WO2016003068A1 - Aluminum alloy conductor wire and method for manufacturing same - Google Patents
Aluminum alloy conductor wire and method for manufacturing same Download PDFInfo
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- WO2016003068A1 WO2016003068A1 PCT/KR2015/005059 KR2015005059W WO2016003068A1 WO 2016003068 A1 WO2016003068 A1 WO 2016003068A1 KR 2015005059 W KR2015005059 W KR 2015005059W WO 2016003068 A1 WO2016003068 A1 WO 2016003068A1
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- aluminum alloy
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
Definitions
- the present invention relates to an aluminum alloy conductor wire and a method of manufacturing the same.
- the present invention relates to an aluminum alloy conductor wire having excellent elongation in trade-off and excellent electrical conductivity, and a method of manufacturing the same, while having excellent mechanical strength such as tensile strength.
- Aluminum conductor wire is lighter and cheaper than copper conductor wire and copper alloy conductor wire, easy to cast, easy to alloy with other metals, easy to process at room temperature and silver, and corrosion resistance in air It is widely used for conductors such as overhead transmission lines, underground transmission lines, and building cables for reasons of excellent durability and the like.
- pure aluminum conductor wire has excellent properties such as elongation and electrical conductivity, but mechanical strength such as tensile strength is insufficient.
- cables used in severe vibration environments such as cables used in automobiles, aircrafts, and motor cylinders.
- the mechanical strength which determines the resistance to vibration needs to be improved.
- the cable industry can simultaneously replace the mechanical and electrical conductors such as tensile strength, elongation at the same time, and electrical conductivity to replace copper and copper alloy conductors with aluminum alloy conductors.
- An object of the present invention is to provide an aluminum alloy conductor wire which is excellent in mechanical strength such as tensile strength, elongation in conflict with this, and electrical conductivity, even when the diameter is small.
- An average distance between precipitates formed from the composition which is the average of the distances between the precipitates distributed within the unit radius (50), based on any precipitate, from 2 to 15 jwm, with an average diameter of from 0.15 to 0.5 kPa, Provides aluminum alloy conductor wires.
- the boron (B) and the: titanium (TO is an Al-Ti-B intermetallic compound
- An aluminum alloy conductor wire which is present, is provided.
- the precipitate provides : an aluminum alloy conductor wire, characterized in that it comprises an Al-Fe intermetallic compound, an Al-Cu intermetallic compound, and an Al-Ti-B metal galvanized compound.
- the aluminum alloy conductor electric wire characterized by having a grain average particle diameter of 50 or less is provided.
- An aluminum alloy conductor wire is provided, characterized in that the tensile strength is at least 140 MPa, the elongation is at least 15%, and the electrical conductivity is at least 59% IACS.
- the inevitable impurities may include: vanadium (V), chromium (Cr) and nickel (Ni), each of the inevitable impurities; the content is 0.01% by weight or less, and inevitable
- An aluminum alloy conductor wire is provided, characterized in that the total content of impurities is 0.01 weight or less.
- Aluminum alloy wire comprising the steps of: manufacturing an aluminum alloy wire by continuous casting rolling of the aluminum alloy composition, drawing the aluminum alloy wire, and subjecting the drawing process to heat treatment of an aluminum alloy wire. It provides a method of manufacturing.
- Al-Ti-B alloy further comprising the step of performing a degassing and foreign matter filtration of the aluminum alloy composition, it provides a method of manufacturing an aluminum alloy conductor wire.
- the temperature of the continuously cast rolling aluminum alloy composition is from 730 to
- a method for producing an aluminum alloy conductor wire characterized in that 900 ° C. Furthermore, the heat treatment is performed for 2 to 12 hours at 260 to 360 ° C., the grain size after the heat treatment is characterized in that 50 m or less, provides a method for producing an aluminum alloy conductor wire.
- the aluminum alloy conductor wire according to the present invention is selected from a specific alloy element and
- the manufacturing method of the aluminum alloy conductor wire according to the present invention does not require a separate grain refinement process, the manufacturing process is simple, and thus, the manufacturing cost is reduced, and the characteristics of the aluminum alloy conductor wire manufactured by precise process conditions and control are obtained. It shows the excellent effect which can be improved evenly.
- Figure 3 shows the distance between the precipitate in the SEM photograph of the aluminum alloy conductor wire of Example 1 according to the present invention and the SEM photograph of the aluminum alloy conductor wire of Comparative Example 5.
- the aluminum alloy composition for forming the aluminum alloy conductor wire according to the present invention contains aluminum (A1) as a main component, and additionally iron (Fe), copper (Cu), boron (B) and titanium (Ti) as alloy elements. It contains.
- the aluminum alloy conductor wire contains aluminum (A1) as a main component, and additionally iron (Fe), copper (Cu), boron (B) and titanium (Ti) as alloy elements. It contains.
- the content of iron (Fe) is the total weight of the aluminum alloy composition
- the iron (Fe) content is less than 0.3 wt%, the degree of improvement in the mechanical strength of the aluminum alloy conductor wire is insufficient, whereas when the content of the iron (Fe) is greater than 0.6 wt%, the Al-Fe intermetallic compound becomes coarse: Extrusion property may fall, and elongation, electrical conductivity, etc. of an aluminum alloy conductor wire may fall large.
- copper (Cu) is dissolved in aluminum (A1) to increase the corrosion potential of the aluminum alloy to improve the corrosion resistance of the aluminum alloy, and like Al (Cu) in the matrix (Ma) between the Al—Cu metal Heat treatment by being present as a compound Precipitation in the step to suppress the growth of grains to improve the mechanical strength, such as tensile strength.
- the content of copper (Cu) may be 0.3 to 0.5% by weight based on the total weight of the aluminum alloy herb.
- the copper (Cu) content is less than 0.3% by weight, the degree of improvement in mechanical strength of the aluminum alloy conductor wire is insufficient, whereas when the content of copper (Cu) is greater than 0.5% by weight, the intermetallic compound is coarse to reduce the extrudability of the aluminum alloy composition.
- Aluminum alloy conductor wire, elongation, electrical conductivity, etc. can be greatly reduced.
- Boron (B) as the alloying element promotes the precipitation of intermetallic compounds in the heat treatment step during the manufacturing process of the aluminum alloy conductor wire, thereby suppressing coarsening of crystal grains, thereby improving the strength of the aluminum alloy conductor wire, and lowering the electrical conductivity. It will act to suppress.
- the content of the boron (B) may be 0.001 to 0 0 ⁇ weight% based on the total weight of the aluminum alloy composition.
- the boron (B) content is less than 0.001% by weight, the degree of improvement in mechanical strength of the one: luminum alloy conductor wire is insufficient.
- the content of the boron (B) is greater than 0.01% by weight, an intermetallic compound is generated to generate an aluminum alloy conductor wire. The electrical conductivity of can be greatly reduced.
- titanium (Ti) has a melting point of 1,800 ° C., so that the melting point of iron (Fe), which is another alloying element, is 1540 ° C., and that of copper (Cu) is higher than 1084.5 ° C., so that Al-Ti-B Alloy rods are added in the form of, for example, and in the form of A1-TL in aluminum alloys :
- the precipitates at the average distance between the precipitates include not only Al-Ti intermetallic compounds, but also Al-Fe intermetallic compounds Al-Cu intermetallic compounds, and the like; average distances between precipitates reduced by addition of titanium (Ti); That is, the average of the distances between the precipitates distributed within the unit radius 50 based on any precipitate is preferably 2 It may be from 15 to 15 urn, more preferably from 2 to 5.5 / m, and thus the average distance between the precipitates is reduced, the precipitate can act as a barrier (barrier) to inhibit the growth of the grains.
- titanium (Ti) acts as a grain refining mechanism and the average distance between precipitates is reduced, the average grain size of the grains is controlled to about 50 m or less, preferably about 10 to 40 jams.
- aluminum alloys containing titanium (Ti) can be refined by Al-Ti intermetallic compounds as described above, so that heat treatment is performed at a higher temperature or for a longer time to improve the elongation of the aluminum alloy. Even though the tensile strength is lowered compared to titanium (aluminum alloy without TO, the titanium alloy is not added and titanium is not added.
- the ⁇ group titanium (Ti) and the content may be 0.01 to 0.03 weight 3 ⁇ 4 based on the total weight of the aluminum alloy composition.
- the content of titanium (Ti) is less than 0.01% by weight, it is difficult to exert grain refinement effect of the aluminum alloy conductor wire, whereas when it exceeds 0.03% by weight, a large amount of impurities are added to the aluminum alloy to make a coarse metal compound.
