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WO2014147380A1 - Commutation d'état de cristaux liquides - Google Patents

Commutation d'état de cristaux liquides Download PDF

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Publication number
WO2014147380A1
WO2014147380A1 PCT/GB2014/050828 GB2014050828W WO2014147380A1 WO 2014147380 A1 WO2014147380 A1 WO 2014147380A1 GB 2014050828 W GB2014050828 W GB 2014050828W WO 2014147380 A1 WO2014147380 A1 WO 2014147380A1
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electric field
liquid crystal
state
helical axis
flexoelectric
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Benjamin Ian OUTRAM
Stephen John ELSTON
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Oxford University Innovation Ltd
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Oxford University Innovation Ltd
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    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/13718—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on a change of the texture state of a cholesteric liquid crystal
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
    • G02F1/13712—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering the liquid crystal having negative dielectric anisotropy

Definitions

  • the present invention relates to methods of controlling a liquid crystal material and to liquid crystal devices, in particular to switching a liquid crystal material between different alignment states.
  • Liquid crystal (LC) materials have found wide use in display technologies, which rely on controlling the optical properties of a liquid crystal by applying an electric field.
  • a typical liquid crystal display (LCD) device one or more liquid crystal layers are positioned in front of a reflector or backlight to modulate the light passing therethrough.
  • Some conventional displays use a twisted nematic or cholesteric LC between two crossed polarisers so that the polarisation state of light is rotated by 90° after it has passed through the first polariser, allowing it to be transmitted through the second polariser.
  • an electric field is applied across the LC layer, the molecules tend to align parallel to the electric field due to coupling of the electric field to the dielectric anisotropy of the LC material.
  • a cholesteric LC phase is a nematic phase that exhibits a spontaneous twist due to chirality of some or all of the molecules of the LC mixture i.e. it has a helicoidal structure with the director rotated slightly between adjacent planes and a helical axis defined normal to the directors. This variation of director is periodic, with the "pitch" of the helicoidal structure being defined as double the period of the angle of the director.
  • Figure 9 illustrates the structure of a helicoidal (e.g. cholesteric) liquid crystal material.
  • the Z-axis defines the helical axis (also known as the helicoidal axis) of the material.
  • the director of the LC molecules is aligned at an angle ⁇ perpendicular to the Z-axis in each layer, and this angle ⁇ varies so that the director rotates with distance along the Z-axis to result in the helicoidal structure.
  • the pitch P is understood to be the distance it takes for the director to rotate one full turn i.e. 2%.
  • the helicoidal structure of a cholesteric LC can be modified by an applied electric field. This can be described in terms of the electric field coupling to the dielectric anisotropy of the liquid crystal.
  • an electric field can be applied across the surfaces to switch the material into an orthogonal state that has its helical axis aligned parallel to the surfaces, known as a Uniform Lying Helix (ULH) state or conic focal state.
  • ULL Uniform Lying Helix
  • the coupling of the electric field to the dielectric anisotropy of LC materials is the best understood mechanism for controlling the alignment state and optical properties of a liquid crystal.
  • Other methods of controlling the optical properties of a LC material include changes in temperature (e.g. as used in aquarium thermometers) and changes in applied stress or strain (e.g. as used to measure stress distribution patterns). It has also been proposed that some other mechanisms, such as electrohydrodynamic effects or flexoelectric properties, may be harnessed to effect control.
  • One established method uses electrohydrodynamic effects to help the alignment of a positive dielectric anisotropy material in the ULH state, e.g. as described in: A stable and switchable uniform lying helix structure in cholesteric liquid crystals, Chun-Ta Wang, WeiYuan Wang and Tsung-Hsien Lin, Appl. Phys. Lett. 99 (2011 ), 041108.
  • the ULH state can switch back to the Grandjean state through a slow relaxation process due to surface interaction with planar alignment layers, which can be enhanced if a large field is applied (unwinding the helix) and the Grandjean state is then allowed to form from the homeotropic state.
  • Flexoelectric coupling with the applied electric field tends to keep the molecules in a helical arrangement and can therefore oppose an electric coupling.
  • the critical field that must be applied to unwind the helical ordering may be increased.
  • the flexoelectric effect can affect how the helicoidal structure of a cholesteric LC is modified or unwound by an applied electric field. This could be used to change when a transition takes place between a helicoidal structure and an unwound (non-helicoidal) structure.
