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WO2014198366A1 - Gant a effet rafraichissant - Google Patents

Gant a effet rafraichissant Download PDF

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Publication number
WO2014198366A1
WO2014198366A1 PCT/EP2014/001239 EP2014001239W WO2014198366A1 WO 2014198366 A1 WO2014198366 A1 WO 2014198366A1 EP 2014001239 W EP2014001239 W EP 2014001239W WO 2014198366 A1 WO2014198366 A1 WO 2014198366A1
Authority
WO
WIPO (PCT)
Prior art keywords
glove
carboxamide
active ingredient
menthane
isopropyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2014/001239
Other languages
German (de)
English (en)
Inventor
Karl-Ludwig Gibis
Julia VON GROTE-PASTRÉ
Norbert Weis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carl Freudenberg KG
Original Assignee
Carl Freudenberg KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Freudenberg KG filed Critical Carl Freudenberg KG
Publication of WO2014198366A1 publication Critical patent/WO2014198366A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/015Protective gloves
    • A41D19/01529Protective gloves with thermal or fire protection
    • A41D19/01541Cooled gloves
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B42/00Surgical gloves; Finger-stalls specially adapted for surgery; Devices for handling or treatment thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61MDEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
    • A61M35/00Devices for applying media, e.g. remedies, on the human body
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/14Dipping a core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0064Producing wearing apparel
    • B29D99/0067Gloves
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/185Magnoliopsida (dicotyledons)
    • A61K36/28Asteraceae or Compositae (Aster or Sunflower family), e.g. chamomile, feverfew, yarrow or echinacea
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K36/00Medicinal preparations of undetermined constitution containing material from algae, lichens, fungi or plants, or derivatives thereof, e.g. traditional herbal medicines
    • A61K36/18Magnoliophyta (angiosperms)
    • A61K36/88Liliopsida (monocotyledons)
    • A61K36/886Aloeaceae (Aloe family), e.g. aloe vera
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2300/00Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
    • A61L2300/40Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action

