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WO2014157160A1 - Procédé et appareil de production d'oxyde de silicium - Google Patents

Procédé et appareil de production d'oxyde de silicium Download PDF

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Publication number
WO2014157160A1
WO2014157160A1 PCT/JP2014/058216 JP2014058216W WO2014157160A1 WO 2014157160 A1 WO2014157160 A1 WO 2014157160A1 JP 2014058216 W JP2014058216 W JP 2014058216W WO 2014157160 A1 WO2014157160 A1 WO 2014157160A1
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WIPO (PCT)
Prior art keywords
silicon oxide
chamber
substrate
raw material
belt
Prior art date
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Ceased
Application number
PCT/JP2014/058216
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English (en)
Japanese (ja)
Inventor
敦雄 川田
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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Priority to JP2015508524A priority Critical patent/JPWO2014157160A1/ja
Publication of WO2014157160A1 publication Critical patent/WO2014157160A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof

Definitions

  • the present invention relates to a silicon oxide production method and production apparatus suitably used for packaging film deposition, a lithium ion secondary battery negative electrode active material, and the like.
  • a raw material mixture composed of silicon dioxide-based oxide powder is heat-treated in a reduced pressure non-oxidizing atmosphere to generate silicon oxide vapor, and the silicon oxide vapor is condensed in the gas phase.
  • a method of continuously producing fine amorphous silicon oxide powder of 0.1 ⁇ m or less (Patent Document 1: Japanese Patent Laid-Open No. 63-103815), and raw material silicon is heated and evaporated to roughen the surface structure
  • Patent Document 2 Japanese Patent Laid-Open No. 9-110412
  • a mixed raw material powder containing silicon dioxide is supplied into the reaction furnace, silicon oxide gas is generated and deposited on the cooled substrate surface, and then this silicon oxide precipitate is continuously recovered (Patent Document 3: JP-A-2001-220123).
  • JP-A-63-103815 can be continuously produced, but the generated SiO powder is fine and high-purity silicon oxide powder is obtained by an oxidation reaction when taken out to the atmosphere. There is a problem that can not be manufactured.
  • the method described in JP-A-9-110412 is capable of producing high-purity silicon oxide, but is premised on a batch method, so that mass production is difficult, and as a result, only expensive silicon oxide powder can be produced.
  • JP-A-2001-220123 can continuously recover high-purity silicon oxide powder, since the silicon oxide is hard, the blade of the scraping device, which is the recovery mechanism, is easily worn, and the long-term There was a problem that it could not be used.
  • the present invention has been made in view of the above circumstances, and provides a silicon oxide production method and production apparatus capable of continuously producing high-purity silicon oxide efficiently and stably for a long period of time.
  • the present inventor in a silicon oxide manufacturing method for generating silicon oxide gas and precipitating it on a substrate, uses a manufacturing apparatus having a belt-shaped substrate, Efficiently by rotating the belt-shaped substrate in the deposition chamber to deposit silicon oxide solids on the substrate surface in the deposition chamber, and separating and collecting the silicon oxide solids deposited on the substrate surface in the collection chamber.
  • the present inventors have found that silicon oxide can be continuously produced stably for a long period of time, and the present invention has been made.
  • a substrate, a deposition chamber for depositing a silicon oxide solid on the substrate, a transport pipe for transporting the silicon oxide gas from the reaction chamber to the deposition chamber, a recovery chamber connected to the deposition chamber, and the belt-shaped substrate Is disposed rotatably between the deposition chamber and the collection chamber, and includes a rotation mechanism for rotating the belt-shaped substrate between the deposition chamber and the collection chamber, and a load lock chamber connected to the collection chamber via a gate valve. Silicon oxide production equipment.
  • FIG. 1 It is a schematic sectional drawing which shows one Example of this invention. 2 is a schematic cross-sectional view of an apparatus used in Comparative Example 1. FIG.
  • the production method of the present invention comprises a reaction chamber for reacting mixed raw material powder containing silicon dioxide powder to generate silicon oxide gas, a raw material supply mechanism for supplying the mixed raw material powder into the reaction chamber, and the silicon oxide gas.
  • the chamber and the belt-like substrate are rotatably arranged between the deposition chamber and the collection chamber, and are connected to the collection chamber via a gate valve and a rotation mechanism that rotates the belt-like substrate between the deposition chamber and the collection chamber.
  • a mixed raw material powder containing silicon dioxide powder is supplied to a reaction furnace chamber using a silicon oxide production apparatus having a load lock chamber, and 1,200 to 1,600 is applied at normal pressure or reduced pressure in the reaction chamber. Heated to °C Silicon oxide gas is generated, and this silicon oxide gas is introduced into the deposition chamber through a transfer tube maintained at a temperature equal to or higher than that of the reaction chamber, and the belt-like substrate is rotated to deposit silicon oxide solids on the substrate surface in the deposition chamber. At the same time, the silicon oxide manufacturing method of peeling the silicon oxide solid deposited on the surface of the substrate in the collection chamber and collecting it.