  • the mere presence of a flexoelectric effect in this case does not necessarily allow the material to be switched between alignment states with the helical axis generally aligned perpendicular or parallel to the bounding surfaces of a LC device.
  • the present invention provides a novel approach to switching between different alignment states of a liquid crystal material.
  • liquid crystal material has a negative dielectric anisotropy ⁇ satisfying:
  • ⁇ ⁇ ,, - ⁇ ⁇ 0 ,
  • ⁇ is the dielectric constant parallel to the helical axis of the liquid crystal material and ⁇ is the dielectric constant perpendicular to the helical axis of the liquid crystal material, such that in a state without flexoelectric coupling the material has a lowest energy alignment state in which the helical axis is aligned parallel to an applied electric field;
  • liquid crystal material can undergo flexoelectric coupling with an applied electric field as a result of an effective dielectric constant ⁇ perpendicular to the helical axis given by:
  • Sfiexo is a contribution from flexoelectric polarisation in the material, such that in a state with flexoelectric coupling the material has a lowest energy alignment state in which the helical axis is aligned perpendicular to an applied electric field;
  • LC material that has a negative dielectric anisotropy and a high flexoelectric response.
  • the applied electric field can be controlled to switch the helical axis of the LC material between parallel and perpendicular alignment states simply by enabling or suppressing the contribution from the flexoelectric response.
  • the invention takes advantage of flexoelectric polarisation to controllably modify the material's effective dielectric constant and therefore enable electrical switching between alignment states of the helical axis.
  • the parameters of the applied electric field that may be adjusted so as to enable or suppress a flexoelectric coupling can be related to changes in amplitude and/or changes in time of an electric field signal.
  • a time-varying waveform this may include the amplitude e.g. voltage, the shape of the waveform, the number and/or duration of amplitude pulses, or the pulse sequence applied.
  • an oscillating waveform such as an AC electric field, this may include amplitude and/or frequency.
  • the method comprises changing the frequency of a time-dependent electric field so as to enable or suppress flexoelectric coupling. Changing the frequency can, for example, result in an effective dielectric constant that is largest in a direction perpendicular to the helical axis at low frequencies and largest in a direction parallel to the helical axis at high frequencies.
  • the electric field is applied parallel to the initial alignment state of the liquid crystal material, i.e. parallel to the helical axis.
  • the material naturally has a lowest energy alignment state in which the helical axis is aligned parallel to the applied electric field.
  • the step of applying the parallel electric field e.g. a high frequency AC field
  • the step of changing the electric field parameter(s) e.g. switching to low frequency
  • the step of applying the parallel electric field e.g.
  • a low frequency AC field enables a flexoelectric coupling then the helical axis tends to align perpendicular to the applied field and the LC material is thereby switched from its initial alignment state to an orthogonal alignment state.
  • the step of changing the electric field parameter(s) e.g. switching to high frequency
  • the electric field is applied perpendicular to the initial alignment state of the liquid crystal material, i.e. perpendicular to the helical axis.
  • the material naturally has a lowest energy alignment state in which the helical axis is aligned parallel to an applied electric field.
  • the step of applying the perpendicular electric field may have two possible outcomes, depending on whether or not the step of applying the electric field enables a flexoelectric coupling.
  • the parameters of the perpendicular electric field do not allow flexoelectric coupling so that the LC material switches to its natural lowest energy alignment state in which the helical axis is aligned parallel to the applied electric field.
  • the step of applying the perpendicular electric field therefore switches the material from its initial alignment state to an orthogonal alignment state.
  • the step of changing the electric field parameters e.g. switching to low frequency
  • the parameters of the perpendicular electric field enable a flexoelectric coupling so that the helical axis tends to remain aligned perpendicular to the applied field.
  • the step of changing the electric field parameter(s) e.g. switching to high frequency
  • the LC material is then switched from its initial alignment state to a lower energy state with its helical axis aligned parallel to the applied electric field.
  • the step of changing one or more parameters of the electric field may comprise changing the parameters) one or more times.
  • the frequency of the applied electric field may be increased/decreased to switch the LC material from one alignment state to another, and then subsequently decreased/increased to switch the LC material back between the alignment states.
  • parameter(s) other than frequency may be changed back and forth in a similar manner. This may be repeated e.g. at regular or irregular intervals to provide for repeated switching of the LC material between different alignment states in which the helical axis is aligned either perpendicular or parallel to the applied electric field.
