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WO2013031313A1 - Composition de prétraitement pour coloration capillaire - Google Patents

Composition de prétraitement pour coloration capillaire Download PDF

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Publication number
WO2013031313A1
WO2013031313A1 PCT/JP2012/063620 JP2012063620W WO2013031313A1 WO 2013031313 A1 WO2013031313 A1 WO 2013031313A1 JP 2012063620 W JP2012063620 W JP 2012063620W WO 2013031313 A1 WO2013031313 A1 WO 2013031313A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
hair color
composition
pretreatment composition
hyaluronic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2012/063620
Other languages
English (en)
Japanese (ja)
Inventor
孝聡 小林
智也 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Publication of WO2013031313A1 publication Critical patent/WO2013031313A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair color pretreatment composition, and more particularly to a hair color pretreatment composition that improves the hair dyeing effect during hair coloring and can reduce damage to the hair.
  • the hair color may be used multiple times to cause damage to the hair.
  • the damaged portion is dyed more and color unevenness occurs, or the hair cannot be dyed to the expected color.
  • a pretreatment composition for example, see Patent Document 1.
  • a pretreatment agent for hair dye containing a protein hydrolyzate for example, see Patent Document 1.
  • the present invention has been made in view of the above-described problems of the prior art, and an object of the present invention is to provide a hair color pretreatment composition capable of improving the hair dyeing effect during hair coloring and reducing damage to the hair. .
  • the present inventors formulated polyoxyethylene oleyl ether phosphoric acid and acetylated hyaluronic acid or salts thereof into a hair color pretreatment composition to obtain a specific pH.
  • a hair color pretreatment composition to obtain a specific pH.
  • the hair color pretreatment composition according to the present invention comprises polyoxyethylene oleyl ether phosphoric acid and acetylated hyaluronic acid or salts thereof, and has a pH of 7.5 to 10.
  • the polyoxyethylene oleyl ether phosphate is preferably represented by the following formula (I).
  • n is the average number of added moles of oxyethylene groups.
  • the acetylated hyaluronic acid or a salt thereof has a repeating structural unit represented by the following formula (II).
  • R 1 , R 2 , R 3 and R 4 each independently represents a hydrogen atom or an ester-linked acetyl group (however, R 1 , R 2 , R in each repeating structural unit on average) 3 and at least two of R 4 represent an acetyl group), R 5 represents a hydrogen atom or an alkali metal, and k represents a number of 2 or more.
  • the composition preferably contains 0.5 to 10% by mass of polyoxyethylene oleyl ether phosphoric acid and 0.0001 to 10% by mass of acetylated hyaluronic acid or a salt thereof.
  • n represented by the formula (I) is preferably 1-20.
  • the hair color pretreatment composition according to the present invention is a composition comprising polyoxyethylene oleyl ether phosphoric acid and acetylated hyaluronic acid or salts thereof and having a pH of 7.5 to 10, and hair color It is possible to provide a hair color pretreatment composition that improves the hair dyeing effect at the time and can reduce damage to the hair.
  • the hair color pretreatment composition according to the present invention contains polyoxyethylene oleyl ether phosphate and acetylated hyaluronic acid or salts thereof.
  • polyoxyethylene oleyl ether phosphate and acetylated hyaluronic acid or salts thereof are polyoxyethylene oleyl ether phosphate and acetylated hyaluronic acid or salts thereof.
  • the polyoxyethylene oleyl ether phosphoric acid is preferably a compound represented by the following formula (I).
  • n is the average number of added moles of oxyethylene groups. n is not particularly limited, but is preferably 1 to 20, and more preferably 3 to 10.
  • the blending amount of polyoxyethylene oleyl ether phosphoric acid is preferably 0.5 to 10% by mass.
  • the blending amount is more preferably 1% by mass or more. When there are too few compounding quantities, it may be inferior to the hair dyeing effect. Further, the blending amount of polyoxyethylene oleyl ether phosphoric acid is more preferably 5% by mass or less. Even if there are too many compounding quantities, the remarkable improvement of an effect may not be seen.
  • acetylated hyaluronic acid or its salts An acetylated hyaluronic acid or a salt thereof is a polymer compound in which the hydroxyl group of hyaluronic acid is partially acetylated.
  • This acetylated hyaluronic acid is a water-soluble polymer having a moisturizing effect, and is known to have an anti-dandruff and damaging effect when applied for a long time.
  • the acetylation rate with respect to the hydroxyl group of acetylated hyaluronic acid or a salt thereof is not particularly limited, but those having a repeating structural unit represented by the following formula (II) can be preferably used.
  • R 1 , R 2 , R 3 , and R 4 each independently represent a hydrogen atom or an ester-linked acetyl group (however, R 1 , R 2 in each repeating structural unit on average) , R 3 and R 4 each represents an acetyl group).
  • R 5 represents a hydrogen atom or an alkali metal.
  • k represents a number of 2 or more.
  • the degree of acetylation is 1, and in the present invention, acetylated hyaluronic acid having a degree of acetylation of 2 to 4 is preferably used.
  • the molecular weight of the acetylated hyaluronic acid used in the present invention is preferably about 10,000 to 1,000,000 in terms of hyaluronic acid.
  • the method for producing acetylated hyaluronic acid or salts thereof used in the present invention is, for example, a method in which powdered hyaluronic acid is dispersed in acetic acid and trifluoroacetic anhydride is added as a catalyst to react, and hyaluronic acid is dispersed in acetic acid. Further, there are known a method in which p-toluenesulfonic acid is added and acetic anhydride is further added to react, and a method in which hyaluronic acid is suspended in an acetic anhydride solvent and then concentrated sulfuric acid is added to react (Japanese Patent Laid-open No. Hei 6). -9707, JP-A-8-53501, etc.), these methods can be used, but the method is not limited to the above-mentioned methods.
  • the amount of acetylated hyaluronic acid or a salt thereof is preferably 0.0001 to 10% by mass.
  • the blending amount is more preferably 0.001% by mass or more, and particularly preferably 0.1% by mass or more. If the amount is too small, the hair dyeing effect may be inferior, or damage to the hair may not be reduced. Further, the blending amount of acetylated hyaluronic acid or a salt thereof is more preferably 5% by mass or less, and particularly preferably 1% by mass or less. If the amount is too large, the viscosity may increase too much.
  • the hair color pretreatment composition of the present invention needs to be adjusted to pH 7.5 to 10. If the pH is less than 7.5, the hair dyeing effect is poor. Even if pH exceeds 10, since the remarkable improvement of an effect is not seen, it is unpreferable.
