Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
  • B29B17/02—Separating plastics from other materials
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J11/00—Recovery or working-up of waste materials
  • C08J11/04—Recovery or working-up of waste materials of polymers
  • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/44—Carbon
  • C09C1/48—Carbon black
  • C09C1/482—Preparation from used rubber products, e.g. tyres
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/44—Carbon
  • C09C1/48—Carbon black
  • C09C1/485—Preparation involving the use of a plasma or of an electric arc
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
  • C10B19/00—Heating of coke ovens by electrical means
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
  • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
  • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
  • C10J3/02—Fixed-bed gasification of lump fuel
  • C10J3/06—Continuous processes
  • C10J3/18—Continuous processes using electricity
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
  • C10K1/00—Purifying combustible gases containing carbon monoxide
  • C10K1/02—Dust removal
  • C10K1/028—Dust removal by electrostatic precipitation
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
  • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
  • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
  • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
  • F23G5/033—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment comminuting or crushing
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F27—FURNACES; KILNS; OVENS; RETORTS
  • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
  • F27D11/00—Arrangement of elements for electric heating in or on furnaces
  • F27D11/06—Induction heating, i.e. in which the material being heated, or its container or elements embodied therein, form the secondary of a transformer
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
  • B29B17/04—Disintegrating plastics, e.g. by milling
  • B29B2017/0424—Specific disintegrating techniques; devices therefor
  • B29B2017/0496—Pyrolysing the materials
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2021/00—Use of unspecified rubbers as moulding material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2305/00—Use of metals, their alloys or their compounds, as reinforcement
  • B29K2305/08—Transition metals
  • B29K2305/12—Iron
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
  • B29L2030/00—Pneumatic or solid tyres or parts thereof
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
  • C10J2300/0913—Carbonaceous raw material
  • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/12—Heating the gasifier
  • C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
  • C10J2300/1238—Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
  • C10J2300/00—Details of gasification processes
  • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
  • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
  • C10J2300/1643—Conversion of synthesis gas to energy
  • C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2201/00—Pretreatment
  • F23G2201/40—Gasification
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2204/00—Supplementary heating arrangements
  • F23G2204/20—Supplementary heating arrangements using electric energy
  • F23G2204/201—Plasma
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2206/00—Waste heat recuperation
  • F23G2206/20—Waste heat recuperation using the heat in association with another installation
  • F23G2206/202—Waste heat recuperation using the heat in association with another installation with an internal combustion engine
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2206/00—Waste heat recuperation
  • F23G2206/20—Waste heat recuperation using the heat in association with another installation
  • F23G2206/203—Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
  • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
  • F23G2209/00—Specific waste
  • F23G2209/28—Plastics or rubber like materials
  • F23G2209/281—Tyres
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F27—FURNACES; KILNS; OVENS; RETORTS
  • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
  • F27D99/00—Subject matter not provided for in other groups of this subclass
  • F27D99/0001—Heating elements or systems
  • F27D99/0006—Electric heating elements or system
  • F27D2099/0031—Plasma-torch heating
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E20/00—Combustion technologies with mitigation potential
  • Y02E20/12—Heat utilisation in combustion or incineration of waste
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P20/00—Technologies relating to chemical industry
  • Y02P20/141—Feedstock
  • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
  • Y02W30/00—Technologies for solid waste management
  • Y02W30/50—Reuse, recycling or recovery technologies
  • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

