WO2015145618A1 - Anti-glare hard coat film - Google Patents

Abstract

Provided is an anti-glare hard coat film which has excellent anti-glare properties and is capable of effectively suppressing the occurrence of glare even in cases where the anti-glare hard coat film is applied to a high-definition display. An anti-glare hard coat film which comprises an anti-glare hard coat layer on the surface of a plastic base. The anti-glare hard coat layer is formed of a cured product of a composition for forming an anti-glare hard coat layer, said composition containing an active energy ray-curable resin (component (A)), fine resin particles (component (B)), a dispersant (component (C)) and a photopolymerization initiator (component (D)). The volume average particle diameter of the fine resin particles (component (B)) is set to be within the range of 1-2.5 μm. The blending amount of the fine resin particles (component (B)) is set to be within a specific range. The dispersant (component (C)) is a compound having a specific polar group. The blending amount of the dispersant (component (C)) is set to be within a specific range.

Description

Anti-glare hard coat film

The present invention relates to an antiglare hard coat film.
In particular, the present invention relates to an antiglare hard coat film that has excellent antiglare properties and can effectively suppress the occurrence of glare even when applied to a high-definition display.

Conventionally, in a display such as a cathode ray tube (CRT), a liquid crystal display (LCD), or a plasma display (PDP), incident light from the outside (hereinafter sometimes referred to as “external light”) is reflected on the screen. There was a problem that the display image was difficult to visually recognize.
In particular, in recent years, with the increase in the size of displays, it has become increasingly important to solve such problems.

Therefore, as one means for solving the problem of external light reflection, a technique using a member having an antiglare hard coat layer has been implemented.
As a method of forming such an antiglare hard coat layer, (1) a method of roughening the surface of the hard coat layer by a physical method when forming the hard coat layer, (2) for forming the hard coat layer The method is roughly divided into three types: a method of mixing a filler into a hard coating agent, and a method of (3) mixing two components that are incompatible with the hard coating agent for forming a hard coating layer and utilizing their phase separation. Can do.
In any of these methods, fine irregularities are formed on the surface of the hard coat layer to suppress regular reflection of external light and prevent reflection of external light such as a fluorescent lamp. The mainstream method is to mix a filler into the hard coat layer (see, for example, Patent Documents 1 and 2).

That is, in Patent Document 1, (A) (a) a polyfunctional (meth) acrylate monomer and / or (meth) acrylate prepolymer and (b) reactive silica fine particles are formed on the surface of a transparent plastic film. A hard coat layer formed using a hard coat layer-forming material containing an active energy ray-sensitive composition, (B) spherical organic fine particles, and (C) a dispersant having at least one polar group in the molecule. And an antiglare hard coat film characterized in that the hard coat layer has a thickness larger than the average particle size of (B) spherical organic fine particles.
Further, (B) the average particle diameter of the spherical organic fine particles is preferably set to a value in the range of 6 to 10 μm.

Patent Document 2 discloses a hard coat layer formed on the surface of a transparent plastic film using a hard coat layer forming material containing (A) an active energy ray-sensitive composition and (B) spherical organic fine particles. Anti-glare hard coat, wherein the total haze value of the hard coat layer is 20% or less, and the value of “total haze value−internal haze value” is in the range of −10 to + 1%. A film is disclosed.
Further, (B) the average particle diameter of the spherical organic fine particles is preferably set to a value in the range of 1 to 10 μm.

Japanese Patent No. 5149052 (Claims) JP 2011-175081 A (Claims)

However, although the anti-glare hard coat film disclosed in Patent Document 1 can obtain a predetermined anti-glare property, the average particle diameter of the spherical organic fine particles is large, resulting in a glare feeling on the screen ( Hereinafter, there is a problem that it may be referred to as “glare”.
In particular, when applied to a high-definition display with a high resolution, it has become difficult to suppress the occurrence of glare, and there has been a problem that comfort when viewing the screen is reduced.

Further, the antiglare hard coat film disclosed in Patent Document 2 is not sufficiently considered in the numerical range of the average particle diameter of the spherical organic fine particles, but also contains a dispersant in the hard coat layer forming material. As a result, there was a problem that it was difficult to sufficiently control the sedimentation of the spherical organic fine particles.
As a result, not only is it difficult to stably obtain the predetermined antiglare property, but even if the predetermined antiglare property can be obtained, the spherical organic fine particles are excessively removed from the surface of the hard coat layer. In other words, there was a problem that the film could easily fall off and sufficient scratch resistance could not be obtained, and the antiglare property was likely to be lowered.

Therefore, the present inventors made extensive efforts in view of the circumstances as described above, and with respect to the antiglare hard coat layer forming composition for forming the antiglare hard coat layer, predetermined volume average particles were obtained. It has been found that, by blending resin fine particles having a diameter in a predetermined ratio and blending a predetermined dispersant in a predetermined ratio, the occurrence of glare can be effectively suppressed while maintaining excellent antiglare properties. The present invention has been completed.
That is, an object of the present invention is to provide an antiglare hard coat film that has excellent antiglare properties and can effectively suppress the occurrence of glare even when applied to a high-definition display. There is.

According to the present invention, an anti-glare hard coat film having an anti-glare hard coat layer on the surface of a plastic substrate, wherein the anti-glare hard coat layer is active energy ray curable as the component (A). Cured product of antiglare hard coat layer forming composition comprising resin, resin fine particles as component (B), dispersant as component (C), and photopolymerization initiator as component (D) The volume average particle diameter of the resin fine particles as the component (B) is set to a value within the range of 1 to 2.5 μm, and the blending amount of the resin fine particles as the component (B) is determined as the activity as the component (A). A value within the range of 0.1 to 20 parts by weight with respect to 100 parts by weight of the energy ray curable resin, and the dispersant as the component (C) has at least one polar group in the molecule, As a polar group, a carboxyl group, Compound having at least one selected from the group consisting of droxyl group, sulfo group, primary amino group, secondary amino group, tertiary amino group, amide group, quaternary ammonium base, pyridium base, sulfonium base and phosphonium base The blending amount of the dispersant as the component (C) is 0 to 2 parts by weight (excluding 0 parts by weight) with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). An anti-glare hard coat film characterized by having a value within the range is provided, and the above-described problems can be solved.
That is, if it is an anti-glare hard coat film of the present invention, resin fine particles having a relatively small volume average particle diameter relative to the anti-glare hard coat layer forming composition for forming the anti-glare hard coat layer Therefore, even if it is applied to a high-definition display, the occurrence of glare can be effectively suppressed.
In addition, since a predetermined dispersant is blended at a predetermined ratio, the sedimentation state of the resin fine particles in the coating film of the composition for forming an antiglare hard coat layer applied to the surface of the plastic substrate is effectively controlled. The anti-glare hard coat layer surface is stably formed with fine irregularities, and the resin particles have excellent anti-glare properties despite the volume average particle diameter being limited to a relatively small range. Can do.
Therefore, the antiglare hard coat film of the present invention has excellent antiglare properties and can effectively suppress the occurrence of glare even when applied to a high-definition display.

