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WO2015056003A3 - Apparatus and method using ultrasounds for gas conversion - Google Patents

Apparatus and method using ultrasounds for gas conversion Download PDF

Info

Publication number
WO2015056003A3
WO2015056003A3 PCT/GB2014/053089 GB2014053089W WO2015056003A3 WO 2015056003 A3 WO2015056003 A3 WO 2015056003A3 GB 2014053089 W GB2014053089 W GB 2014053089W WO 2015056003 A3 WO2015056003 A3 WO 2015056003A3
Authority
WO
WIPO (PCT)
Prior art keywords
ultrasonic energy
process gas
generator
gas
generate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2014/053089
Other languages
French (fr)
Other versions
WO2015056003A2 (en
Inventor
Mark Wells
Andrew Marshall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coldharbour Marine Ltd
Original Assignee
Coldharbour Marine Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB201318187A external-priority patent/GB201318187D0/en
Priority claimed from GB201416538A external-priority patent/GB201416538D0/en
Priority to EA201690778A priority Critical patent/EA034806B1/en
Priority to EP14787029.9A priority patent/EP3057701A2/en
Priority to CN201480068047.XA priority patent/CN105992642A/en
Priority to US15/029,099 priority patent/US10765988B2/en
Application filed by Coldharbour Marine Ltd filed Critical Coldharbour Marine Ltd
Priority to GB1608306.5A priority patent/GB2548418A/en
Priority to KR1020167012727A priority patent/KR20160098189A/en
Priority to JP2016523317A priority patent/JP6727121B2/en
Publication of WO2015056003A2 publication Critical patent/WO2015056003A2/en
Publication of WO2015056003A3 publication Critical patent/WO2015056003A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8671—Removing components of defined structure not provided for in B01D53/8603 - B01D53/8668
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/16—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with particles being subjected to vibrations or pulsations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63J—AUXILIARIES ON VESSELS
    • B63J4/00—Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for
    • B63J4/002—Arrangements of installations for treating ballast water, waste water, sewage, sludge, or refuse, or for preventing environmental pollution not otherwise provided for for treating ballast water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/04—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids
    • F01N3/043—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust using liquids without contact between liquid and exhaust gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/103—Oxidation catalysts for HC and CO only
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
    • F04F1/00—Pumps using positively or negatively pressurised fluid medium acting directly on the liquid to be pumped
    • F04F1/18—Pumps using positively or negatively pressurised fluid medium acting directly on the liquid to be pumped the fluid medium being mixed with, or generated from the liquid to be pumped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/816—Sonic or ultrasonic vibration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00946—Features relating to the reactants or products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0884—Gas-liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B13/00—Conduits for emptying or ballasting; Self-bailing equipment; Scuppers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2250/00—Combinations of different methods of purification
    • F01N2250/08—Combinations of different methods of purification filtering and inertial particulate separation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Toxicology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Ocean & Marine Engineering (AREA)
  • Materials Engineering (AREA)
  • Public Health (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Physical Water Treatments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A gas conversion apparatus (100) for converting a process gas to one or more other gases comprises: means (105) for introducing process gas into a liquid medium in a column (125); and an ultrasonic energy generator (140) arranged to generate ultrasonic energy, the apparatus (100) being configured to launch ultrasonic energy generated by the generator (140) into the liquid medium such that process gas is exposed to ultrasonic energy, the apparatus (100) being arranged to allow collection of process gas that has been exposed to ultrasonic energy. The apparatus (100) also preferably comprises a microbubble generator (120) to generate microbubbles of the process gas for exposure to the ultrasonic energy. The ultrasonic energy generator (140) may be configured to generate ultrasonic energy as a consequence of a flow of a drive gas therethrough.
PCT/GB2014/053089 2013-10-14 2014-10-14 Apparatus and method Ceased WO2015056003A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2016523317A JP6727121B2 (en) 2013-10-14 2014-10-14 Device and method using ultrasound for gas conversion
KR1020167012727A KR20160098189A (en) 2013-10-14 2014-10-14 Apparatus and method using ultrasounds for gas conversion
EP14787029.9A EP3057701A2 (en) 2013-10-14 2014-10-14 Apparatus and method
CN201480068047.XA CN105992642A (en) 2013-10-14 2014-10-14 Apparatus and method using ultrasound for gas conversion
US15/029,099 US10765988B2 (en) 2013-10-14 2014-10-14 Apparatus and method for treating gas in a liquid medium with ultrasonic energy for chemical reaction
EA201690778A EA034806B1 (en) 2013-10-14 2014-10-14 Gas conversion apparatus, fuel burning engine in combination with said apparatus and method of converting one or more reactant chemical species using said apparatus
GB1608306.5A GB2548418A (en) 2013-10-14 2014-10-14 Apparatus and method using ultrasounds for gas conversion

