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WO2013165113A1 - Composition cosmétique de maquillage contenant une résine silicone mq et une résine propyl-silsesquioxane - Google Patents

Composition cosmétique de maquillage contenant une résine silicone mq et une résine propyl-silsesquioxane Download PDF

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Publication number
WO2013165113A1
WO2013165113A1 PCT/KR2013/003412 KR2013003412W WO2013165113A1 WO 2013165113 A1 WO2013165113 A1 WO 2013165113A1 KR 2013003412 W KR2013003412 W KR 2013003412W WO 2013165113 A1 WO2013165113 A1 WO 2013165113A1
Authority
WO
WIPO (PCT)
Prior art keywords
resin
cosmetic composition
silicone resin
makeup cosmetic
propylsilsesquioxane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2013/003412
Other languages
English (en)
Korean (ko)
Inventor
조혜전
김경남
최경호
최영진
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020130043591A external-priority patent/KR102033017B1/ko
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Priority to CN201380022863.2A priority Critical patent/CN104271110B/zh
Priority to HK15100688.0A priority patent/HK1200121B/xx
Priority to US14/398,013 priority patent/US9463152B2/en
Publication of WO2013165113A1 publication Critical patent/WO2013165113A1/fr
Anticipated expiration legal-status Critical
Priority to US15/258,357 priority patent/US20160374929A1/en
Ceased legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585Organosilicon compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone

