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WO2015047260A1 - Composition de nettoyage à tensioactif cationique et non ionique - Google Patents

Composition de nettoyage à tensioactif cationique et non ionique Download PDF

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Publication number
WO2015047260A1
WO2015047260A1 PCT/US2013/061801 US2013061801W WO2015047260A1 WO 2015047260 A1 WO2015047260 A1 WO 2015047260A1 US 2013061801 W US2013061801 W US 2013061801W WO 2015047260 A1 WO2015047260 A1 WO 2015047260A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
cleansing composition
weight
thickener
cleansing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2013/061801
Other languages
English (en)
Inventor
Eugene Hardy
Marian Holerca
Rabab Ahmed
Evangelia Arvanitidou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA2922539A priority Critical patent/CA2922539C/fr
Priority to PCT/US2013/061801 priority patent/WO2015047260A1/fr
Priority to CA3080782A priority patent/CA3080782A1/fr
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of WO2015047260A1 publication Critical patent/WO2015047260A1/fr
Priority to US14/690,320 priority patent/US9265714B2/en
Priority to US15/049,089 priority patent/US10179100B2/en
Anticipated expiration legal-status Critical
Priority to US16/032,503 priority patent/US10383808B2/en
Priority to US16/448,183 priority patent/US10772817B2/en
Priority to US16/993,330 priority patent/US11052031B2/en
Priority to US17/348,411 priority patent/US12194128B2/en
Priority to US19/009,576 priority patent/US20250134793A1/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P31/00—Antiinfectives, i.e. antibiotics, antiseptics, chemotherapeutics
    • A61P31/02—Local antiseptics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • ⁇ OQOiJ Cationic surfactants can provide antibacterial properties to a cleansing composition.
  • cationic surfactants are mixed with nonionic surfactants, there is generally a need to use thickeners to increase the viscosity to a level that is expected by consumers for a cleansing composition, such as a liquid hand soap or body wash.
  • thickeners can increase the viscosity, they can make the cleansing composition opaque or translucent. It would be desirable to provide a cleansing composition containing cationic and nonionic surfactants that is transparent.
  • An aqueous cleansing composition comprising a cationic surfactant, a nonionic surfactant, and a thickener comprising an alkoxylated methyl glucose ether, wherein a weight ratio of cationic surfactant to nonionic surfactant is greater than 0.9:1.
  • cationic surfactant does not include a cationic antibacterial agent selected from t e group consisting of benzalkoninm chloride, benzethonium chloride, and mixtures thereof. While these materials may function as a cationic surfactant, they are not included in the calculation.
  • ⁇ D00 J Transparency is defined as the abilit to read 12 ⁇ point font through the composition contained in a 4 z clear, glass sample bottle of 4cm thickness. Transparency is measured after 24 hours at 4.5°C.
  • jOOI f Viscosity is measured using a Brookfteld RVT viscometer with spindle # 5 at 25 rpra at 2S°C.
  • the composition includes a cationic surfactant.
  • the cationic surfactant can be any cationic surfactant, but it excludes the cationic bacterial agent for weight ratio calculation, in certain embodiments, the cationic surfactant comprises a quaternary ammonium alky I salt.
  • the quaternary ammonium alkyl salt can be an alkyltrimethylammonium salts.
  • the salt can be a halide, such as chloride or bromide, or a methosulfate.
  • the alkyl can be a C8-C24 alkyl or a C14-C18 alkyl.
  • the cationic surfactant is cetyltriraethylamraoniura chloride.
  • the cationic surfactant is present in an amount of 0.1 to 20 weight % of the composition. In other embodiments, the amount is 0.1 to 10, 0J to 5, 0.5 to 10,
  • the composition includes a nonionic surfactant.
  • the nonionic surfactants can be any nonionic surfactant.
  • Nonionic surfactants include, but are not limited to. amine oxides, fatty acid amides, ethoxylated fatty alcohols, block copoly mers of polyethylene glycol and polypropylene glycol, glycerol alkyl esters, alkyl polyglucosides, polyoxyethylerte glycol octylphenol ethers, sorbitan alkyl esters, polyoxyethylene glycol sorbitan alkyl esters, and mixtures thereof
  • amine oxides include, but are not limited to, laurylamidopropyl dimethylamine oxide, myrisrylamidopropyl dimethySaraine oxide, and mixtures thereof.
  • fatty acid amides include, but are not limited to, cocomonoethanolamide ⁇ !auramide monoethanolarnide, cocodiethanolamide, and mixtures thereof.
  • the nomomc surfactant is a combination of an amine oxide and a fatty add amide.
  • the amine oxide is a mixture of laurylamidopropyl dimethylamine oxide and myristyiamido ropyl dimethylamine oxide.
  • the nonionic surfactant is a combination of lauryl'myristylamidopropyl dimethylamine oxide and cocomonoeihanolarnide.
  • the non.ion.ic surfactant is present in an amount of 0.1 to 20 weight % of the composition, in other embodiments, the amount is 0.1 to 10, 0.1 to 5, 0.5 to 10, 0.5 to 5, or 0.5 to 3 weight %.
  • the composition has a cationic.nonionic weight ratio greater than 0.9; 1.
  • the ratio is at least 1: 1 ,
  • the composition does not contain an anionic surfactant.
  • the composition also includes a thickener comprising an alkoxylated methyl glucose ether.
  • the aikoxylation can be ethoxylated and/or propoxylated. In certain embodiments, it is ethoxylated.
