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WO2013030741A3 - Procédé de récupération de molybdène de qualité technique à partir de solutions acides diluées de lixiviation, hautement concentrées en arsenic provenant de résidus métallurgiques - Google Patents

Procédé de récupération de molybdène de qualité technique à partir de solutions acides diluées de lixiviation, hautement concentrées en arsenic provenant de résidus métallurgiques Download PDF

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Publication number
WO2013030741A3
WO2013030741A3 PCT/IB2012/054308 IB2012054308W WO2013030741A3 WO 2013030741 A3 WO2013030741 A3 WO 2013030741A3 IB 2012054308 W IB2012054308 W IB 2012054308W WO 2013030741 A3 WO2013030741 A3 WO 2013030741A3
Authority
WO
WIPO (PCT)
Prior art keywords
solution
pls
molybdenum
order
precipitate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2012/054308
Other languages
English (en)
Spanish (es)
Other versions
WO2013030741A2 (fr
Inventor
Felipe Andrés LAGNO SÁNCHEZ
Ricardo Fernando SEPÚLVEDA LETELIER
Marcelo Gustavo ACUÑA GOYCOLEA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecometales Ltd
Original Assignee
Ecometales Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecometales Ltd filed Critical Ecometales Ltd
Priority to CA2844874A priority Critical patent/CA2844874C/fr
Priority to US14/240,567 priority patent/US9279168B2/en
Priority to CN201280041055.6A priority patent/CN103906709B/zh
Priority to MX2014002072A priority patent/MX349312B/es
Publication of WO2013030741A2 publication Critical patent/WO2013030741A2/fr
Publication of WO2013030741A3 publication Critical patent/WO2013030741A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/02—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/05—Processes using organic exchangers in the strongly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/07—Processes using organic exchangers in the weakly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
    • B01J49/07—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing anionic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

La présente invention concerne un procédé de récupération de molybdène de qualité technique à partir de solutions acides diluées de lixiviation, hautement concentrées en arsenic, ledit procédé comprenant les étapes consistant à: (a) mettre en contact une solution acide de lixiviation préalablement filtrée provenant de la lixiviation des poussières de fonderie avec une résine anionique d'échange d'ions; (b) laver à l'eau la résine chargée; (c) extraire le molybdène de la résine d'échange d'ions avec une solution régénérante alcaline d'ammonium à une valeur de pH comprise entre 8 et 12, pour former du molybdate d'ammonium en solution; (d) laver à l'eau, la résine déchargée; (e) ajouter des sels de magnésium et/ou de fer à la solution ammoniacale récupérée pour obtenir un précipité qui est soumis à l'étape d'élimination de l'arsenic, et une solution qui contient le molybdate d'ammonium en solution; (f) ajouter de l'acide sulfurique à la solution ammoniacale exempte d'arsenic, pour précipiter le molybdène sous forme de molybdate d'ammonium dans un milieu acide à une valeur de pH comprise entre 1,5 et 4; (g) séparer le précipité formé par filtration du molybdate et remettre en circulation la solution obtenue dans la solution initiale de solution acide de lixiviation; (h) calciner le précipité séparé pour obtenir du trioxyde de molybdène et de l'ammoniac; et (i) récupérer l'ammoniac séparé en vue de son renvoi ultérieur dans le processus en tant que solution régénérante recirculée.
PCT/IB2012/054308 2011-08-26 2012-08-24 Procédé de récupération de molybdène de qualité technique à partir de solutions acides diluées de lixiviation, hautement concentrées en arsenic provenant de résidus métallurgiques Ceased WO2013030741A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA2844874A CA2844874C (fr) 2012-08-24 2012-08-24 Procede de recuperation de molybdene de qualite technique a partir de solutions acides diluees de lixiviation, hautement concentrees en arsenic provenant de residus metallurgiques
US14/240,567 US9279168B2 (en) 2011-08-26 2012-08-24 Process for recovery of technical grade molybdenum from diluted leaching acid solutions (PLS), with highly concentrated arsenic, from metallurgical residues
CN201280041055.6A CN103906709B (zh) 2011-08-26 2012-08-24 从含有高浓度砷的冶金废渣稀酸浸溶液(pls)中回收工业级钼的方法
MX2014002072A MX349312B (es) 2011-08-26 2012-08-24 Proceso para la recuperacion de molibdeno grado tecnico a partir de soluciones acidas diluidas de lixiviacion (pls), altamente concentradas en arsenico, provenientes de residuos metalurgicos.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CL20952011 2011-08-26
CL2095-2011 2011-08-26

Publications (2)

Publication Number Publication Date
WO2013030741A2 WO2013030741A2 (fr) 2013-03-07
WO2013030741A3 true WO2013030741A3 (fr) 2013-04-25

Family

ID=47756987

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2012/054308 Ceased WO2013030741A2 (fr) 2011-08-26 2012-08-24 Procédé de récupération de molybdène de qualité technique à partir de solutions acides diluées de lixiviation, hautement concentrées en arsenic provenant de résidus métallurgiques

Country Status (1)

Country Link
WO (1) WO2013030741A2 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3681016A (en) * 1970-12-02 1972-08-01 Continental Ore Corp Recovery of rhenium and molybdenum values from solution
US4273745A (en) * 1979-10-03 1981-06-16 Amax Inc. Production of molybdenum oxide from ammonium molybdate solutions
US4596701A (en) * 1984-02-29 1986-06-24 Gte Products Corporation Process for purifying molybdenum trioxide
ES2004072A6 (es) * 1986-01-23 1988-12-01 France Mokta Comp Procedimiento para la separacion de molibdeno por via resina
US4891067A (en) * 1988-05-13 1990-01-02 Kennecott Utah Copper Corporation Processes for the treatment of smelter flue dust

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3681016A (en) * 1970-12-02 1972-08-01 Continental Ore Corp Recovery of rhenium and molybdenum values from solution
US4273745A (en) * 1979-10-03 1981-06-16 Amax Inc. Production of molybdenum oxide from ammonium molybdate solutions
US4596701A (en) * 1984-02-29 1986-06-24 Gte Products Corporation Process for purifying molybdenum trioxide
ES2004072A6 (es) * 1986-01-23 1988-12-01 France Mokta Comp Procedimiento para la separacion de molibdeno por via resina
US4891067A (en) * 1988-05-13 1990-01-02 Kennecott Utah Copper Corporation Processes for the treatment of smelter flue dust

Also Published As

Publication number Publication date
WO2013030741A2 (fr) 2013-03-07

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