Further, in constituting the antiglare hard coat film of the present invention, the resin fine particles as the component (B) are acrylic polymer resin fine particles, acrylic-styrene copolymer resin fine particles, styrene polymer resin fine particles, and silicone resin fine particles. It is preferably at least one selected from the group consisting of
By comprising in this way, a fine unevenness | corrugation can be more stably formed with respect to the surface of an anti-glare hard-coat layer.

Further, in constituting the antiglare hard coat film of the present invention, the composition for forming an antiglare hard coat layer contains silica fine particles as the component (E), and the volume of the silica fine particles as the component (E). The average particle diameter is set to a value in the range of 2 to 500 nm, and the blending amount of the silica fine particles as the component (E) is 10 to A value within the range of 200 parts by weight is preferred.
By comprising in this way, when the anti-glare hard coat layer forming composition is applied to the surface of the plastic substrate, the sedimentation degree of the resin fine particles as the component (B) in the coating film is controlled more effectively. Thus, fine irregularities can be more stably formed on the surface of the antiglare hard coat layer.

Further, in constituting the antiglare hard coat film of the present invention, the composition for forming an antiglare hard coat layer contains a slip agent as the component (F), and contains a slip agent as the component (F). The amount is preferably set to a value in the range of 0.05 to 20 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A).
By comprising in this way, the abrasion resistance in an anti-glare hard coat film can be improved.

Further, in constituting the antiglare hard coat film of the present invention, the slip agent as the component (F) is preferably silicone oil and modified silicone oil or one of them.
By comprising in this way, the abrasion resistance in an anti-glare hard coat film can further be improved.

In constituting the antiglare hard coat film of the present invention, the film thickness of the antiglare hard coat layer is preferably set to a value in the range of 0.5 to 6 μm.
By configuring in this way, the hardness necessary for practical use is obtained, curling due to curing shrinkage of the active energy ray curable resin, and antiglare hard generated when the antiglare hard coat film is bent. Cracks in the coat layer can be suppressed.

1 (a) to 1 (b) are diagrams for explaining the antiglare hard coat film of the present invention. FIG. 2 is a diagram provided for explaining the relationship between the volume average particle diameter of resin fine particles and the glare and antiglare property of the antiglare hard coat film. FIGS. 3A to 3E are diagrams for explaining a method for evaluating glare in an antiglare hard coat film. FIGS. 4A and 4B are diagrams for explaining a particle size distribution chart of resin fine particles in Examples 1 and 2. FIG. FIG. 5 is a diagram for explaining a particle size distribution chart of resin fine particles in Comparative Example 1.

An embodiment of the present invention is an antiglare hard coat film 14 having an antiglare hard coat layer 13 on the surface of a plastic substrate 12, as shown in FIG. Layer 13 is an active energy ray-curable resin as component (A), resin fine particles as component (B), a dispersant as component (C), a photopolymerization initiator as component (D), The volume average particle diameter of the resin fine particles as the component (B) is in the range of 1 to 2.5 μm, and the component (B) The amount of the resin fine particles is a value within the range of 0.1 to 20 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A), and the dispersion as the component (C) The agent has at least one polar group in the molecule In addition, the polar group consists of carboxyl group, hydroxyl group, sulfo group, primary amino group, secondary amino group, tertiary amino group, amide group, quaternary ammonium base, pyridium base, sulfonium base and phosphonium base. A compound having at least one selected from the group, and the blending amount of the dispersant as the component (C) is 0 to 2 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A) The antiglare hard coat film 14 has a value within the range (excluding 0 parts by weight).
Embodiments of the present invention will be specifically described below with reference to the drawings as appropriate.

1. Anti-glare hard coat layer (1) Anti-glare hard coat layer forming composition The anti-glare hard coat layer in the anti-glare hard coat film of the present invention comprises an active energy ray-curable resin as component (A) and And a cured product of an antiglare hard coat layer forming composition comprising resin fine particles as component (B), a dispersant as component (C), and a photopolymerization initiator as component (D). .
Hereinafter, each component contained in the composition for forming an antiglare hard coat layer will be described.

(1) -1 Component (A): Active energy ray-curable resin As the type of active energy ray-curable resin as the component (A) contained in the composition for forming an antiglare hard coat layer in the present invention, It is not limited, and can be selected from conventionally known ones, and examples include energy ray-curable monomers, oligomers, resins, and mixtures thereof.
More specifically, it is preferable to use a polyfunctional (meth) acrylic monomer or a (meth) acrylate prepolymer.

Examples of the polyfunctional (meth) acrylic monomer include 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, neopentyl glycol di (meth) acrylate, and polyethylene. Glycol di (meth) acrylate, hydroxypivalate neopentyl glycol di (meth) acrylate, dicyclopentanyl di (meth) acrylate, caprolactone modified dicyclopentenyl di (meth) acrylate, ethylene oxide modified di (meth) acrylate phosphate, Allylated cyclohexyl di (meth) acrylate, isocyanurate di (meth) acrylate, trimethylolpropane tri (meth) acrylate, dipentaerythritol tri (meth) acrylate, propionic acid modified dipentaerythritol tri (meth) acrylate , Pentaerythritol tri (meth) acrylate, propylene oxide modified trimethylolpropane tri (meth) acrylate, tris (acryloxyethyl) isocyanurate, propionic acid modified dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) Examples thereof include polyfunctional (meth) acrylates such as acrylate and caprolactone-modified dipentaerythritol hexa (meth) acrylate.
Moreover, these monomers may be used 1 type and may be used in combination of 2 or more type.