- the conductivity may be reduced. i:
- the aluminum alloy composition 3 ⁇ 4 is an impurity inevitably added in the manufacturing process in addition to aluminum (A1) as a main component and iron (Fe), copper (Cu), boron (B), and titanium (Ti) as an alloying element, for example, Vanadium (V), chromium (Cr), nickel (), and the like.
- the content of each of the unavoidable “pures” may be, for example, 0.01 wt% or less, and the total content of the unavoidable impurities may be, for example, 0.1 wt 3 ⁇ 4> or less.
- FIG. 1 is a flow chart of the aluminum alloy conductor wire and manufacturing process according to the present invention. As shown in Figure 1, of the aluminum alloy conductor wire according to the present invention
- the manufacturing method may include the following steps a) wedge e).
- the method of manufacturing an aluminum alloy conductor wire according to the present invention may further include: a) degassing and submaterial filtering of the aluminum alloy composition after step S110.
- the degassing and sub-material filtration step is a)
- step S110 and b) step S120 it is desirable to perform between step S110 and b) step S120.
- step S120 If the degassing and foreign matter filtration step after step S120 is carried out, the A1-Ti intermetallic compound may be degassed with the gas. : As described above, since the precipitates of the Al-Ti-B alloy added in step b) are uniformly distributed in the matrix, the distance between the precipitates that determine the grain size is reduced, and as a result, the grain refinement is achieved. Mechanical strength such as tensile strength of the aluminum alloy can be improved.
- the method of manufacturing the aluminum alloy conductor wire according to the present invention does not require a separate grain refinement process, thereby simplifying the manufacturing process and thus reducing the manufacturing cost.
- step (S130) The temperature of the aluminum alloy composition applied to the continuous casting rolling is preferably 730 to 900 ° C. remind
- the aluminum alloy wire produced in step (S130) is most preferably cast in a size of about 10 ⁇ diameter so that it can be usefully applied to automotive cables, according to the use of the aluminum alloy conductor wire according to the present invention After the casting, the diameter of the aluminum alloy wire can be appropriately selected by a person skilled in the art.
- step S140 the cast aluminum alloy wire is processed to reduce the cross section to produce an alloy wire of a predetermined specification.
- step d) (S140) is a process for drawing a wire drawn from the aluminum alloy wire manufactured in step c) (S130) with an average diameter of about 2 ram, and again the average diameter of about 0.15 to 0.5 mm A thin wire process may be included as a wire rod.
- the aluminum alloy wire drawn in step S140 is heat-treated by the thermomembrane process of step S150 in solid or stranded wire. In the aluminum alloy wire, the elongation is improved through recovery by the stress relief after the internal stress of the alloy is increased by the heat treatment.
- the toughness may be largely damaged by coarsening of grains. Therefore, it is most efficient to stop the heat treatment when the elongation of the aluminum alloy wire is improved to the maximum by the heat treatment and the tensile strength is not largely damaged, that is, when the average grain size of the crystal grains is maintained at about 50 or less.
- the average distance of the precipitate is 2 to 15 ⁇ , that is, the process conditions that the elongation can be improved as much as possible while maintaining the average particle diameter of 50 or less as the heat treatment temperature is about 260 to 360 ° C.
- heat treatment time may be about 2 to 12 hours.
- the lower the heat treatment temperature increases the heat treatment time, while the higher heat treatment temperature shortens the heat treatment time, thereby minimizing the extent to which the tensile strength decreases by heat treatment. The rate of improvement can be maximized.
- an aluminum alloy wire including an alloy component and the remainder of aluminum (A1) and unavoidable impurities was prepared, followed by a drawing process and a heat treatment process (310 ° C., & hr) to perform an example: And wire specimens according to each of the comparative examples were prepared.
- the content and units of the alloying components shown in Table 1 below are by weight.
- the electrical conductivity of each of the aluminum alloy wire specimens according to the Examples or Comparative Examples was calculated by measuring the electrical resistance by the Calvin Double Bridge method according to the ASTM B193 standard.
- the average distance between precipitates is reduced by the optimal combination of alloying elements, the minimum content of alloying elements and the optimal blending ratio, thereby achieving finer grain size, and improving elongation to 15% or more due to heat treatment. Nevertheless, it was confirmed that the tensile strength could be maintained at 140 MPa or more by minimizing the decrease in tensile strength, and furthermore, by minimizing the content of alloying elements.
- the specimens of Comparative Examples 2 and 4 exhibited extremely high amounts of alloying elements of iron (Fe) or copper (Cu), so that the electrical conductivity of aluminum alloys was lower than 59 ACS. It was confirmed that the lowered.
- the specimen of Comparative Example 5 is not added to the titanium (Ti) and boron (B) for grain refinement, although the alloying elements of iron (Fe) and copper (Cu) to improve the tensile strength of the aluminum alloy is added in an appropriate amount As a result, the distance between the precipitates increased, thereby coarsening the crystallized grains, and as a result, it was confirmed that the tensile strength greatly decreased during the heat treatment to improve the elongation.
- FIGS. 2 and 3 are scanning electron microscope (SEM) comparison photographs showing the distance between precipitates and the degree of grain refinement according to the addition of titanium (Ti) in Examples 1 and 5.
- the aluminum alloy conductor wire according to the present invention reduces the distance between the precipitates that determine the size of the grains by the addition of titanium (Ti), thereby causing the grains to be refined.
- Ti titanium
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Abstract
Description
【명세서】 【Specification】
【발명의 명칭】 [Name of invention]
알루미늄 합금 도체 전선 및 이의 제조방법 【기술분야】 Aluminum Alloy Conductor Wire and Manufacturing Method Thereof
본 발명은 알루미늄 합금 도체 전선 및 이의 제조방법에 관한 것이다. The present invention relates to an aluminum alloy conductor wire and a method of manufacturing the same.
구체적으로, 본 발명은 인장강도 등의 기계적 강도가우수한동시에, 상기 강도와 상충관계 (trade—off )에 있는 신율이 우수하며, 또한 전기전도도가 우수한 알루미늄 합금 도체 전선 및 이의 제조방법에 관한 것이다. Specifically, the present invention relates to an aluminum alloy conductor wire having excellent elongation in trade-off and excellent electrical conductivity, and a method of manufacturing the same, while having excellent mechanical strength such as tensile strength.
【배경기술】 Background Art
알루미늄 도체 전선은동 (copper) 도체 전선 및 동 합금 도체 전선에 비해 경량이면서 가격이 저렴하다는 점 , 주조성이 용이하고 다른 금속과의 합금이 용이한 점, 상온 및 고은 가공이 용이하고 대기 중에서 내식성과 내구성이 우수한 점 등의 이유로, 가공송전선, 지중송전선, 빌딩용 케이블 등의 도체로 널리 사용되고 있다. Aluminum conductor wire is lighter and cheaper than copper conductor wire and copper alloy conductor wire, easy to cast, easy to alloy with other metals, easy to process at room temperature and silver, and corrosion resistance in air It is widely used for conductors such as overhead transmission lines, underground transmission lines, and building cables for reasons of excellent durability and the like.
다만, 순수한 알루미늄 도체 전선은 신율, 전기전도도 등의 특성은 우수한 반면 인장강도등 기계적 강도는 불충분한문제가 있고, 특히 자동차, 항공기, 원동기 둥에 사용되는 케이블 같이 진동이 심한 환경에서 사용되는 케이블의 도체로 사용되는 경우, 진동에 대한 내성을 결정하는 기계적 강도가 향상될 필요가 있다. However, pure aluminum conductor wire has excellent properties such as elongation and electrical conductivity, but mechanical strength such as tensile strength is insufficient. Especially, cables used in severe vibration environments such as cables used in automobiles, aircrafts, and motor cylinders. When used as a conductor, the mechanical strength which determines the resistance to vibration needs to be improved.
따라서, 종래에는 알루미늄 (A1 )과 철 (Fe) , 구리 (Cu) , 마그네슘 (Mg) , Therefore, aluminum (A1), iron (Fe), copper (Cu), magnesium (Mg),
지르코늄 (Zr) , 베릴륨 (Be) 등의 합금원소와의 합금을통해 알루미늄 합금 도체 전선의 기계적 강도를 향상시키는 기술이 공지되어 있다. Techniques for improving the mechanical strength of aluminum alloy conductor wires through alloys with alloying elements such as zirconium (Zr) and beryllium (Be) are known.