  • the mixed raw material powder containing silicon dioxide powder a mixture of silicon dioxide powder and powder that reduces the powder is used.
  • the reducing powder include metal silicon compounds and carbon-containing powders, and metal silicon powder is preferable from the viewpoint of increasing reactivity and increasing yield.
  • the reaction proceeds according to the following reaction scheme. Si (s) + SiO 2 (s) ⁇ 2SiO (g)
  • the average particle diameter of the silicon dioxide powder used in the present invention is 0.1 ⁇ m or less, usually 0.005 to 0.1 ⁇ m, preferably 0.005 to 0.08 ⁇ m.
  • the average particle size of the metal silicon powder is 30 ⁇ m or less, usually 0.05 to 30 ⁇ m, preferably 0.1 to 20 ⁇ m.
  • the average particle diameter of the silicon dioxide powder is larger than 0.1 ⁇ m, or the average particle diameter of the metal silicon powder is larger than 30 ⁇ m, the reactivity is lowered and the productivity may be lowered.
  • the average particle diameter can be represented by the cumulative weight average value D 50 in the particle size distribution measurement by the laser light diffraction method.
  • the mixed raw material powder is heated and held in the reaction chamber at a temperature of 1,200 to 1,600 ° C., preferably 1,300 to 1,500 ° C. to generate silicon oxide gas.
  • the reaction temperature is less than 1,200 ° C, the reaction is difficult to proceed and the productivity is lowered.
  • the reaction temperature exceeds 1,600 ° C, it is difficult to select the furnace material because the mixed raw material powder melts. There is.
  • the atmosphere in the furnace is performed under normal pressure or reduced pressure (preferably 1,000 Pa or less). It is preferable to carry out under reduced pressure at which silicon oxide is easily generated as a gas.
  • the inside of the furnace may be in an inert gas. Examples of the inert gas include argon gas and helium gas.
  • the mixed raw material powder is supplied at appropriate intervals or continuously by a raw material supply mechanism, and the reaction is continuously performed.
  • a raw material supply mechanism examples include continuous supply using a screw feeder or the like, intermittent supply using an intermediate hopper having upper and lower dampers, and combinations thereof.
  • the silicon oxide gas generated in the reaction chamber is continuously supplied to the deposition chamber via the transfer pipe.
  • the transfer tube is maintained at the same temperature as the reaction chamber.
  • the silicon oxide gas is deposited on and adhered to the inner wall of the transfer pipe, causing troubles in operation and preventing stable operation.
  • heating to a temperature significantly exceeding the reaction chamber causes an increase in power cost and does not produce an effect, so the same temperature as the reaction chamber to the reaction chamber temperature + 200 ° C. is appropriate.
  • a belt-like substrate on which silicon oxide gas is deposited as a silicon oxide solid on the surface thereof is disposed in the deposition chamber and the recovery chamber, and rotates between the deposition chamber 7 and the recovery chamber 9.
  • the silicon oxide gas introduced into the deposition chamber comes into contact with the substrate in the deposition chamber and is cooled, it deposits as a thick film of silicon oxide (solid) on the surface of the substrate.
  • the temperature of the substrate in the deposition chamber is preferably maintained at 200 to 1,000 ° C., more preferably 300 to 900 ° C., and further preferably 300 to 800 ° C. If the temperature is higher than 1,000 ° C., silicon oxide may be difficult to precipitate. If the temperature is lower than 200 ° C., the obtained silicon oxide may become fine powder and may have too strong activity.
  • the silicon oxide deposited on the substrate surface is transported to the recovery chamber by the rotation of the belt-like substrate.
  • the amount of heat brought into the substrate by the silicon oxide gas is eliminated, so that the temperature of the substrate decreases. Due to this temperature decrease, a difference in thermal shrinkage occurs between the base and silicon oxide, and the silicon oxide is naturally peeled from the base, so that the silicon oxide can be easily recovered.
  • the substrate may be forcibly cooled by a cooling means such as air cooling or water cooling.
  • the temperature of the substrate in the recovery chamber is preferably lowered by 100 ° C. or more, more preferably by 200 ° C. or more from the deposition temperature.
  • the belt-like substrate may be bent in the collection chamber in order to promote peeling.
  • the substrate temperature is measured by measuring the back side of the surface directly exposed to silicon oxide vapor.
  • the measurement can be performed by a method in which the thermocouple is brought into contact with the substrate, a method in which the thermocouple is measured in a non-contact manner, or the like.
  • the shape of the substrate is not particularly limited as long as it is a belt, but for example, a foil-like, net-like, knitted, woven, or chain-like endless belt is preferably used.
  • the material of the substrate is not particularly limited, but a material having heat resistance at the deposition temperature and corrosion resistance to the silicon oxide gas, specifically, a metal material or a ceramic (SUS) material is preferable.
  • a material having a large difference in linear expansion coefficient from silicon oxide is more preferable because silicon oxide is easily peeled off from the surface of the substrate due to a difference in thermal contraction between the substrate and silicon oxide and can be easily recovered.
