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WO2013034712A1 - Nouvelles utilisations de matériau en feuille recyclé - Google Patents

Nouvelles utilisations de matériau en feuille recyclé Download PDF

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Publication number
WO2013034712A1
WO2013034712A1 PCT/EP2012/067543 EP2012067543W WO2013034712A1 WO 2013034712 A1 WO2013034712 A1 WO 2013034712A1 EP 2012067543 W EP2012067543 W EP 2012067543W WO 2013034712 A1 WO2013034712 A1 WO 2013034712A1
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WO
WIPO (PCT)
Prior art keywords
cellulose
release
grinding
paper
release agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/067543
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English (en)
Inventor
Eric Van Pottelbergh
Bart Verhasselt
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Reculiner
Original Assignee
Reculiner
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Filing date
Publication date
Application filed by Reculiner filed Critical Reculiner
Publication of WO2013034712A1 publication Critical patent/WO2013034712A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04—Disintegrating plastics, e.g. by milling
    • B29B17/0412—Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04—Disintegrating plastics, e.g. by milling
    • B29B2017/0424—Specific disintegrating techniques; devices therefor
    • B29B2017/0484—Grinding tools, roller mills or disc mills
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2711/00—Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
    • B29K2711/12—Paper, e.g. cardboard
    • B29K2711/123—Coated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/008—Wide strips, e.g. films, webs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00—Layered products
    • B29L2009/005—Layered products coated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/744—Labels, badges, e.g. marker sleeves
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the present invention relates to new uses of recycled cellulose or polymeric sheet material coated with a release agent, such as used as liner for self-adhesive labels and films.
  • Self adhesive labels, films, and tapes have become very popular for their versatility and ease of use, since no extra gl ue is required to make them adhere to a su bstrate. They are used extensively in offices and by school children of course, but also large volumes are used by industries for labelling their products.
  • the self-adhesive labels are provided attached to a release liner made of paper or a polymeric carrier and usually coated at least on one side with a release agent, most often consisting of a silicone release layer, which provides a release effect against the adhesive of the label.
  • Other release agents are someti mes used, such as wax, paraffin, low surface energy fluorinated compounds, etc.
  • sil icone coated liners are given in US5275855 , JP07279099, and US6036234. Silicone or other release agent coated liners are also used more generally as backing in the production of films, such as PVC fil ms.
  • the total global consumption of release liners in 2008 is believed to be around 32 Billion square meter of coated product, which is equal to 75% of the surface area of Switzerland. Approximately 85% of this material is paper based and 1 5% is plastic based (cf. http: / /en.wikipedia.org /wiki / Release_l iner).
  • the liners are pure waste and must be disposed of. Considering the volumes mentioned above, this results in a great source of waste, which is coming under the scrutiny of several governments which intend to tax the disposal thereof as packaging material .
  • the issue is rendered even more sensitive for cellulose release l iners because the cellulose carriers are usually made of virgin material which has never gone through any recycling cycle yet. Recycling paper coated with a release agent by conventional repulping methods for making printing or packaging paper is possible but difficult without loss in quality because of insufficient disintegration of the fibres and sticking of resin particles on the rolls and felts due to the release coating.
  • Cellulose insulating material has a much lower "embodied energy" than e.g., glasswool or rockwool insulation, wherein the embodied energy is the sum of the energy to transport the raw material to the manufacturing facility + the energy for manufacturing the product + the energy to deliver the manufactured product.
  • embodied energy is the sum of the energy to transport the raw material to the manufacturing facility + the energy for manufacturing the product + the energy to deliver the manufactured product.
  • DEI 9653243 discloses a heat and acoustic insulating material made of cellulose fibres from old paper and impregnated with e.g. boric acid or salts thereof as flame retardant and against formation of mould, wherein the cellulose fibres come at least partly from sticky paper labels.
  • DE4334200 discloses a process for producing thermally insulating materials from waste paper by means of a mild hydromechanical treatment with subsequent drying using hot air. The boards or mats formed therefrom have a very low specific density, from which a high thermal insulation value results.
  • WO2002090682 discloses sound insulation partitions comprising at least a substantially homogeneous self-supporting rectangular cellulose mat having a density ranging between 200 and 800 kg/m 3 , said mat essentially consisting of fibres derived from the treatment of practically lignin-free recycled papers or paperboards, the bond between the fibres within the mat being obtained at least partly during the production of the mat by wet process.
  • DE4402244 discloses a sound and heat insulating material made from a dried, aqueous suspension containing 1 0-50 wt% chopped waste paper and 90-1 0 wt% animal and/or plant fibres such as hairs, short wool fibres, etc.
