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WO2016096220A1 - Agents décolorants contenant des alcools gras et exempts d'ammoniac et d'huiles minérales - Google Patents

Agents décolorants contenant des alcools gras et exempts d'ammoniac et d'huiles minérales Download PDF

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Publication number
WO2016096220A1
WO2016096220A1 PCT/EP2015/074947 EP2015074947W WO2016096220A1 WO 2016096220 A1 WO2016096220 A1 WO 2016096220A1 EP 2015074947 W EP2015074947 W EP 2015074947W WO 2016096220 A1 WO2016096220 A1 WO 2016096220A1
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WO
WIPO (PCT)
Prior art keywords
weight
peroxodisulfate
agents
ammonia
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2015/074947
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German (de)
English (en)
Inventor
Burkhard Müller
Udo Erkens
Sylvia KERL
Susanne Bietz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of WO2016096220A1 publication Critical patent/WO2016096220A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

Definitions

  • the present invention relates to agents for the oxidative color change in the field of cosmetics, which are particularly suitable for lightening keratinic fibers, especially human hair.
  • the oxidizing agents contained in Blondierstoffn are able to lighten the hair fiber by the oxidative destruction of the hair dye melanin.
  • the use of hydrogen peroxide - optionally with the use of ammonia or other alkalizing agents - as the oxidizing agent alone for the achievement of a stronger Blondier bines usually a mixture of hydrogen peroxide and peroxodisulfate salts and / or Peroxomonosulfatsalzen is used.
  • bleaching agents are usually offered in two separately packaged preparations, which are mixed immediately before use to a finished application preparation.
  • commercial bleaching agents consist of a liquid oxidizing agent preparation and a powder containing solid oxidizing agents.
  • pasty agents may be mixed with a liquid oxidizer formulation, thereby avoiding the problems of dusting during manufacture and mixing. Products with other components are also offered commercially.
  • Pasty bleaching agents usually contain larger amounts of an inert oil, which can lead to stability problems (settling of the solid oxidizing agent from the oil). Even with peroxodisulphates that have not yet completely settled, a concentration gradient can occur within the packaging, so that different portions of the packaging can cause different lightening after mixing. To minimize these problems, high viscosity is desirable.
  • the viscosity of the bleaching paste must be so low that it mixes well and quickly with the liquid oxidizing agent preparation.
  • the resulting blending mixture must also be fluid enough to be easily and evenly applied, but thick enough not to drip off the head or application aids such as paint brushes.
  • the resulting blender mixture should not separate as settling or phase separations are perceived by the customer as a quality defect.
  • hair should not only be lightened, but also dyed at the same time.
  • Bleaching pastes should therefore also be readily miscible with cream-form colorants. Often, these colorants contain direct dyes, so that a homogeneous mixing for a uniform dyeing and whitening result is a prerequisite.
  • WO 2009/134875 A1 describes bleaching agents containing persulfate salts and an oil gel, which in turn is composed of oil (s) and certain polymers.
  • Desirable properties of the composition of this invention are resistance to settling and phase separation.
  • EP 1 034 777 A1 discloses compositions for brightening keratinic fibers which contain at least two separately packaged preparations (A) and (B), which are mixed to form an application mixture immediately before use, wherein the preparations (A) are oil-based and polymer (e) which form oleo or lipogels.
  • preparations (A) are oil-based and polymer (e) which form oleo or lipogels.
  • e polymer which form oleo or lipogels.
  • mixtures with natural polymers, such as xanthan are disclosed.
  • DE 10 2013 217 204 discloses agents for whitening keratinic fibers, which, based on their weight - 20 to 75 wt .-% 01 (e); 0.05 to 5 wt .-% xanthan, 1 to 70 wt .-% peroxodisulfate (s) and 1 to 15 wt .-% Cetearylakohol included. These agents are already stable against oil separation, but still need to be improved with regard to their homogeneous miscibility with colorant-containing formulations.
  • the object of the present invention was to further improve the properties of blonding agents.
