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WO2015196889A1 - Side-blast tin smelting apparatus - Google Patents

Side-blast tin smelting apparatus Download PDF

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Publication number
WO2015196889A1
WO2015196889A1 PCT/CN2015/079923 CN2015079923W WO2015196889A1 WO 2015196889 A1 WO2015196889 A1 WO 2015196889A1 CN 2015079923 W CN2015079923 W CN 2015079923W WO 2015196889 A1 WO2015196889 A1 WO 2015196889A1
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WO
WIPO (PCT)
Prior art keywords
tin
furnace
furnace chamber
smelting
slag
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2015/079923
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French (fr)
Chinese (zh)
Inventor
李东波
黎敏
王忠实
张振民
胡丕成
许良
冯双杰
姚霞
曹珂菲
邓兆磊
陈学刚
陈霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China ENFI Engineering Corp
Original Assignee
China ENFI Engineering Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201420348146.0U external-priority patent/CN203960304U/en
Priority claimed from CN201410293171.8A external-priority patent/CN104073652A/en
Application filed by China ENFI Engineering Corp filed Critical China ENFI Engineering Corp
Publication of WO2015196889A1 publication Critical patent/WO2015196889A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B25/00Obtaining tin
    • C22B25/02Obtaining tin by dry processes

Definitions

  • the invention relates to a side blowing tinning device.
  • the technology of tin refining includes tin concentrate reverberation furnace smelting process, electric furnace smelting process, Ausmelt smelting process, blast furnace smelting process, short kiln smelting process, and Caldo furnace smelting process.
  • the short kiln smelting process has been eliminated due to high investment, management and maintenance costs, large amount of flue gas, and low direct yield.
  • the structure of the Caldo furnace is complicated, the maintenance cost is high, the furnace life is short, and the refractory material is consumed.
  • Reverberatory furnaces are rapidly being replaced by enhanced smelting methods due to their low production efficiency, low thermal efficiency, high fuel consumption, and high labor intensity.
  • an object of the present invention is to provide a side-blowing tin-smelting device having the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.
  • a side-blowing tin-smelting apparatus includes: a reaction furnace having a furnace chamber therein, and a wall of the furnace chamber is provided with a feeding port, a slag discharge port, and a tin-discharging port, wherein the furnace cavity
  • the top wall is provided with a smoke outlet for discharging the flue gas; and a side blowing spray gun is disposed on the side wall of the furnace chamber to blow the oxygen-containing gas and the fuel side into the furnace chamber.
  • the side-blown tin-smelting device can realize reduction smelting, strong reduction smelting, and vulcanization volatilization in a single side blowing tin-smelting device, that is, blowing tin in a single closed side-blown tin-smelting device,
  • a single side blowing tin-smelting device that is, blowing tin in a single closed side-blown tin-smelting device
  • the side-blowing tin-smelting device has the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.
  • side-blowing tin-smelting apparatus may further have the following additional technical features:
  • the feeding port is disposed on a sidewall of the cavity, and the tin-discharging port is disposed in the On the side wall of the furnace chamber, the slag discharge port is provided on a side wall of the furnace chamber.
  • the tin-discharging opening is located at a first end of the furnace chamber
  • the slag opening is located at a second end of the furnace chamber, wherein the first end of the furnace chamber is The second end of the furnace chamber is opposite.
  • the tuyere has a third tuyeres on the side wall.
  • a spray gun port is provided on a side wall of the furnace chamber, and the side blow gun is disposed in the spray gun port.
  • the reaction furnace is a horizontal furnace.
  • the side blowing lances are plurality, and a plurality of the side blowing lances are spaced apart from each other along a length direction of the reaction furnace on a side wall of the furnace chamber.
  • the feeding port, the tin-discharging port and the slag discharging port are provided with a sanitary ventilating chamber and a dust removing system.
  • the side blowing tinning apparatus further includes a waste heat boiler having a vertical ascending section integrally formed with the reaction furnace and connected to the outlet.
  • a waste heat boiler having a vertical ascending section integrally formed with the reaction furnace and connected to the outlet.
  • the side blowing tinning apparatus further comprises a dust collector, the dust collector being connected to the waste heat boiler.
  • FIG. 1 is a flow chart of a side blowing tinning process in accordance with an embodiment of the present invention
  • FIG. 2 is a schematic structural view of a side-blowing tin-smelting apparatus according to an embodiment of the present invention
  • FIG. 3 is a schematic structural view of a side-blowing tin-smelting apparatus according to another embodiment of the present invention.
  • top blowing steel In the field of metallurgical technology, the difference between top and side blowing is not only the change in the position of the gun, but the reaction between the two is completely different smelting equipment and processes.
  • the first is the bottom blowing steel, but the later developed top blowing steel is a technological utility model, which is completely different from the bottom blowing. This is not simply blowing the spray gun from the bottom. It becomes a top blow, but it embodies different methods and conditions. It is a completely different type of furnace and process.
  • top-blowing technology In the field of metallurgical technology, the use of top-blowing technology or side-blowing technology results in different kinetic conditions, melt agitation conditions and reaction mechanism (reaction sequence) of the melt in the furnace.
  • each metal element has unique physical and chemical properties. Therefore, the installation of a metal device and process without creative labor (modification) cannot be used to smelt another metal.
  • the equipment and processes for smelting tin are completely different from the equipment and processes for smelting lead. That is to say, without creative labor (modification), for example, it is impossible to smelt tin using equipment and processes for smelting lead.
  • a side blowing tinning process according to an embodiment of the present invention will be described below with reference to FIG. As shown in FIG. 1, the side blowing tinning process according to an embodiment of the present invention includes the following steps:
  • the side blowing tin-removing process can perform reduction smelting and strong reduction smelting in a single side blowing tin-smelting device by performing strong reduction smelting on the tin-rich slag obtained after reduction smelting, that is, can be single-closed
  • the blown tin is realized in the side blowing tin-making apparatus. Therefore, not only the enthalpy of the tin-rich slag can be fully utilized, but also the process of smelting tin can be greatly shortened, the direct yield of the reduced smelting tin can be improved, and the side-spinning tin-smelting process can be simplified.
  • the side blowing tin-smelting process according to the embodiment of the present invention has the advantages of simple process, low energy consumption, high environmental protection, high degree of automation, and high direct yield.
  • each of the first rough tin and the second coarse tin is intermittently discharged (cavity).
  • the investment can be reduced, the working conditions can be improved, the intermediate slag discharge process can be reduced, and the operating environment can be improved.
  • the lean slag can be discharged and then processed in a conventional smelting furnace.
  • the side-blow tinning process may further include: adding a vulcanizing agent to the furnace chamber, and spraying an oxygen-containing gas and fuel from a side of the furnace chamber And entering the furnace cavity to vulcanize and volatilize the lean tin slag and obtain a waste slag, and then discharge the waste slag.
  • the side blowing tin-removing process according to the embodiment of the present invention can perform the reductive smelting, the strong reduction smelting, and the vulcanization volatilization in a single side blowing tin-making apparatus by vulcanizing volatilization of the lean tin slag obtained after the strong reduction smelting, that is, The blowing of the tin can be achieved in a single closed side blowing tinning device.
  • the side blowing tin-smelting process according to the embodiment of the present invention has the advantages of simple process, low energy consumption, high environmental protection, high degree of automation, and high direct yield.
  • the vulcanizing agent may be intermittently added to the furnace chamber, and the waste slag may be intermittently discharged.
  • the tin-rich slag has a tin content of 15% by weight or less, the tin-rich slag has a tin content of 5% by weight or less, and the waste slag has a tin content of 0.3% by weight or less.
  • a tertiary air vent is provided on the side wall of the furnace chamber (the side wall of the furnace chamber is different from the wall of the hood), so that the flammable combustion in the flue gas is utilized by the air delivered from the tertiary vent. Things.
  • the side blowing tinning process further includes: conveying air from the side wall of the air outlet of the furnace chamber to the outlet to burn the smoke Combustible. That is, the flue gas may be produced during the reduction smelting, the strong reduction smelting, and the vulcanization volatilization process. Thereby, the combustibles in the flue gas can be more fully burned, thereby further improving the environmental friendliness of the side blowing tinning process.
  • the oxygen-containing gas has a volume concentration of oxygen of 30% to 65%. That is, the oxygen-containing gas has an oxygen content of 30 v% to 65 v%, and therefore, the oxygen-containing gas is industrial oxygen or oxygen-enriched air.
  • the reducing agent may be granulated coal. It is generally believed by those skilled in the art that the use of metallurgical coke as a reducing agent can effectively reduce the tin-containing material and the tin-rich slag. After in-depth research and creative labor, the inventor discovered that compared with the reduction of tin-containing materials and tin-rich slag by using metallurgical coke, the reduction of tin-containing materials and tin-rich slag by using granular coal can further reduce the lean slag.
  • the tin content in the tin-rich slag is less than or equal to 5 wt%, so that the direct yield and recovery of tin can be further improved. Therefore, by using granular coal as a reducing agent, technical bias is overcome and costs can be reduced.
  • the particle size of the granular coal may be less than or equal to a predetermined value.
  • the fuel may be selected from at least one of pulverized coal, natural gas, coke oven gas, and producer gas.
  • the flux may be limestone, quartz or a mixture of quartz and lime.
  • the vulcanizing agent may be pyrite.