  • the mixed suspension is placed on a sheet former, in particular on a sieve, where the water is removed.
  • a flat flexible mat is formed and subsequently dried and finished.
  • DEI 9835090 discloses a method of production of cellulose insulation materials including the control of various parameters in the mill to obtain a homogeneous material comprising additives.
  • DE3641 464 discloses an insulating board made of a mixture of old newspapers free from any surface treatment or fillers, natural fibres, and a glue and/or reaction promoter.
  • EP061 71 77 discloses a skin/core building element for heat insulation and vibration damping wherein the core is made of a filler of paper like material and thin thermoplastic component to act as binder upon melting.
  • DE4403588 discloses heat insulation components constructed in the form of hollow blocks and prefabricated wall boards, produced, in particular, from pulped, water-resistant old paper, such as old labels, stickers, high-gloss paper, advertising posters and billboards (signs), mixed with water, cement and sand.
  • a preferred mixture ranges from 50 vol% to 80 vol% of water-resistant old paper, from 1 0 vol% to 20 vol% of cement, and from 1 0 vol% to 60 vol% of sand.
  • US2009/ 01 73464 discloses an acoustic panel comprisi ng from 1 0-40 wt% cellulosic fibres, 0-30 wt% gypsu m, 0- 1 5 wt% starch and other components.
  • DEI 0336569 discloses a fire-resistant gypsum fibreboard made from a mixture of 87-78% gypsum and 1 3-22% cellulose fibres made from used paper as a reinforcing component and a 35- 50% boric acid based on the fibre weight for raising the flame resistance.
  • DE202005501 1 4581 discloses a cellulose based insulation material for the exhaust system of a combustion engine and US2002025421 discloses a sound absorbing insulation material containing cellu lose for the cabin of a motor vehicle.
  • DE4331 567 discloses a l ight weight fire protection element for the aircraft industry made of waste paper mixed with a special binder, resulting in an "apparently paradoxical fireproof material made of paper”.
  • the present invention concerns method for treating waste material in the form of release coated cellulose or polymeric sheets comprising the following steps :
  • additives selected from flame retardant, hydrophobic material, pesticides, nutrients, minerals and mixtures thereof and mixing them with the recycled material;
  • the overall efficacy of the new use in accordance with the present invention is further facilitated if the release coated cellulose or polymeric sheet material is collected from producers and end-users thereof in the form of dense, bulky masses, such as rolls and stacks, which are pre-shredded into smaller, less dense masses in preparation to step (b).
  • New uses such as the fields of insulation materials and filling for upholstery which will be discussed more in detail below can be reached if said collected material already comprises a flame retardant, such as boric acid or any salt thereof.
  • the flame retardant would be added to the sheet carrier by the sheet manufacturer, thus anticipating and promoting the recycling of the produced material.
  • the present method is highly advantageous as it is possible for certain release agent coated sheets to mechanically separate, during the primary and /or secondary grinding operations, a substantial fraction of the release coating from the sheet carrier, in the absence of any chemical treatment. If dry -grinding is chosen as the grinding method , the two fractions may then be separated in a separating station, separating the incoming stream into a first, carrier rich fraction and a second, release agent rich fraction.
  • the separating station may comprise one or more of a cyclone, a filter, and an ultrasonic or an electrostatic separation means.
  • This embodiment is very advantageous as it permits the use of the carrier rich fraction to be further processed to produce either insulation materials, e.g., in the form of insulation batts or sheets; or to incorporate a conventional repulping process in an aqueous medium for producing recycled paper.
  • insulation materials need not necessarily be formed from a carrier rich fraction, and is advantageously obtained directly from the comminuted release coated cellulose or polymeric sheet material, possibly blended with e.g., comminuted waste paper such as newspaper, to yield insulation materials of different grades, qualities, and prices.
  • the cellulose and/or the release agent rich fractions may further be treated to become suitable for use as a filler, a binding agent or a viscosity modifier in concrete, cementitious, asphalteous, clay or lime mixtures and coatings, paints and other building materials.
  • the collected or treated material may be blended with cellulose or polymeric sheet waste material from other origins, or with a release agent, for example from the release agent rich fraction obtainable from the separation discussed supra.
  • the second, release agent rich fraction separated from the carrier material can be blended with ground cellulose or polymeric sheet waste material from other origins in order to control the content in release agent of the final material.
  • the cellulose rich fraction thus obtained may be further processed in a wet shaping station to form sheets of paper.
  • a flame retardant preferably boric acid or any salt thereof may be added to, and mixed with the recycled material before, during or after the grinding steps (c).
