WO2014065281A1 - 円筒状ケース及び円筒状ケースの製造方法 - Google Patents
円筒状ケース及び円筒状ケースの製造方法 Download PDFInfo
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- WO2014065281A1 WO2014065281A1 PCT/JP2013/078586 JP2013078586W WO2014065281A1 WO 2014065281 A1 WO2014065281 A1 WO 2014065281A1 JP 2013078586 W JP2013078586 W JP 2013078586W WO 2014065281 A1 WO2014065281 A1 WO 2014065281A1
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- groove
- biaxial
- mandrel
- case
- case body
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/24—Casings; Casing parts, e.g. diaphragms, casing fastenings
- F01D25/243—Flange connections; Bolting arrangements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/30—Mounting, exchanging or centering
- B29C33/301—Modular mould systems [MMS], i.e. moulds built up by stacking mould elements, e.g. plates, blocks, rods
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
- B29C70/22—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
- B29C70/22—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
- B29C70/222—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure the structure being shaped to form a three dimensional configuration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
- B29C70/24—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least three directions forming a three dimensional structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/44—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
- B29C70/446—Moulding structures having an axis of symmetry or at least one channel, e.g. tubular structures, frames
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64D—EQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENT OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
- B64D29/00—Power-plant nacelles, fairings or cowlings
- B64D29/02—Power-plant nacelles, fairings or cowlings associated with wings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D21/00—Shutting-down of machines or engines, e.g. in emergency; Regulating, controlling, or safety means not otherwise provided for
- F01D21/04—Shutting-down of machines or engines, e.g. in emergency; Regulating, controlling, or safety means not otherwise provided for responsive to undesired position of rotor relative to stator or to breaking-off of a part of the rotor, e.g. indicating such position
- F01D21/045—Shutting-down of machines or engines, e.g. in emergency; Regulating, controlling, or safety means not otherwise provided for responsive to undesired position of rotor relative to stator or to breaking-off of a part of the rotor, e.g. indicating such position special arrangements in stators or in rotors dealing with breaking-off of part of rotor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/24—Casings; Casing parts, e.g. diaphragms, casing fastenings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/10—Thermosetting resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2713/00—Use of textile products or fabrics for preformed parts, e.g. for inserts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2022/00—Hollow articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
- B29L2023/003—Tubular articles having irregular or rough surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/748—Machines or parts thereof not otherwise provided for
- B29L2031/7504—Turbines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/772—Articles characterised by their shape and not otherwise provided for
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2220/00—Application
- F05D2220/30—Application in turbines
- F05D2220/36—Application in turbines specially adapted for the fan of turbofan engines
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
- F05D2300/6034—Orientation of fibres, weaving, ply angle
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
Definitions
- the present invention relates to, for example, a cylindrical case used as a fan case that covers a fan blade of an aircraft jet engine and a method for manufacturing the cylindrical case.
- a fan case that covers the fan blades of the aircraft jet engine described above is required to be lightweight and to have high strength.
- the fan case is reinforced as a material. Attempts have been made to apply composite materials of fibers and thermosetting resins.
- annular outward flange that is usually connected to the engine nacelle is integrally formed at the end of the case body that covers the fan blades. Therefore, when a composite material of reinforcing fiber such as carbon fiber and thermosetting resin such as epoxy resin is used as a material, both the case body and the annular flange include a plurality of fabrics including reinforcing fibers such as carbon fiber. It will have a fabric layer.
- the fabric When manufacturing the above fan case (cylindrical case) using a composite material of reinforcing fiber and thermosetting resin, the fabric is placed on the molding surface of the mandrel while rotating the cylindrical mandrel around its axis.
- the laminate of the woven fabric layer is formed by winding the laminate, and the laminate is heated to cure the thermosetting resin impregnated in advance in the laminate.
- the reinforcing fiber has an inclination angle of 0 to 10 ° with respect to the circumferential direction between the plurality of fabric layers.
- the flexibility of the fabric contained in the fabric layer is impaired, and therefore, when forming the laminate, it corresponds to the root of the outward flange that is bent.