• the invention relates to a system and method of recycling waste tyres. Specifically, the invention relates to using high energy gas flow tyre pyrolysis to convert waste tyres into energy. More specifically, the invention relates to using Radio Frequency (RF) inductive plasma heating together with Low Frequency (LF) induction heating to recycle waste tyres into useable products and electricity.
• RF Radio Frequency
• LF Low Frequency
• a first advantage of the system and method in accordance with this invention is that it converts waste tyres into useable products and electricity.
• a second advantage of the system and method in accordance with this invention is that it does not require landfill sites and converts the growing number of waste tyres into a useful product.
• a third advantage of the system and method in accordance with this invention is that pollution is reduced to virtually zero.
• the method also comprises the step of obtaining carbon black at an outlet of the induction thermal processor.
• a turbine and a generator is used to generate electricity using the syngas produced.
• the electricity generated is used to power a system to convert waste tyres into syngas.
• the powder is introduced into the powder injector via a carrier gas.
• the powder is introduced via the carrier gas into a plasma torch of the powder injector.
• the carrier gas is selected from the group comprising argon, nitrogen, neon, helium, carbon dioxide, or a mixture of two or more thereof.
• the plasma torch uses gas that is selected from the group comprising argon, nitrogen, neon, helium, carbon dioxide, or a mixture of two or more thereof.
• the method comprises a further step of setting the powder to have a particle size ranging from 100 microns to 25mm.
• the method comprises a further step of setting the powder feeder rate to the powder injector between kg per hour and 2 tonnes per hour.
• the method comprises a further step of setting the induction frequency of a LF induction coil in the induction thermal processor between 1 kHz and 500 kHz.
• the method comprises a further step of setting the temperature in the induction thermal processor between 900 degrees Centigrade and 1200 degrees Centigrade.
• a carbon black product is obtainable at an outlet of the induction thermal processor.
• the carbon black product comprises a composition of 95% carbon, 2% silicon and 3% zinc oxide by weight.
• a system for converting waste tyres into syngas and carbon black comprising
• a feeding system for feeding said powder into a powder injector
• an induction thermal processor for producing syngas and carbon black.
• the system further comprises a source of carrier gas connected to the feeding system.
• the powder injector comprises a plasma torch and an RF induction coil.
• the powder is introduced into the plasma torch of the powder injector.
• the plasma torch comprises a metal tube in which a plasma stream is created. .
• the metal tube is made of copper.
• the plasma torch comprises a quartz tube in which a plasma stream is created.
• the quartz tube is shielded by a metal shield. Even more preferably, the quartz tube is shielded by a water-cooled metal shield.
• the metal shield is made of a non-magnetic material.
• the induction thermal processor comprises a chamber and a LF induction coil.
• the chamber comprises a metal tube.
• the metal tube is made of ferromagnetic material.
• the metal tube is made of steel, preferably of stainless steel, graphite or carbon steel.
• the metal tube is coated with a ferromagnetic material.
• the metal tube is ceramic coated.
• the metal tube is graphite coated.
• the chamber is rotatable.
• the LF induction coil is rotatable.
• the longitudinal axis of the chamber is at an angle to the longitudinal axis of the powder injector.
• the longitudinal axis of the LF induction coil is at an angle to the longitudinal axis of the powder injector.
• the angle is between 0 and 90 degrees.
• the source provides the carrier gas selected from the group comprising of argon, nitrogen, neon, helium, carbon dioxide, or a mixture of two or more thereof.
• the plasma torch uses gas that is selected from the group comprising of argon, nitrogen, neon, helium, carbon dioxide, or a mixture of two or more thereof.
• the induction frequency of the LF induction coil is between 1 kHz and 500 kHz.
• the feeding system has a feeder rate of between 1 kg per hour and 2 tonnes per hour to the powder injector.
• the temperature in the induction thermal processor is between 900 degrees Centigrade and 1200 degrees Centigrade.
• the temperature in the powder injector is between 6000 degrees Centigrade and 11000 degrees Centigrade.
• the powder used in the feeding system has a particle size ranging from 100 microns to 25mm.
