room temperature. Examples thereof include branched alcohols such as 2-octyldodecyl alcohol and unsaturated alcohols such as oleyl alcohol.
  • the solid higher alkyl alcohol having 12 to 38 carbon atoms is a saturated monohydric alcohol having 12 to 38 carbon atoms and is solid at room temperature, and examples thereof include cetyl alcohol and behenyl alcohol. It is done.
  • the N-acyl amino acid ester of the component (C) can be used singly or in combination of two or more, and preferably includes those having a sterol residue as at least one ester residue.
  • N-acyl amino acid ester of the component (C) examples include N-lauroyl-L-glutamate di (phytosteryl / 2-octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / 2-octyldodecyl) and the like. These may be used individually by 1 type and may use 2 or more types together.
  • N-lauroyl-L-glutamate di cholesteryl / octyldodecyl
  • N-lauroyl-L-glutamate di phytosteryl / 2-octyldodecyl
  • N-lauroyl- More preferred is L-glutamate (phytosteryl / 2-octyldodecyl).
  • N-acyl amino acid ester of the component (C) a commercially available product can be used, and examples of the commercially available product include trade name: Erdeu PS-203 (N-lauroyl-L-glutamate di (phytosteryl / 2).
  • the content of the N-acyl amino acid ester of the component (C) is based on the total amount of the hair cleaning composition in terms of foaming, fineness of foam, softness of the scalp, and moisture content of the scalp. 0.05 mass% to 3 mass% is preferable, and 0.08 mass% to 1 mass% is more preferable. When the content is less than 0.05% by mass, the scalp flexibility and the moisture content of the scalp may be insufficient. When the content exceeds 3% by mass, the foaming is good and the foam is fine. May be insufficient.
  • the (D) component polyoxyethylene hydrogenated castor oil is contained to improve foaming, fineness of foam, flexibility of scalp, and moisture content of scalp.
  • the (D) component polyoxyethylene hydrogenated castor oil is an esterified product obtained by addition polymerization of ethylene oxide to hydrogenated castor oil.
  • the average added mole number of ethylene oxide in the polyoxyethylene hydrogenated castor oil is 5 to 30, preferably 7 to 20.
  • Polyoxyethylene hydrogenated castor oil having an average added mole number of ethylene oxide of less than 5 is generally not commercially available. On the other hand, if it exceeds 30, the foaming quality, the fineness of the foam, the flexibility of the scalp, and the moisture content of the scalp will be insufficient.
  • the HLB value of the polyoxyethylene hydrogenated castor oil is preferably 5 to 11, and more preferably 6 to 9.
  • (D) component polyoxyethylene hydrogenated castor oil a commercially available product can be used.
  • the commercially available product include trade name: EMALEX HC-5 (EO: 5, HLB value: 5), product Name: EMALEX HC-7 (EO: 7, HLB value: 6), Product name: EMALEX HC-10 (EO: 10, HLB value: 7), Product name: EMALEX HC-20 (EO: 20, HLB value: 9), trade name: EMALEX HC-30 (EO: 30, HLB: 11) (above, manufactured by Nippon Emulsion Co., Ltd.), trade name: Braunon CW-20-90 (EO: 20, manufactured by Aoki Oil & Fat Co., Ltd.) Etc. These may be used alone or in combination of two or more. Among these, trade name: EMALEX HC-20 (EO: 20, HLB value: 9) is preferable.
  • the said HLB value is shown by IOB value x10 in an organic conceptual diagram.
  • the IOB in the organic conceptual diagram refers to the ratio of the inorganic value (IV) to the organic value (OV) in the organic conceptual diagram, that is, “inorganic value (IV) / organic value (OV)”.
  • the organic conceptual diagram was proposed by Satoshi Fujita, and details thereof are described in “Pharmaceutical Bulletin”, 1954, vol. 2, 2, pp. 163-173, “Area of Chemistry”, 1957, vol. 11, 10, pp. 719-725, “Fragrance Journal”, 1981, vol. 50, pp. 79-82, “Organic Conceptual Diagram-Fundamentals and Applications” (by Yoshio Koda, Sankyo Publishing, 1984).
  • the content of the (D) component polyoxyethylene hydrogenated castor oil is based on the total amount of the hair cleaning composition from the viewpoint of good foaming, fineness of foam, softness of scalp, and moisture content of scalp. 0.05 mass% to 3 mass% is preferable, and 0.1 mass% to 1 mass% is more preferable. When the content is less than 0.05% by mass, good foaming, fineness of the foam, softness of the scalp, and moisture content of the scalp may be insufficient, and when it exceeds 3% by mass, The foaming quality and the fineness of the foam may be insufficient.
  • the mass ratio (D / C) is 1 to 12.5 in terms of foaming, fineness of foam, smoothness of hair during rinsing, flexibility of scalp, and moisture content of scalp. 3 to 9 are preferred.
  • the mass ratio (D / C) is less than 1, the foaming quality, the scalp flexibility, and the moisture content of the scalp are insufficient, and when it exceeds 12.5, the fineness of the foam and when rinsing The smoothness of the hair becomes insufficient.
  • ⁇ (E) Cationic polymer The cationic polymer of the component (E) is contained to improve the smoothness of hair during rinsing, the flexibility of the scalp, and the moisture content of the scalp.
  • Examples of the cationic polymer of the component (E) include cationized cellulose (for example, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose chloride, trade name: kachinal HC-100, trade name).
  • cationized cellulose for example, O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethyl cellulose chloride, trade name: kachinal HC-100, trade name).
  • Katchinal HC-200 trade name: Katchinal LC-100, trade name: Katchinal LC-200 (Toho Chemical Co., Ltd.), etc.
