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WO2016002819A1 - Membrane semi-perméable composite - Google Patents

Membrane semi-perméable composite Download PDF

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Publication number
WO2016002819A1
WO2016002819A1 PCT/JP2015/068919 JP2015068919W WO2016002819A1 WO 2016002819 A1 WO2016002819 A1 WO 2016002819A1 JP 2015068919 W JP2015068919 W JP 2015068919W WO 2016002819 A1 WO2016002819 A1 WO 2016002819A1
Authority
WO
WIPO (PCT)
Prior art keywords
composite semipermeable
semipermeable membrane
membrane
porous support
water
Prior art date
Application number
PCT/JP2015/068919
Other languages
English (en)
Japanese (ja)
Inventor
晴季 志村
貴史 小川
修治 古野
清彦 高谷
佐々木　崇夫
将弘 木村
Original Assignee
東レ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東レ株式会社 filed Critical 東レ株式会社
Priority to KR1020167036461A priority Critical patent/KR102293090B1/ko
Priority to EP15815706.5A priority patent/EP3162432A4/fr
Priority to CN201580034312.7A priority patent/CN106457165B/zh
Priority to JP2015533770A priority patent/JPWO2016002819A1/ja
Priority to US15/323,039 priority patent/US20170120201A1/en
Publication of WO2016002819A1 publication Critical patent/WO2016002819A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/56—Polyamides, e.g. polyester-amides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0006—Organic membrane manufacture by chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0083—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B01D67/00931—Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B01D69/1071—Woven, non-woven or net mesh
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1216—Three or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • B01D69/1251—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/32—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from aromatic diamines and aromatic dicarboxylic acids with both amino and carboxylic groups aromatically bound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/12—Specific ratios of components used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/30—Cross-linking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/48—Influencing the pH
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/66—Avoiding penetration into pores of support of further porous layer with fluid or counter-pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/30—Chemical resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration

Definitions

  • the present invention relates to a composite semipermeable membrane useful for selective separation of a liquid mixture.
  • the composite semipermeable membrane obtained by the present invention can be suitably used for brine or seawater desalination.
  • the membrane separation method is expanding as a method for removing substances (for example, salts) dissolved in the solvent from the solvent (for example, water).
  • Membrane separation is attracting attention as an energy-saving and resource-saving method.
  • membranes used for membrane separation include microfiltration membranes, ultrafiltration membranes, nanofiltration membranes, and reverse osmosis membranes. These membranes are used, for example, in the production of drinking water and industrial ultrapure water from seawater, brine, water containing harmful substances, etc., as well as in wastewater treatment and recovery of valuable materials (for example, patents). References 1 and 2).
  • the composite semipermeable membrane includes an active layer formed by crosslinking a gel layer and a polymer on a porous support layer, and an activity formed by polycondensation of monomers on the porous support layer and the porous support layer.
  • composite semipermeable membranes composite semipermeable membranes having a separation functional layer containing a crosslinked polyamide obtained by polycondensation reaction of a polyfunctional amine and a polyfunctional acid halide have permeability and selective separation properties. Widely used as a high separation membrane.
  • these composite semipermeable membranes are cleaned of dirt adhering to the membrane surface in order to pursue more stable operation, simple operability, and low cost by extending the membrane life. For this reason, durability against various types of chemical cleaning is required. One of them is washing with alkali.
  • the current polyamide-based composite semipermeable membranes have some durability against liquidity fluctuations, but in order to filter raw water of various water quality, high separation performance and practical use can be obtained even under severer alkaline washing.
  • a composite semipermeable membrane capable of maintaining a level of water permeability is desired.
  • An object of the present invention is to provide a composite semipermeable membrane that achieves both high boron removal performance and a practical water permeability even under conditions where washing with an alkali is frequently performed.
  • the present invention has the following configurations (1) to (4).
  • a composite semipermeable membrane comprising a support membrane having a substrate and a porous support layer, and a separation functional layer provided on the porous support layer of the support membrane, wherein the separation functional layer is crosslinked
  • a composite semipermeable membrane having a wholly aromatic polyamide as a main component and x being a carboxy group / amide group molar ratio x being 0.54 or less.