• a plasma reactor for converting rubber to syngas and carbon black comprising:
• a plasma jet formed by passing a plasma gas through an RF induction coil, said plasma jet positioned proximal to said inlet;
• a LF induction coil positioned proximal to said inlet but distal to said plasma jet;
• syngas and carbon black are obtained from said chamber.
• a carrier gas is introduced into the chamber using the inlet.
• Figure 1 is a flow chart of a method of converting waste tyres into synthetic gas (syngas) in accordance with a first embodiment of the present invention.
• FIG. 2 is an illustrative diagram of the plasma reactor.
• the method 1 10 commences when waste tyres are fed into the system 1 12.
• a crushing and separation system 1 14 removes the steel from the waste tyres and compacts it before sending the steel to the steel mill 116.
• the remaining rubber is comminuted into a powder 1 18 through processes which are well known in the industry.
• the powder typically has particle size ranging from 100 microns to 25mm. In one embodiment, the size of the rubber powder used is between 400 microns and 600 microns.
• This rubber powder (or pulverized tyre) is then fed into a feeder which uses a carrier gas and feeds the rubber powder into a RF plasma reactor and LF induction chamber 120.
• the chamber contains the pyrolysis process and the output is mostly gaseous which is syngas, comprising predominantly of carbon monoxide and hydrogen. Carbon dioxide and long-chain hydrocarbons may also be present.
• Some output from the RF plasma and LF induction chamber is solid, which are base carbon powder and this is commonly known in the industry as carbon black.
• This carbon black is packaged for sale to industries 122, while the syngas is sent to a scrubber 124.
• the scrubber removes any sulphur oxides and nitrogen oxides and sends the syngas to the electrostatic precipitator 126, which removes any residual carbon powder.
• the syngas is then burned in a gas turbine 128, which powers an engine generator 130 to produce electricity 132, as well as exhaust gases.
• the exhaust gases are sent for selective catalytic reduction 134, which removes any nitrogen oxides from the exhaust gas before being vented through the exhaust stack.
• Engine generator systems are well known to those in the industry and include refined processes and systems to collect and remove any residual nitrogen oxide that occurs from burning the gas in the engine. This is crucial since nitrogen oxide is the only hazardous element from burning the syngas. The burning in the engine also breaks down any long-chain hydrocarbons in the exhaust gas.
• the exhaust gas that is vented through the exhaust stack will have minimal amounts of nitrogen oxides and this will have a maximum of 20 parts per million (PPM), which is so minute that it would be difficult to measure using conventional or standard measuring instruments.
• PPM parts per million
• Tests conducted have shown that the nitrogen oxides and carbon monoxide produced is 1 1 mg/NM3 and 13 mg/NM3 representing a significant reduction in nitrogen oxides and carbon monoxide produced by the existing prior art systems.
• a feeder system 210 is used to. feed the rubber powder into a powder injector 220 using a carrier gas.
• the carrier gas used to carry the rubber powder in an oxygen free environment into chamber can be argon, nitrogen, neon, helium, carbon dioxide or a mixture of any of these inert gases.
• the feed rate of the carrier gas is between 0 and 200 standard cubic feet per minute (SCFM), as aside from using carrier gas, the powder can also be fed mechanically to the chamber.
• the size of the rubber powder used is between 100 microns and 25mm, although typically, a size of 400 microns to 600 microns is used.
• the feeder has a variable rubber powder feeding rate of between 1 kg per hour and 2 tonnes per hour. One of the tested feeding rates which provided good returns was at 1 tonne per hour.
• the RF plasma heater consists of a plasma torch and an RF coil.
• the plasma torch is made up of a quartz tube in combination with a water-cooled copper shield. This metal shield can also be any non-magnetic material.
• This acts as a pre-treatment before the induction thermal processor 230.
• the plasma frequency is between 66kHz and 150MHz, while the power used is between 1 kW and 1MW.
• the gas feed rate for the plasma gas is between 0 and 10 cubic meters per hour, and the plasma gas used can be argon, nitrogen, neon, helium, carbon dioxide or a mixture of any of these inert gases.
• the pre-treatment can cause the rubber powder to partially decompose before fully decomposing in the induction thermal processor 230.