- wrinkles and fibers meander in the part, and the strength and rigidity of the outward flange may be reduced.
- the strength and rigidity of the entire fan case cannot be increased, and it has been a conventional problem to solve this problem.
- the fan case includes a composite material of a reinforcing fiber and a thermosetting resin as a material, and a fan case having an outward annular groove and an annular flange.
- an object of the present invention is to provide a cylindrical case and a method for manufacturing the cylindrical case that can ensure high strength and rigidity of the entire case.
- the present invention provides a cylindrical case made of a composite material in which a reinforcing fiber is impregnated with a thermosetting resin, and includes a cylindrical case main body and an end portion of the case main body.
- the groove wall constituting the groove includes a plurality of biaxial fabric layers that are continuous with the plurality of biaxial fabric layers on the peripheral wall of the case body, and an orientation angle of ⁇ 15 to 75 ° with respect to the axial direction of the case body.
- Shaft reinforcing fiber And a plurality of triaxial fabric layers including a triaxial fabric of a non-crimp structure composed of a total of three axes of uniaxial reinforcing fiber bands having an orientation angle of 0 ° with respect to the axial direction of the case body. It is set as the structure currently formed.
- each of the front and back surfaces of the peripheral wall of the case body and the groove wall of the groove is covered with a protective film made of a composite material in which a reinforcing fiber is impregnated with a thermosetting resin.
- the groove wall constituting the groove is covered with a cover made of Ti alloy or Ni alloy, and used as a fan case that covers a fan blade of an aircraft jet engine.
- the present invention is a method for manufacturing the cylindrical case described above, wherein the cylindrical mandrel having an outer peripheral surface as a molding surface is rotated around its axis, and the non-crimp structure comprising the biaxial reinforcing fiber bands is used.
- the triaxial woven fabric having a non-crimp structure composed of the triaxial reinforcing fiber bands is wound around a molding portion of the groove on the molding surface of the mandrel.
- a heating step of curing the thermosetting resin impregnated in each reinforcing fiber of the woven fabric layer by heating the laminated body in which the portion is molded is adopted.
- the present invention is a method of manufacturing a cylindrical case as described above, wherein the cylindrical mandrel whose outer peripheral surface is a molding surface of the case main body is rotated around its axis while the non-crimp comprising the biaxial reinforcing fiber band.
- the two-axis of the non-crimp structure composed of the two-axis reinforcing fiber bands A biaxial fabric layer forming step of winding an object on the groove forming surface of the groove mandrel to form the biaxial fabric layer, and the triaxial reinforcement while rotating the groove mandrel around its axis
- a groove forming step for forming the groove laminate into a portion corresponding to the groove by a groove forming die and the groove mandrel, and forming as a portion corresponding to the groove by this groove forming step An integrated step of integrating the grooved laminated body and a laminated body molded as a portion corresponding to the case main body, and a portion corresponding to the case main body integrated with each other by the integration step in front
- thermosetting resin for example, polyester resin, epoxy resin, vinyl ester resin, phenol resin, bismaleimide resin, oxazoline resin, melamine resin can be used as the matrix. it can.
- the peripheral wall constituting the case main body includes a plurality of biaxial fabric layers including a biaxial woven fabric made of a reinforcing fiber band such as carbon fiber, and carbon fibers along the circumferential direction of the case main body. Since it is formed by alternately laminating a plurality of roving layers including rovings formed by bundling reinforcing fibers, the strength and rigidity of the entire cylindrical case are ensured.
- the groove wall constituting the groove is formed of a plurality of biaxial fabric layers that are continuous with the peripheral wall of the case main body, and one of the reinforcing fiber bands in the triaxial direction. Since it is formed by alternately laminating a plurality of triaxial fabric layers with the orientation angle aligned with the axial direction of the case body, the axial center of the groove wall is maintained while maintaining the strength and rigidity of the entire cylindrical case. The strength and rigidity against the load in the direction can be improved.