  • (2) The composite semipermeable membrane according to (1), wherein x + y is 0.80 or less, where y is an amino group / amide group molar ratio of the separation functional layer.
  • the number of moles of isophthalic acid and its salt is a
  • the number of moles of terephthalic acid and its salt is b
  • the mole of trimesic acid and its salt The composite semipermeable membrane according to (1) or (2), wherein (a + b) /c ⁇ 0.1 when the number is c.
  • the separation functional layer is formed by the following steps (a) to (c): (A) A step of bringing an aqueous solution containing a polyfunctional aromatic amine into contact with the porous support layer (b) A polyfunctional aromatic acid halide on the porous support layer brought into contact with an aqueous solution containing the polyfunctional aromatic amine (C) The step of heating the porous support layer in contact with the organic solvent solution containing the polyfunctional aromatic halide In the composite semipermeable membrane after the step (c) The composite semipermeable membrane according to any one of (1) to (3), wherein the remaining amount of water is controlled to be 30% to 95% of the remaining amount of water after step (b) .
  • the present invention can provide a composite semipermeable membrane having practical water permeability and high alkali resistance.
  • the composite semipermeable membrane according to the present invention includes a support membrane having a base material and a porous support layer, and a separation functional layer provided on the porous support layer of the support membrane.
  • the separation functional layer has substantially separation performance, and the support membrane does not substantially have separation performance of ions or the like, and can give strength to the separation functional layer.
  • Substrates of the substrate include polyester polymers, polyamide polymers, polyolefin polymers, and mixtures and copolymers thereof. Among them, a polyester polymer fabric having high mechanical and thermal stability is particularly preferable.
  • a long fiber nonwoven fabric, a short fiber nonwoven fabric, or a woven or knitted fabric can be preferably used.
  • the long-fiber nonwoven fabric refers to a nonwoven fabric having an average fiber length of 300 mm or more and an average fiber diameter of 3 to 30 ⁇ m.
  • the substrate preferably has an air flow rate of 0.5 cc / cm 2 / sec or more and 5.0 cc / cm 2 / sec or less. Since the polymer solution that forms the porous support layer is impregnated into the substrate when the air permeability of the substrate is within the above range, the adhesion to the substrate is improved, and the physical stability of the support film is improved. Can be increased.
  • the thickness of the substrate is preferably in the range of 10 to 200 ⁇ m, and more preferably in the range of 30 to 120 ⁇ m.
  • the thickness is expressed as an average value, and the average value means an arithmetic average value.
  • the thickness of the base material and the porous support layer can be determined by calculating an average value of thicknesses at 20 points measured at intervals of 20 ⁇ m in a direction (surface direction of the film) orthogonal to the thickness direction by cross-sectional observation.
  • the porous support layer has substantially no separation performance for ions and the like, and is for imparting strength to the separation functional layer having substantially the separation performance. , Formed on a substrate.
  • the size and distribution of the pores of the porous support layer are not particularly limited.For example, uniform and fine pores, or gradually having fine pores from the surface on the side where the separation functional layer is formed to the other surface, and A porous support layer having a fine pore size of 0.1 nm or more and 100 nm or less on the surface on the side where the separation functional layer is formed is preferred, but the material used and its shape are not particularly limited.
  • the material for the porous support layer examples include, for example, polysulfone, polyethersulfone, polyamide, polyester, cellulosic polymer, vinyl polymer, polyphenylene sulfide, polyphenylene sulfide sulfone, polyphenylene sulfone, polyphenylene oxide, homopolymer or copolymer alone or Can be blended and used.
  • cellulose acetate and cellulose nitrate can be used as the cellulose polymer
  • polyethylene, polypropylene, polyvinyl chloride, polyacrylonitrile and the like can be used as the vinyl polymer.
  • homopolymers or copolymers such as polysulfone, polyamide, polyester, cellulose acetate, cellulose nitrate, polyvinyl chloride, polyacrylonitrile, polyphenylene sulfide, and polyphenylene sulfide sulfone are preferable. More preferred is cellulose acetate, polysulfone, polyphenylene sulfide sulfone, or polyphenylene sulfone.
