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WO2013136096A1 - Fabrication additive - Google Patents

Fabrication additive Download PDF

Info

Publication number
WO2013136096A1
WO2013136096A1 PCT/GB2013/050687 GB2013050687W WO2013136096A1 WO 2013136096 A1 WO2013136096 A1 WO 2013136096A1 GB 2013050687 W GB2013050687 W GB 2013050687W WO 2013136096 A1 WO2013136096 A1 WO 2013136096A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
product
regions
reinforcing
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2013/050687
Other languages
English (en)
Inventor
Oana Roxana GHITA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Exeter
Original Assignee
University of Exeter
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB1204619.9A external-priority patent/GB201204619D0/en
Priority claimed from GBGB1212438.4A external-priority patent/GB201212438D0/en
Application filed by University of Exeter filed Critical University of Exeter
Publication of WO2013136096A1 publication Critical patent/WO2013136096A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/141Processes of additive manufacturing using only solid materials
    • B29C64/153Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/30Process control
    • B22F10/36Process control of energy beam parameters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/60Planarisation devices; Compression devices
    • B22F12/63Rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/1017Multiple heating or additional steps
    • B22F3/1028Controlled cooling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • This invention relates to an additive manufacturing method and to a product manufactured thereby.
  • a number of additive manufacturing processes are known. For example, one technique involves depositing a thin layer of material, in powder form, upon a support table and selectively fusing the parts of the layer which are to form part of the product. Subsequently, a further layer of material is deposited upon the previously deposited layer and the fusing process is repeated. These steps are repeated a number of times until a desired product has been formed.
  • the material used can include a range of polymer materials, metals, graphite and wax-like materials.
  • an additive manufacturing method comprising depositing a product material to form a first product layer, undertaking a fusing operation to form reinforcing regions within the first product layer, and depositing and undertaking a fusing operation on at least one further product layer to form a multilayered product integrally formed with reinforcing regions.
  • the reinforcing regions of adjacent layers may be bonded or fused to one another.
  • the product material may be of a type in which heating thereof to a first temperature, and subsequent cooling, results in the formation of regions of the layer with a first structure, and heating thereof to a second, higher temperature, and subsequent cooling thereof, results in the formation of regions of the layer with a second structure.
  • the first and second structures may comprise different crystal structures and/or different super molecular orders.
  • the first and second structures may both comprise crystalline or semicrystalline structures or, alternatively, the first structure may be amorphous whilst the second structure is crystalline or semicrystalline. It will be appreciated that by appropriate control over the melting or sintering operations, the temperatures to which various of parts of the layer are exposed can be controlled with the result that material with the first structure is present in some parts of the layer whilst material with the second structure is present elsewhere.
  • Material of one of the first and second structures may form the majority of the material of the final product, the material of the other of the structures forming reinforcing regions extending within the material. If desired, the reinforcing regions formed in one of the layers may bond with the reinforcing regions of adjacent layers, thereby strengthening the bond between the adjacent layers, and so enhancing the strength of the overall product.
  • the reinforcing regions may be formed where desired within the product, thus some parts of the product may, if desired, contain more reinforcing regions that other. Furthermore, the directions in which the reinforcement formed by the reinforcing regions extends may be controlled as desired.
  • the product material may comprise a substantially uniform blend of a material with a relatively high melting point and a material with a relatively low melting point, the fusing operation heating the product material to a temperature sufficiently high to cause melting of the low melting point material but low enough to cause sintering or fusing of the high melting point material, but avoiding complete melting thereof.
  • the lower melting point material within a matrix of higher melting point material serves to reinforce the higher melting point material, thus forming reinforcing regions within the product.
  • the materials are preferably polymers, conveniently selected from the same polymer family, for example they may be selected from PEK, PEEK and PEKK (all poly aryl ether ketones) or from PA6, PA6.6, PA12 or PA11 (all polyamides).
  • the blend may comprise a blend of PEEK and PEK.
  • the PEK forms the relatively high melting point material, having a melting point of 365°C
  • the PEEK with a melting point of 335°C forming the relatively low melting point material.
  • the additive manufacturing process is conveniently a powder bed process. However, this need not always be the case and the invention may also applicable to arrangements in which other additive manufacturing processes are used.
  • Figure 1 illustrates the manufacture of a product in accordance with one embodiment of the invention
  • Figures 2 and 3 illustrate variants to the arrangement of Figure 1 ;
  • Figure 4 is a view illustrating an alternative arrangement
  • Figure 5 is a graph illustrating the effect of increasing heating.
  • a powder bed type additive manufacturing apparatus comprises a support table 20 which is capable of being incrementally raised and lowered.
  • a delivery device 30 is arranged to deliver uniform thickness layers 5a, 5b of powder material to the table 20, when desired, the thickness of each layer 5a, 5b being determined by the size of the increments by which the table 20 can be lowered.
  • a laser-based heating device 40 is operable to heat the material of the layers 5a, 5b. The heating operation is undertaken by scanning the laser beam output from the device 40 over selected parts of each layer 5a, 5b to raise the temperature of the selected parts of each layer 5a, 5b.
  • the manner in which the laser beam output is scanned could involve physically moving the laser relative to the table 20. However, it will generally be more convenient for the laser and table 20 to both be fixed during the scanning operation, and for the laser beam output to be scanned over the layers 5a, 5b by adjustment of the positions of suitable optical devices such as mirrors or other reflectors.
  • the device 40 is conveniently computer controlled, both in relation to the selection of which parts of each layer to heat and in relation to the temperature to heat each region to. Conveniently, a single computer program undertakes all of this control.
  • Figure 5 illustrates that the use of increased laser power (and hence increased temperature if the other parameters are held constant) results in the formation of materials of enhanced resilience, being capable of withstanding increased loads, and hence undergoing increased elongation, prior to failure.
  • the powder material is nylon
  • the process may result in the formation of, for example, regions 15a of nylon-6 and regions 10a of nylon-6,6.
  • the reinforcing regions 15 each extend perpendicularly to the table 20, this need not always be the case.
  • the reinforcing regions 15 may be angled relative to the table (for example as shown in Figure 2), or may extend parallel to the table 20 (for example as shown in Figure 3). It will be appreciated that these options are merely examples and that a wide range of alternatives are possible without departing from the scope of the invention.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
PCT/GB2013/050687 2012-03-16 2013-03-18 Fabrication additive Ceased WO2013136096A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB1204619.9A GB201204619D0 (en) 2012-03-16 2012-03-16 Self reinforced composite using additive manufacture
GB1204619.9 2012-03-16
GBGB1212438.4A GB201212438D0 (en) 2012-07-12 2012-07-12 Self reinforced composite using additive manufacture
GB1212438.4 2012-07-12