  • the storage stability should be increased, whereby not only the physical stability (settling, phase separation), but also the chemical stability (degradation of persalts) should be improved.
  • miscibility with dye-containing formulations should be improved.
  • the present invention in a first embodiment means for lightening keratinischer fibers containing - based on their weight - a) ⁇ 0, 1 wt .-% ammonia;
  • peroxodisulfate from 1 to 70% by weight of peroxodisulfate (e) from the group of sodium peroxodisulfate and / or potassium peroxodisulfate,
  • compositions according to the invention are primarily suitable for whitening keratin fibers, in principle there is nothing to prevent their use in other fields as well.
  • the agents according to the invention preferably contain only very little or no ammonia, preferred agents being characterized in that they contain 0 to ⁇ 0.1% by weight, preferably 0 to ⁇ 0.05% by weight, more preferably 0 to ⁇ 0.01 wt .-%, particularly preferably 0 to ⁇ 0.001 wt .-% and in particular 0 wt .-% ammonia. Due to the further composition of the compositions according to the invention, it is possible to provide the miscibility and storage stability without the use of oils from the group of alkanes.
  • paraffins with the disadvantages mentioned can therefore be dispensed with, so that preferred agents are characterized in that they contain 0 to ⁇ 0.1% by weight, preferably 0 to ⁇ 0.05% by weight, more preferably 0 to ⁇ 0.01 wt .-%, particularly preferably 0 to ⁇ 0.001 wt .-% and in particular 0 wt .-% paraffin oil (s).
  • the inventive compositions contain 5 to 40 wt .-% at 25 ° C liquid (s) fatty alcohol (s). It is possible to use individual substances or mixtures of substances from this group, the quantities always referring to those fatty alcohols which are liquid at 25 ° C. and normal pressure (1013.25 mbar). If the fatty alcohol mixtures contain other ingredients which are solid under these conditions, their quantities are not included in the total amount.
  • Agents which are particularly preferred according to the invention are characterized in that they contain from 7.5 to 37.5% by weight, preferably from 10 to 35% by weight, more preferably from 12.5 to 34% by weight, particularly preferably from 15 to 33% by weight. % and in particular 16 to 32 wt .-% at 25 ° C liquid (s) fatty alcohol (s) from the group hexyldecanol and / or octyldodecanol included.
  • agents are preferred according to the invention which contain from 1.5 to 12.5% by weight, preferably from 2 to 10% by weight, more preferably 3, 5 to 8 wt .-%, particularly preferably 4 to 7 wt .-% and in particular 5 to 6.5 wt .-% Cetearyalkohol.
  • the preparations according to the invention contain 1 to 70% by weight of peroxodisulfate (s) from the group of sodium peroxodisulfate and / or potassium peroxodisulfate, with preferred agents according to the invention - based on their weight - 2.5 to 65 wt .-%, preferably 5 to 60 wt .-%, more preferably 7.5 to 55 wt .-%, particularly preferably 10 to 50% by weight and in particular 12.5 to 40 wt .-% peroxodisulfate (s) from the group sodium peroxodisulfate and / or Contain potassium peroxodisulfate.
  • peroxodisulfate from the group of sodium peroxodisulfate and / or potassium peroxodisulfate
  • the weight ratio of potassium peroxodisulfate to ammonium peroxodisulfate is> 2, preferably> 5, more preferably> 10, even more preferably> 15 and especially> 20. This weight ratio is determined by the weight% Amount of potassium peroxodisulfate by the sum of the wt .-% - amounts of ammonium peroxodisulfate divided.
  • Agents preferred according to the invention are characterized in that the weight ratio of potassium peroxodisulfate present in the medium to ammonium peroxodisulfates contained in the composition is> 10: 1, preferably> 12.5: 1, more preferably> 15: 1, particularly preferably> 17.5: 1 and in particular> 20: 1.
  • Extremely preferred agents according to the invention contain 0 to ⁇ 2.5% by weight, preferably 0 to ⁇ 1% by weight, more preferably 0 to ⁇ 0.5% by weight, particularly preferably 0 to ⁇ 0.1% by weight. % and in particular 0 wt .-% ammonium peroxodisulfate.
  • the bleaching compositions according to the invention also contain metasilicate (s) as alkalizing agent.
  • metasilicate s
  • These are preferably selected from sodium metasilicate, potassium metasilicate, magnesium metasilicate and / or mixtures thereof. Particular preference is given to using sodium metasilicate, so that preferred agents according to the invention comprise 1.1 to 14% by weight, preferably 1.2 to 13% by weight, more preferably 1.3 to 12% by weight, more preferably 1.4% to 1 1 wt .-% and in particular 1, 5 to 10 wt .-% sodium metasilicate.
