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WO2015130085A1 - Composition for fabric softener - Google Patents

Composition for fabric softener Download PDF

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Publication number
WO2015130085A1
WO2015130085A1 PCT/KR2015/001841 KR2015001841W WO2015130085A1 WO 2015130085 A1 WO2015130085 A1 WO 2015130085A1 KR 2015001841 W KR2015001841 W KR 2015001841W WO 2015130085 A1 WO2015130085 A1 WO 2015130085A1
Authority
WO
WIPO (PCT)
Prior art keywords
fabric softener
softener composition
weight
acid
cationic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2015/001841
Other languages
French (fr)
Korean (ko)
Inventor
조윤진
차경온
김세훈
심연수
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG H&H Co Ltd
Original Assignee
LG Household and Health Care Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020140102209A external-priority patent/KR20150125515A/en
Priority claimed from KR1020140102212A external-priority patent/KR20150125518A/en
Priority claimed from KR1020140102206A external-priority patent/KR20150100464A/en
Priority claimed from KR1020140102210A external-priority patent/KR20150125516A/en
Priority claimed from KR1020140102216A external-priority patent/KR20150125522A/en
Priority claimed from KR1020140102208A external-priority patent/KR20150125514A/en
Priority claimed from KR1020140102207A external-priority patent/KR20150100465A/en
Priority claimed from KR1020150025437A external-priority patent/KR102123613B1/en
Priority claimed from KR1020150025435A external-priority patent/KR20150100546A/en
Priority claimed from KR1020150025436A external-priority patent/KR101809786B1/en
Priority claimed from KR1020150025433A external-priority patent/KR20150100544A/en
Priority claimed from KR1020150025434A external-priority patent/KR101703138B1/en
Priority to JP2016554203A priority Critical patent/JP6817065B2/en
Application filed by LG Household and Health Care Ltd filed Critical LG Household and Health Care Ltd
Priority to CN201580010356.6A priority patent/CN106029857B/en
Publication of WO2015130085A1 publication Critical patent/WO2015130085A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof

Definitions

  • the present invention relates to a fabric softener composition.
  • Fabric softeners are widely used in homes to prevent static electricity generated in clothing and to give the flexibility of the fiber, the amount of use is increasing gradually.
  • the desire for hygiene and cleanliness is increased, and the pursuit of a more comfortable medical life, there is a growing interest in preventing the growth of microorganisms that can occur in clothing and removing odors.
  • the altered odor that occurs in fibers is caused by the reaction of organic compounds, such as sweat odors, with volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • organic compounds such as sweat odors
  • volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • drying time is delayed when drying indoors, and it is known that the odor caused by Morxella asloensis is more likely to occur.
  • a conventional softening agent composition containing an antimicrobial agent was used, but the antimicrobial agent included in the conventional softening agent is harmful to the human body.
  • the use of such antimicrobial agents has been avoided due to the fact that the use of synthetic antimicrobial agents is reported to be harmful to the human body.
  • the fabric softener has been using a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • the human hazard of such cationic surfactants has been revealed, and the desire to avoid them is increasing.
  • An object of the present invention is to provide a fabric softener composition having excellent dissolving and removing effects of calcium carbonate, which is a detergent insoluble component remaining in the fiber, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.
  • Another object of the present invention is to provide a fabric softener composition having excellent dissolution and removal effect of zeolite, which is a detergent-insoluble component remaining in the fiber, without using a cationic surfactant, which has been included as a flexible component in the conventional fabric softener composition. .
  • the present invention has a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of the environmental mark EL306, without using a cationic surfactant that was included as a flexible component in the conventional fabric softener composition, the drying Another object of the present invention is to provide a fabric softener composition which can give a smooth feeling to a subject without being slippery.
  • Another object of the present invention is to provide a fabric softener composition having excellent water repellency / moisture permeability of Gore-Tex outdoor clothing, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.
  • Another object of the present invention is to provide a fabric softener composition capable of removing odors changed after washing by adding an organic acid without using a cationic surfactant, which is included as a flexible component in a conventional fabric softener composition.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant, the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 90 ppm or less It provides a fabric softener composition.
  • the present invention also provides a fabric softener composition containing a pH adjusting agent, no cationic surfactant, and a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less. .
  • the present invention also provides a fabric softener composition
  • a fabric softener composition comprising a pH adjuster, no cationic surfactant, and a coefficient of friction of 2 to 25 fibers after washing and rinsing according to the test method of environmental mark EL306.
  • the present invention also provides a fabric softener composition including a pH adjuster, no cationic surfactant, and having a water repellency degree of 4 or higher after rinsing / dehydrating 5 times with an amount according to the environmental mark EL306.
  • the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 °C, 80% relative humidity
  • the fabric softener composition which has an evaluation of 4 or more points is provided.
  • the fabric softener composition according to the present invention is excellent for dissolving and removing calcium carbonate, which is a detergent insoluble component remaining in fibers, and for dissolving and removing zeolite, a detergent insoluble component.
  • the fabric softener composition according to the present invention having a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of environmental mark EL306, the dried subject is not slippery and smooth I can give a feeling.
  • the fabric softener composition according to the present invention instead of the cationic surfactant harmful to the human body, the water repellent / moisture permeability effect of Gore-Tex outdoor clothing than the fabric softener using the conventional cationic surfactant without using a pH adjuster to the human body Can improve.
  • the fabric softener composition according to the present invention can effectively remove the smell replaced after washing using an organic acid without using a cationic surfactant.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fiber softener composition (hereinafter referred to as a first fabric softener composition) having a content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 90 ppm or less.
  • a fiber softener composition hereinafter referred to as a first fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 in the present invention is 90 ppm or less, 65 ppm or less, 50 ppm or less, 45 ppm or less, 40 ppm or less, Or less than 37 ppm or 0 ppm.
  • the calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 may be removed from 5 to 300 ppm, 10 to 250 ppm, or 30 to 200 ppm.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fabric softener composition (hereinafter referred to as a second fabric softener composition) having a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 20 ppm or less.
  • a fabric softener composition hereinafter referred to as a second fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues, specifically zeolite.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It is possible to exhibit an excellent zeolite removal effect within the above range. Although the zeolite removal effect is excellent even if the content of the pH regulator exceeds 30% by weight, the pH of the rinsing water is lower as the content of the pH regulator is higher, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less, 10 ppm or less, 8 ppm or less, 7 ppm or less, 3 ppm or 0 ppm Can be.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fabric softener composition (hereinafter referred to as a third fabric softener composition) having a friction coefficient of 2 to 25 after finishing washing and rinsing according to the test method of environmental mark EL306.
  • a fabric softener composition hereinafter referred to as a third fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the coefficient of friction of the fibers after washing and rinsing according to the test method of environmental mark EL306 using the fabric softener composition according to the present invention may be 2 to 25, 10 to 25, or 20 to 23.
  • the subject dried in the friction coefficient range may give a smooth feeling without slipping.
  • the subject may be an object of a fabric softener such as clothing.
  • the present invention includes a fabric softener composition containing a pH adjuster, does not contain a cationic surfactant, water repellency degree 4 or more after repeated rinsing / dehydration five times with the amount according to the environmental mark EL306 (hereinafter, 4 fabric softener composition).
  • the fabric softener composition according to the present invention includes a pH adjusting agent.
  • the pH adjusting agent plays a role of water repellency / moisture permeability of Gore-Tex outdoor clothing.
  • the pH adjusting agent may be an organic acid.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the type of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid, and lactic acid.
  • citric acid is suitable for use as an organic acid because the cost of raw materials is low.
  • the content of the pH adjusting agent is not particularly limited, and may be included in an amount of 0.01 to 30% by weight, 0.1 to 20% by weight or 1 to 15% by weight based on 100% by weight of the fabric softener composition. Within the above range can exhibit excellent water repellent / moisture permeability of Gore-Tex outdoor clothing. Even if the content of the organic acid is more than 30% by weight of the excellent Gore-Tex outdoor clothing exhibits a water-repellent / moisture-permeable effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the Gore-Tex outdoor clothing can be easily used as a fabric softener because of excellent water / moisture permeability.
  • the fabric softener composition according to the present invention has a water repellency of 4 or more after repeated rinsing / dehydrating 5 times with the amount according to the environmental mark EL306.
  • the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 °C, 80% relative humidity
  • the evaluation relates to a fibrous softener composition (hereinafter referred to as a fifth fibrous softener composition) having four or more points.
  • the fabric softener composition of the present invention is characterized in that an organic acid is used instead of the cationic surfactant to remove the smell after washing.
  • the organic acid serves to remove detergent residues, specifically calcium carbonate.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid or the like, but is not particularly limited thereto.
  • the organic acid may be citric acid. Since citric acid has a low unit cost of raw material costs, it is possible to reduce the production cost of the fabric softener composition.
  • the content of the organic acid is not particularly limited and may be included in an amount of 1 to 30% by weight, more specifically, 2 to 25% by weight, based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight exhibits excellent calcium carbonate removal effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition of the present invention uses an organic acid instead of a cationic surfactant, and then, after washing for 24 hours at a drying temperature of 30 ° C. and a relative humidity of 80%, a five-point scale sensory evaluation of 4 Shown above the dots can effectively remove the odor. Therefore, it can be used easily as a fabric softener.
  • the fabric softener composition according to the present invention may further include a thickening polymer for viscosity control in addition to the aforementioned organic acid.
  • the thickening polymers include calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxy ethyl cellulose, carbopol 934, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guar gum. , Carrageenan, pectin, acrylic polymer and the like can be used.
  • at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylic acrylates is preferable.
  • the content of the thickening polymer is not particularly limited and may be included as 0.01 to 1.2% by weight, more specifically, 0.05 to 1% by weight based on 100% by weight of the fabric softener composition.
  • Vinegar may further be used in the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) of the present invention.
  • Vinegar is a sour and slightly sweet seasoning that contains acetic acid as its main ingredient, and contains dozens of organic acids such as acetic acid, citric acid and various amino acids, which helps to increase metabolism and remove body wastes, and is a powerful preservative. It serves as a powerful fungicide. In addition, vinegar may serve to remove detergent residues.
  • the content of the vinegar is not particularly limited and may be included in 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight relative to 100% by weight of the fabric softener composition. It has a bactericidal effect and an effect of removing detergent residues within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a flower fermentation vinegar that plays a role of strong deodorization in addition to the above-mentioned composition.
  • the flower fermentation vinegar may be obtained by washing the petals with water, dried and mixed with excess vinegar and sugar fermentation for 3 to 7 days.
  • the vinegar may be commercially available vinegar, it is preferable to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to alcohol ferment the flower extract, it is preferred to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the flower fermentation vinegar is sterilized with the original flower, hot water extracted for 10 to 30 minutes at 100 to 150 °C and then mixed with the hot water extract and vinegar and sugar and fermentation process at 20 to 40 °C for 72 to 96 hours Can be obtained through
  • the vinegar refers to fermented by propagating wild vinegar isolated from vinegar, odorless ( ⁇ ) produced in the traditional manner, the seed vinegar by the acetic acid bacteria Acetobacter sp. Anything that can be produced can be used.
  • the amount of the seed may be added in 5 to 30% by weight based on 100% by weight of the hydrothermal extract flowers.
  • the added amount of the vinegar is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged hydrothermal extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation does not increase any more.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to ferment the flower hydrothermal extract alcohol, and may be added in an amount of 5 to 30% by weight based on 100% by weight of the hydrothermal extract flower.
  • Flower fermentation vinegar prepared by the above method may have a pH of 2.70 to 3.30, the acidity of 3 to 7.
  • Types of flowers used for the flower fermentation vinegar can be used without limitation.
  • a peach blossom, an apricot blossom, an acacia blossom, a chamomile blossom, a jasmine blossom or a lotus blossom can be used.
  • the content of the flower fermentation vinegar is not particularly limited and may be included in 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight relative to 100% by weight of the fabric softener composition. It has an effect of removing bactericidal action and odor within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include ethanol for phase stability of the contents.
  • the content of the ethanol is not particularly limited, and may be included in 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition. It has a phase stability effect of excellent contents within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance.
  • the fragrance may include, for example, a floral fragrance, a citrus fragrance, or the like, but may be used without limitation within a range that does not impair the effects of the present invention if it can be used as a fabric softener.
  • the amount of the perfume is not particularly limited and may be included in 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance solubilizer
  • the fragrance solubilizer is vinegar odor by fermentation vinegar, etc. It alleviates the fragrance satisfaction of the fabric softener. Its content is not particularly limited and may be included in 0.1 to 10% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a plant extract to improve the odor removal effect such as vinegar odor.
  • the plant extract may include one or more selected from the group consisting of persimmon leaves, green tea and dermis.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a small amount of additives within the scope of the present invention.
  • the additive may be an antimicrobial component for further improving the antimicrobial effect.
  • the additive may be a pigment, a preservative, an antioxidant, an antifoaming agent, and the like.
  • the content of the additive is not particularly limited, and may be included in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • compositions of the present invention are generally formulated with fibrous softeners in addition to the components described above in their respective formulations, water, surfactants, A moisturizer, a lower alcohol, a thickener, a chelating agent, a pigment
  • the content thereof is not particularly limited, and may be included in an amount of 55 to 90 wt% or 60 to 85 wt% based on 100 wt% of the fabric softener composition.
  • composition first, second, third, fourth or fifth fabric softener composition
  • the composition may be used by powder, granulation using a method known in the art, may be prepared in a liquid state have.
  • citric acid As pH adjusting agent, citric acid, acetic acid, malic acid, tartaric acid, succinic acid or lactic acid among organic acids were used.
  • Vinegar was used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • An indicator fiber softener was used instead of the fabric softener composition.
  • the indicator fabric softener was produced by the test method in EL306 (fiber softener) of the environmental label certification standard of Korea Environmental Industry and Technology Institute as TEA Ester Quaternary of LG H & H.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • the content of calcium carbonate remaining in the garment after washing and rinsing was measured using the fabric softener composition prepared by the above-described examples and comparative examples.
  • the garments used three white standard cotton cloths (10 X 10 cm) as specified in KS K 0905, and the laundry detergents were powdered detergent (LG Health, Tech) containing calcium carbonate, which is readily available on the market.
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • Example 2 Example 3
  • Example 4 Example 5
  • Example 6 Example 7
  • Example 8 Example 9 Calcium Carbonate Content 0 37 65 45 40 56 50 25 30
  • the fiber softener composition using citric acid in the organic acid was excellent in the ability to remove calcium carbonate, and in Comparative Example 3 using the same amount of cationic surfactant as the organic acid, it was confirmed that there was no effect of removing calcium carbonate.
  • the amount of zeolite remaining in the garment after washing and rinsing was measured using the fabric softener compositions prepared by the above-described examples and comparative examples.
  • the garments used three white standard cotton cloths (10 ⁇ 10 cm) as specified in KS K 0905, and the laundry detergent was a powdered detergent (LG Health, Tech) containing zeolite, which is readily available on the market.
  • LG Health, Tech powdered detergent
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • the analysis of zeolite residue in the garment after washing rinsing was analyzed by using ICP (high frequency inductively coupled plasma) after extracting 0.5 g of the cotton rinsing-washed cotton, acid-treated with a mixture of hydrochloric acid, hydrofluoric acid, nitric acid and boric acid, and extracting for 24 hours. .
  • Example 4 Example 5
  • Example 6 Example 7
  • Example 8 Zeolite content 0 3 10 7 7 8 8 2 2
  • Citric acid in organic acid was used as a pH adjuster.
  • Vinegar was used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • a cationic surfactant was added to purified water at 60 ° C. and stirred for 20 minutes to prepare a fabric softener composition.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • Example 11 Example 12
  • Example 13 Example 14
  • Cationic surfactant 5 - - - - - - - Citric acid - 20 10
  • One 10 Flower Fermented Vinegar - - - - - - One One vinegar - - - - - - One Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight
  • the coefficient of friction of the garment was measured after washing and rinsing using the fabric softener composition prepared according to the above-described examples and comparative examples.
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • the conditions of measurement of the coefficient of friction of the garment were measured using a moving speed of 25 cm / min, weight of 160 g, and NBR (Nitrile Butadiene Rubber). The measurement was carried out to measure the load that occurs when the weight is moved at a constant speed after placing the treated standard cotton cloth on the test plate and placing the weight.
  • the slipperiness index was measured by sensory evaluation of 10 professional monitors, and 5 points were considered as slippery.
  • Comparative Example 1 which was rinsed only with water, showed an increased friction coefficient and the surface was too rough
  • Comparative Example 2 which was rinsed with the indicator fiber softener
  • Comparative Example 3 which was rinsed with the fabric softener containing a cationic surfactant, showed severe slipperiness.
  • a pH adjuster i.e., an organic acid
  • citric acid, vinegar, and flower fermentation vinegar were added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent, and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
  • vinegar used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • a cationic surfactant was added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • Example 21 Comparative Example 5 Flower Fermented Vinegar - - - - 0.5 0.5 - Cationic surfactant - - - - - 5 Citric acid 0.1 One 10 20 10 10 - vinegar - - - - - One - Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight
  • the water repellency of Gore-Tex outdoor clothing was measured using the fabric softener compositions of Examples and Comparative Examples.
  • the Gore-Tex used in the test was purchased directly from the commercial Gore-Tex garment [ISUKA's GORE-TEX cover], and the laundry detergent was used by LG H & H.
  • the water repellency criterion is based on the AATCC (American Textile Chemical Dyeing Association), and it is classified as 5th grade (without surface adhesion or wetting), 4th grade (with slight adhesion or wetting on the surface), Grades 3 (wetting where the water dropped), 2nd (partial wetting over the entire surface), and 1st level (wetting the surface completely).
  • Vinegar was used brewed vinegar (natural food).
  • the fabrication process of the fabric softener composition was performed in the same manner as in the above embodiment except that a cationic surfactant was added instead of citric acid.
  • the cationic surfactant was Polymer LR30M manufactured by DOW Chemical.
  • Example 26 Cationic surfactant 5 - - - - - - Citric acid - 2 5 20 20 20 Thickening Polymer 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spices 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 ethanol 5 5 5 5 5 5 5 Fragrance Solubilizer 5 5 5 5 5 5 5 Antifoam 0.05 0.05 0.05 0.05 0.05 vinegar - - - - - 1.0 Flower Fermented Vinegar - - - - 0.5 0.5 Purified water Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight
  • Washing test conditions were based on the test method in EL306 (Fiber Softener) among the environmental label certification criteria of the Korea Environmental Industry and Technology Institute.
  • the amount of the composition was 0.67 mL / L at the last rinsing.
  • the sensory evaluation of the replaced odor removal ability was not good, but was lower than 4 points of citric acid and / or flower fermentation.
  • the replaced odor removal ability was excellent with a sensory evaluation of 4 or more points.