Definitions

  • the present invention relates to a makeup cosmetic composition containing MQ silicone resin and propylsilsesquioxane as active ingredients to keep the skin moist without drying or pulling the skin.
  • MQ silicone resins can be used to improve the persistence of pigments or other active agents on the skin as a method of prolonging the cosmetic film, but cosmetics to which the MQ silicone resin is applied have a disadvantage of being dry and pulling. Therefore, there is a need for a siloxane resin that has excellent moisturizing feeling and no pulling phenomenon at a level similar to the MQ silicone resin currently used in cosmetic formulations.
  • the skin pulling phenomenon is a phenomenon that comes easily when the skin lacks moisturizing power or poorly supplied with moisture, and the present inventors have found that MQ silicone resin and propylsilsesquioxane have excellent skin pulling prevention and moisturizing effects.
  • the present invention has been completed.
  • an object of the present invention is to provide a makeup cosmetic composition having excellent moisture retention and no pulling phenomenon by containing MQ silicone resin and propylsilsesquioxane resin.
  • the present invention relates to a makeup cosmetic composition containing MQ silicone resin and propylsilsesquioxane as active ingredients to keep the skin moist without drying or pulling the skin.
  • the makeup cosmetic composition according to the present invention forms a firm makeup film on the skin and can maintain moist skin without dryness or skin pulling.
  • FIG. 1 is a photograph of a state (a) coated with artificial leather 4 and Example 2 in artificial leather and a state (b) pulled after drying for 15 minutes after application.
  • the present invention relates to a makeup cosmetic composition containing MQ silicone resin and propylsilsesquioxane as active ingredients to keep the skin moist without drying or pulling the skin.
  • the MQ silicone resin is selected from M units represented by (R 1 3 SiO 1/2 ) a and Q units represented by (SiO 4/2 ) b .
  • R 1 may be independently an alkyl group or an aryl group having 1 to 8 carbon atoms. Examples of the alkyl group are methyl, ethyl, propyl, butyl, pentyl and hexyl and the like, and examples of the aryl group are phenyl, naphthyl, benzyl, tolyl, xylyl and xenyl and the like.
  • a and b represent integers greater than 0, and the ratio of a / b is 0.5 to 1.5.
  • the MQ silicone resin may further contain at least one of D and T units, provided that at least 80 mol%, or at least 90 mol% of the total MQ silicone resin is M and Q units.
  • the MQ silicone resin may be, for example, trimethylsiloxysilicate, but is not limited thereto.
  • the propylsilsesquioxane resin includes 80 mol% or more of the T unit represented by R 2 SiO 3/2 with respect to the total propylsesquioxane resin.
  • R 2 is independently an alkyl group or an aryl group having 1 to 8 carbon atoms, and at least 40 mol% is propyl.
  • the propylsilsesquioxane resin may further contain one or more selected from the group consisting of the M, D and Q units, but in this case, 80 mol% or more of the total propylsilsesquioxane resin is T unit. to be.
  • the propylsilsesquioxane resin can be, for example, polypropylsilsesquioxane.
  • the M unit, D unit, T unit and Q unit may be represented by the following Chemical Formula 1 as a silicone polymer unit.
  • the MQ silicone resin may be contained in an amount of 0.01 to 30% by weight, preferably 0.01 to 10% by weight based on the total weight of the composition. If it is less than 0.01% by weight does not contribute significantly to the skin moisturizing, if it exceeds 30% by weight is a severe pulling phenomenon.
  • the propylsilsesquioxane resin may be contained in an amount of 0.01 to 30% by weight, and preferably 0.01 to 10% by weight, based on the total weight of the composition. If it is less than 0.01% by weight does not contribute significantly to the skin moisturizing, if it exceeds 30% by weight may be a heavy feeling.
  • the MQ silicone resin and the propylsilsesquioxane resin may be contained in a weight ratio of 1: 150 to 150: 1 in the composition, preferably 1:80 to 80: 1. Can be. This is because when the weight ratio is out of the range, the feeling of use may be impaired.
  • compositions according to one aspect of the invention may be formulated containing a cosmetically or dermatologically acceptable medium or base. It is any formulation suitable for topical application, and may preferably include a type selected from the group consisting of water-in-oil type, oil-in-water type and oil-dispersed type. It may also be provided in the form of suspensions, microemulsions, microcapsules, microgranules or ionic (liposomal) and nonionic vesicle dispersions, or in the form of creams, skins, lotions, powders, ointments, sprays or concealed sticks. . It may also be used in the form of a foam or in the form of an aerosol composition further containing a compressed propellant. These compositions can be prepared according to conventional methods in the art.
  • Makeup cosmetic composition is a fatty substance, an organic solvent, a dissolving agent, a thickening agent, a gelling agent, an emollient, an antioxidant, a suspending agent used in cosmetics in the art within the scope of not impairing the object of the present invention , Stabilizers, foaming agents, fragrances, surfactants, water, ionic or nonionic emulsifiers, fillers, metal ion sequestrants, chelating agents, preservatives, vitamins, blockers, wetting agents, essential oils, dyes, pigments, hydrophilic or hydrophilic It may contain adjuvants commonly used in the field of cosmetics or dermatology, such as oil-based actives, lipid vesicles or any other ingredients commonly used in cosmetics. Such adjuvants are introduced in amounts generally used in the cosmetic or dermatological arts.
  • the composition of the present invention may contain a skin absorption promoting substance to increase the skin improving effect.
  • the powder component was dispersed in the silicone resin solution with the composition shown in Table 3 below, and the solution was thinly coated on artificial leather and dried for 15 minutes.
  • the dried artificial leather was pulled 30 times each up, down, left and right, and a physical stimulus was applied to observe the surface of the artificial leather to which the solution was applied.
  • a photograph of the surface of the artificial leather is shown in FIG. 1.
  • Example 2 Trimethylsiloxysilicate 95 47.5 Polypropylsilsesquioxane - 47.5 Alkylsilane Surface Treatment Titanium Oxide 4.00 4.00 Alkylsilane Surface Treatment Yellow Iron Oxide 0.30 0.30 Alkylsilane Surface Treatment Red Iron Oxide 0.10 0.10 Alkylsilane Surface Treatment Black Iron Oxide 0.07 0.07 Polymethyl methacrylate 0.53 0.53
  • the makeup cosmetic composition according to the present invention may provide a cosmetic that can maintain a moist makeup without drying by providing a siloxane resin composition including MQ silicone resin and having excellent moisture retention and no pulling phenomenon.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/KR2013/003412 2012-04-30 2013-04-22 Composition cosmétique de maquillage contenant une résine silicone mq et une résine propyl-silsesquioxane Ceased WO2013165113A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201380022863.2A CN104271110B (zh) 2012-04-30 2013-04-22 含有mq硅树脂及丙基倍半硅氧烷树脂的化妆品组合物
HK15100688.0A HK1200121B (en) 2012-04-30 2013-04-22 Make-up cosmetic composition containing mq silicone resin and propyl silsesquioxane resin
US14/398,013 US9463152B2 (en) 2012-04-30 2013-04-22 Make-up cosmetic composition containing MQ silicone resin and propyl silsesquioxane resin
US15/258,357 US20160374929A1 (en) 2012-04-30 2016-09-07 Make-up cosmetic composition containing mq silicone resin and propyl silsesquioxane resin