Examples of the (meth) acrylate prepolymer include polyester acrylate, epoxy acrylate, urethane acrylate, and polyol acrylate.
Here, as the polyester acrylate-based prepolymer, for example, by esterifying hydroxyl groups of a polyester oligomer having hydroxyl groups at both ends obtained by condensation of a polyvalent carboxylic acid and a polyhydric alcohol with (meth) acrylic acid, or It can be obtained by esterifying a hydroxyl group at the terminal of an oligomer obtained by adding an alkylene oxide to a polyvalent carboxylic acid with (meth) acrylic acid.
The epoxy acrylate prepolymer can be obtained, for example, by reacting (meth) acrylic acid with an oxirane ring of a relatively low molecular weight bisphenol-type epoxy resin or novolak-type epoxy resin and esterifying it.
The urethane acrylate prepolymer can be obtained, for example, by esterifying, with (meth) acrylic acid, a polyurethane oligomer obtained by a reaction between polyether polyol or polyester polyol and polyisocyanate.
Furthermore, the polyol acrylate-based prepolymer can be obtained by esterifying the hydroxyl group of the polyether polyol with (meth) acrylic acid. These prepolymers may be used individually by 1 type, may be used in combination of 2 or more type, and may be used together with the polyfunctional (meth) acrylate type monomer mentioned above.

(1) -2 Component (B): Resin Fine Particle (i) Type As the type of resin fine particle as component (B) contained in the composition for forming an antiglare hard coat layer in the present invention, for example, silicone resin fine particles , Modified silicone resin fine particles, melamine resin fine particles, acrylic polymer resin fine particles (for example, polymethyl methacrylate resin fine particles, etc.), acrylic-styrene copolymer resin fine particles, polycarbonate resin fine particles, polyethylene resin fine particles, styrene polymer Examples thereof include resin fine particles and benzoguanamine resin fine particles.
Among these, at least one selected from the group consisting of acrylic polymer resin fine particles, acrylic-styrene copolymer resin fine particles, styrene polymer resin fine particles, and silicone resin fine particles is preferable.
This is because these resin fine particles can stably form fine irregularities on the surface of the antiglare hard coat layer.
From the viewpoint of homogenizing the light scattering state and stabilizing the antiglare property, it is preferable that the resin fine particles have a spherical shape.

(Ii) Volume average particle diameter In the present invention, the volume average particle diameter of the resin fine particles is set to a value within the range of 1 to 2.5 μm.
This is because the occurrence of glare can be effectively suppressed while maintaining excellent anti-glare properties by setting the volume average particle diameter of the resin fine particles to a value within this range.
That is, when the volume average particle diameter of the resin fine particles is less than 1 μm, it may be difficult to maintain sufficient antiglare properties. On the other hand, when the volume average particle diameter of the resin fine particles exceeds 2.5 μm, it may be difficult to effectively suppress the occurrence of glare particularly when applied to a high-definition display. .
Accordingly, the volume average particle diameter of the resin fine particles is more preferably set to a value within the range of 1.2 to 2.3 μm, and further preferably set to a value within the range of 1.3 to 2 μm.
The volume average particle diameter of the resin fine particles can be measured using a laser diffraction / scattering particle size distribution measuring apparatus.

Next, the relationship between the volume average particle diameter of the resin fine particles and the glare and antiglare property of the antiglare hard coat film will be described with reference to FIG.
That is, in FIG. 2, the horizontal axis represents the volume average particle diameter (μm) of the resin fine particles, the left vertical axis represents the glare (ppi) in the antiglare hard coat film, and the right vertical axis represents The characteristic curve B which took 60 degree specular glossiness (%) in an anti-glare hard coat film is shown.
In addition, specific methods for measuring glare (ppi) and 60 ° specular gloss (%) in an antiglare hard coat film are described in Examples.
In addition, it means that generation | occurrence | production of glare can be suppressed effectively, so that the value (ppi) of glare is large.

First, as understood from the characteristic curve A, the glare value tends to decrease as the volume average particle diameter of the resin fine particles increases.
Here, when applied to an actual high-definition display of 280 ppi or more, it is confirmed that the glare value in the characteristic curve A should be set to a value exceeding 80 ppi in order to stably suppress the occurrence of glare. Has been.
Therefore, it is understood that the volume average particle diameter of the resin fine particles should be 2.5 μm or less in order to set the glare value to a value exceeding 80 ppi and effectively suppress the glare.

Next, as understood from the characteristic curve B, the 60 ° specular gloss also tends to decrease as the volume average particle diameter of the resin fine particles increases.
Here, in order to stably obtain a predetermined antiglare property when applied to an actual display, it is necessary to set the 60 ° specular glossiness to a value of 120% or less.
Therefore, it is understood that the volume average particle diameter of the resin fine particles should be a value of 1 μm or more in order to set the 60 ° specular gloss to a value of 120% or less and stably obtain a predetermined antiglare property.
As described above, from the characteristic curves A and B, in order to effectively suppress the occurrence of glare and to obtain a predetermined antiglare property, the volume average particle diameter of the resin fine particles is set to 1-2. It is understood that the value should be in the range of 5 μm.

The Cv value of the resin fine particles is preferably set to a value of 50% or less.
The reason for this is that when the Cv value exceeds 50%, the abundance of particles having a particle size larger or smaller than the volume average particle size increases, and if the abundance of a large particle size increases, glare occurs. This is because it may be difficult to suppress the occurrence of the occurrence of an antiglare, and it may be difficult to obtain a desired antiglare property when the amount of small particle size increases.
Therefore, the Cv value of the resin fine particles is more preferably 40% or less, and further preferably 30% or less.
In addition, Cv value means the variation coefficient of the particle size distribution represented by following formula (1).
Cv value (%) = (standard deviation particle diameter / volume average particle diameter) × 100 (1)
The Cv value can be measured using a laser diffraction / scattering particle size distribution measuring apparatus.

