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WO2016082525A1 - Device for moving small heat insulating plate at bottom of polycrystalline silicon ingot furnace and polycrystalline silicon ingot furnace - Google Patents

Device for moving small heat insulating plate at bottom of polycrystalline silicon ingot furnace and polycrystalline silicon ingot furnace Download PDF

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Publication number
WO2016082525A1
WO2016082525A1 PCT/CN2015/081431 CN2015081431W WO2016082525A1 WO 2016082525 A1 WO2016082525 A1 WO 2016082525A1 CN 2015081431 W CN2015081431 W CN 2015081431W WO 2016082525 A1 WO2016082525 A1 WO 2016082525A1
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insulation board
thermal insulation
polycrystalline silicon
silicon ingot
small thermal
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Chinese (zh)
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吕铁铮
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    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B35/00Apparatus not otherwise provided for, specially adapted for the growth, production or after-treatment of single crystals or of a homogeneous polycrystalline material with defined structure

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  • the invention relates to a polycrystalline silicon ingot furnace, in particular to a small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, and a polycrystalline silicon ingot furnace comprising the bottom small thermal insulation board movable device.
  • the growth of silicon crystals is generally divided into three methods: polycrystalline ingot, single crystal pulling and zone melting.
  • the solar grade crystalline wafer industry continues to mature and mature, and silicon wafers are used as The price of raw materials has gradually fallen back in rationality, and it has also caused the continuous compression of the profit margin of wafer manufacturers.
  • Increasing the quality of silicon wafers and reducing processing costs have become a problem for all solar wafer manufacturers.
  • the crystalline silicon photovoltaic power generation industry chain includes processes from silicon-silicon-battery-component-systems, in which silicon wafers are produced mainly by crystal growth and crystal cutting, and crystal growth is fundamental to manufacturing high-quality silicon wafers. .
  • the difference between the polycrystalline ingot and the single crystal pulling method is that the pulling growth has a seed crystal, the subsequent seeding, the equal diameter and the like are all performed based on the seed crystal, so the crystal has a certain crystal orientation, and the polycrystal Nucleation in an ingot is a process of random nucleation according to thermodynamics, and the structure of the polycrystalline ingot is different every time.
  • Different crystal orientations of silicon materials have different ability to recombine carriers and accept impurities. Among them, the ⁇ 110> and ⁇ 112> twin structures of silicon are precipitated due to dense atomic arrangement and low interface energy. Less, and the carrier recombination is very weak, so the minority carrier lifetime (ie carrier lifetime) is relatively high, this part is very suitable for the base wafer of the battery.
  • the polycrystalline ingot is a typical melt solidification growth method: the polycrystalline silicon raw material is heated and melted into a melt at a high temperature, and then cooled by the bottom, and the crystal is grown by upward directional solidification, and the growth process is relatively slow, after the growth is completed.
  • the crystal is annealed and cooled to normal temperature. Studies have shown that in order to form suitable silicon germanium structures of ⁇ 110> and ⁇ 112>, it is necessary to form a certain degree of subcooling in the process of crystal nucleation, usually between 10 and 100 K below the melting point.
  • G5, G6, and G7 refer to the weight of the silicon ingot, respectively.
  • the yield of G6 and G7 is 44% and 96% higher than that of G5, respectively.
  • the weight of the ingot after the transformation was increased by 44% and 96% respectively.
  • the heat dissipation capacity at the bottom of the heat field is also required to be improved accordingly, and the heat dissipation capability of the existing heat insulating cage lifting technology is only slightly increased, so that the solidification speed in the ingot casting process is greatly reduced.
  • the solidification time of the G5 ingot is about 25 hours, but the solidification time of the G6 ingot is about 40 hours, and the solidification time of the G7 ingot is longer.
  • the bottom insulation boards of G5, G6, and G7 are all one-piece boards.
  • the heat at the bottom of the crucible is hard to radiate out of the heat at the edge of the crucible, causing the solid-liquid interface at the time of crystal growth to be slightly concave and dissolved. Impurities in the silicon melt will be deposited in the middle, so that the quality of the crystal grown is low, and the efficiency of the cut wafer is also low.
  • the latent heat of crystallization is huge. According to the current heat dissipation method of the insulating cage, it is difficult to effectively emit the latent heat of crystallization. .
  • the technical problem to be solved by the present invention is to overcome the above-mentioned defects existing in the prior art, and to provide a small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, comprising a polycrystalline silicon ingot furnace having the bottom small thermal insulation plate movable device, in the long crystal
  • a small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, comprising a polycrystalline silicon ingot furnace having the bottom small thermal insulation plate movable device, in the long crystal
  • it also provides a vertical radiant heat dissipation channel directly below the , so that not only the initial cooling of the crystal growth, but also the solid-liquid during the growth process.
  • the interface has a beneficial micro-convex shape, and the heat dissipation capability of the coagulation block is strengthened. When the directional solidification is performed, the speed is fast and the quality of the crystal product is high.
  • a small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace comprising a small thermal insulation board at the bottom, a support rod, a telescopic tube, a lifting device; the bottom portion is made with a nut and a lower nut a small insulation board is fixed on the upper part of the support rod; a lower part of the support rod extends to the bottom of the telescopic tube; an upper end of the extension tube is connected to the furnace body, and a lower end of the extension tube is connected with the lifting device; under the control of the lifting device
  • the bottom small insulation board can move up and down along the axial direction of the support rod.
  • the lifting device is composed of a lifting rod and a servo motor, and the lifting rod can move up and down along the servo motor, thereby driving the bottom of the upper part of the supporting rod to move under the small thermal insulation board.
  • the lifting device can also be replaced by a C-shaped card, and a C-shaped card of a corresponding height is configured according to different lifting heights of the bottom small thermal insulation board.
  • the telescopic tube is sealed and welded by a bellows and a quick-change joint; a sealing ring is arranged at an upper end of the telescopic tube and a furnace body, and the clamp can be sealed and fixed; the lower end of the telescopic tube is connected with the blind plate; The sealing ring can be sealed and fixed with a clamp.
  • the support rod is one of a molybdenum rod, a tungsten rod, a mast, a graphite rod or a carbon-carbon composite rod.
  • the bottom small thermal insulation board has a rectangular or inverted T-shaped cross section
  • the bottom large thermal insulation board has a rectangular or inverted T-shaped cross section corresponding to the matching hole.
  • the bottom small thermal insulation board has a circular or rectangular top view
  • the bottom large thermal insulation board has a circular or rectangular shape corresponding to the top view of the matching hole.
  • the separation distance between the bottom small thermal insulation board and the bottom large thermal insulation board is 10 to 300 mm.
  • the telescopic tube is made of a temperature resistant stainless steel, specifically 316L.
  • the upper nut, the lower nut and the backing plate are made of a graphite material or a carbon-carbon composite material.
  • the method for using the small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace when the silicon material is melted, the bottom small thermal insulation board and the bottom large thermal insulation board are in a closed state; when the melting is completed and enters the long crystal stage, the lifting device is started to make the bottom The small thermal insulation board is separated from the large thermal insulation board at the bottom to accelerate the growth rate of the silicon crystal; when the crystal growth enters the annealing stage, the lifting device is started to close the small thermal insulation board at the bottom and the large thermal insulation board at the bottom until the silicon ingot is cooled out.
  • the invention has the following advantages:
  • the present invention accelerates the cooling of the core of the coagulation block by providing a small thermal insulation plate movable device at the bottom of the polycrystalline silicon ingot furnace, thereby improving the heat dissipation capability of the coagulation block, thereby improving the cooling crystallization rate of the silicon melt in the crucible. Improve the efficiency of directional solidification, shorten the production cycle and reduce the production cost;
  • FIG. 1 is a schematic structural view of a small thermal insulation plate movable device at the bottom of the polycrystalline silicon ingot furnace of the present invention when the silicon material is melted;
  • FIG. 2 is FIG.
  • Part A Partially enlarged view of Part A
  • FIG. 3 is a schematic structural view of a telescopic tube in a movable device for a small thermal insulation board at the bottom of a polycrystalline silicon ingot furnace according to the present invention