  • the invention has been described in the context of a liquid crystal material having constant material properties, which is electrically switched between different alignment states.
  • another mechanism may be used to enable or suppress the flexoelectric effect, in addition to electrical switching or even as an alternative method of control.
  • the flexoelectric response of the cholesteric LC material may be changed so as to adjust the contribution Sfi eX o from flexoelectric polarisation in the material.
  • the method further comprises changing one or more parameters of the liquid crystal material, so as to enable or suppress flexoelectric coupling and thereby switch the helical axis between perpendicular or parallel alignment with an applied electric field.
  • the present invention provides a method of controlling a helicoidal liquid crystal material
  • ⁇ is the dielectric constant parallel to the helical axis of the liquid crystal material and ⁇ is the dielectric constant perpendicular to the helical axis of the liquid crystal material, such that in a state without flexoelectric coupling the material has a lowest energy alignment state in which the helical axis is aligned parallel to an applied electric field;
  • liquid crystal material can undergo flexoelectric coupling with an applied electric field as a result of an effective dielectric constant ⁇ perpendicular to the helical axis given by:
  • Seffective Sflexo + + ⁇ _
  • this provides an alternative mechanism for switching on and off the flexoelectric interaction and therefore changing the effective dielectric constant so as to dictate whether the helical axis tends to align with the applied electric field or not.
  • This may be achieved by changing the dielectric and/or flexoelectric response of the material.
  • Changing one or more parameters of the liquid crystal material may comprise changing one or more parameters that relate to the material's flexoelectric response such as the flexoelectric coefficients ( ⁇ or e 3 ), or the elastic coefficients e.g. for splay, twist or bend (K 1 t K 2 or K 3 ).
  • changing one or more parameters of the liquid crystal material may comprise changing one or more dielectric properties of the material such as the dielectric constants ⁇ ,, and/or ⁇ .
  • changing one or more parameters of the liquid crystal material may comprise changing the pitch of the helicoidal structure.
  • the pitch could be varied using optical addressing of photosensitive chiral dopants, or with temperature, or by another means.
  • a molecular structure or configuration of the liquid crystal molecules could be changed.
  • a light-induced trans-cis change in molecular configuration could be used to change the flexoelectric properties, or helicoidal pitch, or another material property, of the liquid crystal material such that switching takes place.
  • light for example sunlight, could be used to induce a change in material properties that results in switching.
  • the liquid crystal material may include dichroic absorbing dyes. This may allow switchable polarising elements to be engineered based on the switching mechanism of changing one or more material parameter(s).
  • changing one or more parameters of the liquid crystal material may comprise adding additional species and/or particles to the liquid crystal material to adjust its dielectric properties.
  • particles in the liquid crystal material such as, but not limited to, nano-particles, nano-tubes, metallic nano-beads, etc.
  • the inclusion of "bent" nano-tubes could potentially enhance the flexoelectric polarisation e.g. at lower frequencies of the applied field, but this effect may not be present e.g. at higher frequencies.
  • This effect is not limited to these particular particles, but may be achieved through the inclusion of a number of types of particles and other molecular species and possibly mixtures of particles and/or molecules with the liquid crystal material.
  • the incorporation of certain particles or other species in the liquid crystal material could be used to cancel the flexoelectric polarisation e.g. at lower frequencies. Then the lower frequencies would show the smaller flexoelectric polarisation and hence smaller dielectric constant perpendicular to the helicoidal axis, while the higher frequencies would show the larger flexoelectric polarisation and hence larger dielectric constant perpendicular to the helical axis. This could be used to invert the switching scheme.
  • the step of changing material parameter(s) to effect switching may be used alone, or in combination with electrical switching as described above in relation to the first aspect of the invention.
  • the step of applying the electric field may enable a flexoelectric coupling or not. For example, if a high frequency electric field is applied then the material may naturally have a lowest energy alignment state in which the helical axis is aligned parallel to the applied electric field. On the other hand, if a low frequency electric field is applied then a flexoelectric coupling may be enabled that causes the helical axis to align perpendicular to the applied field.
  • the step of applying the electric field may include selecting the parameters) e.g. frequency of the electric field so that the material is switched from its initial alignment state to a different, lower energy state in which the helical axis is aligned either perpendicular or parallel to the applied electric field.