  • alkalizing agents which can be used according to the invention are preferably selected from sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, sodium phosphate, potassium phosphate, sodium carbonate and potassium carbonate. Particularly preferred are sodium hydroxide and / or potassium hydroxide.
  • suitable alkalizing agents which can be used according to the invention are preferably selected from alkanolamines of primary, secondary or tertiary amines having a C 2 -C 6 -alkyl basic body which carries at least one hydroxyl group.
  • alkanolamines are selected from the group formed from 2-aminoethane-1-ol (monoethanolamine), 3-aminopropan-1-ol, 4-aminobutan-1-ol, 5-aminopentan-1-ol, 1 -Aminopropan-2-ol (monoisopropanolamine), 1-aminobutan-2-ol, 1-aminopentan-2-ol, 1-aminopentan-3-ol, 1-aminopentan-4-ol, 2-amino-2-methyl propanol, 2-amino-2-methylbutanol, 3-amino-2-methylpropan-1-ol, 1-amino-2-methylpropan-2-ol, 3-aminopropane-1,2-diol, 2-amino 2-methylpropane-1, 3-diol, 2-amino-2-ethyl-1, 3-propanediol, ⁇ , ⁇ -dimethyl-ethanolamine, methylgluc
  • the basic amino acids which can be used as alkalizing agents according to the invention are preferably selected from the group consisting of L-arginine, D-arginine, D / L-arginine, L-lysine, D-lysine, D / L-lysine, L-ornithine, D-ornithine, D / L-ornithine, L-histidine, D-histidine and / or D / L-histidine.
  • L-arginine, D-arginine and / or D / L-arginine as an alkalizing agent in the context of the invention.
  • compositions according to the invention may contain, in addition to consistency, one or more oils, these oil (s) preferably being liquid under normal conditions.
  • Non-volatile oils are oils which at 20 ° C and an ambient pressure of 1013 hPa a Vapor pressure of less than 2.66 Pa (0.02 mm Hg). Volatile oils are understood to mean those oils which, at 20 ° C. and an ambient pressure of 1013 hPa, have a vapor pressure of 2.66 Pa - 40,000 Pa (0.02 mm - 300 mm Hg), preferably 10 - 12,000 Pa (0, 1). 90 mm Hg), more preferably 13-3000 Pa, most preferably 15-500 Pa.
  • Volatile cosmetic oils are usually selected from cyclic silicone oils having the INCI name Cyclomethicone.
  • the INCI name cyclomethicones is understood in particular as meaning cyclotrisiloxane (hexamethylcyclotrisiloxane), cyclotetrasiloxane (octamethylcyclotetrasiloxane), cyclopentasiloxane (decamethylcyclopentasiloxane) and cyclohexasiloxane (dodecamethylcyclohexasiloxane).
  • These oils have a vapor pressure of about 13-15 Pa at 20 ° C.
  • a preferred cyclomethicone substitute according to the invention is a mixture of Ci3-Ci6 isoparaffinen, C12 - Cw isoparaffins and C13 - cis alkanes whose viscosity is 25 ° C in the range of 2 to 6 mPas and which has a vapor pressure at 20 ° C in the range of 10 to 150 Pa, preferably 100 to 150 Pa has.
  • Such a mixture is z. B. under the name SiClone SR-5 from Presperse Inc. available.
  • esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated Preference is given to esters of linear or branched saturated fatty alcohols having 2 to 5 carbon atoms with linear or branched saturated or unsaturated fatty acids having 10 to 18 carbon atoms which may be hydroxylated.
  • Preferred examples thereof are isopropyl palmitate, isopropyl stearate, isopropyl myristate, 2-hexyldecyl stearate, 2-hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate.
  • isopropyl isostearate isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate , n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, ethylene glycol dioleate
  • isopropyl esters of C 12 -carboxylic acids in particular the use of isopropyl myristate, and more preferably mixtures of isopropyl myristate with Cio-Ci3-isoparaffin mixtures, the latter preferably having a vapor pressure at 20 ° C of 10-400 Pa, proved.
  • oils mentioned some have proven to be particularly suitable because they are excellently compatible with the other ingredients of the invention.
  • Agents preferred according to the invention are characterized in that they additionally contain 0.5 to 20% by weight, preferably 1 to 19% by weight, more preferably 2.5 to 18% by weight, particularly preferably 3.5 to 17% by weight.
  • oil (s) from the group of alkyl benzoates, isopropyl palmitate, isohexadecane, isododecane, isononyl isononanoate.
  • Extremely preferred agents additionally contain 0.5 to 20 wt .-%, preferably 1 to 19 wt .-%, more preferably 2.5 to 18 wt .-%, particularly preferably 3.5 to 17 wt .-% and in particular 5 to 15% by weight of isopropyl palmitate.
