WO2016099005A1 - Shampoo composition having outstanding usability and foaming power - Google Patents

Abstract

The present invention relates to a shampoo composition having outstanding usability and foaming power, and the shampoo composition of the present invention is characterised by comprising a mixture of a first topical preparation comprising sodium bicarbonate and a second topical preparation comprising a plant-based natural organic acid comprising citric acid, such that carbon dioxide is produced due to a reaction between the sodium bicarbonate and the citric acid in the plant-based natural organic acid. Due to such features, according to the present invention, when the shampoo is used, a large quantity of carbon dioxide gas is produced and foaming power is substantially increased and at the same time the viscosity remains unchanged, thus the usability is improved.

Description

Shampoo composition with excellent usability and foaming power

The present invention relates to a shampoo composition having excellent usability and foaming power, and more particularly, when applied to the skin such as scalp, the use of a greatly improved usability by generating a large amount of carbon dioxide gas while maintaining an appropriate viscosity The present invention relates to a shampoo composition having excellent performance and foaming power.

Carbon dioxide gas is known to act to expand the blood vessels of the human body, and for this reason, as a skin care product, a pack product using carbon dioxide such as carbon dioxide (CO2) generated by mixing carbonate and acid is known.

However, since the carbon dioxide generated by this method is released into the air at a short time, it is difficult to maintain the state in which the carbon dioxide is continuously in contact with the human skin.

In order to solve the above problems, by adding a viscous composition composed of a water-soluble thickener such as alginate or sodium carboxymethyl cellulose to a product containing a carbonate, the water-soluble acid is mixed in the base material having a certain viscosity in advance just before use to give carbonic acid. Pack products and the like that generate gas and improve carbon captureability have been developed.

However, when a proper adhesive force is added to the external preparation for skin such as a pack product to improve its usability as described above, the composition constituting the external preparation becomes a paste, and when mixed with a water-soluble acid, the generation of carbon dioxide gas becomes very soft and occurs quietly. Therefore, it is not easy for the user to recognize whether carbon dioxide is being generated.

In order to solve this problem, there is also a method of increasing the amount of carbon dioxide generated by changing the type of carbonate or water-soluble acid to prepare the external preparation for skin, but in this case, although carbon dioxide is generated easily, As a result, the viscosity of the composition is significantly lowered, and thus, when applied to the skin, the external preparation may not adhere to the skin and may easily flow down from the skin, contaminating clothing and the like.

In other words, conventional skin external preparations have higher visibility but lower usability when increasing the amount of carbon dioxide generated so that the user can easily confirm the generation of carbon dioxide. Losing is a problem.

The present inventors, when mixing a liquid carboxy external preparation (first external preparation) containing sodium bicarbonate and a second external preparation of a liquid containing a natural organic acid containing citric acid, a large amount of carbon dioxide is generated, also generated carbon dioxide It was confirmed through experiments that the foam by the small, homogeneous, excellent retention and good use, and came to complete the present invention.

Therefore, the present invention was devised to solve the problems of conventional external preparations for skin based on the finding of the above fact, and to provide a shampoo composition having excellent usability and foaming power by generating a large amount of carbon dioxide. There is a purpose.

An object of the present invention as described above is to construct a shampoo composition by mixing a first external preparation of a liquid containing sodium bicarbonate and a second external preparation containing a vegetable natural organic acid containing citric acid, the vegetable natural organic acid and sodium bikao This is accomplished by allowing the nates to react with each other to generate carbon dioxide.

In addition, the present invention is characterized in that the vegetable natural organic acid is selected from fermented goji berry concentrate, fermented blue plum concentrate, fermented citrus concentrate, fermented apple concentrate, fermented bokbunja concentrate.

The present invention also provides a first external preparation comprising: A group containing xanthan gum as purified water and thickener, B group containing ammonium laureth sulfate as cleaning agent, C group containing fragrance, and polyquaternium-7. Another feature consists of an E group comprising a D group and sodium bicarbonate.

In addition, in the present invention, the second external preparation includes A group containing purified water and butylene glycol, B group containing ammonium laureth sulfate as a cleaning agent, C group containing fragrance, and purified water and vegetable natural organic acid. It is another feature that it is made of a D group containing.