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB201318187A GB201318187D0 (en) 2013-10-14 2013-10-14 Apparatus and method
GB1318187.0 2013-10-14
GB1416538.5 2014-09-18
GB201416538A GB201416538D0 (en) 2014-09-18 2014-09-18 Apparatus And Method

Publications (2)

Publication Number Publication Date
WO2015056003A2 WO2015056003A2 (en) 2015-04-23
WO2015056003A3 true WO2015056003A3 (en) 2015-06-11

Family

ID=51787131

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2014/053089 Ceased WO2015056003A2 (en) 2013-10-14 2014-10-14 Apparatus and method

Country Status (8)

Country Link
US (1) US10765988B2 (en)
EP (1) EP3057701A2 (en)
JP (1) JP6727121B2 (en)
KR (1) KR20160098189A (en)
CN (2) CN109364778A (en)
EA (1) EA034806B1 (en)
GB (2) GB2521258B8 (en)
WO (1) WO2015056003A2 (en)

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US9724703B2 (en) 2014-06-06 2017-08-08 LLT International (Ireland) Ltd. Systems and methods for processing solid materials using shockwaves produced in a supersonic gaseous vortex
US9050604B1 (en) 2014-06-06 2015-06-09 LLT International (Ireland) Ltd. Reactor configured to facilitate chemical reactions and/or comminution of solid feed materials
US9452434B1 (en) 2015-04-17 2016-09-27 LLT International (Ireland) Ltd. Providing wear resistance in a reactor configured to facilitate chemical reactions and/or comminution of solid feed materials using shockwaves created in a supersonic gaseous vortex
US10427129B2 (en) * 2015-04-17 2019-10-01 LLT International (Ireland) Ltd. Systems and methods for facilitating reactions in gases using shockwaves produced in a supersonic gaseous vortex
US10434488B2 (en) 2015-08-11 2019-10-08 LLT International (Ireland) Ltd. Systems and methods for facilitating dissociation of methane utilizing a reactor designed to generate shockwaves in a supersonic gaseous vortex
CA3041545C (en) * 2016-11-14 2023-04-18 William H. Mitchell, Jr. Systems and methods for separating soluble solutions
US11203725B2 (en) 2017-04-06 2021-12-21 LLT International (Ireland) Ltd. Systems and methods for gasification of carbonaceous materials
US11484860B2 (en) 2017-07-11 2022-11-01 University Of Kentucky Research Foundation Apparatus and method for enhancing yield and transfer rate of a packed bed
CN108599624B (en) * 2018-07-02 2024-02-02 浙江理工大学 Flue-indoor temperature difference energy collecting device
CN110091612B (en) * 2019-04-09 2021-01-12 镭德杰标识科技武汉有限公司 White ink jet numbering machine is mixing system independently
BE1027227B1 (en) * 2019-04-25 2020-11-23 Atlas Copco Airpower Nv Apparatus and method for separating liquid from a gas and compressor apparatus provided with such apparatus
CN112495310B (en) * 2019-09-14 2023-02-03 南京延长反应技术研究院有限公司 System and process for strengthening propylene polymerization
FR3104450B1 (en) * 2019-12-17 2022-06-03 Univ Grenoble Alpes Fluid degassing process
CN114870663B (en) * 2022-04-01 2023-08-08 北京化工大学 Spiral-flow type hypergravity reactor

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