  • the degree of aikoxylation can be any degree that provides thickening, in certain embodiments, the degree of aikoxylation is 100 to 200. In certain embodiments, the aikoxylation is 120 to 150.
  • the alkoxylated methyl glucose ether can be esierified with fatty acid, in certain embodiments, the alkoxylated methyl glucose ether at least one of an alkoxylated.
  • the alkoxylated methyl glueos.de is at least one of PEG-120 methyl glucose dioleate, PEG-120 methyl glucose trioleate, PEG-120 methyl glucose distearate.
  • the alkoxylated methyl glucose ether is PEG-120 methyl, glucose dioleate.
  • the thickener can be present in any amount to provide any desired viscosity level.
  • the thickener is present in an amount of 0.1 to 2 weight % of the composition.
  • the amount is 0.1 to 1 , 0,2 to I . 0.3 to 1, 0.4 to 1, 0.1 to 0.9, 0.1 to 0.8, 0.1 to 0.7, 0.3 to 0.8, or 0.4 to 0.8 weight %.
  • the amount is 0.4 to 0.7 weight .
  • the viscosity is at least 1000 mPas. In other embodiments, the viscosity is at least 2000, at least 3000, or at least 4000 mPas. In certain embodiments, the viscosity is 1 00 to 20000, 3000 to 6000, or 3500 to 5000 rnPas.
  • the composition does not include a polyacryiate thickener.
  • the composition, ca include a cationic antibacterial agent selected from the group consisting of benzalkonium chloride, benzethomum chloride, and mixtures thereof.
  • the composition includes ben aikonhim chloride.
  • These cationic antibacterial agents can be included in their regulatory amount, which can be 0.13 weight %.
  • composition is aqueous, in certain embodiments, water can be included in an amount of 70 to 95 weight % of the composition, In other embodiments, the amount of water is 90 to 95 weight %.
  • the composition can flutlier include salt, such as sodium chloride to assist in increasing viscosity at upper ranges of viscosity, in certain embodiments, the salt is present at 0.1 to 1.2 weight % of the composition, in certain embodiments, the amount is about 0.6 weight%.
  • salt such as sodium chloride to assist in increasing viscosity at upper ranges of viscosity
  • the salt is present at 0.1 to 1.2 weight % of the composition, in certain embodiments, the amount is about 0.6 weight%.
  • he cleansing compositions can be used to cleanse skin by washing skin with the cleansing composition and optionally rinsing with water.
  • the examples and comparativ examples are made by mixing of the materials.
  • the compositions are shown in Tables 1 and 2 below.
  • the examples list the cationicnonionic surfactant ratio. Hie viscosity and the transparency after storage at 4.5°C are measured.
  • the combination of the PEG-120 methyl glucose dioleate and the cationicrnonionic surfactant ratio provides a composition that is clear after cold storage and has a desired viscosity over 4000 naPas.
  • PEG-120 methyl glucose dioleate is present in all compositions, a desired viscosity is obtained, bat when the cationicrnonionic surfactant ratio is less tha 0.9 in the comparative examples, the composition is hazy after cold storage.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • Oncology (AREA)
  • Communicable Diseases (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition aqueuse de nettoyage comprenant un tensioactif cationique, un tensioactif non ionique et un agent épaississant comprenant un éther de glucose de méthyle alcoxylé, un rapport pondéral tensioactif cationique sur tensioactif non ionique dépassant 0,9:1. L'association du rapport tensioactif cationique:tensioactif non ionique avec l'agent épaississant éther de glucose de méthyle alcoxylé donne une composition stable au froid. La stabilité au froid est observée quand la composition reste transparente après stockage au froid.
PCT/US2013/061801 2013-09-26 2013-09-26 Composition de nettoyage à tensioactif cationique et non ionique Ceased WO2015047260A1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
CA2922539A CA2922539C (fr) 2013-09-26 2013-09-26 Composition transparente de nettoyage comprenant un tensioactif cationique, un tensioactif non ionique et un agent epaississant comprenant un ether de glucose de methyle alcoxyle
PCT/US2013/061801 WO2015047260A1 (fr) 2013-09-26 2013-09-26 Composition de nettoyage à tensioactif cationique et non ionique
CA3080782A CA3080782A1 (fr) 2013-09-26 2013-09-26 Compositions transparentes de nettoyage comprenant un agent epaississantde dioleate de methylglucose peg-120, du chlorate de sodium, un agent desurface cationique et un agent de surface non ionique
US14/690,320 US9265714B2 (en) 2013-09-26 2015-04-17 Cleansing composition comprising a cationic and nonionic surfactant mixture
US15/049,089 US10179100B2 (en) 2013-09-26 2016-02-21 Transparent aqueous cleansing composition comprising a nonionic and cationic surfactant mixture
US16/032,503 US10383808B2 (en) 2013-09-26 2018-07-11 Thickened cationic and nonionic surfactant cleansing composition
US16/448,183 US10772817B2 (en) 2013-09-26 2019-06-21 Cleansing composition comprising a nonionic/cationic surfactant mixture
US16/993,330 US11052031B2 (en) 2013-09-26 2020-08-14 Cleansing composition comprising a nonionic / cationic surfactant mixture
US17/348,411 US12194128B2 (en) 2013-09-26 2021-06-15 Cleansing composition comprising a nonionic and cationic surfactant mixture and a cationic antibacterial agent
US19/009,576 US20250134793A1 (en) 2013-09-26 2025-01-03 Cleansing Composition Comprising a Nonionic and Cationic Surfactant Mixture And a Cationic Antibacterial Agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2013/061801 WO2015047260A1 (fr) 2013-09-26 2013-09-26 Composition de nettoyage à tensioactif cationique et non ionique

