[go: up one dir, main page]

WO2014040708A3 - Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters - Google Patents

Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters Download PDF

Info

Publication number
WO2014040708A3
WO2014040708A3 PCT/EP2013/002648 EP2013002648W WO2014040708A3 WO 2014040708 A3 WO2014040708 A3 WO 2014040708A3 EP 2013002648 W EP2013002648 W EP 2013002648W WO 2014040708 A3 WO2014040708 A3 WO 2014040708A3
Authority
WO
WIPO (PCT)
Prior art keywords
tertiary alkyl
glycidyl esters
alkyl glycidyl
aqueous polyurethane
polyurethane dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2013/002648
Other languages
French (fr)
Other versions
WO2014040708A2 (en
Inventor
Christophe Steinbrecher
Denis Heymans
Bedri Erdem
Mike O'Shaughnessy
Jeff BLAISDELL (Habb Co)
Gerhard Mueller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion Research Belgium SA
Hexion Inc
Original Assignee
Momentive Specialty Chemicals Research SA
Momentive Specialty Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP12075105.2A external-priority patent/EP2708564A1/en
Priority claimed from EP13000586.1A external-priority patent/EP2765147A1/en
Priority to CN201380053993.2A priority Critical patent/CN104918975B/en
Priority to KR1020157009201A priority patent/KR101766984B1/en
Priority to PL13766889T priority patent/PL2895522T3/en
Priority to US14/427,585 priority patent/US20150240077A1/en
Application filed by Momentive Specialty Chemicals Research SA, Momentive Specialty Chemicals Inc filed Critical Momentive Specialty Chemicals Research SA
Priority to DK13766889.3T priority patent/DK2895522T3/en
Priority to EP13766889.3A priority patent/EP2895522B1/en
Priority to ES13766889T priority patent/ES2842202T3/en
Priority to TW102133015A priority patent/TWI500715B/en
Publication of WO2014040708A2 publication Critical patent/WO2014040708A2/en
Publication of WO2014040708A3 publication Critical patent/WO2014040708A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Dispersion Chemistry (AREA)

Abstract

This invention relates to a Waterborne Polyurethane Dispersions (WPU) derived from the reaction products of tertiary alkyl glycidyl esters based hydroxyl terminal polyester polyols with polyisocyanates and chain extended with poly-functional amines and dispersed in water have shown the surprising inherent ability for self-coalescence. Furthermore the cured films have shown improved hardness and abrasion resistance over these benchmarks with a significant reduction in coalescing solvent needed to accomplish film formation.
PCT/EP2013/002648 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters Ceased WO2014040708A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES13766889T ES2842202T3 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkylglycidyl esters
EP13766889.3A EP2895522B1 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
KR1020157009201A KR101766984B1 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
PL13766889T PL2895522T3 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
US14/427,585 US20150240077A1 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkenyl glycidyl esters
CN201380053993.2A CN104918975B (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl ethylene oxidic ester
DK13766889.3T DK2895522T3 (en) 2012-09-13 2013-09-03 AQUATIC POLYURETHANE DISPERSION DERIVED FROM TERTIARY ALKYLGYCIDYLESTERS
TW102133015A TWI500715B (en) 2012-09-13 2013-09-12 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP12075105.2A EP2708564A1 (en) 2012-09-13 2012-09-13 Aqueous polyurethane dispersion derived from tertiary alkenyl glycidyl esters
EP12075105.2 2012-09-13
EP13000586.1A EP2765147A1 (en) 2013-02-06 2013-02-06 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
EP13000586.1 2013-02-06

Publications (2)

Publication Number Publication Date
WO2014040708A2 WO2014040708A2 (en) 2014-03-20
WO2014040708A3 true WO2014040708A3 (en) 2014-12-04

Family

ID=49253241

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/002648 Ceased WO2014040708A2 (en) 2012-09-13 2013-09-03 Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters

Country Status (9)

Country Link
US (1) US20150240077A1 (en)
EP (1) EP2895522B1 (en)
KR (1) KR101766984B1 (en)
CN (1) CN104918975B (en)
DK (1) DK2895522T3 (en)
ES (1) ES2842202T3 (en)
PL (1) PL2895522T3 (en)
TW (1) TWI500715B (en)
WO (1) WO2014040708A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019519400A (en) * 2016-06-06 2019-07-11 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ New methods for the production of composite materials
CN109642114A (en) 2016-07-14 2019-04-16 米切尔曼公司 Water-based polyurethane/crylic acid ester mixture dispersion
CN106750129B (en) * 2016-12-28 2019-12-27 中昊北方涂料工业研究设计院有限公司 Low dielectric loss polyurethane resin and preparation method thereof
JP7086992B2 (en) * 2017-05-11 2022-06-20 ダウ グローバル テクノロジーズ エルエルシー Aqueous polyurethane dispersion adhesive composition
CN107840936A (en) * 2017-11-19 2018-03-27 哈尔滨师范大学 A kind of antistatic bio-based nonionic surfactant and preparation method thereof
CN108949075A (en) * 2018-07-11 2018-12-07 翟琳 A kind of preparation method of concrete crack repair sheets

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0682049A1 (en) * 1994-05-09 1995-11-15 Hoechst Aktiengesellschaft Hydrophilic polyurethane-polyureas and their use as a dispersant for synthetic resins
WO1998012273A1 (en) * 1996-09-20 1998-03-26 Ppg Industries, Inc. Humidity resistant aqueous urethane resins based on hydrophobic polyhydroxy compounds and coatings
WO2000056827A1 (en) * 1999-03-23 2000-09-28 Avecia Bv Crosslinkable coating compositions