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Abstract

The present invention relates to a composition for a fabric softener which contains a pH regulator, does not contain a cationic surfactant, and yields no more than 90 ppm of calcium carbonate remaining in fabric that has undergone washing and rinsing according to a testing method by environmental label EL306, and the composition for the fabric softener very effectively dissolves and removes calcium carbonate, which is detergent-insoluble, from fabric. The present invention relates to a composition for a fabric softener which contains a pH regulator, does not contain a cationic surfactant, and yields no more than 20 ppm of zeolite remaining in fabric that has undergone washing and rinsing according to a testing method by environmental label EL306, and the composition for the fabric softener very effectively dissolves and removes zeolite, which is detergent-insoluble, from fabric. The present invention relates to a composition for a fabric softener which contains a pH regulator, does not contain a cationic surfactant, and yields a friction coefficient of 2 to 25 in fabric that has undergone washing and rinsing according to a testing method by environmental label EL306, thereby achieving a dry and fluffy sensation after use, instead of a slippery sensation, of the dried article. Also, the composition for the fabric softener, according to the present invention, uses the pH regulator instead of the cationic surfactant, which is harmful to the body, thereby having excellent water-repellent/moisture-permeable effects in Gore-Tex outdoor clothing. Also, the present invention can effectively remove damp odor after washing by using an organic acid instead of the cationic surfactant.

Description

섬유유연제 조성물Fabric softener composition

본 발명은 섬유유연제 조성물에 관한 것이다. The present invention relates to a fabric softener composition.

섬유유연제는 의류에 발생하는 정전기를 방지하고 섬유의 유연성을 부여하기 위하여 가정에서 널리 사용하고 있으며, 그 사용량이 점차 증가하고 있는 추세이다. 최근에는 소비자의 생활 수준이 향상되고, 위생 및 청결에 대한 욕구가 증가하며, 보다 쾌적한 의생활을 추구하려 함에 따라, 의류에 발생할 수 있는 미생물의 증식방지 및 악취제거에 대한 관심이 늘고 있다. Fabric softeners are widely used in homes to prevent static electricity generated in clothing and to give the flexibility of the fiber, the amount of use is increasing gradually. In recent years, as consumer's living standard is improved, the desire for hygiene and cleanliness is increased, and the pursuit of a more comfortable medical life, there is a growing interest in preventing the growth of microorganisms that can occur in clothing and removing odors.

일반적으로 섬유에 발생하는 꿉꿉한 냄새는 땀냄새 등의 성분인 유기화합물이 피부 상재균이 분해되어 생성된 불포화 저급 지방산 및 암모니아 등의 휘발성 유기화합물과 반응하거나 세탁세제 또는 섬유유연제 잔류성분과 반응하여 발생될 수 있다. 특히 장마철의 경우, 실내 건조시 건조시간이 지연되므로 악취균인 Morxella asloensis로 인해 꿉꿉한 냄새가 더 발생하고 있는 것으로 알려졌다. In general, the altered odor that occurs in fibers is caused by the reaction of organic compounds, such as sweat odors, with volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners. Can be. In particular, in the rainy season, drying time is delayed when drying indoors, and it is known that the odor caused by Morxella asloensis is more likely to occur.