그러나, 종래 알루미늄 합금 도체 전선은 목적한 기계적 강도를 달성하기 위해 과량의 합금원소를 첨가해야하므로 상기 기계적 강도와 상충관계에 있는 신율 그리고, 전기전도도 등이 크게 저하되거나, 제조를 위해 높은 열처리 은도가 요구되거나 장시간의 열처리가요구되는 등의 문제가 있으며, 나아가 환경규제 However, in the conventional aluminum alloy conductor wires, an excessive amount of alloying elements must be added to achieve the desired mechanical strength, so the elongation and the electrical conductivity, which are in conflict with the mechanical strength, are greatly reduced, There is a problem such as required or long time heat treatment, and furthermore, environmental regulation
대체용지 (규칙 제 26조) 물질인 베릴륨 (Be)의 첨가로 인해 환경문제가유발되고 생산단가가증가하는 문제가 있었다. Alternative Site (Article 26) Due to the addition of beryllium (Be), there was a problem of causing environmental problems and increasing production costs.
또한, 알루미늄 합금 도체 전선의 신율, 전기전도도 등이 크게 저하되는 것을 회피하기 위해 합금원소를 소량 첨가하는 경우 알루미늄 합금 도체 전선의 기계적 강도의 향상이 불층분하거나, 상기 알루미늄 합금 도체 전선의 기계적 강도의 향상을 위해 추가로 결정립 미세화 공정이 필요한 등 제조공정이 복잡해지는 문제가 있다. In addition, when a small amount of alloying element is added in order to avoid a large decrease in elongation, electrical conductivity, etc. of the aluminum alloy conductor wire, the improvement of mechanical strength of the aluminum alloy conductor wire is uneven, or the mechanical strength of the aluminum alloy conductor wire There is a problem in that the manufacturing process is complicated, such as an additional grain refinement process is required to improve.
이러한 상황에서, 현재 케이블 업계에서는 동 도체 전선 및 동 합금 도체 전선을 알루미늄 합금 도체 전선으로 대체할 수 있도록 인장강도 등의 기계적 강도 및 이와상충관계에 있는 신율, 그리고 전기전도도 등을 동시에 In this situation, the cable industry can simultaneously replace the mechanical and electrical conductors such as tensile strength, elongation at the same time, and electrical conductivity to replace copper and copper alloy conductors with aluminum alloy conductors.
향상시키기 위한 연구가 활발히 진행되고는 있으나, 알루미늄 합금 도체 전선에 대한 최적의 합금원소의 조합과 공정조건이 정립되어 있지 않고, 특히 알루미늄 합금 도체 전선의 소선경이 작아질수록 인장강도가 증가하지만 신율 및 전기전도도는 감소하는 경향이 있기 때문에 직경이 0. 15 내지 0.5画인 세선 도체 전선의 경우 최적의 합금원소의 조합을 찾아내는 것이 극히 곤란하여 기술적 진보에 많은 어려움을 겪고 있다. Although researches to improve are being actively conducted, the optimal combination of alloying elements and process conditions for aluminum alloy conductor wires is not established. In particular, as the wire diameter of aluminum alloy conductor wires decreases, tensile strength increases, but elongation is increased. And since the electric conductivity tends to decrease, it is extremely difficult to find the optimal combination of alloying elements in the case of a thin wire conductor wire having a diameter of 0.1 to 0.5 画, and thus suffers a lot of technical progress.
【발명의 상세한 설명】 [Detailed Description of the Invention]
【기술적 과제】 [Technical problem]
본 발명은 알루미늄 합금 도체 전선으로서, 직경이 작은 경우에도 인장강도 등의 기계적 강도 및 이와 상충관계에 있는 신율, 그리고 전기전도도 등이 동시에 우수한 알루미늄 합금 도체 전선을 제공하는 것을 목적으로 한다. SUMMARY OF THE INVENTION An object of the present invention is to provide an aluminum alloy conductor wire which is excellent in mechanical strength such as tensile strength, elongation in conflict with this, and electrical conductivity, even when the diameter is small.
또한, 본 발명은 친환경작이고 생산원가가 절감될 수 있는 알루미늄 합금 도체 전선을 제공하는 것을 목 으로 한다. In addition, it is an object of the present invention to provide an aluminum alloy conductor wire that is environmentally friendly and can reduce the production cost.
나아가, 본 발명은 제조공정이 간단학고 따라서 제조비용이 절감되며 상기 알루미늄 합금 도체 전선의 제조방법을 제공하는 것을 또 다른 목적으로 한다. 【기술적 해결방법】 Furthermore, another object of the present invention is to provide a method for manufacturing the aluminum alloy conductor wire, which is simplified in the manufacturing process and thus the manufacturing cost is reduced. Technical Solution
상기 과제를 해결하가 위해, 본 발명은, 철 (Fe) 0.3내지 0.6중량 %, 구리 (Cu) 0.3내지 0.5중량 %, 붕소 (B) 0.001 내지 0.01중량 %및 티타늄 (Ti ) 0.01 내지 0.03중량 %를포함하고, 나머지 잔량부가 알루미늄 (A1 ) 및불가피한불순물로 이루어진 알루미늄 합금 In order to solve the above problems, the present invention, 0.3 to 0.6% by weight of iron (Fe), 0.3 to 0.5% by weight of copper (Cu), 0.001 to 0.01% by weight of boron (B) and 0.01 to 0.03% by weight of titanium (Ti), with the remainder being aluminum (A1) And aluminum alloys consisting of inevitable impurities
조성물로부터 형성되고, 임의의 석출물을 기준으로 단위 반경 (50 ) 내에 분포되어 있는석출물들간의 거리의 평균인 석출물간평균거리가 2내지 15 jwm이며 , 평균직경이 0. 15내지 : 0.5瞧인, 알루미늄 합금도체 전선을 제공한다. 여기서, 상기 붕소 (B) 및 상기 :티타늄 (TO은 Al-Ti -B금속간화합물로 An average distance between precipitates formed from the composition, which is the average of the distances between the precipitates distributed within the unit radius (50), based on any precipitate, from 2 to 15 jwm, with an average diameter of from 0.15 to 0.5 kPa, Provides aluminum alloy conductor wires. Here, the boron (B) and the: titanium (TO is an Al-Ti-B intermetallic compound
존재하는 것을 특징으로 하는, 알루이늄 합금 도체 전선을 제공한다. An aluminum alloy conductor wire, which is present, is provided.
또한, 상기 석출물은 Al-Fe금속간화합물, Al-Cu금속간화합물 및 Al-Ti -B 금속갔화합물을포함하는 것을특징으로 하는, :알루미늄 합금도체 전선을 제공한다. Further, the precipitate provides : an aluminum alloy conductor wire, characterized in that it comprises an Al-Fe intermetallic compound, an Al-Cu intermetallic compound, and an Al-Ti-B metal galvanized compound.
한편,;결정립 평균입경이 50 :이하인 것을특징으로 하는, 알루미늄 합금 도체 전선을 제공한다. On the other hand, the aluminum alloy conductor electric wire characterized by having a grain average particle diameter of 50 or less is provided.
그리고, 인장강도가 140 MPa 이상, 신율이 15% 이상, 전기전도도가 59%IACS 이상인 것을특징으로 하는, 알루미늄 합금 도체 전선을 제공한다. An aluminum alloy conductor wire is provided, characterized in that the tensile strength is at least 140 MPa, the elongation is at least 15%, and the electrical conductivity is at least 59% IACS.
또한, 상기 불가피한불순물은:바나듐 (V) , 크롬 (Cr ) 및 니켈 (Ni )을포함할수 있고, 불가피한불순물 각각의 ;함량은 0.01 중량 %이하이고, 불가피한 In addition, the inevitable impurities may include: vanadium (V), chromium (Cr) and nickel (Ni), each of the inevitable impurities; the content is 0.01% by weight or less, and inevitable
불순물의 총 함량은 0. 1중량 이하인 것을특징으로 하는, 알루미늄 합금 도체 전선을 제공한다. An aluminum alloy conductor wire is provided, characterized in that the total content of impurities is 0.01 weight or less.