- a triaxial fabric layer in which the orientation angle of one reinforcing fiber band is aligned with the axial direction of the case body is adopted for the groove wall of the groove, so that the groove wall can be expanded in the circumferential direction.
- the grooves are formed without causing wrinkles or meandering of the fibers, and automatic forming is possible in order to save labor and shorten the construction period.
- FIG. 1 is a schematic cross-sectional explanatory diagram of an aircraft jet engine employing a fan case according to an embodiment of the present invention. It is a partial expanded sectional explanatory view of the fan case of FIG.
- FIG. 3 is a partial plan view illustrating a state in which a fabric is laminated in a portion F of FIG.
- FIG. 3 is a partial plan view illustrating a laminated state of a woven fabric and a roving in a portion C of FIG.
- FIG. 3 is a partial plan view illustrating a state in which a woven fabric in a portion R in FIG. 2 is partially broken.
- FIG. 6 is a first process explanatory diagram illustrating a situation at the start of manufacturing in the method for manufacturing the fan case of FIG.
- FIG. 8 is a third process explanatory diagram of a molding process in the fan case manufacturing method of FIG. 1.
- FIG. 8 is a fourth process explanatory diagram of a molding process in the fan case manufacturing method of FIG. 1.
- FIG. 10 is a fifth process explanatory diagram of a molding process in the fan case manufacturing method of FIG. 1. It is 6th process explanatory drawing of the formation process in the manufacturing method of the fan case of FIG.
- FIG. 10 is an explanatory diagram of a seventh process of the molding process in the fan case manufacturing method of FIG.
- FIG. 1 to 5F show an embodiment of a cylindrical case according to the present invention.
- a case where the cylindrical case according to the present invention is a fan case of an aircraft jet engine will be described as an example. explain.
- an aircraft jet engine 1 sends air taken from the front (left side in the figure) to a compressor 3 by a fan 2 having a plurality of fan blades, and is compressed into air compressed by the compressor 3.
- Fuel is injected and burned in the combustion chamber 4, and the high-pressure turbine 5 and the low-pressure turbine 6 are rotated by the expansion of the high-temperature gas generated thereby.
- a fan case 9 that covers a plurality of fan blades of the fan 2 is made of a composite material in which a reinforcing fiber such as carbon fiber is impregnated with a thermosetting resin such as an epoxy resin, and includes a case body 10 having a cylindrical shape. Yes.
- An outward annular flange 11 that can be connected to the engine cowl 7 is formed at the front end portion (the left end portion in the figure) of the case body 10, and the rear end portion (the right end portion in the figure) opens to the centrifugal side.
- the groove 12 is formed in an annular shape, and for example, a metal inward flange of the engine nacelle 8 is fitted into the annular groove 12.
- the standing wall 11a constituting the annular flange 11 is formed by laminating a plurality of biaxial fabric layers 13, and the biaxial fabric layer 13 is formed as shown in FIG. 3A.
- a biaxial woven fabric 13A composed of reinforcing fiber bands 13a and 13b such as carbon fibers.
- the biaxial woven fabric 13A has a non-crimp structure composed of biaxial reinforcing fiber bands 13a and 13b, and the orientation angle of the biaxial reinforcing fiber bands 13a and 13b with respect to the axial center CL direction of the case body 10 is: In this embodiment, as shown in the enlarged circle of FIG. 3A, the orientation angle is set to ⁇ 45 °.
- part shown with the broken line in FIG. 3A is a stitch thread
- the absolute value of the orientation angle with respect to the axial center CL direction of the biaxial reinforcing fiber bands 13a and 13b is less than 15 °, it is not preferable because it is difficult to ensure the strength and rigidity of the fan case 9,
- the absolute value of the orientation angle of the biaxial reinforcing fiber bands 13a and 13b with respect to the axial center CL direction exceeds 75 °, wrinkles and fiber meandering may occur in the manufacturing process of the fan case 9. It is not preferable.
