WO2015046091A1 - ステンレス鋼部材の接合方法およびステンレス鋼 - Google Patents
ステンレス鋼部材の接合方法およびステンレス鋼 Download PDFInfo
- Publication number
- WO2015046091A1 WO2015046091A1 PCT/JP2014/074972 JP2014074972W WO2015046091A1 WO 2015046091 A1 WO2015046091 A1 WO 2015046091A1 JP 2014074972 W JP2014074972 W JP 2014074972W WO 2015046091 A1 WO2015046091 A1 WO 2015046091A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stainless steel
- joining
- bonding
- steel member
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/22—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded
- B23K20/227—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating taking account of the properties of the materials to be welded with ferrous layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/02—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a press ; Diffusion bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/02—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a press ; Diffusion bonding
- B23K20/021—Isostatic pressure welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/02—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of a press ; Diffusion bonding
- B23K20/023—Thermo-compression bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/24—Preliminary treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/02—Iron or ferrous alloys
- B23K2103/04—Steel or steel alloys
- B23K2103/05—Stainless steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the present invention relates to a method for joining stainless steel members and stainless steel.
- Patent Document 1 discloses a technique for diffusion bonding at a low temperature so that crystal grains are not coarsened by activating the surface of a metal member by removing oxide on the bonding surface by chemical treatment. .
- This invention is made in view of the said subject, and aims at providing the joining method and stainless steel of the stainless steel member in which a high performance joining is obtained.
- the first stainless steel member and the second stainless steel member are brought into contact with the first stainless steel member and a second stainless steel member having a strain exceeding 50% reduction. Is heated above the recrystallization start temperature.
- the first stainless steel member may have a strain exceeding 50% reduction.
- the first stainless steel member and the second stainless steel member may be heated to a recrystallization start temperature or higher and a recrystallization start temperature + 100 ° C. or lower.
- the stainless steel according to the present invention is stainless steel obtained by joining the first stainless steel member and the second stainless steel member by the joining method of the stainless steel members.
- the austenitic first stainless steel member is brought into contact with an austenitic second stainless steel member containing 30% by volume or more of martensite, and the first stainless steel The member and the second stainless steel member are heated to the As point or higher.
- the first stainless steel member may contain 30% by volume or more of martensite.
- the first stainless steel member and the second stainless steel member may be heated to the As point or higher and the recrystallization start temperature + 100 ° C. or lower.
- Another stainless steel according to the present invention is stainless steel obtained by joining the first stainless steel member and the second stainless steel member by the joining method of the stainless steel members.
- Stainless steel is generally manufactured by smelting and refining, and then shipped after adjusting its microstructure to exhibit sufficient performance.
- various devices are manufactured by processing and assembling the stainless steel into parts.
- There are various bonding techniques for assembling stainless steel but as a bonding technique for stainless steel, which can be used at relatively high temperatures and is strong, a small stainless steel of several millimeters or less, the bonding surface is brought into close contact in a solid state. Therefore, it is necessary to use solid phase diffusion bonding that heats the substrate.
- FIG. 1 is a diagram showing a solid phase diffusion bonding method according to a comparative embodiment.
- the stainless steel member 10 and the stainless steel member 20 are pressed against each other by the pressurizing device 30 at a high temperature.
- the stainless steel 40 which is a joined product is obtained.
- the temperature In order to sufficiently activate the diffusion of the constituent atoms, the temperature must be about 1000 ° C. or higher.
- the high temperature treatment causes a problem that the crystal grains in the stainless steel 40 are coarsened and softened to lower the strength.
- Patent Document 1 described above can be cited.
- the activated surface is contaminated by oxygen as soon as it comes into contact with air, and may be inactivated. Therefore, there is a possibility that high-performance bonding cannot be obtained.
- a series of processes from surface treatment to bonding may be performed in a vacuum vessel, there is a problem of cost.
- the present inventors paid attention to the phenomenon of recrystallization occurring in the final heat treatment of the process for adjusting the structure of the stainless steel material.
- This phenomenon occurs, inside the material, newly generated crystal grains (recrystallized grains) grow while taking atoms from the surrounding material into the surface.
- This driving force is caused by a difference in internal energy between a stable recrystallized grain having a low internal energy in an equilibrium state and an unrecrystallized grain having a high internal energy and unstable due to distortion.
- the energy inside the member is made unstable by making it unstable, the atoms near the metal surface should reach the surface of the recrystallized grains appearing on the mating surface beyond the joint surface. Become stable. Moreover, if the surface disappears, the energy becomes lower and stable.
- FIG. 2 is a diagram illustrating a bonding method according to the first embodiment.
- FIG. 3 is a flow of the joining method.
- strain is accumulated inside by applying a reduction exceeding 50% to at least one of the stainless steel member 10 and the stainless steel member 20 (step S1).
- the joining surfaces of the stainless steel members 10 and 20 are smoothed (step S2).
- step S3 the joining surfaces of the stainless steel members 10 and 20 are brought into contact with each other and heated.
- the temperature in this case should just be more than the recrystallization start temperature of the stainless steel members 10 and 20.
- the temperature of the stainless steel members 10 and 20 is equal to or higher than the recrystallization start temperature, recrystallized grains are generated inside the stainless steel members 10 and 20, and the recrystallized grains grow beyond the joint surface on the joint surface, and are strong. Complete joining. Thereby, the stainless steel 40 is obtained.
- step S ⁇ b> 3 the stainless steel members 10, 20 are brought into close contact with each other by being pressurized by the pressurizing device 30, thereby completing stronger bonding.
- the stainless steel member 10 and the stainless steel member 20 by applying a reduction exceeding 50% to at least one of the stainless steel member 10 and the stainless steel member 20 to accumulate strain therein, a relatively higher temperature than the recrystallization start temperature is obtained.
- High-performance bonding can be realized at low temperatures. Since joining at low temperature is realizable, the crystal
- a necessary fine structure can be adjusted by a combination of strain imparting treatment for increasing internal energy added in advance, joining temperature, and time. Therefore, material production and parts assembly can be performed in a series of processes in parallel, and the heat treatment process for fine structure adjustment in material production can be omitted, thereby contributing to work efficiency and energy saving.