이러한 꿉꿉한 냄새 등을 제거하기 위하여, 종래에는 항균제를 포함하는 섬유유연제 조성물을 사용했는데, 종래 섬유유연제에 포함되는 항균제는 인체에 유해하다. 최근에는 합성 항균제 사용시 인체에 유해하다는 내용이 보도됨에 따라 이러한 항균제의 사용이 기피되고 있는 실정이다. In order to remove such a odor, a conventional softening agent composition containing an antimicrobial agent was used, but the antimicrobial agent included in the conventional softening agent is harmful to the human body. Recently, the use of such antimicrobial agents has been avoided due to the fact that the use of synthetic antimicrobial agents is reported to be harmful to the human body.

또한 섬유유연제는 1950년 대에 전 세계적으로 상용화된 이후로 60년이 넘도록 유연성분으로 양이온 계면활성제를 사용하고 있다[한국공개특허 제10-2007-0090861호]. 그러나, 근래에 들어 이러한 양이온 계면활성제의 인체 유해성이 밝혀져 이를 기피하고자 하는 욕구가 증가하고 있다.In addition, the fabric softener has been using a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861]. However, recently, the human hazard of such cationic surfactants has been revealed, and the desire to avoid them is increasing.

본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 섬유 내 잔존하는 세제 불용성 성분인 탄산칼슘의 용해 및 제거 효과가 우수한 섬유유연제 조성물을 제공하는 것을 목적으로 한다.An object of the present invention is to provide a fabric softener composition having excellent dissolving and removing effects of calcium carbonate, which is a detergent insoluble component remaining in the fiber, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.

또한, 본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 섬유 내 잔존하는 세제 불용성 성분인 제올라이트의 용해 및 제거 효과가 우수한 섬유유연제 조성물을 제공하는 것을 다른 목적으로 한다.Another object of the present invention is to provide a fabric softener composition having excellent dissolution and removal effect of zeolite, which is a detergent-insoluble component remaining in the fiber, without using a cationic surfactant, which has been included as a flexible component in the conventional fabric softener composition. .

또한, 본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수가 2 내지 25를 가짐으로써, 상기 건조된 피검체가 미끈거리지 않고 뽀송뽀송한 느낌을 줄 수 있는 섬유유연제 조성물을 제공하는 것을 또 다른 목적으로 한다.In addition, the present invention has a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of the environmental mark EL306, without using a cationic surfactant that was included as a flexible component in the conventional fabric softener composition, the drying Another object of the present invention is to provide a fabric softener composition which can give a smooth feeling to a subject without being slippery.

또한, 본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 고어텍스 아웃도어 의류의 발수/투습 효과가 우수한 섬유유연제 조성물을 제공하는 것을 또 다른 목적으로 한다.Another object of the present invention is to provide a fabric softener composition having excellent water repellency / moisture permeability of Gore-Tex outdoor clothing, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.

또한, 본 발명은 종래 섬유유연제 조성물에 유연성분으로 포함되던 양이온 계면활성제를 사용하지 않고, 유기산을 첨가하여 세탁 후 꿉꿉한 냄새를 제거할 수 있는 섬유유연제 조성물을 제공하는 것을 또 다른 목적으로 한다.Another object of the present invention is to provide a fabric softener composition capable of removing odors changed after washing by adding an organic acid without using a cationic surfactant, which is included as a flexible component in a conventional fabric softener composition.

상기 목적을 달성하기 위하여, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 탄산칼슘의 함량이 90 ppm 이하인 섬유유연제 조성물을 제공한다. In order to achieve the above object, the present invention includes a pH adjusting agent, does not include a cationic surfactant, the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 90 ppm or less It provides a fabric softener composition.

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 제올라이트의 함량이 20 ppm 이하인 섬유유연제 조성물을 제공한다.The present invention also provides a fabric softener composition containing a pH adjusting agent, no cationic surfactant, and a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less. .

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수가 2 내지 25인 섬유유연제 조성물을 제공한다. The present invention also provides a fabric softener composition comprising a pH adjuster, no cationic surfactant, and a coefficient of friction of 2 to 25 fibers after washing and rinsing according to the test method of environmental mark EL306.

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며, 환경마크 EL306에 따른 사용량으로 헹굼/탈수를 5회 반복한 후 발수도 4급 이상을 갖는 섬유유연제 조성물을 제공한다. The present invention also provides a fabric softener composition including a pH adjuster, no cationic surfactant, and having a water repellency degree of 4 or higher after rinsing / dehydrating 5 times with an amount according to the environmental mark EL306.

또한, 본 발명은 유기산을 포함하고, 양이온 계면활성제를 포함하지 않으며, 환경마크 EL306에 따라 세탁완료 후 건조온도 30℃, 상대습도 80%의 조건에서 24시간 방치 시 꿉꿉한 냄새의 5점 척도 관능평가가 4점 이상인 섬유유연제 조성물을 제공한다.In addition, the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 ℃, 80% relative humidity The fabric softener composition which has an evaluation of 4 or more points is provided.

본 발명에 따른 섬유유연제 조성물은 섬유 내 잔존하는 세제 불용성 성분인 탄산칼슘의 용해 및 제거, 세제 불용성 성분인 제올라이트의 용해 및 제거에 탁월하다. The fabric softener composition according to the present invention is excellent for dissolving and removing calcium carbonate, which is a detergent insoluble component remaining in fibers, and for dissolving and removing zeolite, a detergent insoluble component.

또한, 본 발명에 따른 섬유유연제 조성물을 이용하여 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수가 2 내지 25의 수치를 가짐으로써, 상기 건조된 피검체는 미끈거리지 않고 뽀송뽀송한 느낌을 줄 수 있다.In addition, by using the fabric softener composition according to the present invention having a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of environmental mark EL306, the dried subject is not slippery and smooth I can give a feeling.

또한, 본 발명에 따른 섬유유연제 조성물은 인체에 유해한 양이온성 계면활성제 대신, pH 조절제를 사용하여 인체에 유해하지 않으면서 기존 양이온성 계면활성제를 사용한 섬유유연제 보다 고어텍스 아웃도어 의류의 발수/투습 효과를 향상시킬 수 있다. In addition, the fabric softener composition according to the present invention, instead of the cationic surfactant harmful to the human body, the water repellent / moisture permeability effect of Gore-Tex outdoor clothing than the fabric softener using the conventional cationic surfactant without using a pH adjuster to the human body Can improve.

또한, 본 발명에 따른 섬유유연제 조성물은 양이온 계면활성제를 사용하지 않고, 유기산을 사용하여 세탁 후 꿉꿉한 냄새를 효과적으로 제거할 수 있다.In addition, the fabric softener composition according to the present invention can effectively remove the smell replaced after washing using an organic acid without using a cationic surfactant.

본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,The present invention includes a pH adjusting agent, does not include a cationic surfactant,

환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 탄산칼슘의 함량이 90 ppm 이하인 섬유유연제 조성물(이하, 제 1 섬유유연제 조성물)에 관한 것이다. The present invention relates to a fiber softener composition (hereinafter referred to as a first fabric softener composition) having a content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 90 ppm or less.

상기 EL306의 시험방법은 EL306 내 시험방법 중 유연성 시험 방법에 따라 세탁 및 헹굼을 수행할 수 있다. The test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.

본 발명에서 pH 조절제는 세제 찌꺼기 제거 역할을 수행할 수 있다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행할 수 있다.In the present invention, the pH adjusting agent may serve to remove detergent residues. In addition, the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).

상기 pH 조절제는 유기산일 수 있다. 이러한 유기산의 종류는 특별히 제한되지 않으며, 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 그룹으로부터 선택된 하나 이상을 포함할 수 있다.The pH adjusting agent may be an organic acid. The kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.

상기 pH 조절제의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 1 내지 30 중량%, 5 내지 20 중량%, 또는 8 내지 15 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 탄산칼슘 제거 효과를 나타낼 수 있다. pH 조절제의 함량이 30 중량%를 초과해도 우수한 탄산칼슘 제거 효과를 나타내나, pH 조절제의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다. The content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.

본 발명에 따른 섬유유연제 조성물은 양이온 계면활성제를 포함하지 않아도 세제 찌꺼기 제거 효과가 우수하므로, 섬유유연제로 용이하게 사용할 수 있다. The fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.

일 구체예에서, 본 발명에서 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 탄산칼슘의 함량은 90 ppm 이하, 65 ppm 이하, 50 ppm 이하, 45 ppm 이하, 40 ppm 이하, 37 ppm 이하 또는 0 ppm일 수 있다.In one embodiment, the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 in the present invention is 90 ppm or less, 65 ppm or less, 50 ppm or less, 45 ppm or less, 40 ppm or less, Or less than 37 ppm or 0 ppm.

또한, 본 발명에서 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 탄산칼슘을 5 내지 300 ppm, 10 내지 250 ppm, 또는 30 내지 200 ppm 제거할 수 있다. In addition, in the present invention, the calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 may be removed from 5 to 300 ppm, 10 to 250 ppm, or 30 to 200 ppm.

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,In addition, the present invention includes a pH adjusting agent, does not include a cationic surfactant,

환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 제올라이트의 함량이 20 ppm 이하인 섬유유연제 조성물(이하, 제 2 섬유유연제 조성물)에 관한 것이다. The present invention relates to a fabric softener composition (hereinafter referred to as a second fabric softener composition) having a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 20 ppm or less.

상기 EL306의 시험방법은 EL306 내 시험방법 중 유연성 시험 방법에 따라 세탁 및 헹굼을 수행할 수 있다.The test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.

본 발명에서 pH 조절제는 세제 찌꺼기, 구체적으로 제올라이트의 제거 역할을 수행할 수 있다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행할 수 있다.In the present invention, the pH adjusting agent may serve to remove detergent residues, specifically zeolite. In addition, the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).

상기 pH 조절제는 유기산일 수 있다. 이러한 유기산의 종류는 특별히 제한되지 않으며, 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 그룹으로부터 선택된 하나 이상을 포함할 수 있다.The pH adjusting agent may be an organic acid. The kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.

상기 pH 조절제의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 1 내지 30 중량%, 5 내지 20 중량%, 또는 8 내지 15 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 제올라이트 제거 효과를 나타낼 수 있다. pH 조절제의 함량이 30 중량%를 초과해도 우수한 제올라이트 제거 효과를 나타내나, pH 조절제의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다. The content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It is possible to exhibit an excellent zeolite removal effect within the above range. Although the zeolite removal effect is excellent even if the content of the pH regulator exceeds 30% by weight, the pH of the rinsing water is lower as the content of the pH regulator is higher, it is better to use less than 30% by weight.

본 발명에 따른 섬유유연제 조성물은 양이온 계면활성제를 포함하지 않아도 세제 찌꺼기 제거 효과가 우수하므로, 섬유유연제로 용이하게 사용할 수 있다. The fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.

일 구체예에서, 본 발명은 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 제올라이트의 함량은 20 ppm 이하, 10 ppm 이하 8 ppm 이하, 7 ppm 이하, 3 ppm 이하 또는 0 ppm일 수 있다.In one embodiment, the present invention, the content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less, 10 ppm or less, 8 ppm or less, 7 ppm or less, 3 ppm or 0 ppm Can be.

또한, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유에 잔존하는 제올라이트를 5 내지 300 ppm, 10 내지 250 ppm, 또는 30 내지 200 ppm 제거할 수 있다. In addition, it is possible to remove 5 to 300 ppm, 10 to 250 ppm, or 30 to 200 ppm of the zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306.