(Iii) Blending amount The blending amount of the resin fine particles is set to a value within the range of 0.1 to 20 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). And
This is because fine irregularities are formed on the surface of the antiglare hard coat layer to obtain excellent antiglare properties.
That is, when the amount of the resin fine particles is less than 0.1 parts by weight, fine irregularities cannot be sufficiently formed on the surface of the antiglare hard coat layer, and a desired antiglare property can be obtained. This is because it may be difficult. On the other hand, when the amount of the resin fine particles exceeds 20 parts by weight, the haze value becomes excessively large, and the visibility of the display image on the display may be lowered.
Therefore, the amount of the resin fine particles is more preferably set to a value within the range of 1 to 15 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). It is more preferable to set the value within the range.

(1) -3 Component (C): Dispersant The composition for forming an antiglare hard coat layer in the present invention is characterized by containing a dispersant as the component (C).
The reason for this is that when the composition for forming an antiglare hard coat layer is applied to the surface of a plastic substrate, the amount of resin fine particles as the component (B) in the coating film is effectively settled by including a dispersant. The anti-glare hard coat layer surface is stably controlled to form fine irregularities, and the anti-glare property is excellent even though the volume average particle diameter of the resin fine particles is limited to a relatively small range. It is because it can be obtained.
That is, resin fine particles are unevenly distributed in a suitable range on the surface side of the antiglare hard coat layer, and fine irregularities on the surface of the antiglare hard coat layer can be stably formed. Obtainable.

(I) Type The dispersant as the component (C) contained in the composition for forming an antiglare hard coat layer in the present invention has at least one polar group in the molecule, and includes a carboxyl group, a hydroxyl group as the polar group. It is a compound having a group, a sulfo group, a primary amino group, a secondary amino group, a tertiary amino group, an amide group, a quaternary ammonium base, a pyridium base, a sulfonium base and a phosphonium base.
The reason for this is that if it is a dispersant having these polar groups, it effectively controls the sedimentation of resin fine particles in the coating film of the antiglare hard coat layer-forming composition applied to the surface of the plastic substrate. It is because it can do.
Although the mechanism of such a dispersant has not been clearly clarified, the polar group in the dispersant is coordinated to the surface of the resin fine particles, and as a result, the polarity of the surface of the resin fine particles changes, and the resin fine particles are coated. It is presumed that the probability of being present near the surface of the film increases.

Among the polar groups described above, a carboxyl group, a sulfo group, and a primary to tertiary amino group are particularly preferable.
This is because these polar groups can more effectively coordinate the dispersant to the surface of the resin fine particles.
In addition, one or more of the polar groups described above may be introduced into the molecule.
In addition, when having a plurality of polar groups in the molecule, a basic skeleton for bonding organic compounds having each polar group is required. As such a basic skeleton, an ester chain, a vinyl chain, an acrylic chain, Those composed of an ether chain and a urethane chain are preferred.
Moreover, a part of hydrogen atoms in these molecules may be substituted with a halogen atom.
Of these, acrylic resins, urethane resins, polyester resins and alkyd resins are preferred, and acrylic resins, urethane resins and polyester resins are particularly preferred.

Moreover, although the polar group mentioned above may be arrange | positioned at random in the molecule | numerator of resin, what has the polar group arrange | positioned at the terminal part in a molecule | numerator by a block structure or a graft structure is preferable.
This is because the adsorption performance to the resin fine particles is enhanced by the polar group being arranged at the terminal portion.
The molecular weight of the dispersant is not particularly limited, but can be selected from a wide range of from 100 to 900,000.
In addition, a dispersing agent may be used individually by 1 type, and may be used in combination of 2 or more type.

(Ii) Blending amount The blending amount of the dispersant is in the range of 0 to 2 parts by weight (excluding 0 parts by weight) with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). It is characterized by being a value within.
This is because the resin fine particles can be unevenly distributed in a suitable range on the surface of the antiglare hard coat layer.
That is, when the blending amount of the dispersant is 0 part by weight, the resin fine particles cannot be unevenly distributed in a suitable range on the surface of the antiglare hard coat layer, and it becomes difficult to obtain a desired antiglare property. Because there is. On the other hand, if the blending amount of the dispersant exceeds 2 parts by weight, the scratch resistance may decrease.
Therefore, the blending amount of the dispersant is more preferably set to a value within the range of 0.01 to 1 part by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). More preferably, the value is within the range of 0.5 parts by weight.

(1) -4 Component (E): Silica Fine Particle The composition for forming an antiglare hard coat layer in the present invention preferably contains silica fine particles as the component (E).
This is because when the composition for forming an antiglare hard coat layer is applied to the surface of a plastic substrate, the amount of resin fine particles as the component (B) in the coating film is more effectively controlled to prevent This is because fine irregularities can be more stably formed on the surface of the dazzling hard coat layer.
That is, by utilizing the difference in specific gravity with the resin fine particles, the resin fine particles are unevenly distributed on the surface side of the antiglare hard coat layer in a more suitable range, and the fine irregularities on the surface of the antiglare hard coat layer are more stable. Thus, excellent antiglare properties can be obtained.

(I) Kind As the kind of silica fine particles, it is preferable to use colloidal silica fine particles or silica fine particles having a surface functional group.
Examples of the silica fine particles having a surface functional group include silica fine particles having a group containing a (meth) acryloyl group as the surface functional group (hereinafter sometimes referred to as reactive silica fine particles).
Such reactive silica fine particles can be obtained, for example, by reacting a silanol group on the surface of the silica fine particles with a polymerizable unsaturated group-containing organic substance having a functional group capable of reacting with the silanol group.
Examples of the polymerizable unsaturated group include a radical polymerizable (meth) acryloyl group.
Examples of the polymerizable unsaturated group-containing organic compound having a functional group capable of reacting with a silanol group include acrylic acid, acrylic acid chloride, 2-isocyanatoethyl acrylate, glycidyl acrylate, and 2,3-acrylic acid. Iminopropyl, 2-hydroxyethyl acrylate, acryloyloxypropyltrimethoxysilane, and the like, and methacrylic acid derivatives corresponding to these acrylic acid derivatives can be preferably used.
In addition, these acrylic acid derivatives and methacrylic acid derivatives may be used individually by 1 type, and may be used in combination of 2 or more type.

(Ii) Volume average particle size The volume average particle size of the silica fine particles is preferably set to a value in the range of 2 to 500 nm.
This is because when the volume average particle diameter of the silica fine particles is less than 2 nm, the dispersion stability of the silica fine particles may decrease. On the other hand, when the volume average particle diameter of the silica fine particles exceeds 500 nm, the haze value may excessively increase due to the silica fine particles.
Accordingly, the volume average particle diameter of the silica fine particles is more preferably set to a value within the range of 4 to 300 nm, and further preferably set to a value within the range of 6 to 50 nm.
The volume average particle diameter of the silica fine particles can be measured using a laser diffraction / scattering particle size distribution measuring apparatus.