- high-performance bonding can be realized if the temperature is equal to or higher than the recrystallization start temperature. It is preferable to join at a temperature of 100 ° C. or lower. Moreover, it is preferable to apply a reduction exceeding 50% to both the stainless steel member 10 and the stainless steel member 20 to accumulate strain therein.
- FIG. 4 is a flow of the bonding method according to the second embodiment.
- metastable austenitic stainless steel is used as the stainless steel members 10 and 20.
- the same device as that in the first embodiment can be used.
- At least one of the stainless steel member 10 and the stainless steel member 20 is strained at a temperature equal to or lower than the Md point, so that the strained stainless steel member is 30% by volume.
- the above martensite is generated (step S11).
- the Md point is a temperature at which martensitic transformation is performed when processing is performed at or below that temperature.
- step S12 the joining surfaces of the stainless steel members 10 and 20 are smoothed.
- step S13 the joining surfaces of the stainless steel members 10 and 20 are brought into contact with each other and heated.
- the temperature in this case should just be more than the As point of the stainless steel members 10 and 20.
- the As point is a temperature at which martensite transforms to an austenite phase when heated to a temperature higher than that temperature.
- the temperature of the stainless steel members 10 and 20 is equal to or higher than the As point, recrystallized grains are generated inside the stainless steel members 10 and 20, and further, the recrystallized grains grow beyond the joint surface on the joint surface, and the strong joint Is completed. Thereby, the stainless steel 40 is obtained.
- step S13 the stainless steel members 10 and 20 are brought into close contact with each other by being pressurized by the pressurizing device 30, whereby a stronger bond is completed.
- high performance at a relatively low temperature above the As point is obtained by generating 30% by volume or more of martensite in at least one of the metastable austenitic stainless steel members 10 and 20. Bonding can be realized. Since joining at low temperature is realizable, the crystal
- the bonding method according to the present embodiment high-performance bonding can be realized if the temperature is equal to or higher than the As point.
- the As point is higher than the recrystallization start temperature + 100 ° C.
- it is preferable to join at a temperature of it is preferable that 50% by volume or more of martensite is generated in at least one of the stainless steel members 10 and 20, and 80% by volume or more of martensite is more preferably generated. 30% or more of martensite may be generated in both of the stainless steel members 10 and 20. In this case, it is preferable that 50% by volume or more of martensite is generated in both of the stainless steel members 10 and 20, and 80% by volume or more of martensite is more preferably generated.
- martensite is introduced by processing below the Md point.
- martensite may be introduced by rapidly cooling from the stable austenite state to the Ms point or less.
- the Ms point is a temperature at which martensite is generated when rapidly cooled below that temperature.
- Example 1 One side of each of the two small pieces obtained by cutting a 1 mm thick plate of austenitic stainless steel SUS316L (for Md point or higher) at 99 ° C. forging and rolling at room temperature into a 12 mm width ⁇ 20 mm length.
- the mirror surface was adjusted with emery paper and buffing. These mirror surfaces were faced to each other and arranged in a cross-shaped manner in a vacuum chamber, and 12 mm ⁇ 12 mm surfaces were brought into close contact with each other.
- the plate After evacuation, while applying a load of 1 kN so that the plates were brought into close contact with each other, the plate was heated to 730 ° C., which is higher than the recrystallization start temperature by high-frequency heating, unloaded after holding for 30 minutes, taken out after cooling, and firmly joined.
- 730 ° C. which is higher than the recrystallization start temperature by high-frequency heating
- unloaded after holding for 30 minutes taken out after cooling, and firmly joined.
- one of the members joined to the cross was fixed with a vise and the other was fixed with a hammer so that the other could be peeled off.
- Example 2 In Example 2, joining was performed under the same conditions as in Example 1 except that 80% rolling was added. Also in Example 2, strong bonding was realized.
- Comparative Example 1 In Comparative Example 1, bonding was performed under the same conditions as in Example 1 except that 50% rolling was added. The obtained joint was torn off by hitting it with a hammer.
- Comparative Example 2 In Comparative Example 2, bonding was performed under the same conditions as in Example 1 except that a SUS316L material that had been subjected to solution treatment by completely removing strain was used. The resulting bonded product was easily peeled off by hand.
- Example 3 In Example 3, the thickness of the metastable austenitic stainless steel SUS304 subjected to 90% equivalent multidirectional forging and rolling at 90 ° C. (above the Md point) and 90% rolling, and a total strain equivalent to 99%.
- One side of each of the two small pieces obtained by cutting a 1 mm thick plate into 12 mm width ⁇ 20 mm length was adjusted to a mirror surface by emery paper and buffing in the atmosphere. These mirror surfaces were faced to each other and arranged in a cross-shaped manner in a vacuum chamber, and 12 mm ⁇ 12 mm surfaces were brought into close contact with each other.
- FIG. 5 shows the observation results.
- the space between the left and right arrows is a joint. Although it was smooth before joining, it has been observed that it is uneven due to crystal grain growth from above and below.
- Example 4 In Example 4, two pieces of a 1 mm thick plate obtained by applying 99% equivalent reduction by forging and rolling at room temperature (above Md point) to austenitic stainless steel SUS316L, cut into 10 mm width ⁇ 50 mm length Each side was adjusted to a mirror surface by emery paper and buffing in the atmosphere. The mirror surfaces were faced to each other and placed in a cross shape in a vacuum chamber, and a 10 mm ⁇ 10 mm surface was brought into close contact therewith. After evacuation, while applying a load of 1 kN through a punch having a diameter of 5 mm so as to bring the plate into close contact, the plate was heated to various temperatures by high-frequency heating, unloaded after holding for 30 minutes, and taken out after cooling. For confirmation, cross tension was performed under the condition of 0.01 mm / s, and the bonding strength was evaluated.
- Comparative Example 3 bonding was performed under the same conditions as in Example 4 except that a SUS316L material that had been subjected to solution treatment by completely removing strain was used.
- FIG. 6 shows the relationship between the bonding temperature and the bonding temperature in Example 4 and Comparative Example 3.