Publications (1)

Publication Number Publication Date
WO2013136096A1 true WO2013136096A1 (fr) 2013-09-19

Family

ID=48444421

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2013/050687 Ceased WO2013136096A1 (fr) 2012-03-16 2013-03-18 Fabrication additive

Country Status (1)

Country Link
WO (1) WO2013136096A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103990798A (zh) * 2014-05-06 2014-08-20 华中科技大学 一种用于激光增材制造的高温粉床系统
EP2875938A1 (fr) 2013-11-21 2015-05-27 Airbus Operations GmbH Procédé et outil de fabrication d'éléments structuraux renforcés
EP2962789A3 (fr) * 2014-06-30 2016-04-20 General Electric Company Procédés et systèmes de fabrication additive avec renforcement par fibres
DE102015211559A1 (de) * 2015-06-23 2016-12-29 Airbus Operations Gmbh Metallbauteil mit integrierten Glasfasern für ein Luft- oder Raumfahrzeug und 3D-Druckverfahren zur Herstellung eines Metallbauteils mit integrierten Glasfasern
WO2017015241A1 (fr) * 2015-07-18 2017-01-26 Vulcanforms Inc. Fabrication additive par fusion de matériau spatialement contrôlée
US20180162456A1 (en) * 2016-12-08 2018-06-14 Ford Global Technologies, Llc Vehicle component and method of constructing
WO2019094792A1 (fr) * 2017-11-10 2019-05-16 Local Motors IP, LLC Structure formée par fabrication additive et procédé pour la formation de celle-ci
WO2019241286A1 (fr) * 2018-06-11 2019-12-19 Local Motors IP, LLC Structure fabriquée de manière additive et procédé pour sa fabrication
US10875094B2 (en) 2018-03-29 2020-12-29 Vulcanforms Inc. Additive manufacturing systems and methods
US11338507B2 (en) 2015-05-15 2022-05-24 Hewlett-Packard Development Company, L.P. Coalescing agent concentrations and contone densities for three-dimensional objects
US11654623B2 (en) 2015-11-11 2023-05-23 Xerox Corporation Additive manufacturing system with layers of reinforcing mesh
US11731342B2 (en) 2018-04-23 2023-08-22 Rapidflight Holdings, Llc Additively manufactured structure and method for making the same
US11745423B2 (en) 2018-04-23 2023-09-05 Rapidflight Holdings, Llc Method and apparatus for additive manufacturing
US11813790B2 (en) 2019-08-12 2023-11-14 Rapidflight Holdings, Llc Additively manufactured structure and method for making the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5147587A (en) * 1986-10-17 1992-09-15 Board Of Regents, The University Of Texas System Method of producing parts and molds using composite ceramic powders
WO2001014127A1 (fr) * 1999-08-19 2001-03-01 Bae Systems Plc Procede stereolithographique de fabrication d'articles possedant des regions a densites differentes
DE10042132A1 (de) * 2000-08-28 2002-03-28 Concept Laser Gmbh Selektives Randschichtschmelzen
FR2878771A1 (fr) * 2004-12-07 2006-06-09 3D Systems Inc Procede et appareil de frittage au laser a densification controlee de la poudre fusible
EP2123430A1 (fr) * 2008-05-20 2009-11-25 EOS GmbH Electro Optical Systems Influences des propriétés mécaniques spécifiques d'objets tridimensionnels fabriqués par un frittage sélectif au moyen d'un rayonnement électromagnétique à partir d'une poudre comportant au moins un polymère ou copolymère