  • the parameter(s) of the applied electric field may alternatively be selected so that the material remains in its initial alignment state until one or more parameters of the liquid crystal material are changed so as to switch the alignment of the helical axis in the LC material from one alignment state to another alignment state, or vice versa.
  • a liquid crystal material can be switched between different alignment states by changing its effective dielectric constant, and hence the way it couples with an applied electric field, without necessarily changing the amplitude of the electric field.
  • the method may further comprise changing the amplitude of the applied electric field. This could be used, for example, to provide additional switching steps at different times.
  • the step of changing one or more parameters of the electric field, or changing one or more parameters of the liquid crystal material may switch the LC material between a Grandjean state and a Uniform Lying Helix (ULH) or focal conic state, or vice versa.
  • UDH Uniform Lying Helix
  • the switching mechanism applies to any states which can be accessed by enabling or disabling the flexoelectric coupling.
  • a liquid crystal device comprising at least one layer of a helicoidal liquid crystal material between surface plates, wherein the liquid crystal material has a negative dielectric anisotropy ⁇ satisfying:
  • ⁇ is the dielectric constant parallel to the helical axis of the liquid crystal material and ⁇ is the dielectric constant perpendicular to the helical axis of the liquid crystal material, such that a state without flexoelectric coupling the material has a lowest energy alignment state in which the helical axis is aligned parallel to an applied electric field;
  • liquid crystal material can undergo flexoelectric coupling with an applied electric field as a result of an effective dielectric constant e e ⁇ ec a e perpendicular to the helical axis given by:
  • one or more parameters of the applied electric field, or one or more parameters of the liquid crystal material are changed so as to enable or suppress said flexoelectric coupling and thereby switch the material to a second, different, alignment state in which the helical axis is aligned orthogonal to the initial direction relative to the surface plates.
  • the electric field is applied parallel to the surface plates (i.e. in-plane). If flexoelectric coupling is enabled then, in the first device state, the helical axis is aligned perpendicular to the applied electric field in the material's first alignment state.
  • the first alignment state may be the Grandjean state in which the helical axis is oriented perpendicular to the surface plates (in the bulk of the liquid crystal material).
  • the liquid crystal material will change to a lower energy state in which its helical axis is aligned parallel to the applied electric field.
  • the second alignment state may be the Uniform Lying Helix (ULH) or focal conic state with the helical axis oriented parallel to the surface plates (in the bulk of the liquid crystal material).
  • the first and second alignment states may be swapped if the applied electric field does suppress flexoelectric coupling in the first device state (e.g. a high frequency electric field).
  • the electric field is applied perpendicular to the surface plates (i.e. out-of-plane). If flexoelectric coupling is enabled then, in the first device state, the helical axis is aligned perpendicular to the applied electric field in the material's first alignment state. Accordingly the first alignment state may be the Uniform Lying Helix (ULH) or focal conic state with the helical axis oriented parallel to the surface plates (in the bulk of the liquid crystal material).
  • UDH Uniform Lying Helix
  • the liquid crystal material will change to a lower energy state in which its helical axis is aligned parallel to the applied electric field.
  • the second alignment state may be the Grandjean state in which the helical axis is oriented perpendicular to the surface plates (in the bulk of the liquid crystal material).
  • the first and second alignment states may be swapped if the applied electric field does suppress flexoelectric coupling in the first device state (e.g. a high frequency electric field). It will be understood from the discussion above that, when the electric field is applied to create the first device state, this may also change the alignment state of the liquid crystal material.
  • the material may be in an initial alignment state, in the absence of an applied electric field, in which the helical axis is oriented perpendicular to the surface plates i.e. the so-called Grandjean state.
  • Applying an electric field to the device may then switch the material from this initial alignment state to a first alignment state that is the focal conic or ULH state.
  • a first alignment state that is the focal conic or ULH state.
  • the material can then be switched to a second alignment state that is back to the Grandjean state.
  • a complete cycle of device states may therefore be achieved.
  • the device could also be driven in reverse.
  • the material may be in an initial alignment state, in the absence of an applied electric field, in which the helical axis is oriented parallel to the surface plates i.e. the so-called Uniform Lying Helix (ULH) or focal conic state.
  • UDH Uniform Lying Helix
  • Applying an electric field to the device may then switch the material from this initial alignment state to a first alignment state that is the Grandjean state.