  • cationized guar gum for example, O- [2-hydroxy-3- (trimethylammonium chloride) E) Propyl] Guar gum, trade name: JAGUAR EXCEL, manufactured by Sansho Corporation
  • cationized locust bean gum trade name: JAGUAR EXCEL, manufactured by Sansho Corporation
  • cationized locust bean gum trade name: JAGUAR EXCEL, manufactured by Sansho Corporation
  • cationized locust bean gum cationized tara gum
  • homopolymer of diallyl quaternary ammonium salt diallyl quaternary ammonium salt / acrylamide copolymer
  • dimethyldiallylammo Um chloride / acrylamide copolymer trade name: Marquat 2200, manufactured by Nalco Co., Ltd.
  • cationized cellulose chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose
  • cationized guar gum O- [2-chloride
  • Hydroxy-3- (trimethylammonio) propyl] guam gum is preferred
  • cationized cellulose chlorinated O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose
  • weight average molecular weight of the cationic polymer of the said (E) component there is no restriction
  • the weight average molecular weight is a value measured using GPC-MALLS, and a sample solution diluted with a mobile phase having a pure polymer concentration of about 1,000 ppm is used as a TSK-GELA column (manufactured by Tosoh Corporation).
  • a wavelength of about 633 nm can be measured with a multi-angle light scattering detector.
  • polyethylene glycol having a known molecular weight can be used as a standard product.
  • the content of the cationic polymer of the component (E) is 0.05% with respect to the total amount of the hair cleaning composition in terms of the smoothness of the hair during rinsing, the flexibility of the scalp, and the moisture content of the scalp. % By mass to 2% by mass is preferable, and 0.1% by mass to 1% by mass is more preferable. When the content is less than 0.05% by mass, the smoothness of the hair at the time of rinsing, the flexibility of the scalp, and the moisture content of the scalp may be insufficient, and when the content exceeds 2% by mass, Not only may the flexibility of hair be insufficient, but there may be problems such as stiff hair.
  • the other components are not particularly limited, and can contain other components in addition to the components (A) to (E) as long as the effects of the present invention are not impaired.
  • the pH of the hair cleansing composition at 25 ° C. is preferably 3-7. If the pH is less than 3, there is a concern about irritation to the background, and if it exceeds 7, the antiseptic power may be reduced and microorganisms may propagate.
  • the pH can be measured according to the quasi-drug raw material standard general test method pH measurement method.
  • the pH of the hair cleaning composition can be adjusted by adding a pH adjusting agent such as citric acid while confirming the pH after mixing all the components. More specifically, purified water is balanced and mixed and stirred so that the total of components other than the pH adjuster such as citric acid is about 98% by mass. If necessary, it may be heated. While mixing and stirring, an aqueous solution of a pH adjusting agent such as citric acid is gradually added, and each is added to the target pH while measuring the pH. When the target pH is reached, the remaining purified water is finally added, and water is added so that the total amount becomes 100% by mass.
  • the pH can be measured according to the quasi-drug raw material standard general test method pH measurement method.
  • the viscosity of the hair cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 Pa ⁇ s to 25 Pa ⁇ s, preferably 8 Pa ⁇ s to 16 Pa ⁇ s at 25 ° C. More preferred.
  • the viscosity is less than 1 Pa ⁇ s, it may be difficult to use because it spills from the hand during use, and when it exceeds 25 Pa ⁇ s, the dischargeability from the container may be deteriorated.
  • said viscosity it can measure at 25 degreeC based on a quasi-drug raw material standard general test method viscosity measuring method 2nd method.
  • -Dosage form There is no restriction
  • the properties include liquid, cream, foam, gel, and wax.
  • the dosage form include a pump type, a spray type, and a tube type.
  • the method for producing the hair cleaning composition is not particularly limited and may be appropriately selected depending on the intended purpose. It is prepared by mixing the component (A) to the component (E) and the other components. can do. Specifically, the component (E) and purified water are uniformly mixed at 50 ° C. to 60 ° C. and swollen, and then heated to 70 ° C. to 75 ° C. to obtain the component (A) and the component (B ) Add ingredients and mix uniformly. Then, it cools to 40 degrees C or less, the mixture of the said (C) component and the said (D) component is added, and it mixes uniformly. After cooling to 30 ° C.
  • the other components are added, and the remaining amount of purified water is blended and mixed uniformly so that the total amount of the hair cleaning composition is 100% by mass to obtain a hair cleaning composition.
  • an apparatus which prepares the said hair-cleaning-agent composition According to the objective, it can select suitably, For example, it equips with several stirring blades (propeller, turbine, a disper, etc.) which can carry out shearing and the whole mixing. And a stirrer.
  • tube containers such as an aluminum laminate tube, an EVAL tube, an aluminum tube, a glass vapor deposition plastic tube, a pump container by mechanical or a differential pressure And squeeze containers, laminate film containers, dropper containers, bottle containers, and the like.
  • the material of the aluminum laminated tube container include a laminated film.
  • the laminate film usually has two or more layers, and more preferably two to five layers, from the viewpoint of strength, flexibility, weather resistance and the like.