  • polysulfone is highly stable chemically, mechanically and thermally, and is easy to mold. Can be used generally.
  • polysulfone composed of repeating units represented by the following chemical formula because the pore diameter of the porous support layer can be easily controlled and the dimensional stability is high.
  • n is a positive integer.
  • the polysulfone preferably has a weight average molecular weight (Mw) of 10,000 or more and 200,000 or less when measured by gel permeation chromatography (GPC) using N-methylpyrrolidone as a solvent and polystyrene as a standard substance. 15000 or more and 100000 or less.
  • Mw weight average molecular weight
  • GPC gel permeation chromatography
  • Mw is 10,000 or more, mechanical strength and heat resistance preferable as a porous support layer can be obtained.
  • Mw is 200000 or less, the viscosity of the solution falls within an appropriate range, and good moldability can be realized.
  • an N, N-dimethylformamide (hereinafter referred to as DMF) solution of the above polysulfone is cast on a densely woven polyester cloth or non-woven fabric to a certain thickness, and wet coagulated in water.
  • a porous support layer having most of the surface having fine pores with a diameter of several tens of nm or less can be obtained.
  • the thickness of the substrate and the porous support layer affects the strength of the composite semipermeable membrane and the packing density when it is used as an element.
  • the total thickness of the base material and the porous support layer is preferably 30 ⁇ m or more and 300 ⁇ m or less, and more preferably 100 ⁇ m or more and 220 ⁇ m or less.
  • the thickness of the porous support layer is preferably 20 ⁇ m or more and 100 ⁇ m or less.
  • the separation functional layer contains a crosslinked wholly aromatic polyamide.
  • the separation functional layer preferably contains a crosslinked wholly aromatic polyamide as a main component.
  • the main component refers to a component occupying 50% or more of the components of the separation functional layer.
  • the separation functional layer contains 50% by weight or more of the crosslinked wholly aromatic polyamide, high separation performance can be exhibited.
  • the separation functional layer is formed substantially only of a crosslinked wholly aromatic polyamide. That is, it is preferable that the crosslinked wholly aromatic polyamide occupies 90% by weight or more of the separation functional layer.
  • the cross-linked wholly aromatic polyamide can be formed by interfacial polycondensation of a polyfunctional aromatic amine and a polyfunctional aromatic acid halide.
  • a polyfunctional aromatic amine and a polyfunctional aromatic acid halide contains a trifunctional or higher functional compound.
  • the separation functional layer in the present invention may be referred to as a polyamide separation functional layer.
  • the polyfunctional aromatic amine has two or more amino groups of at least one of a primary amino group and a secondary amino group in one molecule, and at least one of the amino groups is a primary amino group.
  • An aromatic amine that is an amino group is meant.
  • polyfunctional aromatic amines include o-phenylenediamine, m-phenylenediamine, p-phenylenediamine, o-xylylenediamine, m-xylylenediamine, p-xylylenediamine, o-diaminopyridine, m- 1,3,5-triaminobenzene, a polyfunctional aromatic amine in which two amino groups such as diaminopyridine and p-diaminopyridine are bonded to an aromatic ring in any of the ortho, meta, and para positions 1, 2,4-triaminobenzene, 3,5-diaminobenzoic acid, 3-aminobenzylamine, polyfunctional aromatic amines such as 4-amin
  • m-phenylenediamine, p-phenylenediamine, and 1,3,5-triaminobenzene are preferably used in consideration of the selective separation property, permeability, and heat resistance of the membrane.
  • m-phenylenediamine hereinafter also referred to as m-PDA
  • m-PDA polyfunctional aromatic amines may be used alone or in combination of two or more.
  • the polyfunctional aromatic acid halide refers to an aromatic acid halide having at least two carbonyl halide groups in one molecule.
  • trifunctional acid halides include trimesic acid chloride
  • bifunctional acid halides include biphenyl dicarboxylic acid dichloride, azobenzene dicarboxylic acid dichloride, terephthalic acid chloride, isophthalic acid chloride, naphthalene dicarboxylic acid chloride, and the like. Can be mentioned.