  • the pH can be adjusted by using one or more pH adjusting agents.
  • pH adjusters include inorganic acids such as phosphoric acid, sulfuric acid, hydrochloric acid, and carbonic acid, alkali metal salts of organic acids such as citric acid, glycolic acid, and tartaric acid, ammonia, monoethanolamine, diethanolamine, and triethanolamine. And organic alkali salts such as aminomethylpropanol.
  • the hair color pretreatment composition of the present invention water, protein hydrolyzate, surfactant, humectant such as glycerin, propylene glycol, sorbitol, carboxymethylcellulose, hydroxyethylcellulose as long as the effects of the present invention are not impaired.
  • Optional components such as viscosity modifiers such as xanthan gum, lower alcohols, preservatives, and the like can be appropriately blended.
  • the hair color pretreatment composition of the present invention is preferably used for pretreatment of an oxidative hair dye type hair color.
  • the hair color pretreatment composition of the present invention is applied to the hair before the hair color, and is applied to the hair uniformly by hand, comb, etc., and then rinsed as it is or after being lightly rinsed, then any hair color is used. be able to.
  • the hair color pretreatment composition of the present invention preferably uses any hair color as it is after coating.
  • the present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto.
  • the blending amount is expressed in mass% with respect to the system in which the component is blended. Prior to the description of the examples, the evaluation method of the test used in the present invention will be described.
  • Evaluation (1) Color difference The color difference of the hair before and after the treatment (dry state) was measured using a color difference meter CM-3600 (manufactured by Minolta).
  • the present inventors manufactured hair dye-type hair color by a conventional method with the composition shown in Table 1 below, and manufactured a hair color pretreatment composition with the composition shown in Table 2 below. did. Then, after wetting 1 g of the black hair bundle with water (Test Example 1-0), or after applying 0.3 g of the pretreatment composition of Test Examples 1-1 to 1-5 to 1 g of the black hair bundle, The hair color was applied by applying 3 g of hair color and allowed to stand for 20 minutes. And it evaluated by the said evaluation method (1). The results are shown in Table 2. In the following test examples, the hair color used was a mixture of the first agent and the second agent in a ratio of 1: 1 (each 1.5 g) immediately before use. The pH of the hair color described in Table 1 was 10 (when the first agent and the second agent were mixed).
  • the inventors of the present invention manufactured an oxidative hair dye type hair color by the conventional method with the formulation shown in Table 1 above, and manufactured a hair color pretreatment composition with the formulation shown in Table 3 below. Then, after applying 0.3 g of the pretreatment composition to 1 g of the black hair bundle, 3 g of the hair color was applied, and the hair was dyed by being left for 20 minutes. And it evaluated by the said evaluation method (1). The results are shown in Table 3.
  • the hair color pretreatment composition of the present invention needs to contain polyoxyethylene oleyl ether phosphate and have a pH of 7.5 to 10.
  • the inventors of the present invention manufactured an oxidative hair dye type hair color with the formulation shown in Table 1 above, and manufactured a hair color pretreatment composition with the formulation shown in Table 4 below. Then, after applying 0.3 g of the pretreatment composition to 1 g of the black hair bundle, 3 g of the hair color was applied, and the hair was dyed by being left for 20 minutes. And it evaluated by the said evaluation method (1) and (2). The results are shown in Table 4.
  • the normal method is a method of applying a hair dyeing treatment by applying 0.3 g of the pretreatment composition to 1 g of black hair bundle, then applying 3 g of hair color, and washing after standing for 20 minutes.
  • Method X is a method of applying hair coloring treatment by applying 3 g of hair color to 1 g of black hair bundle, applying 0.3 g of the pretreatment composition, and washing after standing for 20 minutes.
  • Test Example 3-2 ′ even when the pretreatment composition of the present invention was applied after applying the hair color, the color difference was the same as in the case of no pretreatment (Test Example 3-0), and the hair dyeing effect was improved. I was not able to admit. Therefore, it is necessary to use the hair color pretreatment composition of the present invention before hair color.
  • the inventors of the present invention examined the difference in effect when the active ingredient of the pretreatment composition was blended into the hair color.
  • the inventors of the present invention manufactured hair dye-type hair color by a conventional method with the composition shown in Table 1 and Table 6 below, and the hair color pretreatment composition with the composition shown in Table 7 below. Manufactured.
  • the pH of the hair color described in Table 6 was 10 (when the first agent and the second agent were mixed).
  • the above-mentioned usual method or the hair dyeing process was carried out without pretreatment. And it evaluated by the said evaluation method (1). The results are shown in Table 7.
  • Test Example 3-2 in which the same amount of the active ingredient as the pretreatment composition with Test Example 3-2 was applied as a hair color to a black hair bundle, is a test in which a hair color containing no active ingredient was applied The color difference was not so different from Example 3-0. For this reason, it becomes clear that the active ingredient of the present invention can exhibit an excellent hair dyeing effect when applied before the hair color as a hair color pretreatment composition, rather than being blended into the hair color. It was.
  • the following is a formulation example of the hair color pretreatment composition of the present invention.
  • the present invention is not limited by this formulation example.
  • Formulation Example 1 Liquid composition for hair color pretreatment polyoxyethylene (10) oleyl ether phosphate 2.0% by mass Acetylated sodium hyaluronate 0.01 Arginine 0.4 Hydrolyzed wheat protein 0.1 Ethylparaben 0.2 Methylparaben 0.1 Phenoxyethanol 0.1 Purified water balance (production method) Each component is stirred and mixed at room temperature, homogenized, and manufactured.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de prétraitement pour la coloration capillaire, qui permet d'améliorer l'effet de coloration des cheveux pendant une coloration capillaire, tout en réduisant les dommages aux cheveux. Une composition de prétraitement pour la coloration des cheveux de la présente invention est caractérisée en ce qu'elle contient un phosphate d'oléyléther de polyoxyéthylène et un acide hyaluronique acétylé ou un sel de celui-ci et en ce qu'elle a un pH de 7,5 à 10.
PCT/JP2012/063620 2011-09-01 2012-05-28 Composition de prétraitement pour coloration capillaire Ceased WO2013031313A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-190617 2011-09-01
JP2011190617 2011-09-01