  • the present invention also provides a side blowing tinning apparatus 10.
  • a side blowing tinning apparatus 10 according to an embodiment of the present invention will be described below with reference to FIG.
  • the side blowing tin-making apparatus 10 includes a reaction furnace 101 and a side blowing lance 102.
  • the furnace 101 has a furnace chamber 1011.
  • the wall of the furnace chamber 1011 is provided with a feeding port 1012, a slag opening 1013 and a tin discharging port 1014.
  • the top wall of the furnace chamber 1011 is provided with a venting port 1016 for discharging flue gas.
  • a side blow gun 102 is provided on the side wall of the furnace chamber 1011 to blow the oxygen-containing gas and fuel side into the furnace chamber 1011.
  • the side-blown tinning apparatus 10 can be used to implement the side-blow tinning process according to the above embodiment of the present invention.
  • the side-blowing tin-making apparatus 10 can realize the vulcanization and volatilization of the reduction smelting, the strong reduction smelting, and the lean slag in the single side blowing tin-making apparatus 10, that is, in the single closed side blowing tin-making apparatus 10
  • the blowing of tin is achieved, so the sealing performance is good and the environmental protection is high. Therefore, not only the enthalpy of the tin-rich slag can be fully utilized, but also the process of smelting tin can be greatly shortened, the direct yield of the reduced smelting tin can be improved, and the side-spinning tin-smelting device and process can be simplified.
  • the side blowing tin-removing device 10 has the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.
  • L1 is the liquid surface of the tin-rich slag and the lean tin slag
  • L2 is the liquid surface of the crude tin.
  • L1 is a liquid surface of the tin-rich slag
  • L1 is a liquid surface of the lean slag.
  • the molten pool of the furnace chamber 1011 is for accommodating the first crude tin, the second crude tin, the tin-rich slag, the lean tin slag, and the waste slag.
  • the reaction furnace 101 may be a horizontal furnace.
  • the reaction furnace 101 may be a long oval or rectangular fixed horizontal furnace.
  • the bottom wall of the furnace chamber 1011 may have a concave curved shape.
  • the feeding port 1012 is disposed on the side wall of the furnace chamber 1011
  • the tin-discharging port 1014 is disposed on the side wall of the furnace chamber 1011
  • the slag discharging port 1013 is disposed on the side wall of the furnace chamber 1011.
  • the tin port 1014 can be adjacent the bottom wall of the furnace chamber 1011. Thereby, the first coarse tin and the second coarse tin can be discharged more quickly and more thoroughly.
  • the tin discharge port 1014 is located at the first end of the furnace chamber 1011, and the slag discharge port 1013 is located at the second end of the furnace chamber 1011, wherein the first end of the furnace chamber 1011 is opposite to the second end of the furnace chamber 1011.
  • a spray gun port is disposed on a side wall of the furnace chamber 1011, and a side blow gun 102 is disposed in the spray gun port. This makes it easier and more secure to install the side blow gun 102.
  • the end of the side-blowing lance 102 may be located in the lance mouth, and the end of the side-blowing lance 102 may also extend out of the lance, that is, the end of the side blasting gun 102 may extend into the cavity 1011. .
  • the side-blowing lance 102 can spray an oxygen-containing gas and fuel onto the liquid surface L2 of the rough tin of the furnace chamber 1011 and the tin-rich slag (the lean slag) Below the liquid level L1.
  • the side-blowing lance 102 can inject oxygen-containing gas and fuel into the tin-rich slag and lean slag in the furnace chamber 1011. That is, the lance opening is located above the liquid level L2 of the rough tin of the furnace chamber 1011 and below the liquid level L1 of the rich tin slag (the lean slag).
  • the side blow gun 102 (the gun mouth) may be provided on the side wall of the lower portion of the furnace chamber 1011.
  • a plurality of side blowing lances 102 are provided, and a plurality of side blowing lances 102 are provided on the side walls of the furnace chamber 1011 at intervals in the longitudinal direction of the reaction furnace 101.
  • the structure of the side blowing tin-making apparatus 10 can be made more reasonable.
  • the longitudinal direction of the reaction furnace 101 is as shown by an arrow A in FIGS. 2 and 3.
  • the tin-containing material, the flux and the reducing agent are added into the furnace chamber 1011 from the feeding port 1012, and the oxygen-containing gas and the fuel are injected into the furnace chamber 1011 by the side-blowing lance 102 to reduce and smelt the tin-containing material and obtain the first coarse Tin and tin-rich slag.
  • the reducing agent is added into the furnace chamber of the reaction furnace, and the oxygen-containing gas and the fuel are injected into the furnace chamber 1011 by the side blowing lance 102 to perform strong reduction smelting on the slag-rich slag and obtain the second coarse tin and the lean Tin slag.
  • the vulcanizing agent is introduced into the furnace chamber 1011 from the feeding port 1012, and the oxygen-containing gas and the fuel are injected into the cavity 1011 by the side blowing lance 102 to vulcanize and volatilize the tin in the lean slag and obtain the waste slag.
  • a portion of the fuel injected by the side-blowing lance 102 can also be used as a reducing agent to reduce the tin-containing material and the tin-rich slag together with the added reducing agent.
  • the first rough tin and the second coarse tin may be periodically discharged from the furnace opening 1014 from the furnace opening 1014.
  • the waste slag i.e., the slag produced after the sulfur-depleted slag is vulcanized and volatilized in the furnace chamber 1011 is periodically discharged from the slag discharge port 1013 to the furnace chamber 1011.
  • a tertiary air vent is provided on the side wall of the furnace chamber (the side wall of the furnace chamber is different from the wall of the hood), so that the flammable combustion in the flue gas is utilized by the air delivered from the tertiary vent. Things.
  • a sanitary ventilating chamber and a dust removal system are provided at the feeding port 1012 to prevent the overflow of smoke and dust.
  • a ventilating chamber and a dust removal system are arranged at the slag port 1013 to prevent the overflow of smoke and dust.
  • the side blowing tinning apparatus 10 may further include a waste heat boiler 102 having a vertical rising section 1021, and the vertical rising section 1021 is integrally formed with the reaction furnace 101, and the vertical rising section 1021 is connected to the outlet 1016.
  • the waste heat boiler 102 can be used to recover the heat in the flue gas generated by the reduction smelting, the strong reduction smelting, and the vulcanization volatilization process.
  • the vertical rising section 1021 integrally with the reaction furnace 101, Thereby, the soot adhesion can be prevented, so that the side blowing tin-making apparatus 10 can be stably operated for a long period of time.
  • the vertical rising section 1021 has a cavity 10211 therein, and the cavity 10211 is in communication with the smoke outlet 1016.
  • the side blowing tin-making device 10 further includes a dust collector (for example, a bag dust collector), and the dust collector may be connected to the waste heat boiler to recover the reduction smelting, the strong reduction smelting, and the vulcanization and volatilization process by using the dust collector. Tin-containing soot in the generated flue gas.
  • a dust collector for example, a bag dust collector
  • the side-blow tinmaking apparatus 10 may further include a cooler that may be coupled to the waste heat boiler and the dust collector may be coupled to the cooler.
  • tin-containing soot can be added to the furnace chamber 1011.
  • the tin-containing material and the flux can be added to the furnace chamber 1011.
  • the tin-containing soot, the tin-containing material, and the flux may be added to the furnace chamber 1011.
  • the side-blowing tin-smelting apparatus 10 can realize regular tinning, regular tin discharge, and regular slagging.
  • tin concentrate smelting process in a closed reaction furnace 101, to avoid the escape of smoke, tin concentrate or other tin raw materials with the granulation directly into the furnace, the material preparation process is simple, the production process The tin soot produced in the middle is sealed and transported and returned to the ingredients, effectively preventing the dispersion of tin dust; the flue gas produced by the smelting and vulcanization is recovered and collected by the waste heat, and then sent to the desulfurization system.
  • the crude tin produced by the side melting furnace reduction smelting section and the strong reduction smelting section is discharged from the tin discharge port, and the waste slag which is vulcanized and volatilized is discharged from the slag discharge port, and the ventilating chamber is provided at the feeding port, the tin discharging port and the slag discharging port.
  • High recovery rate In the side-blowing tin furnace, due to the full utilization of the slag enthalpy, industrial smelting process uses industrial oxygen, and the use of granular coal as a reducing agent effectively reduces the amount of smoke and smoke, and reduces the rate.
  • the tin content in the slag increases the direct yield and recovery of tin.
  • side blowing tinning method is the method of all tinning, including material preparation system, the shortest process, simple process equipment, investment.
  • first and second are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated.
  • features defining “first” or “second” may include at least one of the features, either explicitly or implicitly.
  • the meaning of "a plurality” is at least two, such as two, three, etc., unless specifically defined otherwise.
  • the terms “installation”, “connected”, “connected”, “fixed” and the like shall be understood broadly, and may be either a fixed connection or a detachable connection, unless explicitly stated and defined otherwise. Or in one piece; it may be a mechanical connection, or it may be an electrical connection or a communication with each other; it may be directly connected or indirectly connected through an intermediate medium, and may be an internal connection of two elements or an interaction relationship between two elements. Unless otherwise expressly defined. For those skilled in the art, the specific meanings of the above terms in the present invention can be understood on a case-by-case basis.
  • the first feature "on” or “under” the second feature may be a direct contact of the first and second features, or the first and second features may be indirectly through an intermediate medium, unless otherwise explicitly stated and defined. contact.
  • the first feature "above”, “above” and “above” the second feature may be that the first feature is directly above or above the second feature, or merely that the first feature level is higher than the second feature.
  • the first feature “below”, “below” and “below” the second feature may be that the first feature is directly below or obliquely below the second feature, or merely that the first feature level is less than the second feature.