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/690,320 Continuation US9265714B2 (en) 2013-09-26 2015-04-17 Cleansing composition comprising a cationic and nonionic surfactant mixture

Publications (1)

Publication Number Publication Date
WO2015047260A1 true WO2015047260A1 (fr) 2015-04-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/061801 Ceased WO2015047260A1 (fr) 2013-09-26 2013-09-26 Composition de nettoyage à tensioactif cationique et non ionique

Country Status (2)

Country Link
CA (2) CA2922539C (fr)
WO (1) WO2015047260A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160115978A (ko) * 2014-02-04 2016-10-06 바스프 에스이 수성 계면활성제 조성물
WO2017116462A1 (fr) * 2015-12-31 2017-07-06 Colgate-Palmolive Company Compositions de soin personnel
EP3878920A4 (fr) * 2018-11-09 2022-07-27 Kao Corporation Modificateur de rhéologie

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5696069A (en) * 1995-11-21 1997-12-09 The Andrew Jergens Company Personal foaming cleansing composition
US6013683A (en) * 1998-12-17 2000-01-11 Dow Corning Corporation Single phase silicone and water compositions
US6306805B1 (en) * 2000-09-15 2001-10-23 Stepan Company Shampoo and body wash composition comprising ternary surfactant blends of cationic, anionic, and bridging surfactants and methods of preparing same
US20010036963A1 (en) * 1996-11-05 2001-11-01 Air Liquide Sante (International) Washing disinfectant for hygienic and surgical hand disinfection
US20030022941A1 (en) * 2001-03-27 2003-01-30 Taylor Timothy J. Antibacterial compositions
US20050153852A1 (en) * 2003-11-04 2005-07-14 Evans Erica L. Personal cleaning compositions
US20060130246A1 (en) * 2004-12-16 2006-06-22 Kpss-Kao Professional Salon Services Gmbh Cleansing composition

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5696069A (en) * 1995-11-21 1997-12-09 The Andrew Jergens Company Personal foaming cleansing composition
US20010036963A1 (en) * 1996-11-05 2001-11-01 Air Liquide Sante (International) Washing disinfectant for hygienic and surgical hand disinfection
US6013683A (en) * 1998-12-17 2000-01-11 Dow Corning Corporation Single phase silicone and water compositions
US6306805B1 (en) * 2000-09-15 2001-10-23 Stepan Company Shampoo and body wash composition comprising ternary surfactant blends of cationic, anionic, and bridging surfactants and methods of preparing same
US20030022941A1 (en) * 2001-03-27 2003-01-30 Taylor Timothy J. Antibacterial compositions
US20050153852A1 (en) * 2003-11-04 2005-07-14 Evans Erica L. Personal cleaning compositions
US20060130246A1 (en) * 2004-12-16 2006-06-22 Kpss-Kao Professional Salon Services Gmbh Cleansing composition

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160115978A (ko) * 2014-02-04 2016-10-06 바스프 에스이 수성 계면활성제 조성물
US10792237B2 (en) * 2014-02-04 2020-10-06 Basf Se Aqueous surfactant compositions
KR102348890B1 (ko) 2014-02-04 2022-01-07 바스프 에스이 수성 계면활성제 조성물
WO2017116462A1 (fr) * 2015-12-31 2017-07-06 Colgate-Palmolive Company Compositions de soin personnel
CN108430589A (zh) * 2015-12-31 2018-08-21 高露洁-棕榄公司 个人护理组合物
AU2015419256B2 (en) * 2015-12-31 2019-06-06 Colgate-Palmolive Company Personal care compositions
RU2697394C1 (ru) * 2015-12-31 2019-08-14 Колгейт-Палмолив Компани Композиции для личной гигиены
CN108430589B (zh) * 2015-12-31 2021-08-24 高露洁-棕榄公司 个人护理组合物
EP3878920A4 (fr) * 2018-11-09 2022-07-27 Kao Corporation Modificateur de rhéologie
US12415755B2 (en) 2018-11-09 2025-09-16 Kao Corporation Rheology modifying agent

Also Published As

Publication number Publication date
CA2922539A1 (fr) 2015-04-02
CA3080782A1 (fr) 2015-04-02
CA2922539C (fr) 2020-07-21

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