Definitions

  • the invention relates to a glove with cooling effect and a method for its preparation.
  • Gloves made of flexible materials are used for a variety of purposes, for example in the household, in industry or in the medical field for protection against chemicals,
  • so-called glove former prepared in various dipping baths containing, for example, elastomeric materials or precursors thereof.
  • the glove former can be slipped over in advance a textile glove. This can then be completely or partially in the different
  • Dipping baths are immersed.
  • the elastomeric material can then be
  • CONFIRMATION COPY cured, for example, vulcanized and then stripped or detached from the glove former.
  • the gloves have to meet a wide variety of requirements. First, they must have a high density to a high
  • the invention has for its object to overcome the disadvantages mentioned above and in particular to provide a glove, the
  • a glove comprising at least one layer of flexible material which forms a cavity to receive a hand and a proportion of at least one active substance which is able to stimulate cold receptors on and / or in the human skin.
  • the glove according to the invention has a cold receptor stimulating agent.
  • the cold receptors on and / or in the human skin are stimulated, whereby a cooling effect is achieved.
  • This cooling effect signals to the body that the glove is at a lower temperature than the actual temperature Case is.
  • the sweat production can be reduced and the wearing comfort of the glove can be significantly improved.
  • a stimulation of the cold receptors TRPM8 (CMR1) and / or TRPA1 in the skin by suitable active ingredients is suitable for the perception of a cooling effect.
  • the glove of the invention can be made of a variety of materials, provided that it has at least one layer of a flexible material.
  • flexible materials for example, natural polymers, in particular natural rubber, synthetic polymers, in particular synthetic rubber and / or mixtures thereof can be used.
  • the synthetic polymer may be selected from the group consisting of polychloroprene, carboxylated acrylonitrile, butadiene, polyisoprene,
  • Polyurethane Polyurethane, styrene-butadiene, polyvinyl chloride, polyacrylate and / or mixtures thereof.
  • a natural polymer in particular rubber has proven to be particularly suitable.
  • a synthetic polymer in particular acrylonitrile is mentioned.
  • the active ingredient a variety of chemical substances can be used, which are capable of cold receptors, in particular the
  • the active ingredient may be selected from the group consisting of menthol, preferably (-) - menthol, furthermore from isopulegol, in particular (-) - isopulegol, N-2,3-trimethyl-2-isopropylbutamide, menthyl lactate,
  • Menthylpyrrolidonecarboxylic acid menthylmethyl ether, menthoxypropane-1,2-diol, menthoglycerol acetal (9-methyl-6- (1-methylethyl) -1, 4-dioxaspiro (4.5) decane-2-methanol), monomenthyl succinate, menthyl ethylamido oxalates, 2-hydroxymethyl -3,5,5-trimethylcyclohexanol, 2-isopropyl-N, 2,3-trimethylbutyramide, N-ethyl-p-menthane-3-carboxamide, especially 1R, 3R, 4S-N-ethyl-p-menthane-3-carboxamide, Ethyl 3- (p-menthane-3-carboxamido) acetate, (1R, 2S, 5R) -N- (4-methoxyphenyl) pentanhane carboxamide, N-ethyl-2,2-d
  • FEMA 4684 N- (2-hydroxyethyl) -2,3-dimethyl-2-isopropylbutyramide (now FEMA 4602), N- (1, 1-dimethyl-2-ydroxyethyl) 2,2-diethylbutanamide (now FEMA 4603), N- ( 2-hydroxyethyl) -2,3-dimethyl-2-isopropylbutyramide (now FEMA 4602), WS-12 ((1R, 2S, 5R) -N- (4-methoxyphenyl) pentanhane carboxamide), N-cyclopropyl 5-methyl-2-isopropylcyclohexanecarboxamide, (2S, 5R) -N- [4- (2-amino-2-oxo-ethyl) -phenyl] -p-pentane-carboxamide, FEMA 4684,
  • FEMA 4053 ice & trans p-menthane-3,8-diols (PMD38 CoolAct 38D ®), Questice ® (menthyl pyrrolidone carboxylate), (1 R, 3R, 4S) -3-menthyl 3,6-dioxaheptanoate, (1 R, 2S, 5R) - 3-menthyl methoxyacetate, (1R, 2S, 5R) -3-menthyl 3,6,9-trioxadecanoate,
  • N- (4-cyanomethylphenyl) p-menthane carboxamide FEMA 4496
  • Givaudan's Evercool G-180 Givaudan's Evercool G-180
  • neo-menthane carboxamide such as neo isomer (1S, 2S, 5R) -N- (4- (cyanomethyl) phenyl) -2- isopropyl 5-methylcyclohexanecarboxamide, Neo G-180
  • the active ingredient can be present in the glove in free form. It is also conceivable, however, that the active ingredient is present, for example, embedded in microcapsules.
  • An advantage of the use of microcapsules is that the release of active ingredient can be controlled and thus, for example, a sustained release can be achieved.
  • the microcapsules are selected so that a release of the active ingredient under pressure, for example when putting on the glove, under heat and / or moisture is triggered.
  • the active ingredient can be uniformly distributed in the glove and in particular in the flexible material.
  • the glove is preferably designed as a disposable glove.
  • Disposable gloves have the advantage that they are easy to manufacture and hygienic due to their one-time use. As with this
  • Embodiment may be a part of the drug is not exploited, since it does not come into direct contact with the skin, it is advantageous if the gloves have only a small thickness, preferably from 0.02 mm to 0.2 mm, in particular between 0 , 04 mm and 0.15 mm.
  • the active ingredient is thus advantageously present on the inside of the glove. If the glove has a multilayer structure, then expediently at least the innermost layer contains the active substance. In this case, the active ingredient, if it is present in a sufficient concentration, even form an innermost layer.
  • This embodiment has the advantage that the concentration of the active ingredient, based on the total amount of active ingredient on the skin, can be maximized.
  • the active ingredient may also be present embedded in and / or on the innermost layer of the glove.
  • the innermost layer consist of the flexible material.
  • the innermost layer can also be a layer other than that of the flexible material and, for example, as open-pore and / or
  • closed-pore layer in particular as a textile, foam and / or
  • Flocking especially cotton and / or viscose flocking be configured.