한편, 철 (Fe) 및 구리 (Cu)를 포함하고, 나머지 잔량부가 알루미늄 및 불가피한 불순물로 이루어진 알루미늄 합금 조성물을 제조하는 단계, 상기 알루미늄 합금조성물의 주조 직전에 Al-Ti -B합금을 첨가하는 단계, 상기 알루미늄 합금조성물의 연속주조압연에 의해 알루미늄 합금선재를 제조하는 단계, 상기 알루미늄 합금 선재를신선하는단계, 및 상기 신선 공정을 거친 : 알루미늄합금 선재를 열처리하는 단계를포함하는, 알루미늄 합금도체 전선의 제조방법을 제공한다. 여기서, 상기 Al-Ti-B 합금을 첨가하기 전에 상기 알루미늄 합금 조성물의 탈가스화 및 이물질 여과를 수행하는 단계를 추가로 포함하는 것을 특징으로 하는, 알루미늄 합금 도체 전선의 제조방법을 제공한다. : On the other hand, manufacturing an aluminum alloy composition containing iron (Fe) and copper (Cu), the remainder is made of aluminum and unavoidable impurities, adding Al-Ti -B alloy immediately before the casting of the aluminum alloy composition , Aluminum alloy wire comprising the steps of: manufacturing an aluminum alloy wire by continuous casting rolling of the aluminum alloy composition, drawing the aluminum alloy wire, and subjecting the drawing process to heat treatment of an aluminum alloy wire. It provides a method of manufacturing. Here, before the addition of the Al-Ti-B alloy, further comprising the step of performing a degassing and foreign matter filtration of the aluminum alloy composition, it provides a method of manufacturing an aluminum alloy conductor wire. :
또한, 상기 연속주조압연되는 알루미늄 합금 조성물의 온도는 730 내지 In addition, the temperature of the continuously cast rolling aluminum alloy composition is from 730 to
900°C인 것을 특징으로 하는, 알루미늄 합금 도체 전선의 제조방법을 제공한다. 나아가, 상기 열처리는 260 내지 360°C에서 2 내지 12 시간 동안수행되고, 열처리 후의 결정립 평균입경이 50 m 이하인 것을 특징으로 하는, 알루미늄 합금 도체 전선의 제조방법을 제공한다. Provided is a method for producing an aluminum alloy conductor wire, characterized in that 900 ° C. Furthermore, the heat treatment is performed for 2 to 12 hours at 260 to 360 ° C., the grain size after the heat treatment is characterized in that 50 m or less, provides a method for producing an aluminum alloy conductor wire.
【유리한 효과] : [Effective Effect] :
본 발명에 따른 알루미늄 합금 도체 전선은 특정한 합금원소의 선택 및 The aluminum alloy conductor wire according to the present invention is selected from a specific alloy element and
배합비의 정밀한 제어를 통해 직경이 작은 경우에도 알루미늄 합금 도체 전선의 기계적 강도 및 이와 상충관계에 있는 신율, 그리고 전기전도도 등을 동시에 향상시킬 수 있는 우수한 효과를 나타낸다. Through precise control of the mixing ratio, even when the diameter is small, the mechanical strength of the aluminum alloy conductor wire, the elongation in conflict with the electrical conductivity, and the like can be simultaneously improved.
본 발명에 따른 알루미늄 합금 도체 전선은 환경문제를 유발하는 합금원소를 사용하지 않으므로 찬환경적인 동시에 합금원소를 과량으로 포함하지 않으므로 생산원가가 :절감될 수 있는 우^한 효과를 나타낸다 Does not contain an aluminum alloy conductor wires alloying elements it does not at the same time of cold environment using an alloying element that causes an environmental problem according to the invention in an amount in excess production costs: shows a right ^ effect, which may be reduced
본 발명에 따른 알루미늄 합금 도체 전선의 제조방법은 별도의 결정립 미세화 공정이 불필요하므로 제조공정이 단순하고, 따라서 제조비용이 절감되는 동시에, 정밀한 공정조건와 제어를 통해 제조돠는 알루미늄 합금 도체 전선의 특성을 균등하게 향상시킬 수 있는 우수한 효과를 나타낸다. Since the manufacturing method of the aluminum alloy conductor wire according to the present invention does not require a separate grain refinement process, the manufacturing process is simple, and thus, the manufacturing cost is reduced, and the characteristics of the aluminum alloy conductor wire manufactured by precise process conditions and control are obtained. It shows the excellent effect which can be improved evenly.
【도면의 간단한 설명】 [Brief Description of Drawings]
도 1은 본 발명에 따른 알루미늄 합금 도체 전선의 제조공정의 흐름도이다. 도 2는 본 발명에 따른 실시예 1의 알루미늄 합금 도체 전선의 SEM사진과 비교예 5의 알루미늄 합금 도체:전선의 SEM사진을 도시한 것이다. 1 is a flowchart of a manufacturing process of an aluminum alloy conductor wire according to the present invention. Figure 2 shows a SEM photograph of the aluminum alloy conductor wire of Example 1 and the aluminum alloy conductor of Comparative Example 5 : SEM picture of the wire according to the present invention.
도 3은 본 발명에 따른 실시예 1의 알루미늄 합금 도체 전선의 SEM사진과 비교예 5의 알루미늄 합금 도체 전선의 SEM사진에서 석출물간 거리를 표시한 것이다. 【발명의 실시를 위한 형태】 Figure 3 shows the distance between the precipitate in the SEM photograph of the aluminum alloy conductor wire of Example 1 according to the present invention and the SEM photograph of the aluminum alloy conductor wire of Comparative Example 5. [Form for implementation of invention]
28이하, 본 발명의 바람직한 실시예들을 상세히 설명하기로 한다. 그러나, 본 발명은 여기서 설명된 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 오히려, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록, 그리고 당업자에게 본 발명의 사상이 층분히 전달될 수 있도록 하기 위해 제공되어지는 것이다. Hereinafter, preferred embodiments of the present invention will be described in detail. However, the invention is not limited to the embodiments described herein but may be embodied in other forms. Rather, the embodiments introduced herein are provided so that the disclosure may be made thorough and complete, and the spirit of the present invention may be fully conveyed to those skilled in the art.
본 발명에 따른 알루미늄 합금 도체 전선을 형성하는 알루미늄 합금 조성물은 알루미늄 (A1 )을 주성분으로 함유하고, 합금원소로서 철 (Fe) , 구리 (Cu) , 붕소 (B) 및 티타늄 (Ti )을 추가로 함유한다. 상기 알투미늄 합금 도체 전선은 The aluminum alloy composition for forming the aluminum alloy conductor wire according to the present invention contains aluminum (A1) as a main component, and additionally iron (Fe), copper (Cu), boron (B) and titanium (Ti) as alloy elements. It contains. The aluminum alloy conductor wire
평균직경이 0.15 내지 0.5 mm안세선이고, 이러한세선인 알루미늄 합금 도체 전선은 인장강도 등의 기계적 강도 및 이와 상충관계에 있는 신율, 그리고 전기전도도 등을 동시에 향상시키는 것이 극히: 곤란함에도 불구하고, 아래 기술하는 합금원소와 최적의 배합비와 결정립을 형성하는 석출물간 거리제어에 의한 결정립 미세화를 통해 이를 달성할 수 있다. 상기 합금원소로서 철 (Fe)은 기지 (Matrix) 내에서 AI-Fe 금속간 화합물로 존재한다. 특히 , 상기 Al-Fe 금속간 화합물은 상기 알루미늄 합금 도체 전선의 제조공정 중 열처리 단계에서 대부분:석출되어 결정립의 성장을 억제함으로써 인장강도 등 기계적 강도를 향상시키는 작용을 하게 된다. And an average diameter of 0.15 to 0.5 mm Anse ray, such thin wires of aluminum alloy conductor wires is extremely improving the elongation, and electric conductivity and so on in the mechanical strength, this trade-off, such as tensile strength at the same time: Although difficult, under This can be achieved through grain refinement by controlling the distance between the alloying elements described and the optimum mixing ratio and the precipitates forming the grains. Iron (Fe) as the alloying element is present as an AI-Fe intermetallic compound in the matrix. In particular, the Al-Fe intermetallic compound is most precipitated during the heat treatment step of the aluminum alloy conductor wire manufacturing process to inhibit the growth of the crystal grains to improve the mechanical strength, such as tensile strength.
여기서, 상기 철 (Fe)의 함량은 상기 알루미늄 합금 조성물의 총 중량을 Here, the content of iron (Fe) is the total weight of the aluminum alloy composition
기준으로 0.3 내지 0.6 중량 %일 수 있다. 상기 철 (Fe)의 함량이 0.3 중량 % 미만인 경우 상기 알루미늄 합금 도체 전선의 기계적 강도가 향상되는 정도가 불충분한 반면, 0.6 중량 %초과인 경우 Al-Fe 금속간 화합물이 조대해져 : 알루미늄 합금 조성물의 압출성이 저하되고, 알루미늄 합금 도체 전선의 신율, 전기전도도 등이 크게 저하될 수 있다. It may be 0.3 to 0.6% by weight on the basis. When the iron (Fe) content is less than 0.3 wt%, the degree of improvement in the mechanical strength of the aluminum alloy conductor wire is insufficient, whereas when the content of the iron (Fe) is greater than 0.6 wt%, the Al-Fe intermetallic compound becomes coarse: Extrusion property may fall, and elongation, electrical conductivity, etc. of an aluminum alloy conductor wire may fall large.