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2012-0045406 2012-04-30
KR20120045406 2012-04-30
KR10-2013-0043591 2013-04-19
KR1020130043591A KR102033017B1 (ko) 2012-04-30 2013-04-19 Mq 실리콘 레진 및 프로필실세스퀴옥산 수지를 함유하는 메이크업 화장료 조성물

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US14/398,013 A-371-Of-International US9463152B2 (en) 2012-04-30 2013-04-22 Make-up cosmetic composition containing MQ silicone resin and propyl silsesquioxane resin
US15/258,357 Continuation-In-Part US20160374929A1 (en) 2012-04-30 2016-09-07 Make-up cosmetic composition containing mq silicone resin and propyl silsesquioxane resin

Publications (1)

Publication Number Publication Date
WO2013165113A1 true WO2013165113A1 (fr) 2013-11-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2013/003412 Ceased WO2013165113A1 (fr) 2012-04-30 2013-04-22 Composition cosmétique de maquillage contenant une résine silicone mq et une résine propyl-silsesquioxane

Country Status (1)

Country Link
WO (1) WO2013165113A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020031488A1 (en) * 2000-06-19 2002-03-14 Mohamed Kanji Cosmetic compositions comprising at least one polymethylsilsesquioxane film former
JP3631941B2 (ja) * 1999-05-22 2005-03-23 ワツカー−ケミー ゲゼルシヤフト ミツト ベシユレンクテル ハフツング 化粧品での使用のための安定したクリーム状ゲル組成物、その製造方法および化粧品
KR20070004617A (ko) * 2004-02-02 2007-01-09 다우 코닝 코포레이션 Mq 및 t-프로필 실록산 수지 조성물
KR20070121059A (ko) * 2005-04-14 2007-12-26 모멘티브 퍼포먼스 머티리얼즈 인크. 특성이 강화된 실리콘 레진을 포함하여 구성되는 퍼스널케어 조성물, 그 제조 방법 및 사용 방법
KR20090054540A (ko) * 2007-11-27 2009-06-01 (주)아모레퍼시픽 지속성이 우수하고 묻어나지 않는 유중수형 메이크업화장료 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3631941B2 (ja) * 1999-05-22 2005-03-23 ワツカー−ケミー ゲゼルシヤフト ミツト ベシユレンクテル ハフツング 化粧品での使用のための安定したクリーム状ゲル組成物、その製造方法および化粧品
US20020031488A1 (en) * 2000-06-19 2002-03-14 Mohamed Kanji Cosmetic compositions comprising at least one polymethylsilsesquioxane film former
KR20070004617A (ko) * 2004-02-02 2007-01-09 다우 코닝 코포레이션 Mq 및 t-프로필 실록산 수지 조성물
KR20070121059A (ko) * 2005-04-14 2007-12-26 모멘티브 퍼포먼스 머티리얼즈 인크. 특성이 강화된 실리콘 레진을 포함하여 구성되는 퍼스널케어 조성물, 그 제조 방법 및 사용 방법
KR20090054540A (ko) * 2007-11-27 2009-06-01 (주)아모레퍼시픽 지속성이 우수하고 묻어나지 않는 유중수형 메이크업화장료 조성물

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