  • beneficial flame retardant effects can be obtained by adding fungal tissue preferably the mycelium to the waste material prior, during or after the grinding process.
  • the waste material can be inoculated with a suitable fungal species prior to the grinding process, allowing the fungal tissue to form itself prior or after the grinding process.
  • Yet another alternative could be the inoculation of the ground material in its final application allowing the in situ creation of flame retardancy by the fungal growth.
  • Spent oyster mushroom substrate (Ostreatus pleurotus) has been identified as a possible source for the above application.
  • this spent oyster mushroom substrate may not only be used as an additive, but also in its pure form, allowing to obtain a flame retardant mass that can be used for different purposes equal or similar to the ones based on the sources of release coated cellulose or polymeric sheet material mentioned below.
  • This flame retardant mass can either be used as such or alternatively ground and/or compressed thus obtaining different application possibilities.
  • a preferred source of release coated cellulose or polymeric sheet material is liners for holding self-adhesive labels or films. They can conveniently be collected at the liner manufacturers, the self-adhesive label base material manufacturers, the label printers, the producers of goods on which are applied self-adhesive labels, and so on, all of them generating large volumes of such liners.
  • the release agent is generally one of silicone, wax, paraffin, or fluorinated material.
  • release coated cellulose or polymeric sheet material is liners used for the production of cast polymeric materials, self-adhesive tapes etc.
  • Recycled material obtained from the method discussed above can be used in various application.
  • the thermal and acoustic insulating properties thereof can advantageously be used for insulating thermally and/or acoustically any of:
  • the recycled release coated cellulose material may be used for the production of recycled paper in a conventional wet process.
  • Another field of applications of release coated cellulose sheet material is casing soil or growing medium used for growing some vegetables and mushrooms, or as additive to earth to enhance the water balance and water flow in said soil or earth.
  • the treated material offered an optimal water buffering effect for the growth, e.g., of mushrooms.
  • the material seems to act as a heat capacitor, absorbing heat, which it gradually releases in time. This property may also partly explain the excellent growth of mushrooms observed with the present material. This property makes the material suitable for other applications such as hot pillows, or hot compresses to be applied onto the skin.
  • the heat capacitive properties of the material can be used to this effect, by e.g., lining the walls of the packaging with the present material, preferably sandwiched between two walls of the packaging.
  • Hydromulching / hydroseeding is another application wherein the present material shows excellent potential. Hydromulching is applying a slurry of water, wood fibre mulch, and often a tackifier, to prevent soil erosion. Hydroseeding, often used as synonym of hydromulching, is a method for planting seeds, e.g., in the field of grass planting, comprising the steps of mixing mulch, seed, fertilizer, and water in the tank of a hydromulching machine. The mixed material is then pumped from the tank and sprayed onto the ground. The material is often referred to as a slurry, much like a soupy batch of green papier-mache. Once applied to the soil, the material enhances initial growth by providing a microenvironment beneficial to seed germination.
  • the present invention also concerns an insulation material comprising shredded recycled material, flame retardant, and optionally other components.
  • the paper or thermoplastic sheet material is a liner for adhesive labels, tapes, or films, and is preferably coated with sil icone as release agent and the carrier is as follows:
  • the cellulose sheet material is paper, preferably glassine paper or kraft paper, or, alternatively,
  • the polymeric sheet material is a thermoplastic film, preferably selected from PE, PP, or PET.
  • the insulation material of the present invention is preferably in a form suitable for blowing it dry into a cavity, as loose fill onto a surface, or wet against a surface.
  • it can be in the form of a batt or a sheet.
  • Figure 1 shows a transversal cut of a release coated carrier, typically used as liner for adhesive labels and the l ike.
  • Figure 2A shows a schematic representation of a first embodi ment of the method of the present invention.
  • Figure 2B shows a schematic representation of a second embodi ment of the method of the present invention.
  • Figure 3 shows three embodiments for the appl ication of an insulating material in a building or means of transportation ;
  • Figure 4 is a flowchart illustrating the complete life cycle of a release coated sheet material form production, use thereof as liner, to recycling thereof, in case (a) of no flame retardant in the original sheet carrier, and (b) of an original sheet carrier comprising flame retardant.
  • the present invention offers a new and advantageous solution to the d ifficult problem of recycling release coated sheet carriers (1 ), in particular silicone coated carriers which are widely used e.g., as liners for self adhesive labels, tapes, films and the like.
  • such liners comprise a carrier (2) wh ich is often a cellulose material , such as glassine paper or kraft paper, or alternatively, the carrier (2) can be a thermoplastic film, made of a polyolefin like PE or PP, or of a polyester such as PET, PEN, etc.