- the horizontal axis represents the temperature during bonding
- the vertical axis represents the bonding strength.
- W99 represents the result of Example 4
- SOL / SOL represents the result of Comparative Example 3.
- the bonding strength tends to improve with the increase in temperature at the time of bonding, but the result of Example 4 shifts to the low temperature side as compared with Comparative Example 3. is doing. That is, in order to obtain the same joint strength, it was found that the temperature at the time of joining can be lowered in Example 4 as compared with Comparative Example 3.
- Example 5 the metastable austenitic stainless steel SUS304 was subjected to reduction corresponding to 90% by multidirectional forging and rolling at 300 ° C. (above the Md point), and further 90% rolled at room temperature (below the Md point).
- the surface of each of the two small pieces obtained by cutting a 1 mm-thick plate made of martensite almost entirely into 12 mm width ⁇ 20 mm length was adjusted to a mirror surface by emery paper and buffing in the atmosphere. These mirror surfaces were faced to each other and arranged in a cross-shaped manner in a vacuum chamber, and 12 mm ⁇ 12 mm surfaces were brought into close contact with each other.
- Comparative Example 4 In Comparative Example 4, a joining experiment was carried out under the same conditions as in Example 5 using a SUS304 sample in which multidirectional forging equivalent to 90% at 300 ° C. and rolling and 90% rolling were added and a strain equivalent to 99% in total was applied. . Since rolling is not performed below the Md point, martensite is not generated. When one of the members joined to the cross was fixed with a vise and the other side was peeled off with a hammer, it was peeled off.
- Comparative Example 5 Comparative Example 5
- SUS304 having the same size without strain after heat treatment for strain removal was used.
- the attached members could be easily removed by hand.
- Example 5 (Analysis 3) In Example 5, 30% by volume or more of martensite was generated, and bonding was performed at a temperature above the As point, so that the recrystallized grains grew beyond the bonding surface, and high-performance bonding was obtained. It is thought that. On the other hand, in Comparative Examples 4 and 5, since martensite was not generated, it is considered that strong bonding was not obtained. In Comparative Example 4, although strain was applied, the temperature was not raised above the recrystallization temperature, and it is considered that strong bonding was not obtained.
- Example 6 the metastable austenitic stainless steel SUS304 was subjected to reduction corresponding to 90% by multi-directional forging and rolling at 300 ° C. (above Md point), and further rolled at 90% at room temperature (below Md point).
- the mirror surfaces were faced to each other and placed in a cross shape in a vacuum chamber, and a 10 mm ⁇ 10 mm surface was brought into close contact therewith.
- Example 7 joining was performed under the same conditions as in Example 6 except that a SUS304 material that had been subjected to solution treatment by completely removing strain was used as one of the two small pieces.
- Comparative Example 6 In Comparative Example 6, bonding was performed under the same conditions as in Example 7 except that SUS304 material that had been subjected to solution treatment by completely removing strain was used as two pieces.
- FIG. 7 shows the relationship between the temperature at the time of bonding in Examples 6 and 7 and Comparative Example 6 and the bonding strength.
- the horizontal axis represents the temperature during bonding
- the vertical axis represents the bonding strength.
- WC / WC represents the result of Example 6
- WC / SOL represents the result of Example 7
- SOL / SOL represents the result of Comparative Example 6.
- the bonding strength tends to improve with the increase in temperature during bonding, but the results of Examples 6 and 7 are lower than those of Comparative Example 6. Has shifted to. That is, in order to obtain the same bonding strength, it was found that in Examples 6 and 7, the temperature at the time of bonding can be lowered as compared with Comparative Example 6.
- Example 8 In Example 8, a 1 mm thick plate obtained by applying 99% reduction by forging and rolling to austenitic stainless steel SUS304 (at Md point or higher) at 300 ° was cut into 10 mm width ⁇ 50 mm length. One side of each small piece was adjusted to a mirror surface by emery paper and buffing in the atmosphere. The mirror surfaces were faced to each other and placed in a cross shape in a vacuum chamber, and a 10 mm ⁇ 10 mm surface was brought into close contact therewith. After evacuation, while applying a load of 1 kN through a punch having a diameter of 5 mm so as to bring the plate into close contact, the plate was heated to various temperatures by high-frequency heating, unloaded after holding for 30 minutes, and taken out after cooling. For confirmation, cross tension was performed under the condition of 0.01 mm / s, and the bonding strength was evaluated.
- Example 9 In Example 9, joining was performed under the same conditions as in Example 8 except that 80% rolling was added.
- FIG. 8 shows the relationship between the bonding temperature and the bonding temperature in Examples 8, 9, and Comparative Example 6.
- the horizontal axis represents the temperature during bonding, and the vertical axis represents the bonding strength.
- W99 represents the result of Example 8
- W80 represents the result of Example 9
- SOL / SOL represents the result of Comparative Example 6.