또한, 상기 합금원소로서 구리 (Cu)는 알루미늄 (A1 )에 고용되어 알루미늄 합금의 부식전위를 높여 알루미늄 합금의 내식성을 향상시키고, 철 (Fe)과 마찬가지로 기지 (Matrix) 내에서 Al— Cu금속간 화합물로 존재하여 열처리 단계에서 석출되어 결정립의 성장을 억제함으로써 인장강도 등 기계적 강도를 향상시키는 작용을 하게 된다. In addition, as the alloying element, copper (Cu) is dissolved in aluminum (A1) to increase the corrosion potential of the aluminum alloy to improve the corrosion resistance of the aluminum alloy, and like Al (Cu) in the matrix (Ma) between the Al—Cu metal Heat treatment by being present as a compound Precipitation in the step to suppress the growth of grains to improve the mechanical strength, such as tensile strength.
여기서 , 상기 구리 (Cu)의 함량은 상기 알루미늄 합금 초성물의 총 중량을 기준으로 0.3 내지 0.5 중량 %일 수 있다. 상기 구리 (Cu)의 함량이 0.3 중량 % 미만인 경우 상기 알루미늄 합금 도체 전선의 기계적 강도가 향상되는 정도가 불충분한 반면 0.5 중량 %초과인 경우 금속간 화합물이 조대해져 알루미늄 합금 조성물의 압출성이 저하되고, 알루미늄 합금 도체 전선와신율, 전기전도도 등이 크게 저하될 수 있다. Here, the content of copper (Cu) may be 0.3 to 0.5% by weight based on the total weight of the aluminum alloy herb. When the copper (Cu) content is less than 0.3% by weight, the degree of improvement in mechanical strength of the aluminum alloy conductor wire is insufficient, whereas when the content of copper (Cu) is greater than 0.5% by weight, the intermetallic compound is coarse to reduce the extrudability of the aluminum alloy composition. Aluminum alloy conductor wire, elongation, electrical conductivity, etc. can be greatly reduced.
상기 합금원소로서 붕소 (B)는 알루미늄 합금 도체 전선의 제조공정 중 열처리 단계에서 금속간 화합물의 석출을 촉진시켜 결정립의 조대화를 억제함으로써 상기 알루미늄 합금 도체 전선의 강도를 향상시키며, 전기전도도의 저하를 억제하는 작용을 하게 된다. Boron (B) as the alloying element promotes the precipitation of intermetallic compounds in the heat treatment step during the manufacturing process of the aluminum alloy conductor wire, thereby suppressing coarsening of crystal grains, thereby improving the strength of the aluminum alloy conductor wire, and lowering the electrical conductivity. It will act to suppress.
여기서, 상기 붕소 (B)의 함량은 상기 알루미늄 합금 조성물의 총 중량을 기준으호 0.001 내지 0 0Γ중량 %일 수 있다. 상기 붕소 (B)의 함량이 0.001 중량 % 미만인 경우 상기 일:루미늄 합금 도체 전선의 기계적 강도가 향상되는 정도가 불^분한:반면, 0.01 중량 %초과인 경우 금속간 화합물을 생성시켜 알루미늄 합금 도체 전선의 전기전도도가 크게 저하될 수 있다. Here, the content of the boron (B) may be 0.001 to 0 0Γ weight% based on the total weight of the aluminum alloy composition. When the boron (B) content is less than 0.001% by weight, the degree of improvement in mechanical strength of the one: luminum alloy conductor wire is insufficient. On the other hand, when the content of the boron (B) is greater than 0.01% by weight, an intermetallic compound is generated to generate an aluminum alloy conductor wire. The electrical conductivity of can be greatly reduced.
상기 합금원소로서 티타늄 (Ti )은 융점이 1 ,800°C로 다른 합금원소인 철 (Fe)의 융점 1540°C , 구리 (Cu)의 융점: 1084.5°C에 비해 높기 때문에 Al-Ti-B 합금 로드 (rod) 등의 형태로 첨가되고, 알루미늄 합금 내에서 A1-TL 형태의 : As the alloying element, titanium (Ti) has a melting point of 1,800 ° C., so that the melting point of iron (Fe), which is another alloying element, is 1540 ° C., and that of copper (Cu) is higher than 1084.5 ° C., so that Al-Ti-B Alloy rods are added in the form of, for example, and in the form of A1-TL in aluminum alloys :
석출물로 균일하게 존재함으로^, 알루미늄 합금의 결정립의 크기를 결정하는 석출불간 평균 거리를 추가로 감축시키고, 결과적으로 결정립의 미세화에 의해 상기 알루미늄 합금도체 전선의 강도를 추가로 향상시키는 작용을 하게 된다. 상기 석출물간 평균 거리에서의 석출물은 Al-Ti 금속간 화합물뿐만 아니라, Al-Fe 금속간 화합물 Al-Cu금속간 화합물 등을 포함하고, 티타늄 (Ti )의 첨가에 의해 감축되는 석출물간 평균거리, 즉, 임의의 석출물을 기준으로 단위 반경 (50 ) 내에 분포되어 있는 석출물들간의 거리의 평균은 바람직하게는 2 내지 15 urn, 더욱 바람직하게는 2 내지 5.5 /m일 수 있으며, 이와 같이 석출물간 평균거리가 감소됨으로써 석출물이 장벽 (barrier) 역할을 하여 결정립의 성장을 억제할 수 있다. 즉, 티타늄 (Ti )이 결정립 미세화 기구로 작용하여 석출물간 평균거리가:감축되므로 결정립의 평균입경은 약 50 m 이하, 바람직하게는, 약 10 내자 40 jam로 제어될 수 있는 우수한 효과가 나타난다. 또한ᅳ 티타늄 (Ti )이 첨가된 알루미늄 합금은 앞서 기술한 바와 같은 Al-Ti 금속간 화합물에 의한 결정립의 미세화가 가능하므로, 알루미늄 합금의 신율을 향상시키기 위해 더욱 높은 온도에서 또는 더욱 장시간 열처리를 수행하는 경우에도 인장강도가 저하되는 정도가 티타늄 (TO이 첨가되지 않은 알루미늄 합금에 비해 매우 낮기 때문에, 티타늄 (Ti )이 첨가되지 않고 동일한 By being uniformly present as a precipitate, it further reduces the average distance between precipitations, which determines the size of the grains of the aluminum alloy, and consequently, further enhances the strength of the aluminum alloy conductor wire by miniaturization of the grains. . The precipitates at the average distance between the precipitates include not only Al-Ti intermetallic compounds, but also Al-Fe intermetallic compounds Al-Cu intermetallic compounds, and the like; average distances between precipitates reduced by addition of titanium (Ti); That is, the average of the distances between the precipitates distributed within the unit radius 50 based on any precipitate is preferably 2 It may be from 15 to 15 urn, more preferably from 2 to 5.5 / m, and thus the average distance between the precipitates is reduced, the precipitate can act as a barrier (barrier) to inhibit the growth of the grains. That is, since titanium (Ti) acts as a grain refining mechanism and the average distance between precipitates is reduced, the average grain size of the grains is controlled to about 50 m or less, preferably about 10 to 40 jams. In addition, aluminum alloys containing titanium (Ti) can be refined by Al-Ti intermetallic compounds as described above, so that heat treatment is performed at a higher temperature or for a longer time to improve the elongation of the aluminum alloy. Even though the tensile strength is lowered compared to titanium (aluminum alloy without TO, the titanium alloy is not added and titanium is not added.
인장강도를 나타내는 알루미늄 합금의 신율에 비해 크게 향상된 신율을 나타낼 수 있다. Compared to the elongation of the aluminum alloy exhibiting tensile strength it can exhibit a significantly improved elongation.