Publications (1)

Publication Number Publication Date
WO2013031313A1 true WO2013031313A1 (fr) 2013-03-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/063620 Ceased WO2013031313A1 (fr) 2011-09-01 2012-05-28 Composition de prétraitement pour coloration capillaire

Country Status (2)

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JP (1) JP5955646B2 (fr)
WO (1) WO2013031313A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107789218A (zh) * 2016-09-02 2018-03-13 株式会社美丽化妆品 染毛组合物及其制备方法

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7033391B2 (ja) * 2016-03-08 2022-03-10 クローダジャパン株式会社 毛髪用染毛剤
JP6980438B2 (ja) * 2017-07-19 2021-12-15 株式会社サニープレイス ヘアカラートリートメント方法
JP7176712B2 (ja) * 2017-07-19 2022-11-22 株式会社サニープレイス 毛髪化粧料組成物
JP7626435B2 (ja) * 2021-03-05 2025-02-04 タカラベルモント株式会社 毛髪処理剤セット及び毛髪処理用組成物
JP2023084523A (ja) * 2021-12-07 2023-06-19 アンファー株式会社 毛髪に対するアルカリ施術と共に低分子ムコ多糖類を適用する毛髪改質方法、並びにムコ多糖類を含む毛髪用化粧料

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JPH0853501A (ja) * 1994-08-11 1996-02-27 Shiseido Co Ltd アセチル化ヒアルロン酸の製造方法及び精製方法
JP2010037283A (ja) * 2008-08-06 2010-02-18 Asutaa Biyo:Kk 毛髪化粧料組成物

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Publication number Priority date Publication date Assignee Title
JPH069707A (ja) * 1992-04-21 1994-01-18 Shiseido Co Ltd 高アセチル化率ヒアルロン酸及びその製造方法
JPH0853501A (ja) * 1994-08-11 1996-02-27 Shiseido Co Ltd アセチル化ヒアルロン酸の製造方法及び精製方法
JP2010037283A (ja) * 2008-08-06 2010-02-18 Asutaa Biyo:Kk 毛髪化粧料組成物

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107789218A (zh) * 2016-09-02 2018-03-13 株式会社美丽化妆品 染毛组合物及其制备方法
CN107789218B (zh) * 2016-09-02 2020-12-01 株式会社美丽化妆品 染毛组合物及其制备方法

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JP2013063948A (ja) 2013-04-11

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