  • Changing one or more parameters of the applied electric field, or one or more parameters of the liquid crystal material may then switch the material to a second alignment state that is back to the ULH or focal conic state.
  • a complete cycle of device states may therefore be achieved.
  • the device could also be driven in reverse.
  • the liquid crystal device may be any device that can take advantage of controlled switching between alignment states of the LC material in which the helical axis is perpendicular or parallel to an applied electric field.
  • the device may be an optical device, for example an optical display device.
  • the Grandjean geometry has been proposed for ultra-fast transmissive displays, and has also been commercialised as a reflective technology.
  • the focal conic texture can be weakly scattering, and has been suggested for use in reflective display technology, including bistable modes.
  • the ULH has long been developed for use as a transmissive display technology, having major advantages over existing technology, including sub-millisecond switching times and the possibility of having an in-plane rotation of the optic axis without the need for complicated interdigitated electrode structures.
  • One potential application is in creating a dual- mode display, which can be switched from a transmissive display (exploiting the ULH switching), to a reflective bi-stable display (exploiting Grandjean and focal conic or ULH textures) by addressing at different frequencies.
  • a further potential application is in creating a reflective cholesteric display technology, which can be switched from a reflecting state to a non-reflecting state by addressing at different frequencies.
  • the liquid crystal device is a reflective display device.
  • Such a bi-stable device can enable the selection of focal conic or Grandjean states using appropriate driving frequencies.
  • the focal conic state When used in front of a dark light-absorbing material, the focal conic state provides a dark, non-reflective state.
  • the cross-over frequency may be adjusted dependent on the pitch of the material.
  • These devices may allow a much greater flexibility, in comparison with dual-frequency materials, in the choice of other parameters, including surface alignment condition, driving scheme and material parameters. Unlike specially engineered dual-frequency materials, it can be possible to switch between states at frequencies as low as 200 Hz rather than 30 kHz as typically required. Furthermore the LC material may not require polymer network stabilisation.
  • the device may comprise a switchable diffractive structure.
  • the helicoidal pitch of the material may be appropriately chosen so that one of the alignment states e.g. the ULH state acts as a period structure leading to diffraction, whereas the other alignment state e.g. the Grandjean state does not result in diffraction.
  • the device may then be switched between these two alignment states in order to switch between a diffractive and non-diffractive effect.
  • the device may include one or more emissive material(s) and take advantage of the switching mechanism to influence the resulting emissive properties.
  • the device can form a liquid crystal based lasing system if appropriate emissive materials are included. Switching between the ULH and Grandjean states may then allow switching between edge-emitting and surface-emitting laser systems. There may be many other switchable emissive systems in which the device could be employed.
  • the device is provided as part of a lens or other optical element. Switching between device states could be exploited in order to engineer novel optical elements.
  • the switchable device may be used within integrated optics systems. For example, the possibility of switching between alignment states could be used to engineer a switchable Bragg-type reflector in an integrated optical system (such as, but not necessarily limited to, a wave guide) in order to allow switchable wavelength selection etc. There may be many other possible applications within integrated optics systems.
  • the device could be used as the basis of switchable polarisation filters and related optical elements.
  • the Grandjean state could be arranged to act as a circular polariser (through selective reflection). Switching from this alignment state to a ULH state would allow switching of the circular polariser.
  • combining the switchable device together with appropriate optical wave plates may allow a switchable linear polariser to be engineered.
  • the liquid crystal material may comprise a polymer dispersed system, in which switching between alignment states alters the refractive index mismatch to control scattering, for example, or to produce another optical effect.
  • Liquid crystal materials that are immiscible or otherwise prevented from mixing, e.g. through a polymer dispersed system, could have a different helical pitch, chirality or other properties. This could be exploited in a single device for increased functionality, e.g. selection of reflected colour(s) or to produce greater reflectivity.
  • one or more parameters of the liquid crystal material may be altered through the absorption of external particles or chemical entities that may be present in the ambient environment e.g. surrounding a liquid crystal device. Such a device could therefore find use as a detector.
  • the liquid crystal device may comprise more than one layer of a cholesteric liquid crystal material, or multiple layers comprising a cholesteric liquid crystal material layer together with one or more layers of a non-cholesteric liquid crystal material.
  • the multiple layers could be addressed by the same electric field, e.g. in order to achieve a brighter reflectance or additional functionality, such as wavelength or reflective selectivity.