  • FIG. 4 is a schematic structural view of a small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace of the present invention
  • Figure 5 is a schematic view showing the structure of the lifting device of Figure 4 replaced with a C-shaped card
  • Figure 6 is a partial enlarged view of a portion B of Figure 5;
  • Figure 7 is a top view of the small thermal insulation board at the bottom of the rectangle in Figure 1, Figure 4 or Figure 5;
  • Figure 8 is a top view of the small bottom thermal insulation board of Figure 1, Figure 4 or Figure 5;
  • Figure 9 is a schematic view showing the inverted T-shaped cross section of the bottom small insulation board when the silicon material is melted
  • Figure 10 is a schematic view showing the inverted T-shaped cross section of the bottom small thermal insulation plate when the crystal is grown
  • Figure 11 is a top plan view of the rectangular bottom insulation board of Figure 9 or Figure 10;
  • Figure 12 is a top plan view of the circular bottom small insulation board of Figure 9 or Figure 10;
  • 1- bottom large insulation board 2- bottom small insulation board, 3-support rod, 4-upper nut, 5-pad, 6-telduct, 7-lifting device, 8-lifting rod, 9-servo motor ,10-seal ring,11-clamp,12-blind plate,13-corrugated pipe,14-fast change joint,15-separation distance between small insulation board and bottom large insulation board, 16-lower nut, 17-solid Liquid interface, 18-low furnace body, 19-upper furnace, 20-C-shaped card.
  • the embodiment comprises a bottom small thermal insulation board 2, a support rod 3, a telescopic tube 6, and a lifting device 7; the bottom small thermal insulation board 2 is fixed on the upper part of the support rod 3 by the upper nut 4 and the lower nut 16; the lower part of the support rod 3 is worn
  • the upper end of the telescopic tube 6 is connected to the furnace body, and the lower end of the telescopic tube 6 is connected to the lifting device 7; under the control of the lifting device 7, the bottom small thermal insulation board 2 can move up and down along the axial direction of the support rod 3. (As shown in Figure 1);
  • the lifting device 7 is composed of a lifting rod 8 and a servo motor 9.
  • the lifting rod 8 can move up and down along the servo motor 9, thereby driving the bottom small thermal insulation board 2 on the upper part of the supporting rod 3 to move up and down.
  • the bellows 6 is sealed and welded by the bellows 13 and the quick-change joint 14; the upper end of the bellows 6 is connected with the furnace body with a sealing ring 10, which can be sealed and fixed by the clamp 11; the lower end of the telescopic tube 6 is connected with the blind plate 12 A sealing ring 10 is provided, which can be sealed and fixed by the clamp 11. (as shown in Figure 2 and Figure 3);
  • a backing plate 5 is further disposed between the bottom small thermal insulation board 2 and the lower nut 16. (as shown in Figure 1, Figure 4, Figure 5, Figure 9 and Figure 10);
  • the support rod 3 is a molybdenum rod.
  • the bottom small thermal insulation board 2 has a rectangular cross section and is also rectangular in plan view (as shown in FIG. 7), and the bottom large thermal insulation board 1 has a rectangular cross section corresponding to the matching hole.
  • the telescopic tube 6 is made of a temperature-resistant stainless steel, specifically 316L.
  • the upper nut, lower nut and backing plate are made of graphite material.
  • the bottom small thermal insulation board 2 and the bottom large thermal insulation board 1 are in a closed state (as shown in FIG. 1); when the melting is completed and enters the long crystal stage, the lifting device 7 is activated to make the bottom small thermal insulation board 2 and the bottom. Large insulation board 1 is separated and separated The distance 15 is 10mm, which accelerates the crystal growth rate of the silicon crystal; and the solid-liquid interface 17 is slightly convex (as shown in FIG. 4); when the crystal growth enters the annealing stage, the lifting device 7 is activated to make the bottom small thermal insulation board 2 The bottom large thermal insulation board 1 is in a closed state until the silicon ingot is cooled out of the furnace.
  • the use of the polycrystalline silicon ingot furnace bottom small thermal insulation plate movable device to produce the silicon ingot can increase the solidification rate of the silicon melt inside the crucible, thereby accelerating the growth of the ingot, increasing the ingot production, and reducing the electricity cost of the ingot. .
  • the weight of the ingot is increased from 500 kg to 800 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 40 hours, and the total The process time is 75 hours; and with the small thermal insulation plate moving device of the polycrystalline silicon ingot furnace of the invention, the crystal growth time is shortened to 30 hours, and the total process time is shortened to 65 hours. Since the power is kept constant at 60-66 kW during the growth period, each ingot can save about 600-660 degrees of power consumption, and the production efficiency is increased by about 13%-15%. At the same time, the ingot yield is increased by about 1%, and 300 wafers/ingot of silicon wafers can be produced. The current polycrystalline silicon wafer is 6.5 yuan/piece, which increases the income by 1950 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.8% to 17.9%).
  • the support rod 3 is a tungsten rod;
  • the bottom small insulation board 2 has a rectangular cross section and a circular shape in plan view (as shown in FIG. 8 ), and the bottom large insulation board 1 corresponds to the matching hole.
  • the cross section is circular; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 60 mm.
  • Example 1 The same as Example 1.
  • the weight of the ingot is increased from 500 kg to 800 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 40 hours, and the total The process time is 75 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 29 hours, and the total process time is shortened to 64 hours. Since the power is kept constant at 60-66 kW during the growth period, each ingot can save about 660-726 degrees of power consumption, and the production efficiency is increased by about 14%-15%.
  • the ingot yield is increased by about 1.2%, and the wafer can be produced in a total of 360 pieces/ingot.
  • the current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 2340 yuan.
  • the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.8% to 17.9%).
  • the support rod 3 is a mast; the upper nut 4, the lower nut 16 and the back plate 5 are made of carbon-carbon composite material; the lifting device 7 is replaced by a C-shaped card 20, when When the melting is completed and the crystal growth stage is entered, the bottom small thermal insulation board 2 is separated from the bottom large thermal insulation board 1 by the C-shaped card 20, and the separation distance 15 is 100 mm (as shown in Figs. 5 and 6).
  • Example 1 the support rod 3 is a mast; the upper nut 4, the lower nut 16 and the back plate 5 are made of carbon-carbon composite material; the lifting device 7 is replaced by a C-shaped card 20, when When the melting is completed and the crystal growth stage is entered, the bottom small thermal insulation board 2 is separated from the bottom large thermal insulation board 1 by the C-shaped card 20, and the separation distance 15 is 100 mm (as shown in Figs. 5 and 6).
  • Example 1 The same as Example 1.
  • the weight of the ingot is increased from 500 kg to 1200 kg.
  • the crystal growth time takes about 52 hours, and the total process time is 90 hours; and the crystal growth time of the polysilicon ingot furnace bottom small thermal insulation board movable device is adopted. Shortened to 42 hours and the total process time was reduced to 81 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 700-750 degrees of power consumption, and the production efficiency is increased by about 10%-13%.
  • the ingot yield is increased by about 1%, and 450 wafers/ingot of silicon wafer can be produced.
  • the current polycrystalline silicon wafer is 6.5 yuan/piece, which increases the income by 2,925 yuan.
  • the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).
  • the support rod 3 is a graphite rod;
  • the bottom small thermal insulation board 2 has an inverted T-shaped cross section and a rectangular shape in plan view (as shown in FIG. 11), and the bottom large thermal insulation board 1 is matched.
  • the cross section of the hole is inverted T-shaped; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 180 mm.
  • Example 1 The same as Example 1.
  • the weight of the ingot is increased from 800 kg to 1200 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 52 hours, and the total The process time is 92 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 41 hours, and the total process time is shortened to 82 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 770-825 degrees of power consumption, and the production efficiency is increased by about 11%-15%.
  • the ingot yield is increased by about 1.1%, and the wafer can be produced in a total of 500 pieces/ingot.
  • the current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 3,250 yuan.
  • the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).
  • the support rod 3 is a carbon-carbon composite rod;
  • the bottom small insulation board 2 has an inverted T-shaped cross section and a circular shape in a plan view (as shown in FIG. 12), and the bottom portion is large.
  • the cross section of the heat insulating plate 1 corresponding to the matching hole is inverted T-shaped; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 300 mm.
  • Example 1 The same as Example 1.
  • the weight of the ingot is increased from 800 kg to 1200 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 52 hours, and the total The process time is 92 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 40 hours, and the total process time is shortened to 82 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 840-900 degrees of power consumption, and the production efficiency is increased by about 12%-15%.
  • the ingot yield is increased by about 1.1%, and the wafer can be produced in a total of 500 pieces/ingot.
  • the current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 3,250 yuan.
  • the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).