  • a metal material is preferable, and stainless steel, nickel alloy, titanium alloy, or the like is preferably used in terms of workability.
  • the width and all the lengths of the belt-like substrate are appropriately selected depending on the amount of silicon oxide gas and the like, but preferably have a width of 30 to 300 cm and a total length of 100 to 1,000 cm.
  • the rotation mechanism for rotating the belt-shaped substrate is not particularly limited, and examples thereof include a rotation mechanism including at least two rollers and a driving motor. Furthermore, it is preferable to provide a tensioner for keeping the tension of the belt-like substrate constant.
  • the rotation of the belt-like substrate may be performed at intervals or continuously as appropriate, but is preferably continuous.
  • the rotation speed (linear speed) of the substrate is appropriately selected depending on the feed rate of the raw material, the cooling rate of the substrate, etc., and the linear velocity is preferably 1 cm / min to 10 m / min.
  • the substrate after the silicon oxide is peeled returns to the deposition chamber by the rotation of the belt-shaped substrate.
  • the substrate may be preheated by a heating mechanism such as a heater.
  • a heating mechanism such as a heater.
  • the silicon oxide accumulated in the recovery chamber can be taken out through the load lock chamber by appropriately opening and closing the gate valve during continuous operation without stopping the operation of the apparatus, and silicon oxide can be continuously produced efficiently.
  • the collection tray is previously arranged below the base in the collection chamber, it can be taken out earlier.
  • the recovery chamber is in a reduced pressure atmosphere, it is necessary to decompress the load lock chamber to equalize the pressure with the recovery chamber before opening the gate valve, and before removing silicon oxide from the load lock chamber, The chamber needs to be restored to atmospheric pressure. Even in this case, it is possible to take out silicon oxide accumulated in the recovery chamber and arrange the recovery tray without stopping the operation and stopping the introduction of the silicon oxide gas into the deposition chamber.
  • the purity of silicon oxide in the obtained silicon oxide is 99.9 to 99.95% by mass, and a high-purity product can be obtained.
  • the obtained bulk silicon oxide solid can be made into silicon oxide powder by using an appropriate pulverizer and classifier.
  • a silicon oxide powder having an average particle size of 0.01 to 30 ⁇ m and a BET specific surface area of 0.5 to 30 m 2 / g can be obtained.
  • Such silicon oxide powder is suitable for film deposition for packaging, negative electrode active material for lithium ion secondary battery, and the like.
  • a reaction chamber in which a mixed raw material powder containing silicon dioxide powder is reacted to generate silicon oxide gas, and the mixed raw material powder is supplied into the reaction chamber.
  • a raw material supply mechanism a belt-like substrate for depositing a silicon oxide solid from the silicon oxide gas, a deposition chamber for depositing a silicon oxide solid on the substrate, and a transport for transporting the silicon oxide gas from the reaction chamber to the deposition chamber
  • a pipe a recovery chamber connected to the deposition chamber for recovering the silicon oxide solid deposited on the substrate, and the belt-shaped substrate is rotatably disposed between the deposition chamber and the recovery chamber.
  • Examples include a continuous production apparatus for silicon oxide, which includes a rotation mechanism for rotating a substrate and a load lock chamber connected to a recovery chamber via a gate valve.
  • the reaction furnace 1 has a reaction chamber 2 therein.
  • the reaction chamber 2 is provided with a reaction chamber heater 3, a raw material supply mechanism 5 is connected to the reaction chamber 2, and the reaction chamber 2 is connected to a deposition chamber 7 through a transport pipe 6.
  • the transport pipe 6 includes a transport pipe heater 8.
  • the deposition chamber 7 is connected to the collection chamber 9 with a partition wall 10 having a slit-shaped opening interposed therebetween.
  • the belt-like substrate 11 is disposed in the deposition chamber 7 and the collection chamber 9 so as to be rotatable between the deposition chamber 7 and the collection chamber 9 through the slit-shaped opening.
  • the opening is preferably as small as possible within the range in which the belt-like substrate 11 can pass.
  • the rotation mechanism for rotating the belt-shaped substrate 11 includes a deposition chamber roller 12a, a collection chamber roller 12b, and a roller driving motor 13.
  • the belt-shaped substrate 11 is wound around the deposition chamber roller 12a and the collection chamber roller 12b.
  • the deposition chamber 7 is provided with a deposition chamber heater 14, and the recovery chamber 9 is provided with a cooling mechanism 15.
  • a recovery tray 16 a is disposed below the belt-like substrate 11 in the recovery chamber 9.
  • the collection chamber 9 is connected to a load lock chamber 18 via a gate valve 17, and the load lock chamber 18 is provided with a load lock chamber door 19. In the load lock chamber 18, a spare collection tray 16b to be exchanged with the collection tray 16a is disposed.
  • Reference numerals 20a to 20c denote vacuum pumps, which are connected to the deposition chamber 7, the load lock chamber 18, and the raw material supply mechanism 5, respectively.
  • the reaction chamber 2 is heated to 1,200 to 1,600 ° C. by the reaction chamber heater 3.
  • a mixed raw material powder 4 containing silicon dioxide powder is continuously or intermittently supplied to the reaction chamber 2 by a raw material supply mechanism 5.