- the bonding strength tends to improve as the temperature at the time of bonding increases, but the results of Example 8 and Example 9 are higher than those of Comparative Example 6. Shifted to the low temperature side. That is, in order to obtain the same bonding strength, it was found that the temperature at the time of bonding can be lowered in Example 8 and Example 9 as compared with Comparative Example 6.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Abstract
Description
図2は、第1実施形態に係る接合方法を表す図である。図3は、当該接合方法のフローである。まず、接合のための加熱に先立って、ステンレス鋼部材10およびステンレス鋼部材20の少なくともいずれか一方に、50%を上回る圧下を加えることによって、内部にひずみを蓄積させておく(ステップS1)。次に、ステンレス鋼部材10,20の接合表面を平滑化する(ステップS2)。
第2実施形態では、準安定オーステナイト系ステンレス鋼の相変態による効果を利用する。図4は、第2実施形態に係る接合方法のフローである。本実施形態においては、ステンレス鋼部材10,20として、準安定オーステナイト系ステンレス鋼を用いる。なお、本実施形態においても、第1実施形態と同様の装置を用いることができる。
オーステナイト系ステンレス鋼SUS316Lに(Md点以上である)常温で鍛造および圧延で99%相当の圧下を加えた厚さ1mmの板を12mm幅×20mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、12mm×12mmの面を密着させた。真空引き後、板を密着するように1kNの荷重を加えながら、高周波加熱で再結晶開始温度以上である730℃に加熱し、30分保持後に除荷し冷却後に取り出したところ強固に接合した。確認のために十文字に接合した部材の片方を万力で固定し、もう一方を引きはがす向きにハンマーでたたいたところ、はがれずに、万力で固定した方の部材が曲がった。
実施例2では、80%圧延を加えたこと以外は実施例1と同様の条件で接合を行った。実施例2でも、強固な接合が実現された。
比較例1では、50%圧延を加えたこと以外は実施例1と同様の条件で接合を行った。得られた接合品は、ハンマーでたたくことで引きはがされてしまった。
比較例2では、ひずみを完全に除去して溶体化処理されたSUS316L材を用いたこと以外は実施例1と同様の条件で接合を行った。得られた接合品は、手で容易に引きはがされた。
実施例1,2では、50%を上回る圧下を加えて内部にひずみを蓄積させたうえで再結晶開始温度以上の温度で接合を行ったことで、再結晶粒は接合面を超えて成長し、高性能な接合が得られたものと考えられる。一方、比較例2では、ひずみを完全に除去したため、強固な接合が得られなかったものと考えられる。比較例1では、内部にひずみを蓄積させたことから所定の接合強度が得られたが、ひずみの不足により十分な接合強度が得られなかったものと考えられる。
実施例3では、準安定オーステナイト系ステンレス鋼SUS304に(Md点以上である)300℃で90%相当の多方向鍛造および圧延と90%の圧延を加えて合計99%相当のひずみを加えた厚さ1mmの板を12mm幅×20mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、12mm×12mmの面を密着させた。真空引き後、板を密着するように1kNの荷重を加えながら、高周波加熱で再結晶開始温度以上である730℃に加熱し、30分保持後に除荷し冷却後に取り出したところ通常は1000℃程度でないと拡散接合されないSUS304が強固に接合した。
実施例4では、オーステナイト系ステンレス鋼SUS316Lに(Md点以上である)常温で鍛造および圧延で99%相当の圧下を加えた厚さ1mmの板を10mm幅×50mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、10mm×10mmの面を密着させた。真空引き後、板を密着するように直径5mmのパンチを介して1kNの荷重を加えながら、高周波加熱で種々の温度まで加熱し、30分保持後に除荷し冷却後に取り出した。確認のために十字引張を0.01mm/sの条件で行い、接合強度を評価した。
比較例3では、ひずみを完全に除去して溶体化処理されたSUS316L材を用いたこと以外は実施例4と同様の条件で接合を行った。
実施例4および比較例3の接合時の温度と接合強度との関係を図6に示す。図6において、横軸は接合時の温度を表し、縦軸は接合強度を表す。W99は実施例4の結果を表し、SOL/SOLは比較例3の結果を表す。図6に示すように、いずれの場合においても接合強度は接合時の温度の上昇とともに向上する傾向が得られているが、比較例3と比較して、実施例4の結果が低温側にシフトしている。すなわち、同じ接合強度を得るために、実施例4では、比較例3と比較して、接合時の温度を低くすることができることがわかった。
実施例5では、準安定オーステナイト系ステンレス鋼SUS304に(Md点以上である)300℃で多方向鍛造および圧延により90%相当の圧下を加え、さらに(Md点以下である)常温で90%圧延を加えることでほぼ全体をマルテンサイトとした厚さ1mmの板を12mm幅×20mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、12mm×12mmの面を密着させた。真空引き後、板を密着するように1kNの荷重を加えながら、高周波加熱でAs点以上である700℃に加熱し、30分保持後に除荷し冷却後に取り出したところ、通常は1000℃程度でないと拡散接合されないSUS304が強固に接合した。確認のために十文字に接合した部材の片方を万力で固定し、もう一方を引きはがす向きにハンマーでたたいたところ、はがれずに、万力で固定した方の部材が曲がった。
比較例4では、300℃で90%相当の多方向鍛造および圧延と90%の圧延を加えて合計99%相当のひずみを加えたSUS304試料で実施例5と同様の条件で接合実験を行った。Md点以下での圧延をしていないため、マルテンサイトは生成していない。十文字に接合した部材の片方を万力で固定し、もう一方を引きはがす向きにハンマーでたたいたところ、はがれてしまった。
比較例5では、ひずみ除去のための熱処理後にひずみを加えていない同寸法のSUS304を用いたほかは比較例4と同様の条件で実験を行った。付着した部材同士は手で簡単にはがすことができた。
実施例5では、30体積%以上のマルテンサイトを生成させたうえでAs点以上の温度で接合を行ったことで、再結晶粒は接合面を超えて成長し、高性能な接合が得られたものと考えられる。一方、比較例4,5では、マルテンサイトを生成していないため、強固な接合が得られなかったものと考えられる。なお、比較例4ではひずみを加えたものの、再結晶温度以上に温度を上昇させなかったため、強固な接合が得られなかったものと考えられる。
実施例6では、準安定オーステナイト系ステンレス鋼SUS304に(Md点以上である)300℃で多方向鍛造および圧延により90%相当の圧下を加え、さらに(Md点以下である)常温で90%圧延を加えることでほぼ全体をマルテンサイトとした厚さ1mmの板を10mm幅×50mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、10mm×10mmの面を密着させた。真空引き後、直径5mmのパンチを介して板を密着するように1kNの荷重を加えながら、高周波加熱で種々の温度まで加熱し、30分保持後に除荷し冷却後に取り出した。確認のために十字引張を0.01mm/sの条件で行い、接合強度を評価した。
実施例7では、2個の小片のうちの片方として、ひずみを完全に除去して溶体化処理されたSUS304材を用いたこと以外は実施例6と同様の条件で接合を行った。
比較例6では、2個の小片として、ひずみを完全に除去して溶体化処理されたSUS304材を用いたこと以外は実施例7と同様の条件で接合を行った。