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3607900A (en) 1969-09-25 1971-09-21 Stauffer Wacker Silicone Corp Transhalogenation of organosilicon halides with silicon tetrafluoride
US5095069A (en) * 1990-08-30 1992-03-10 Ppg Industries, Inc. Internally-curable water-based polyurethanes
DE19847791A1 (en) * 1998-10-16 2000-04-20 Bayer Ag Aqueous polyurethane dispersions
DE19849702B9 (en) * 1998-10-28 2004-09-09 Degussa Construction Chemicals Gmbh Process for producing a polyurethane-polymer hybrid dispersion with high film hardness and its use
GB9828444D0 (en) 1998-12-24 1999-02-17 Ici Plc Coating composition
US6610784B1 (en) 1999-03-23 2003-08-26 Avecia Bv Crosslinkable coating compositions
US20040171748A1 (en) * 2000-12-22 2004-09-02 Swaminathan Ramesh Polyester resin, a method of preparing the polyester resin, and a coating composition thereof
US7728068B2 (en) * 2003-06-12 2010-06-01 Valspar Sourcing, Inc. Coating compositions containing reactive diluents and methods
GB0414594D0 (en) 2004-06-30 2004-08-04 Avecia Bv Aqueous composition 1
CN103314025B (en) * 2010-10-29 2016-08-10 路博润高级材料公司 Waterborne Cationic Polyurethane Dispersion

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0682049A1 (en) * 1994-05-09 1995-11-15 Hoechst Aktiengesellschaft Hydrophilic polyurethane-polyureas and their use as a dispersant for synthetic resins
WO1998012273A1 (en) * 1996-09-20 1998-03-26 Ppg Industries, Inc. Humidity resistant aqueous urethane resins based on hydrophobic polyhydroxy compounds and coatings
WO2000056827A1 (en) * 1999-03-23 2000-09-28 Avecia Bv Crosslinkable coating compositions

Also Published As

Publication number Publication date
CN104918975B (en) 2018-08-14
DK2895522T3 (en) 2021-01-18
TW201425496A (en) 2014-07-01
EP2895522B1 (en) 2020-11-11
US20150240077A1 (en) 2015-08-27
ES2842202T3 (en) 2021-07-13
KR20150065720A (en) 2015-06-15
CN104918975A (en) 2015-09-16
KR101766984B1 (en) 2017-08-09
EP2895522A2 (en) 2015-07-22
TWI500715B (en) 2015-09-21
WO2014040708A2 (en) 2014-03-20
PL2895522T3 (en) 2021-08-16

Similar Documents

Publication Publication Date Title
WO2014040708A3 (en) Aqueous polyurethane dispersion derived from tertiary alkyl glycidyl esters
WO2010006073A3 (en) Dendritic polyurethane coating
WO2016069396A8 (en) Thermoplastic polyurethane film for delivery of active agents to skin surfaces
MX365509B (en) Waterborne two component polyurethane coating compositions comprising alicyclic rigid polyols.
WO2013006611A3 (en) Waterborne polyurethane coating compositions
WO2013189882A3 (en) Coating agent having high scratch resistance
WO2014153046A3 (en) Polyurethanes, articles and coatings prepared therefrom and methods of making the same
EP3194482C0 (en) USE OF PHOSPHORUS-CONTAINING ORGANIC OXYIMIDES AS FLAME RETARDANTS FOR PLASTICS, FLAME-RETARDANT PLASTIC COMPOSITIONS, PROCESSES FOR THE PRODUCTION THEREOF, AND MOLDED PARTS, PAINTS AND COATINGS
EP3305828A4 (en) Polyester polyol, polyurethane resin, and production processes therefor
EP2674443A4 (en) Waterborne polyurethane resin dispersion and use thereof
WO2013006605A3 (en) Waterborne polyurethane coating compositions
WO2013006606A3 (en) Free radical curable waterborne glass coating compositions
EP2751170A4 (en) Water-based polymer emulsions for opaque films and coatings applications on flexible substrates
MX370235B (en) Pigmented coating material and method for producing a multi-layer coating using the pigmented coating material.
PL2686361T3 (en) Polyurethane coating agent composition, multistage coating method using said coating agent compositions, and use of the coating agent compositions as clear coating or pigmented coating material and use of the coating method for automotive repair painting and/or for coating plastic substrates and/or commercial vehicles
MX2016015931A (en) Compact elastomer molded parts on the basis of polyurethane.
SG11201506957XA (en) High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers
WO2014064035A3 (en) Two-component waterborne polyurethane coating composition
SG11201501009RA (en) Polyisocyanate composition and isocyanate polymer composition
WO2013052190A3 (en) Coating/sealant systems, aqueous resinous dispersions, and methods of electrocoating
MY186801A (en) Polyurethane elastomeric composition and method of preparing the same
WO2013147701A8 (en) Aqueous cationic polyurethane dispersions and their uses
WO2016196565A3 (en) Amphiphilic siloxane- polyurethane fouling-release coatings and uses thereof
WO2013081817A3 (en) Clear coat coating composition
WO2013006609A3 (en) Waterborne polyurethane coating compositions

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 14427585

Country of ref document: US

ENP Entry into the national phase

Ref document number: 20157009201

Country of ref document: KR

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13766889

Country of ref document: EP

Kind code of ref document: A2