  • This embodiment has the advantage that, by suitable choice of the inner layer, the fixation of the active substance on the glove can be improved.
  • the active ingredient can be contained in an emulsion or suspension arranged on the inside of the glove, which contains skin-care and / or moisturizing substances, preferably glycerol, aloe vera, chamomile and / or fragrances.
  • skin-care and / or moisturizing substances preferably glycerol, aloe vera, chamomile and / or fragrances.
  • the glove according to the invention may also have further layers. These may be on one or both sides of the flexible layer and / or, if present, the innermost layer. It is also conceivable that one or more further layers between flexible layer and innermost layer are arranged.
  • the provision of further layers, in particular outer layers, has the advantage that the durability and waterproofness of the glove can be further improved.
  • the further layers may likewise be flexible layers and consist of the same materials as the flexible layer described above.
  • the further layers can also be configured as textile layers, in particular woven, knitted, laid, nonwoven and / or nonwoven fabrics. These textile layers can consist of the most diverse materials,
  • cotton For example, cotton, viscose, nylon, PA, PE, PP, and / or mixtures thereof.
  • the concentration of the active ingredient may vary depending on the materials used and the cooling effect desired. So can the concentration of the active ingredient.
  • Concentration of the active ingredient for example, to values of 0.005-0.6 wt.%, Preferably 0.02-0.25 wt.%, In each case based on the total weight of the glove set.
  • Another object of the invention is a process for the preparation of the glove according to the invention, containing a proportion of at least one active ingredient which is able to stimulate cold receptors on the human skin.
  • a flexible material and / or a precursor thereof is molded in the form of a solution, suspension or emulsion onto the surface of a hand-shaped one
  • the flexible material and / or the precursor thereof after it has been optionally cured and / or dried, detached from the glove former.
  • the application and / or introduction of the active ingredient is advantageously carried out in one of the following ways and means:
  • the active ingredient is incorporated directly into the solution, suspension or emulsion of the flexible material and / or precursor thereof.
  • This embodiment is particularly suitable for the production of thin gloves.
  • the active ingredient is usually due to production, evenly distributed in the flexible material. As already discussed above, however, only the part of the active substance which is present on the surface of the glove is usually relevant for the cooling effect.
  • a solution or emulsion containing the active ingredient may be sprayed into the interior of the detached glove. This type of application is procedurally very simple and inexpensive.
  • the active ingredient is applied to the glove during the drying process.
  • the active ingredient can be present for example as an aerosol in the drying atmosphere. This approach has the advantage that no separate process step for the application of the drug must be applied.
  • the active ingredient is applied to the inside of the glove together with an emulsion or suspension which contains skin-care and / or moisturizing substances, preferably glycerol, aloe vera, chamomile and / or fragrances.
  • an emulsion or suspension which contains skin-care and / or moisturizing substances, preferably glycerol, aloe vera, chamomile and / or fragrances.
  • the mixture can be sprayed into the interior of the glove.
  • the active ingredient in emulsions or suspensions can be easily embedded and released from them.
  • a coating in particular in the form of a flocking, a textile material and / or a foam, comprising the active ingredient is applied to the inside of the glove.
  • an adhesive layer can first be applied to the flexible material and then provided with flock fibers.
  • the adhesive layer while the same materials can be used as they have been described above for the flexible material already.
  • An alternative form of producing a flocked layer is that the flock fibers are first mixed with the adhesive material and then this mixture is applied to the inside of the glove.
  • This embodiment has the advantage that the flock fibers adhere better and there are less loose flock fibers unbonded on the inside of the glove.
  • Example 1 Here, after cleaning, a ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation.
  • the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators wetting agents and various additives.
  • This formulation contains the active ingredient, for example in encapsulated form.
  • the latex formulation is then dried on the former and then dipped into several leaching tanks and then coagulated in an oven. Afterwards, further wash baths are run through. Then the glove is released from the former and turned to the right. The gloves are then dried in a dryer.
  • Example 2
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators, wetting agents and various additives in the
  • the latex formulation is dried on the former and then immersed in several leaching tanks and then coagulated in an oven. Afterwards follow again various wash baths. Then the glove is released from the former and turned to the right. The gloves are then dried in a dryer, at the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • the latex formulation is then dried on the former and then dipped into several leaching tanks and then coagulated in an oven.
  • the gloves then undergo an online chlorination followed by several wash baths. Then the glove is released from the former and turned to the right.
  • the gloves are then dried in a dryer, towards the end of the drying cycle of the Active substance may be added together with other substances by spraying in the dryer.
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators, wetting agents and various additives in the
