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WO2016060451A1 - Matériau actif de cathode de batterie au lithium à structure poreuse et procédé de préparation associé - Google Patents

Matériau actif de cathode de batterie au lithium à structure poreuse et procédé de préparation associé Download PDF

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Publication number
WO2016060451A1
WO2016060451A1 PCT/KR2015/010801 KR2015010801W WO2016060451A1 WO 2016060451 A1 WO2016060451 A1 WO 2016060451A1 KR 2015010801 W KR2015010801 W KR 2015010801W WO 2016060451 A1 WO2016060451 A1 WO 2016060451A1
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WO
WIPO (PCT)
Prior art keywords
active material
cathode active
lithium
metal
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2015/010801
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English (en)
Korean (ko)
Inventor
강도순
이아람
임규선
최승언
이지원
문재웅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ENF Technology CO Ltd
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ENF Technology CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ENF Technology CO Ltd filed Critical ENF Technology CO Ltd
Priority to CN201580066165.1A priority Critical patent/CN107004852B/zh
Priority to JP2017540533A priority patent/JP6744319B2/ja
Publication of WO2016060451A1 publication Critical patent/WO2016060451A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the radial porous structure is formed according to the present invention by forming a plate- or needle-shaped primary particle radially from a center inside the secondary particle, and forming pores based on a radial region formed from the primary particle.
  • a positive electrode active material having a porous structure having a radial distribution may be formed.
  • the transition metal according to the present invention may be preferably a transition metal selected from Ni, Co, and Mn, and more preferably, a three-component cathode active material including the Ni, Co, and Mn may be preferable, but is not limited thereto. .
  • Cathode active material according to a preferred embodiment of the present invention may be a lithium metal composite oxide represented by the formula (1).
  • the positive electrode active material of the present invention contains an additive element in order to improve the output characteristics, structural stability, lifespan characteristics, and the like of the battery.
  • the addition element is added in a small amount compared to the content of the main element and is preferably uniformly distributed on the surface or inside of the lithium nickel composite oxide particles.
  • grains of the metal composite hydroxide represented by General formula (1) is used.
  • the metal compound is composed of a compound of a metal salt corresponding to the metal in order to have an atomic ratio of the metal corresponding to the atomic ratio of the metal in the nickel composite hydroxide represented by the formula (1).

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention concerne un matériau actif de cathode d'une batterie au lithium, lequel est une particule d'une structure poreuse dans laquelle des pores sont répartis sur toute la zone intérieure d'une particule secondaire formée sous la forme d'un agrégat d'une particule primaire, la forme de répartition des pores étant conçue de manière radiale pour avoir une grande superficie spécifique de façon à réduire la résistance à la migration d'un ion lithium étant donné qu'un électrolyte peut s'écouler facilement dans les pores, ce qui permet la fabrication d'une batterie secondaire présentant des caractéristiques de haute puissance.
PCT/KR2015/010801 2014-10-14 2015-10-14 Matériau actif de cathode de batterie au lithium à structure poreuse et procédé de préparation associé Ceased WO2016060451A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201580066165.1A CN107004852B (zh) 2014-10-14 2015-10-14 具有多孔结构的锂电池用正极活性物质及其制造方法
JP2017540533A JP6744319B2 (ja) 2014-10-14 2015-10-14 多孔性構造を有するリチウム電池用正極活物質及び製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020140138375A KR101593401B1 (ko) 2014-10-14 2014-10-14 다공성 구조를 갖는 리튬전지용 양극활물질 및 제조방법
KR10-2014-0138375 2014-10-14

Publications (1)

Publication Number Publication Date
WO2016060451A1 true WO2016060451A1 (fr) 2016-04-21

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PCT/KR2015/010801 Ceased WO2016060451A1 (fr) 2014-10-14 2015-10-14 Matériau actif de cathode de batterie au lithium à structure poreuse et procédé de préparation associé

Country Status (4)

Country Link
JP (1) JP6744319B2 (fr)
KR (1) KR101593401B1 (fr)
CN (1) CN107004852B (fr)
WO (1) WO2016060451A1 (fr)

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JP2018014325A (ja) * 2016-07-20 2018-01-25 三星エスディアイ株式会社Samsung SDI Co., Ltd. リチウム二次電池用ニッケル系活物質、その製造方法、及びそれを含む正極を含むリチウム二次電池
CN107644982A (zh) * 2016-07-20 2018-01-30 三星Sdi株式会社 用于锂二次电池的基于镍的活性材料、制备其的方法、和包括包含其的正极的锂二次电池
JP2018045759A (ja) * 2016-08-31 2018-03-22 住友化学株式会社 リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池
JP2020074264A (ja) * 2016-07-20 2020-05-14 三星エスディアイ株式会社Samsung SDI Co., Ltd. リチウム二次電池用ニッケル系活物質、その製造方法、及びそれを含む正極を含んだリチウム二次電池
US11309542B2 (en) 2016-12-08 2022-04-19 Samsung Sdi Co., Ltd. Nickel-based active material for lithium secondary battery, preparing method thereof, and lithium secondary battery including positive electrode including the same
US11456458B2 (en) 2016-12-08 2022-09-27 Samsung Sdi Co., Ltd. Nickel-based active material precursor for lithium secondary battery, preparing method thereof, nickel-based active material for lithium secondary battery formed thereof, and lithium secondary battery comprising positive electrode including the nickel-based active material
CN115280551A (zh) * 2020-09-30 2022-11-01 宁德时代新能源科技股份有限公司 混合正极材料、正极极片及制备方法、电池和装置
US20230081939A1 (en) * 2020-01-29 2023-03-16 Lg Chem, Ltd. Positive Electrode Active Material Precursor for Secondary Battery, Positive Electrode Active Material, and Lithium Secondary Battery Including the Positive Electrode Active Material
CN119706978A (zh) * 2025-02-25 2025-03-28 河南科隆新能源股份有限公司 一种均匀放射状的正极材料前驱体及其制备方法