  • the term "sheet” is used to designate "a wide expanse or thin piece of something" (The Chambers Dictionary (2000)), which can be continuous or in d iscreet pieces of regular or irregular geometry, presented in any form such as rolled, stacked, or even crumpled.
  • the carrier (2) is coated on one or two sides with a release agent (3), which provides a release effect against any type of sticky material such as the adhesive on a label .
  • the release agents (3) most widely used on liners for adhesive labels, tapes, fil ms, and the like, are crosslinkable silicones, but other release agents such as wax, paraffin, polyurethane or a fluorinated or acrylic based material may also be fou nd.
  • the release agent is generally applied in an amount of the order 0.2 to 1 0.0 g / m 2 , wh ich is enough to degrade the quality of paper recycled with such cellulose based liners by traditional wet paper repulping processes, because the disintegration of the fibres is insufficient and the resin particles tend to stick on the rolls and felts.
  • This is a major inconven ience because unlike newspapers and the like, paper used for liners is generally prod uced from virgin material, which has never gone throug h any recycling cycle and has therefore a high ecological value.
  • solutions exist to overcome this d rawback associated with conventional wet repul ping processes, but they require additional treatment steps and chemicals. The problem is even more acute when the carrier is a thermoplastic film since the generally crosslinked release coating cannot be easily separated from the carrier and may not be melted and reprocessed therewith .
  • the present invention provides particularly advantageous new uses of recycled both cellulose and thermoplastic based release coated carriers (1 ) such as li ners.
  • the release coated carrier may be processed to form a novel and advantageous insulating material (1 0) suitable for the sound and thermal insulation of buildings and of sound barriers along the roads, as well as of means of transportation such as automotive vehicles, trains, airplanes, and the like. It can also be used to fill quilted garments and blankets, or upholstery. Other applications are possible, such as growing medium for mushrooms, vegetables, plants, etc. , or as heat capacitor in heated pillows or compresses to be applied on the skin.
  • a cellulose rich fraction may be separated from a release agent rich fraction.
  • Each fraction can be treated separately in conventional recycling processes, or combined with other sources of materials for further processing.
  • the waste material can be collected from the producers and end users of for example adhesive labels, etc. like offices and administrations, but it is preferably collected from industries generating large amounts of waste liners.
  • the waste material can be collected from liner manufacturers, self-adhesive labels manufacturers, label printers, producers of goods on which are applied self-adhesive labels, and the like.
  • the thus produced laminate is then slit to the desired width of the labels, thus generating large amounts of waste.
  • label printers if different from the former, as they may be in charge of the final cutting of the labels.
  • the producers of goods on which are applied self-adhesive labels will generate as much liner waste as self-adhesive labels are applied on their goods.
  • the amount of waste liner material thus generated can be huge and these industries are usually equipped with automated collecti ng means for collecting the waste liners, as described e.g. , in WO2005 1 1 0902. In most cases, the huge amou nts of waste liners thus collected are in the form of dense, bulky masses, usually rolls or stacks.
  • the collected release coated sheet waste material may be conveyed with supplying means (21 0), such as a conveying belt, to a supply station (2 1 ).
  • supplying means 21 0
  • a supply station 2 1
  • the collected material is in the form of dense, bulky masses (29a), such as rolls or stacks of liners, which cannot be ground as such in, for example, conventional dry-grinding lines
  • the material is first supplied from supply station (21 ) to a pre-shredding station (22), breaking the dense masses of sheet material into looser chunks and lumps of smaller sizes suitable for being ground in dry conventional grinding stations.
  • Pre-shredding stations suitable for the purpose of the present invention can be found, as illustrative purpose and in no way being restricted thereto, in the catalogue of the company SSI Shredding Systems (cf. e.g. , www.ssiworld.com/watch / industrial_paper.htm and www.ssiworld.com /watch / printers- waste.htm).
  • the thus pre-shredded chunks of waste material are comparable in size and texture with more traditional sources of household waste sheet material comprising newspapers, magazines, packaging, etc., and may from here on be blended with other such sources of waste material.
  • the release coated waste material blended or not with other sources of waste material, can be prepared for pri mary grinding by mixing it and removing all foreign bodies such as metal clips, staples, plastic sheets in case of cellulose waste material, and the like.
  • the material can be wet or dry-shredded and wet or dry-ground into particulate material in a grinding station (23), (24). It is often preferred to use several grinders, which can be grouped as a primary, coarser grinder (23) and a secondary, finer grinder (24).