  • compositions of the invention may additionally contain at least one further bleaching enhancer other than the inorganic persalts.
  • Bleach amplifiers which can be used are compounds which, under perhydrolysis conditions, give aliphatic peroxocarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
  • polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxo-hexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2, 5-diacetoxy-2,5-dihydrofuran.
  • TAED tetraacety
  • a second subject of the invention is a process for the color change of keratinous fibers in which at least two separately packaged preparations (A) and (B), of which preparation (A) at least one persulfate and preparation (B) contains at least one oxidizing agent, to one Application mixture are mixed, this is applied to the fibers and rinsed again after an exposure time, characterized in that preparation (A)
  • peroxodisulfate from 1 to 70% by weight of peroxodisulfate (e) from the group of sodium peroxodisulfate and / or potassium peroxodisulfate,
  • the ready-to-use agents are prepared immediately before use on the hair by mixing the two preparations (A) and (B) and optionally a third preparation (C) and / or other preparations.
  • a third preparation C
  • ready-to-use resources consisting of more than two Preparations are mixed to form a finished application mixture, it may be irrelevant whether initially two preparations are mixed together and then the third preparation is added and mixed in, or whether all preparations are brought together and then mixed.
  • the mixing can be done by stirring in a bowl or a cup or by shaking in a sealable container.
  • the term "immediate” is to be understood as a period of a few seconds to one hour, preferably up to 30 minutes, in particular up to 15 minutes.
  • compositions according to the invention are used in a process for lightening keratinic fibers, in particular human hair, in which the composition is applied to the keratin-containing fibers at a temperature of from room temperature to 45 ° C. for a period of from 10 to 60 minutes on the fiber and then rinsed with water or washed out with a shampoo.
  • the exposure time of the ready-to-use brightening agents is preferably from 10 to 60 minutes, in particular from 15 to 50 minutes, particularly preferably from 20 to 45 minutes.
  • the heat supply can be done by an external heat source, such as with the help of a hot air blower, as well as, especially in a hair lightening on the living subjects, by the body temperature of the subject. In the latter option, usually the brightening lot is covered with a hood.
  • An exposure phase at room temperature is also according to the invention.
  • the temperature during the exposure time is preferably between 20 ° C and 40 ° C, in particular between 25 ° C and 38 ° C.
  • the brightening agents give good bleaching and brightening results even at physiologically compatible temperatures of below 45 ° C.
  • the remaining whitening preparation is rinsed out of the hair with water or a cleaning agent.
  • a cleaning agent commercially available shampoo can be used as the cleaning agent, in which case the cleaning agent can be dispensed with, in particular, and the rinsing-off process can be carried out with tap water if the brightening agent has a carrier which is highly surfactant-containing.
  • the preferred embodiments of the first subject of the invention also apply mutatis mutandis for the second subject of the invention.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des agents qui contienent, rapporté à son poids, ≤ 0,1 % en poids d'ammoniac; ≤ 0,1 % en poids d'huile(s) de paraffine, 5 à 40 % en poids d'au moins un alcool gras liquide à 25 °C), 1 à 70 % en poids de péroxodisulfate(s) du groupe du péroxodisulfate de sodium et/ou du péroxodisulfate de potassium et 1 à 15 % en poids de métasilicate(s), lesditsprésentant une meilleure stabilité au stockage, lesdits agents se caractérisant en ce que outre le fait que leur stabilité physique (décantation, séparation de phases) est améliorée, leur stabilité chimique (décomposition des persels) est elle aussi améliorée. La miscibilité avec des formulations contenant des colorants est en outre nettement améliorée.
PCT/EP2015/074947 2014-12-16 2015-10-28 Agents décolorants contenant des alcools gras et exempts d'ammoniac et d'huiles minérales Ceased WO2016096220A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102014225989.4 2014-12-16
DE102014225989.4A DE102014225989A1 (de) 2014-12-16 2014-12-16 Ammoniak- und mineralölfreie Blondiermittel mit Fettalkoholen