  • Examples of the material of the laminate film include polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, synthetic resin such as ethylene-vinyl acetate copolymer, paper, aluminum vapor-deposited plastic, and the like.
  • Examples of the material of the bottle container include polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile-styrene resin, ABS resin, polyamide, glass, and the like. Single layer to two layers It is preferable to use in combination.
  • the hair cleanser composition of the present invention is excellent in foaming, fineness of foam, and smoothness of hair at the time of rinsing, can improve the flexibility of the scalp, and can increase the moisture content of the scalp, For example, it is suitable for in bath hair care agents such as shampoo and rinse-in shampoo.
  • compositions and contents of the hair cleaning compositions shown in Tables 1 to 13 below were prepared by the following method. That is, (E) component or (E ′) component and purified water are uniformly mixed at 50 ° C. to 60 ° C., swollen, and then heated to 70 ° C. to 75 ° C. to obtain (A) component or (A ′ ) Component and (B) component or (B ′) component were added and mixed uniformly. Then, it cooled to 40 degrees C or less, the mixture of (C) component or (C ') component, and (D) component or (D') component was added, and it mixed uniformly.
  • Average value of judgment points is 4.5 points or more ⁇ : Average value of judgment points is 3.5 points or more and less than 4.5 points ⁇ : Average value of judgment points is 2.5 points or more and less than 3.5 points ⁇ : Average value of judgment points is less than 2.5
  • ⁇ Flexibility of scalp> Four male panelists in their 30s to 40s who feel the scalp hardening and dryness with aging wash their hair with 4 g of each hair cleaning composition, and measure the hardness of the scalp at the top and bottom of the hair before and after washing.
  • the hardness of the scalp was measured using a viscoelasticity measuring device (trade name: Vesmeter E-100HS, manufactured by Wave Cyber Co., Ltd.). Specifically, after acclimating for 30 minutes in a constant temperature and humidity chamber adjusted to 25 ° C. and 40% RH before washing the hair, the probe of the portable wireless viscoelasticity measuring instrument is placed on the top of the head before washing. It was pressed against the scalp and the maximum load was measured.
  • the measurement was performed 10 times, and the average value of the maximum load was defined as the hardness (initial value) of the scalp before washing.
  • shampooing was performed, and after the shampooing, the average value of the maximum load after shampooing was determined under the same habituation and measurement conditions as before the shampooing, and was used as the hardness of the scalp after shampooing.
  • For 4 male panelists calculate the cure rate of the scalp hardness after washing the hair relative to the scalp hardness (initial value) before washing the hair, calculate the average cure rate of 4 male panelists, and based on the following evaluation criteria
  • the “scalp flexibility” was evaluated. It is known that the average curing rate when washing with a commercially available hair cleansing composition is about 100% to 130%.
  • the lower the average curing rate the softer the scalp is than before washing the hair.
  • the top of the head means a place that is at the uppermost position on the head when anatomically normal.
  • -Evaluation criteria for scalp flexibility A: Average curing rate is less than 90% (the scalp is softer than before washing) ⁇ : The average curing rate is 90% or more and less than 100% (the scalp becomes slightly softer than before washing the hair) (Triangle
  • X The average curing rate is 110% or more (the scalp is harder than before washing the hair)
  • ⁇ Moisture content of scalp> Four male panelists in their 30s to 40s who feel the scalp hardening and dryness with aging performed shampooing under the same conditions as in the above-mentioned evaluation of “flexibility of the scalp”.
  • the moisture content of the scalp was measured using a highly sensitive stratum corneum moisture meter (trade name: ASA-MX, manufactured by Asahi Biomed Co., Ltd.).
  • the moisture content of the scalp before and after shampooing is measured, the average value of the moisture content before and after shampooing, the moisture content of the scalp before shampooing (initial value), and The moisture content of the scalp after shampooing was used.
  • the hair cleanser composition of the present invention is excellent in foaming, fineness of foam, and smoothness of hair at the time of rinsing, can improve the flexibility of the scalp, and can increase the moisture content of the scalp, For example, it is suitable for in bath hair care agents such as shampoo and rinse-in shampoo.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition nettoyante pour les cheveux comprenant (A) un sulfate d'éther d'alkyle de polyoxyéthylène, (B) un tensioactif amphotère, (C) un ester de N-acylaminoacide, (D) de l'huile de ricin hydrogénée polyoxyéthylénique ayant un nombre moyen de moles de motifs d'oxyde d'éthylène ajoutées de 5 à 30, et (E) un polymère cationique, dans lequel le rapport en masse (D/C) de la teneur (% en masse) de l'ester de N-acylaminoacide (C) à la teneur (% en masse) de l'huile de ricin hydrogénée polyoxyéthylénique (D) ayant un nombre moyen de moles de motifs d'oxyde d'éthylène ajoutées de 5 à 30 est de 1 à 12,5.
PCT/JP2016/064476 2015-05-29 2016-05-16 Composition nettoyante pour les cheveux Ceased WO2016194595A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MYPI2017704220A MY185250A (en) 2015-05-29 2016-05-16 Hair cleanser composition
KR1020177030288A KR102539780B1 (ko) 2015-05-29 2016-05-16 모발 세정제 조성물