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  • Manufacturing & Machinery (AREA)
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Abstract

Disclosed is a side-blast tin smelting apparatus (10). The side-blast tin smelting apparatus (10) comprises: a reaction furnace (101); the reaction furnace (101) comprises a furnace chamber (1011); provided on the wall of the furnace chamber (1011) are a material feed inlet (1012), a slag discharge outlet (1013), and a tin discharge outlet (1014). The ceiling of the furnace chamber (1011) is provided with smoke outlets (1016) for discharging flue gas; a side-blast spray gun (102), the side blast spray gun (102) being provided on the side wall of the furnace chamber (1011) to blast oxygen-containing gas and fuel into the furnace chamber (1011).

Description

侧吹炼锡装置Side blowing tinning device 技术领域Technical field

本发明涉及一种侧吹炼锡装置。The invention relates to a side blowing tinning device.

背景技术Background technique

炼锡的技术有锡精矿反射炉熔炼工艺、电炉熔炼工艺、Ausmelt熔炼工艺、鼓风炉熔炼工艺、短窑熔炼工艺、卡尔多炉炼锡工艺。短窑熔炼工艺因投资、管理和维修费用高、烟气量大,直收率低早已被淘汰。卡尔多炉设备结构复杂,维修费用高,炉寿短,耐火材料消耗大。反射炉由于其生产效率低、热效率低、燃料消耗大、劳动强度大等缺点,正迅速被强化熔炼方法所取代。电炉炼锡的缺点电耗太高,只适合处理低铁物料;鼓风炉熔炼工艺要求物料需要制粒或制团,消耗昂贵的冶金焦,炉内气氛难于控制,锡的挥发率高等缺点,已不再使用。Ausmelt熔炼属强化熔池熔炼技术,分段作业,渣含锡可降至较低水平,但投资大,维护费用高,且操作复杂。The technology of tin refining includes tin concentrate reverberation furnace smelting process, electric furnace smelting process, Ausmelt smelting process, blast furnace smelting process, short kiln smelting process, and Caldo furnace smelting process. The short kiln smelting process has been eliminated due to high investment, management and maintenance costs, large amount of flue gas, and low direct yield. The structure of the Caldo furnace is complicated, the maintenance cost is high, the furnace life is short, and the refractory material is consumed. Reverberatory furnaces are rapidly being replaced by enhanced smelting methods due to their low production efficiency, low thermal efficiency, high fuel consumption, and high labor intensity. The shortcomings of electric furnace tinning are too high, and it is only suitable for processing low-iron materials. The blast furnace smelting process requires materials to be granulated or pelletized, consumes expensive metallurgical coke, the furnace atmosphere is difficult to control, and the volatilization rate of tin is high. reuse. Ausmelt smelting is an intensive molten pool smelting technology. The slag tin content can be reduced to a lower level, but the investment is large, the maintenance cost is high, and the operation is complicated.

发明内容Summary of the invention

本发明旨在至少在一定程度上解决相关技术中的技术问题之一。为此,本发明的一个目的在于提出一种具有能耗低、密封性能好、环保性高、结构简单、易操作等优点的侧吹炼锡装置。The present invention aims to solve at least one of the technical problems in the related art to some extent. Therefore, an object of the present invention is to provide a side-blowing tin-smelting device having the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.

根据本发明实施例的侧吹炼锡装置包括:反应炉,所述反应炉内具有炉腔,所述炉腔的壁上设有加料口、放渣口和放锡口,所述炉腔的顶壁上设有用于排出烟气的出烟口;和侧吹喷枪,所述侧吹喷枪设在所述炉腔的侧壁上以便将含氧气体和燃料侧吹到所述炉腔内。A side-blowing tin-smelting apparatus according to an embodiment of the present invention includes: a reaction furnace having a furnace chamber therein, and a wall of the furnace chamber is provided with a feeding port, a slag discharge port, and a tin-discharging port, wherein the furnace cavity The top wall is provided with a smoke outlet for discharging the flue gas; and a side blowing spray gun is disposed on the side wall of the furnace chamber to blow the oxygen-containing gas and the fuel side into the furnace chamber.

根据本发明实施例的侧吹炼锡装置可以在单个侧吹炼锡装置内能够实现还原熔炼、强还原熔炼以及硫化挥发,即在单个封闭的侧吹炼锡装置内实现了吹炼锡,在产出粗锡的同时将渣吹炼成弃渣,省去了中间渣的排放,因此密封性能好,环保性高。由此不仅可以充分地利用富锡渣的热焓,而且可以极大地缩短冶炼锡的流程,提高了还原熔炼锡的直收率,简化侧吹炼锡工艺。The side-blown tin-smelting device according to the embodiment of the present invention can realize reduction smelting, strong reduction smelting, and vulcanization volatilization in a single side blowing tin-smelting device, that is, blowing tin in a single closed side-blown tin-smelting device, When the crude tin is produced, the slag is blown into the waste slag, and the discharge of the intermediate slag is omitted, so the sealing performance is good and the environmental protection is high. Therefore, not only the enthalpy of the tin-rich slag can be fully utilized, but also the process of smelting tin can be greatly shortened, the direct yield of the reduced smelting tin can be improved, and the side-spinning tin-smelting process can be simplified.

因此,根据本发明实施例的侧吹炼锡装置具有能耗低、密封性能好、环保性高、结构简单、易操作等优点。Therefore, the side-blowing tin-smelting device according to the embodiment of the invention has the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.

另外,根据本发明上述实施例的侧吹炼锡装置还可以具有如下附加的技术特征:In addition, the side-blowing tin-smelting apparatus according to the above embodiment of the present invention may further have the following additional technical features:

根据本发明的一个实施例,所述加料口设在所述炉腔的侧壁上,所述放锡口设在所述 炉腔的侧壁上,所述放渣口设在所述炉腔的侧壁上。According to an embodiment of the present invention, the feeding port is disposed on a sidewall of the cavity, and the tin-discharging port is disposed in the On the side wall of the furnace chamber, the slag discharge port is provided on a side wall of the furnace chamber.

根据本发明的一个实施例,所述放锡口位于所述炉腔的第一端,所述放渣口位于所述炉腔的第二端,其中所述炉腔的第一端与所述炉腔的第二端相对。According to an embodiment of the invention, the tin-discharging opening is located at a first end of the furnace chamber, the slag opening is located at a second end of the furnace chamber, wherein the first end of the furnace chamber is The second end of the furnace chamber is opposite.

根据本发明的一个实施例,所述出烟口的侧壁上设有三次风口。According to an embodiment of the invention, the tuyere has a third tuyeres on the side wall.

