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WO2013021498A1 - Feuille de transfert - Google Patents

Feuille de transfert Download PDF

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Publication number
WO2013021498A1
WO2013021498A1 PCT/JP2011/068327 JP2011068327W WO2013021498A1 WO 2013021498 A1 WO2013021498 A1 WO 2013021498A1 JP 2011068327 W JP2011068327 W JP 2011068327W WO 2013021498 A1 WO2013021498 A1 WO 2013021498A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
resin
self
transfer foil
healing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2011/068327
Other languages
English (en)
Japanese (ja)
Inventor
光紀 小松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nagase and Co Ltd
Nitto Giken KK
Original Assignee
Nagase and Co Ltd
Nitto Giken KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nagase and Co Ltd, Nitto Giken KK filed Critical Nagase and Co Ltd
Priority to JP2013527826A priority Critical patent/JP5867751B2/ja
Priority to PCT/JP2011/068327 priority patent/WO2013021498A1/fr
Publication of WO2013021498A1 publication Critical patent/WO2013021498A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing
    • B29C37/0028—In-mould coating, e.g. by introducing the coating material into the mould after forming the article
    • B29C2037/0042—In-mould coating, e.g. by introducing the coating material into the mould after forming the article the coating being applied in solid sheet form, e.g. as meltable sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00—Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0025—Applying surface layers, e.g. coatings, decorative layers, printed layers, to articles during shaping, e.g. in-mould printing