  • the polyfunctional aromatic acid halide is preferably a polyfunctional aromatic acid chloride, and in consideration of selective separation of the membrane and heat resistance, one molecule More preferred is a polyfunctional aromatic acid chloride having 2 to 4 carbonyl chloride groups therein.
  • the terminal carboxy group of the polyamide functional layer can be reduced as compared with the case where the trifunctional or higher functional acid halide is used.
  • a trifunctional acid halide from the viewpoint of forming a three-dimensional crosslinked structure and ensuring water permeability by improving hydrophilicity.
  • trimesic acid chloride from the viewpoint of easy availability and easy handling.
  • the molar ratio of the bifunctional acid halide such as terephthalic acid chloride or isophthalic acid chloride to the trifunctional acid halide such as trimesic acid chloride is preferably 0 or more and 0.1 or less. That is, when the number of moles of isophthalic acid and its salt is a, the number of moles of terephthalic acid and its salt is b, and the number of moles of trimesic acid and its salt is c, 0 ⁇ (a + b) /c ⁇ 0.1 Preferably there is.
  • This molar ratio can be calculated from the weight of a carboxylate obtained by alkaline hydrolysis of the separation functional layer.
  • the polyamide separation functional layer has an amide group derived from polymerization of a polyfunctional aromatic amine and a polyfunctional aromatic acid halide, an amino group derived from an unreacted functional group, and a carboxy group.
  • the present inventors have found that the molar ratio of carboxy group to amide group correlates with alkali resistance.
  • the carboxy group may be ionized. This degree is determined by the alkalinity of the solution and the base dissociation constant of the carboxy group.
  • the carboxy group is ionized, the higher-order structure of the film is broken by the Coulomb force, and the degree of reduction of the removal rate is increased.
  • x is 0.54 or less, preferably 0.4 or less, and 0.35 or less. It is more preferable that In order to impart hydrophilicity to the polyamide separation functional layer, x is preferably 0.1 or more.
  • the total amount of carboxy groups and amino groups and the molar ratio of amide groups correlate with alkali resistance.
  • the amide group is hydrolyzed, the molecular chain is cut, and the removal rate may be lowered.
  • the polyamide functional layer with a small proportion of carboxy groups and amino groups, which are terminal functional groups, and a large proportion of amide groups has a high molecular weight and is highly cross-linked. The rate of decline is low.
  • x + y is 0.80 or less, where x is the carboxy group / amide group molar ratio and y is the amino group / amide group molar ratio. The removal rate can be maintained.
  • x + y is preferably 0.1 or more.
  • the molar ratio of the carboxy group, amino group, and amide group can be determined from 13 C solid state NMR measurement of the separation functional layer. Specifically, after peeling the base material from the composite semipermeable membrane 5m 2 to obtain a polyamide separation functional layer and a porous support layer, the porous support layer is dissolved and removed to obtain a polyamide separation functional layer. The obtained polyamide separation functional layer is measured by DD / MAS- 13C solid-state NMR method, and each ratio is calculated by comparing the integrated value of the carbon peak of each functional group or the carbon peak to which each functional group is bonded. be able to.
  • the element ratio of carbon, nitrogen and oxygen in the crosslinked wholly aromatic polyamide is 64.0% by weight or more and 67.0% by weight or less of carbon and 10.5% by weight of nitrogen in order to realize the above chemical structure. It is preferably 14.5% by weight or less and oxygen 15.0% by weight or more and 21.0% by weight or less.
  • the polyamide separation functional layer has an amide group derived from polymerization of a polyfunctional aromatic amine and a polyfunctional aromatic acid halide, an amino group derived from an unreacted functional group, and a carboxy group.
  • functional groups can be introduced into the polyamide separation functional layer, and the performance of the composite semipermeable membrane can be improved.
  • new functional groups include alkyl groups, alkenyl groups, alkynyl groups, halogeno groups, hydroxyl groups, ether groups, thioether groups, ester groups, aldehyde groups, nitro groups, nitroso groups, nitrile groups, azo groups, and the like.
  • chlorine groups can be introduced by treatment with an aqueous sodium hypochlorite solution.
  • a halogeno group can also be introduced by a Sandmeyer reaction via formation of a diazonium salt.