Applications Claiming Priority (2)

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JP2015-110548 2015-05-29
JP2015110548A JP6476070B2 (ja) 2015-05-29 2015-05-29 毛髪洗浄剤組成物

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WO2016194595A1 true WO2016194595A1 (fr) 2016-12-08

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KR (1) KR102539780B1 (fr)
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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN109745246A (zh) * 2017-11-01 2019-05-14 日油株式会社 毛发清洗剂组合物

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7333686B2 (ja) * 2018-10-05 2023-08-25 ライオン株式会社 フォーマー容器入り皮膚洗浄剤組成物

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JPH10175826A (ja) * 1996-12-16 1998-06-30 Lion Corp シャンプー組成物
JPH11240828A (ja) * 1997-12-25 1999-09-07 Ajinomoto Co Inc 化粧料用油性原料
JP2000154112A (ja) * 1998-06-01 2000-06-06 Ajinomoto Co Inc 新規化粧料組成物
JP2004210658A (ja) * 2002-12-27 2004-07-29 Kose Corp 毛髪化粧料
JP2005239625A (ja) * 2004-02-26 2005-09-08 Kanebo Cosmetics Inc 毛髪化粧料

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JP5078130B2 (ja) 2007-03-23 2012-11-21 株式会社 資生堂 洗浄料
JP5280873B2 (ja) 2009-01-22 2013-09-04 株式会社 資生堂 毛髪化粧料
JP5630801B2 (ja) 2009-03-31 2014-11-26 株式会社コーセー 洗浄剤組成物

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JPH10175826A (ja) * 1996-12-16 1998-06-30 Lion Corp シャンプー組成物
JPH11240828A (ja) * 1997-12-25 1999-09-07 Ajinomoto Co Inc 化粧料用油性原料
JP2000154112A (ja) * 1998-06-01 2000-06-06 Ajinomoto Co Inc 新規化粧料組成物
JP2004210658A (ja) * 2002-12-27 2004-07-29 Kose Corp 毛髪化粧料
JP2005239625A (ja) * 2004-02-26 2005-09-08 Kanebo Cosmetics Inc 毛髪化粧料

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109745246A (zh) * 2017-11-01 2019-05-14 日油株式会社 毛发清洗剂组合物

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KR102539780B1 (ko) 2023-06-07
KR20180011067A (ko) 2018-01-31
MY185250A (en) 2021-04-30
JP6476070B2 (ja) 2019-02-27

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