Definitions

  • the present invention relates to a transfer foil.
  • This self-healing resin paint is made of a resin having a high elastic restoring force, and when this paint is applied to the surface of the coated body by a spray method or the like, even if the surface of the coated body is scratched once It is confirmed to disappear.
  • a transfer foil used for a processing method in which a transfer object such as a resin molded product is transferred through an adhesive layer by thermal transfer or in-mold molding. According to this transfer foil, it is possible to protect the surface of the transfer object, to provide an antistatic function, or to decorate it with any color or pattern, so that home appliances, automotive interior / exterior products, acoustic products, Widely used in furniture furniture products.
  • the present inventors expect that if the above-mentioned self-healing resin paint can be made into a transfer foil, problems such as paint scattering and the difficulty of mirror finishing can be solved, and the application will be further expanded.
  • the transfer foil of self-healing resin paint was studied. However, conventionally known transfer foil forming methods have not been able to form a self-healing resin paint into a transfer foil.
  • an object of the present invention is to provide a transfer foil obtained by forming a self-healing resin paint into a transfer foil.
  • the present invention is a transfer foil in which a release layer, a self-healing resin layer, an anchor layer and an adhesive layer are sequentially laminated on a base film, and the release layer does not transfer and adheres to the base film.
  • the anchor layer has an acrylic urethane resin, vinyl acetate resin (vinyl chloride / vinyl acetate copolymer resin), polyester resin, or thermosetting resin.
  • a transfer foil is provided.
  • the self-healing resin layer is formed as a transfer foil, the paint can be easily placed on the surface by being transferred to the transfer target, and the paint is scattered around. There is no worry. Furthermore, when the transfer foil of the present invention is used for in-mold molding, the surface layer of the self-healing resin can be easily mirror-finished by mirror-treating the surface of the mold.
  • the self-healing resin layer is preferably made of a thermosetting resin or a UV curable resin.
  • the adhesive layer is preferably made of an acrylic resin, a vinyl acetate resin, an olefin resin or a composite resin thereof, or a thermosetting resin.
  • an antistatic layer made of a surfactant type, metal compound type or polymer type antistatic agent is laminated on the surface of the base film opposite to the surface on which the release layer is laminated. It is also preferred that the base film contains an antistatic agent.
  • the self-healing resin layer is preferably made of a thermosetting resin containing a polydimethylsiloxane copolymer, and the release layer is preferably made of a mixture of a polyether-modified silicone and an ionizing radiation curable resin.
  • the self-healing resin layer is preferably made of a UV curable resin containing a urethane (meth) acrylate oligomer, and the release layer is preferably made of a vinyl resin.
  • the transfer foil of the present invention since the self-healing resin layer is formed as a transfer foil, the coating can be easily placed on the surface by transferring to the transfer target, and the coating is scattered around. There is no worry. Furthermore, when the transfer foil of the present invention is used for in-mold molding, the surface layer of the self-healing resin can be easily mirror-finished by mirror-treating the surface of the mold. Furthermore, the transfer foil of the present invention can be used in the same manner as a conventional transfer foil because it can be laminated with a decorative ink or the like in the same manner as a conventional transfer foil.
  • the transfer foil 1 can be suitably used as a transfer foil for transferring by applying heat and pressure, such as for in-mold molding, roll type or hot stamping type thermal transfer.
  • a release layer 5, a self-healing resin layer 7, an anchor layer 9 and an adhesive layer 11 are sequentially laminated on one surface of the base film 3, and an antistatic layer is further formed on the other surface of the base film 3. 13 is laminated.
  • the thickness of each layer is substantially the same, but of course, the thickness of the layer can be adjusted as appropriate.
  • a decorative layer (not shown) and an adhesive layer (not shown) may be further laminated on the adhesive layer 11.
  • the base film 3 is made of a flexible film.
  • the material constituting this is not particularly limited as long as it has desired heat resistance, mechanical strength, etc., and known materials that have been used for conventional general in-mold molding and thermal transfer can be used.
  • Specific examples of the base film 3 include stretched or unstretched transparent plastics such as polyethylene terephthalate (PET), polybutylene terephthalate, polypropylene, polyethylene, nylon, polymethyl acrylate, polymethyl methacrylate, polycarbonate, and polyurethane. , Paper, metal, and composites thereof, and polyethylene terephthalate having good heat resistance and mechanical strength is particularly preferable.
  • the thickness of the base film 3 is usually about 10 to 200 ⁇ m.
  • the release layer 5 is a layer that enables the base film 3 and the self-healing resin layer 7 to be separated and does not transfer.
  • a material constituting the release layer 5 known materials that have been used for conventional general in-mold molding and thermal transfer can be used.