  • the silicon oxide gas generated in the reaction chamber 2 is transported to the deposition chamber 7 through the transport pipe 6.
  • the transfer tube 6 is held above the temperature of the reaction chamber 2 by a transfer tube heater 8.
  • the belt-shaped substrate 11 in the deposition chamber 7 is held at a predetermined temperature by the deposition chamber heater 14, and the belt-shaped substrate 11 in the recovery chamber 9 is cooled to a predetermined temperature by the cooling mechanism 15.
  • the silicon oxide gas is deposited as a silicon oxide solid on the surface of the belt-like substrate 11 in the deposition chamber 7.
  • the deposited silicon oxide is conveyed to the collection chamber 9 by the rotation of the belt-shaped substrate 11, and is naturally separated due to the thermal contraction difference, and is accumulated on the collection tray 16 a in the collection chamber 9.
  • the accumulated silicon oxide is appropriately opened / closed during the continuous operation, and is replaced with a spare collection tray 16b disposed in the load lock chamber 18, and from the load lock chamber door 19 via the load lock chamber 18. It can be taken out.
  • the reaction for generating the silicon oxide gas is performed under reduced pressure, the pressure in the furnace is reduced using the vacuum pump 20a with the gate valve 17 closed.
  • the load lock chamber 18 When recovering the peeled silicon oxide solid, if the recovery chamber 9 is in a reduced pressure atmosphere, before opening the gate valve 17, the load lock chamber 18 is depressurized to equalize the pressure with the recovery chamber 9, and further the load lock chamber Before the silicon oxide is taken out of the load, the load lock chamber 18 is returned to the atmospheric pressure and taken out.
  • silicon oxide is continuously and stably manufactured at a low cost by continuously depositing and peeling silicon oxide while rotating the belt-shaped substrate and sequentially collecting the silicon oxide. it can.
  • Example 1 Silicon oxide was manufactured using the continuous manufacturing apparatus shown in FIG.
  • the raw material was a silicon dioxide powder (average particle size 0.02 ⁇ m, BET specific surface area 200 m 2 / g) and metal silicon powder (average particle size 10 ⁇ m, BET specific surface area 3 m 2 / g) in an equimolar mole ratio.
  • 20 kg of mixed raw material powder was initially charged in the reaction chamber 2 (volume 0.5 m 3 ) in the reaction furnace 1. Next, after the pressure inside the furnace is reduced to 10 Pa or less using the vacuum pump 20a with the gate valve 17 closed, the base 11 made of a stainless steel endless belt is rotated by the driving motor 13 (linear velocity 10 cm / min).
  • the reaction chamber heater 3 was energized, and the temperature of the reaction chamber was maintained at 1,400 ° C.
  • the transfer tube heater 8 was energized to hold the transfer tube 6 at 1,400 ° C.
  • the deposition chamber heater 14 was energized to hold the belt-like substrate 11 in the deposition chamber 7 at 650 ° C. Since it was confirmed from the pressure increase in the reaction chamber 2 that silicon oxide gas was generated, the cooling mechanism 15 was operated to cool the belt-shaped substrate 11 in the recovery chamber 9 to 500 ° C. Silicon oxide gas was introduced into the deposition chamber 7, and a silicon oxide solid was deposited on the surface of the belt-like substrate in the deposition chamber 7.
  • the deposited silicon oxide solid in the collection chamber 9 naturally separated from the belt-shaped substrate without applying physical force directly to the silicon oxide solid, and accumulated on the collection tray 16a in the collection chamber 9.
  • the raw material supply mechanism 5 was operated, and the mixed raw material powder was continuously supplied at a rate of 2 kg / h. Since the reaction chamber pressure was stable after that, it was confirmed that the reaction was continuous.
  • the load lock chamber 18 was depressurized by the vacuum pump 20b until the pressure became almost the same as that of the recovery chamber 9, the gate valve 17 was opened, and silicon oxide entered.
  • the collection tray 16a was replaced with an empty collection tray 16b, and the gate valve 17 was closed again.
  • the load lock chamber 18 was restored to atmospheric pressure, and the tray 16 a was taken out from the load lock chamber door 19.
  • the powder having an average particle diameter D 50 of 5 ⁇ m obtained by pulverizing the silicon oxide thus obtained with a ball mill is an amorphous powder having a BET specific surface area of 8 m 2 / g and a purity of 99.9% by mass or more. there were.
  • Silicon oxide powder was produced using the continuous production apparatus shown in FIG. 1 (FIG. 2) of JP-A-2001-220123.
  • the raw material is the same mixed powder of silicon dioxide powder and metal silicon powder as in Example 1, and 20 kg of mixed raw material powder is initially charged in the reaction chamber (volume 0.5 m 3 ) in the reactor as in Example 1. did.
  • the heater was energized, and the temperature was raised to 1,400 ° C., which was the same as in Example 1.
  • the conveyance pipe was heated and held at 1,400 ° C., water was introduced into the refrigerant introduction pipe, and the SUS substrate was cooled.
  • the feeder was operated, and the mixed raw material powder was continuously supplied at a rate of 2 kg / h to carry out a continuous reaction.
  • the silicon oxide deposited on the substrate was continuously scraped by a scraper having a tungsten carbide blade, which is a super hard material, and recovered in a recovery chamber.
  • the powder having an average particle diameter D 50 of 5 ⁇ m obtained by pulverizing the silicon oxide solid thus obtained with a ball mill is an amorphous powder having a BET specific surface area of 8 m 2 / g and a purity of 99.9% or more.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