  • the thus prepared waste material is shredded into small pieces, preferably into stripes of an average length comprised between 5 and 30 mm, more preferably, between 7 and 20 mm, most preferably between 1 0 and 1 5 mm. For some applications, this size is sufficiently small and the material needs no further comminution steps.
  • the primary grinding station (23) may be connected to an additive supply means (28a) to add additives such as flame retardants, hydrophobic materials, pest repellents, and the like.
  • the material may also be blended with other sources of waste material in the primary grinding station (23).
  • the stripes thus obtained may also undergo a crimping process to yield an insulating material with higher specific volume. For many applications, however, it is preferred to further reduce the size of the particles to lower than 1 0 mm.
  • the stripes of waste material may be transferred to a secondary grinding station (24).
  • the secondary grinding station (24) may be composed of a cascade of several grinders (24a), (24b), (24c).
  • the size of the stripes is further reduced to an average particle size smaller than 4 mm, preferably smaller than 2 mm; more preferably smaller than 1 mm.
  • the secondary grinding station (24) may be connected to an additive supply means (28b) to add additives. Suitable primary and secondary grinding stations may be found, for example, in
  • the dry -grinding is a grinding process whereby only a limited amount of liquid is added onto the material, such as flame retardant, and other additives, whereas wet-grinding includes the formation of a suspension of the treated material in a liquid as in conventional paper repulping processes.
  • the treated material is in a solid form.
  • the particulate material 26(b) is transferred to a treating station (26c) for e.g., shaping the material into sheets, panels, batts, etc. and/or for packaging.
  • Treating station (26c) may be connected to an additive supply means (28c) to supply e.g., water, an organic or mineral binder (e.g., cement), flame retardant, a dye, or the like.
  • Treating station (26c) may comprise any means for shaping the recycled particles in any desired form, such as a press to form e.g., panels, means for dewatering the slurry to form sheets, in case water was added after dry-grinding the material, curing means, such as convection, induction or IR-ovens, UV-station, etc, in case a binder is used, and the like.
  • the recycled material (1 0) can then be removed with conveying means (21 1 ) and is ready for commercialisation as insulating material as dry particulate, sheets, panels, batts, and the like, as is discussed below.
  • the comminuted material may be advantageously used as a filler, a binding agent or a viscosity modifier in concrete, cementitious, asphalteous, clay or lime mixtures and coatings, paints and other building materials
  • Another possible application for the thus recycled material (1 0) is in hydro mulching or hydro seeding applications, with enhanced results compared with similar applications with conventional paper, in particular, with respect to dry crust formation and clogging observed with conventional paper.
  • the comminuted release coated material can also be used as casing soil in replacement of, or complement to peat casing soil used for growing some vegetables and mushrooms.
  • the treating station (26c) could include composting means and the additive supply means (28c) may include a source of nitrogen and possibly a source of a hydrophobic material.
  • Composting and nitrogenation are preferably carried out off-line from the grinding line, as illustrated by the broken line (26b). It can also be taken profit of the advantageous behaviour of the materials produced with the method of the present invention by using it as additive to earth, to enhance the water balance and water flow in said earth and soil.
  • the treated material shows a relatively high heat capacity, storing energy that it releases gradually to ambient. This property could partly explain the excellent results obtained with mushrooms.
  • the compost layer is the layer containing fermented manure, straw and some different additives, and acts as feeding stock for the growth of the mushrooms. This compost layer is covered by casing soil onto which the mushrooms start growing.
  • the current problem with this system is the initial rising of the temperature of the compost in the first days of the process. This leads to too fast and uncontrolled mycelium growth.
  • the traditional way of solving this problem is to cool down the whole atmosphere in the room. Besides costing a lot of energy, the negative effect of the cooling is a slowing down of the entire growth cycle by several days.
  • the property of the present material to act as a heat capacitance, absorbing thermal energy that it releases gradually in time can advantageously be used in heated pillows and compresses to be applied on the skin, or to not only passively insulate a piece of good contained in a package, but actually actively heating it.
  • a substantial fraction of the release coating is mechanically released from the carrier during the primary or secondary grinding stages (23), (24). This may happen in particular when dry-grinding is used as grinding process in that dry-grinding generates intense shear stresses that may provoke cohesive failure in the carrier material, close and parallel to the interface between carrier and release coating.
  • the separating station may comprise any known means for separating two bodies having differing physical and chemical properties, such as, for example, a cyclone, a floatation station, a filter, and ultrasonic or electrostatic separation means, and any combinations thereof.
  • the release agent rich fraction (27) may further be processed in a treating station (27a) to to be suitable for use as a filler or a binding agent in concrete, cementitious asphalteous, clay or lime mixtures and coatings.