- the peripheral wall 10a constituting the case body 10 has a plurality of biaxial fabric layers 13 continuous with the standing wall 11a of the annular flange 11, that is, an orientation angle with respect to the direction of the axis CL is ⁇ 15 to 75 ° (in this embodiment, orientation)
- a plurality of biaxial fabric layers 13 including a biaxial fabric 13A composed of biaxial reinforcing fiber bands 13a and 13b set at an angle of ⁇ 45 °) and a plurality of roving layers 14 are alternately laminated.
- the roving layer 14 includes a roving (fiber bundle) 14A formed by bundling reinforcing fibers such as carbon fibers along the circumferential direction of the case body 10 as shown in FIG. 3B.
- the inclination angle of the roving 14A with respect to the circumferential direction of the case body 10 exceeds 15 °, it is difficult to ensure the strength and rigidity in the manufacturing process of the fan case 9, so the inclination angle should be 15 ° or less. Is desirable.
- main body 10 is required to prevent the front end side of the fan blade that breaks and scatters from penetrating the peripheral wall 10a when, for example, a bird strike is encountered.
- a plurality of fabric layers (not shown) including reinforcing fiber bands whose orientation angle with respect to the axial center CL direction is set to 30 ° are laminated.
- the groove wall 12a constituting the groove 12 is a plurality of biaxial fabric layers 13 continuing to the peripheral wall 10a of the case body 10, that is, biaxial reinforcement whose orientation angle with respect to the axial center CL direction is set to ⁇ 45 °.
- a plurality of biaxial fabric layers 13 including a biaxial fabric 13A composed of fiber bands 13a and 13b and a plurality of triaxial fabric layers 15 are alternately stacked.
- the triaxial fabric layer 15 is formed of a biaxial reinforcing fiber band having an orientation angle of ⁇ 15 to 75 ° (in this embodiment, an orientation angle of ⁇ 45 °) with respect to the axial center CL direction of the case body 10.
- 15A and 15b and a triaxial woven fabric 15A having a non-crimp structure including a total of three reinforced fiber bands 15a, 15b and 15c of a uniaxial reinforced fiber band 15c having an orientation angle of 0 ° with respect to the axial center CL direction of the case body 10 is included. It is out.
- the front and back surfaces of the peripheral wall 10a of the case body 10, the standing wall 11a of the annular flange 11, and the groove wall 12a of the groove 12 are all impregnated with a thermosetting resin such as epoxy resin in a reinforcing fiber such as glass fiber. It is covered with a protective film G (shown only in the enlarged ellipse in FIG. 2) made of the composite material.
- the protective film G serves as a cutting allowance during machining after the case body 10 is molded, and also serves as an electrolytic corrosion preventing material. In addition, it also serves as a protective layer when handling the finished fan case 9.
- case main body 10 and the annular flange 11 and between the case main body 10 and the groove 12 is made of a composite material obtained by impregnating a reinforcing fiber such as glass fiber with a thermosetting resin such as an epoxy resin.
- the protective layers 16 and 17 are arranged in a segmented state.
- covered with the protective composite material G as mentioned above is coat
- a method for manufacturing the fan case 9 will be described.
- a cylindrical mandrel 20C constituting the forming apparatus 20 a flange forming die 20F that can approach and separate from the front end portion (the left end portion in the drawing) of the mandrel 20C, and a mandrel A release agent L is sprayed on each molding surface of the groove forming die 20R that can approach and separate from the rear end portion (right end portion in the drawing) of 20C.
- the spacers S are set on the front and rear ends of the mandrel 20C, respectively.
- the biaxial fabric layer 13A is wound around the forming surface of the mandrel 20C while rotating the mandrel 20C and the spacer S around the axis CL thereof.
- a triaxial fabric layer forming step of forming the triaxial fabric layer 15 by wrapping the triaxial fabric 15A around the forming portion of the groove 12 on the molding surface of the mandrel 20C is repeated, and a laminate having a portion corresponding to the case body 10
- the body 9A is molded, and the surface of the laminate 9A is covered with the protective film G after these steps.
- the flange forming die 20F and the front end portion of the mandrel 20C are used to form a portion corresponding to the annular flange 11 at the front end portion of the laminate 9A, and the groove forming die 20R.