  • Example 5 Following the latex formulation is dried on the former and then immersed in several leaching tanks and then coagulated in an oven. The gloves then undergo an online chlorination followed by several wash baths. Then the glove is released from the former and turned to the right. The gloves are then chlorinated offline and then dried in a dryer, at the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • Example 5 Following the latex formulation is dried on the former and then immersed in several leaching tanks and then coagulated in an oven. The gloves then undergo an online chlorination followed by several wash baths. Then the glove is released from the former and turned to the right. The gloves are then chlorinated offline and then dried in a dryer, at the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • Example 5 Example 5:
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators, wetting agents and various additives in the
  • the latex formulation is dried on the former and then immersed in several leaching tanks and then coagulated in an oven. Afterwards follow again various wash baths. Then the glove is released from the former and turned to the right. The gloves are then chlorinated off-line and then dried in a dryer, at the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators, wetting agents and various additives in the
  • the latex formulation is dried on the former and then immersed in several leaching tanks and then coagulated in an oven. Subsequently, the glove is coated with a polymer layer and again driven through an oven. Then again followed by various baths. Then the glove is released from the former and turned to the right. The gloves are then dried in a dryer, wherein towards the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • Example 7 Here, after cleaning, the ceramic former is immersed in a coagulant bath which also contains polymer and subsequently dried, followed by immersion in a bath containing a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both Crosslinker, vulcanization accelerator, wetting agent and various additives) is followed by the latex formulation on the former dried and then dipped in several leaching tanks and then coagulated in an oven. Subsequently, the glove is coated with a polymer layer and again driven through an oven. Then again followed by various baths. Then the glove is released from the former and turned to the right. The gloves are then dried in a dryer, wherein towards the end of the drying cycle, the active ingredient may be added together with other substances by spraying into the dryer.
  • Multilayer gloves Multilayer gloves:
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators wetting agents, optional color pigments and
  • a latex mixture which, in addition to the natural and or synthetic latex, crosslinker, vulcanization accelerator, wetting agent, optional
  • this second layer may already contain the jib fibers or act as a carrier layer for a flock lining, in which case the glove is driven directly thereafter through a flocking chamber or becomes this second layer not as a latex film but as a foam which optionally also contains flock fibers.
  • the second layer is then dried again with or without flock fibers and then immersed in several leaching tanks and then in an oven coagulated. Followed by an online chlorination and then again various baths. Then the glove is released from the former and turned to the right. The gloves are then dried in a dryer.
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators wetting agents, optional color pigments and
  • the latex formulation is then dried on the former and submerged again in a second bath with a latex mixture (these too, besides the natural and / or synthetic latex, crosslinker, vulcanization accelerator, wetting agent, optional
  • This second layer can already contain the Fockmaschinen or act as a support layer for a flock lining, in this case, the glove is driven directly through a flocking chamber, or this second layer is not executed as a latex film but as a foam possibly also
  • Flock fibers dried again and then dipped into several leaching tanks and then coagulated in an oven. Following an online chlorination followed by various washing baths. Then the glove is released from the former and turned to the right.
  • Gloves will be chlorinated offline afterwards. The gloves will either be removed after shedding from the shaper or after being taken offline
  • Chlorination subsequently dried in a dryer, towards the end of the Drying cycle of the active ingredient may be added together with other substances by spraying in the dryer.
  • the ceramic former is dipped in a coagulant bath and subsequently dried, followed by immersion in a bath with a latex formulation (the latex formulation contains natural latex or synthetic latex, or mixtures of both, as well as crosslinkers,
  • Vulcanization accelerators wetting agents, optional color pigments and
  • the latex formulation is then dried on the former and submerged again in a second bath with a latex mixture (these too, besides the natural and / or synthetic latex, crosslinker, vulcanization accelerator, wetting agent, optional
  • This second layer can already contain the Fockmaschinen or act as a support layer for a flock lining, in this case, the glove is driven directly through a flocking chamber, or this second layer is not executed as a latex film but as a foam possibly also
  • Flock fibers dried again and then dipped into several leaching tanks and then coagulated in an oven. This is followed by an online chlorination followed by various washing baths. After that, the
  • the gloves detached from the former and turned to the right.
  • the gloves can then be chlorinated offline.
  • the gloves will either be removed after shedding from the shaper or after being taken offline
  • Chlorination predried in a dryer Following is the
  • Formulation that may contain the active substance together with other substances sprayed inside the gloves and the gloves in the
  • the multi-layered gloves may also have three or more layers, and then between the first and the second layer further latex layer (consisting of natural and / or synthetic latex, crosslinker, vulcanization accelerator, wetting agent, optional
  • Color pigments and various additives were applied by dipping.