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,In addition, the present invention includes a pH adjusting agent, does not include a cationic surfactant,

환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수가 2 내지 25인 섬유유연제 조성물(이하, 제 3 섬유유연제 조성물)에 관한 것이다. The present invention relates to a fabric softener composition (hereinafter referred to as a third fabric softener composition) having a friction coefficient of 2 to 25 after finishing washing and rinsing according to the test method of environmental mark EL306.

상기 EL306의 시험방법은 EL306 내 시험방법 중 유연성 시험 방법에 따라 세탁 및 헹굼을 수행할 수 있다.The test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.

본 발명에서 pH 조절제는 세제 찌꺼기 제거 역할을 수행할 수 있다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행할 수 있다.In the present invention, the pH adjusting agent may serve to remove detergent residues. In addition, the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).

상기 pH 조절제는 유기산일 수 있다. 이러한 유기산의 종류는 특별히 제한되지 않으며, 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 그룹으로부터 선택된 하나 이상을 포함할 수 있다.The pH adjusting agent may be an organic acid. The kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.

상기 pH 조절제의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 1 내지 30 중량%, 5 내지 20 중량%, 또는 8 내지 15 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 탄산칼슘 제거 효과를 나타낼 수 있다. pH 조절제의 함량이 30 중량%를 초과해도 우수한 탄산칼슘 제거 효과를 나타내나, pH 조절제의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다. The content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.

본 발명에 따른 섬유유연제 조성물은 양이온 계면활성제를 포함하지 않아도 세제 찌꺼기 제거 효과가 우수하므로, 섬유유연제로 용이하게 사용할 수 있다. The fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.

일 구체예에서, 본 발명에 따른 섬유유연제 조성물을 이용하여 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수는 2 내지 25, 10 내지 25, 또는 20 내지 23일 수 있다. 상기 마찰계수 범위에서 건조된 피검체는 미끈거리지 않고 뽀송뽀송한 느낌을 줄 수 있다. 여기서, 상기 피검체는 의류 등의 섬유유연제의 대상이 되는 것일 수 있다. In one embodiment, the coefficient of friction of the fibers after washing and rinsing according to the test method of environmental mark EL306 using the fabric softener composition according to the present invention may be 2 to 25, 10 to 25, or 20 to 23. The subject dried in the friction coefficient range may give a smooth feeling without slipping. Here, the subject may be an object of a fabric softener such as clothing.

또한, 본 발명은 pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며, 환경마크 EL306에 따른 사용량으로 헹굼/탈수를 5회 반복한 후 발수도 4급 이상을 갖는 섬유유연제 조성물(이하, 제 4 섬유유연제 조성물)에 관한 것이다.In addition, the present invention includes a fabric softener composition containing a pH adjuster, does not contain a cationic surfactant, water repellency degree 4 or more after repeated rinsing / dehydration five times with the amount according to the environmental mark EL306 (hereinafter, 4 fabric softener composition).

본 발명에 따른 섬유유연제 조성물은 전술한 바와 같이, pH 조절제를 포함한다. The fabric softener composition according to the present invention, as described above, includes a pH adjusting agent.

본 발명에서 pH 조절제는 고어텍스 아웃도어 의류의 발수/투습 역할을 수행한다. 상기 pH 조절제는 유기산일 수 있다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행한다. 이러한 유기산의 종류는 특별히 제한되지 않으며, 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 군에서 선택된 하나 이상을 포함할 수 있다. 특히, 구연산은 원재료비의 단가가 낮으므로 유기산으로 사용하기에 적합하다.In the present invention, the pH adjusting agent plays a role of water repellency / moisture permeability of Gore-Tex outdoor clothing. The pH adjusting agent may be an organic acid. In addition, the organic acid serves as a softener intrinsic (to soften the cloth and to feel good). The type of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid, and lactic acid. In particular, citric acid is suitable for use as an organic acid because the cost of raw materials is low.

상기 pH 조절제의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 30 중량%, 0.1 내지 20 중량% 또는 1 내지 15 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 고어텍스 아웃도어 의류의 발수/투습 효과를 나타낼 수 있다. 유기산의 함량이 30 중량% 이상에서도 우수한 고어텍스 아웃도어 의류의 발수/투습 효과를 나타내나, 유기산의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다. The content of the pH adjusting agent is not particularly limited, and may be included in an amount of 0.01 to 30% by weight, 0.1 to 20% by weight or 1 to 15% by weight based on 100% by weight of the fabric softener composition. Within the above range can exhibit excellent water repellent / moisture permeability of Gore-Tex outdoor clothing. Even if the content of the organic acid is more than 30% by weight of the excellent Gore-Tex outdoor clothing exhibits a water-repellent / moisture-permeable effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.

상술한 본 발명에 따른 조성물은 양이온 계면활성제를 포함하지 않아도 고어텍스 아웃도어 의류의 발수/투습 효과가 우수하여 섬유유연제로 용이하게 사용할 수 있다.Even if the composition according to the present invention does not contain a cationic surfactant, the Gore-Tex outdoor clothing can be easily used as a fabric softener because of excellent water / moisture permeability.

일 구체예에서, 본 발명에 따른 섬유유연제 조성물은 환경마크 EL306에 따른 사용량으로 헹굼/탈수를 5회 반복한 후 발수도 4급 이상을 갖는다.In one embodiment, the fabric softener composition according to the present invention has a water repellency of 4 or more after repeated rinsing / dehydrating 5 times with the amount according to the environmental mark EL306.

또한, 본 발명은 유기산을 포함하고, 양이온 계면활성제를 포함하지 않으며, 환경마크 EL306에 따라 세탁완료 후 건조온도 30℃, 상대습도 80%의 조건에서 24시간 방치 시 꿉꿉한 냄새의 5점 척도 관능평가가 4점 이상인 섬유유연제 조성물(이하, 제 5 섬유유연제 조성물)에 관한 것이다.In addition, the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 ℃, 80% relative humidity The evaluation relates to a fibrous softener composition (hereinafter referred to as a fifth fibrous softener composition) having four or more points.

본 발명의 섬유유연제 조성물은 양이온 계면활성제 대신 유기산을 사용하여 세탁 후 꿉꿉한 냄새를 제거한 것을 특징으로 한다.The fabric softener composition of the present invention is characterized in that an organic acid is used instead of the cationic surfactant to remove the smell after washing.

본 발명에서 유기산은 세제 찌꺼기, 구체적으로 탄산칼슘 제거 역할을 수행한다. 또한, 상기 유기산은 유연제 본연의(옷감을 부드럽게 하고 촉감을 좋게 하는) 역할을 수행한다.In the present invention, the organic acid serves to remove detergent residues, specifically calcium carbonate. In addition, the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).

상기 유기산은 예를 들어, 구연산, 초산, 주석산, 호박산, 사과산 또는 젖산 등을 하나 이상 사용할 수 있으나, 이에 특별히 제한하는 것은 아니다. 바람직하게는, 유기산은 구연산일 수 있다. 상기 구연산은 원재료비의 단가가 낮으므로 섬유유연제 조성물의 생산 단가를 절감할 수 있다.The organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid or the like, but is not particularly limited thereto. Preferably, the organic acid may be citric acid. Since citric acid has a low unit cost of raw material costs, it is possible to reduce the production cost of the fabric softener composition.

상기 유기산의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 1 내지 30 중량%, 더 구체적으로, 2 내지 25 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 탄산칼슘 제거 효과를 나타낼 수 있다. 유기산의 함량이 30 중량%를 초과하는 경우에서도 우수한 탄산칼슘 제거 효과를 나타내나, 유기산의 함량이 높아질수록 헹굼수의 pH가 낮아지므로, 30 중량% 이하로 사용하는 것이 좋다.The content of the organic acid is not particularly limited and may be included in an amount of 1 to 30% by weight, more specifically, 2 to 25% by weight, based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight exhibits excellent calcium carbonate removal effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.

본 발명의 섬유유연제 조성물은 양이온 계면활성제 대신 유기산을 사용함으로써 환경마크 EL306에 따라 세탁완료 후 건조온도 30℃, 상대습도 80%의 조건에서 24시간 방치 시 꿉꿉한 냄새의 5점 척도 관능평가가 4점 이상을 나타내어 효과적으로 꿉꿉한 냄새를 제거할 수 있다. 따라서, 섬유유연제로 용이하게 사용할 수 있다.According to the environmental mark EL306, the fabric softener composition of the present invention uses an organic acid instead of a cationic surfactant, and then, after washing for 24 hours at a drying temperature of 30 ° C. and a relative humidity of 80%, a five-point scale sensory evaluation of 4 Shown above the dots can effectively remove the odor. Therefore, it can be used easily as a fabric softener.

본 발명에 따른 섬유유연제 조성물은 전술한 유기산 외에 점도 조절을 위한 증점용 폴리머를 더 포함할 수 있다. The fabric softener composition according to the present invention may further include a thickening polymer for viscosity control in addition to the aforementioned organic acid.

상기 증점용 폴리머로 칼슘-카르복시메틸 셀룰로스, 메틸 셀룰로스/하이드록시프로필메틸셀룰로스, 하이드록시 에틸 셀룰로스, 카보폴 934(carbopol 934), 카보폴 941(carbopol 941), 잔탄검, 소듐 알기네이트, 구아검, 카라기난, 펙틴, 아크릴계 폴리머 등을 사용할 수 있다. 바람직하게는, 아크릴산폴리머류 및 아크릴코폴리머, 아크릴화실리콘계로 이루어진 군에서 선택된 하나 이상의 아크릴계 폴리머가 좋다. The thickening polymers include calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxy ethyl cellulose, carbopol 934, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guar gum. , Carrageenan, pectin, acrylic polymer and the like can be used. Preferably, at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylic acrylates is preferable.

상기 증점용 폴리머의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 1.2 중량%, 보다 구체적으로, 0.05 내지 1 중량%로 포함될 수 있다.The content of the thickening polymer is not particularly limited and may be included as 0.01 to 1.2% by weight, more specifically, 0.05 to 1% by weight based on 100% by weight of the fabric softener composition.

본 발명의 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)에 식초가 추가로 사용될 수 있다. Vinegar may further be used in the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) of the present invention.

식초는 주성분으로 초산을 함유하여 시고 약간 단맛이 있는 조미료로서, 초산, 구연산 및 각종 아미노산 등 수십여 가지 유기산이 들어 있어, 신진대사를 활발하게 하고, 체내 노폐물을 없애는데 도움을 줄 뿐만 아니라, 강력한 방부제이자 강력한 살균제로서의 역할을 수행한다. 또한, 식초는 세제 찌꺼기 제거 역할을 수행할 수 있다.Vinegar is a sour and slightly sweet seasoning that contains acetic acid as its main ingredient, and contains dozens of organic acids such as acetic acid, citric acid and various amino acids, which helps to increase metabolism and remove body wastes, and is a powerful preservative. It serves as a powerful fungicide. In addition, vinegar may serve to remove detergent residues.

상기 식초의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%, 0.5 내지 5 중량% 또는 1 내지 3 중량%로 포함될 수 있다. 상기 범위 내에서 살균 효과 및 세제 찌꺼기를 제거하는 효과를 가진다.The content of the vinegar is not particularly limited and may be included in 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight relative to 100% by weight of the fabric softener composition. It has a bactericidal effect and an effect of removing detergent residues within the above range.