実施例6,7および比較例6の接合時の温度と接合強度との関係を図7に示す。図7において、横軸は接合時の温度を表し、縦軸は接合強度を表す。WC/WCは実施例6の結果を表し、WC/SOLは実施例7の結果を表し、SOL/SOLは比較例6の結果を表す。図7に示すように、いずれの場合においても接合強度は接合時の温度の上昇とともに向上する傾向が得られているが、比較例6と比較して、実施例6,7の結果が低温側にシフトしている。すなわち、同じ接合強度を得るために、実施例6,7では、比較例6と比較して、接合時の温度を低くすることができることがわかった。
実施例8では、オーステナイト系ステンレス鋼SUS304に(Md点以上である)300°で鍛造および圧延で99%相当の圧下を加えた厚さ1mmの板を10mm幅×50mm長に切った2個の小片それぞれの片面を大気中でエメリー紙とバフ研磨で鏡面に調整した。この鏡面同士を向かい合わせて十文字状に真空チャンバ中に配置し、10mm×10mmの面を密着させた。真空引き後、板を密着するように直径5mmのパンチを介して1kNの荷重を加えながら、高周波加熱で種々の温度まで加熱し、30分保持後に除荷し冷却後に取り出した。確認のために十字引張を0.01mm/sの条件で行い、接合強度を評価した。
実施例9では、80%圧延を加えたこと以外は実施例8と同様の条件で接合を行った。
実施例8、実施例9および比較例6の接合時の温度と接合強度との関係を図8に示す。図8において、横軸は接合時の温度を表し、縦軸は接合強度を表す。W99は実施例8の結果を、W80は実施例9の結果を表し、SOL/SOLは比較例6の結果を表す。図6に示すように、いずれの場合においても接合強度は接合時の温度の上昇とともに向上する傾向が得られているが、比較例6と比較して、実施例8および実施例9の結果が低温側にシフトしている。すなわち、同じ接合強度を得るために、実施例8および実施例9では、比較例6と比較して、接合時の温度を低くすることができることがわかった。
30 加圧装置
40 ステンレス鋼
Claims (8)
- 第1ステンレス鋼部材と、50%圧下を超えるひずみを有する第2ステンレス鋼部材とを接触させ、前記第1ステンレス鋼部材および前記第2ステンレス鋼部材を再結晶開始温度以上に加熱することを特徴とするステンレス鋼部材の接合方法。
- 前記第1ステンレス鋼部材は、50%圧下を超えるひずみを有することを特徴とする請求項1記載のステンレス鋼部材の接合方法。
- 前記加熱の際に、前記第1ステンレス鋼部材および前記第2ステンレス鋼部材を、再結晶開始温度以上、再結晶開始温度+100℃以下に加熱することを特徴とする請求項1または2記載のステンレス鋼部材の接合方法。
- 請求項1~3のいずれかに記載のステンレス鋼部材の接合方法によって、前記第1ステンレス鋼部材と前記第2ステンレス鋼部材とを接合させることによって得られたステンレス鋼。
- オーステナイト系の第1ステンレス鋼部材と、マルテンサイトを30体積%以上含むオーステナイト系の第2ステンレス鋼部材とを接触させ、前記第1ステンレス鋼部材および前記第2ステンレス鋼部材をAs点以上に加熱することを特徴とするステンレス鋼部材の接合方法。
- 前記第1ステンレス鋼部材は、マルテンサイトを30体積%以上含むことを特徴とする請求項5記載のステンレス鋼部材の接合方法。
- 前記加熱の際に、前記第1ステンレス鋼部材および前記第2ステンレス鋼部材を、As点以上、再結晶開始温度+100℃以下に加熱することを特徴とする請求項5または6記載のステンレス鋼部材の接合方法。
- 請求項5~7のいずれかに記載のステンレス鋼の接合方法によって、前記第1ステンレス鋼部材と前記第2ステンレス鋼部材とを接合させることによって得られたステンレス鋼。
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020157030591A KR20150135452A (ko) | 2013-09-27 | 2014-09-19 | 스테인리스강 부재의 접합 방법 및 스테인리스강 |
| JP2015539177A JP6082866B2 (ja) | 2013-09-27 | 2014-09-19 | ステンレス鋼部材の接合方法およびステンレス鋼 |
| KR1020177037014A KR101923340B1 (ko) | 2013-09-27 | 2014-09-19 | 스테인리스강 부재의 접합 방법 및 스테인리스강 |
| DE112014001895.3T DE112014001895T5 (de) | 2013-09-27 | 2014-09-19 | Verfahren zum Verbinden von Edelstahlelementen und Edelstähle |
| US14/881,971 US20160031035A1 (en) | 2013-09-27 | 2015-10-13 | Method for bonding stainless steel members and stainless steel |
| US15/359,216 US10449629B2 (en) | 2013-09-27 | 2016-11-22 | Method for bonding stainless steel members and stainless steel |
| US15/471,712 US20170197276A1 (en) | 2013-09-27 | 2017-03-28 | Method for bonding stainless steel members and stainless steel |
| US15/471,635 US10549380B2 (en) | 2013-09-27 | 2017-03-28 | Method for bonding stainless steel members and stainless steel |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-201834 | 2013-09-27 | ||
| JP2013201834 | 2013-09-27 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US14/881,971 Continuation US20160031035A1 (en) | 2013-09-27 | 2015-10-13 | Method for bonding stainless steel members and stainless steel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015046091A1 true WO2015046091A1 (ja) | 2015-04-02 |
Family
ID=52743228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2014/074972 Ceased WO2015046091A1 (ja) | 2013-09-27 | 2014-09-19 | ステンレス鋼部材の接合方法およびステンレス鋼 |
Country Status (5)
| Country | Link |
|---|---|
| US (4) | US20160031035A1 (ja) |
| JP (1) | JP6082866B2 (ja) |
| KR (2) | KR20150135452A (ja) |
| DE (1) | DE112014001895T5 (ja) |
| WO (1) | WO2015046091A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015066558A (ja) * | 2013-09-27 | 2015-04-13 | 独立行政法人産業技術総合研究所 | 金属部材の接合方法及び接合金属製品 |
| JP2017104877A (ja) * | 2015-12-08 | 2017-06-15 | 株式会社スギノマシン | レーザを用いた接合方法 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6165127B2 (ja) * | 2014-12-22 | 2017-07-19 | 三菱重工工作機械株式会社 | 半導体装置及び半導体装置の製造方法 |
| US10485728B2 (en) * | 2016-07-22 | 2019-11-26 | PTStudio Oy | Fitness and massage roller |