  • the release agent rich fraction (27) may be added to a stream of cellulose insulation material based on waste paper other than release coated, such as newspapers, magazines, packaging material, and the like, to enhance the properties thereof.
  • the carrier rich fraction (26) may further be processed in a treating station (26a) to produce, as discussed above in respect of station (26c) in Figure 2(a), an insulating material of more accurately controlled composition or, alternatively, to produce recycled paper by methods well known in the art in case of cellulose carriers.
  • the recycled product (1 0a) can then be removed with conveying means (21 1 ).
  • the further treatment of both fractions in treating stations (26a), (27a), in particular if it concerns producing recycled paper with the cellulose rich fraction, needs not necessarily be carried out continuously in the same production apparatus but, as illustrated by the broken lines (26), (27), it may be carried out in another plant.
  • the treated material can be used as insulating material (1 0) to be applied in different forms and different ways to a surface;
  • the insulating material (1 0) may be blown in a dry form with a gun (20) into a cavity (1 3) formed by two panels or walls or any retainer (1 ).
  • the material can be blown through a hole drilled on top of the outer panel of a wall.
  • the insulation material (1 0) must be blown until it reaches the appropriate density. With this form of application settling is observed and may reach as much as 20% with state of the art cellulose insulation materials. It is usually observed that a lower degree of settling occurs with higher initial densities.
  • the level of settling is very much reduced with the insulation material of the present invention since the silicone acts somewhat like a loose binder that stabilizes the structure.
  • a similar stabilizing effect can also be obtained as the result of the presence of ground self-adhesive label material originating from a certain percentage of self-adhesive labels still adhered to the release coated sheet material prior to grinding or brought into the production stream at any stage thereafter.
  • the front panel may be withdrawn if desired as, depending on the degree of compaction thereof, the material will remain in place.
  • the application of the insulating material (1 0) by dry blowing has the advantages of minimizing air gaps especially around inserts or intricate regions.
  • the insulating material (1 0) in a particulate form may also be sprayed in place with a gun (20) against a wall (1 ) or even a horizontal ceiling by mixing it with a fluid like water. Upon drying the material will remain in place thanks to the hydrogen bonds between cellulose hydroxyl groups created by the fluid such as water.
  • the carrier (2) is a thermoplastic material, the use of a binder may be necessary in this type of applications.
  • the insulation material (1 0) in a particulate form for blowing/spraying it can be supplied as preforms (1 0A) such as batts, sheets, mats, tiles, or even bricks.
  • a binder may be necessary, but not mandatory, as with cellulose materials sufficient integrity of the preforms may be obtained through a wet process.
  • a binder can be organic, like a glue or a resin, or mineral like cement, gypsum, etc. Fillers like sand, talc, etc. may be used too.
  • the preforms (1 0A) may have a sandwich structure with two skins holding a central core made of the insulating material (1 0).
  • a single skin may be sufficient.
  • the role of the skins is not restricted to mechanical integrity of the preforms (1 0A), but may advantageously act as a barrier against moisture, gas, radiations, etc. and can therefore be useful when a binder is used too.
  • FIG. 3 illustrates embodi ments of applications in the insulation of a building.
  • the insulation material of the present invention can be used in other fields such as the transportation industry, e.g., in applications as disclosed e.g., in DE202005501 1 581 and US200202542 1 for the automotive industry and in DE4331 567 for the aircraft industry. It can also be used on sound dampening wall along roads. Other applications can be found in the textile industry, as fill for quilted garments and blankets or even for upholstery and mattresses.
  • the insulation material of the present invention has an even lower embodied energy than most traditional cellulose insu lation materials for the following reasons.
  • Traditional cellu lose material is generally made of recycled paper of various origins, including newspapers, printed matter, wrapping papers, etc., which may need an additional treatment to eliminate inks and volatile components before being reprocessed into insulation material. This additional treatment usually involves a thermal treatment with chemicals, which is not necessary with waste liners collected from industrial end users, as the material is homogeneous and devoid of any printed matter.
  • Another advantage of the insulation material of the present invention is that packaging volume can be reduced with respect to most traditional cellulose insulation materials on the market.
  • Particulate cellulose insulation material is generally su pplied in 1 0- 1 5 kg packages with a degree of compaction which is lim ited by the ability of the compacted material to fluff up to the desired density upon dry blowing thereof.
  • the degree of compaction of the packaged materiel is about double of the desired density of the insulation material in place when applied d ry, i.e., with one package of volu me Vi , a cavity of volume of the order of 2 x Vi can be filled . It has been found that insulation material according to the present invention could be dry blown to a desired density even when the material was packaged with a degree of compaction of three or four (i.e., down to a volume of the order of 1 ⁇ 2 Vi).