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JP6979880B2 (ja) * 2016-02-03 2021-12-15 住友化学株式会社 遷移金属含有水酸化物およびリチウム含有複合酸化物の製造方法
KR102237950B1 (ko) * 2016-02-25 2021-04-08 주식회사 엘지화학 양극활물질 및 이를 포함하는 리튬 이차전지용 양극
KR102295366B1 (ko) * 2016-07-20 2021-08-31 삼성에스디아이 주식회사 리튬이차전지용 니켈계 활물질, 그 제조방법 및 이를 포함하는 양극을 포함한 리튬이차전지
US20180151876A1 (en) * 2016-11-30 2018-05-31 Samsung Sdi Co., Ltd. Nickel-based active material for lithium secondary battery, method of preparing nickel-based active material, and lithium secondary battery including positive electrode including nickel-based active material
KR102184370B1 (ko) * 2016-12-02 2020-11-30 삼성에스디아이 주식회사 리튬이차전지용 니켈계 활물질 전구체, 그 제조방법, 이로부터 형성된 리튬이차전지용 니켈계 활물질 및 이를 포함하는 양극을 함유한 리튬이차전지
CN110073527B (zh) * 2016-12-02 2023-07-14 三星Sdi株式会社 镍活性物质前驱体及其制备方法、镍活性物质以及锂二次电池
US11201328B2 (en) 2016-12-02 2021-12-14 Samsung Sdi Co., Ltd. Nickel active material precursor for lithium secondary battery, method for producing nickel active material precursor, nickel active material for lithium secondary battery produced by method, and lithium secondary battery having cathode containing nickel active material
CN107565125B (zh) * 2017-08-25 2019-10-29 湖南杉杉能源科技股份有限公司 一种高电压镍钴锰酸锂前驱体及其制备方法和高电压镍钴锰酸锂正极材料
WO2019076023A1 (fr) 2017-10-20 2019-04-25 湖南杉杉能源科技股份有限公司 Poudre d'oxyde métallique de cobalt et de lithium et son procédé de préparation, et procédé de mesure de la teneur en tétroxyde de tricobalt
KR102130484B1 (ko) * 2017-11-15 2020-07-06 주식회사 에코프로비엠 이차전지용 양극 활물질 및 이의 제조 방법
US11670754B2 (en) 2017-12-04 2023-06-06 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium battery, preparing method thereof and rechargeable lithium battery comprising positive electrode including positive active material
US11522189B2 (en) 2017-12-04 2022-12-06 Samsung Sdi Co., Ltd. Positive electrode for rechargeable lithium battery, preparing method thereof, and rechargeable lithium battery comprising positive electrode
US11777075B2 (en) 2017-12-04 2023-10-03 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium battery, preparing method thereof and rechargeable lithium battery comprising positive electrode including positive active material
US10847781B2 (en) 2017-12-04 2020-11-24 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium battery, preparing method thereof and rechargeable lithium battery comprising positive electrode including positive active material
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WO2021154024A1 (fr) * 2020-01-29 2021-08-05 주식회사 엘지화학 Précurseur de matériau actif d'électrode positive pour batterie secondaire, matériau actif d'électrode positive, son procédé de production, et batterie secondaire au lithium le comprenant
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JP2024083947A (ja) 2022-12-12 2024-06-24 住友金属鉱山株式会社 リチウムイオン二次電池用正極活物質
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US11569503B2 (en) 2016-07-20 2023-01-31 Samsung Sdi Co., Ltd. Nickel-based active material for lithium secondary battery, method of preparing the same, and lithium secondary battery including positive electrode including the nickel-based active material
CN107644982A (zh) * 2016-07-20 2018-01-30 三星Sdi株式会社 用于锂二次电池的基于镍的活性材料、制备其的方法、和包括包含其的正极的锂二次电池
JP2020064849A (ja) * 2016-07-20 2020-04-23 三星エスディアイ株式会社Samsung SDI Co., Ltd. リチウム二次電池用ニッケル系活物質、その製造方法、及びそれを含む正極を含むリチウム二次電池
JP2020074264A (ja) * 2016-07-20 2020-05-14 三星エスディアイ株式会社Samsung SDI Co., Ltd. リチウム二次電池用ニッケル系活物質、その製造方法、及びそれを含む正極を含んだリチウム二次電池
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