여기서, ^기 티타늄 (Ti )와 함량은 상기 알루미늄 합금 조성물의 총;중량을 기준으로 0.01 내지 0.03 중량 ¾일 수 있다. 상기 티타늄 (Ti )의 함량이 0.01 중량 %미만인 경우 상기 알루미늄 합금 도체 전선의 결정립 미세화 효과가 발휘되기 어려운 반면, 0.03 중량 %초과인 경우 알루미늄 합금에 다량의 불순물이 첨가되어 조대한 금슉간 화합물을 만들어 상기 :알루미늄 합금 Here, the ^ group titanium (Ti) and the content may be 0.01 to 0.03 weight ¾ based on the total weight of the aluminum alloy composition. When the content of titanium (Ti) is less than 0.01% by weight, it is difficult to exert grain refinement effect of the aluminum alloy conductor wire, whereas when it exceeds 0.03% by weight, a large amount of impurities are added to the aluminum alloy to make a coarse metal compound. Above: Aluminum alloy
조성물의 압출성 및 상기 알루미늄 합금 도체 전선의 인장강도 및 Extrudability of the composition and tensile strength of the aluminum alloy conductor wire and
전기전도도가 저하 ¾수 있다. i : The conductivity may be reduced. i:
상기 알루미늄 합금 조성 ¾은 주성분으로서 알루미늄 (A1 )과 합금원소로서 철 (Fe) , 구리 (Cu) , 붕소 (B) 및 티타늄 (Ti ) 이외에 제조공정에서 불가피하게 첨가되는 불순물로서, 예를 들어, 바나듐 (V) , 크롬 (Cr) , 니¾( ) 등을 포함할 수 있다. 상기 불가피한 :순물 각각의 함량은 예를;들어 0.01 중량 % 이하일 수 있고, 상기 불가피한 불순물의 총 함량은 예를 들어 0.1 중량 ¾> 이하일 수 있다. : The aluminum alloy composition ¾ is an impurity inevitably added in the manufacturing process in addition to aluminum (A1) as a main component and iron (Fe), copper (Cu), boron (B), and titanium (Ti) as an alloying element, for example, Vanadium (V), chromium (Cr), nickel (), and the like. The content of each of the unavoidable “pures” may be, for example, 0.01 wt% or less, and the total content of the unavoidable impurities may be, for example, 0.1 wt ¾> or less. :
상기 알루미늄 합금조성물로부터 제조된 알루미늄 합금 도체 전선은 The aluminum alloy conductor wire manufactured from the aluminum alloy composition
합금원소로서 첨가되는 철 (Fe) , 구리 (Cu) 및 티타늄 (Ti )으로부터의 미세한 석출물의 균일한 분포, 즉 석출물간 거리의 감축에 의한 결정립 미세화와 붕소 (B)에 의한 Al-Fe, Al-Cu등의 금속간 화합물의 석출 촉진에 의한 Fine from iron (Fe), copper (Cu) and titanium (Ti) added as alloying elements Uniform distribution of precipitates, that is, due to the reduction of the distance between precipitates and the promotion of precipitation of intermetallic compounds such as Al-Fe and Al-Cu by boron (B)
추가적인 결정립 미세화를 통해 140 MPa 이상와인장강도를 나타내고, 상기 결정립 미세화를 통해, 인장강도의 저하를 최소화하면서 고온에서 장시간 열처리가 가능하기 때문에 신율이 15% 이상 및 전기전도도가 59 ACS 이상으로 동시에 향상될 수 있는 탁월한 효과를 달성할 수 있다. It exhibits a tensile strength of 140 MPa or more through additional grain refinement, and the elongation is improved more than 15% and electrical conductivity to 59 ACS or more because the grain refinement enables long-term heat treatment at high temperature while minimizing the decrease in tensile strength. Excellent effect can be achieved.
도 1은 본 발명에 따른 알루미늄 합금 도체 전선와제조공정의 흐름도이다. 도 1에 도시된 바와 같이, 본 발명에 따른알루미늄 합금 도체 전선의 1 is a flow chart of the aluminum alloy conductor wire and manufacturing process according to the present invention. As shown in Figure 1, of the aluminum alloy conductor wire according to the present invention
제조방법은 아래 a) ᅫ지 e) 단계를 포함할 수 있다. The manufacturing method may include the following steps a) wedge e).
a) 철 (Fe) 0.3 내지 0.6 중량 % 및 구리 (Cu) 0.3 내지 0.5 중량 %를 포함하고, 나머지 잔량부가 알루미늄 및 불가피한 불순물로 이루어진 알루미늄 합금 조성물 (용탕)을 제조하는 단계 (S110) ; a) preparing an aluminum alloy composition (molten metal) containing 0.3 to 0.6% by weight of iron (Fe) and 0.3 to 0.5% by weight of copper (Cu), and the remaining balance consisting of aluminum and inevitable impurities (S110);
b) 상가 알루미늄 ¾금 조성물의 주조 직전에 Al-m-B 합금을 첨가하여 붕소 (B) 0.001 내지 0.01 중량 % 및 티타 (Ti ) 0.01 내지 0.03 중량 %를 추가로 b) 0.001 to 0.01% by weight of boron (B) and 0.01 to 0.03% by weight of titan (Ti) by adding Al-m-B alloy immediately before casting of the additive aluminum ¾ gold composition
포함하는 알루미늄 합금 조성물을 제조하는 단계 (S120) ; Preparing an aluminum alloy composition comprising a step (S120);
c) 상기 알루미늄 합금 조성물의 연속주조압연에 의해 알루미늄 합금 선재를 제조하는 단계 (S130):; c) step (S130) for producing the aluminum alloy wire by the continuous casting and rolling of the aluminum alloy composition:;
d) 상기 알루미늄 합금 선재를:신선하는 단계 (S140) ; 및 : d) drawing the aluminum alloy wire: drawing (S140); And:
e) 상기 신선 공정을거친 알루미늄 합금 선재를 260 내지 360°C의 e) to 260 to 360 ° C.
온도범위에서 2 내지 12시간 동안 열처리하는 단계 (S150):. Heat treatment for 2 to 12 hours in the temperature range (S150) :.
특히, 본 발명에 따른 알루미늄 합금 도체 전선의 제조방법은 : a) 단계 (S110) 이후에 알루미늄 합금조성물의 탈가스화 및 아물질 여과 단계를 추가로 포함할 수 있다. 여기서, 상기 탈가스화 및 아물질 여과 단계는 a) In particular, the method of manufacturing an aluminum alloy conductor wire according to the present invention may further include: a) degassing and submaterial filtering of the aluminum alloy composition after step S110. Here, the degassing and sub-material filtration step is a)
단계 (S110)와 b) 단계 (S120) 사이에 수행하는 것이 ;바람^하다. b) 단계 (S120) 이후에 상기 탈가스화 및 이물질 여과 단계를 수행하는 경우 가스와 함께 A1- Ti 금속간 화합물이 탈루될 수:있기 때문이다. : 앞서 기술한 바와 같이, b) 단계에서 첨가되는 Al-Ti-B 합금의 석출물이 기지 (Matrix) 내에서 균일하게 분포함으로써, 결정립 크기를 결정하는 석출물간 거리가 감축되고, 결과적으로 결정립 미세화에 의해 알루미늄 합금의 인장강도 등 기계적 강도가 향상될 수 있다. It is desirable to perform between step S110 and b) step S120. b) If the degassing and foreign matter filtration step after step S120 is carried out, the A1-Ti intermetallic compound may be degassed with the gas. : As described above, since the precipitates of the Al-Ti-B alloy added in step b) are uniformly distributed in the matrix, the distance between the precipitates that determine the grain size is reduced, and as a result, the grain refinement is achieved. Mechanical strength such as tensile strength of the aluminum alloy can be improved.
이로써, 본 발명에 따른 알루미늄 합금 도체 전선의 제조방법은 별도의 결정립 미세화 공정이 불필요하므로 제조공정이 간단하고 따라서 제조비용이 절감될 수 있다. As a result, the method of manufacturing the aluminum alloy conductor wire according to the present invention does not require a separate grain refinement process, thereby simplifying the manufacturing process and thus reducing the manufacturing cost.