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  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
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  • Silicon Compounds (AREA)
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Abstract

Provided are a device for moving a small heat insulating plate at the bottom of a polycrystalline silicon ingot furnace and a polycrystalline silicon ingot furnace. The moving device comprises a small bottom heat insulating plate (2), a support rod (3), a telescopic tube (6), and a lifting device (7); the small bottom heat insulating plate (2) is fixed to the upper part of the support rod (3) using an upper nut (4) and a lower nut (16); the lower part of the support rod (3) extends to the bottom of the telescopic tube (6); the upper end of the telescopic tube (6) is connected to the furnace body, and the lower end of the telescopic tube (6) is connected to the lifting device (7); and the small bottom heat insulating plate (2) can move upward and downward under the control of the lifting device (7). The above-mentioned structure achieves: when the crystal growth begins inside the furnace, the small bottom heat insulating plate (2) moves downward to be separated from a large bottom heat insulating plate (1), which quickens the cooling of a core of a coagulation enhancement block, such that the cooling crystallization rate of a silicon melt inside a crucible can be improved, and in addition, the silicon melt forms a considerable degree of supercooling to improve the quality of the polycrystalline silicon ingot.

Description

一种多晶硅铸锭炉底部小保温板活动装置及多晶硅铸锭炉Small heat insulation board movable device and polysilicon ingot furnace at the bottom of polycrystalline silicon ingot furnace 技术领域:Technical field:

本发明涉及一种多晶硅铸锭炉,尤其是涉及一种多晶硅铸锭炉底部小保温板活动装置,及包括所述底部小保温板活动装置的多晶硅铸锭炉。The invention relates to a polycrystalline silicon ingot furnace, in particular to a small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, and a polycrystalline silicon ingot furnace comprising the bottom small thermal insulation board movable device.

背景技术:Background technique:

硅晶体的生长,一般分为多晶铸锭,单晶提拉以及区熔生长三种方法,随着晶体硅光伏产品的大规模应用,太阳能级晶体硅片产业的不断发展成熟,硅片作为原材料,其价格逐渐在理性的回落,同时也造成了硅片生产厂家利润空间的不断压缩。提高硅片质量,降低加工成本成为摆在所有太阳能硅片生产厂家面前的问题。晶体硅光伏发电的产业链包含从硅料-硅片-电池-组件-系统的过程,其中硅片的生产主要由晶体生长及晶体切割两大块,而晶体生长是制造高质量硅片的根本。在晶体硅光伏发电中,多晶定向凝固由于成本低,产量大,逐渐成为硅片生产的主流技术,但是由于其存在的晶体缺陷,杂质等因素,使得多晶电池的转换效率始终和单晶电池有一定的差距。改进多晶铸锭的生长方法,已经成为当前多晶硅片改进的主要方向。多晶铸锭与单晶提拉方法的不同之处在于,提拉生长拥有子晶,后续引晶,等径等步骤都是基于子晶来完成,所以晶体具有一定的晶向,而多晶铸锭中成核是一个根据热力学随机成核的过程,多晶硅锭的结构每次都不尽相同。硅材料的不同晶向对载流子的复合能力以及杂质缺陷的接受能力不同,其中硅的〈110〉和〈112〉的孪晶结构由于原子排列密集,界面能低等原因,杂质缺陷沉淀得少,且载流子的复合很弱,因此少子寿命(即载流子寿命)相对较高,该部分非常适合用来做电池的基底硅片。The growth of silicon crystals is generally divided into three methods: polycrystalline ingot, single crystal pulling and zone melting. With the large-scale application of crystalline silicon photovoltaic products, the solar grade crystalline wafer industry continues to mature and mature, and silicon wafers are used as The price of raw materials has gradually fallen back in rationality, and it has also caused the continuous compression of the profit margin of wafer manufacturers. Increasing the quality of silicon wafers and reducing processing costs have become a problem for all solar wafer manufacturers. The crystalline silicon photovoltaic power generation industry chain includes processes from silicon-silicon-battery-component-systems, in which silicon wafers are produced mainly by crystal growth and crystal cutting, and crystal growth is fundamental to manufacturing high-quality silicon wafers. . In crystalline silicon photovoltaic power generation, polycrystalline directional solidification has become a mainstream technology for wafer production due to its low cost and large output. However, due to its crystal defects, impurities and other factors, the conversion efficiency of polycrystalline cells is always single crystal. There is a certain gap in the battery. Improving the growth method of polycrystalline ingots has become the main direction of the current improvement of polycrystalline silicon wafers. The difference between the polycrystalline ingot and the single crystal pulling method is that the pulling growth has a seed crystal, the subsequent seeding, the equal diameter and the like are all performed based on the seed crystal, so the crystal has a certain crystal orientation, and the polycrystal Nucleation in an ingot is a process of random nucleation according to thermodynamics, and the structure of the polycrystalline ingot is different every time. Different crystal orientations of silicon materials have different ability to recombine carriers and accept impurities. Among them, the <110> and <112> twin structures of silicon are precipitated due to dense atomic arrangement and low interface energy. Less, and the carrier recombination is very weak, so the minority carrier lifetime (ie carrier lifetime) is relatively high, this part is very suitable for the base wafer of the battery.