| CN106493466A (zh) * | 2016-10-14 | 2017-03-15 | 贝原合金(苏州)有限公司 | 耐高压双金属复合材料及其加工设备、加工方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0364233B2 (ja) * | 1984-04-13 | 1991-10-04 | Nippon Kokan Kk | |
| JPH05245658A (ja) * | 1992-03-06 | 1993-09-24 | Nkk Corp | 母材の脆性破壊伝播停止特性に優れたオーステナイト系ステンレスクラッド鋼板の製造方法 |
| JPH06269959A (ja) * | 1993-03-22 | 1994-09-27 | Nkk Corp | 高純度フェライト系ステンレスクラッド鋼板の製造方法 |
| JPH0716792B2 (ja) * | 1990-03-30 | 1995-03-01 | 新日本製鐵株式会社 | クラッド鋼板の製造方法 |
| JP2510783B2 (ja) * | 1990-11-28 | 1996-06-26 | 新日本製鐵株式会社 | 低温靭性の優れたクラッド鋼板の製造方法 |
| JP2568313B2 (ja) * | 1990-11-30 | 1997-01-08 | 川崎製鉄 株式会社 | プロセスラインにおけるステンレス鋼帯のシ−ム溶接方法 |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3019513A (en) * | 1958-05-22 | 1962-02-06 | Gen Motors Corp | Method of manufacture |
| SE300117B (ja) * | 1963-01-05 | 1968-04-08 | Bofors Ab | |
| DE1667168A1 (de) * | 1967-02-25 | 1972-04-20 | Mitsubishi Heavy Ind Ltd | Mehrlagen-Druckbehaelter |
| US3879838A (en) * | 1967-03-30 | 1975-04-29 | Rockwell International Corp | Method of manufacturing a bonded electrical contact for thermoelectric semiconductor element |
| US3650844A (en) * | 1968-09-19 | 1972-03-21 | Gen Electric | Diffusion barriers for semiconductive thermoelectric generator elements |
| FR2148888A5 (ja) * | 1971-08-09 | 1973-03-23 | Pequignot Michel | |
| JPS6024750B2 (ja) * | 1977-09-05 | 1985-06-14 | 三菱重工業株式会社 | 銅とステンレス鋼の拡散溶接法 |
| JPS55117562A (en) | 1979-02-09 | 1980-09-09 | Japan Steel Works Ltd:The | Build-up welding method of stainless steel |
| JPS594971A (ja) * | 1982-06-29 | 1984-01-11 | Kawasaki Steel Corp | 肉盛り溶接方法 |
| US4455352A (en) * | 1982-11-08 | 1984-06-19 | The Babcock & Wilcox Company | Materials system for high strength corrosion resistant bimetallic products |
| JPS5987988A (ja) * | 1982-11-13 | 1984-05-21 | Daihou Giken Kk | 刃物用複合ステンレス鋼 |
| JPS6046326A (ja) * | 1983-08-25 | 1985-03-13 | Ishikawajima Harima Heavy Ind Co Ltd | 肉盛溶接金属の剥離割れ防止方法 |
| JPS60131875A (ja) * | 1983-12-20 | 1985-07-13 | 三菱重工業株式会社 | セラミツクと金属の接合法 |
| JPS62199277A (ja) * | 1986-02-26 | 1987-09-02 | Sumitomo Metal Ind Ltd | ステンレス鋼の拡散接合方法 |
| JPS63293143A (ja) | 1987-05-25 | 1988-11-30 | Nippon Kinzoku Kogyo Kk | 深冷処理硬化型マルテンサイト系ステンレス鋼 |
| AT395122B (de) * | 1990-07-20 | 1992-09-25 | Voest Alpine Eisenbahnsysteme | Verfahren zur verbindung von aus manganhartstahlguss bestehenden weichenteilen bzw. manganstahlschienen mit einer schiene aus kohlenstoffstahl |
| GB2250941B (en) * | 1990-12-20 | 1994-02-02 | Rolls Royce Plc | Improvements in or relating to diffusion bonding |
| JPH11129078A (ja) * | 1997-08-29 | 1999-05-18 | Daido Steel Co Ltd | 二相ステンレス鋼の接合方法 |
| JP2916619B1 (ja) | 1998-01-14 | 1999-07-05 | 工業技術院長 | ステンレス鋼の超塑性加工法及び超塑性加工用ステンレス鋼材の製造法 |
| JP3720973B2 (ja) * | 1998-03-16 | 2005-11-30 | 新日本製鐵株式会社 | 拡散接合メタル担体とその製造方法 |
| FR2779983B1 (fr) * | 1998-06-23 | 2000-07-13 | Commissariat Energie Atomique | Procede d'assemblage par soudage diffusion d'un acier inoxydable martensitique et d'un alliage de cuivre, et element bimetallique obtenu |
| JP3793667B2 (ja) | 1999-07-09 | 2006-07-05 | 株式会社日立製作所 | 低圧蒸気タービン最終段動翼の製造方法 |
| DE60043151D1 (de) * | 1999-08-06 | 2009-11-26 | Sumitomo Metal Ind | Geschweisstes rohr aus martensitischen rostfreien stahl |
| JP2002273579A (ja) | 2001-03-15 | 2002-09-25 | Hitachi Ltd | 鉄基材料の接合方法およびその構造物 |
| JP3905739B2 (ja) * | 2001-10-25 | 2007-04-18 | 三菱重工業株式会社 | タービンロータ用12Cr合金鋼、その製造方法及びタービンロータ |
| DE10208216C1 (de) * | 2002-02-26 | 2003-03-27 | Benteler Automobiltechnik Gmbh | Verfahren zur Herstellung eines metallischen Bauteils |
| JP3968011B2 (ja) * | 2002-05-27 | 2007-08-29 | 新日本製鐵株式会社 | 低温靱性および溶接熱影響部靱性に優れた高強度鋼とその製造方法および高強度鋼管の製造方法 |
| US7294212B2 (en) * | 2003-05-14 | 2007-11-13 | Jfe Steel Corporation | High-strength stainless steel material in the form of a wheel rim and method for manufacturing the same |