  • an azo group can be introduced by carrying out an azo coupling reaction via diazonium salt formation, and a phenolic hydroxyl group can also be introduced by hydrolyzing the diazonium salt.
  • the composite semipermeable membrane includes a step of forming a porous support layer on at least one surface of the substrate, and a step of forming a separation functional layer on the porous support layer.
  • porous support layer As the base material and the porous support layer, “Millipore Filter VSWP” (trade name) manufactured by Millipore and “Ultra Filter UK10” (trade name) manufactured by Toyo Roshi Kaisha, Ltd. are used. An appropriate membrane can be selected from various commercially available membranes. Also, “Office of Saleen Water Research and Development Progress Report” No. 359 (1968). In addition, a known method is suitably used as a method for forming the porous support layer.
  • the step of forming the separation functional layer includes the following steps (a) to (c).
  • the concentration of the polyfunctional aromatic amine in the polyfunctional aromatic amine aqueous solution is preferably in the range of 0.1 wt% to 20 wt%, more preferably 0.5 wt% to 15 wt%. Within the range of% by weight or less. When the concentration of the polyfunctional aromatic amine is within this range, sufficient solute removal performance and water permeability can be obtained.
  • the polyfunctional aromatic amine aqueous solution includes surfactants, organic solvents, alkaline compounds, antioxidants, etc., as long as they do not interfere with the reaction between the polyfunctional aromatic amine and the polyfunctional aromatic acid halide. It may be.
  • the surfactant has the effect of improving the wettability of the support membrane surface and reducing the interfacial tension between the polyfunctional aromatic amine aqueous solution and the nonpolar solvent.
  • the organic solvent may act as a catalyst for the interfacial polycondensation reaction, and when added, the interfacial polycondensation reaction may be efficiently performed.
  • polyfunctional aromatic amines are susceptible to degradation due to oxidation, re-purification immediately before making an aqueous polyfunctional aromatic amine solution improves the yield of the reaction in step (b), resulting in resistance to resistance.
  • a highly alkaline membrane can be obtained. Methods such as recrystallization and sublimation purification can be used for purification.
  • the purity of the polyfunctional aromatic amine is preferably 99% or more, and more preferably 99.9% or more.
  • the contact of the polyfunctional aromatic amine aqueous solution is preferably performed uniformly and continuously on the porous support layer.
  • Specific examples include a method of coating a porous support layer with a polyfunctional aromatic amine aqueous solution and a method of immersing the porous support layer in a polyfunctional aromatic amine aqueous solution.
  • the contact time between the porous support layer and the polyfunctional amine aqueous solution is preferably 1 second or longer and 10 minutes or shorter, and more preferably 10 seconds or longer and 3 minutes or shorter.
  • the liquid After the polyfunctional amine aqueous solution is brought into contact with the porous support layer, the liquid is sufficiently drained so that no droplets remain on the membrane. By sufficiently draining the liquid, it is possible to prevent the remaining portion of the liquid droplet from becoming a membrane defect after the formation of the porous support layer and the removal performance from being deteriorated.
  • a method of draining for example, as described in Japanese Patent Application Laid-Open No. 2-78428, a method of allowing an excess aqueous solution to flow down naturally by gripping a support membrane after contacting a polyfunctional amine aqueous solution in a vertical direction.
  • the membrane surface after draining, the membrane surface can be dried to partially remove water from the aqueous solution.
  • the concentration of the polyfunctional acid halide in the organic solvent solution is preferably in the range of 0.01 wt% to 10 wt%, and is 0.02 wt% to 2.0 wt%. It is more preferable that it is within the range. This is because a sufficient reaction rate can be obtained when the content is 0.01% by weight or more, and the occurrence of side reactions can be suppressed when the content is 10% by weight or less. Furthermore, when an acylation catalyst is contained in the organic solvent solution, interfacial polycondensation is promoted, which is more preferable.
  • the organic solvent is preferably immiscible with water and dissolves the polyfunctional acid halide and does not break the support membrane, and is inert to the polyfunctional amine compound and polyfunctional acid halide. I just need it.
  • Preferable examples include hydrocarbon compounds such as n-hexane, n-octane, n-decane, and isooctane.