When the present invention is used to clean the scalp, since sodium bicarbonate and constituent natural organic acids including citric acid react with each other to generate a large amount of carbon dioxide, the user may easily generate carbon dioxide (carbon dioxide). In addition, since the viscosity remains the same, the shampoo does not easily flow out of the hair during use, so that clothes and the like are not easily contaminated.

And the present invention has the advantage of more environmentally friendly and excellent reaction with the skin because it uses a vegetable natural organic acid, such as a concentration of fermented gojija, cheongmaesil, citrus, apples, bokbunja.

 In addition, the present invention by supplying a large amount of carbon dioxide gas to the scalp to recognize that the scalp is deficient in oxygen gas by the supplied carbon dioxide to increase blood flow and Vascular Endothelial Growth Factor (VEGF) to promote blood circulation and scalp cell regeneration It has the effect of promoting.

1 is a manufacturing flow chart showing a method for producing a shampoo composition excellent in usability and foaming power according to the present invention in order.

Hereinafter, the configuration and operation of the present invention through the accompanying drawings showing a preferred embodiment of the present invention in more detail.

The present invention is to provide a shampoo composition excellent in usability and foaming ability while generating a large amount of carbon dioxide gas, the shampoo composition of the present invention is made by mixing the first external agent and the second external agent to each other, Explain.

<First external preparation>

The first external preparations include hydroxyethyl cellulose and purified water, trihydroxystearin, glycerin, disodium ethane, methylparaben, panthenol, glycol stearate, cocamide die, sodium laureth sulfate, sodium lauroyl gluta Made, cocamidopropylbetaine, fragrance, phenoxyethanol, polycoternium-7, dimethicone and sodium bicarbonate, where steares-2 or steares-20 may be used instead of dimethicone.

When preparing the first external preparation having the composition as described above, as shown in Table 1 and Table 1 below, each composition is prepared in a predetermined amount by dividing each composition into A, B, C, D, and E groups (S100), and then A first. After dissolving the composition of the group into a dissolution tank using a stirrer rotating at a speed of 200 rpm while warming to 75 ° C. (S200), the composition of the group B, C, and D was sequentially added to the dissolved group A. While stirring, using a stirrer and uniformly stirred (S300), and then cooled to 45 ° C or less (S400) is prepared by slowly adding the composition of the E group (S500).

In the composition of the group A, hydroxyethyl cellulose is used as a gelling agent, an emulsion stabilizer, a film forming agent, a thickener, and in the present invention, such a hydroxyethyl cellulose is a binder and an emulsion stabilizer of a shampoo. Used as

Tri-hydroxystearin is a vegetable, which is used as a water evaporation blocker and a thickener, and it is effective in smoothing the skin and supplying oil. Glycerin (glycerophosphoric acid) is used as a denaturant, perfume, hair conditioning agent, Widely used as skin moisturizer, skin protectant, viscosity reducer and moisturizer, it is used to moisturize hair or skin and to prevent shampoo from drying out.

In addition, in the composition of Group B, di-sodium EDTA is a metal ion blocking agent (corrosion inhibitor), and is widely used in cosmetics as a use for preventing the rancidity, bacterial infection, and deposits of cosmetics. , Methylparaben (methylparaben) is a preservative that has a bactericidal effect against all bacteria, is known to have little toxicity and little toxicity to the human body.

Panthenol is a hair conditioning agent that promotes cell growth, moisturizes the skin, and is known to be effective in providing radiance to skin mucous membranes and healing wounds. Glycolstearate is mainly used as an emulsifying stabilizer, opacifier and skin softener, and cocamide DEA is an alkylolamide made by condensing palm oil fatty acid and an equivalent diethanolamine. (Bubble accelerator) and thickener. Sodium laureth sulfate is an anionic surfactant, sodium lauroyl glutamate is a hair conditioning agent, cocamidopropyl betaine is a synthetic surfactant and soft and It has a foaming and washing effect and is used as a detergent, skin conditioner, hair conditioner and thickener.

In addition, in the composition of the group C, phenoxyethanol is used as a chemical preservative to suppress the growth of microorganisms and bacteria, and to prevent the decay of cosmetics.