본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 전술한 조성성분 외에 강력한 탈취의 역할을 담당하는 꽃 발효식초를 추가로 포함할 수 있다.The fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a flower fermentation vinegar that plays a role of strong deodorization in addition to the above-mentioned composition.

상기 꽃 발효식초는 꽃잎을 수세 및 건조하고 과량의 식초 및 당물과 혼합하여 3일 내지 7일 동안 발효시켜 얻은 것일 수 있다. The flower fermentation vinegar may be obtained by washing the petals with water, dried and mixed with excess vinegar and sugar fermentation for 3 to 7 days.

상기 식초는 시판되는 양조식초일 수 있으며, 꽃잎 1 중량부에 대하여 5 내지 30 중량부 사용하는 것이 바람직하다. 또한, 상기 당물을 포도당, 설탕, 과당, 올리고당, 또는 물엿 등 각종 당을 포함하는 것일 수 있다. 상기 당물은 꽃 추출물을 알코올 발효시키는 역할을 하며, 꽃잎 1 중량부에 대하여 5 내지 30 중량부를 사용하는 것이 바람직하다.The vinegar may be commercially available vinegar, it is preferable to use 5 to 30 parts by weight based on 1 part by weight of the petals. In addition, the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup. The sugar serves to alcohol ferment the flower extract, it is preferred to use 5 to 30 parts by weight based on 1 part by weight of the petals.

또는, 상기 꽃 발효식초는 꽃 원물을 멸균하고, 100 내지 150℃에서 10 내지 30분 동안 열수 추출한 후 상기의 열수 추출물과 종초 및 당물을 혼합한 후 20 내지 40℃에서 72 내지 96시간 동안 발효 과정을 거쳐 얻을 수 있다.Alternatively, the flower fermentation vinegar is sterilized with the original flower, hot water extracted for 10 to 30 minutes at 100 to 150 ℃ and then mixed with the hot water extract and vinegar and sugar and fermentation process at 20 to 40 ℃ for 72 to 96 hours Can be obtained through

상기 종초는 전통방식으로 제조된 이미(異味), 이취(異臭)가 없는 양조식초에서 분리된 야생식초균을 증식시켜 발효시킨 것을 말하며, 상기 종초는 야생초산균 아세토박터균(Acetobacter sp.)에 의하여 제조될 수 있는 것이면, 모두 사용될 수 있다. 이때, 상기 종초의 첨가량은 꽃 열수 추출물 100 중량%에 대하여 5 내지 30 중량%로 첨가될 수 있다. 상기 종초의 첨가량이 5 중량% 미만일 경우, 상기 숙성된 꽃 열수 추출물의 식초 발효를 유도하기 어렵고, 30 중량%를 초과할 경우 첨가량에 비하여, 식초 발효의 효율이 더 이상 증가하지 않는다. The vinegar refers to fermented by propagating wild vinegar isolated from vinegar, odorless (이미) produced in the traditional manner, the seed vinegar by the acetic acid bacteria Acetobacter sp. Anything that can be produced can be used. At this time, the amount of the seed may be added in 5 to 30% by weight based on 100% by weight of the hydrothermal extract flowers. When the added amount of the vinegar is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged hydrothermal extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation does not increase any more.

상기 당물을 포도당, 설탕, 과당, 올리고당, 또는 물엿 등 각종 당을 포함하는 것일 수 있다. 상기 당물은 꽃 열수 추출물을 알코올 발효시키는 역할을 하며, 꽃 열수 추출물 100 중량%에 대하여 5 내지 30 중량%로 첨가될 수 있다. The sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup. The sugar serves to ferment the flower hydrothermal extract alcohol, and may be added in an amount of 5 to 30% by weight based on 100% by weight of the hydrothermal extract flower.

상기 방법을 통하여 제조된 꽃 발효식초는 pH가 2.70 내지 3.30, 산도는 3 내지 7을 가질 수 있다.Flower fermentation vinegar prepared by the above method may have a pH of 2.70 to 3.30, the acidity of 3 to 7.

상기 꽃 발효식초 제조에 사용하는 꽃의 종류는 제한 없이 사용할 수 있다. 일예로, 도화꽃, 살구꽃, 아카시아꽃, 카모마일꽃, 자스민꽃 또는 연꽃 등을 사용할 수 있다.Types of flowers used for the flower fermentation vinegar can be used without limitation. For example, a peach blossom, an apricot blossom, an acacia blossom, a chamomile blossom, a jasmine blossom or a lotus blossom can be used.

상기 꽃 발효식초의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.001 내지 10 중량%, 0.05 내지 5 중량% 또는 0.1 내지 2 중량%로 포함될 수 있다. 상기 범위 내에서 살균 작용 및 냄새를 제거하는 효과를 가진다.The content of the flower fermentation vinegar is not particularly limited and may be included in 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight relative to 100% by weight of the fabric softener composition. It has an effect of removing bactericidal action and odor within the above range.

또한, 본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 내용물의 상 안정성을 위해 에탄올을 추가로 포함할 수 있다. In addition, the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include ethanol for phase stability of the contents.

상기 에탄올의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%, 0.5 내지 8 중량% 또는 1 내지 7 중량%로 포함될 수 있다. 상기 범위 내에서 우수한 내용물의 상 안정성 효과를 가진다.The content of the ethanol is not particularly limited, and may be included in 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition. It has a phase stability effect of excellent contents within the above range.

또한, 본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 향료를 추가로 사용할 수 있다. 상기 향료는 예를 들어 플로랄계 향료, 시트러스계 향료 등을 포함할 수 있으나, 이외에 섬유유연제로 사용할 수 있는 것이라면 본 발명의 효과를 저해하지 않는 범위 내에서 제한 없이 사용될 수 있다. 상기 향료의 함량은 특별히 제한되지 않으며 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 5 중량% 또는 0.1 내지 3 중량%로 포함될 수 있다.In addition, the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance. The fragrance may include, for example, a floral fragrance, a citrus fragrance, or the like, but may be used without limitation within a range that does not impair the effects of the present invention if it can be used as a fabric softener. The amount of the perfume is not particularly limited and may be included in 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.

또한, 본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 향가용화제를 추가로 사용할 수 있으며, 향가용화제는 발효식초 등에 의한 식초취를 완화시켜 섬유유연제의 향취 만족도를 향상시킨다. 이의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량% 또는 1 내지 7 중량%로 포함될 수 있다.In addition, the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance solubilizer, the fragrance solubilizer is vinegar odor by fermentation vinegar, etc. It alleviates the fragrance satisfaction of the fabric softener. Its content is not particularly limited and may be included in 0.1 to 10% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition.

또한, 본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 식초취 등의 악취제거 효과를 향상시키기 위하여 식물추출물을 추가로 포함할 수 있다. 상기 식물추출물은 감잎, 녹차 및 진피로 이루어진 그룹으로부터 선택된 하나 이상을 포함할 수 있다. In addition, the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a plant extract to improve the odor removal effect such as vinegar odor. The plant extract may include one or more selected from the group consisting of persimmon leaves, green tea and dermis.

또한, 본 발명에 따른 섬유유연제 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)에는 본 발명의 목적범위 내에서 소량의 첨가제가 더 포함될 수 있다. 상기 첨가제로는 항균 효과를 더욱 향상시키기 위한 항균 성분일 수 있으며, 이외에도, 색소, 방부제, 산화방지제, 소포제 등일 수 있다. 첨가제의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 5 중량% 또는 0.1 내지 3 중량%로 포함될 수 있다.In addition, the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a small amount of additives within the scope of the present invention. The additive may be an antimicrobial component for further improving the antimicrobial effect. In addition, the additive may be a pigment, a preservative, an antioxidant, an antifoaming agent, and the like. The content of the additive is not particularly limited, and may be included in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.

또한, 본 발명의 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 각각의 제형에 상기 기재한 성분들 이외에 일반적으로 섬유유연제에 배합되는 유분, 물, 계면활성제, 보습제, 저급알코올, 증점제, 킬레이트제, 색소, 방부제 등을 필요에 따라 적절히 배합하여 사용할 수 있다. 이의 함량은 특별히 제한되지 않으며, 섬유유연제 조성물 100 중량%에 대하여 55 내지 90 중량% 또는 60 내지 85 중량%로 포함될 수 있다.In addition, the compositions of the present invention (first, second, third, fourth or fifth fibrous softener compositions) are generally formulated with fibrous softeners in addition to the components described above in their respective formulations, water, surfactants, A moisturizer, a lower alcohol, a thickener, a chelating agent, a pigment | dye, a preservative, etc. can be mix | blended suitably as needed, and can be used. The content thereof is not particularly limited, and may be included in an amount of 55 to 90 wt% or 60 to 85 wt% based on 100 wt% of the fabric softener composition.

본 발명에 따른 조성물(제 1, 제 2, 제 3, 제 4 또는 제 5 섬유유연제 조성물)은 당업계에 공지된 방법을 이용하여 분말, 과립화하여 사용할 수 있으며, 액체상태로 제조하여 사용할 수도 있다.The composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may be used by powder, granulation using a method known in the art, may be prepared in a liquid state have.

실시예 1~9Examples 1-9

하기 표 1의 함량(중량%) 구성을 가지는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having a content (weight%) of the composition of Table 1.

먼저, 정제수에 유기산, 식초, 꽃발효식초를 넣고 30 분간 교반한 후, 여기에 에탄올, 향료, 향가용화제 및 소포제를 용해한 용액을 투입하고 30 분간 교반하여 섬유유연제 조성물을 제조하였다. First, an organic acid, vinegar, and fermented vinegar were added to purified water, followed by stirring for 30 minutes. Then, a solution in which ethanol, a fragrance, a solubilizer, and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.

pH 조절제로는 유기산 중 구연산, 초산, 사과산, 주석산, 호박산 또는 젖산을 사용하였다.As pH adjusting agent, citric acid, acetic acid, malic acid, tartaric acid, succinic acid or lactic acid among organic acids were used.

식초는 양조식초(천연식품)를 사용하였다.Vinegar was used brewed vinegar (natural food).

또한, 꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후, 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다. In addition, the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.

비교예 1 Comparative Example 1

섬유유연제 조성물 대신 물을 사용하였다.Water was used instead of the fabric softener composition.

비교예 2 Comparative Example 2

섬유유연제 조성물 대신 지표섬유유연제를 사용하였다. An indicator fiber softener was used instead of the fabric softener composition.

상기 지표섬유유연제는 LG생활건강의 TEA Ester Quaternary로 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 의해 제조하였다.The indicator fabric softener was produced by the test method in EL306 (fiber softener) of the environmental label certification standard of Korea Environmental Industry and Technology Institute as TEA Ester Quaternary of LG H & H.

비교예 3 Comparative Example 3

하기 표 1의 함량(중량%) 구성을 가지는 섬유유연제 조성물을 제조하였다.To prepare a fabric softener composition having a content (weight%) of the composition of Table 1.

양이온 계면활성제는 TEA Ester Quaternary(INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%)를 사용하였다.The cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).