  • the insulation material obtained with the method of the present invention is advantageous over other similar materials of the prior art, even without separation of the release coating from the carrier, because the presence of the generally crosslinked release agent such as silicone gives the particulate material a cohesion which cannot be found in the prior art materials without the addition of a separate binder.
  • This cohesion is advantageous in dry blow applications (cf. Figure 3(a)) because it reduces substantially the amount of dust upon blowing, and it especially reduces substantially the level of settling of the material, yielding an insulation layer stable in time and homogeneous throughout the height of the insulated wall.
  • wet spraying applications cf.
  • VOC volatile organic compounds
  • allergies cf. e.g., http:/ /www.healthyhouseinstitute.com/a_688- Cellulosejnsulation.
  • VOC volatile organic compounds
  • large volumes of release coated sheet material can be recovered directly from companies, a control on the quality of the waste material to be recycled never afforded to date is possible, thus allowing to provide a "premium version" of VOC-free insulation material.
  • a flame retardant such as boric acid
  • This step increases substantially the overall cost of production and use of such materials for the following reasons.
  • An additional flame retardant dosing station with metering means must be provided in the material treatment apparatus, prior to packing and shipping the material. This additional investment can easily be absorbed by a high production line, producing centrally material to be distributed over a rather large area for use by the operators. The finer the material is comminuted, however, the higher the packaging volume, with direct consequences on the cost of transportation.
  • the liner producers (1 00) treat their liners with flame retardant to yield flame retarded liners (FR-liners (1 01 b) (cf. Figure 4).
  • the amount of flame retardant for treating a given amount of liner material is less if applied directly to the pulp by the liner producer, upstream of the life cycle of the material, than if added at any stage after collection of the liner waste material.
  • the flame retardant is more homogeneously distributed at the level of the cellulose fibres, it is likely that higher fire resistance classes can be reached by the paper producer with the same amount of flame retardant.
  • FR-liners would be sold at a higher cost to the printer (1 02b) who would sell their labels applied on flame treated liners to the end users (1 03b) to an overall higher cost, comprising the non refundable price of a label applied on a non flame treated liner + a refundable, recycling deposit for recycling the liner.
  • the waste FR-liners are collected as described above, and the recycling deposit is refunded to the end user, by the recycling operator, who can save money in flame retardant, and transportation.
  • the material needs only be dry-ground to the desired particle size prior to being used as insulating material in the building, transportation, furniture, or apparel industries (1 08) without the need of adding any additional flame retardant.
  • An insulating material according to the present invention is particularly advantageous because, on the one hand, it offers a solution for recycling huge volumes of release coated sheet material such as liners, which is otherwise very difficult to recycle and, on the other hand, because the properties of this material, in particular volumetric stability in time, are superior to most existing comparable products in the market, obtained from other sources of sheet materials.
  • the insulating material (1 0) of the present invention comprises shredded and ground particles of recycled release coated sheet material admixed with additives to control the resistance to flame, moisture, and pests, such as insects, bugs, rodents, etc. as discussed supra.
  • boric acid or any salt thereof is the most commonly used flame retardant and is particularly advantageous, since not only does it provide the required resistance to flame but it also provides moisture, mould, and microbial resistance and acts as a repellent against pests of different kinds.
  • Salts of boric acid that can be used are for example, borax with different levels of hydratation, such as borax penthahydrate and borax decahydrate.
  • Boric acid or salts thereof may be applied in an amount comprised between 1 and 50 wt%, preferably between 1 0 and 45 wt%, more preferably between 25 and 40 wt%. It can be added to the recycled material as dry powder but is in some cases mixed with water and wet sprayed into the recycled material.
  • flame retardants may be used instead of or additionally with the boric acid or salt thereof, such as mono- or diammonium sulphate, aluminium sulphate, aluminium hydroxide, soda ash, anhydrous silica gel, diammonium phosphate, sodium tetraborate, ferrous sulfate, zinc sulfate, and mixtures thereof, as disclosed, e.g., in US41 82681 .
  • beneficial flame retardant effects can be obtained by adding fungal tissue preferably the mycelium to the waste material prior, during or after the grinding process.
  • the waste material can be inoculated with a suitable fungal species prior to the grinding process, allowing the fungal tissue to form itself prior or after the grinding process.
  • a suitable fungal species prior to the grinding process
  • the fungal tissue can form itself prior or after the grinding process.