And in the composition of group D, polyquatenium-7 is widely used as a hair conditioning agent, an antistatic agent, a film former and a hair fixative agent, and di-methicone is a linear siloxane polymer. As a kind of silicone oil obtained by completely methylation, it is used as an antifoaming agent, a water vapor barrier, and a skin protectant, and steares-2 and steares-20 are used as a synthetic emulsifier and a dissolution aid.

In addition, in the composition of the group E, sodium bicarbonate is used as a pH adjusting agent, a pH buffer, a skin protector, and a deodorant, and at the same time, used to generate carbon dioxide by reacting with a vegetable natural organic acid.

<2nd external preparation>

The second external preparation is purified water, xanthan gum, trihydroxystearin, butylene glycol, ammonium laureth sulfate, disodium ethane, menthol, ammonium lauryl sulfate, cocamide M, cetrimonium chloride, sodium lauro Ilglutamate, methylparaben, phenoxyethanol, flavoring, chloride (or Trideces 12), dimethicone and vegetable natural organic acids, wherein steares-2 or steares-20 may be used in place of dimethicone.

And when preparing a second external preparation having the composition as described above, as shown in Table 2 below, each composition is prepared in a predetermined amount by dividing each composition into groups A, B, C, and D (S100), and then the composition of group A first. The solution was completely dissolved using a stirrer rotating at a speed of 200 rpm while being heated to 75 ° C. (S200). Then, the composition of group B and C was again added to the dissolved group A composition in order to use the stirrer. After stirring uniformly (S300), the composition of the group D is slowly added (S500) in a state of cooling to 45 ° C or less (S400).

In the composition of Group A, xanthan gum is a natural thickener, which is used to improve physical properties and feel by dissolving well in water, increasing adhesiveness and viscosity, enhancing emulsification stability, and in addition, a safety agent. Used as binders, binders, foaming agents. In addition, trihydroxystearin is used for vegetable skin conditioning agent, water vapor barrier and thickener, and it is used to smooth skin and supply oil. Butylene glycol is used in cosmetics. It is mainly used as a humectant to keep moisture on the skin.

In addition, in the composition of group B, ammonium laureth sulfate (ALES) is widely used as a shampoo composition as an anionic surfactant, and disodium EDTA is a discoloration of the product as a metal ion blocking agent. It is used to prevent the menthol (menthol) is a substance obtained by distilling or synthesizing the leaves or stems of peppermint, widely used as an additive for adding a refreshing feeling to medicines, sweets, cosmetics and the like.

Ammonium lauryl sulfate is a surfactant and a detergent, and cocamide MEA is an alkylolamide obtained by condensing palm oil fatty acid and an equivalent monoethanolamine, and is mainly composed of a surfactant (bubble accelerator) and Used as a thickener. In addition, cetrimonium chloride is used as a surfactant (emulsifier), antistatic agent, etc., as a disinfectant and antiseptic, which can be applied to the human body.

In addition, sodium lauroyl glutamate is mainly used in shampoos and cosmetics as a hair conditioning agent, methylparaben (methylparaben) is widely used as a bactericidal preservative.

On the other hand, in the composition of the group C, phenoxyethanol (flavoxyethanol) is a flavoring agent, antiseptic preservative, chloride functions as an antistatic agent antiseptic preservative or surfactant, trideceth-12 is a surfactant Function as.

And in the composition of the group D, the vegetable natural organic acid is a function of generating carbon dioxide by reacting with sodium bicarbonate (sodiumbicarbonate) of the E group constituting the first external agent, the vegetable natural organic acid used in the present invention is a wolfberry, A fruit concentrate made by putting natural fruit such as green plum, apple or bokbunja into a container, and fermenting for about 3 months by adding 20% by weight of sugar to 100% by weight of fruit is used. There is a large amount of citric acid which is stable.

The present inventors, when preparing a shampoo composition by mixing the first external preparation and the second external preparation prepared by the above process, the hydroxyl group (-OH) contained in the sodium bicarbonate and vegetable natural organic acid of the first external preparation Citric acid (citric acid), which is one of the polybasic carboxylic acids having a large amount of carbon dioxide is generated by reaction with each other, and as a result, the bubble power when using the shampoo is greatly improved.