| JP4235030B2 (ja) * | 2003-05-21 | 2009-03-04 | 新日本製鐵株式会社 | 局部成形性に優れ溶接部の硬さ上昇を抑制した引張強さが780MPa以上の高強度冷延鋼板および高強度表面処理鋼板 |
| US8387228B2 (en) * | 2004-06-10 | 2013-03-05 | Ati Properties, Inc. | Clad alloy substrates and method for making same |
| JP4288364B2 (ja) * | 2004-12-21 | 2009-07-01 | 株式会社神戸製鋼所 | 伸びおよび伸びフランジ性に優れる複合組織冷延鋼板 |
| JP5208354B2 (ja) * | 2005-04-11 | 2013-06-12 | 新日鐵住金株式会社 | オーステナイト系ステンレス鋼 |
| JP5087894B2 (ja) * | 2005-10-28 | 2012-12-05 | 日産自動車株式会社 | 燃料電池スタック構造体 |
| JP4907151B2 (ja) * | 2005-11-01 | 2012-03-28 | 新日鐵住金ステンレス株式会社 | 高圧水素ガス用オ−ステナイト系高Mnステンレス鋼 |
| JP5098235B2 (ja) * | 2006-07-04 | 2012-12-12 | 新日鐵住金株式会社 | 低温靱性に優れたラインパイプ用高強度鋼管及びラインパイプ用高強度鋼板並びにそれらの製造方法 |
| US20080296354A1 (en) * | 2007-05-31 | 2008-12-04 | Mark Crockett | Stainless steel or stainless steel alloy for diffusion bonding |
| DE102007054071B4 (de) * | 2007-11-13 | 2010-06-10 | Eisfink Max Maier Gmbh & Co. Kg | Verbundmetallgegenstand und Verfahren zur Herstellung eines Verbundmetallgegenstands |
| US20090166259A1 (en) * | 2007-12-28 | 2009-07-02 | Steven Bradley | Metal-based coatings for inhibiting metal catalyzed coke formation in hydrocarbon conversion processes |
| US20100136369A1 (en) * | 2008-11-18 | 2010-06-03 | Raghavan Ayer | High strength and toughness steel structures by friction stir welding |
| KR101061941B1 (ko) | 2008-12-11 | 2011-09-05 | 웰텍코리아 (주) | 입방정 질화 붕소(씨비엔)를 접합한 공구의 제조방법 및 그를 이용한 입방정 질화 붕소(씨비엔) 공구 |
| US7874471B2 (en) | 2008-12-23 | 2011-01-25 | Exxonmobil Research And Engineering Company | Butt weld and method of making using fusion and friction stir welding |
| JP4853575B2 (ja) * | 2009-02-06 | 2012-01-11 | Jfeスチール株式会社 | 耐座屈性能及び溶接熱影響部靭性に優れた低温用高強度鋼管およびその製造方法 |
| JP5926723B2 (ja) * | 2010-03-26 | 2016-05-25 | ウオーターズ・テクノロジーズ・コーポレイシヨン | 拡散結合され表面改質された構成要素を有するクロマトグラフィ装置 |
| JP5656144B2 (ja) | 2010-03-26 | 2015-01-21 | 国立大学法人群馬大学 | 金属部材の接合方法 |
| JP5048167B2 (ja) * | 2010-09-14 | 2012-10-17 | 新日本製鐵株式会社 | 低温靭性に優れた厚肉溶接鋼管および低温靭性に優れた厚肉溶接鋼管の製造方法、厚肉溶接鋼管製造用鋼板 |
| JP5709881B2 (ja) * | 2010-09-29 | 2015-04-30 | 新日鐵住金ステンレス株式会社 | オーステナイト系高Mnステンレス鋼およびその製造方法と、その鋼を用いた部材 |
| WO2012102794A1 (en) | 2011-01-28 | 2012-08-02 | Exxonmobil Upstream Research Company | High toughness weld metals with superior ductile tearing resistance |
| US20120214017A1 (en) * | 2011-02-22 | 2012-08-23 | Pourin Welding Engineering Co., Ltd. | Weld Overlay Structure and a Method of Providing a Weld Overlay Structure |
| JP5668592B2 (ja) * | 2011-04-22 | 2015-02-12 | アイシン・エィ・ダブリュ株式会社 | 複合鋼部品の製造方法 |
| JP5776472B2 (ja) | 2011-09-28 | 2015-09-09 | Jfeスチール株式会社 | 車両補強用中空部材 |
| JP5846868B2 (ja) * | 2011-11-16 | 2016-01-20 | 日新製鋼株式会社 | ステンレス鋼拡散接合製品の製造方法 |
| FR2984782B1 (fr) * | 2011-12-23 | 2014-09-26 | Commissariat Energie Atomique | Procede d'assemblage par soudage diffusion d'une piece en acier a forte teneur en carbone avec une piece en acier ou en alliage de nickel a faible teneur en carbone, et assemblage ainsi obtenu. |
| CN103764388B (zh) * | 2011-12-29 | 2016-08-17 | 奥秘合金设计有限公司 | 冶金结合的不锈钢 |
| FR2991213B1 (fr) * | 2012-06-05 | 2015-07-03 | Alstom Hydro France | Procede de soudage de deux bords d'une ou plusieurs pieces en acier l'un a l'autre et conduite forcee obtenue par un tel procede. |
| US20150129559A1 (en) | 2012-07-27 | 2015-05-14 | Douglas P. Fairchild | High Strength Weld Metal for Demanding Structural Applications |
| WO2014051119A1 (ja) * | 2012-09-27 | 2014-04-03 | 新日鐵住金株式会社 | 電縫溶接鋼管 |
| KR101699646B1 (ko) * | 2012-12-17 | 2017-01-24 | 제이에프이 스틸 가부시키가이샤 | 스테인리스 강판 및 스테인리스박 |
| CN105209209A (zh) * | 2013-01-22 | 2015-12-30 | 犹他大学研究基金会 | 摩擦点焊和摩擦缝焊 |
| US20150361664A1 (en) * | 2013-04-26 | 2015-12-17 | Nippon Steel & Sumitomo Metal Corporation | H-section steel and method of producing the same |
| WO2014184890A1 (ja) * | 2013-05-15 | 2014-11-20 | 日新製鋼株式会社 | ステンレス鋼拡散接合製品の製造方法 |
-
2014
- 2014-09-19 JP JP2015539177A patent/JP6082866B2/ja active Active