L'invention concerne un appareil de production d'oxyde de silicium, doté de : une chambre de réaction pour produire de l'oxyde de silicium gazeux par réaction d'une poudre de matière première mélangée contenant une poudre de dioxyde de silicium ; un mécanisme d'introduction de matière première pour introduire la poudre de matière première mélangée dans l'intérieur de cette chambre de réaction ; un substrat en forme de ceinture pour déposer l'oxyde de silicium solide à partir de l'oxyde de silicium gazeux ; une chambre de dépôt pour déposer l'oxyde de silicium solide sur le substrat ; un tuyau de transport pour transporter l'oxyde de silicium gazeux à partir de la chambre de réaction dans la chambre de dépôt ; et une chambre de récupération connectée à la chambre de dépôt ; un mécanisme rotatif placé pour permettre au substrat en forme de ceinture de tourner entre la chambre de dépôt et la chambre de récupération, pour mettre en rotation le substrat en forme de ceinture entre la chambre de dépôt et la chambre de récupération ; et une chambre de verrouillage de charge connectée à la chambre de récupération par l'intermédiaire d'un robinet vanne. L'invention rend possible de produire de façon efficace et stable de l'oxyde de silicium de pureté élevée de façon continue sur une période prolongée de temps.
PCT/JP2014/058216 2013-03-29 2014-03-25 Procédé et appareil de production d'oxyde de silicium Ceased WO2014157160A1 (fr)