  • the material constituting the release layer 5 include a release resin, a resin to which a release agent is added or copolymerized, or a material containing a curable resin that is cured by a crosslinking reaction.
  • release resins and resins containing release agents include fluororesins, silicone resins, melamine resins, waxes, acrylic resins with added or copolymerized release agents such as various waxes, and vinyl resins
  • curable resins that can be cured by crosslinking reaction (by irradiation with ionizing radiation) include epoxy-modified acrylate resins, urethane-modified acrylate resins, acrylic-modified polyester resins, and polyether-modified resins.
  • a silicone resin, an acrylic resin, etc. are mentioned. These can be used alone or in combination.
  • the release layer 5 has a polyether-modified silicone and an ionizing radiation curable resin (preferably, A mixture of acrylic resins) (for example, a polyether-modified silicone content of 10 to 70% by mass) is preferable.
  • an ionizing radiation curable resin preferably, A mixture of acrylic resins
  • a vinyl type is used. Resins are preferred. According to these combinations, the self-healing resin layer 7 and the release layer 5 can be released more easily.
  • the thickness of the release layer 5 is usually about 0.01 to 20 ⁇ m, preferably about 0.1 to 10 ⁇ m, considering the film formability and ease of release.
  • the release layer 5 is prepared by dispersing or dissolving the above-described materials in a solvent, roll coating, reverse roll coating, gravure coating, micro gravure coating, reverse gravure coating, bar coating, rod coating, kiss coating, knife coating, die coating, comma. It is applied on the base film 3 by a known method such as a coating method such as coating, flow coating, spray coating, or a coating method, followed by drying by heating. Moreover, it can be hardened
  • the self-healing resin layer 7 has a three-dimensional structure, and is made of a self-healing resin having an elastic shape recovery function that elastically restores to its original shape over time even when deformed.
  • self-healing resins include acrylic resins, urethane resins, polycarbonate resins, polycarbonate diol resins, polystyrene resins, polyester resins, silicone resins, fluorine resins, and their copolymers or blends, which are relatively soft. There are elastic and easily deformable.
  • an ultraviolet (UV) curable or thermosetting paint sold as “Self-healing clear” (manufactured by NATCO CORPORATION) can be suitably used.
  • thermosetting type As shown in JP-A-11-228905, those using polydimethylsiloxane copolymers, such as those containing polydimethylsiloxane copolymers, polycaprolactone and polysiloxane are typical.
  • an ultraviolet curable type as shown in JP-A No. 2001-2744, a urethane (meth) acrylate oligomer, for example, a urethane (meth) acrylate oligomer and a photoinitiator are used. What is included is typical.
  • the self-healing resin is also preferably a resin (polycarbonate diol type) containing acrylic polyol, polycarbonate diol and polyisocyanate.
  • the film thickness of the self-healing resin layer 7 is usually about 3 to 100 ⁇ m in consideration of recoverability.
  • the self-healing resin layer 7 can be formed in the same manner as the release layer 5 in the case of the thermosetting type. In the case of the ultraviolet curable type, ultraviolet rays are further irradiated.
  • the anchor layer 9 is provided for protecting the self-healing resin layer 7 and interposing between the cured self-healing resin layer 7 and the adhesive layer 11 to be laminated next, so as to adhere to each layer. It is. It is difficult for the self-healing resin to adhere an adhesive layer or a decorative layer thereon, and the insertion of the anchor layer 9 is important.
  • the material constituting the anchor layer 9 include acrylic urethane resin, vinyl chloride resin, polyester resin, melamine resin, and epoxy thermosetting resin.
  • the material constituting the anchor layer 9 is preferably a material harder than the self-healing resin in order to exhibit the performance of the self-healing resin to a higher degree. In addition, the hardness of resin can be confirmed by the nanoindentation method, for example.
  • the film thickness of the anchor layer 9 is usually about 1 to 2 ⁇ m in consideration of adhesion.
  • the anchor layer 9 can be formed in the same manner as the release layer 5.
  • the adhesive layer 11 When the decorative layer is provided, the adhesive layer 11 is in close contact with the decorative ink, and when directly placed on the transferred material, the adhesive layer 11 is in close contact with the transferred material. Therefore, as a material constituting the adhesive layer 11, when a decorative layer is provided, a material having an affinity with a decorating material with the other side to be in close contact is appropriately selected and used, and is directly placed on the transferred object. In this case, a compatible, heat-sensitive, and pressure-sensitive resin suitable for the other-side transferred object is appropriately selected and used. Examples of the material constituting the adhesive layer 11 include resins such as acrylic resins, vinyl acetate resins, olefin resins, composite resins thereof, and thermosetting resins. The film thickness of the adhesive layer 11 is usually about 0.1 to 5.0 ⁇ m in consideration of adhesion. The adhesive layer 11 can be formed in the same manner as the release layer 5.