其中多晶铸锭为典型的熔体固化的生长方法:多晶硅原料先在高温下被加热熔化成熔体,然后通过底部冷却,向上定向凝固开始晶体生长,其生长过程相对缓慢,在生长完成后,晶体进行退火冷却到常温。研究显示,为了形成适宜的〈110〉和〈112〉的硅孪晶结构,需要在结晶成核的过程中形成一定的过冷度,通常为低于熔点10-100K之间。The polycrystalline ingot is a typical melt solidification growth method: the polycrystalline silicon raw material is heated and melted into a melt at a high temperature, and then cooled by the bottom, and the crystal is grown by upward directional solidification, and the growth process is relatively slow, after the growth is completed. The crystal is annealed and cooled to normal temperature. Studies have shown that in order to form suitable silicon germanium structures of <110> and <112>, it is necessary to form a certain degree of subcooling in the process of crystal nucleation, usually between 10 and 100 K below the melting point.

目前,大部分多晶硅铸锭炉开始进行铸锭量扩大的升级改造,即保持现有多晶硅铸锭炉的炉体结构不变的情况下,扩大热场,由原来的G5型锭升级到G6,G7型锭。G5,G6,G7分别指硅锭的重量,G5指该硅锭由5x5=25个相同重量的小硅块组成,类推之,则G6,G7的产量分别比G5提高了44%,96%。通过改造,可以提高铸锭的产量及降低硅片的单位成本,降低光伏发电的每瓦成本。但是由于改造后炉体尺寸不变,改造后锭的重量分别提高44%,96%, 需要热场底部散热能力也相应提高,利用现有隔热笼提升技术的散热能力仅仅少量提高,所以将会使得铸锭过程中的凝固速度大大降低。如目前G5型铸锭的凝固时间约为25小时,但是G6型铸锭的凝固时间达到了40小时左右,而G7型铸锭的凝固时间更长。这样无形中增加了硅片生产的成本,同时由于凝固过程中,硅料大部分仍处于高温熔化状态,也增加了漏硅的风险。此外,由于硅锭与坩埚接触时间长,也会造成氧一定的扩散污染,使得晶体质量下降。At present, most polycrystalline silicon ingot furnaces have begun to upgrade the ingot volume expansion, that is, to maintain the existing polycrystalline silicon ingot furnace body structure unchanged, expand the thermal field, upgrade from the original G5 ingot to G6, G7 type ingot. G5, G6, and G7 refer to the weight of the silicon ingot, respectively. G5 means that the silicon ingot is composed of 5x5=25 small silicon blocks of the same weight. By analogy, the yield of G6 and G7 is 44% and 96% higher than that of G5, respectively. Through the transformation, the output of the ingot can be increased and the unit cost of the silicon wafer can be reduced, and the cost per watt of photovoltaic power generation can be reduced. However, due to the constant size of the furnace after the transformation, the weight of the ingot after the transformation was increased by 44% and 96% respectively. The heat dissipation capacity at the bottom of the heat field is also required to be improved accordingly, and the heat dissipation capability of the existing heat insulating cage lifting technology is only slightly increased, so that the solidification speed in the ingot casting process is greatly reduced. For example, the solidification time of the G5 ingot is about 25 hours, but the solidification time of the G6 ingot is about 40 hours, and the solidification time of the G7 ingot is longer. This invisibly increases the cost of wafer production, and at the same time, most of the silicon material is still in a high-temperature melting state during the solidification process, which also increases the risk of silicon leakage. In addition, due to the long contact time between the silicon ingot and the crucible, it also causes a certain diffusion and contamination of oxygen, resulting in a decrease in crystal quality.

目前,G5,G6,G7的底部保温板均为一个整块板,长晶时坩埚底部的热量较坩埚边缘的热量难以辐射出去,造成了长晶时的固液界面呈微凹形的,溶解在硅熔体中的杂质将沉积在中间部位,这样生长出来的晶体质量偏低,切出来的硅片转化效率也偏低。同时对于较大的G6型(800公斤左右),G7型(1200公斤左右)的多晶铸锭而言,结晶潜热巨大,按照目前的隔热笼辐射散热方式,已经很难有效的散发结晶潜热。At present, the bottom insulation boards of G5, G6, and G7 are all one-piece boards. When the crystals are grown, the heat at the bottom of the crucible is hard to radiate out of the heat at the edge of the crucible, causing the solid-liquid interface at the time of crystal growth to be slightly concave and dissolved. Impurities in the silicon melt will be deposited in the middle, so that the quality of the crystal grown is low, and the efficiency of the cut wafer is also low. At the same time, for the larger G6 type (about 800 kg) and the G7 type (about 1200 kg) polycrystalline ingot, the latent heat of crystallization is huge. According to the current heat dissipation method of the insulating cage, it is difficult to effectively emit the latent heat of crystallization. .

发明内容:Summary of the invention:

本发明要解决的技术问题是,克服现有技术存在的上述缺陷,提供一种多晶硅铸锭炉底部小保温板活动装置,包括具有该底部小保温板活动装置的多晶硅铸锭炉,在长晶过程中,除了有边缘隔热笼提升的辐射散热外,还提供一个坩埚正下方的竖直的辐射散热通道,这样不仅有长晶初期的过冷度,而且还可以调节生长过程中的固液界面呈有益的微凸型,并且助凝块的散热能力加强,进行定向凝固时,速度快,晶体产品质量高。The technical problem to be solved by the present invention is to overcome the above-mentioned defects existing in the prior art, and to provide a small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, comprising a polycrystalline silicon ingot furnace having the bottom small thermal insulation plate movable device, in the long crystal In addition to the radiant heat dissipation from the edge insulation cage, it also provides a vertical radiant heat dissipation channel directly below the ,, so that not only the initial cooling of the crystal growth, but also the solid-liquid during the growth process. The interface has a beneficial micro-convex shape, and the heat dissipation capability of the coagulation block is strengthened. When the directional solidification is performed, the speed is fast and the quality of the crystal product is high.

本发明解决其技术问题采用的技术方案是:一种多晶硅铸锭炉底部小保温板活动装置,包括底部小保温板,支撑杆,伸缩管,升降装置;用上螺母和下螺母将所述底部小保温板固定在支撑杆的上部;所述支撑杆的下部穿伸至伸缩管底部;所述伸缩管上端与炉体相连,伸缩管下端与升降装置相连接;在所述升降装置的控制下底部小保温板可以沿支撑杆的轴向上下活动。The technical solution adopted by the invention to solve the technical problem is: a small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace, comprising a small thermal insulation board at the bottom, a support rod, a telescopic tube, a lifting device; the bottom portion is made with a nut and a lower nut a small insulation board is fixed on the upper part of the support rod; a lower part of the support rod extends to the bottom of the telescopic tube; an upper end of the extension tube is connected to the furnace body, and a lower end of the extension tube is connected with the lifting device; under the control of the lifting device The bottom small insulation board can move up and down along the axial direction of the support rod.

进一步,所述升降装置由升降杆和伺服电机组成,升降杆沿伺服电机可以上下运动,从而带动支撑杆上部的底部小保温板上下运动。Further, the lifting device is composed of a lifting rod and a servo motor, and the lifting rod can move up and down along the servo motor, thereby driving the bottom of the upper part of the supporting rod to move under the small thermal insulation board.

进一步,所述升降装置还可以替换为C形卡,根据底部小保温板不同的升降高度配置相应高度的C形卡。Further, the lifting device can also be replaced by a C-shaped card, and a C-shaped card of a corresponding height is configured according to different lifting heights of the bottom small thermal insulation board.