- a groove forming portion 20a located at the rear end portion of the mandrel 20C a flange groove forming step of forming a portion corresponding to the groove 12 at the rear end portion of the laminated body 9A is performed.
- the protective layers 16 and 17 are disposed between the case body equivalent portion and the flange equivalent portion of the laminate 9A and between the case body equivalent portion and the groove equivalent portion.
- 5D as shown in FIG. 5D, as a sixth step, the laminated body 9A on the molding apparatus 20 is covered with the bag B, and the laminated body 9A is heated and pressurized while evacuating the inside of the bag B. A heat and pressure step is performed to cure the thermosetting resin impregnated in the reinforcing fibers of the layers 13, 14, and 15.
- a laminated body 9B formed by curing the thermosetting resin impregnated in the reinforcing fibers of the layers 13, 14, and 15 is formed from the molding device 20.
- the laminated body 9 ⁇ / b> B released from the molding apparatus 20 is machined to finish the shape of the fan case 9, and then the groove Twelve groove walls 12a are covered with a cover 18 made of Ti alloy or Ni alloy.
- the standing wall 11a constituting the annular flange 11 includes a plurality of biaxial fabric layers 13 including only the biaxial fabric 13A composed of reinforcing fiber bundles 13a and 13b such as carbon fibers.
- the stretchability characteristic of the non-crimp structure is exhibited, and the annular flange 11 is formed without causing wrinkles or fiber meandering.
- the peripheral wall 10a constituting the case body 10 includes a plurality of biaxial fabric layers 13 including a biaxial fabric 13A including reinforcing fiber bands 13a and 13b such as carbon fibers, and the case body. 10 is formed by alternately laminating a plurality of roving layers 14 including rovings 14A formed by bundling reinforcing fibers such as carbon fibers along the circumferential direction, so that the strength and rigidity of the entire fan case 9 are ensured. It will be.
- the groove wall 12a that constitutes the groove 12 includes a plurality of biaxial fabric layers 13 that are continuous with the peripheral wall 10a of the case body 10, and triaxial reinforcing fiber bands 15a, 15b, 15c is formed by alternately laminating a plurality of triaxial fabric layers 15 formed by aligning the orientation angle of one reinforcing fiber band 15c with the axial center CL direction of the case body 10.
- the strength and rigidity against the load in the direction of the axis CL of the groove wall 12a can be improved while maintaining the strength and rigidity.
- the groove wall 12a of the groove 12 is used. In this way, the groove 12 can be formed without causing wrinkles or meandering of the fibers, and automatic molding for saving labor and shortening the construction period is allowed. Is possible.
- the biaxial fabric layer forming step, the roving layer forming step, and the triaxial fabric layer forming step are repeatedly performed to have a portion corresponding to the case body.
- a portion corresponding to the groove 12 is formed integrally with an end of a portion corresponding to the case main body 10 in the laminated body 9A.
- the biaxial fabric layer forming step and the roving layer forming step are repeated to form a layered body corresponding to the case body, and the biaxial fabric layer forming step and the triaxial fabric layer forming step are performed.
- the groove laminate is formed to form the groove laminate as a portion corresponding to the groove. age May be be integrated molded with a multilayer body.
- the case body 10 has a straight shape.
- the case body 10 of the fan case 9 has an axis CL.
- a mandrel 20C composed of a plurality of divided pieces 20P shown in FIG. 6B is employed.
- the configuration of the cylindrical case and the manufacturing method of the cylindrical case according to the present invention is not limited to the above-described embodiments.