  • the decorative layer can be formed by a known printing method such as a gravure printing method, an offset printing method, a screen printing method, a letterpress printing method, or a metal vapor deposition using various printing inks containing a known pigment or dye. It can be formed by transferring a film. When the decorative layer is provided, it is possible to place the decorative layer on the transfer target by further providing an adhesive layer thereon.
  • a known printing method such as a gravure printing method, an offset printing method, a screen printing method, a letterpress printing method, or a metal vapor deposition using various printing inks containing a known pigment or dye. It can be formed by transferring a film.
  • the antistatic layer 13 is provided in order to prevent dust from adhering to the foil, and is preferably provided because the self-healing paint is easily charged.
  • the antistatic layer 13 preferably has a surface electrical resistance of 10 11 ⁇ / ⁇ or less, and can withstand the heat treatment during the production of the transfer foil 1 and is not deteriorated at a high temperature of about 170 ° C. for about 5 minutes. Those that can withstand are preferred.
  • Examples of the material constituting the antistatic layer 13 include surfactant, metal compound, and polymer antistatic agents. These can be used alone or in combination.
  • the antistatic layer 13 can be formed in the same manner as the release layer 5. Instead of providing the antistatic layer 13, the base film 3 may contain the above components to impart an antistatic function.
  • each layer described above can be applied by dissolving in a solvent such as toluene, methyl ethyl ketone, methyl isobutyl ketone, butyl acetate or cyclohexanone.
  • a solvent such as toluene, methyl ethyl ketone, methyl isobutyl ketone, butyl acetate or cyclohexanone.
  • the transfer foil 1 can be manufactured using a normal transfer foil manufacturing apparatus 14, for example, as shown in FIG.
  • the base film 3 is wound around the unrolling roller 15.
  • the base film 3 is unwound from the unwinding side roller 15 and is transported along a predetermined path by the transport rollers 29a to 29e and 31a to 31e.
  • the roller 17 is wound up.
  • a container 19 containing a coating material such as a releasable resin is disposed on the upstream side of the transport path of the base film 3 so that the above-described layers are formed by gravure printing using the coating roller 27. It has become.
  • drying furnaces 21a to 21f are provided on the downstream side thereof.
  • a corona treatment unit 25 may be provided on the upstream side of the manufacturing apparatus 14, or an ionizing radiation or UV irradiation unit 23 may be provided on the downstream side.
  • Example 1 As the base film 3, polyethylene terephthalate (manufactured by Toyobo Co., Ltd., trade name: E-5100, thickness: 38 ⁇ m) is prepared, and the transfer of Example 1 is performed through the following steps 1 to 7 using the manufacturing apparatus 14. A foil was produced. In addition, it shows in following Table 1 about the coating conditions and coating material of each layer.
  • Step 1 Coating an antistatic layer on one surface of polyethylene terephthalate so that the surface electrical resistance is 10 11 ⁇ / ⁇ or less.
  • Process 2 A release layer is coated on the other surface of polyethylene terephthalate.
  • Step 3 A self-healing resin layer is applied on the release layer.
  • Step 4 Corona treatment of the self-healing resin layer at a discharge density of 50 to 100 W / m 2 .
  • Step 5 An anchor layer is applied on the corona-treated self-healing resin layer.
  • Step 6 Corona treatment of the anchor layer at a discharge density of 50 to 100 W / m 2 .
  • Step 7 An adhesive layer is applied on the corona-treated anchor layer.
  • Example 2 As the base film 3, polyethylene terephthalate (manufactured by Toyobo, trade name: A4100, thickness 50 ⁇ m) is prepared, and the transfer foil of Example 2 is manufactured through the following steps 1 to 6 using the manufacturing apparatus 14 described above. did. In addition, it shows in Table 2 about the coating conditions and coating material of each layer.
  • Step 1 Coating an antistatic layer on one surface of polyethylene terephthalate so that the surface electrical resistance is 10 11 ⁇ / ⁇ or less.
  • Process 2 A release layer is coated on the other surface of polyethylene terephthalate.
  • Step 3 A self-healing resin layer is applied on the release layer.
  • Step 4 Corona treatment of the self-healing resin layer at a discharge density of 50 to 100 W / m 2 .
  • Step 5 An anchor layer is applied on the corona-treated self-healing resin layer.
  • Process 6 Applying an adhesive layer on the anchor layer.
  • Example 3 Polyethylene terephthalate (trade name: E-5100, thickness: 38 ⁇ m, manufactured by Toyobo Co., Ltd.) is prepared as the base film 3, and the transfer of Example 3 is performed through the following steps 1 to 5 using the manufacturing apparatus 14 described above. A foil was produced. In addition, it shows in Table 3 about the coating conditions and coating material of each layer.
  • Step 1 Coating an antistatic layer on one surface of polyethylene terephthalate so that the surface electrical resistance is 10 11 ⁇ / ⁇ or less.
  • Process 2 A release layer is coated on the other surface of polyethylene terephthalate.
  • Step 3 A self-healing resin layer is applied on the release layer.
  • Step 4 An anchor layer is applied on the self-healing resin layer.
  • Process 5 Applying an adhesive layer on the anchor layer.
  • Comparative Example 1 A transfer foil of Comparative Example 1 was produced in the same manner as Example 2 except that no anchor layer was formed.
  • the transfer foil of the present invention can be used in the same manner as a conventional transfer foil.