한편, 상기 c) 단계 (S130)에서 ;상기 연속주조압연에 적용되는 상기 알루미늄 합금 조성물의 온도가 730 내지 900°C인 것이 바람직하다. 상기 On the other hand, c) in step (S130); The temperature of the aluminum alloy composition applied to the continuous casting rolling is preferably 730 to 900 ° C. remind
연속주조압연에 적용되는 조성물의 주입 온도를 상기와 같이 한정하는 이유는 금속간 화합물인 고용체, 즉 치밀한 미세조직을갖는 주물을 얻기 위함이다. 여기서, 상기 알루미늄 합^ 조성물의 주입 은도가 90C C를 초과하는 경우 주물의 미세조직이 조대해지는 문제가 있는 반면, 730°C 미만 ¾ 경우 상기 조성물의 유동성이 부족하여 주형 공간을 치밀하게 채우지 못하는 미스런 (Mi ss Run) 현상이 발생할 수 있다. 여기서, 상기 연속주조압연 공법은 The reason for limiting the injection temperature of the composition applied to continuous casting rolling as described above is to obtain a solid solution which is an intermetallic compound, that is, a casting having a dense microstructure. Here, when the injection silver of the aluminum composite composition exceeds 90C C, there is a problem in that the casting microstructure is coarse, while in the case of less than 730 ° C ¾ the lack of fluidity of the composition can not fill the mold space tightly Miss Run may occur. Here, the continuous casting rolling method
연속주조 (Cont inuous: cast ing) 공법으로 대체될 수 있다 Can be replaced by Cont inuous: cast ing
상기 c) 단계 (S130)에서 제조되는 알루미늄 합금 선재는 자동차용 케이블에 유용하게 적용될 수 있도록 직경이 약 10匪의 크기로 주조되는 것이 가장 바람직하나, 본 발명에 따른 알루미늄 합금 도체 전선의 용도에 따라상기 주조뒤는 알루미늄 합금 선재의 직경은 통상의 기술자에 의해 적절히 선택될 수 있다. C) The aluminum alloy wire produced in step (S130) is most preferably cast in a size of about 10 匪 diameter so that it can be usefully applied to automotive cables, according to the use of the aluminum alloy conductor wire according to the present invention After the casting, the diameter of the aluminum alloy wire can be appropriately selected by a person skilled in the art.
*55d) 단계 (S140)인 신선 공정에서는 상기 주조 알루미늄 합금 선재를 가공하여 단면을 감소시킴으로써 정해진 규격의 합금 선재를 제조한다. 예를 들어, 상기 d) 단계 (S140)는 c) 단계 (S130)에서 제조된 알루미늄 합금 선재를 평균직경 약 2 ram의 선재로하는태신선 공정 및 이를 다시 평균직경 약 0. 15 내지 0.5 mm의 선재로하는 세신선 공정을 포함할 수 있다. d) 단계 (S140)에서 신선된 알루미늄 합금 선재는 단선 또는 연선으로 e) 단계 (S150)인 열처뫼 공정에 의해 열처리된다. 알루미늄 합금 선재는 상기 열처리에 의해 합금의 내부웅력이 증가된 후 웅력해소에 의한 회복을 통해 신율이 향상된다. 다만, 열처리 온도가 과도하게 높거나 열처리 시간이 과도하게 지연되는 경우 결정립의 조대화에 의해 인강강도가크게 손상될 수 있다. 따라서, 열처리에 의해 알루미늄 합금 선재의 신율이 최대로 향상되면서 인장강도가 크게 손상되지 않은 시점, 즉 결정립의 평균입경이 약 50 이하로 유지될 때에 열처리를 중단하는 것이 가장 효율적이다. 55d) In the drawing process of step S140, the cast aluminum alloy wire is processed to reduce the cross section to produce an alloy wire of a predetermined specification. For example, step d) (S140) is a process for drawing a wire drawn from the aluminum alloy wire manufactured in step c) (S130) with an average diameter of about 2 ram, and again the average diameter of about 0.15 to 0.5 mm A thin wire process may be included as a wire rod. d) The aluminum alloy wire drawn in step S140 is heat-treated by the thermomembrane process of step S150 in solid or stranded wire. In the aluminum alloy wire, the elongation is improved through recovery by the stress relief after the internal stress of the alloy is increased by the heat treatment. However, when the heat treatment temperature is excessively high or the heat treatment time is excessively delayed, the toughness may be largely damaged by coarsening of grains. Therefore, it is most efficient to stop the heat treatment when the elongation of the aluminum alloy wire is improved to the maximum by the heat treatment and the tensile strength is not largely damaged, that is, when the average grain size of the crystal grains is maintained at about 50 or less.
상기 e) 단계 (S150)의 열처리 공정에서 석출물의 평균거리가 2 내지 15 ^로, 즉, 결정립의 평균입경이 50 이하로 유지되면서 신율이 최대한 향상될 수 있는 공정조건으로서 열처리 온도는 약 260 내지 360°C이고, 열처리 시간은 약 2 내지 12시간일 수 있다. 이러한 열처리 공정 조건을 만족하는 범위 내에서 , 열처리 온도가 낮을수록 열처리 시간을 증가시키고ᅳ 반면 열처리 온도가 높을수록 열처리 시간을 단축시킴으로써, 열처리에 의해:인장강도가 저하되는 정도를 최^화하면사신율의 향상을 극대화할 수 있다. In the e) heat treatment process of step (S150), the average distance of the precipitate is 2 to 15 ^, that is, the process conditions that the elongation can be improved as much as possible while maintaining the average particle diameter of 50 or less as the heat treatment temperature is about 260 to 360 ° C., heat treatment time may be about 2 to 12 hours. Within the range satisfying the heat treatment process conditions, the lower the heat treatment temperature increases the heat treatment time, while the higher heat treatment temperature shortens the heat treatment time, thereby minimizing the extent to which the tensile strength decreases by heat treatment. The rate of improvement can be maximized.
[실시예] : : EXAMPLES:
1. 제조예 1. Preparation
아래 표 1에 나타난 바와 같은;합금성분을 포함하고 나머지는 알루미늄 (A1 ) 및 불가피한 불순물로 이루어진 알루미늄 합금 선재를 제조하고, 신선 공정과 열처리 공정 (310°C , &시간)을수행하여 실시예:및 비교예 각각에 따른 소선 시편을 제조했다. 아래 표 1에 나타난 합금성분의 함량와단위는 중량 %이다.As shown in Table 1 below, an aluminum alloy wire including an alloy component and the remainder of aluminum (A1) and unavoidable impurities was prepared, followed by a drawing process and a heat treatment process (310 ° C., & hr) to perform an example: And wire specimens according to each of the comparative examples were prepared. The content and units of the alloying components shown in Table 1 below are by weight.
2. 물성 평가 2. Property evaluation
1) 인장강도 및 신율의 평가 1) Evaluation of tensile strength and elongation
실시예 또는 비교예에 따른 각각의 알루미늄 합금 소선 시편의 인장강도 및 신율은 ASTM B557 규격에 따라 와이어용 그리핑 장치 (gripping device)를 이용하여 시편의 :양끝을 고정한 상태에서 lmm/s의 속도로잡아당기는데 소요되는 힘을 측정한후 오프셋 방법 (offset method)을 이용하여 인장강도를 산출했고, 시편이 끊어지는 시점에서의 시편의 길이로부터 신율을 산출했으며, 그 결과는 아래 표 1에 나타난 바와 같다. Tensile strength and elongation of each aluminum alloy wire specimens according to the Examples or Comparative Examples were measured at a rate of lmm / s with both ends of the specimen fixed using a wire gripping device in accordance with ASTM B557. After measuring the force required to pull, the tensile strength is measured using the offset method. Elongation was calculated from the length of the specimen at the time the specimen was broken, and the results are shown in Table 1 below.
2) 전기전도도의 평가 2) Evaluation of electrical conductivity
실시예 또는 비교예에 따른 각각의 알루미늄 합금 소선 시편의 전기전도도는 ASTM B193 규격에 따라 캘빈 더블브리지 (Double Br idge)법으로 전기저항을 측정하여 산출했다. The electrical conductivity of each of the aluminum alloy wire specimens according to the Examples or Comparative Examples was calculated by measuring the electrical resistance by the Calvin Double Bridge method according to the ASTM B193 standard.
【표 1】 Table 1
합금 소선 시편은 최적의 합금원소의 조합 및 합금원소의 최소함량과 최적의 배합비에 의해 석출물간 평균거리가 감축되고, 이로써 결정립의 미세화를 달성함으로써, 열처리에 와해 신율을 15% 이상으로 향상시킴에도 불구하고 인장강도가 저하되는 것을 최소화하여 상기 인장강도를 140 MPa 이상으로 유지할 수 있음을 확인했고, 나아가 합금원소와함량의 최소화에 의해 In the case of alloy wire specimens, the average distance between precipitates is reduced by the optimal combination of alloying elements, the minimum content of alloying elements and the optimal blending ratio, thereby achieving finer grain size, and improving elongation to 15% or more due to heat treatment. Nevertheless, it was confirmed that the tensile strength could be maintained at 140 MPa or more by minimizing the decrease in tensile strength, and furthermore, by minimizing the content of alloying elements.