根据本发明的一个实施例,所述炉腔的侧壁上设有喷枪口,所述侧吹喷枪设在所述喷枪口内。According to an embodiment of the invention, a spray gun port is provided on a side wall of the furnace chamber, and the side blow gun is disposed in the spray gun port.

根据本发明的一个实施例,所述反应炉为卧式炉。According to an embodiment of the invention, the reaction furnace is a horizontal furnace.

根据本发明的一个实施例,所述侧吹喷枪为多个,多个所述侧吹喷枪沿所述反应炉的长度方向间隔开地设在所述炉腔的侧壁上。According to an embodiment of the invention, the side blowing lances are plurality, and a plurality of the side blowing lances are spaced apart from each other along a length direction of the reaction furnace on a side wall of the furnace chamber.

根据本发明的一个实施例,所述加料口、所述放锡口和所述放渣口处均设有卫生通风室和除尘系统。According to an embodiment of the invention, the feeding port, the tin-discharging port and the slag discharging port are provided with a sanitary ventilating chamber and a dust removing system.

根据本发明的一个实施例,所述侧吹炼锡装置进一步包括余热锅炉,所述余热锅炉具有垂直上升段,所述垂直上升段与所述反应炉一体形成且与所述出烟口相连。由此可以防止烟尘粘接,从而可以使所述侧吹炼锡装置能够长期稳定运行。According to an embodiment of the present invention, the side blowing tinning apparatus further includes a waste heat boiler having a vertical ascending section integrally formed with the reaction furnace and connected to the outlet. Thereby, the adhesion of the soot can be prevented, so that the side blowing tin-storing device can be stably operated for a long period of time.

根据本发明的一个实施例,所述侧吹炼锡装置还包括收尘器,所述收尘器与所述余热锅炉相连。According to an embodiment of the invention, the side blowing tinning apparatus further comprises a dust collector, the dust collector being connected to the waste heat boiler.

附图说明DRAWINGS

图1是根据本发明实施例的侧吹炼锡工艺的流程图;1 is a flow chart of a side blowing tinning process in accordance with an embodiment of the present invention;

图2是根据本发明的一个实施例的侧吹炼锡装置的结构示意图;2 is a schematic structural view of a side-blowing tin-smelting apparatus according to an embodiment of the present invention;

图3是根据本发明的另一个实施例的侧吹炼锡装置的结构示意图。3 is a schematic structural view of a side-blowing tin-smelting apparatus according to another embodiment of the present invention.

具体实施方式detailed description

下面详细描述本发明的实施例,所述实施例的示例在附图中示出。下面通过参考附图描述的实施例是示例性的,旨在用于解释本发明,而不能理解为对本发明的限制。Embodiments of the invention are described in detail below, examples of which are illustrated in the accompanying drawings. The embodiments described below with reference to the drawings are intended to be illustrative of the invention and are not to be construed as limiting.

在冶金技术领域,顶吹和侧吹的区别不仅仅是喷枪位置的变化,二者反应的是完全不同的冶炼设备和工艺。例如,在炼钢技术领域,最初的都是底吹炼钢,但是后来发展的顶吹炼钢是开创性的实用新型,与底吹是完全不同的技术,这不是简单地将喷枪从底吹变成顶吹,而是体现了不同的方法和条件,是完全不同的两类炉型和工艺。In the field of metallurgical technology, the difference between top and side blowing is not only the change in the position of the gun, but the reaction between the two is completely different smelting equipment and processes. For example, in the field of steelmaking technology, the first is the bottom blowing steel, but the later developed top blowing steel is a groundbreaking utility model, which is completely different from the bottom blowing. This is not simply blowing the spray gun from the bottom. It becomes a top blow, but it embodies different methods and conditions. It is a completely different type of furnace and process.

在冶金技术领域,采用顶吹技术还是采用侧吹技术,会导致炉内熔体的动力学条件、熔体搅拌状态和反应机理(反应顺序)不同。 In the field of metallurgical technology, the use of top-blowing technology or side-blowing technology results in different kinetic conditions, melt agitation conditions and reaction mechanism (reaction sequence) of the melt in the furnace.

更具体而言,现有的锡冶炼技术都是基于还原熔炼的过程。但是,在实践中具体采用什么设备来实现还原熔炼是工程化应用中最核心的问题。对设备的不同选择决定了实现还原熔炼过程的不同技术路线(即工艺),技术路线将决定工业化的可靠性、可实施性和技术指标的先进性。而喷吹位置的选择(即喷枪的安装位置)则是设备选择、设备设计中最基本、最核心的问题之一。当选定了侧吹或顶吹,其冶炼设备(炉型)结构形式、喷枪结构、布置是完全不同的。More specifically, existing tin smelting techniques are based on a process of reduction smelting. However, what equipment is specifically used in practice to achieve reduction smelting is the core issue in engineering applications. The different choices of equipment determine the different technical routes (ie processes) to achieve the reduction smelting process, and the technical route will determine the reliability, feasibility and advancement of technical indicators of industrialization. The choice of the blowing position (ie the installation position of the spray gun) is one of the most basic and core problems in equipment selection and equipment design. When side blowing or top blowing is selected, the structure of the smelting equipment (furnace type), the structure and arrangement of the spray gun are completely different.

对于本领域技术人员来说,一种基本成型的冶炼装置无论存在什么技术问题,无论对其进行何种改进,这种改进都不可能改变其喷吹位置的选择。因此,对于本领域技术人员来说,喷枪位置的改变并不是一个常规的、显而易见的选择。It will be apparent to those skilled in the art that a substantially shaped smelting apparatus, regardless of any technical problems, no matter what improvements it makes, that such an improvement is unlikely to change the choice of its blowing position. Thus, variations in the position of the spray gun are not a routine and obvious choice for those skilled in the art.

而且,每一个金属元素都具有独特的物理性质和化学性质。因此,冶炼一种金属的装置和工艺不经过创造性的劳动(改动),不能用于冶炼另一种金属。例如,冶炼锡的装置和工艺完全不同于冶炼铅的装置和工艺。也就是说,不经过创造性的劳动(改动),例如无法利用冶炼铅的装置和工艺冶炼锡。Moreover, each metal element has unique physical and chemical properties. Therefore, the installation of a metal device and process without creative labor (modification) cannot be used to smelt another metal. For example, the equipment and processes for smelting tin are completely different from the equipment and processes for smelting lead. That is to say, without creative labor (modification), for example, it is impossible to smelt tin using equipment and processes for smelting lead.

下面参考图1描述根据本发明实施例的侧吹炼锡工艺。如图1所示,根据本发明实施例的侧吹炼锡工艺包括以下步骤:A side blowing tinning process according to an embodiment of the present invention will be described below with reference to FIG. As shown in FIG. 1, the side blowing tinning process according to an embodiment of the present invention includes the following steps:

将含锡物料、熔剂和还原剂加入到反应炉的炉腔内,并将含氧气体和燃料从所述炉腔的侧面喷入所述炉腔内,以便对含锡物料进行还原熔炼并得到第一粗锡和富锡渣,然后排出所述第一粗锡;和Adding tin-containing material, flux and reducing agent into the furnace cavity of the reaction furnace, and injecting oxygen-containing gas and fuel into the cavity from the side of the furnace cavity to reduce and smelt the tin-containing material and obtain First coarse tin and rich tin slag, and then discharging the first coarse tin; and

将还原剂加入到反应炉的炉腔内,并将含氧气体和燃料从所述炉腔的侧面喷入所述炉腔内,以便对所述富锡渣进行强还原熔炼并得到第二粗锡和贫锡渣,然后排出所述第二粗锡。Adding a reducing agent into the furnace cavity of the reaction furnace, and injecting an oxygen-containing gas and fuel from the side of the furnace chamber into the furnace cavity to perform strong reduction smelting on the tin-rich slag and obtain a second coarse Tin and lean tin slag, and then the second coarse tin is discharged.

根据本发明实施例的侧吹炼锡工艺通过对还原熔炼后得到的富锡渣进行强还原熔炼,从而可以在单个侧吹炼锡装置内实现还原熔炼和强还原熔炼,即可以在单个封闭的侧吹炼锡装置内实现吹炼锡。由此不仅可以充分地利用所述富锡渣的热焓,而且可以极大地缩短冶炼锡的流程,提高了还原熔炼锡的直收率,简化侧吹炼锡工艺。The side blowing tin-removing process according to the embodiment of the present invention can perform reduction smelting and strong reduction smelting in a single side blowing tin-smelting device by performing strong reduction smelting on the tin-rich slag obtained after reduction smelting, that is, can be single-closed The blown tin is realized in the side blowing tin-making apparatus. Therefore, not only the enthalpy of the tin-rich slag can be fully utilized, but also the process of smelting tin can be greatly shortened, the direct yield of the reduced smelting tin can be improved, and the side-spinning tin-smelting process can be simplified.