표 1 구분 실시예 1 실시예 2 실시예 3 실시예 4 실시예 5 실시예 6 실시예 7 실시예 8 실시예 9 비교예 3 구연산 20 5 - - - - - 5 5 - 초산 - - 5 - - - - - - - 사과산 - - - 5 - - - - - - 주석산 - - - - 5 - - - - - 호박산 - - - - - 5 - - - - 젖산 - - - - - - 5 - - - 양이온 계면활성제 - - - - - - - - - 5 꽃발효식초 - - - - - - - 1 1 - 식초 - - - - - - - - 1 향료 0.5 에탄올 5 향가용화제 5 소포제 0.05 정제수 100 중량% 까지 Table 1 division Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Comparative Example 3 Citric acid 20 5 - - - - - 5 5 - Acetic acid - - 5 - - - - - - - Malic acid - - - 5 - - - - - - Tartaric acid - - - - 5 - - - - - Succinic acid - - - - - 5 - - - - Lactic acid - - - - - - 5 - - - Cationic surfactant - - - - - - - - - 5 Flower Fermented Vinegar - - - - - - - One One - vinegar - - - - - - - - One Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight

실험예 1; 세탁 후 의류 내 잔존탄산칼슘의 함량 측정Experimental Example 1; Determination of the amount of calcium carbonate remaining in clothing after washing

전술한 실시예 및 비교예에 의해 제조된 섬유유연제 조성물을 사용하여 세탁 헹굼 후 의류 내 잔존하는 탄산칼슘의 함량을 측정하였다. The content of calcium carbonate remaining in the garment after washing and rinsing was measured using the fabric softener composition prepared by the above-described examples and comparative examples.

의류는 KS K 0905에 규정된 백색 표준 면포(10 X 10 cm) 3장을 사용하였고, 세탁세제는 시중에서 쉽게 구입 가능한 탄산칼슘이 함유된 분말 세제(LG 생활건강, 테크)를 사용하였다.The garments used three white standard cotton cloths (10 X 10 cm) as specified in KS K 0905, and the laundry detergents were powdered detergent (LG Health, Tech) containing calcium carbonate, which is readily available on the market.

세탁은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 섬유유연제 조성물의 사용량은 0.67 mL/L였다.Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.

세탁 헹굼 후 의류 내 탄산칼슘 잔류량에 대한 분석은 세탁 헹굼이 완료된 면포를 0.5 g 분취해 염산/불산/질산/붕산의 혼합액으로 산 처리한 후, 24시간 추출해 ICP(고주파 유도 결합 플라스마)를 이용해 분석하였다. Analysis of calcium carbonate residue in the garment after washing rinsing was performed using 0.5 g aliquots of cotton rinsed garments, acid-treated with a mixture of hydrochloric acid, hydrofluoric acid, nitric acid and boric acid, and then extracted for 24 hours and analyzed using ICP (High Frequency Inductively Coupled Plasma). It was.

상기 의류 내 잔존 탄산칼슘 함량(ppm) 측정 결과를 하기 표 2 및 3에 나타냈다.The residual calcium carbonate content (ppm) measurement results in the garments are shown in Tables 2 and 3 below.

표 2 구분 실시예 1 실시예 2 실시예 3 실시예 4 실시예 5 실시예 6 실시예 7 실시예 8 실시예 9 탄산칼슘 함량 0 37 65 45 40 56 50 25 30 TABLE 2 division Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Calcium Carbonate Content 0 37 65 45 40 56 50 25 30

표 3 구분 비교예 1 비교예2 비교예 3 탄산칼슘 함량 155 158 150 TABLE 3 division Comparative Example 1 Comparative Example 2 Comparative Example 3 Calcium Carbonate Content 155 158 150

물 또는 지표섬유유연제로 헹군 비교예 1 및 2의 경우, 세탁세제 불용성분인 탄산칼슘을 제거하지 못해 의류 내 잔존량이 많았다. 그러나, 유기산을 포함하는 섬유유연제 조성물로 헹군 실시예에서는 상기 섬유유연제 조성물이 탄산칼슘을 용해시켜 의류 내 탄산칼슘의 잔존량이 현저히 낮아짐을 확인할 수 있었다. In Comparative Examples 1 and 2, which were rinsed with water or an indicator fiber softener, calcium carbonate, which is an insoluble ingredient of laundry detergent, could not be removed, and thus the residual amount in clothing was large. However, in the embodiment rinsed with a fiber softener composition containing an organic acid, it was confirmed that the fiber softener composition dissolves calcium carbonate and the residual amount of calcium carbonate in the garment is significantly lowered.

또한, 유기산 중 구연산을 이용한 섬유유연제 조성물의 탄산칼슘 제거 능력이 우수했으며, 유기산과 동량의 양이온 계면활성제를 사용한 비교예 3에서는 탄산칼슘의 제거 효과가 없음을 확인할 수 있었다.In addition, the fiber softener composition using citric acid in the organic acid was excellent in the ability to remove calcium carbonate, and in Comparative Example 3 using the same amount of cationic surfactant as the organic acid, it was confirmed that there was no effect of removing calcium carbonate.

실험예 2: 세탁 후 의류 내 잔존 제올라이트의 함량 측정Experimental Example 2: Determination of the content of the remaining zeolite in the garment after washing

전술한 실시예 및 비교예에 의해 제조된 섬유유연제 조성물을 사용하여 세탁 헹굼 후 의류 내 잔존하는 제올라이트의 함량을 측정하였다. The amount of zeolite remaining in the garment after washing and rinsing was measured using the fabric softener compositions prepared by the above-described examples and comparative examples.

의류는 KS K 0905에 규정된 백색 표준 면포(10 X 10 cm) 3장을 사용하였고, 세탁세제는 시중에서 쉽게 구입 가능한 제올라이트가 함유된 분말 세제(LG 생활건강, 테크)를 사용하였다.The garments used three white standard cotton cloths (10 × 10 cm) as specified in KS K 0905, and the laundry detergent was a powdered detergent (LG Health, Tech) containing zeolite, which is readily available on the market.

세탁은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 섬유유연제 조성물의 사용량은 0.67 mL/L였다.Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.

세탁 헹굼 후 의류 내 제올라이트 잔류량에 대한 분석은 세탁 헹굼이 완료된 면포를 0.5 g 분취해 염산/불산/질산/붕산의 혼합액으로 산 처리한 후, 24시간 추출해 ICP(고주파 유도 결합 플라스마)를 이용해 분석하였다. The analysis of zeolite residue in the garment after washing rinsing was analyzed by using ICP (high frequency inductively coupled plasma) after extracting 0.5 g of the cotton rinsing-washed cotton, acid-treated with a mixture of hydrochloric acid, hydrofluoric acid, nitric acid and boric acid, and extracting for 24 hours. .

상기 의류 내 잔존 제올라이트 함량(ppm) 측정 결과를 하기 표 4 및 5에 나타냈다.The residual zeolite content (ppm) measurement results in the garments are shown in Tables 4 and 5 below.

표 4 구분 실시예 1 실시예 2 실시예 3 실시예 4 실시예 5 실시예 6 실시예 7 실시예 8 실시예 9 제올라이트 함량 0 3 10 7 7 8 8 2 2 Table 4 division Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Zeolite content 0 3 10 7 7 8 8 2 2

표 5 구분 비교예 1 비교예2 비교예 3 제올라이트 함량 52 51 253 Table 5 division Comparative Example 1 Comparative Example 2 Comparative Example 3 Zeolite content 52 51 253

물 또는 지표섬유유연제로 헹군 비교예 1 및 2의 경우, 세탁세제 불용성분인 제올라이트를 제거하지 못해 의류 내 잔존량이 많았다. 그러나, 유기산을 포함하는 섬유유연제 조성물로 헹군 실시예에서는 상기 섬유유연제 조성물이 제올라이트를 용해시켜 의류 내 제올라이트의 잔존량이 현저히 낮아짐을 확인할 수 있었다. 또한, 유기산 중 구연산을 이용한 섬유유연제 조성물의 제올라이트 제거 능력이 우수했으며, 유기산과 동량의 양이온 계면활성제를 사용한 비교예 3에서는 제올라이트의 제거 효과가 없음을 확인할 수 있었다.In Comparative Examples 1 and 2, which were rinsed with water or an indicator fiber softener, the remaining amount in the garment was large because the zeolite which is an insoluble ingredient of the laundry detergent could not be removed. However, in the embodiment rinsed with a fabric softener composition containing an organic acid, it was confirmed that the fiber softener composition dissolves the zeolite, thereby significantly lowering the remaining amount of the zeolite in the garment. In addition, the zeolite removal ability of the fabric softener composition using citric acid in the organic acid was excellent, and in Comparative Example 3 using the same amount of the cationic surfactant with the organic acid, it was confirmed that there is no zeolite removal effect.

실시예 10~15Examples 10-15

하기 표 6의 함량(중량%) 구성을 가지는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having a content (% by weight) of the composition of Table 6.

먼저, 정제수에 셀룰로오즈 계열의 증점용 폴리머를 넣고 용해시시까지 충분히 교반하고, 유기산, 식초, 꽃발효초를 넣고 30 분간 교반한 후, 여기에 에탄올, 향료, 향가용화제 및 소포제를 용해한 용액을 투입하고 30 분간 교반하여 섬유유연제 조성물을 제조하였다.First, add a cellulose-based thickening polymer to purified water, stir until dissolved, add organic acid, vinegar, and fermented vinegar, and stir for 30 minutes, and then add a solution of ethanol, flavor, fragrance solubilizer, and antifoaming agent. And stirred for 30 minutes to prepare a fabric softener composition.

pH 조절제로는 유기산 중 구연산을 사용하였다.Citric acid in organic acid was used as a pH adjuster.

식초는 양조식초(천연식품)를 사용하였다.Vinegar was used brewed vinegar (natural food).

또한, 꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후, 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다.In addition, the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.

비교예 4Comparative Example 4

하기 표 6의 함량(중량%) 구성을 가지는 섬유유연제 조성물을 제조하였다.To prepare a fabric softener composition having a content (% by weight) of the composition of Table 6.

60℃의 정제수에 양이온 계면활성제를 넣어 20 분간 교반하여 섬유유연제 조성물을 제조하였다. A cationic surfactant was added to purified water at 60 ° C. and stirred for 20 minutes to prepare a fabric softener composition.

이때, 양이온 계면활성제는 TEA Ester Quaternary(INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%)를 사용하였다.At this time, the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).

표 6 구분 비교예 4 실시예 10 실시예 11 실시예 12 실시예 13 실시예 14 실시예 15 양이온 계면활성제 5 - - - - - - 구연산 - 20 10 5 1 10 10 꽃발효식초 - - - - - 1 1 식초 - - - - - - 1 향료 0.5 에탄올 5 향가용화제 5 소포제 0.05 정제수 100 중량% 까지 Table 6 division Comparative Example 4 Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Cationic surfactant 5 - - - - - - Citric acid - 20 10 5 One 10 10 Flower Fermented Vinegar - - - - - One One vinegar - - - - - - One Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight

실험예 3: 세탁 후 의류의 마찰계수 측정Experimental Example 3: Measurement of the friction coefficient of the garment after washing

전술한 실시예 및 비교예에 의해 제조된 섬유유연제 조성물을 사용하여 세탁 헹굼 후 의류의 마찰계수를 측정하였다. The coefficient of friction of the garment was measured after washing and rinsing using the fabric softener composition prepared according to the above-described examples and comparative examples.