  • a three-layer device maybe addressed by changing the driving frequency of an applied electric field in order to switch the layers independently to select a desired reflectivity spectrum or colour(s).
  • the multi-layer device could also be addressed by using multiple electrode arrangements, e.g. by different electrodes for each layer.
  • the liquid crystal device may comprise one or more polarisers, compensating filters, transmission windows, or the like, as desirable to take advantage of the switching between alignment states e.g. to produce a controllable display.
  • the LC device may take the form of a window that reflects a particular frequency of electromagnetic radiation, e.g. infrared or ultraviolet light, but whose reflectivity at these wavelengths can be controlled by switching between alignment states.
  • the Grandjean state also known as the Uniform Standing Helix (USH) state, is one in which the helical axis in the bulk is aligned perpendicular to the bounding surfaces of a liquid crystal device. This state has a range of interesting optical properties depending on whether the helix pitch is substantially less than the wavelength of light, similar to the wavelength of light, or substantially greater than the wavelength of light.
  • Another distinct alignment state is one in which the helical axis in the bulk is aligned generally parallel with the bounding surfaces of a liquid crystal device (again there may be a variety of surface transition regions present depending of the nature of the surface alignment used).
  • This state has a number of sub-forms, but two key ones mentioned above are where the helical axis has no preferential direction, leading to what is commonly called the focal conic state, and one where there is a well-defined orientation of the axis in the bulk, leading to what is commonly called the Uniform Lying Helix (ULH) state.
  • the focal conic state or ULH state may be interchanged with any other alignment state in which the helical axis in the bulk is aligned generally parallel, including mixtures of these two states or intermediary states.
  • a liquid crystal (LC) material is one existing in a liquid crystalline phase, usually defined as having a significant anisotropic orientational structure and short-range orientational order while still having an ability to flow.
  • a large number of chemical compounds have been identified as having a liquid crystalline phase.
  • the cholesteric liquid crystal material may comprise one or more different liquid crystal materials, for example a mixture of liquid crystal materials.
  • a cholesteric material also known as twisted nematic or chiral nematic
  • the liquid crystal structure must have an overall lack of axial symmetry due to chirality i.e. a helicoidal structure.
  • the helicity may be obtained through the use of chiral materials, or chiral doping, or by other means such as the use of a polymer network, or by any other means.
  • the LC material may comprise one or more nematic materials, that are either chiral or achiral.
  • the LC permittivity can therefore be measured by measuring the cell capacitance and comparing it to the empty cell capacitance to eliminate A and d.
  • the other requirement of the LC material is that it provides a flexoelectric contribution Sfiexo to the dielectric properties which is sufficient to change which alignment state is the lowest energy state. In practice this may result from a high flexoelectric coefficient e-, - e 3 and/or, in some situations, a high flexoelectric coefficient ei + e 3 .
  • LC materials may be found, or tailored, to have a negative dielectric anisotropy and the necessary flexoelectric response.
  • the skilled person will be able to select a suitable LC material by measuring its dielectric anisotropy and flexoelectric response.
  • An exemplary material having suitable properties is a liquid crystal mixture A comprising 60% by weight MDA-1245 and 40% by weight MLC-7029 (both obtained from Merck).
  • MDA-1245 is a highly chiral LC material.
  • MLC-7029 is an achiral nematic LC material having a negative dielectric anisotropy ⁇ of -3.7.
  • MLC-7029 gives the material an overall negative dielectric anisotropy ⁇ while MDA-1245 provides a flexoelectric contribution Sfi eX o to the dielectric properties that is sufficient to change which orientation of the helicoidal axis corresponds to the lowest energy state when the field frequency (or another parameter) is altered to enable or suppress the flexoelectric interaction.
  • the overall dielectric anisotropy of mixture A was determined from capacitance data to be -0.5 at 40 °C.
  • the liquid crystal mixture A was capillary filled while in the isotropic phase into a cell comprising two glass substrates with anti-parallel aligned polyimide alignment surfaces.
  • the cell gap between glass substrates is of thickness 5pm, and there is indium-tin-oxide on both substrate surfaces in order to apply a transverse field to the liquid crystal.
  • a 2 kHz electric field of 20 was applied transverse to the liquid crystal film.
  • the initial alignment state of the device, shown in Figure 1 a is a Grandjean texture. If the electric field is removed and the device is left (e.g. for 30 s) then the Grandjean texture is seen to remain, showing that this initial alignment state is stable over long periods. From the Grandjean state there are two other alignment states that are easily accessible.