  • the method of contacting the porous support layer in contact with the polyfunctional aromatic amine compound aqueous solution in the organic solvent solution of the polyfunctional aromatic acid halide is a method of coating the porous support layer with the polyfunctional aromatic amine aqueous solution. The same may be done.
  • step (c) the porous support layer in contact with the organic solvent solution of the polyfunctional aromatic acid halide is heated.
  • the temperature for the heat treatment is 50 ° C. or higher and 180 ° C. or lower, preferably 60 ° C. or higher and 160 ° C. or lower.
  • the remaining amount of water contained in the composite semipermeable membrane after the step (c) needs to be 30% to 95% of the remaining amount of water after the step (b).
  • the remaining amount of water contained in the composite semipermeable membrane after the step (c) is preferably 60% or more and 90% or less of the remaining amount of water after the step (b).
  • the heat treatment temperature in the step (c) is 50 ° C.
  • step (c) the remaining amount of water immediately after the heat treatment (step (c)) is 95% or less of that before the heat treatment (step (b)). Since the interfacial polymerization reaction can be accelerated by concentrating the aqueous amine solution, the remaining amount of carboxy groups can be reduced. Further, by setting the remaining amount of water immediately after the heat treatment to 30% or more before the heat treatment, it is possible to prevent overdrying of the polyamide functional layer and the porous support layer and to ensure practical water permeability.
  • the heating method is not particularly limited, and hot air, infrared rays, microwaves, heating rolls, and the like can be used. However, it is necessary to perform heating while controlling the remaining amount of water to be within the above-mentioned preferable range. Using a general dryer, oven, heating roll, etc., it is easy to uniformly control the remaining amount of water in the composite semipermeable membrane to the above range only by setting conditions such as temperature, wind speed, time, etc. is not. A part where the film is overdried or a part where water remains but is insufficiently heated and the interfacial polymerization is not accelerated may occur over the entire film or partially.
  • the method for controlling the remaining amount of water is not particularly limited, but a method for suppressing the evaporation rate of water from the front and back of the membrane or an atmosphere control for appropriately adding water or water vapor to the membrane can be used. .
  • the composite semipermeable membrane of the present invention comprises a plurality of pores together with a feed water channel material such as a plastic net, a permeate channel material such as tricot, and a film for increasing pressure resistance as required. Is wound around a cylindrical water collecting pipe and is suitably used as a spiral composite semipermeable membrane element. Furthermore, a composite semipermeable membrane module in which these elements are connected in series or in parallel and accommodated in a pressure vessel can be obtained.
  • the above-described composite semipermeable membrane, its elements, and modules can be combined with a pump for supplying supply water to them, a device for pretreating the supply water, and the like to constitute a fluid separation device.
  • a separation device it is possible to separate the supplied water into permeated water such as drinking water and concentrated water that has not permeated through the membrane, thereby obtaining water that meets the purpose.
  • TDS Total Dissolved Solids: total dissolved solids
  • the solution filtered through a 0.45 micron filter can be evaporated at a temperature of 39.5 ° C. or higher and 40.5 ° C. or lower and calculated from the weight of the residue.
  • the operating pressure at the time of permeation is preferably 0.5 MPa or more and 10 MPa or less.
  • the functional group / composition analysis and the remaining amount of water were measured as follows. Hereinafter, when there was no special description, operation was performed at 25 degreeC.
  • the base material was physically peeled from the composite semipermeable membrane 5 m 2 to recover the porous support layer and the separation functional layer. After being allowed to stand for 24 hours to dry, it was added little by little in a beaker containing dichloromethane and stirred to dissolve the polymer constituting the porous support layer. Insoluble matter in the beaker was collected with filter paper. The insoluble material was placed in a beaker containing dichloromethane and stirred, and the insoluble material in the beaker was collected again. This operation was repeated until no elution of the polymer forming the porous support layer in the dichloromethane solution could be detected.
  • the collected separation functional layer was dried with a vacuum dryer to remove the remaining dichloromethane.
  • the obtained separation functional layer was made into a powdery sample by freeze pulverization, sealed in a sample tube used for solid NMR measurement, and subjected to 13 C solid NMR measurement by CP / MAS method and DD / MAS method.