Applicant conducted an experiment to check the difference in the degree of bubble generation according to the type of vegetable natural organic acid, the experiment first prepared the first external solvent of the liquid according to the above process, then the wolfberry, green plum, apple and bokbunja After preparing four second external solutions containing the fruit concentrate (vegetable natural organic acid) made by fermentation, these second external solutions and the first external solution are mixed to prepare shampoos, respectively. The amount of bubbles generated was measured, and the measurement results are shown in Table 3 below.

division Fermented Fruit Concentrate (Natural Organic Acid) Wolfberry Fresh plum Citrus Apple Bokbunja pH 5.9 6.3 6.5 6.3 6.5 Bubble amount after shaking five times (ml) 190 180 174 165 158 Bubble amount after 5 minutes (ml) 180 168 158 145 138

As can be seen in Table 3 above, the amount of bubbles after five times and the amount of bubbles after five minutes were relatively higher in the shampoo added with goji berry concentrate than in shampoos containing other fruit concentrates.

In addition, the inventors of the present invention to select the panel of 50 men and women without distinguishing between young and old to examine the usability of the shampoo made by adding the fermented gojija concentrate was confirmed as the most excellent bubble based on the above experiment results After using the shampoo manufactured three times or more, the questionnaire was used to evaluate one's feelings through the questionnaire about the viscosity, spreading, foaming ability, bubble quality, hair feel, cleansing, moisturizing power, and hair gloss. Is shown in Table 4 below.

Classification (frequency%) Very good good usually Bad Very bad Shampoo 16 43 33 8 0 Bubble generation 36 45 18 One 0 Bubble retention 19 72 8 One 0 Cleaning power 42 55 3 0 0

In Table 4 above, it can be seen that most of the panels evaluated positively about the shampoo added with the fermented goji berry concentrate in relation to the evaluation items of viscosity, bubble generation capacity, bubble retention power, and segmentation area.

In addition, the present inventors selected 100 panels of men and women without distinguishing between sexes and youngsters in order to further understand the usability of the shampoo made by adding the fermented goji berry concentrate, and then having these panels use the manufactured shampoo three times or more, Give 5 points for 'very good' and 1 point for 'very bad' through the questionnaire on the viscosity, spreading, bubble creation, bubble quality, hair feel, cleansing, moisturizing, and hair gloss of shampoo Quantification was performed, and the results are shown in Table 5 below.

division Number of evaluators Average Shampoo viscosity 50 2.65 Spreadability 50 2.45 Bubble generation 50 2.5 Air quality 50 1.83 Hair feeling 50 2.54 Cleaning power 50 1.65 Moisturizing 50 1.9 Hair gloss 50 1.85 Average 50 2.35

In the above Table 5, in particular, the viscosity and foaming capacity of the shampoo and hair rating was evaluated above average, from which it can be seen that the external preparation for skin according to the present invention is relatively excellent in viscosity and foaming ability.

Claims (4)

In the shampoo composition used to wash the hair, The composition is a mixture of a first external agent containing sodium bicarbonate and a second external agent containing a vegetable natural organic acid containing citric acid, the citric acid and the sodium bicarbonate in the vegetable natural organic acid react with each other carbon dioxide Shampoo composition excellent in usability and air bubbles, characterized in that to be generated. The method according to claim 1, The vegetable natural organic acid is a shampoo composition excellent in usability and foaming, characterized in that any one selected from fermented wolfberry concentrate, fermented blue plum concentrate, fermented citrus concentrate, fermented apple concentrate, fermented bokbunja concentrate. The method according to claim 1, The first external preparation is a group A containing xanthan gum as purified water and a thickener, Group B comprising ammonium laureth sulfate as a cleaning agent, C group containing fragrance, D group comprising polyquaternium-7, and A shampoo composition having excellent usability and foaming power, comprising an E group containing sodium bicarbonate. The method according to claim 1, The second external preparation is A group containing purified water and butylene glycol, Group B comprising ammonium laureth sulfate as a cleaning agent, C group containing fragrances, A shampoo composition having excellent usability and foaming power, comprising a D group containing purified water and a vegetable natural organic acid.

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