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Publication Number Publication Date
WO2016096220A1 true WO2016096220A1 (fr) 2016-06-23

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PCT/EP2015/074947 Ceased WO2016096220A1 (fr) 2014-12-16 2015-10-28 Agents décolorants contenant des alcools gras et exempts d'ammoniac et d'huiles minérales

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DE (1) DE102014225989A1 (fr)
WO (1) WO2016096220A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2593569A (en) * 2019-12-09 2021-09-29 Henkel Ag & Co Kgaa Dust-reduced ammonium-free bleaching powder

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202009008383U1 (de) * 2009-06-15 2009-08-27 Szaidel Cosmetic Gmbh Kosmetische Zubereitung zum Blondieren von keratinischen Fasern, insbesondere von menschlichen Haaren
WO2009134875A2 (fr) * 2008-04-29 2009-11-05 Hair Systems, Inc. Composition et procédé pour un produit de décoloration sous forme de crème

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19909661A1 (de) 1999-03-05 2000-09-07 Wella Ag Mittel zum Entfärben oder Blondieren von Haaren
DE102013217204A1 (de) 2013-08-28 2015-03-05 Henkel Ag & Co. Kgaa "Blondiermittel mit Fettalkoholen"

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009134875A2 (fr) * 2008-04-29 2009-11-05 Hair Systems, Inc. Composition et procédé pour un produit de décoloration sous forme de crème
DE202009008383U1 (de) * 2009-06-15 2009-08-27 Szaidel Cosmetic Gmbh Kosmetische Zubereitung zum Blondieren von keratinischen Fasern, insbesondere von menschlichen Haaren

Non-Patent Citations (1)

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Title
DATABASE GNPD [online] MINTEL; November 2002 (2002-11-01), L`OREAL: "Highlights Kit", XP002752384, Database accession no. 176211 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2593569A (en) * 2019-12-09 2021-09-29 Henkel Ag & Co Kgaa Dust-reduced ammonium-free bleaching powder
GB2593569B (en) * 2019-12-09 2022-05-04 Henkel Ag & Co Kgaa Dust-reduced ammonium-free bleaching powder

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