  • Yet another alternative could be the inoculation of the ground material in its final application allowing the in situ creation of flame retardancy by the fungal growth.
  • Spent oyster mushroom substrate (Ostreatus pleurotus) has been identified as a possible source for the above application.
  • this spent oyster mushroom substrate may not only be used as an additive, but also in its pure form, allowing to obtain a flame retardant mass that can be used for different purposes equal or similar to the ones based on the sources of release coated cellulose or polymeric sheet material mentioned below. This flame retardant mass can either be used as such or alternatively ground and/or compressed thus obtaining different application possibilities.
  • the mixture of recycled material and additives can then be used as such for blowing/spraying dry or with addition of some water to enhance adhesion to non horizontal walls (cf. Figure 3(a)&(b)) or, alternatively, can be formed into a sheet, batt, or the like by pressing optionally with admixture of a binder and/or sandwiched between two sheets.
  • additives or fillers may of course be added as well known by the persons skilled in the art.
  • Material clogging in a hose is a major issue when blowing/spraying the insulation material in place. This is particularly sensitive when there is a reduction of the tube diameter, e.g., for allowing access to thinner cavities.
  • a tube reduction connector is used to connect two hoses of different diameter, as can be found, e.g., in http:/ /www.x- floc.com/en/zubehoer/schlaueche-zub.html. Clogging often occurs at such reduction connectors when the blowing/spraying is resumed after an interruption.
  • the test carried out intends to simulate a blowing situation wherein, at the end of cavity filling, the operator gives a last extra shot of material to prevent settling. At that moment, pressure continues to build up in the hose while there is hardly any material flowing out anymore and material density builds up in the hose. After 20 seconds, the operator finally switches off the machine and inserts the hose into another, empty cavity. At that moment, the flow in the connecting part between the 2 hoses is very critical, and if not sufficiently high, clogging occurs.
  • COMPARATIVE one of the major cellulose brands available on the Belgian market with an average particle length of about 4 mm.
  • Tests were performed 5 times with each material by filling a first cavity of dimensions 1 000 X 400 X 1 00 mm, continuing blowing for 20 s after filling of the cavity to build up the pressure within the hose and switching off the pump. After 30 s, the pump was activated again with the hose introduced into a new, empty cavity. The comparative cellulose material clogged 4 times out of 5 when started again, requiring the manual unclogging of the reduction connector, whilst the silicone coated cellulose material according to the present invention started flowing again immediately in all five repetitions of the test.
  • the present invention therefore not only offers an economically and ecologically viable solution to the recycling of release coated liners, which are particularly difficult to recycle, but also provides an alternative insulating material with enhanced properties over the conventional insulating materials available in the market.

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L'invention concerne une nouvelle utilisation de cellulose revêtue de manière antiadhésive ou de matériau en feuille polymère et un procédé de traitement de cellulose revêtue de manière antiadhésive ou de matériau en feuille polymère comprenant les étapes suivantes : (a) collecte de cellulose revêtue de manière antiadhésive ou de matériau en feuille polymère chez des producteurs et des utilisateurs finaux ; (b) préparation éventuelle du matériau collecté par mélange, séparation de corps étrangers comme des métaux, etc., et alimentation de celui-ci dans un poste de broyage-séchage (23), (24) ; (c) déchiquetage et broyage des matériaux dans un ou plusieurs postes de broyage (23), (24) ; et (d) addition éventuelle d'additifs sélectionnés parmi des agents ignifuges, un matériau hydrophobe, des pesticides, des nutriments minéraux et leurs mélanges, et mélange de ceux-ci avec le matériau recyclé.
PCT/EP2012/067543 2011-09-07 2012-09-07 Nouvelles utilisations de matériau en feuille recyclé Ceased WO2013034712A1 (fr)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110089342A (zh) * 2019-04-26 2019-08-06 山西省农业科学院食用菌研究所 一种草生菇覆土用网垫及其制备与使用方法
CN112497777A (zh) * 2020-11-27 2021-03-16 陈辉煌 一种可diy香薰蜡块制作装置
FR3157235A1 (fr) * 2023-12-20 2025-06-27 Jonathan BRUNETON Procédé de recyclage de filtres de traitement d’air usagés

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110089342A (zh) * 2019-04-26 2019-08-06 山西省农业科学院食用菌研究所 一种草生菇覆土用网垫及其制备与使用方法
CN112497777A (zh) * 2020-11-27 2021-03-16 陈辉煌 一种可diy香薰蜡块制作装置
FR3157235A1 (fr) * 2023-12-20 2025-06-27 Jonathan BRUNETON Procédé de recyclage de filtres de traitement d’air usagés

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