• the induction thermal processor 230 is the reaction chamber where pyrolysis takes place and the chamber can be mounted such that it can be rotated, even while gas is flowing.
• the chamber can either be mounted stationary or rotated up to l Orpm.
• the chamber can be installed at an angle or be mounted completely vertical or horizontal, depending on the user specification. There are situations that require the chamber to be mounted at an angle of between 0 to 90°, i.e. completely horizontal to completely vertical.
• One embodiment of the chamber was mounted between 10 to 15 degrees to the powder injector.
• the induction thermal processor 230 has an LF induction heater and its frequency is between 1 kHz and 500kHz while the power used is between 10kW and 5MW. In some instances, it would found the a frequency of between 1 kHz and 40kHz was suitable.
• the LF induction heater can be mounted at various positions, including inside and outside the chamber.
• the LF induction heater can also be mounted at an angle or rotated, independent of the chamber.
• the induction thermal processor chamber can be made of stainless steel or carbon steel, and it can be further coated with ceramic, graphite or any other magnetic material where induction can take place.
• the processing time in the induction thermal processor is dependent on the time required to decompose the rubber powder via pyrolysis, and the temperature in the chamber can range between 900°C and 1200°C. A convenient temperature which provided a good yield was 1000°C.
• the induction thermal processor produces exhaust gases, which is sent to the exhaust stack 240, consisting mainly of carbon monoxide and hydrogen, as well as a solid material known as carbon black.
• RF induced electrode-less plasma system is a flexible pyrolysis technique and consists of passing gas through a plasma torch combined with RF power to form a hot plasma stream. This allows different gases to be used to control the end result and also eliminates the need to shut down the reactor to replace the electrodes (since there are no electrodes needed).
• An induction heater is attached to a conduit tube which is in turn attached to the RF plasma outlet and the conduit tube is used as the susceptor for LF Induction heater.
• the tube radiates and convectively heats the matter passing through the conduit tube.
• the pyrolysis takes place in oxygen starved high heat atmosphere that does not allow dioxins, furans, and other hazardous by-products to be produced.
• the RF induced plasma can operate at extremely high temperatures ranging from 6000 to 1 1000 degrees centigrade.
• a separate LF induction heater is used in tandem with the RF plasma torch.
• the LF induction heater can be mounted after the RF plasma torch and can be mounted at an angle to the RF plasma torch to create a fluidized bath and allow the variation of rubber particle dwell time. This added dwell time breaks down any heavy oils, leaving behind long chain hydrocarbon gases that are used to increase the heating value of the syngas to produce energy from the waste tyres. Further, the LF induction heater can be rotated.
• the conduit tube can be any metal that can be inductively heated, typically made of iron or any of its alloy (due to their ferromagnetic nature), and possible materials that was tested were steel or even graphite.
• the different gas compositions from the tyre pyrolysis are affected by various factors including the reaction temperature, process dwell time, type of plasma gas and type of carrier gas. This variability of inputs provides the ability to produce a range in the parameters used during the recycling of the waste tyres.
• Waste material other than waste tyres may be processed using the method and system described above.

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Organic Chemistry (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Combustion & Propulsion (AREA)
• Materials Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Power Engineering (AREA)
• General Chemical & Material Sciences (AREA)
• Dispersion Chemistry (AREA)
• Environmental & Geological Engineering (AREA)
• Life Sciences & Earth Sciences (AREA)
• Sustainable Development (AREA)
• Health & Medical Sciences (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Processing Of Solid Wastes (AREA)
• Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Priority Applications (1)

Applications Claiming Priority (2)

Publications (1)

Family

ID=54256892

Family Applications (1)

Country Status (2)

Cited By (24)

Citations (3)

• 2012
  • 2012-06-07 SG SG2012042222A patent/SG195420A1/en unknown
• 2013
  • 2013-06-07 SG SG2014012199A patent/SG2014012199A/en unknown
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