进一步,所述伸缩管由波纹管与快换接头密封焊接而成;所述伸缩管上端与炉体相连处设有密封圈,用卡箍可以密封固定;伸缩管下端与盲板相连处设有密封圈,用卡箍可以密封固定。Further, the telescopic tube is sealed and welded by a bellows and a quick-change joint; a sealing ring is arranged at an upper end of the telescopic tube and a furnace body, and the clamp can be sealed and fixed; the lower end of the telescopic tube is connected with the blind plate; The sealing ring can be sealed and fixed with a clamp.

进一步,为了增加底部小保温板的稳定性,在所述底部小保温板与下螺母之间还设置有 垫板。Further, in order to increase the stability of the small thermal insulation board at the bottom, between the small thermal insulation board and the lower nut, Pad.

进一步,所述支撑杆为钼杆、钨杆、铱杆、石墨杆或炭-炭复合材料杆中的一种。Further, the support rod is one of a molybdenum rod, a tungsten rod, a mast, a graphite rod or a carbon-carbon composite rod.

进一步,所述底部小保温板横截面为矩形或倒T字形,底部大保温板对应配合孔的横截面为矩形或倒T字形。Further, the bottom small thermal insulation board has a rectangular or inverted T-shaped cross section, and the bottom large thermal insulation board has a rectangular or inverted T-shaped cross section corresponding to the matching hole.

进一步,所述底部小保温板俯视图为圆形或矩形,底部大保温板对应配合孔俯视图为圆形或矩形。Further, the bottom small thermal insulation board has a circular or rectangular top view, and the bottom large thermal insulation board has a circular or rectangular shape corresponding to the top view of the matching hole.

进一步,所述底部小保温板与底部大保温板的分离距离为10~300mm。Further, the separation distance between the bottom small thermal insulation board and the bottom large thermal insulation board is 10 to 300 mm.

进一步,所述伸缩管为耐温不锈钢材质,具体为316L。Further, the telescopic tube is made of a temperature resistant stainless steel, specifically 316L.

进一步,所述上螺母、下螺母和垫板材质为石墨材料或炭-炭复合材料。Further, the upper nut, the lower nut and the backing plate are made of a graphite material or a carbon-carbon composite material.

使用所述多晶硅铸锭炉底部小保温板活动装置的方法:当硅料在熔化时,底部小保温板与底部大保温板处于闭合状态;当熔化完毕进入长晶阶段时,启动升降装置使底部小保温板与底部大保温板分离开,加快硅晶体的长晶速度;当长晶完毕进入退火阶段时,启动升降装置使底部小保温板与底部大保温板处于闭合状态直至硅锭冷却出炉。The method for using the small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace: when the silicon material is melted, the bottom small thermal insulation board and the bottom large thermal insulation board are in a closed state; when the melting is completed and enters the long crystal stage, the lifting device is started to make the bottom The small thermal insulation board is separated from the large thermal insulation board at the bottom to accelerate the growth rate of the silicon crystal; when the crystal growth enters the annealing stage, the lifting device is started to close the small thermal insulation board at the bottom and the large thermal insulation board at the bottom until the silicon ingot is cooled out.

本发明与现有技术相比,具有以下优点:Compared with the prior art, the invention has the following advantages:

(1)本发明通过设置有多晶硅铸锭炉底部小保温板活动装置,加快对助凝块芯部进行冷却,提高了助凝块的散热能力,从而可以提高坩埚内硅熔体的冷却结晶速率,提高定向凝固的效率,缩短了生产周期,降低了生产成本;(1) The present invention accelerates the cooling of the core of the coagulation block by providing a small thermal insulation plate movable device at the bottom of the polycrystalline silicon ingot furnace, thereby improving the heat dissipation capability of the coagulation block, thereby improving the cooling crystallization rate of the silicon melt in the crucible. Improve the efficiency of directional solidification, shorten the production cycle and reduce the production cost;

(2)应用本发明多晶硅铸锭炉底部小保温板活动装置,可以形成硅孪晶生长所需要的较大过冷度,多晶硅锭的质量将有所提高。(2) Applying the movable device of the small thermal insulation board at the bottom of the polycrystalline silicon ingot furnace of the present invention can form a large degree of subcooling required for the growth of silicon twin crystal, and the quality of the polycrystalline silicon ingot will be improved.

(3)应用本发明多晶硅铸锭炉底部小保温板活动装置,加大了对助凝块芯部的冷却,多晶硅锭的中央冷却能力要强于边缘,可以形成微凸型固液界面,溶解在硅熔体中的杂质将向周边沉积,这样生长出来的晶体质量好,切出来的硅片转化效率较高。(3) Applying the movable device of the small thermal insulation board at the bottom of the polycrystalline silicon ingot furnace of the invention, the cooling of the core of the coagulation block is increased, and the central cooling capacity of the polycrystalline silicon ingot is stronger than the edge, and a micro convex solid-liquid interface can be formed, dissolved in The impurities in the silicon melt will be deposited to the periphery, so that the crystals grown are of good quality, and the cut silicon wafers have high conversion efficiency.

附图说明:BRIEF DESCRIPTION OF THE DRAWINGS:

图1为硅料熔化时本发明多晶硅铸锭炉底部小保温板活动装置结构示意图;图2为图11 is a schematic structural view of a small thermal insulation plate movable device at the bottom of the polycrystalline silicon ingot furnace of the present invention when the silicon material is melted; FIG. 2 is FIG.

的A部分局部放大图;Partially enlarged view of Part A;

图3为本发明多晶硅铸锭炉底部小保温板活动装置中伸缩管结构示意图;3 is a schematic structural view of a telescopic tube in a movable device for a small thermal insulation board at the bottom of a polycrystalline silicon ingot furnace according to the present invention;

图4为长晶时本发明多晶硅铸锭炉底部小保温板活动装置结构示意图;4 is a schematic structural view of a small thermal insulation board movable device at the bottom of the polycrystalline silicon ingot furnace of the present invention;

图5为图4中的升降装置替换为C形卡的结构示意图;Figure 5 is a schematic view showing the structure of the lifting device of Figure 4 replaced with a C-shaped card;

图6为图5的B部分局部放大图;Figure 6 is a partial enlarged view of a portion B of Figure 5;

图7为图1、图4或图5中矩形底部小保温板俯视图; Figure 7 is a top view of the small thermal insulation board at the bottom of the rectangle in Figure 1, Figure 4 or Figure 5;

图8为图1、图4或图5中圆形底部小保温板俯视图;Figure 8 is a top view of the small bottom thermal insulation board of Figure 1, Figure 4 or Figure 5;

图9为硅料熔化时底部小保温板横截面呈倒T字形结构示意图;Figure 9 is a schematic view showing the inverted T-shaped cross section of the bottom small insulation board when the silicon material is melted;

图10为长晶时底部小保温板横截面呈倒T字形结构示意图;Figure 10 is a schematic view showing the inverted T-shaped cross section of the bottom small thermal insulation plate when the crystal is grown;

图11为图9或图10中矩形底部小保温板俯视图;Figure 11 is a top plan view of the rectangular bottom insulation board of Figure 9 or Figure 10;

图12为图9或图10中圆形底部小保温板俯视图;Figure 12 is a top plan view of the circular bottom small insulation board of Figure 9 or Figure 10;

其中:1-底部大保温板,2-底部小保温板,3-支撑杆,4-上螺母,5-垫板,6-伸缩管,7-升降装置,8-升降杆,9-伺服电机,10-密封圈,11-卡箍,12-盲板,13-波纹管,14-快换接头,15-底部小保温板与底部大保温板的分离距离,16-下螺母,17-固液界面,18-下炉体,19-上炉体,20-C形卡。Among them: 1- bottom large insulation board, 2- bottom small insulation board, 3-support rod, 4-upper nut, 5-pad, 6-telduct, 7-lifting device, 8-lifting rod, 9-servo motor ,10-seal ring,11-clamp,12-blind plate,13-corrugated pipe,14-fast change joint,15-separation distance between small insulation board and bottom large insulation board, 16-lower nut, 17-solid Liquid interface, 18-low furnace body, 19-upper furnace, 20-C-shaped card.