  • the cell can be driven in approximately 100 ms back to the Grandjean state by changing the frequency of the applied electric field from 100 Hz or 300 Hz to 2 kHz.
  • Figure 1d shows the Grandjean texture accessed in the same cell by the application of a 2 kHz driving field.
  • the series of optical micrographs in Figures 1a to 1d therefore illustrates a complete cycle of state switching from Grandjean to ULH or focal conic and back again to Grandjean, by using appropriate driving frequencies at each stage.
  • Figure 2 shows the capacitance of the cell as a function of frequency whilst in the Grandjean i.e. Uniform Standing Helix (USH) state, the Uniform Lying Helix (ULH) state, and the focal conic state.
  • the Grandjean capacitance is roughly independent of frequency, until frequencies higher than 1000 Hz.
  • the ULH and focal conic states exhibit a larger capacitance (and therefore dielectric magnitude) at 100 Hz and a smaller capacitance at larger frequencies compared to the Grandjean state.
  • Figure 3 shows the measured capacitance of the 5 ⁇ cell as a function of frequency for both the ULH and Grandjean states, together with the appropriate fits to the data from analytical relaxation models.
  • the amplitude of the signal used for the capacitance measurement is 100 mV, which is not large enough to switch the state of the cell.
  • Fitting the ULH capacitance data to an analytical model for the dielectric constant of a liquid crystal material provides the following values for a cell area of 1 cm 2 :
  • Figure 4 shows the voltage signal (before amplification by 10X for application to the cell) in the top plot, and the optical response of the device whilst in the ULH state in the bottom plot.
  • the electro-optic response was taken using a photodiode attached to an optical polarising microscope.
  • the polariser and analyser are set at 90°, and white light is incident on the device.
  • the optic axis of the ULH state when there is no field applied is at 22.5° to the polariser axis.
  • the response is typical of flexoelectrooptic switching in the ULH state, and shows a characteristic switching time (the time for the transmission to reach within 1/e of the new value after a field polarity inversion) of approximately 333 ⁇ (NB. this is not the rise time shown in Fig. 4, which does not represent the 1/e time).
  • the capacitance data and electro-optic measurements have shown that there is a relaxation in the relative permittivity of material A, that this relaxation is due to the suppression in the flexoelectric switching at high frequencies, and that this allows a change in the lowest energy state of the liquid crystal material at a cross-over frequency.
  • the device can therefore switch between ULH and Grandjean states simply by changing the frequency of the applied electric field.
  • a liquid crystal mixture B comprises 40% by weight of MLC-7029 (obtained from Merck) and 60% by weight of MDA-10-4409 (obtained from Merck).
  • MLC-7029 is a nematic having negative dielectric anisotropy at room temperature, while MDA-10-4409 is a high flexoelectricity, bimesogenic liquid crystal.
  • Mixture B was doped with small amounts of high-twisting-power chiral additive R501 1 , in order to obtain a range of desired pitch lengths.
  • Two samples of mixture B were filled into planar-aligned cells and allowed to form the Grandjean texture. The two samples had Bragg reflection maxima, as measured on a spectrometer, centred on 480 and 590 nm.
  • Grandjean state to be accessed via an elastic interaction with the surface we have chosen to demonstrate the technology with homeotropic anchoring, which greatly increases the viewing angle without the need for a polymer network.
  • the device On application of a 5 kHz, 10 V rms prrf 1 signal, the device is driven into the Grandjean texture, which is stable for long periods once the field is removed.
  • Capacitance is plotted as a function of frequency (using the 100 mV test voltage) for cells filled with the two samples of mixture B while in stable focal conic and Grandjean states. At frequencies below the cross-over frequency, for a given sample, the focal conic state has a larger capacitance than the Grandjean state. At frequencies beyond the relaxation, the focal conic capacitance is lower than the Grandjean.
  • a larger capacitance implies a larger effective dielectric permittivity, and the larger component of the permittivity will have a tendency to reorient parallel to the applied field, in order to minimise the electric potential energy.
  • the cross-over frequency is pitch dependent, the ability to switch between states is not affected by pitch variation. It can be seen that the cross-over frequency for material B is between 200 and 400 Hz, orders of magnitude smaller than the ⁇ réelle relaxation frequency in specially engineered dual-frequency materials previously used in this context.