의류는 KS K 0905에 규정된 백색 표준 면포(10 X 10 cm) 3장을 사용하였고, 세탁세제는 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법 중 지표세제를 사용하였다For clothing, three white standard cotton cloths (10 X 10 cm) specified in KS K 0905 were used, and the laundry detergent used the detergent in the test method in EL306 (Fiber Softener) among the environmental label certification standards of the Korea Institute of Environmental Research and Technology.

세탁은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 섬유유연제 조성물의 사용량은 0.67 mL/L였다.Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.

세탁 후 의류의 마찰계수의 측정 조건은 이동속도 25 cm/min, 추의 무게 160g, 사용 퍼프는 NBR(Nitrile Butadiene Rubber)를 사용해 측정하였다. 측정은 시험판에 처리된 표준면포를 올려놓고 추를 올려놓은 후 일정 속도로 추를 이동시킬 때 발생하는 load를 측정하였다After washing, the conditions of measurement of the coefficient of friction of the garment were measured using a moving speed of 25 cm / min, weight of 160 g, and NBR (Nitrile Butadiene Rubber). The measurement was carried out to measure the load that occurs when the weight is moved at a constant speed after placing the treated standard cotton cloth on the test plate and placing the weight.

미끈거림 지수는 전문 모니터요원 10명에 대해 관능평가로 진행했으며, 5점이 가장 미끈거림으로 평가하였다. The slipperiness index was measured by sensory evaluation of 10 professional monitors, and 5 points were considered as slippery.

상기 의류의 마찰계수 및 미끈거림 지수를 측정하여 그 결과를 하기 표 7에 나타냈다.The friction coefficient and slipperiness index of the garment were measured and the results are shown in Table 7 below.

표 7 구분 비교예 1 비교예 2 비교예 4 실시예 10 실시예 11 실시예 12 실시예 13 실시예 14 실시예 15 미끈거림 지수 1.5 4.5 4.3 3.0 2.9 3.0 3.0 2.9 3.0 마찰계수 55 8 10 23 20 20 21 20 18 TABLE 7 division Comparative Example 1 Comparative Example 2 Comparative Example 4 Example 10 Example 11 Example 12 Example 13 Example 14 Example 15 Slippery index 1.5 4.5 4.3 3.0 2.9 3.0 3.0 2.9 3.0 Coefficient of friction 55 8 10 23 20 20 21 20 18

물로만 헹군 비교예 1은 마찰계수가 증가하고 표면이 너무 거친 반면, 지표섬유유연제로 헹군 비교예 2 및 양이온 계면활성제를 포함하는 섬유유연제로 헹군 비교예 3은 미끈거림이 심한 것으로 나타났다. 양이온 계면활성제를 사용하지 않고, pH 조절제, 즉 유기산을 사용한 실시예의 섬유유연제 조성물을 사용한 경우 의류가 너무 거치거나 너무 미끈거리지 않고, 뽀송뽀송한 느낌을 주었다.Comparative Example 1, which was rinsed only with water, showed an increased friction coefficient and the surface was too rough, whereas Comparative Example 2, which was rinsed with the indicator fiber softener, and Comparative Example 3, which was rinsed with the fabric softener containing a cationic surfactant, showed severe slipperiness. Without the use of cationic surfactants and the fabric softener composition of the example using a pH adjuster, i.e., an organic acid, the garment was not too rough or too slippery, giving a soft feeling.

실시예 16~21Examples 16-21

하기 표 8의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having the composition and content of Table 8.

먼저, 정제수에 구연산, 식초, 꽃 발효식초를 넣고 30분 교반한 후, 여기에 에탄올, 향가용화제 및 소포제를 용해시킨 용액을 투입하고 30분 교반하여 섬유유연제 조성물을 제조하였다.First, citric acid, vinegar, and flower fermentation vinegar were added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent, and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.

또한, pH 조절제로는 유기산 중 구연산 0.1~20 중량%를 사용하였다.In addition, 0.1-20 weight% of citric acid in the organic acid was used as a pH adjuster.

또한, 식초는 양조식초(천연식품)를 사용하였다.In addition, vinegar used brewed vinegar (natural food).

또한, 꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후, 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다.In addition, the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.

비교예 5Comparative Example 5

하기 표 8의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다. To prepare a fabric softener composition having the composition and content of Table 8.

먼저, 정제수에 양이온 계면활성제를 넣고 30분 교반한 후, 여기에 에탄올, 향가용화제 및 소포제를 용해시킨 용액을 투입하고 30분 교반하여 섬유유연제 조성물을 제조하였다.First, a cationic surfactant was added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.

양이온성 계면활성제는 TEA Ester Quaternary(INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%)를 사용하였다.The cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).

표 8 구분(중량%) 실시예 16 실시예 17 실시예 18 실시예 19 실시예 20 실시예 21 비교예 5 꽃발효식초 - - - - 0.5 0.5 - 양이온성 계면활성제 - - - - - - 5 구연산 0.1 1 10 20 10 10 - 식초 - - - - - 1 - 향료 0.5 에탄올 5 향가용화제 5 소포제 0.05 정제수 100 중량% 까지 Table 8 Division (weight%) Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 Comparative Example 5 Flower Fermented Vinegar - - - - 0.5 0.5 - Cationic surfactant - - - - - - 5 Citric acid 0.1 One 10 20 10 10 - vinegar - - - - - One - Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight

실험예 4: 고어텍스 아웃도어 의류의 발수도 측정Experimental Example 4: Measurement of Water Repellency of Gore-Tex Outdoor Clothing

상기 제조된 실시예 및 비교예의 섬유유연제 조성물을 사용하여 고어텍스 아웃도어 의류의 발수도를 측정하였다.The water repellency of Gore-Tex outdoor clothing was measured using the fabric softener compositions of Examples and Comparative Examples.

시험에 사용한 고어텍스는 시중에 판매하는 고어텍스 소재의 의류 [ISUKA의 GORE-TEX cover]를 직접 구입해 사용하였으며, 세탁세제는 LG생활건강 테크를 사용하였다.The Gore-Tex used in the test was purchased directly from the commercial Gore-Tex garment [ISUKA's GORE-TEX cover], and the laundry detergent was used by LG H & H.

발수도 판정기준은 발수도 판정기준은 AATCC(미국 섬유화학염색자협회) 기준이며, 5급(표면에 부착 또는 습윤이 없는 것), 4급(표면에 약간의 부착 또는 습윤을 나타내는 것), 3급(물이 떨어진 자리에 습윤을 나타내는 것), 2급(전 표면에 걸쳐 부분적 습윤을 나타내는 것), 1급(표면이 완전히 습윤된 것)으로 표시하였다.The water repellency criterion is based on the AATCC (American Textile Chemical Dyeing Association), and it is classified as 5th grade (without surface adhesion or wetting), 4th grade (with slight adhesion or wetting on the surface), Grades 3 (wetting where the water dropped), 2nd (partial wetting over the entire surface), and 1st level (wetting the surface completely).

상기 고어텍스 아웃도어 의류의 발수도 측정 결과를 하기 표 9에 나타내었다. The water repellency measurement results of the Gore-Tex outdoor clothing are shown in Table 9 below.

표 9 구분 발수도 등급 실시예 16 4 실시예 17 4 실시예 18 4 실시예 19 4 실시예 20 4 실시예 21 4 비교예 1 4 비교예 2 1 비교예 5 1 Table 9 division Water repellency rating Example 16 4 Example 17 4 Example 18 4 Example 19 4 Example 20 4 Example 21 4 Comparative Example 1 4 Comparative Example 2 One Comparative Example 5 One

상기 표 9에 나타난 바와 같이, 양이온 계면활성제를 사용한 비교예 5의 경우에는 고어텍스 소재에 양이온 계면활성제가 흡착되어 물의 접촉각을 낮춰 발수기능이 현저히 떨어졌고, 지표섬유유연제를 사용한 비교예 2의 경우에도 발수도가 현저히 떨어졌지만, 물만 사용한 비교예 1의 경우나 양이온 계면활성제를 사용하지 않은 실시예 16~21의 경우에는 발수기능이 떨어지지 않음을 확인할 수 있었다.As shown in Table 9, in Comparative Example 5 using a cationic surfactant, the cationic surfactant was adsorbed on the Gore-Tex material to lower the contact angle of water, thereby significantly reducing the water repellency, and in the case of Comparative Example 2 using the surface fiber softener. Although the water repellency was remarkably inferior, in the case of Comparative Example 1 using only water or Examples 16 to 21 without using a cationic surfactant, it was confirmed that the water repellency was not impaired.

실시예 22~26Examples 22-26

하기 표 10의 조성 및 함량을 갖는 섬유유연제 조성물을 제조하였다.To prepare a fabric softener composition having the composition and content of Table 10.

먼저, 정제수에 증점용 폴리머를 넣어 완전 용해 시까지 교반한 다음 여기에 구연산, 식초, 꽃 발효식초를 넣은 후 30분간 교반하고, 여기에 에탄올, 향료, 첨가제를 미리 용해한 용액을 투입해 30분 교반하여 제조하였다. First, add the thickening polymer to purified water and stir until complete dissolution, add citric acid, vinegar, and flower fermentation vinegar to it, and stir for 30 minutes, add ethanol, fragrance, and additives in advance, and stir for 30 minutes. It was prepared by.

상기 첨가제로 향가용화제(5 중량%)와 소포제(0.05 중량%)의 혼합을 사용하였고, 증점용 폴리머로는 아크릴코폴리머(BASF사의 Rheovis FRC)를 사용하였으며, 유기산으로 구연산을 사용하였다. A mixture of a fragrance solubilizer (5% by weight) and an antifoaming agent (0.05% by weight) was used as the additive, and an acrylic copolymer (Rheovis FRC, BASF) was used as a thickening polymer, and citric acid was used as an organic acid.

식초는 양조식초(천연식품)을 사용하였다.Vinegar was used brewed vinegar (natural food).

꽃 발효식초는 자스민 꽃잎을 수세하고 건조한 후 꽃잎 1 중량부 대비 식초 15 중량부 및 당물 15 중량부를 상기 건조된 꽃잎과 혼합하고 약 7일 동안 자연 발효 과정을 거쳐 얻은 것을 사용하였다.Flower fermented vinegar was washed with jasmine petals and dried, and then mixed with 15 parts by weight of vinegar and 15 parts by weight of the dried petals compared to 1 part by weight of the petals and was obtained through a natural fermentation process for about 7 days.

비교예 6 Comparative Example 6

하기 표 10의 함량(중량%) 구성을 가지는 섬유유연제 조성물을 제조하였다.To prepare a fabric softener composition having a content (% by weight) of the composition of Table 10.

섬유유연제 조성물의 제조 과정은 구연산 대신 양이온 계면활성제를 첨가하는 것을 제외하고는 상기 실시예의 과정과 동일하게 수행하였다.The fabrication process of the fabric softener composition was performed in the same manner as in the above embodiment except that a cationic surfactant was added instead of citric acid.