因此,根据本发明实施例的侧吹炼锡工艺具有工艺简单、能耗低、环保性高、自动化程度高、直收率高等优点。Therefore, the side blowing tin-smelting process according to the embodiment of the present invention has the advantages of simple process, low energy consumption, high environmental protection, high degree of automation, and high direct yield.

有利地,所述第一粗锡和所述第二粗锡中的每一个均被间断地排出(炉腔)。由此不仅可以使所述还原熔炼和所述强还原熔炼更加稳定地进行,而且可以进一步简化侧吹炼锡工艺的操作、降低投资、改善作业条件,减少了中间渣排放工序,改善了操作环境。Advantageously, each of the first rough tin and the second coarse tin is intermittently discharged (cavity). Thereby, not only the reduction smelting and the strong reduction smelting can be performed more stably, but also the operation of the side blowing smelting process can be further simplified, the investment can be reduced, the working conditions can be improved, the intermediate slag discharge process can be reduced, and the operating environment can be improved. .

所述贫锡渣可以被排出,然后在常规的烟化炉中进行处理。 The lean slag can be discharged and then processed in a conventional smelting furnace.

在本发明的一些实施例中,根据本发明实施例的侧吹炼锡工艺可以进一步包括:将硫化剂加入到所述炉腔内,并将含氧气体和燃料从所述炉腔的侧面喷入所述炉腔内,以便对所述贫锡渣进行硫化挥发并得到弃渣,然后排出所述弃渣。In some embodiments of the present invention, the side-blow tinning process according to an embodiment of the present invention may further include: adding a vulcanizing agent to the furnace chamber, and spraying an oxygen-containing gas and fuel from a side of the furnace chamber And entering the furnace cavity to vulcanize and volatilize the lean tin slag and obtain a waste slag, and then discharge the waste slag.

根据本发明实施例的侧吹炼锡工艺通过对所述强还原熔炼后得到的贫锡渣进行硫化挥发,从而可以在单个侧吹炼锡装置内实现还原熔炼、强还原熔炼和硫化挥发,即可以在单个封闭的侧吹炼锡装置内实现吹炼锡。由此不仅可以充分地利用所述富锡渣和所述贫锡渣的热焓,而且可以极大地缩短冶炼锡的流程,一炉多用,提高了还原熔炼锡的直收率,简化侧吹炼锡工艺。The side blowing tin-removing process according to the embodiment of the present invention can perform the reductive smelting, the strong reduction smelting, and the vulcanization volatilization in a single side blowing tin-making apparatus by vulcanizing volatilization of the lean tin slag obtained after the strong reduction smelting, that is, The blowing of the tin can be achieved in a single closed side blowing tinning device. Therefore, not only the enthalpy of the tin-rich slag and the lean slag can be fully utilized, but also the process of smelting tin can be greatly shortened, and the furnace can be used in a multi-purpose manner to improve the direct yield of the reduced smelting tin and simplify the side blowing. Tin process.

因此,根据本发明实施例的侧吹炼锡工艺具有工艺简单、能耗低、环保性高、自动化程度高、直收率高等优点。Therefore, the side blowing tin-smelting process according to the embodiment of the present invention has the advantages of simple process, low energy consumption, high environmental protection, high degree of automation, and high direct yield.

具体而言,所述硫化剂可以被间断地加入到所述炉腔内,所述弃渣可以被间断地排出。Specifically, the vulcanizing agent may be intermittently added to the furnace chamber, and the waste slag may be intermittently discharged.

其中,所述富锡渣的含锡量小于等于15wt%,所述贫锡渣的含锡量小于等于5wt%,所述弃渣的含锡量小于等于0.3wt%。Wherein, the tin-rich slag has a tin content of 15% by weight or less, the tin-rich slag has a tin content of 5% by weight or less, and the waste slag has a tin content of 0.3% by weight or less.

在现有的金属冶炼工艺中,都是在炉腔的侧壁(炉腔的侧壁不同于出烟口的壁)上设置三次风口,以便利用从三次风口输送的空气燃烧烟气中的可燃物。In the existing metal smelting process, a tertiary air vent is provided on the side wall of the furnace chamber (the side wall of the furnace chamber is different from the wall of the hood), so that the flammable combustion in the flue gas is utilized by the air delivered from the tertiary vent. Things.

但是经过发明人深入地研究后,创造性地发现:从出烟口的侧壁向所述出烟口输送空气,可以更加充分地燃烧烟气中的可燃物。在本发明的一个具体示例中,根据本发明实施例的侧吹炼锡工艺进一步包括:从所述炉腔的出烟口的侧壁向所述出烟口输送空气,以便燃烧烟气中的可燃物。也就是说,烟气可以是所述还原熔炼、所述强还原熔炼和硫化挥发过程中产生的。由此可以更加充分地燃烧烟气中的可燃物,从而进一步提高所述侧吹炼锡工艺的环保性。However, after intensive research by the inventors, it has been found creatively that the air can be more fully burned from the side wall of the hood to the vent. In a specific example of the present invention, the side blowing tinning process according to an embodiment of the present invention further includes: conveying air from the side wall of the air outlet of the furnace chamber to the outlet to burn the smoke Combustible. That is, the flue gas may be produced during the reduction smelting, the strong reduction smelting, and the vulcanization volatilization process. Thereby, the combustibles in the flue gas can be more fully burned, thereby further improving the environmental friendliness of the side blowing tinning process.

所述含氧气体的氧气的体积浓度为30%-65%。也就是说,所述含氧气体的含氧量为30v%-65v%,因此,含氧气体为工业氧气或者富氧空气。The oxygen-containing gas has a volume concentration of oxygen of 30% to 65%. That is, the oxygen-containing gas has an oxygen content of 30 v% to 65 v%, and therefore, the oxygen-containing gas is industrial oxygen or oxygen-enriched air.

所述还原剂可以是粒煤。本领域技术人员普遍认为:利用冶金焦作为还原剂可以有效地对含锡物料和富锡渣进行还原。发明人经过深入的研究和创造性的劳动后发现:与利用冶金焦对含锡物料和富锡渣进行还原相比,利用粒煤对含锡物料和富锡渣进行还原,可以进一步降低贫锡渣中的锡含量(所述贫锡渣的含锡量小于等于5wt%),从而可以进一步提高锡的直收率和回收率。因此,通过利用粒煤作为还原剂,克服了技术偏见,而且可以降低成本。The reducing agent may be granulated coal. It is generally believed by those skilled in the art that the use of metallurgical coke as a reducing agent can effectively reduce the tin-containing material and the tin-rich slag. After in-depth research and creative labor, the inventor discovered that compared with the reduction of tin-containing materials and tin-rich slag by using metallurgical coke, the reduction of tin-containing materials and tin-rich slag by using granular coal can further reduce the lean slag. The tin content in the tin-rich slag is less than or equal to 5 wt%, so that the direct yield and recovery of tin can be further improved. Therefore, by using granular coal as a reducing agent, technical bias is overcome and costs can be reduced.

有利地,粒煤的粒径可以小于等于预定值。Advantageously, the particle size of the granular coal may be less than or equal to a predetermined value.

所述燃料可以选自粉煤、天然气、焦炉煤气和发生炉煤气中的至少一种。 The fuel may be selected from at least one of pulverized coal, natural gas, coke oven gas, and producer gas.

所述熔剂可以是石灰石、石英石或者石英石与石灰的混合物。The flux may be limestone, quartz or a mixture of quartz and lime.

所述硫化剂可以是黄铁矿。The vulcanizing agent may be pyrite.

本发明还提供了一种侧吹炼锡装置10。下面参考图2描述根据本发明实施例的侧吹炼锡装置10。如图2所示,根据本发明实施例的侧吹炼锡装置10包括反应炉101、侧吹喷枪102。The present invention also provides a side blowing tinning apparatus 10. A side blowing tinning apparatus 10 according to an embodiment of the present invention will be described below with reference to FIG. As shown in FIG. 2, the side blowing tin-making apparatus 10 according to an embodiment of the present invention includes a reaction furnace 101 and a side blowing lance 102.