具体实施方式detailed description

以下结合实例及附图对本发明作进一步说明。The invention will be further described below in conjunction with the examples and the accompanying drawings.

实施例1Example 1

本实施例包括底部小保温板2,支撑杆3,伸缩管6,升降装置7;用上螺母4和下螺母16将底部小保温板2固定在支撑杆3的上部;支撑杆3的下部穿伸至伸缩管6底部;伸缩管6上端与炉体相连,伸缩管6下端与升降装置7相连接;在升降装置7的控制下底部小保温板2可以沿支撑杆3的轴向上下活动。(如图1所示);The embodiment comprises a bottom small thermal insulation board 2, a support rod 3, a telescopic tube 6, and a lifting device 7; the bottom small thermal insulation board 2 is fixed on the upper part of the support rod 3 by the upper nut 4 and the lower nut 16; the lower part of the support rod 3 is worn The upper end of the telescopic tube 6 is connected to the furnace body, and the lower end of the telescopic tube 6 is connected to the lifting device 7; under the control of the lifting device 7, the bottom small thermal insulation board 2 can move up and down along the axial direction of the support rod 3. (As shown in Figure 1);

升降装置7由升降杆8和伺服电机9组成,升降杆8沿伺服电机9可以上下运动,从而带动支撑杆3上部的底部小保温板2上下运动。The lifting device 7 is composed of a lifting rod 8 and a servo motor 9. The lifting rod 8 can move up and down along the servo motor 9, thereby driving the bottom small thermal insulation board 2 on the upper part of the supporting rod 3 to move up and down.

伸缩管6由波纹管13与快换接头14密封焊接而成;伸缩管6上端与炉体相连处设有密封圈10,用卡箍11可以密封固定;伸缩管6下端与盲板12相连处设有密封圈10,用卡箍11可以密封固定。(如图2、图3所示);The bellows 6 is sealed and welded by the bellows 13 and the quick-change joint 14; the upper end of the bellows 6 is connected with the furnace body with a sealing ring 10, which can be sealed and fixed by the clamp 11; the lower end of the telescopic tube 6 is connected with the blind plate 12 A sealing ring 10 is provided, which can be sealed and fixed by the clamp 11. (as shown in Figure 2 and Figure 3);

为了增加底部小保温板2的稳定性,在底部小保温板2与下螺母16之间还设置有垫板5。(如图1、图4、图5、图9和图10所示);In order to increase the stability of the bottom small thermal insulation board 2, a backing plate 5 is further disposed between the bottom small thermal insulation board 2 and the lower nut 16. (as shown in Figure 1, Figure 4, Figure 5, Figure 9 and Figure 10);

支撑杆3为钼杆。The support rod 3 is a molybdenum rod.

底部小保温板2横截面为矩形且其俯视图也为矩形(如图7所示),底部大保温板1对应配合孔的横截面为矩形。The bottom small thermal insulation board 2 has a rectangular cross section and is also rectangular in plan view (as shown in FIG. 7), and the bottom large thermal insulation board 1 has a rectangular cross section corresponding to the matching hole.

伸缩管6为耐温不锈钢材质,具体为316L。The telescopic tube 6 is made of a temperature-resistant stainless steel, specifically 316L.

上螺母、下螺母和垫板材质为石墨材料。The upper nut, lower nut and backing plate are made of graphite material.

当硅料在熔化时,底部小保温板2与底部大保温板1处于闭合状态(如图1所示);当熔化完毕进入长晶阶段时,启动升降装置7使底部小保温板2与底部大保温板1分离开,分离 距离15为10mm,加快硅晶体的长晶速度;且固液界面17呈微凸型(如图4所示);当长晶完毕进入退火阶段时,启动升降装置7使底部小保温板2与底部大保温板1处于闭合状态直至硅锭冷却出炉。When the silicon material is melting, the bottom small thermal insulation board 2 and the bottom large thermal insulation board 1 are in a closed state (as shown in FIG. 1); when the melting is completed and enters the long crystal stage, the lifting device 7 is activated to make the bottom small thermal insulation board 2 and the bottom. Large insulation board 1 is separated and separated The distance 15 is 10mm, which accelerates the crystal growth rate of the silicon crystal; and the solid-liquid interface 17 is slightly convex (as shown in FIG. 4); when the crystal growth enters the annealing stage, the lifting device 7 is activated to make the bottom small thermal insulation board 2 The bottom large thermal insulation board 1 is in a closed state until the silicon ingot is cooled out of the furnace.

采用本发明的多晶硅铸锭炉底部小保温板活动装置生产硅锭,能使得坩埚内部的硅熔体的凝固速率提高,进而可以加快长晶,提高铸锭产量,同时降低铸锭的用电成本。The use of the polycrystalline silicon ingot furnace bottom small thermal insulation plate movable device to produce the silicon ingot can increase the solidification rate of the silicon melt inside the crucible, thereby accelerating the growth of the ingot, increasing the ingot production, and reducing the electricity cost of the ingot. .

以GT多晶硅铸锭炉的G5改造成G6为例,铸锭重量由500公斤提高到800公斤,如果简单采用隔热笼提升的长晶方案,其长晶时间需要40个小时左右,而总的工艺时间为75小时;而采用本发明多晶硅铸锭炉底部小保温板活动装置后,其长晶时间缩短至30个小时,且总的工艺时间缩短为65小时。由于长晶期间,功率保持恒定为60-66千瓦左右,则每个锭可以节省电耗约600-660度,而生产效率提高约13%-15%。同时,铸锭良率约提高1%,可以多产硅片300片/锭,以目前多晶硅片6.5元/片计,则增加收入1950元;此外,硅片的平均转换效率提高了0.1%的绝对值(转换效率从17.8%提高至17.9%)。Taking the G5 of the GT polysilicon ingot furnace into G6 as an example, the weight of the ingot is increased from 500 kg to 800 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 40 hours, and the total The process time is 75 hours; and with the small thermal insulation plate moving device of the polycrystalline silicon ingot furnace of the invention, the crystal growth time is shortened to 30 hours, and the total process time is shortened to 65 hours. Since the power is kept constant at 60-66 kW during the growth period, each ingot can save about 600-660 degrees of power consumption, and the production efficiency is increased by about 13%-15%. At the same time, the ingot yield is increased by about 1%, and 300 wafers/ingot of silicon wafers can be produced. The current polycrystalline silicon wafer is 6.5 yuan/piece, which increases the income by 1950 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.8% to 17.9%).

实施例2Example 2

本实施例与实施例1的区别仅在于:支撑杆3为钨杆;底部小保温板2横截面为矩形且其俯视图为圆形(如图8所示),底部大保温板1对应配合孔的横截面为圆形;当熔化完毕进入长晶阶段时,启动升降装置7使底部小保温板2与底部大保温板1分离开,分离距离15为60mm。余同实施例1。The difference between the embodiment and the embodiment 1 is that the support rod 3 is a tungsten rod; the bottom small insulation board 2 has a rectangular cross section and a circular shape in plan view (as shown in FIG. 8 ), and the bottom large insulation board 1 corresponds to the matching hole. The cross section is circular; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 60 mm. The same as Example 1.