(Iii) Blending amount The blending amount of the silica fine particles is preferably set to a value within the range of 10 to 200 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A).
The reason for this is that if the amount of silica fine particles is less than 10 parts by weight, it may be difficult to make the resin fine particles unevenly distributed on the surface of the antiglare hard coat layer. On the other hand, when the blending amount of the silica fine particles exceeds 200 parts by weight, the scratch resistance may be lowered due to a decrease in the blending ratio of the active energy ray-curable resin.
Accordingly, the blending amount of the silica fine particles is more preferably 12 to 175 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A), preferably 15 to 150 parts by weight. It is more preferable to set the value within the range.

(1) -5 (D) Component: Photopolymerization Initiator (i) Type As the type of the photopolymerization initiator as the (D) component contained in the antiglare hard coat layer forming composition in the present invention, for example, , Benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin-n-butyl ether, benzoin isobutyl ether, acetophenone, dimethylaminoacetophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxy-2- Phenylacetophenone, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, 2-methyl-1- [4- (methylthio) phenyl] -2-morpholino-propane-1- ON, 4- (2-hydroxy Toxi) phenyl-2 (hydroxy-2-propyl) ketone, benzophenone, p-phenylbenzophenone, 4,4'-diethylaminobenzophenone, dichlorobenzophenone, 2-methylanthraquinone, 2-ethylanthraquinone, 2-tertiarybutylanthraquinone, 2 -Aminoanthraquinone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, benzyldimethyl ketal, acetophenone dimethyl ketal, p-dimethylaminobenzoate, etc. Can be mentioned.
In addition, these may be used individually by 1 type and may be used in combination of 2 or more type.

(Ii) Blending amount The blending amount of the photopolymerization initiator should be a value within the range of 0.2 to 10 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). Is preferred.
This is because it may be difficult to obtain sufficient curability when the blending amount of the photopolymerization initiator is less than 0.2 parts by weight. On the other hand, when the blending amount of the photopolymerization initiator exceeds 10 parts by weight, the scratch resistance may be lowered.
Accordingly, the blending amount of the photopolymerization initiator is more preferably set to a value within the range of 0.5 to 7 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). More preferably, the value is within the range of 5 parts by weight.

(1) -6 (F) Component: Slip Agent The antiglare hard coat layer forming composition in the present invention preferably contains a slip agent as the component (F).
This is because the scratch resistance of the antiglare hard coat film can be improved by including a slip agent.
That is, in the present invention, since the volume average particle diameter of the resin fine particles as the component (B) is limited to a relatively small range, the resin fine particles unevenly distributed on the surface of the antiglare hard coat layer are caused by friction or the like. It may be easy to drop off.
In this regard, by improving the slip property of the antiglare hard coat layer surface by the slip agent, the predetermined fine scratch resistance can be obtained even though the volume average particle diameter of the resin fine particles is limited to a relatively small range. Obtainable.

(I) Type The type of slip agent is preferably silicone oil and modified silicone oil or one of them.
This is because these slip agents are excellent in compatibility with other components in the antiglare hard coat layer forming composition, and further improve the scratch resistance in the antiglare hard coat film. Because it can.
More specifically, silicone-modified urethane acrylate and a mixture of urethane acrylate, polydimethylsiloxane, modified polydimethylsiloxane and the like can be mentioned.

(Ii) Blending amount The blending amount of the slip agent is preferably set to a value in the range of 0.05 to 20 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). .
This is because when the blending amount of the slip agent is less than 0.05 parts by weight, sufficient slip properties cannot be obtained, and it may be difficult to obtain sufficient scratch resistance. On the other hand, when the blending amount of the slip agent exceeds 20 parts by weight, the scratch resistance may be lowered due to a decrease in the blending ratio of the active energy ray-curable resin.
Therefore, the blending amount of the slip agent is more preferably 0.5 to 15 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). More preferably, the value is within the range of parts by weight.

(1) -7 Preparation of composition for forming antiglare hard coat layer The composition for forming an antiglare hard coat layer used in the present invention may be used as an essential component described above in an appropriate solvent, if necessary. It can be prepared by adding the components A) to (D) and the optional components (E) to (F) and dissolving or dispersing them.
At this time, in addition to the components (A) to (F), for example, an antioxidant, an ultraviolet absorber, a silane coupling agent, a light stabilizer, a leveling agent, an antifoaming agent and the like can be added.
Examples of the solvent used include aliphatic hydrocarbons such as hexane and heptane, aromatic hydrocarbons such as toluene and xylene, halogenated hydrocarbons such as methylene chloride and ethylene chloride, methanol, ethanol, propanol, and butanol. Alcohols, acetone, methyl ethyl ketone, ketones such as 2-pentanone, isophorone and cyclohexanone, esters such as ethyl acetate and butyl acetate, cellosolve solvents such as ethyl cellosolve and the like.
The concentration and viscosity of the antiglare hard coat layer forming composition thus prepared may be in a numerical range that can be coated on the surface of the plastic substrate, and should be appropriately selected according to the situation. Can do.

(2) Film thickness The film thickness of the antiglare hard coat layer is preferably set to a value in the range of 0.5 to 6 μm.
This is because when the film thickness of the antiglare hard coat layer is less than 0.5 μm, it may be difficult to obtain the hardness required for actual use in pencil hardness. On the other hand, when the film thickness of the antiglare hard coat layer exceeds 6 μm, curling due to the curing shrinkage of the active energy ray curable resin and antiglare generated when the antiglare hard coat film is bent. This is because it may be difficult to suppress cracks in the conductive hard coat layer.
Therefore, the film thickness of the antiglare hard coat layer is more preferably set to a value within the range of 1 to 6 μm, and further preferably set to a value within the range of 2 to 5 μm.