反应炉101内具有炉腔1011,炉腔1011的壁上设有加料口1012、放渣口1013和放锡口1014,炉腔1011的顶壁上设有用于排出烟气的出烟口1016。侧吹喷枪102设在炉腔1011的侧壁上以便将含氧气体和燃料侧吹到炉腔1011内。The furnace 101 has a furnace chamber 1011. The wall of the furnace chamber 1011 is provided with a feeding port 1012, a slag opening 1013 and a tin discharging port 1014. The top wall of the furnace chamber 1011 is provided with a venting port 1016 for discharging flue gas. A side blow gun 102 is provided on the side wall of the furnace chamber 1011 to blow the oxygen-containing gas and fuel side into the furnace chamber 1011.

根据本发明实施例的侧吹炼锡装置10可以用于实施根据本发明上述实施例的侧吹炼锡工艺。The side-blown tinning apparatus 10 according to an embodiment of the present invention can be used to implement the side-blow tinning process according to the above embodiment of the present invention.

根据本发明实施例的侧吹炼锡装置10可以在单个侧吹炼锡装置10内能够实现还原熔炼、强还原熔炼和贫锡渣的硫化挥发,即在单个封闭的侧吹炼锡装置10内实现了吹炼锡,因此密封性能好,环保性高。由此不仅可以充分地利用富锡渣的热焓,而且可以极大地缩短冶炼锡的流程,提高了还原熔炼锡的直收率,简化侧吹炼锡装置和工艺。The side-blowing tin-making apparatus 10 according to the embodiment of the present invention can realize the vulcanization and volatilization of the reduction smelting, the strong reduction smelting, and the lean slag in the single side blowing tin-making apparatus 10, that is, in the single closed side blowing tin-making apparatus 10 The blowing of tin is achieved, so the sealing performance is good and the environmental protection is high. Therefore, not only the enthalpy of the tin-rich slag can be fully utilized, but also the process of smelting tin can be greatly shortened, the direct yield of the reduced smelting tin can be improved, and the side-spinning tin-smelting device and process can be simplified.

因此,根据本发明实施例的侧吹炼锡装置10具有能耗低、密封性能好、环保性高、结构简单、易操作等优点。Therefore, the side blowing tin-removing device 10 according to the embodiment of the present invention has the advantages of low energy consumption, good sealing performance, high environmental protection, simple structure, and easy operation.

如图2所示,在炉腔1011内,L1为富锡渣和贫锡渣的液面,L2为粗锡的液面。具体而言,当进行还原熔炼时,L1为富锡渣的液面,当进行强还原熔炼时,L1为贫锡渣的液面。炉腔1011的熔池用于容纳第一粗锡、第二粗锡、富锡渣、贫锡渣和弃渣。As shown in FIG. 2, in the furnace chamber 1011, L1 is the liquid surface of the tin-rich slag and the lean tin slag, and L2 is the liquid surface of the crude tin. Specifically, when performing reduction smelting, L1 is a liquid surface of the tin-rich slag, and when performing strong reduction smelting, L1 is a liquid surface of the lean slag. The molten pool of the furnace chamber 1011 is for accommodating the first crude tin, the second crude tin, the tin-rich slag, the lean tin slag, and the waste slag.

在本发明的一个具体示例中,如图2所示,反应炉101可以是卧式炉。具体地,反应炉101可以是长椭形或者矩形的固定卧式炉。炉腔1011的底壁可以为下凹的弧形。In a specific example of the present invention, as shown in FIG. 2, the reaction furnace 101 may be a horizontal furnace. Specifically, the reaction furnace 101 may be a long oval or rectangular fixed horizontal furnace. The bottom wall of the furnace chamber 1011 may have a concave curved shape.

如图2所示,加料口1012设在炉腔1011的侧壁上,放锡口1014设在炉腔1011的侧壁上,放渣口1013设在炉腔1011的侧壁上。由此可以使侧吹炼锡装置10的结构更加合理。As shown in FIG. 2, the feeding port 1012 is disposed on the side wall of the furnace chamber 1011, the tin-discharging port 1014 is disposed on the side wall of the furnace chamber 1011, and the slag discharging port 1013 is disposed on the side wall of the furnace chamber 1011. Thereby, the structure of the side blowing tin-making apparatus 10 can be made more reasonable.

有利地,放锡口1014可以邻近炉腔1011的底壁。由此可以更加快速地、更加彻底地排出第一粗锡和第二粗锡。Advantageously, the tin port 1014 can be adjacent the bottom wall of the furnace chamber 1011. Thereby, the first coarse tin and the second coarse tin can be discharged more quickly and more thoroughly.

放锡口1014位于炉腔1011的第一端,放渣口1013位于炉腔1011的第二端,其中炉腔1011的第一端与炉腔1011的第二端相对。由此可以使侧吹炼锡装置10的结构更加合理。The tin discharge port 1014 is located at the first end of the furnace chamber 1011, and the slag discharge port 1013 is located at the second end of the furnace chamber 1011, wherein the first end of the furnace chamber 1011 is opposite to the second end of the furnace chamber 1011. Thereby, the structure of the side blowing tin-making apparatus 10 can be made more reasonable.

炉腔1011的侧壁上设有喷枪口,侧吹喷枪102设在所述喷枪口内。由此可以更加方便地、稳固地安装侧吹喷枪102。A spray gun port is disposed on a side wall of the furnace chamber 1011, and a side blow gun 102 is disposed in the spray gun port. This makes it easier and more secure to install the side blow gun 102.

具体而言,侧吹喷枪102的端部可以位于所述喷枪口内,侧吹喷枪102的端部也可以伸出所述喷枪口,即侧吹喷枪102的端部可以伸入到炉腔1011内。 Specifically, the end of the side-blowing lance 102 may be located in the lance mouth, and the end of the side-blowing lance 102 may also extend out of the lance, that is, the end of the side blasting gun 102 may extend into the cavity 1011. .

如图2所示,更具体而言,侧吹喷枪102可以将含氧气体和燃料喷入到炉腔1011的粗锡的液面L2之上以及所述富锡渣(所述贫锡渣)的液面L1之下。换言之,侧吹喷枪102可以将含氧气体和燃料喷入到炉腔1011内的富锡渣和贫锡渣内。也就是说,所述喷枪口位于炉腔1011的粗锡的液面L2之上以及所述富锡渣(所述贫锡渣)的液面L1之下。As shown in FIG. 2, more specifically, the side-blowing lance 102 can spray an oxygen-containing gas and fuel onto the liquid surface L2 of the rough tin of the furnace chamber 1011 and the tin-rich slag (the lean slag) Below the liquid level L1. In other words, the side-blowing lance 102 can inject oxygen-containing gas and fuel into the tin-rich slag and lean slag in the furnace chamber 1011. That is, the lance opening is located above the liquid level L2 of the rough tin of the furnace chamber 1011 and below the liquid level L1 of the rich tin slag (the lean slag).

具体地,侧吹喷枪102(所述喷枪口)可以设在炉腔1011的下部的侧壁上。Specifically, the side blow gun 102 (the gun mouth) may be provided on the side wall of the lower portion of the furnace chamber 1011.

如图2所示,在本发明的一个示例中,侧吹喷枪102为多个,多个侧吹喷枪102沿反应炉101的长度方向间隔开地设在炉腔1011的侧壁上。由此可以使侧吹炼锡装置10的结构更加合理。其中,反应炉101的长度方向如图2和图3中的箭头A所示。As shown in FIG. 2, in one example of the present invention, a plurality of side blowing lances 102 are provided, and a plurality of side blowing lances 102 are provided on the side walls of the furnace chamber 1011 at intervals in the longitudinal direction of the reaction furnace 101. Thereby, the structure of the side blowing tin-making apparatus 10 can be made more reasonable. Here, the longitudinal direction of the reaction furnace 101 is as shown by an arrow A in FIGS. 2 and 3.

含锡物料、熔剂和还原剂从加料口1012加入到炉腔1011内,利用侧吹喷枪102向炉腔1011内喷入含氧气体和燃料,以便对含锡物料进行还原熔炼并得到第一粗锡和富锡渣。然后,将还原剂加入到反应炉的炉腔内,并利用侧吹喷枪102向炉腔1011内喷入含氧气体和燃料,以便对富锡渣进行强还原熔炼并得到第二粗锡和贫锡渣。最后,将硫化剂从加料口1012加入到炉腔1011内,利用侧吹喷枪102向炉腔1011内喷入含氧气体和燃料,以便对贫锡渣中的锡进行硫化挥发并得到弃渣。The tin-containing material, the flux and the reducing agent are added into the furnace chamber 1011 from the feeding port 1012, and the oxygen-containing gas and the fuel are injected into the furnace chamber 1011 by the side-blowing lance 102 to reduce and smelt the tin-containing material and obtain the first coarse Tin and tin-rich slag. Then, the reducing agent is added into the furnace chamber of the reaction furnace, and the oxygen-containing gas and the fuel are injected into the furnace chamber 1011 by the side blowing lance 102 to perform strong reduction smelting on the slag-rich slag and obtain the second coarse tin and the lean Tin slag. Finally, the vulcanizing agent is introduced into the furnace chamber 1011 from the feeding port 1012, and the oxygen-containing gas and the fuel are injected into the cavity 1011 by the side blowing lance 102 to vulcanize and volatilize the tin in the lean slag and obtain the waste slag.