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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Public Health (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Microbiology (AREA)
  • Mechanical Engineering (AREA)
  • Anesthesiology (AREA)
  • Hematology (AREA)
  • Surgery (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Molecular Biology (AREA)
  • Medical Informatics (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un gant comprenant au moins une couche de matériau souple qui forme une cavité destinée à recevoir une main. Ce gant a une teneur en au moins un agent actif apte à stimuler des récepteurs de froid sur et/ou dans la peau humaine.
PCT/EP2014/001239 2013-06-14 2014-05-08 Gant a effet rafraichissant Ceased WO2014198366A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013009963.3A DE102013009963A1 (de) 2013-06-14 2013-06-14 Handschuh mit Kühlwirkung
DE102013009963.3 2013-06-14

Publications (1)

Publication Number Publication Date
WO2014198366A1 true WO2014198366A1 (fr) 2014-12-18

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/001239 Ceased WO2014198366A1 (fr) 2013-06-14 2014-05-08 Gant a effet rafraichissant

Country Status (2)

Country Link
DE (1) DE102013009963A1 (fr)
WO (1) WO2014198366A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY190527A (en) * 2019-11-20 2022-04-27 Top Glove Int Sdn Bhd Coating composition and elastomeric article containing the same
US20240269094A1 (en) * 2023-01-27 2024-08-15 Edward Tak Wei Treatment of canine dermatitis and skin irritation

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EP1250941A1 (fr) * 2001-04-17 2002-10-23 The Procter & Gamble Company Articles contenant un agent rafraichissant sans odeur de menthe
WO2004060338A1 (fr) * 2003-01-03 2004-07-22 Wrp Asia Pacific Sdn. Bhd. Preparation topique pour le soin de la peau et articles polymeres a base de caoutchouc elastomere trempe produits a partir de cette preparation
US20050222543A1 (en) * 2004-04-01 2005-10-06 Zechuan Shao Skin-care protective gloves and manufacturing method
DE102004043566A1 (de) * 2004-09-09 2006-03-30 Würtz, Heike Kosmetischer Pflegehandschuh
US20080085290A1 (en) * 2006-10-10 2008-04-10 Lisa Ann Flugge-Berendes Skin cooling compositions
WO2010103351A1 (fr) * 2009-03-12 2010-09-16 Dipped Products Plc Article élastomère présentant une couche interne spéciale absorbant l'humidité
CN102106621A (zh) * 2011-02-19 2011-06-29 镇江苏惠乳胶制品有限公司 一种具有清凉感的防护橡胶手套及其制备方法
US20110223222A1 (en) * 2008-08-11 2011-09-15 Alexandros Spyros Botsaris Antiperspirant Compositions and Methods for Reducing Perspiration in Humans

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