以GT多晶硅铸锭炉的G5改造成G6为例,铸锭重量由500公斤提高到800公斤,如果简单采用隔热笼提升的长晶方案,其长晶时间需要40个小时左右,而总的工艺时间为75小时;而采用本发明多晶硅铸锭炉底部小保温板活动装置后,其长晶时间缩短至29个小时,且总的工艺时间缩短为64小时。由于长晶期间,功率保持恒定为60-66千瓦左右,则每个锭可以节省电耗约660-726度,而生产效率提高约14%-15%。同时,铸锭良率约提高1.2%,可以多产硅片360片/锭,以目前多晶硅片6.5元/片计,则增加收入2340元;此外,硅片的平均转换效率提高了0.1%的绝对值(转换效率从17.8%提高至17.9%)。Taking the G5 of the GT polysilicon ingot furnace into G6 as an example, the weight of the ingot is increased from 500 kg to 800 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 40 hours, and the total The process time is 75 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 29 hours, and the total process time is shortened to 64 hours. Since the power is kept constant at 60-66 kW during the growth period, each ingot can save about 660-726 degrees of power consumption, and the production efficiency is increased by about 14%-15%. At the same time, the ingot yield is increased by about 1.2%, and the wafer can be produced in a total of 360 pieces/ingot. The current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 2340 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.8% to 17.9%).

实施例3Example 3

本实施例与实施例1的区别仅在于:支撑杆3为铱杆;上螺母4、下螺母16和垫板5材质为炭-炭复合材料;升降装置7被替换为C形卡20,当熔化完毕进入长晶阶段时,用C形卡20使底部小保温板2与底部大保温板1分离开,分离距离15为100mm(如图5、图6所示)。余同实施例1。The difference between this embodiment and the embodiment 1 is that the support rod 3 is a mast; the upper nut 4, the lower nut 16 and the back plate 5 are made of carbon-carbon composite material; the lifting device 7 is replaced by a C-shaped card 20, when When the melting is completed and the crystal growth stage is entered, the bottom small thermal insulation board 2 is separated from the bottom large thermal insulation board 1 by the C-shaped card 20, and the separation distance 15 is 100 mm (as shown in Figs. 5 and 6). The same as Example 1.

以JYT多晶硅铸锭炉的G5改造成G7为例,铸锭重量有500公斤提高到1200公斤,如果 简单采用隔热笼提升的长晶方案,其长晶时间需要52个小时左右,而总的工艺时间为90小时;而采用本发明多晶硅铸锭炉底部小保温板活动装置后,其长晶时间缩短至42个小时,且总的工艺时间缩短为81小时。由于长晶期间,功率保持恒定为70-75千瓦左右,则每个锭可以节省电耗约700-750度,而生产效率提高约10%-13%。同时,铸锭良率约提高1%,可以多产硅片450片/锭,以目前多晶硅片6.5元/片计,则增加收入2925元;此外,硅片的平均转换效率提高了0.1%的绝对值(转换效率从17.75%提高至17.85%)。Taking the G5 of JYT polysilicon ingot furnace into G7 as an example, the weight of the ingot is increased from 500 kg to 1200 kg. Simply adopt the long crystal scheme of the insulated cage, the crystal growth time takes about 52 hours, and the total process time is 90 hours; and the crystal growth time of the polysilicon ingot furnace bottom small thermal insulation board movable device is adopted. Shortened to 42 hours and the total process time was reduced to 81 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 700-750 degrees of power consumption, and the production efficiency is increased by about 10%-13%. At the same time, the ingot yield is increased by about 1%, and 450 wafers/ingot of silicon wafer can be produced. The current polycrystalline silicon wafer is 6.5 yuan/piece, which increases the income by 2,925 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).

实施例4Example 4

本实施例与实施例1的区别仅在于:支撑杆3为石墨杆;底部小保温板2横截面为倒T字形且其俯视图为矩形(如图11所示),底部大保温板1对应配合孔的横截面为倒T字形;当熔化完毕进入长晶阶段时,启动升降装置7使底部小保温板2与底部大保温板1分离开,分离距离15为180mm。余同实施例1。The difference between this embodiment and the first embodiment is that the support rod 3 is a graphite rod; the bottom small thermal insulation board 2 has an inverted T-shaped cross section and a rectangular shape in plan view (as shown in FIG. 11), and the bottom large thermal insulation board 1 is matched. The cross section of the hole is inverted T-shaped; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 180 mm. The same as Example 1.

以JYT多晶硅铸锭炉的G6改造成G7为例,铸锭重量有800公斤提高到1200公斤,如果简单采用隔热笼提升的长晶方案,其长晶时间需要52个小时左右,而总的工艺时间为92小时;而采用本发明多晶硅铸锭炉底部小保温板活动装置后,其长晶时间缩短至41个小时,且总的工艺时间缩短为82小时。由于长晶期间,功率保持恒定为70-75千瓦左右,则每个锭可以节省电耗约770-825度,而生产效率提高约11%-15%。同时,铸锭良率约提高1.1%,可以多产硅片500片/锭,以目前多晶硅片6.5元/片计,则增加收入3250元;此外,硅片的平均转换效率提高了0.1%的绝对值(转换效率从17.75%提高至17.85%)。Taking the G6 of JYT polycrystalline silicon ingot furnace into G7 as an example, the weight of the ingot is increased from 800 kg to 1200 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 52 hours, and the total The process time is 92 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 41 hours, and the total process time is shortened to 82 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 770-825 degrees of power consumption, and the production efficiency is increased by about 11%-15%. At the same time, the ingot yield is increased by about 1.1%, and the wafer can be produced in a total of 500 pieces/ingot. The current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 3,250 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).

实施例5Example 5

本实施例与实施例1的区别仅在于:支撑杆3为炭-炭复合材料杆;底部小保温板2横截面为倒T字形且其俯视图为圆形(如图12所示),底部大保温板1对应配合孔的横截面为倒T字形;当熔化完毕进入长晶阶段时,启动升降装置7使底部小保温板2与底部大保温板1分离开,分离距离15为300mm。余同实施例1。The difference between this embodiment and the embodiment 1 is that the support rod 3 is a carbon-carbon composite rod; the bottom small insulation board 2 has an inverted T-shaped cross section and a circular shape in a plan view (as shown in FIG. 12), and the bottom portion is large. The cross section of the heat insulating plate 1 corresponding to the matching hole is inverted T-shaped; when the melting is completed into the crystal growth stage, the lifting device 7 is activated to separate the bottom small thermal insulation board 2 from the bottom large thermal insulation board 1, and the separation distance 15 is 300 mm. The same as Example 1.