  • 13 C solid state NMR measurement for example, CMX-300 manufactured by Chemicals can be used. An example of measurement conditions is shown below.
  • composition analysis The separation functional layer recovered above was immersed in a 40% sodium bicarbonate aqueous solution, sealed in a pressure vessel, heated at 120 ° C. for 10 hours, and completely hydrolyzed. The obtained solution was subjected to 1 H NMR measurement, and the ratio of decomposed products was analyzed.
  • the composite semipermeable membrane before heating was also cut out separately and subjected to the same measurement to determine the amount of moisture before heating.
  • Residual amount of water (%) (water content after heating / water content before heating) ⁇ 100
  • Residual amount of water (%) (water content after heating / water content before heating) ⁇ 100
  • the various characteristics of the composite semipermeable membrane are as follows. Seawater (TDS concentration 3.5%, boron concentration about 5 ppm) adjusted to pH 6.5 is supplied to the composite semipermeable membrane at an operating pressure of 5.5 MPa, and membrane filtration treatment is performed 24 times. It was determined by measuring the quality of the permeated water and the feed water after that time.
  • membrane permeation flux The membrane permeation amount of the feed water (seawater) was defined as the permeation amount per cubic meter of the membrane surface per day (cubic meter), and the membrane permeation flux (m 3 / m 2 / day) was expressed.
  • the composite semipermeable membrane was immersed in an aqueous sodium hydroxide solution adjusted to pH 13 for 20 hours. Thereafter, it was thoroughly washed with water and evaluated by evaluating the boron removal rate of the composite semipermeable membrane.
  • Example 1 The m-phenylenediamine was purified by sublimation to a purity of 99.95%, and a 6.0 wt% aqueous solution was immediately prepared.
  • the support membrane obtained by the above operation was immersed in the aqueous solution for 2 minutes, the support membrane was slowly pulled up in the vertical direction, and nitrogen was blown from the air nozzle to remove excess aqueous solution from the surface of the support membrane.
  • the decane solution at 45 ° C. containing 0.165% by weight of trimesic acid chloride (TMC) was applied so that the surface was completely wetted and allowed to stand for 10 seconds.
  • TMC trimesic acid chloride
  • Example 2 A composite semipermeable membrane in Example 2 was obtained in the same manner as in Example 1 except that the solution of trimesic acid chloride was a decane solution containing 0.006% by weight of isophthalic acid chloride and 0.157% by weight of trimesic acid chloride. .
  • Example 3 Example 1 Example 3 except that the solution of trimesic acid chloride was a decane solution containing 0.006% by weight of isophthalic acid chloride, 0.006% by weight of terephthalic acid chloride and 0.149% by weight of trimesic acid chloride. A composite semipermeable membrane in 3 was obtained.
  • Example 4 Example 1 Example 1 except that the solution of trimesic acid chloride was a decane solution containing 0.013% by weight of isophthalic acid chloride, 0.013% by weight of terephthalic acid chloride and 0.132% by weight of trimesic acid chloride. A composite semipermeable membrane in 4 was obtained.
  • Example 5 A composite semipermeable membrane in Example 5 was obtained in the same manner as in Example 1 except that m-phenylenediamine was purified to 99.9% by recrystallization and a 6.0 wt% solution prepared immediately was used.
  • Example 6 A composite semipermeable membrane in Example 6 was obtained in the same manner as in Example 1 except that m-phenylenediamine was used without purification.
  • Example 7 A composite semipermeable membrane in Example 7 was obtained in the same manner as in Example 6 except that air heated and humidified to 100 ° C. and humidity of 80% was supplied from the back side of the membrane.
  • Example 8 A composite semipermeable membrane in Example 8 was obtained in the same manner as in Example 6 except that air heated and humidified to 100 ° C. and 50% humidity was supplied from the back surface of the membrane.
  • Example 9 A composite semipermeable membrane in Example 9 was obtained in the same manner as in Example 6 except that 100 ° C. water vapor was supplied from the back surface of the membrane and the heating time was 5 seconds.