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Abstract
Description
図1~図5Fは本発明に係る円筒状ケースの一実施例を示しており、この実施例では、本発明に係る筒状ケースが航空機用ジェットエンジンのファンケースである場合を例に挙げて説明する。
まず、図4Aに示すように、第1工程として、成形装置20を構成する筒状のマンドレル20C,このマンドレル20Cの前端部(図示左端部)に対して接近離間可能なフランジ成形型20F及びマンドレル20Cの後端部(図示右端部)に対して接近離間可能な溝成形型20Rの各成形面に離型剤Lを吹き付ける。
9 ファンケース
9A 加熱前の積層体
9B 加熱後の積層体
10 ケース本体
10a 周壁
12 溝
12a 溝壁
13 2軸織物層
13A 2軸織物
13a,13b 2軸の強化繊維帯
14 ロービング層
14A ロービング
15 3軸織物層
15A 3軸織物
15a,15b,15c 3軸の強化繊維帯
18 カバー
20C マンドレル
20R 溝成形型
20a 溝成形部
CL 軸心
G 保護膜
Claims (5)
- 強化繊維に熱硬化性樹脂を含浸させた複合材料から成る円筒状ケースであって、
円筒状を成すケース本体と、
前記ケース本体の端部において周方向に沿って環状に配置された遠心側に開口する溝を備え、
前記ケース本体を構成する周壁は、前記ケース本体の軸心方向に対する配向角が±15~75°の2軸の強化繊維帯から成るノンクリンプ構造の2軸織物を含む複数の2軸織物層と、前記ケース本体の周方向に沿う強化繊維を束ねて成るロービングを含む複数のロービング層とを交互に積層して形成され、
前記溝を構成する溝壁は、前記ケース本体の周壁における前記複数の2軸織物層に連続する複数の2軸織物層と、前記ケース本体の軸心方向に対する配向角が±15~75°の2軸の強化繊維帯及び前記ケース本体の軸心方向に対する配向角が0°の1軸の強化繊維帯の合計3軸の強化繊維帯から成るノンクリンプ構造の3軸織物を含む複数の3軸織物層とを交互に積層して形成されている円筒状ケース。 - 前記ケース本体の周壁及び前記溝の溝壁における各表裏面がいずれも強化繊維に熱硬化性樹脂を含浸させた複合材料から成る保護膜で被覆されている請求項1に記載の円筒状ケース。
- 前記溝を構成する溝壁がTi合金製又はNi合金製のカバーで被覆され、航空機用ジェットエンジンのファンブレードを覆うファンケースとして用いられる請求項1又は2に記載の円筒状ケース。
- 請求項1~3のいずれかに記載の円筒状ケースの製造方法であって、
外周面を成形面とした筒状のマンドレルをその軸心周りに回転させつつ、前記2軸の強化繊維帯から成るノンクリンプ構造の前記2軸織物を該マンドレルの前記成形面上に巻き付けて前記2軸織物層を形成する2軸織物層形成工程と、
前記マンドレルをその軸心周りに回転させつつ、前記強化繊維を束ねて成るロービングを該マンドレルの前記成形面における前記ケース本体の成形部位上に周方向に沿ってらせん状に巻き付けて前記ロービング層を形成するロービング層形成工程と、
前記マンドレルをその軸心周りに回転させつつ、前記3軸の強化繊維帯から成るノンクリンプ構造の前記3軸織物を該マンドレルの前記成形面における前記溝の成形部位上に巻き付けて前記3軸織物層を形成する3軸織物層形成工程と、を繰り返し行って前記ケース本体に相当する部分を有する積層体を成形した後、
溝成形型と前記マンドレルの端部に位置する溝成形部とにより、前記積層体における前記ケース本体に相当する部分の端部に前記溝に相当する部分を成形する溝成形工程と、
この溝成形工程によって前記ケース本体に相当する部分の端部に前記溝に相当する部分が成形された前記積層体を加熱することにより、前記織物層の各強化繊維に含浸させた熱硬化性樹脂を硬化させる加熱工程と、を経る円筒状ケースの製造方法。 - 請求項1~3のいずれかに記載の円筒状ケースの製造方法であって、
外周面をケース本体成形面とした筒状のマンドレルをその軸心周りに回転させつつ、前記2軸の強化繊維帯から成るノンクリンプ構造の前記2軸織物を該マンドレルの前記成形面上に巻き付けて前記2軸織物層を形成する2軸織物層形成工程と、
前記マンドレルをその軸心周りに回転させつつ、前記強化繊維を束ねて成るロービングを該マンドレルの前記成形面上に周方向に沿ってらせん状に巻き付けて前記ロービング層を形成するロービング層形成工程と、を繰り返し行って前記ケース本体に相当する部分の積層体を成形すると共に、
外周面を溝成形面とした筒状の溝用マンドレルをその軸心周りに回転させつつ、前記2軸の強化繊維帯から成るノンクリンプ構造の前記2軸織物を該溝用マンドレルの前記溝成形面上に巻き付けて前記2軸織物層を形成する2軸織物層形成工程と、
前記溝用マンドレルをその軸心周りに回転させつつ、前記3軸の強化繊維帯から成るノンクリンプ構造の前記3軸織物を該溝用マンドレルの前記溝成形面上に巻き付けて前記3軸織物層を形成する3軸織物層形成工程と、を繰り返し行って溝用積層体を成形した後、
溝成形型と前記溝用マンドレルとにより、前記溝用積層体を前記溝に相当する部分とすべく成形する溝成形工程と、
この溝成形工程によって前記溝に相当する部分として成形された前記溝用積層体と、前記ケース本体に相当する部分として成形された積層体とを一体化させる一体化工程と、
この一体化工程によって互いに一体化された前記ケース本体に相当する部分の前記積層体と、前記溝に相当する部分として成形された前記溝用積層体とを加熱することにより、前記織物の各強化繊維に含浸させた熱硬化性樹脂を硬化させる加熱工程と、を経る円筒状ケースの製造方法。