2. Plastic substrate As the type of plastic substrate in the present invention, it can be appropriately selected from known plastic substrates as a substrate for conventional optical hard coat films, such as polyethylene terephthalate, polybutylene terephthalate, Polyester film such as polyethylene naphthalate, polyethylene film, polypropylene film, cellophane, diacetyl cellulose, triacetyl cellulose, acetyl cellulose butyrate, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, ethylene-vinyl acetate copolymer, polystyrene, polycarbonate , Polymethylpentene, polysulfone, polyether ether ketone, polyether sulfone, polyether imide, polyimide, fluororesin, poly Examples include imide, acrylic resin, norbornene resin, and cycloolefin resin.
The film thickness of the plastic substrate is preferably set to a value in the range of 15 to 300 μm, and more preferably set to a value in the range of 30 to 200 μm.

Further, for example, as shown in FIG. 1 (b), the antiglare hard coat film of the present invention can be bonded to a polarizer to form a polarizing plate 20.
That is, a film 12a having no optical anisotropy, such as a triacetylcellulose (TAC) film, is used as a plastic substrate, and an antiglare hard coat layer 13 is formed on one surface thereof, and an antiglare hard coat film 14 is formed. And
Next, a TAC film 12a having an antiglare hard coat layer 13 formed on one surface of the polyvinyl alcohol polarizer 11 is laminated via an adhesive layer 15a, and an antiglare hard disk is formed on the opposite surface of the polyvinyl alcohol polarizer. The TAC film 12b on which the coat layer 13 is not formed is laminated via the adhesive layer 15b.
Thereby, while having the outstanding anti-glare property, even if it is a case where it applies to a high-definition display, the polarizing plate 20 which can suppress generation | occurrence | production of glare effectively is obtained.
The polarizing plate 20 may be provided with an adhesive layer 16 and a release sheet 17 for bonding to an optical component such as a liquid crystal cell.

3. Characteristics of antiglare hard coat film (1) 60 ° specular gloss The 60 ° specular gloss of an antiglare hard coat film measured in accordance with JIS Z 8741 may be 130% or less. preferable.
This is because it may be difficult to obtain excellent antiglare properties when the 60 ° specular glossiness exceeds 130%.
Accordingly, the 60 ° specular gloss of the antiglare hard coat film measured in accordance with JIS Z 8741 is more preferably 120% or less, and even more preferably 115% or less.

(2) Glitter In addition, as will be described later in the embodiment, a grid pattern in which a light transmission portion is provided so as to have a predetermined ppi (pixel / inch) as shown in FIGS. It is preferable to set the glare evaluation result to be a value within a range exceeding 80 ppi.
This is because, when the evaluation result of the glare is a value of 80 ppi or less, glare is likely to occur when applied to an actual high-definition display of 280 ppi or more.
Therefore, it is more preferable to set the glare evaluation result implemented as described later in the examples to a value of 90 ppi or more, and more preferably to a value of 100 ppi or more.
The glare caused by the antiglare hard coat film is more likely to occur as the ppi in the lattice pattern increases, in other words, as the display becomes higher definition.
Therefore, the larger the ppi value mentioned above, the more effectively the occurrence of glare can be suppressed.

(3) Haze value The haze value of the antiglare hard coat film measured in accordance with JIS K 7136 is preferably set to a value in the range of 3 to 40%.
The reason for this is that when the haze value is less than 3%, it may be difficult to obtain excellent antiglare properties. On the other hand, if the haze value exceeds 40%, the visibility of the display image on the display may be lowered.
Accordingly, the haze value of the antiglare hard coat film measured in accordance with JIS K 7136 is more preferably set to a value in the range of 3.5 to 35%, and a value in the range of 4 to 30%. More preferably.

(4) Total light transmittance Moreover, it is preferable to make the total light transmittance of the anti-glare hard coat film measured based on JIS K 7361 into the value of 85% or more.
This is because the visibility of the display image on the display may be reduced when the total light transmittance is less than 85%.
Therefore, the total light transmittance of the antiglare hard coat film measured in accordance with JIS K 7361 is more preferably 88% or more, and even more preferably 90% or more.

(5) Hardness Moreover, it is preferable that an anti-glare hard coat film is a thing without an external appearance change in the abrasion-resistant evaluation using steel wool.
This is because it may be difficult to obtain sufficient scratch resistance as a hard coat film when a change in appearance is observed in the evaluation of scratch resistance.
Details of the evaluation of the scratch resistance will be described later.

4). Method for Producing Antiglare Hard Coat Film As a method for producing the antiglare hard coat film of the present invention, first, a composition for forming an antiglare hard coat layer on the surface of a plastic substrate is a conventionally known method, For example, the coating is performed using a bar coating method, a knife coating method, a roll coating method, a blade coating method, a die coating method, a gravure coating method, or the like.
Subsequently, after drying a coating film, an active energy ray is irradiated, a coating film is hardened, and an anti-glare hard coat film is obtained by making a coating film into an anti-glare hard coat layer.

The active energy ray for curing the coating film includes ultraviolet rays, and the ultraviolet rays can be irradiated by a high-pressure mercury lamp, an electrodeless lamp, a metal halide lamp, a xenon lamp, or the like.
In addition, it is preferable that the irradiation amount of ultraviolet rays is usually in the range of 100 to 500 mJ / cm ² .

Hereinafter, the antiglare hard coat film of the present invention will be described in more detail with reference to Examples.

[Example 1]
1. Production of Antiglare Hard Coat Film (1) Preparation Step of Composition for Forming Antiglare Hard Coat Layer As shown in Table 1 and below, active energy ray-curable resin as component (A), and (B) Resin fine particles as a component, a dispersant as a component (C), a photopolymerization initiator as a component (D), a silica fine particle as a component (E), and a slip agent as a component (F). While mixing, it was diluted with propylene glycol monomethyl ether to prepare a composition for forming an antiglare hard coat layer having a solid content of 30% by weight.
In addition, the compounding quantity in Table 1 and the following shows the value converted into solid content.