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JP2013-073020 2013-03-29
JP2013073020 2013-03-29

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105600454A (zh) * 2015-10-16 2016-05-25 南京钢铁股份有限公司 一种再次回收利用焦化除尘粉的装置及其方法
CN112689612A (zh) * 2018-08-27 2021-04-20 株式会社大阪钛技术 SiO粉末的制造方法及球形颗粒状SiO粉末
JP2025086883A (ja) * 2023-11-28 2025-06-09 ポスコホールディングス インコーポレーティッド シリコン酸化物連続製造設備及び連続製造方法

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DE19844357A1 (de) * 1998-09-28 2000-03-30 Hilmar Weinert Bandbedampfungsanlage zur Herstellung von planparallelen Plättchen
JP2001220123A (ja) * 2000-02-04 2001-08-14 Shin Etsu Chem Co Ltd 酸化珪素粉末の連続製造方法及び連続製造装置
JP2005517620A (ja) * 2002-02-18 2005-06-16 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 亜酸化ケイ素、二酸化ケイ素及び／又は炭化ケイ素の面平行な構造を製造する方法、当該方法によって得られる面平行な構造ならびにその使用

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JPS6227318A (ja) * 1985-07-29 1987-02-05 Kawasaki Steel Corp Ｓｉｏ微粉末の製造方法およびその装置
JPH0925112A (ja) * 1995-07-11 1997-01-28 Shin Etsu Chem Co Ltd 金属ケイ素の処理方法及び装置

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Publication number Priority date Publication date Assignee Title
DE19844357A1 (de) * 1998-09-28 2000-03-30 Hilmar Weinert Bandbedampfungsanlage zur Herstellung von planparallelen Plättchen
JP2001220123A (ja) * 2000-02-04 2001-08-14 Shin Etsu Chem Co Ltd 酸化珪素粉末の連続製造方法及び連続製造装置
JP2005517620A (ja) * 2002-02-18 2005-06-16 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 亜酸化ケイ素、二酸化ケイ素及び／又は炭化ケイ素の面平行な構造を製造する方法、当該方法によって得られる面平行な構造ならびにその使用

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105600454A (zh) * 2015-10-16 2016-05-25 南京钢铁股份有限公司 一种再次回收利用焦化除尘粉的装置及其方法
CN112689612A (zh) * 2018-08-27 2021-04-20 株式会社大阪钛技术 SiO粉末的制造方法及球形颗粒状SiO粉末
CN112689612B (zh) * 2018-08-27 2024-04-19 株式会社大阪钛技术 SiO粉末的制造方法及球形颗粒状SiO粉末
JP2025086883A (ja) * 2023-11-28 2025-06-09 ポスコホールディングス インコーポレーティッド シリコン酸化物連続製造設備及び連続製造方法
JP7778896B2 (ja) 2023-11-28 2025-12-02 ポスコホールディングス インコーポレーティッド シリコン酸化物連続製造設備及び連続製造方法

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