  • the switching time may be affected by the bimesogenic component, which in mixture B had a very large viscosity. Switching times may be improved by techniques such as the use of polymer networks or the exploitation of Helfrich instabilities.
  • a liquid crystal material was prepared comprising a mixture of 60% by weight MDA-1245 and 40% by weight BL-087 (obtained from Merck), which is an achiral nematic LC material with a positive dielectric anisotropy.
  • Figure 7 shows the measured capacitance of the cell as a function of frequency.
  • MDA-1245 is a large flexoelectric contribution at low frequencies in the Uniform Lying Helix (ULH) state
  • UDH Uniform Lying Helix
  • the positive dielectric anisotropy of BL-087 means that the Grandjean state always has a lower capacitance than the ULH state. Without an overall negative value for the dielectric anisotropy, there is no possibility of switching between alignment states because there is no change in which state has the lowest energy.
  • a liquid crystal material was prepared comprising MLC-7029 ( ⁇ of -3.7) mixed with 2.1% by weight of R-5011 (obtained from Merck), a chiral additive.
  • the resulting LC material is cholesteric with an overall negative dielectric anisotropy.
  • Figure 8 shows the measured capacitance of the cell as a function of frequency. This material does not provide a sufficient contribution Sfi eX o from flexoelectric polarisation in the material to be able to lift the capacitance of the ULH state higher than the Grandjean state at low frequencies. Hence there is no possibility of switching between the alignment states of this material by changing the frequency of the applied electric field.

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Abstract

La présente invention porte sur un procédé de commande de matière de cristaux liquides hélicoïdale dans lequel la matière de cristaux liquides a une anisotropie diélectrique négative Δε satisfaisant Δε = εΜ - εχ < 0, εΜ étant la constante diélectrique parallèle à l'axe hélicoïdal de la matière de cristaux liquides et ε± étant la constante diélectrique perpendiculaire à l'axe hélicoïdal de la matière de cristaux liquides, de telle sorte que dans un état sans couplage flexo-électrique la matière a un état d'alignement à énergie la plus faible dans lequel l'axe hélicoïdal est aligné parallèle à un champ électrique appliqué. La matière de cristaux liquides peut subir un couplage flexo-électrique avec un champ électrique appliqué par suite d'une constante diélectrique effective εeffective perpendiculaire à l'axe hélicoïdal donné par εeffective =εflexo + (ε,, + ε⊥)/2 > ε⊥, εflexo étant une contribution d'une polarisation flexo-électrique dans la matière, de telle sorte que dans un état avec le couplage flexo-électrique la matière a un état d'alignement à énergie la plus faible dans lequel l'axe hélicoïdal est aligné perpendiculaire à un champ électrique appliqué. Le procédé comprend l'application d'un champ électrique à la matière et le changement d'un ou plusieurs paramètres du champ électrique de manière à permettre ou supprimer ledit couplage flexo-électrique et ainsi commuter la matière entre des états d'alignement à énergie la plus faible dans lesquels l'axe hélicoïdal est aligné soit perpendiculaire, soit parallèle au champ électrique appliqué.
PCT/GB2014/050828 2013-03-18 2014-03-17 Commutation d'état de cristaux liquides Ceased WO2014147380A1 (fr)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107850812A (zh) * 2015-07-02 2018-03-27 默克专利股份有限公司 制备光调制元件的方法
EP4579328A1 (fr) * 2023-12-27 2025-07-02 AGP Worldwide Operations GmbH Vitrage commutable

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006003441A1 (fr) * 2004-07-02 2006-01-12 Cambridge Enterprise Limited Dispositif flexoelectro-optique a cristaux liquides
US20060061720A1 (en) * 2004-09-23 2006-03-23 Wei-Chou Chen Flexoelectric liquid crystal displays

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006003441A1 (fr) * 2004-07-02 2006-01-12 Cambridge Enterprise Limited Dispositif flexoelectro-optique a cristaux liquides
US20060061720A1 (en) * 2004-09-23 2006-03-23 Wei-Chou Chen Flexoelectric liquid crystal displays

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107850812A (zh) * 2015-07-02 2018-03-27 默克专利股份有限公司 制备光调制元件的方法
EP4579328A1 (fr) * 2023-12-27 2025-07-02 AGP Worldwide Operations GmbH Vitrage commutable

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