  • Example 10 The composite semipermeable membrane obtained in Example 1 was immersed in an aqueous solution of m-PDA 500 ppm for 120 seconds, and then immersed in an aqueous solution containing 0.4 wt% sodium nitrite adjusted to pH 3.0 and 35 ° C. for 1 minute. The pH of the sodium nitrite aqueous solution was adjusted using sulfuric acid. Thereafter, the composite semipermeable membrane was immersed in a 0.1 wt% sodium sulfite aqueous solution at 35 ° C. for 2 minutes to obtain a composite semipermeable membrane in Example 10.
  • Comparative Example 1 A composite semipermeable membrane in Comparative Example 1 was obtained in the same manner as in Example 1 except that the step of placing in the oven was omitted.
  • Comparative Example 2 A composite semipermeable membrane in Comparative Example 2 was obtained in the same manner as in Example 5 except that the step of placing in the oven was omitted.
  • Comparative Example 3 A composite semipermeable membrane in Comparative Example 3 was obtained in the same manner as in Example 6 except that steam was not supplied from a nozzle provided on the back side of the membrane in an oven at 120 ° C., but was heated for 15 seconds.
  • Comparative Example 4 A composite semipermeable membrane in Comparative Example 4 was obtained in the same manner as in Example 6 except that in an oven at 120 ° C., water vapor was not supplied from the nozzle provided on the back side of the membrane and heated for 180 seconds.
  • Comparative Example 5 The solution of trimesic acid chloride was IP Solvent 1016 (manufactured by Idemitsu Kosan Co., Ltd.), and it was the same as in Example 6 except that it was heated for 180 seconds without supplying water vapor from the nozzle provided on the back side of the membrane in an oven at 120 ° C. Thus, a composite semipermeable membrane in Comparative Example 5 was obtained.
  • Example 6 Comparison was made in the same manner as in Example 6 except that the solution of trimesic acid chloride was Isopar L (manufactured by Exxon Mobil), the reaction was performed for 60 seconds in a booth maintained at 25 ° C., and the step of placing in the oven was omitted. The composite semipermeable membrane in Example 6 was obtained.
  • the solution of trimesic acid chloride was Isopar L (manufactured by Exxon Mobil)
  • the reaction was performed for 60 seconds in a booth maintained at 25 ° C., and the step of placing in the oven was omitted.
  • the composite semipermeable membrane in Example 6 was obtained.
  • Comparative Example 7 A composite semipermeable membrane in Comparative Example 7 was obtained in the same manner as Comparative Example 2 except that the solution concentration of m-phenylenediamine was changed to 10%.
  • Table 1 shows the amount of water remaining in the composite semipermeable membrane obtained above, the terminal functional groups, the ratio of the carboxylate after hydrolysis, and the membrane performance results before and after the alkali resistance test.
  • the composite semipermeable membrane of the present invention has high alkali resistance and high practical water permeability.
  • the composite semipermeable membrane of the present invention can be suitably used for brine or seawater desalination.

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Abstract

La présente invention concerne une membrane semi-perméable composite qui présente un degré de perméabilité à l'eau pratique et une résistance aux alcali élevée. Cette membrane semi-perméable composite comprend une membrane support, qui comprend un matériau de base et une couche de support poreuse, et une couche fonctionnelle de séparation qui est placée sur la couche de support poreuse de la membrane support, laquelle couche fonctionnelle de séparation contient un polyamide entièrement aromatique réticulé et x, qui représente le rapport molaire groupe carboxy/groupe amide, est inférieur ou égal à 0,54.
PCT/JP2015/068919 2014-06-30 2015-06-30 Membrane semi-perméable composite WO2016002819A1 (fr)

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CN109456477B (zh) * 2017-09-06 2021-08-06 欧美新材料(浙江)有限公司 一种改性间位芳纶、其制备方法和中空纤维膜
JP7427190B2 (ja) * 2020-03-31 2024-02-05 株式会社Lixil 複合半透膜
CN115518535B (zh) * 2022-10-25 2025-05-30 沃顿科技股份有限公司 一种高脱盐海水淡化复合反渗透膜的制备方法

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JPWO2016002819A1 (ja) 2017-04-27
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