Landscapes

  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

L'invention porte sur une feuille de transfert, laquelle feuille est obtenue par stratification séquentielle d'une couche anti-adhérente, d'une couche de résine auto-réparatrice, d'une couche d'ancrage et d'une couche adhésive sur un film de base. La couche anti-adhérente n'est pas transférée, mais est amenée à adhérer étroitement au film de base, tout en ayant des propriétés d'aptitude à la libération à partir de la couche de résine auto-réparatrice. La couche d'ancrage est constituée par une résine de copolymère de poly(chlorure) de vinyle, une résine d'uréthane acrylique, une résine de copolymère de chlorure de vinyle-acétate de vinyle, une résine de polyester ou une résine thermodurcissable.
PCT/JP2011/068327 2011-08-10 2011-08-10 Feuille de transfert Ceased WO2013021498A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013527826A JP5867751B2 (ja) 2011-08-10 2011-08-10 転写箔
PCT/JP2011/068327 WO2013021498A1 (fr) 2011-08-10 2011-08-10 Feuille de transfert

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2011/068327 WO2013021498A1 (fr) 2011-08-10 2011-08-10 Feuille de transfert

Publications (1)

Publication Number Publication Date
WO2013021498A1 true WO2013021498A1 (fr) 2013-02-14

Family

ID=47668044

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2011/068327 Ceased WO2013021498A1 (fr) 2011-08-10 2011-08-10 Feuille de transfert

Country Status (2)

Country Link
JP (1) JP5867751B2 (fr)
WO (1) WO2013021498A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015129721A1 (fr) * 2014-02-28 2015-09-03 大日本印刷株式会社 Feuille décorative
JP2015163434A (ja) * 2014-02-28 2015-09-10 大日本印刷株式会社 加飾シート
JP2015163435A (ja) * 2014-02-28 2015-09-10 大日本印刷株式会社 加飾シート
WO2016120705A1 (fr) * 2015-01-27 2016-08-04 王子ホールディングス株式会社 Stratifié et produit moulé décoratif
WO2018062074A1 (fr) * 2016-09-27 2018-04-05 東レフィルム加工株式会社 Film de transfert de couche de résine souple

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0253885A (ja) * 1988-08-17 1990-02-22 Dainippon Printing Co Ltd 転写箔
JPH0867099A (ja) * 1994-08-26 1996-03-12 Minnesota Mining & Mfg Co <3M> 装飾用熱転写シート及びその製法
JPH11228905A (ja) * 1998-02-13 1999-08-24 Natoko Kk 塗料組成物
WO2006035805A1 (fr) * 2004-09-30 2006-04-06 Dai Nippon Printing Co., Ltd. Film de transfert thermique de couche de protection et article imprime
WO2008105083A1 (fr) * 2007-02-28 2008-09-04 Takiron Co., Ltd. Article moulé de résine synthétique, film stratifié ou film de transfert pour former celui-ci
JP2011011376A (ja) * 2009-06-30 2011-01-20 Dainippon Printing Co Ltd インモールド用ハードコート転写箔
JP2011161888A (ja) * 2010-02-15 2011-08-25 Nitto Giken Kk 自己治癒性転写箔

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0253885A (ja) * 1988-08-17 1990-02-22 Dainippon Printing Co Ltd 転写箔
JPH0867099A (ja) * 1994-08-26 1996-03-12 Minnesota Mining & Mfg Co <3M> 装飾用熱転写シート及びその製法
JPH11228905A (ja) * 1998-02-13 1999-08-24 Natoko Kk 塗料組成物
WO2006035805A1 (fr) * 2004-09-30 2006-04-06 Dai Nippon Printing Co., Ltd. Film de transfert thermique de couche de protection et article imprime
WO2008105083A1 (fr) * 2007-02-28 2008-09-04 Takiron Co., Ltd. Article moulé de résine synthétique, film stratifié ou film de transfert pour former celui-ci
JP2011011376A (ja) * 2009-06-30 2011-01-20 Dainippon Printing Co Ltd インモールド用ハードコート転写箔
JP2011161888A (ja) * 2010-02-15 2011-08-25 Nitto Giken Kk 自己治癒性転写箔

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015129721A1 (fr) * 2014-02-28 2015-09-03 大日本印刷株式会社 Feuille décorative
JP2015163434A (ja) * 2014-02-28 2015-09-10 大日本印刷株式会社 加飾シート
JP2015163435A (ja) * 2014-02-28 2015-09-10 大日本印刷株式会社 加飾シート
WO2016120705A1 (fr) * 2015-01-27 2016-08-04 王子ホールディングス株式会社 Stratifié et produit moulé décoratif
CN107206757A (zh) * 2015-01-27 2017-09-26 王子控股株式会社 层叠体及装饰成型体
WO2018062074A1 (fr) * 2016-09-27 2018-04-05 東レフィルム加工株式会社 Film de transfert de couche de résine souple
JPWO2018062074A1 (ja) * 2016-09-27 2019-07-04 東レフィルム加工株式会社 軟質樹脂層の転写用フィルム

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