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| CA2889366A CA2889366C (en) | 2012-10-25 | 2013-10-22 | Cylindrical case and manufacturing method of cyclindrical case |
| EP13849096.6A EP2913179B1 (en) | 2012-10-25 | 2013-10-22 | Cylindrical case and process for producing cylindrical case |
| RU2015119471/05A RU2598936C1 (ru) | 2012-10-25 | 2013-10-22 | Цилиндрический кожух и способ изготовления цилиндрического кожуха |
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Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2995038B1 (fr) * | 2012-08-30 | 2014-09-19 | Snecma | Carter de soufflante de turbine a gaz ayant une ceinture de fixation d'equipements |
| US9714583B2 (en) * | 2014-08-21 | 2017-07-25 | Honeywell International Inc. | Fan containment cases for fan casings in gas turbine engines, fan blade containment systems, and methods for producing the same |
| US10107202B2 (en) * | 2014-11-26 | 2018-10-23 | United Technologies Corporation | Composite fan housing assembly of a turbofan engine and method of manufacture |
| JP6417933B2 (ja) | 2014-12-26 | 2018-11-07 | 株式会社Ihi | 円筒状ケース及びジェットエンジン |
| PT3334387T (pt) | 2015-08-11 | 2021-03-30 | Sc Medica | Dispositivo para manter um espaço intervertebral |
| FR3040014B1 (fr) * | 2015-08-14 | 2017-09-08 | Conseil & Technique | Procede de fabrication d’un cadre de forme annulaire |
| CN108430746B (zh) * | 2015-12-22 | 2021-10-12 | 赛峰飞机发动机公司 | 由复合材料制成的轻质壳体以及其制造方法 |
| PL415487A1 (pl) * | 2015-12-31 | 2017-07-03 | General Electric Company | Formowana kompozytowa osłona chroniąca przed zużyciem krawędzi dla złącza w postaci wpustu V-kształtnego i łopatki V-kształtnej |
| US20200391880A1 (en) * | 2019-06-13 | 2020-12-17 | Roller Bearing Company Of America, Inc. | Machinable molded fretting buffer |
| CN112709612B (zh) * | 2019-10-24 | 2023-02-28 | 中国航发商用航空发动机有限责任公司 | 一种包容机匣、航空发动机及包容机匣的制造方法 |
| EP4061496A1 (en) * | 2019-11-19 | 2022-09-28 | PDA Ecolab | Shaft for athletic activities |
| CN114060305B (zh) * | 2020-07-29 | 2024-07-12 | 中国航发商用航空发动机有限责任公司 | 一种风扇包容机匣及其制备方法 |
| US11428160B2 (en) | 2020-12-31 | 2022-08-30 | General Electric Company | Gas turbine engine with interdigitated turbine and gear assembly |
| US12480425B2 (en) | 2024-01-26 | 2025-11-25 | Hamilton Sundstrand Corporation | Rotor containment structure |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005097759A (ja) * | 2003-09-22 | 2005-04-14 | Toyota Industries Corp | 三次元繊維構造体及びその製造方法並びに複合材 |