(A) Component: Multifunctional acrylate: 100 parts by weight (B) Component: Cross-linked acrylic polymer resin fine particles: 10 parts by weight (manufactured by Sekisui Plastics Co., Ltd., Techpolymer XX-27LA, volume average particle diameter: 1 .5 μm, Cv value: 23%)
Component (C): Modified carboxyl group-containing polymer: 0.1 part by weight (Kyoeisha Chemical Co., Ltd., Floren G700)
Component (D): 1-hydroxy-cyclohexyl-phenyl-ketone: 5 parts by weight (manufactured by BSF Corporation, Irgacure 184)
Component (E): acryloyl group-introduced nano silica sol: 150 parts by weight (volume average particle diameter: 50 nm)
Component (F): Silicone-modified urethane acrylate / urethane acrylate: 7 parts by weight (manufactured by Nippon Synthetic Chemical Industry Co., Ltd., purple light UV-AF100)

Further, the Cv value of the component (B) means a variation coefficient of the particle size distribution represented by the following formula (1).
Cv value (%) = (standard deviation particle diameter / volume average particle diameter) × 100 (1)
The volume average particle size and Cv value of the component (B) were measured using a laser diffraction / scattering particle size distribution analyzer (LA-920, manufactured by Horiba, Ltd.).
At this time, methyl ethyl ketone was used as a dispersion solvent.
In addition, the particle size distribution chart of (B) component used in Example 1 is shown to Fig.4 (a).

(2) Coating process Next, the obtained composition for forming an antiglare hard coat layer was easily made into a polyester film with an easy-adhesion layer as a plastic substrate (manufactured by Toray Industries, Inc., Lumirror U48, film thickness: 100 μm). The wire layer # 14 was applied to the adhesive layer so that the film thickness after curing was 5 μm to form a coating layer.

(3) Drying process Next, the obtained coating layer was dried under conditions of 70 ° C. for 1 minute using a hot air drying apparatus.

(4) Curing step Next, the dried coating layer is irradiated with ultraviolet rays under the following conditions using an ultraviolet irradiation device (GS Yuasa Corporation, light source: high-pressure mercury lamp) to cure the coating layer. Thus, a final antiglare hard coat film was obtained as an antiglare hard coat layer.
Illuminance: 100 mW / cm ²
Light intensity: 240 mJ / cm ²

2. Evaluation (1) Evaluation 1 of antiglare property
The antiglare property of the obtained antiglare hard coat film was evaluated.
That is, the obtained antiglare hard coat film was placed on a black plate so that the antiglare hard coat layer was on top.
Next, a three-wavelength fluorescent lamp was turned on above the antiglare hard coat film, reflected by the antiglare hard coat film, and evaluated according to the following criteria. The obtained results are shown in Table 2.
○: The outline of the fluorescent lamp visually recognized by the reflection on the antiglare hard coat film is blurred. ×: The outline of the fluorescent lamp visually recognized by the reflection on the antiglare hard coat film is not blurred.

(2) Anti-glare evaluation 2
The antiglare property of the obtained antiglare hard coat film was evaluated based on the specular gloss (%).
That is, using a gloss meter (Nippon Denshoku Industries Co., Ltd., VG2000), the 60 ° specular gloss (%) of the obtained antiglare hard coat film was measured according to JIS Z 8741. The obtained results are shown in Table 2.

(3) Evaluation of glare The occurrence of glare in the obtained antiglare hard coat film was evaluated.
That is, as shown in FIG. 3A, a lattice pattern provided with a light transmission portion so as to be 60 ppi (pixels / inch) was prepared.
Such a lattice-shaped pattern was prepared by providing a metal vapor deposition layer on a glass plate, performing a resist treatment on the metal vapor deposition layer, etching, and then removing the resist.
Next, the prepared grid pattern was placed on a backlight (Bright Box 5000, manufactured by King Corp.).
Subsequently, the obtained antiglare hard coat film was placed on the lattice pattern so that the antiglare hard coat layer was on top, and the occurrence of glare was confirmed.
Next, the antiglare hard coat film is moved in a direction parallel to the lattice pattern, and when the occurrence of the glare previously confirmed moves together with the antiglare hard coat film, the glare It was judged that the occurrence of the phenomenon was caused by the antiglare hard coat film.

In addition, when the occurrence of glare due to the antiglare hard coat film was not confirmed in the lattice pattern of 60 ppi, the antiglare hard coat was sequentially used by increasing the ppi in increments of 10 ppi. The same operation was repeated until the occurrence of glare caused by the film was confirmed.
Table 2 shows the largest lattice pattern (ppi) in which the occurrence of glare due to the antiglare hard coat film is not confirmed.
The glare caused by the antiglare hard coat film is more likely to occur as the ppi in the lattice pattern increases, in other words, as the display becomes higher definition.
Therefore, it means that generation | occurrence | production of glare can be suppressed effectively, so that the value of ppi shown in Table 2 is large.
FIG. 3B shows a photograph of an 80 ppi lattice pattern, FIG. 3C shows a photograph of a 100 ppi lattice pattern, and FIG. 3D shows a photograph of a 140 ppi lattice pattern. FIG. 3E shows photographs of a 180 ppi lattice pattern.

(4) Evaluation of haze value The haze value (%) in the obtained antiglare hard coat film was evaluated.
That is, the haze value (%) of the obtained antiglare hard coat film was measured based on JIS K 7136 using a haze meter (NDH5000, manufactured by Nippon Denshoku Industries Co., Ltd.). The obtained results are shown in Table 2.

(5) Evaluation of total light transmittance Total light transmittance (%) in the obtained antiglare hard coat film was evaluated.
That is, the total light transmittance (%) of the obtained antiglare hard coat film was measured based on JIS K 7361 using a haze meter (NDH5000, manufactured by Nippon Denshoku Industries Co., Ltd.). The obtained results are shown in Table 2.

(6) Evaluation of scratch resistance The scratch resistance of the obtained antiglare hard coat film was evaluated.
That is, using a # 0000 steel wool, the anti-glare hard coat layer of the obtained anti-glare hard coat film was subjected to a 10 reciprocating rub test at a load of 250 g / cm ² and a sliding distance of 10 cm. .
Next, the presence or absence of scratches on the antiglare hard coat layer was visually confirmed under a three-wavelength fluorescent lamp, and evaluated according to the following criteria. The obtained results are shown in Table 2.
○: No change is confirmed in the appearance of the antiglare hard coat layer ×: A change is confirmed in the appearance of the antiglare hard coat layer

[Example 2]
In Example 2, the antiglare hard coat film was the same as in Example 1 except that the components (A) to (B) and (E) in the antiglare hard coat layer forming composition were changed as follows. Were manufactured and evaluated. The obtained results are shown in Table 2.
Moreover, the particle size distribution chart of (B) component used in Example 2 is shown in FIG.4 (b).