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5147587A (en) * 1986-10-17 1992-09-15 Board Of Regents, The University Of Texas System Method of producing parts and molds using composite ceramic powders
WO2001014127A1 (fr) * 1999-08-19 2001-03-01 Bae Systems Plc Procede stereolithographique de fabrication d'articles possedant des regions a densites differentes
DE10042132A1 (de) * 2000-08-28 2002-03-28 Concept Laser Gmbh Selektives Randschichtschmelzen
FR2878771A1 (fr) * 2004-12-07 2006-06-09 3D Systems Inc Procede et appareil de frittage au laser a densification controlee de la poudre fusible
EP2123430A1 (fr) * 2008-05-20 2009-11-25 EOS GmbH Electro Optical Systems Influences des propriétés mécaniques spécifiques d'objets tridimensionnels fabriqués par un frittage sélectif au moyen d'un rayonnement électromagnétique à partir d'une poudre comportant au moins un polymère ou copolymère

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2875938A1 (fr) 2013-11-21 2015-05-27 Airbus Operations GmbH Procédé et outil de fabrication d'éléments structuraux renforcés
CN103990798A (zh) * 2014-05-06 2014-08-20 华中科技大学 一种用于激光增材制造的高温粉床系统
EP2962789A3 (fr) * 2014-06-30 2016-04-20 General Electric Company Procédés et systèmes de fabrication additive avec renforcement par fibres
US9757802B2 (en) 2014-06-30 2017-09-12 General Electric Company Additive manufacturing methods and systems with fiber reinforcement
US11338507B2 (en) 2015-05-15 2022-05-24 Hewlett-Packard Development Company, L.P. Coalescing agent concentrations and contone densities for three-dimensional objects
DE102015211559A1 (de) * 2015-06-23 2016-12-29 Airbus Operations Gmbh Metallbauteil mit integrierten Glasfasern für ein Luft- oder Raumfahrzeug und 3D-Druckverfahren zur Herstellung eines Metallbauteils mit integrierten Glasfasern
CN106270507A (zh) * 2015-06-23 2017-01-04 空中客车德国运营有限责任公司 包括集成的玻璃纤维的金属组件及制造它的3d打印方法
US10919090B2 (en) 2015-07-18 2021-02-16 Vulcanforms Inc. Additive manufacturing by spatially controlled material fusion
WO2017015241A1 (fr) * 2015-07-18 2017-01-26 Vulcanforms Inc. Fabrication additive par fusion de matériau spatialement contrôlée
CN107921536A (zh) * 2015-07-18 2018-04-17 伏尔肯模型公司 通过空间控制的材料熔合的增材制造
US12226956B2 (en) 2015-07-18 2025-02-18 Vulcanforms Inc. Additive manufacturing by spatially controlled material fusion
US11602792B2 (en) 2015-07-18 2023-03-14 Vulcanforms Inc. Additive manufacturing by spatially controlled material fusion
US11654623B2 (en) 2015-11-11 2023-05-23 Xerox Corporation Additive manufacturing system with layers of reinforcing mesh
US12337534B2 (en) 2015-11-11 2025-06-24 Xerox Corporation Additive manufacturing method for embedding fibers in a three-dimensional structure
US10583871B2 (en) * 2016-12-08 2020-03-10 Ford Global Technologies, Llc Vehicle component and method of constructing
US20180162456A1 (en) * 2016-12-08 2018-06-14 Ford Global Technologies, Llc Vehicle component and method of constructing
US10967576B2 (en) 2017-11-10 2021-04-06 Local Motors IP, LLC Additive manufactured structure having a plurality of layers in a stacking direction and method for making the same
US11623401B2 (en) 2017-11-10 2023-04-11 Rapidflight Holdings, Llc Additive manufactured structure having a plurality of layers in a stacking direction that define a plurality of interfaces and method for making the same
WO2019094792A1 (fr) * 2017-11-10 2019-05-16 Local Motors IP, LLC Structure formée par fabrication additive et procédé pour la formation de celle-ci
US10875094B2 (en) 2018-03-29 2020-12-29 Vulcanforms Inc. Additive manufacturing systems and methods
US12233476B2 (en) 2018-03-29 2025-02-25 Vulcanforms Inc. Additive manufacturing systems and methods
US11731342B2 (en) 2018-04-23 2023-08-22 Rapidflight Holdings, Llc Additively manufactured structure and method for making the same
US11745423B2 (en) 2018-04-23 2023-09-05 Rapidflight Holdings, Llc Method and apparatus for additive manufacturing
WO2019241286A1 (fr) * 2018-06-11 2019-12-19 Local Motors IP, LLC Structure fabriquée de manière additive et procédé pour sa fabrication
US11813790B2 (en) 2019-08-12 2023-11-14 Rapidflight Holdings, Llc Additively manufactured structure and method for making the same

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