| JP2006069166A (ja) * | 2004-09-06 | 2006-03-16 | Honda Motor Co Ltd | 繊維強化複合材環状構造体の製造方法、及びその構造体からなる航空機胴体用環状フレーム |
| JP2006177364A (ja) * | 2004-12-23 | 2006-07-06 | General Electric Co <Ge> | タービンエンジン用の複合ファン閉込めケースおよびその製造方法 |
| JP2009107337A (ja) | 2007-10-16 | 2009-05-21 | General Electric Co <Ge> | ほぼ円筒形の複合材物品及びファンケーシング |
| JP2011002069A (ja) * | 2009-06-22 | 2011-01-06 | Toyota Industries Corp | 樹脂成形体である被締結部材に形成された締結用の貫通孔に配置される繊維強化複合材である補強部材及び貫通孔に補強部材が配置された被締結部材の締結構造 |
| JP2011098524A (ja) * | 2009-11-06 | 2011-05-19 | Ihi Corp | ケースの製造方法、及びケース |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE115464T1 (de) * | 1990-06-29 | 1994-12-15 | Flexline Services Ltd | Verfahren zur herstellung von verstärktem verbundmaterial und ein fasermaterial zur benutzung während dieses verfahrens. |
| JP4168734B2 (ja) * | 2002-11-15 | 2008-10-22 | 東レ株式会社 | プリフォーム基材、プリフォームおよび繊維強化プラスチックの成形方法 |
| RU2290483C2 (ru) * | 2004-02-10 | 2006-12-27 | Алексей Вадимович Асеев | Длинномерный конструкционный элемент из композиционного материала (варианты) |
| US8231958B2 (en) * | 2007-10-09 | 2012-07-31 | United Technologies Corporation | Article and method for erosion resistant composite |
| JP2011098523A (ja) * | 2009-11-06 | 2011-05-19 | Ihi Corp | ケースの製造方法、及びケース |
| JP5514658B2 (ja) * | 2010-07-09 | 2014-06-04 | 株式会社Ihi | ケース及びその製造方法 |
-
2012
- 2012-10-25 JP JP2012235353A patent/JP6018877B2/ja active Active
-
2013
- 2013-10-22 CN CN201380055805.XA patent/CN104768734B/zh not_active Expired - Fee Related
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- 2013-10-22 RU RU2015119471/05A patent/RU2598936C1/ru active
-
2015
- 2015-04-24 US US14/696,073 patent/US9988156B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005097759A (ja) * | 2003-09-22 | 2005-04-14 | Toyota Industries Corp | 三次元繊維構造体及びその製造方法並びに複合材 |
| JP2006069166A (ja) * | 2004-09-06 | 2006-03-16 | Honda Motor Co Ltd | 繊維強化複合材環状構造体の製造方法、及びその構造体からなる航空機胴体用環状フレーム |
| JP2006177364A (ja) * | 2004-12-23 | 2006-07-06 | General Electric Co <Ge> | タービンエンジン用の複合ファン閉込めケースおよびその製造方法 |
| JP2009107337A (ja) | 2007-10-16 | 2009-05-21 | General Electric Co <Ge> | ほぼ円筒形の複合材物品及びファンケーシング |
| JP2011002069A (ja) * | 2009-06-22 | 2011-01-06 | Toyota Industries Corp | 樹脂成形体である被締結部材に形成された締結用の貫通孔に配置される繊維強化複合材である補強部材及び貫通孔に補強部材が配置された被締結部材の締結構造 |
| JP2011098524A (ja) * | 2009-11-06 | 2011-05-19 | Ihi Corp | ケースの製造方法、及びケース |
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