(A1) Component: Urethane Acrylate Prepolymer: 70 parts by weight (A2) Component: Multifunctional acrylate: 30 parts by weight (B) Component: Crosslinked acrylic-styrene copolymer resin fine particles: 5 parts by weight (Sekisui Plastics Industry ( Co., Ltd., Techpolymer XX16LA, volume average particle size: 2.5 μm, Cv value: 28%)
Component (E): Nanosilica sol: 45 parts by weight (manufactured by Nissan Chemical Co., Ltd., MIBK-ST, volume average particle size: 10 nm)

[Example 3]
In Example 3, an antiglare hard coat film was produced in the same manner as in Example 1, except that the components (A) to (E) in the antiglare hard coat layer forming composition were changed as follows: evaluated. The obtained results are shown in Table 2.

Component (A): Multifunctional acrylate (dipentaerythritol hexaacrylate): 100 parts by weight (manufactured by Shin-Nakamura Kogyo Co., Ltd., NK Ester A-DPH)
(B) component: Silicone resin fine particles: 5 parts by weight (Momentive Co., Ltd., Tospearl 120, volume average particle size: 2 μm, Cv value: 20%)
Component (C): Modified carboxyl group-containing polymer: 0.05 parts by weight (Kyoeisha Chemical Co., Ltd., Floren G700)
Component (D): 1-hydroxy-cyclohexyl-phenyl-ketone: 3 parts by weight (manufactured by BSF Corporation, Irgacure 184)
Component (E): Reactive nano silica sol: 18 parts by weight (manufactured by Nissan Chemical Co., Ltd., MIBK-SD, volume average particle size: 10 nm)

[Example 4]
In Example 4, an antiglare hard coat film was produced and evaluated in the same manner as in Example 1 except that the component (F) was not blended in the antiglare hard coat layer forming composition. The obtained results are shown in Table 2.

[Comparative Example 1]
In Comparative Example 1, an antiglare hard coat film was produced and evaluated in the same manner as in Example 1 except that the component (B) in the antiglare hard coat layer forming composition was changed as follows. The obtained results are shown in Table 2.
Further, a particle size distribution chart of the component (B) used in Comparative Example 1 is shown in FIG.
(B) Component: Crosslinked acrylic polymer resin fine particles: 10 parts by weight (manufactured by Soken Chemical Co., Ltd., MX-80H3 wt, volume average particle size: 0.8 μm, Cv value: 10%)

[Comparative Example 2]
In Comparative Example 2, an antiglare hard coat film was produced and evaluated in the same manner as in Example 1 except that the component (B) in the antiglare hard coat layer forming composition was changed as follows. The obtained results are shown in Table 2.
Component (B): Cross-linked acrylic polymer resin fine particles: 10 parts by weight (manufactured by Soken Chemical Co., Ltd., Mx-300, volume average particle size: 3 μm, Cv value: 10%)

As described above in detail, according to the present invention, resin fine particles having a predetermined volume average particle diameter are predetermined for an antiglare hard coat layer forming composition for forming an antiglare hard coat layer. In addition, by adding a predetermined dispersant at a predetermined ratio, it has become possible to effectively suppress the occurrence of glare while maintaining excellent antiglare properties.
As a result, according to the present invention, an antiglare hard coat film that has excellent antiglare properties and can effectively suppress the occurrence of glare even when applied to a high-definition display is obtained. I was able to do it.
Therefore, the antiglare hard coat film of the present invention is expected to contribute significantly to the improvement of visibility in a high-definition display.

12: Plastic substrate, 12a, b: TAC film, 13: Antiglare hard coat layer, 14: Antiglare hard coat film, 15a, b: Adhesive layer, 16: Adhesive layer, 17: Release sheet, 20: Polarizing plate

Claims (6)

An antiglare hard coat film comprising an antiglare hard coat layer on the surface of a plastic substrate,
The antiglare hard coat layer comprises an active energy ray-curable resin as component (A), resin fine particles as component (B), a dispersant as component (C), and light as component (D). And a cured product of a composition for forming an antiglare hard coat layer containing a polymerization initiator,
The volume average particle diameter of the resin fine particles as the component (B) is set to a value within the range of 1 to 2.5 μm, and the blending amount of the resin fine particles as the component (B) is defined as the active energy as the component (A). A value within the range of 0.1 to 20 parts by weight with respect to 100 parts by weight of the linear curable resin, and
The dispersant as the component (C) has at least one polar group in the molecule, and the polar group includes a carboxyl group, a hydroxyl group, a sulfo group, a primary amino group, a secondary amino group, and a tertiary amino group. A compound having at least one selected from the group consisting of a group, an amide group, a quaternary ammonium base, a pyridium base, a sulfonium base, and a phosphonium base, and the blending amount of the dispersant as the component (C) is ( A) Antiglare hard coat characterized by having a value within the range of 0 to 2 parts by weight (excluding 0 parts by weight) with respect to 100 parts by weight of the active energy ray-curable resin as component A) the film. The resin fine particles as the component (B) are at least one selected from the group consisting of acrylic polymer resin fine particles, acrylic-styrene copolymer resin fine particles, styrene polymer resin fine particles, and silicone resin fine particles. The antiglare hard coat film according to claim 1. The antiglare hard coat layer forming composition contains silica fine particles as the component (E), and the volume average particle size of the silica fine particles as the component (E) is set to a value within the range of 2 to 500 nm. The blending amount of the silica fine particles as the component (E) is set to a value within the range of 10 to 200 parts by weight with respect to 100 parts by weight of the active energy ray-curable resin as the component (A). The anti-glare hard coat film according to claim 1 or 2. The composition for forming an antiglare hard coat layer contains a slip agent as the component (F), and the amount of the slip agent as the component (F) is cured with active energy rays as the component (A). The antiglare hard coat film according to any one of claims 1 to 3, wherein the value is in the range of 0.05 to 20 parts by weight with respect to 100 parts by weight of the adhesive resin. The anti-glare hard coat film according to claim 4, wherein the slip agent as the component (F) is silicone oil or modified silicone oil. 6. The antiglare hard coat film according to claim 1, wherein the film thickness of the antiglare hard coat layer is set to a value within a range of 0.5 to 6 μm.

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