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WO2014114291A3 - Device and method for producing a sodium hypochlorite solution having a redox value of more than 800 mv - Google Patents

Device and method for producing a sodium hypochlorite solution having a redox value of more than 800 mv Download PDF

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Publication number
WO2014114291A3
WO2014114291A3 PCT/DE2014/100022 DE2014100022W WO2014114291A3 WO 2014114291 A3 WO2014114291 A3 WO 2014114291A3 DE 2014100022 W DE2014100022 W DE 2014100022W WO 2014114291 A3 WO2014114291 A3 WO 2014114291A3
Authority
WO
WIPO (PCT)
Prior art keywords
chamber
solution
anode
cathode
anode chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE2014/100022
Other languages
German (de)
French (fr)
Other versions
WO2014114291A2 (en
Inventor
Jörg HEIL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WATERCLEAN GmbH
Original Assignee
WATERCLEAN GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WATERCLEAN GmbH filed Critical WATERCLEAN GmbH
Publication of WO2014114291A2 publication Critical patent/WO2014114291A2/en
Publication of WO2014114291A3 publication Critical patent/WO2014114291A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/02Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/08Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46115Electrolytic cell with membranes or diaphragms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/04Oxidation reduction potential [ORP]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to a device (1) for producing a sodium hypochlorite solution having a redox value of more than 800 mV and in particular a pH value greater than 8, comprising a compartmented electrolysis cell (10) having a separating chamber (2), which is divided by a flat membrane (3) into a cathode chamber (4) and an anode chamber (5), wherein the separating chamber (2) is permeated on both sides of the membrane (3) along the same, wherein a cathode (45) is provided in the cathode chamber (4) and is arranged at a preselected distance from the membrane (3), wherein the cathode chamber (4) has a cathode chamber solution inlet (41) for a cathode chamber solution (43) and a cathode chamber solution outlet (42) for a catholyte (44), and wherein an anode (55) is provided in the anode chamber (5) and is arranged at a preselected distance from the membrane (3), wherein the anode chamber (5) has an anode chamber solution inlet (51) for an anode chamber solution (53) and an anode chamber solution outlet (52) for anolyte (54), wherein a sodium chlorite-water solution (common salt solution) (6) can be fed to the anode chamber solution inlet (51) and can flow through the anode chamber (5) and can be removed from the anode chamber (5) as anolyte (54) at the anode chamber solution outlet (52), and in that an anolyte pipe (56) is provided, via which the anolyte (54) can be fed from the anode chamber solution outlet (52) to the cathode chamber (4) at the cathode chamber solution inlet (41) and is able to flow through the cathode chamber parallel to the anode chamber (5), and in that the sodium hypochlorite solution can be removed as catholyte (44) at the cathode chamber solution outlet (42).
PCT/DE2014/100022 2013-01-28 2014-01-28 Device and method for producing a sodium hypochlorite solution having a redox value of more than 800 mv and in particular a ph value greater than 8 Ceased WO2014114291A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013100834.8 2013-01-28
DE102013100834.8A DE102013100834A1 (en) 2013-01-28 2013-01-28 Apparatus and process for the preparation of a sodium hypochlorite solution having a redox value of more than 800 mV and in particular a pH of greater than 8

Publications (2)

Publication Number Publication Date
WO2014114291A2 WO2014114291A2 (en) 2014-07-31
WO2014114291A3 true WO2014114291A3 (en) 2014-09-18

Family

ID=50272239

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2014/100022 Ceased WO2014114291A2 (en) 2013-01-28 2014-01-28 Device and method for producing a sodium hypochlorite solution having a redox value of more than 800 mv and in particular a ph value greater than 8

Country Status (2)

Country Link
DE (1) DE102013100834A1 (en)
WO (1) WO2014114291A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6139589B2 (en) * 2015-03-18 2017-05-31 株式会社東芝 Electrolyzer
CN113201756A (en) * 2021-05-08 2021-08-03 潍坊思源环保设备有限公司 Household slightly acidic sterilizer and use method thereof
AT525630B1 (en) * 2022-03-08 2023-06-15 Luna Ip Gmbh SHELF-STABLE SOLUTION COMPRISING HYPOCHLOROIC ACID OR HYPOCHLORITE
AT525645B1 (en) * 2022-02-09 2023-06-15 Luna Ip Gmbh SHELF-STABLE SOLUTION COMPRISING HYPOCHLOROUS ACID OR HYPOCHLORITE
DE102024201152A1 (en) * 2024-02-08 2025-08-14 BSH Hausgeräte GmbH Providing cleaning supplies on site

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020008069A1 (en) * 1999-12-22 2002-01-24 Kinya Kato Method and apparatus for purifying polluted soil, and apparatus for emitting chlorine-containing gas and apparatus for decomposing polluted gas using the same
GB2409684A (en) * 2003-12-04 2005-07-06 Medipure Ltd Method of production of a biocidal liquid medium
WO2005093129A1 (en) * 2004-02-27 2005-10-06 Barbin-Harper Llc Production of electrolytic water
DE102006058454A1 (en) * 2006-12-12 2008-06-19 Sautter, Joachim Production of sodium hypochlorite solution comprises feeding water and saturated brine to cathode chamber of electrolysis cell and passing mixture of aqueous sodium hydroxide and hydrogen gas produced into anode chamber

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1157720A (en) * 1996-11-07 1999-03-02 Honda Motor Co Ltd Electrolytic functional water, its production method and production apparatus
US20050194261A1 (en) * 2004-03-02 2005-09-08 Hadia Ali A. Electrochemically activated solutions and a new economical way of producing these solutions
DE102007022994A1 (en) * 2007-05-15 2008-11-20 Actides Gmbh Disinfectants based on electrochemically activated water / electrolyte solutions, process for their preparation and use thereof
DE102009024488B4 (en) * 2009-06-10 2013-04-25 Pauly Gmbh Hydraulic module for the production of a disinfectant based on diaphragm analysis and process for the production of a disinfectant

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020008069A1 (en) * 1999-12-22 2002-01-24 Kinya Kato Method and apparatus for purifying polluted soil, and apparatus for emitting chlorine-containing gas and apparatus for decomposing polluted gas using the same
GB2409684A (en) * 2003-12-04 2005-07-06 Medipure Ltd Method of production of a biocidal liquid medium
WO2005093129A1 (en) * 2004-02-27 2005-10-06 Barbin-Harper Llc Production of electrolytic water
DE102006058454A1 (en) * 2006-12-12 2008-06-19 Sautter, Joachim Production of sodium hypochlorite solution comprises feeding water and saturated brine to cathode chamber of electrolysis cell and passing mixture of aqueous sodium hydroxide and hydrogen gas produced into anode chamber

Also Published As

Publication number Publication date
DE102013100834A1 (en) 2014-08-14
WO2014114291A2 (en) 2014-07-31

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