- 2014-09-19 DE DE112014001895.3T patent/DE112014001895T5/de not_active Ceased
- 2014-09-19 KR KR1020157030591A patent/KR20150135452A/ko not_active Ceased
- 2014-09-19 WO PCT/JP2014/074972 patent/WO2015046091A1/ja not_active Ceased
- 2014-09-19 KR KR1020177037014A patent/KR101923340B1/ko active Active
-
2015
- 2015-10-13 US US14/881,971 patent/US20160031035A1/en not_active Abandoned
-
2016
- 2016-11-22 US US15/359,216 patent/US10449629B2/en active Active
-
2017
- 2017-03-28 US US15/471,712 patent/US20170197276A1/en not_active Abandoned
- 2017-03-28 US US15/471,635 patent/US10549380B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0364233B2 (ja) * | 1984-04-13 | 1991-10-04 | Nippon Kokan Kk | |
| JPH0716792B2 (ja) * | 1990-03-30 | 1995-03-01 | 新日本製鐵株式会社 | クラッド鋼板の製造方法 |
| JP2510783B2 (ja) * | 1990-11-28 | 1996-06-26 | 新日本製鐵株式会社 | 低温靭性の優れたクラッド鋼板の製造方法 |
| JP2568313B2 (ja) * | 1990-11-30 | 1997-01-08 | 川崎製鉄 株式会社 | プロセスラインにおけるステンレス鋼帯のシ−ム溶接方法 |
| JPH05245658A (ja) * | 1992-03-06 | 1993-09-24 | Nkk Corp | 母材の脆性破壊伝播停止特性に優れたオーステナイト系ステンレスクラッド鋼板の製造方法 |
| JPH06269959A (ja) * | 1993-03-22 | 1994-09-27 | Nkk Corp | 高純度フェライト系ステンレスクラッド鋼板の製造方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015066558A (ja) * | 2013-09-27 | 2015-04-13 | 独立行政法人産業技術総合研究所 | 金属部材の接合方法及び接合金属製品 |
| JP2017104877A (ja) * | 2015-12-08 | 2017-06-15 | 株式会社スギノマシン | レーザを用いた接合方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20170072503A1 (en) | 2017-03-16 |
| JPWO2015046091A1 (ja) | 2017-03-09 |
| JP6082866B2 (ja) | 2017-02-22 |
| KR101923340B1 (ko) | 2018-11-28 |
| US10449629B2 (en) | 2019-10-22 |
| KR20150135452A (ko) | 2015-12-02 |
| US20170197276A1 (en) | 2017-07-13 |
| US20170197275A1 (en) | 2017-07-13 |
| US20160031035A1 (en) | 2016-02-04 |
| DE112014001895T5 (de) | 2016-01-07 |
| KR20180000747A (ko) | 2018-01-03 |
| US10549380B2 (en) | 2020-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6082866B2 (ja) | ステンレス鋼部材の接合方法およびステンレス鋼 | |
| JP6381944B2 (ja) | 金属積層材の製造方法 | |
| JP6454606B2 (ja) | 酸化物単結晶薄膜を備えた複合ウェーハの製造方法 | |
| JP6396854B2 (ja) | 酸化物単結晶薄膜を備えた複合ウェーハの製造方法 | |
| CN103895313B (zh) | 一种铁基非晶合金-铜多层复合板材的制备方法 | |
| JPH10158829A (ja) | スパッタリングターゲット組立体の製造方法 | |
| CN104372277A (zh) | 一种颗粒状δ相均匀分布的GH4169合金制备方法 | |
| JP2010094683A (ja) | アルミニウム合金の拡散接合法 | |
| CN105624622B (zh) | 靶材组件的制造方法 | |
| CN105080998B (zh) | 制备无中间层钛钢复合板的方法 | |
| JP3845722B2 (ja) | 超塑性ステンレス鋼材の製造方法及びステンレス鋼材の超塑性加工方法 | |
| JP7178020B2 (ja) | 金属薄板の表面清浄化方法及び接合方法 | |
| RU2415738C1 (ru) | Способ сварки давлением заготовок из титанового сплава | |
| CN102753722B (zh) | 溅射靶材的制造方法及溅射靶材 | |
| JP2018096666A (ja) | 熱交換器の製造方法 | |
| JP2823411B2 (ja) | 拡散接合部材の製造方法 | |
| JPH02200757A (ja) | チタン合金薄板の焼鈍法 | |
| JP6670441B2 (ja) | 金属ベルト用鋼帯の製造方法 | |
| JP2015066558A (ja) | 金属部材の接合方法及び接合金属製品 | |
| JP2011214065A (ja) | 珪素鋼板の製造方法 | |
| CN110494250A (zh) | 热交换器的制造方法 | |
| RU2537407C2 (ru) | Способ изготовления диффузионной сваркой стоистой тонкостенной конструкции из титановых листовых материалов | |
| KR100916122B1 (ko) | 연속소둔로내의 미소 덴트 발생 방지방법 | |
| JP2001262330A (ja) | 拡散接合スパッタリングターゲット組立て体及びその製造方法 | |
| JP2020022992A (ja) | 圧延接合体及びその製造方法、並びに電子機器用の放熱補強部材 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 14849330 Country of ref document: EP Kind code of ref document: A1 |
|
| ENP | Entry into the national phase |
Ref document number: 20157030591 Country of ref document: KR Kind code of ref document: A |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 112014001895 Country of ref document: DE Ref document number: 1120140018953 Country of ref document: DE |
|
| ENP | Entry into the national phase |
Ref document number: 2015539177 Country of ref document: JP Kind code of ref document: A |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 14849330 Country of ref document: EP Kind code of ref document: A1 |