양이온 계면활성제는 DOW Chemical사의 Polymer LR30M를 사용하였다. The cationic surfactant was Polymer LR30M manufactured by DOW Chemical.

표 10 구분(중량%) 비교예6 실시예 22 실시예 23 실시예 24 실시예 25 실시예 26 양이온 계면활성제 5 - - - - - 구연산 - 2 5 20 20 20 증점용 폴리머 0.3 0.3 0.3 0.3 0.3 0.3 향료 0.5 0.5 0.5 0.5 0.5 0.5 에탄올 5 5 5 5 5 5 향가용화제 5 5 5 5 5 5 소포제 0.05 0.05 0.05 0.05 0.05 0.05 식초 - - - - - 1.0 꽃 발효식초 - - - - 0.5 0.5 정제수 100중량%까지 100중량%까지 100중량%까지 100중량%까지 100중량%까지 100중량%까지 Table 10 Division (weight%) Comparative Example 6 Example 22 Example 23 Example 24 Example 25 Example 26 Cationic surfactant 5 - - - - - Citric acid - 2 5 20 20 20 Thickening Polymer 0.3 0.3 0.3 0.3 0.3 0.3 Spices 0.5 0.5 0.5 0.5 0.5 0.5 ethanol 5 5 5 5 5 5 Fragrance Solubilizer 5 5 5 5 5 5 Antifoam 0.05 0.05 0.05 0.05 0.05 0.05 vinegar - - - - - 1.0 Flower Fermented Vinegar - - - - 0.5 0.5 Purified water Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight

실험예 5: 세탁 후 관능평가Experimental Example 5: Sensory evaluation after washing

상기 제조된 실시예 및 비교예의 섬유유연제 조성물을 사용하여 세탁 후 관능평가를 수행하였다. Sensory evaluation was performed after washing using the fabric softener compositions of Examples and Comparative Examples.

세탁의류로 KS K 0905에 규정된 백색 표준면포(10×10 cm) 2장을 사용하였고, 사용된 세탁세제는 LG 생활건강 테크를 사용하였다. Two white standard cotton cloths (10 × 10 cm) specified in KS K 0905 were used as laundry clothes, and the laundry detergent used was LG H & H Tech.

세탁실험 조건은 한국환경산업기술원의 환경표지인증기준 중 EL306(섬유유연제) 내 시험방법에 준하며, 마지막 헹굼 시 조성물의 사용량은 0.67 mL/L였다. Washing test conditions were based on the test method in EL306 (Fiber Softener) among the environmental label certification criteria of the Korea Environmental Industry and Technology Institute. The amount of the composition was 0.67 mL / L at the last rinsing.

상기 세탁실험 조건에서 진행된 세탁의류를 건조온도 30℃, 상대습도 80% 항온항습조건에서 24시간 방치한 후 10명의 전문 모니터 요원을 통해 꿉꿉한 냄새를 5점 척도 관능평가를 했으며, 1점은 꿉꿉한 냄새 제거력이 거의 없는 경우이며, 5점이 가장 꿉꿉한 냄새 제거력이 우수함을 나타낸다.After washing the laundry clothing under the test conditions of drying for 24 hours at a drying temperature of 30 ° C. and a relative humidity of 80% at a constant temperature and humidity condition, the sensory evaluation was carried out on a scale of 5 points, and the smell was changed by 10 professional monitors. It is the case that there is little odor removal power, and 5 points shows the excellent odor removal power.

표 11 구분 비교예 1 비교예 2 비교예 6 실시예 22 실시예 23 실시예 24 실시예 25 실시예26 꿉꿉한 냄새 제거력(5점척도) 1.2 1.0 3.0 4.0 4.2 4.8 4.9 5.0 Table 11 division Comparative Example 1 Comparative Example 2 Comparative Example 6 Example 22 Example 23 Example 24 Example 25 Example 26 Odor removal power (five points scale) 1.2 1.0 3.0 4.0 4.2 4.8 4.9 5.0

표 11에 나타난 바와 같이, 유연제를 사용하지 않거나, 지표섬유유연제를 사용하거나, 양이온 계면활성제가 함유된 섬유유연제 조성물에서는 꿉꿉한 냄새 제거력의 관능평가 4점 이하로 좋지 않았으나, 구연산 및/또는 꽃 발효식초가 함유된 조성물에서는 꿉꿉한 냄새 제거력이 관능평가 4점 이상으로 우수하였다.As shown in Table 11, in the fabric softener composition which does not use a softening agent, uses a surface fiber softener, or contains a cationic surfactant, the sensory evaluation of the replaced odor removal ability was not good, but was lower than 4 points of citric acid and / or flower fermentation. In the composition containing vinegar, the replaced odor removal ability was excellent with a sensory evaluation of 4 or more points.

양이온 계면활성제가 함유된 조성물에서는 향료가 사용된 조성물이므로, 미약하게 꿉꿉한 냄새가 일부 마스킹되는 것으로 판단되었다. In the composition containing the cationic surfactant, since the fragrance was used, it was judged that the slightly changed odor was partially masked.

Claims (17)

pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,contains a pH adjusting agent, no cationic surfactant, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 탄산칼슘의 함량이 90 ppm 이하인 섬유유연제 조성물. A fiber softener composition having a content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 90 ppm or less. pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,contains a pH adjusting agent, no cationic surfactant, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유 내 잔존하는 제올라이트의 함량이 20 ppm 이하인 섬유유연제 조성물. A fabric softener composition having a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 20 ppm or less. pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,contains a pH adjusting agent, no cationic surfactant, 환경마크 EL306의 시험방법에 따른 세탁 및 헹굼을 마친 섬유의 마찰계수가 2 내지 25인 섬유유연제 조성물. Fabric softener composition having a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of environmental mark EL306. pH 조절제를 포함하고, 양이온성 계면활성제를 포함하지 않으며,contains a pH adjusting agent, no cationic surfactant, 환경마크 EL306에 따른 사용량으로 헹굼/탈수를 5회 반복한 후 발수도 4급 이상을 갖는 섬유유연제 조성물.Fabric softener composition having a water repellency degree of 4 or more after repeated rinsing / dehydration five times with the amount according to the environmental mark EL306. 제 1 항 내지 제 4 항 중에서 어느 한 항에 있어서,The method according to any one of claims 1 to 4, pH 조절제는 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 군에서 선택된 하나 이상인 섬유 유연제 조성물.pH adjusting agent is at least one selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid. 제 1 항 내지 제 4 항 중에서 어느 한 항에 있어서,The method according to any one of claims 1 to 4, pH 조절제는 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 30 중량%로 포함되는 섬유 유연제 조성물.A pH softening agent composition comprising 0.01 to 30% by weight relative to 100% by weight of the fabric softener composition. 유기산을 포함하고, 양이온 계면활성제를 포함하지 않으며, 환경마크 EL306에 따라 세탁완료 후 건조온도 30℃, 상대습도 80%의 조건에서 24시간 방치 시 꿉꿉한 냄새의 5점 척도 관능평가가 4점 이상인 섬유유연제 조성물.It contains organic acid, does not contain cationic surfactant, and according to environmental mark EL306, the five-point scale sensory evaluation of the changed odor after 4 hours at the drying temperature of 30 ℃ and the relative humidity of 80% is 4 or more. Fabric softener composition. 제 7 항에 있어서,The method of claim 7, wherein 유기산은 구연산, 초산, 주석산, 호박산, 사과산 및 젖산으로 이루어진 그룹으로부터 선택되는 하나 이상을 포함하는 섬유유연제 조성물.The organic softener composition includes at least one selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid. 제 7 항에 있어서,The method of claim 7, wherein 유기산은 섬유유연제 조성물 100 중량%에 대하여 1 내지 30 중량%로 포함되는 섬유유연제 조성물.An organic acid is included in an amount of 1 to 30% by weight relative to 100% by weight of the fabric softener composition. 제 7 항에 있어서,The method of claim 7, wherein 증점용 폴리머를 추가로 포함하는 섬유유연제 조성물.A fabric softener composition further comprising a thickening polymer. 제 10 항에 있어서,The method of claim 10, 증점용 폴리머는 칼슘-카르복시메틸 셀룰로스, 메틸 셀룰로스/하이드록시프로필메틸셀룰로스, 하이드록시 에틸 셀룰로스, 카보폴 934(carbopol 934), 카보폴 941(carbopol 941), 잔탄검, 소듐 알기네이트, 구아검, 카라기난, 펙틴 및 아크릴계 폴리머로 이루어진 그룹으로부터 선택되는 하나 이상을 포함하는 섬유유연제 조성물.Thickening polymers include calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxy ethyl cellulose, carbopol 934, carbopol 9934, xanthan gum, sodium alginate, guar gum, A fabric softener composition comprising at least one selected from the group consisting of carrageenan, pectin and acrylic polymer. 제 10 항에 있어서,The method of claim 10, 증점용 폴리머는 섬유유연제 조성물 100 중량%에 대하여 0.01 내지 1.2 중량%로 포함되는 섬유유연제 조성물.The thickener polymer is contained in 0.01 to 1.2% by weight relative to 100% by weight of the fabric softener composition. 제 1 항, 제 2 항, 제 3 항, 제 4 항 또는 제 7 항에 있어서,The method according to claim 1, 2, 3, 4 or 7, 꽃 발효식초를 추가로 포함하는 섬유유연제 조성물.A fabric softener composition further comprising flower fermented vinegar. 제 13 항에 있어서,The method of claim 13, 꽃 발효식초는 도화꽃, 살구꽃, 아카시아꽃, 카모마일꽃, 자스민꽃 및 연꽃으로 이루어진 그룹에서 선택된 하나 이상의 꽃잎을 수세 및 건조하고 식초 및 당물과 혼합하여 3일 내지 7일 동안 발효시켜 얻은 것인 섬유유연제 조성물.Flower fermented vinegar is obtained by washing and drying one or more petals selected from the group consisting of iris, apricot, acacia, chamomile, jasmine and lotus, and mixing with vinegar and sugar for 3-7 days Fabric softener composition. 제 13 항에 있어서,The method of claim 13, 꽃 발효식초는 섬유유연제 조성물 100 중량%에 대하여 0.001 내지 10 중량%로 포함되는 섬유유연제 조성물.The flower fermentation vinegar is contained in 0.001 to 10% by weight relative to 100% by weight of the fabric softener composition. 제 1 항, 제 2 항, 제 3 항, 제 4 항 또는 제 7 항에 있어서,The method according to claim 1, 2, 3, 4 or 7, 식초를 추가로 포함하는 섬유유연제 조성물.A fabric softener composition further comprising vinegar. 제 16 항에 있어서,The method of claim 16, 식초는 섬유유연제 조성물 100 중량%에 대하여 0.1 내지 10 중량%로 포함되는 섬유유연제 조성물.Vinegar is 0.1 to 10% by weight relative to 100% by weight of the fabric softener composition.
PCT/KR2015/001841 2014-02-25 2015-02-25 Composition for fabric softener Ceased WO2015130085A1 (en)

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KR1020150025437A KR102123613B1 (en) 2014-02-25 2015-02-23 Fabric softener composition
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