需要理解的是,通过控制喷入量,侧吹喷枪102喷入的部分燃料也可以作为还原剂与加入的还原剂一起还原含锡物料以及富锡渣。It is to be understood that by controlling the amount of injection, a portion of the fuel injected by the side-blowing lance 102 can also be used as a reducing agent to reduce the tin-containing material and the tin-rich slag together with the added reducing agent.

所述第一粗锡和所述第二粗锡可以从放锡口1014定期排出炉腔1011。所述弃渣(即所述贫锡渣在炉腔1011内被硫化挥发后产生的渣)从放渣口1013定期排出炉腔1011。The first rough tin and the second coarse tin may be periodically discharged from the furnace opening 1014 from the furnace opening 1014. The waste slag (i.e., the slag produced after the sulfur-depleted slag is vulcanized and volatilized in the furnace chamber 1011) is periodically discharged from the slag discharge port 1013 to the furnace chamber 1011.

在现有的金属冶炼工艺中,都是在炉腔的侧壁(炉腔的侧壁不同于出烟口的壁)上设置三次风口,以便利用从三次风口输送的空气燃烧烟气中的可燃物。In the existing metal smelting process, a tertiary air vent is provided on the side wall of the furnace chamber (the side wall of the furnace chamber is different from the wall of the hood), so that the flammable combustion in the flue gas is utilized by the air delivered from the tertiary vent. Things.

但是经过发明人深入地研究后,创造性地发现:通过在出烟口1016的侧壁上设置三次风口1015,从而可以从出烟口1016的侧壁向出烟口1016输送空气,可以更加充分地燃烧烟气中的可燃物。由此可以更加充分地燃烧烟气中的可燃物,从而进一步提高根据本发明实施例的侧吹炼锡装置10的环保性。However, after intensive research by the inventors, it has been found creatively that by providing the tertiary tuyere 1015 on the side wall of the outlet 1016, air can be delivered from the side wall of the outlet 1016 to the outlet 1016, which can be more fully Burning combustibles in the flue gas. Thereby, the combustibles in the flue gas can be more sufficiently burned, thereby further improving the environmental friendliness of the side-blown tin-sizing device 10 according to the embodiment of the present invention.

加料口1012处设有卫生通风室及除尘系统,以便防止烟气和粉尘的外溢。放渣口1013处设有卫生通风室及除尘系统,以便防止烟气和粉尘的外溢。放锡口1014处设有卫生通风室及除尘系统,以便防止烟气和粉尘的外溢。A sanitary ventilating chamber and a dust removal system are provided at the feeding port 1012 to prevent the overflow of smoke and dust. A ventilating chamber and a dust removal system are arranged at the slag port 1013 to prevent the overflow of smoke and dust. There is a sanitary ventilating room and a dust removal system at 1014, so as to prevent the overflow of smoke and dust.

如图3所示,在本发明的一些示例中,侧吹炼锡装置10还可以包括余热锅炉102,余热锅炉102具有垂直上升段1021,垂直上升段1021与反应炉101一体形成,垂直上升段1021与出烟口1016相连。由此可以利用余热锅炉102回收还原熔炼、强还原熔炼以及硫化挥发过程产生的烟气中的热量。而且,通过使垂直上升段1021与反应炉101一体形成, 从而可以防止烟尘粘接,以便可以使侧吹炼锡装置10能够长期稳定运行。As shown in FIG. 3, in some examples of the present invention, the side blowing tinning apparatus 10 may further include a waste heat boiler 102 having a vertical rising section 1021, and the vertical rising section 1021 is integrally formed with the reaction furnace 101, and the vertical rising section 1021 is connected to the outlet 1016. Thereby, the waste heat boiler 102 can be used to recover the heat in the flue gas generated by the reduction smelting, the strong reduction smelting, and the vulcanization volatilization process. Moreover, by forming the vertical rising section 1021 integrally with the reaction furnace 101, Thereby, the soot adhesion can be prevented, so that the side blowing tin-making apparatus 10 can be stably operated for a long period of time.

具体而言,垂直上升段1021内具有腔体10211,腔体10211与出烟口1016连通。Specifically, the vertical rising section 1021 has a cavity 10211 therein, and the cavity 10211 is in communication with the smoke outlet 1016.

侧吹炼锡装置10还包括收尘器(例如布袋收尘器),所述收尘器可以与所述余热锅炉相连,以便利用所述收尘器回收还原熔炼、强还原熔炼以及硫化挥发过程产生的烟气中的含锡烟尘。The side blowing tin-making device 10 further includes a dust collector (for example, a bag dust collector), and the dust collector may be connected to the waste heat boiler to recover the reduction smelting, the strong reduction smelting, and the vulcanization and volatilization process by using the dust collector. Tin-containing soot in the generated flue gas.

侧吹炼锡装置10可以进一步包括冷却器,所述冷却器可以与所述余热锅炉相连且所述收尘器可以与所述冷却器相连。The side-blow tinmaking apparatus 10 may further include a cooler that may be coupled to the waste heat boiler and the dust collector may be coupled to the cooler.

其中,含锡烟尘可以加入到炉腔1011内。在开始启动侧吹炼锡装置10时,由于没有产生含锡烟尘,因此可以将含锡物料和熔剂加入到炉腔1011内。待产生含锡烟尘后,可以将含锡烟尘、含锡物料和熔剂加入到炉腔1011内。Among them, tin-containing soot can be added to the furnace chamber 1011. At the start of the side blowing of the tin-smelting device 10, since tin-containing soot is not generated, the tin-containing material and the flux can be added to the furnace chamber 1011. After the tin-containing soot is generated, the tin-containing soot, the tin-containing material, and the flux may be added to the furnace chamber 1011.

根据本发明实施例的侧吹炼锡装置10可以实现定期炼锡、定期排锡和定期排渣。The side-blowing tin-smelting apparatus 10 according to the embodiment of the present invention can realize regular tinning, regular tin discharge, and regular slagging.

根据本发明实施例的侧吹炼锡装置10和侧吹炼锡工艺的技术优势在于:The technical advantages of the side-blow tinning apparatus 10 and the side-blow tinning process according to embodiments of the present invention are:

1、能耗低:在一个炉子里面实现了从锡物料到粗锡的熔炼过程和贫锡渣的硫化挥发过程,熔炼过程采用工业氧气(氧气体积浓度30%-100%),烟气量少,烟尘率低,采用碎煤(粒煤)作为还原剂,不需要相对昂贵的冶金焦,同时回收还原熔炼、强还原熔炼和硫化挥发过程烟气中的余热。1. Low energy consumption: The smelting process from tin material to crude tin and the vulcanization volatilization process of lean tin slag are realized in a furnace. Industrial oxygen (oxygen volume concentration 30%-100%) is used in the smelting process, and the amount of flue gas is small. The dust smoke rate is low, and the crushed coal (grain coal) is used as the reducing agent, and the relatively expensive metallurgical coke is not required, and the residual heat in the flue gas of the reduction smelting, the strong reduction smelting and the vulcanization volatilization process is recovered.

2、环保好:锡精矿熔炼过程在一台密闭的反应炉101中进行,避免了烟气外逸,锡精矿或其它锡原料配合制粒后直接入炉,物料制备过程简单,生产过程中产出的锡烟尘均密封输送并返回配料,有效防止了锡尘的弥散;熔炼及硫化挥发产出的烟气经余热回收和收尘后,送脱硫系统。侧吹炉还原熔炼段和强还原熔炼段产出的粗锡从放锡口排出,硫化挥发产出的弃渣从放渣口排出,同时在加料口、放锡口和放渣口设通风室,防止锡蒸气的扩散。基本解决了锡冶炼烟气、锡尘污染的问题。2, good environmental protection: tin concentrate smelting process in a closed reaction furnace 101, to avoid the escape of smoke, tin concentrate or other tin raw materials with the granulation directly into the furnace, the material preparation process is simple, the production process The tin soot produced in the middle is sealed and transported and returned to the ingredients, effectively preventing the dispersion of tin dust; the flue gas produced by the smelting and vulcanization is recovered and collected by the waste heat, and then sent to the desulfurization system. The crude tin produced by the side melting furnace reduction smelting section and the strong reduction smelting section is discharged from the tin discharge port, and the waste slag which is vulcanized and volatilized is discharged from the slag discharge port, and the ventilating chamber is provided at the feeding port, the tin discharging port and the slag discharging port. To prevent the spread of tin vapor. Basically solved the problem of tin smelting smoke and tin dust pollution.