전기전도도를 59WACS 이상으로 유지할 수 있음을 확인했다. It was confirmed that the electrical conductivity can be maintained above 59WACS.
반면, 비교예 1 및 3의 시편은 알루미늄 합금의 인장강도를 향상시키는 철 (Fe) 또는 구리 (Cu)의 합금원소가 극히 소량 첨가되어 알루미늄 합금에서 On the other hand, in the specimens of Comparative Examples 1 and 3, an extremely small amount of alloying elements of iron (Fe) or copper (Cu) is added in the aluminum alloy to improve the tensile strength of the aluminum alloy.
인장강도가 향상되는정도가 미미한 것으로 확¾1되었고, 반대로 비교예 2 및 4의 시편은 철 (Fe) 또는 구리 (Cu)의 합금원소가 극히 과량 첨가되어 알루미늄 합금에서 전기전도도를 규격인 59 ACS 미만으로 저하된 것으로 확인되었다. 또한, 비교예 5의 시편은 알루미늄 합금의 인장강도를 향상시키는 철 (Fe) 및 구리 (Cu)의 합금원소가 적당량 첨가되었음에도불구하고 결정립 미세화를 위한 티타늄 (Ti ) 및 붕소 (B)가 첨가되지 않아 석출물간 거리가 증가하고, 이로써 결정림이 조대화되어, 결과적으로 신율의 향상을 위한 열처리시 인장강도가 크게 저하된 것으로 확인되:었고, 반대로 비교예 6의 시편은 티타늄 (Ti ) 및 붕소 (B)가 과량 첨가되어 오히려 조대한 금속간 화합물이 생성되고, 이로써 인장강도 및 전기전도도가크게 저하된 것으로 확인되었다. 그리고, 비교예 7 및 9의 시편은 소선의 직경이 과도하게 작기 때문에 인장강도는 우수하나 이와상층관계에 있는 신율, 그리고 전기전도도가크게 저하된 반면, 비교예 8 및 10의 시편은 소선의 직경이 과도하게 크기 때문에 신율과 전기전도도는 우수하나 인장강도가 크게 저하된 것으로 확인되었다. 참고로, 도 2 및 3은 실시예 1 및 비교예 5에서 티타늄 (Ti )의 첨가 여부에 따른 석출물간 거리 및 결정립 미세화 정도를 나타내는 주사전자현미경 (SEM) 비교 사진이다. In contrast, the specimens of Comparative Examples 2 and 4 exhibited extremely high amounts of alloying elements of iron (Fe) or copper (Cu), so that the electrical conductivity of aluminum alloys was lower than 59 ACS. It was confirmed that the lowered. In addition, the specimen of Comparative Example 5 is not added to the titanium (Ti) and boron (B) for grain refinement, although the alloying elements of iron (Fe) and copper (Cu) to improve the tensile strength of the aluminum alloy is added in an appropriate amount As a result, the distance between the precipitates increased, thereby coarsening the crystallized grains, and as a result, it was confirmed that the tensile strength greatly decreased during the heat treatment to improve the elongation. On the contrary, the specimen of Comparative Example 6 was made of titanium (Ti) and boron. Excessive addition of (B) produced rather coarse intermetallic compounds, which resulted in a significant decrease in tensile strength and electrical conductivity. In addition, the specimens of Comparative Examples 7 and 9 had an excellent tensile strength because the diameter of the wire was excessively small, but the elongation and electrical conductivity of the upper layer were greatly reduced, whereas the specimens of Comparative Examples 8 and 10 had the diameter of the wire. Due to this excessive size, the elongation and electrical conductivity were excellent, but the tensile strength was significantly reduced. For reference, FIGS. 2 and 3 are scanning electron microscope (SEM) comparison photographs showing the distance between precipitates and the degree of grain refinement according to the addition of titanium (Ti) in Examples 1 and 5.
앞서 기술한 실시예와 도 2 및 3에 나타난 바와 같이, 본 발명에 따른 알루미늄 합금 도체 전선은 티타늄 (Ti )의 첨가에 의해 결정립의 크기를 결정하는 석출물간 거리를 감축시켜 결정립의 미세화를 유발함으로써, 알루미늄 합금 선재의 신율의 향상을 위한 열처리시 인장강도가 저하되는 정도릊 최소화할 수 있고 결과적으로 인장강도 및 이와상층관계에 있는 신율을 동시에 향상시키는 예측불허의 탁월한효과를 나타낸다. 2 and 3, the aluminum alloy conductor wire according to the present invention reduces the distance between the precipitates that determine the size of the grains by the addition of titanium (Ti), thereby causing the grains to be refined. In addition, it is possible to minimize the degree to which the tensile strength decreases during heat treatment to improve the elongation of the aluminum alloy wire, and as a result, it shows an unpredictable excellent effect of simultaneously improving the tensile strength and elongation in the upper layer relationship.
나아가, 결정립 미세화에 의해 합금원소 중 찰 (Fe) 및 구리 (Cu)를 소량만 첨가해도 충분한 인장강도를 달성할 수 있기 때문에, 전체전인 합금원소의 함량을 최소화하여 전기전도도의 저하를 최소화할 수 있는 우수한 효과를 나타낸다. In addition, since only a small amount of friction (Fe) and copper (Cu) in the alloy elements can be achieved by grain refinement, sufficient tensile strength can be achieved, thereby minimizing the content of the alloy element as a whole, thereby minimizing the decrease in the electrical conductivity. That shows excellent effect.
상기에서는 본 발명의 바람직한 실시예를 참조하여 설명하였지만, 해당 기술분야의 당업자는 이하에서 서술하는 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경 실시할 수 있을 것이다. 그러므로 변형된 실시가 기본적으로 본 발명의 특허청구범위의 구성요소를 포함한다면 모두 본 발명의 기술작 범주에 포함된다고 보아야 한다. ' Although the above has been described with reference to a preferred embodiment of the present invention, those skilled in the art to various modifications and changes to the present invention without departing from the spirit and scope of the invention described in the claims described below You can do it. Therefore, it should be regarded that all modifications are included in the technical scope of the present invention if they basically include elements of the claims of the present invention. '
Claims
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020516777A (en) * | 2017-05-17 | 2020-06-11 | エルエス ケーブル アンド システム リミテッド. | Aluminum alloy for cable conductor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120084479A (en) * | 2011-01-20 | 2012-07-30 | 엘에스전선 주식회사 | Aluminum alloy wire with high electrical conductivity and high strength and manufacturing method thereof |
| KR20130089665A (en) * | 2011-04-11 | 2013-08-12 | 스미토모덴키고교가부시키가이샤 | Aluminum alloy wire and aluminum alloy twisted wire, covered electric wire, and wire harness using same |
| JP5367926B1 (en) * | 2012-03-29 | 2013-12-11 | 古河電気工業株式会社 | Aluminum alloy wire and manufacturing method thereof |
| CN103474153A (en) * | 2013-08-07 | 2013-12-25 | 武汉宏联电线电缆有限公司 | Rare earth aluminum alloy power cable and production technology thereof |
| CN103903673A (en) * | 2014-04-21 | 2014-07-02 | 合肥市科亿铝业有限公司 | Aluminum alloy cable |
-
2015
- 2015-05-20 WO PCT/KR2015/005059 patent/WO2016003068A1/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20120084479A (en) * | 2011-01-20 | 2012-07-30 | 엘에스전선 주식회사 | Aluminum alloy wire with high electrical conductivity and high strength and manufacturing method thereof |
| KR20130089665A (en) * | 2011-04-11 | 2013-08-12 | 스미토모덴키고교가부시키가이샤 | Aluminum alloy wire and aluminum alloy twisted wire, covered electric wire, and wire harness using same |
| JP5367926B1 (en) * | 2012-03-29 | 2013-12-11 | 古河電気工業株式会社 | Aluminum alloy wire and manufacturing method thereof |
| CN103474153A (en) * | 2013-08-07 | 2013-12-25 | 武汉宏联电线电缆有限公司 | Rare earth aluminum alloy power cable and production technology thereof |
| CN103903673A (en) * | 2014-04-21 | 2014-07-02 | 合肥市科亿铝业有限公司 | Aluminum alloy cable |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020516777A (en) * | 2017-05-17 | 2020-06-11 | エルエス ケーブル アンド システム リミテッド. | Aluminum alloy for cable conductor |
| US11508493B2 (en) | 2017-05-17 | 2022-11-22 | Ls Cable & System Ltd. | Aluminum alloy for cable conductor |
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