以JYT多晶硅铸锭炉的G6改造成G7为例,铸锭重量有800公斤提高到1200公斤,如果简单采用隔热笼提升的长晶方案,其长晶时间需要52个小时左右,而总的工艺时间为92小时;而采用本发明多晶硅铸锭炉底部小保温板活动装置后,其长晶时间缩短至40个小时,且总的工艺时间缩短为82小时。由于长晶期间,功率保持恒定为70-75千瓦左右,则每个锭可以节省电耗约840-900度,而生产效率提高约12%-15%。同时,铸锭良率约提高1.1%,可以多产硅片500片/锭,以目前多晶硅片6.5元/片计,则增加收入3250元;此外,硅片的平均转换效率提高了0.1%的绝对值(转换效率从17.75%提高至17.85%)。 Taking the G6 of JYT polycrystalline silicon ingot furnace into G7 as an example, the weight of the ingot is increased from 800 kg to 1200 kg. If the long crystal scheme of the insulated cage is simply adopted, the crystal growth time takes about 52 hours, and the total The process time is 92 hours; and with the small thermal insulation board moving device of the polycrystalline silicon ingot furnace of the present invention, the crystal growth time is shortened to 40 hours, and the total process time is shortened to 82 hours. Since the power is kept constant at about 70-75 kW during the growth period, each ingot can save about 840-900 degrees of power consumption, and the production efficiency is increased by about 12%-15%. At the same time, the ingot yield is increased by about 1.1%, and the wafer can be produced in a total of 500 pieces/ingot. The current polycrystalline silicon sheet is 6.5 yuan/piece, which increases the income by 3,250 yuan. In addition, the average conversion efficiency of the silicon wafer is increased by 0.1%. Absolute value (conversion efficiency increased from 17.75% to 17.85%).

以上所述,仅是本发明的较佳实施例,并非对本发明作任何限制,凡是根据本发明技术实质对以上实施例所作的任何修改、变更以及等效结构变换,均仍属本发明技术方案的保护范围。 The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention. Any modification, modification, and equivalent structural transformation of the above embodiments in accordance with the technical spirit of the present invention are still the technical solutions of the present invention. The scope of protection.

Claims (10)

一种多晶硅铸锭炉底部小保温板活动装置,包括底部小保温板(2),支撑杆(3),伸缩管(6),升降装置(7);用上螺母(4)和下螺母(16)将所述底部小保温板(2)固定在支撑杆(3)的上部;所述支撑杆(3)的下部穿伸至伸缩管(6)底部;所述伸缩管(6)上端与炉体相连,伸缩管(6)下端与升降装置(7)相连接;其特征在于:在所述升降装置(7)的控制下底部小保温板(2)可以沿支撑杆(3)的轴向上下运动。A small thermal insulation board movable device at the bottom of a polycrystalline silicon ingot furnace, comprising a small thermal insulation board at the bottom (2), a support rod (3), a telescopic tube (6), a lifting device (7); an upper nut (4) and a lower nut ( 16) fixing the bottom small thermal insulation board (2) to the upper part of the support rod (3); the lower part of the support rod (3) is extended to the bottom of the telescopic tube (6); the upper end of the extension tube (6) is The furnace body is connected, and the lower end of the telescopic tube (6) is connected with the lifting device (7); characterized in that: under the control of the lifting device (7), the bottom small thermal insulation board (2) can be along the axis of the support rod (3) Move up and down. 根据权利要求1所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述升降装置(7)由升降杆(8)和伺服电机(9)组成,升降杆(8)沿伺服电机(9)可以上下运动,从而带动支撑杆(3)上部的底部小保温板(2)上下运动。The movable device for small insulation board at the bottom of a polycrystalline silicon ingot furnace according to claim 1, characterized in that: the lifting device (7) is composed of a lifting rod (8) and a servo motor (9), and the lifting rod (8) is along the servo The motor (9) can move up and down to drive the small insulation board (2) at the bottom of the upper part of the support rod (3) to move up and down. 根据权利要求1所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述升降装置(7)替换为C形卡(20),在所述C形卡(20)的控制下底部小保温板(2)可以沿支撑杆(3)的轴向上下运动。A small thermal insulation board movable device for a polycrystalline silicon ingot furnace according to claim 1, wherein said lifting device (7) is replaced by a C-shaped card (20) under the control of said C-shaped card (20) The bottom small insulation board (2) can move up and down along the axial direction of the support rod (3). 根据权利要求1所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述伸缩管(6)由波纹管(13)与快换接头(14)密封焊接而成;所述伸缩管(6)上端与炉体相连处设有密封圈(10),用卡箍(11)固定;伸缩管(6)下端与盲板(12)相连处设有密封圈(10),用卡箍(11)固定。The movable device for a small thermal insulation board at the bottom of a polycrystalline silicon ingot furnace according to claim 1, wherein the telescopic tube (6) is sealed and welded by a bellows (13) and a quick-change joint (14); A sealing ring (10) is arranged at the upper end of the pipe (6) and the furnace body, and is fixed by a clamp (11); a sealing ring (10) is provided at a lower end of the telescopic pipe (6) and the blind plate (12), and the card is used. The hoop (11) is fixed. 根据权利要求1所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述底部小保温板(2)与下螺母(16)之间还设置有垫板(5)。The movable device for the small thermal insulation board at the bottom of the polycrystalline silicon ingot furnace according to claim 1, characterized in that: a spacer (5) is further disposed between the bottom small thermal insulation board (2) and the lower nut (16). 根据权利要求1至5任意一权利要求所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述支撑杆(3)可以为杆件或者管件,材料可以是钼、钨、不锈钢、石墨或炭-炭复合材料中的一种。The movable device for the bottom of the polycrystalline silicon ingot furnace according to any one of claims 1 to 5, characterized in that the support rod (3) can be a rod or a pipe member, and the material can be molybdenum, tungsten or stainless steel. One of graphite, or carbon-carbon composites. 根据权利要求1至5任意一权利要求所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述底部小保温板(2)横截面为矩形或倒T字形,底部大保温板(1)对应配合孔的横截面为矩形或倒T字形。The movable device for the small thermal insulation board at the bottom of the polycrystalline silicon ingot furnace according to any one of claims 1 to 5, characterized in that: the bottom small thermal insulation board (2) has a rectangular or inverted T-shaped cross section, and a large thermal insulation board at the bottom. (1) The cross section of the corresponding mating hole is rectangular or inverted T-shaped. 根据权利要求1至5任意一权利要求所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述底部小保温板(2)俯视图为圆形或矩形,底部大保温板(1)对应配合孔俯视图为圆形或矩形。The movable device for the bottom small insulation board of the polycrystalline silicon ingot furnace according to any one of claims 1 to 5, characterized in that: the bottom small thermal insulation board (2) has a circular or rectangular top view and a large thermal insulation board at the bottom (1) The top view of the corresponding matching hole is circular or rectangular. 根据权利要求1至5任意一权利要求所述的多晶硅铸锭炉底部小保温板活动装置,其特征在于:所述底部小保温板(2)与底部大保温板(1)的竖直分离距离(15)为10~300mm。The movable device for the small thermal insulation board at the bottom of the polycrystalline silicon ingot furnace according to any one of claims 1 to 5, characterized in that: the vertical separation distance between the bottom small thermal insulation board (2) and the bottom large thermal insulation board (1) (15) is 10 to 300 mm. 一种多晶硅铸锭炉,包括下炉体(18),上炉体(19),其特征在于:具有权利要求1至9任意一权利要求所述的多晶硅铸锭炉底部小保温板活动装置。 A polycrystalline silicon ingot furnace comprising a lower furnace body (18) and an upper furnace body (19), characterized in that the polycrystalline silicon ingot furnace bottom small thermal insulation board movable device according to any one of claims 1 to 9.
PCT/CN2015/081431 2014-11-27 2015-06-15 Device for moving small heat insulating plate at bottom of polycrystalline silicon ingot furnace and polycrystalline silicon ingot furnace Ceased WO2016082525A1 (en)

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