3、回收率高:在侧吹炼锡炉中,由于充分的利用了炉渣的热焓,熔炼过程采用工业氧气,和使用粒煤作为还原剂有效的降低了烟气量和烟尘率、降低了炉渣中的锡含量,提高了锡的直收率和回收率。3. High recovery rate: In the side-blowing tin furnace, due to the full utilization of the slag enthalpy, industrial smelting process uses industrial oxygen, and the use of granular coal as a reducing agent effectively reduces the amount of smoke and smoke, and reduces the rate. The tin content in the slag increases the direct yield and recovery of tin.

4、侧吹炼锡法是所有炼锡方法中,包括物料制备系统,流程最短的工艺,工艺装置简单、投资省。4, side blowing tinning method is the method of all tinning, including material preparation system, the shortest process, simple process equipment, investment.

在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所 指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " After, "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inside", "Outside", "Clockwise", "Counterclockwise", "Axial", The orientation or positional relationship of the "radial", "circumferential" and the like is based on the orientation or positional relationship shown in the drawings, and is merely for the convenience of describing the present invention and simplifying the description, rather than indicating or implying The device or component referred to must have a particular orientation, is constructed and operated in a particular orientation, and thus is not to be construed as limiting the invention.

此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本发明的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。Moreover, the terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, features defining "first" or "second" may include at least one of the features, either explicitly or implicitly. In the description of the present invention, the meaning of "a plurality" is at least two, such as two, three, etc., unless specifically defined otherwise.

在本发明中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接或彼此可通讯;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the present invention, the terms "installation", "connected", "connected", "fixed" and the like shall be understood broadly, and may be either a fixed connection or a detachable connection, unless explicitly stated and defined otherwise. Or in one piece; it may be a mechanical connection, or it may be an electrical connection or a communication with each other; it may be directly connected or indirectly connected through an intermediate medium, and may be an internal connection of two elements or an interaction relationship between two elements. Unless otherwise expressly defined. For those skilled in the art, the specific meanings of the above terms in the present invention can be understood on a case-by-case basis.

在本发明中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present invention, the first feature "on" or "under" the second feature may be a direct contact of the first and second features, or the first and second features may be indirectly through an intermediate medium, unless otherwise explicitly stated and defined. contact. Moreover, the first feature "above", "above" and "above" the second feature may be that the first feature is directly above or above the second feature, or merely that the first feature level is higher than the second feature. The first feature "below", "below" and "below" the second feature may be that the first feature is directly below or obliquely below the second feature, or merely that the first feature level is less than the second feature.

在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任一个或多个实施例或示例中以合适的方式结合。此外,在不相互矛盾的情况下,本领域的技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合和组合。In the description of the present specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" and the like means a specific feature described in connection with the embodiment or example. A structure, material or feature is included in at least one embodiment or example of the invention. In the present specification, the schematic representation of the above terms is not necessarily directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in a suitable manner in any one or more embodiments or examples. In addition, various embodiments or examples described in the specification, as well as features of various embodiments or examples, may be combined and combined.

尽管上面已经示出和描述了本发明的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本发明的限制,本领域的普通技术人员在本发明的范围内可以对上述实施例进行变化、修改、替换和变型。 Although the embodiments of the present invention have been shown and described, it is understood that the above-described embodiments are illustrative and are not to be construed as limiting the scope of the invention. The embodiments are subject to variations, modifications, substitutions and variations.

Claims (10)

一种侧吹炼锡装置,其特征在于,包括:A side blowing tinning device, comprising: 反应炉,所述反应炉内具有炉腔,所述炉腔的壁上设有加料口、放渣口和放锡口,所述炉腔的顶壁上设有用于排出烟气的出烟口;和a reaction furnace, wherein the reaction furnace has a furnace chamber, and a wall of the furnace chamber is provided with a feeding port, a slag discharging port and a tin discharging port, and the top wall of the furnace cavity is provided with a venting port for discharging flue gas ;with 侧吹喷枪,所述侧吹喷枪设在所述炉腔的侧壁上以便将含氧气体和燃料侧吹到所述炉腔内。A side blowing lance is disposed on a sidewall of the furnace chamber to blow an oxygen-containing gas and a fuel side into the furnace chamber. 根据权利要求1所述的侧吹炼锡装置,其特征在于,所述加料口设在所述炉腔的侧壁上,所述放锡口设在所述炉腔的侧壁上,所述放渣口设在所述炉腔的侧壁上。The side-blown tin-smelting apparatus according to claim 1, wherein the feeding port is provided on a side wall of the furnace chamber, and the tin-discharging opening is provided on a side wall of the furnace chamber, A slag tap is provided on a side wall of the furnace chamber. 根据权利要求2所述的侧吹炼锡装置,其特征在于,所述放锡口位于所述炉腔的第一端,所述放渣口位于所述炉腔的第二端,其中所述炉腔的第一端与所述炉腔的第二端相对。The side-blown tinning apparatus according to claim 2, wherein the tin-discharging opening is located at a first end of the furnace chamber, and the slag opening is located at a second end of the furnace chamber, wherein A first end of the furnace chamber is opposite the second end of the furnace chamber. 根据权利要求1所述的侧吹炼锡装置,其特征在于,所述出烟口的侧壁上设有三次风口。The side-blown tin-smelting apparatus according to claim 1, wherein a third tuyeres are provided on a side wall of the outlet. 根据权利要求1所述的侧吹炼锡装置,其特征在于,所述炉腔的侧壁上设有喷枪口,所述侧吹喷枪设在所述喷枪口内。The side-blown tin-smelting apparatus according to claim 1, wherein a spray gun port is provided on a side wall of the furnace chamber, and the side blow gun is disposed in the spray gun port. 根据权利要求1所述的侧吹炼锡装置,其特征在于,所述反应炉为卧式炉。The side-blown tinning apparatus according to claim 1, wherein the reaction furnace is a horizontal furnace. 根据权利要求6所述的侧吹炼锡装置,其特征在于,所述侧吹喷枪为多个,多个所述侧吹喷枪沿所述反应炉的长度方向间隔开地设在所述炉腔的侧壁上。The side-blown tin-smelting apparatus according to claim 6, wherein the side-blowing lances are plural, and a plurality of the side-blowing lances are spaced apart from each other in the length direction of the reaction furnace. On the side wall. 根据权利要求1所述的侧吹炼锡装置,其特征在于,所述加料口、所述放锡口和所述放渣口处均设有卫生通风室和除尘系统。The side-blown tin-smelting apparatus according to claim 1, wherein the feeding port, the tin-discharging port and the slag discharging port are provided with a sanitary ventilating chamber and a dust removing system. 根据权利要求1所述的侧吹炼锡装置,其特征在于,进一步包括余热锅炉,所述余热锅炉具有垂直上升段,所述垂直上升段与所述反应炉一体形成且与所述出烟口相连。The side-blown tinning apparatus according to claim 1, further comprising a waste heat boiler having a vertical rising section integrally formed with the reaction furnace and with the smoke outlet Connected. 根据权利要求1所述的侧吹炼锡装置,其特征在于,还包括收尘器,所述收尘器与所述余热锅炉相连。 A side-blown tinning apparatus according to claim 1, further comprising a dust collector, said dust collector being connected to said waste heat boiler.
PCT/CN2015/079923 2014-06-25 2015-05-27 Side-blast tin smelting apparatus Ceased WO2015196889A1 (en)

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CN201420348146.0 2014-06-25
CN201420348146.0U CN203960304U (en) 2014-06-25 2014-06-25 Side-blown tin metallurgy device
CN201410293171.8 2014-06-25
CN201410293171.8A CN104073652A (en) 2014-06-25 2014-06-25 Side-blown tin smelting device

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CN115478171A (en) * 2022-08-01 2022-12-16 长沙有色冶金设计研究院有限公司 Oxygen-enriched side-blown furnace and treatment method of high-sulfur metallurgical slag

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