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WO2013006781A3 - Compostable or biobased foams, method of manufacture and use - Google Patents

Compostable or biobased foams, method of manufacture and use Download PDF

Info

Publication number
WO2013006781A3
WO2013006781A3 PCT/US2012/045723 US2012045723W WO2013006781A3 WO 2013006781 A3 WO2013006781 A3 WO 2013006781A3 US 2012045723 W US2012045723 W US 2012045723W WO 2013006781 A3 WO2013006781 A3 WO 2013006781A3
Authority
WO
WIPO (PCT)
Prior art keywords
compostable
foamed
biobased
manufacture
strand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/045723
Other languages
French (fr)
Other versions
WO2013006781A9 (en
WO2013006781A2 (en
Inventor
Adam Pawloski
Jeffrey Cernohous
Kent Kaske
Garrett Van Gorden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lifoam Industries LLC
Original Assignee
Lifoam Industries LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/178,272 external-priority patent/US20120010307A1/en
Priority claimed from US13/178,293 external-priority patent/US20120009420A1/en
Priority claimed from US13/230,158 external-priority patent/US8962706B2/en
Priority to CN201280043807.2A priority Critical patent/CN103890066A/en
Priority to AU2012278774A priority patent/AU2012278774A1/en
Priority to MX2014000279A priority patent/MX2014000279A/en
Priority to EP12807830.0A priority patent/EP2729521A4/en
Priority to CA2841130A priority patent/CA2841130A1/en
Application filed by Lifoam Industries LLC filed Critical Lifoam Industries LLC
Publication of WO2013006781A2 publication Critical patent/WO2013006781A2/en
Publication of WO2013006781A3 publication Critical patent/WO2013006781A3/en
Publication of WO2013006781A9 publication Critical patent/WO2013006781A9/en
Anticipated expiration legal-status Critical
Priority to ZA2014/00868A priority patent/ZA201400868B/en
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3461Making or treating expandable particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/3469Cell or pore nucleation
    • B29C44/348Cell or pore nucleation by regulating the temperature and/or the pressure, e.g. suppression of foaming until the pressure is rapidly decreased
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03Extrusion of the foamable blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/06CO2, N2 or noble gases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/08Supercritical fluid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00Characterised by the use of unspecified polymers
    • C08J2300/16Biodegradable polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

The present invention describes compostable or biobased foamed beads produced by cutting the foamed strand at the face of the extrusion die and the foamed bead or strand is subsequently cooled. The foamed beads are useful for fabricating foamed articles. The foamed beads are produced using a compound comprising a compostable or biobased polyester and a blowing agent. Additives including plasticizers and chain extenders are optionally included in the compostable or biobased composition.
PCT/US2012/045723 2011-07-07 2012-07-06 Compostable or biobased foams, method of manufacture and use Ceased WO2013006781A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN201280043807.2A CN103890066A (en) 2011-07-07 2012-07-06 Compostable or bio-based foams, methods of manufacture and use
AU2012278774A AU2012278774A1 (en) 2011-07-07 2012-07-06 Compostable or biobased foams, method of manufacture and use
MX2014000279A MX2014000279A (en) 2011-07-07 2012-07-06 Compostable or biobased foams, method of manufacture and use.
EP12807830.0A EP2729521A4 (en) 2011-07-07 2012-07-06 COMPOSTABLE OR BIOLOGICAL FOOTS, AND METHOD FOR MANUFACTURING AND USING THE SAME
CA2841130A CA2841130A1 (en) 2011-07-07 2012-07-06 Compostable or biobased foams, method of manufacture and use
ZA2014/00868A ZA201400868B (en) 2011-07-07 2014-02-05 Compostable or biobased foams, method of manufacture and use

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
US13/178,293 US20120009420A1 (en) 2010-07-07 2011-07-07 Compostable or Biobased Foams
US13/178,300 US20120007267A1 (en) 2010-07-07 2011-07-07 Method of Producing Compostable or Biobased Foams
US13/178,272 2011-07-07
US13/178,300 2011-07-07
US13/178,293 2011-07-07
US13/178,272 US20120010307A1 (en) 2010-07-07 2011-07-07 Expandable Beads of a Compostable or Biobased Thermoplastic Polymer
US13/230,158 US8962706B2 (en) 2010-09-10 2011-09-12 Process for enabling secondary expansion of expandable beads
US13/230,158 2011-09-12

Publications (3)

Publication Number Publication Date
WO2013006781A2 WO2013006781A2 (en) 2013-01-10
WO2013006781A3 true WO2013006781A3 (en) 2013-04-04
WO2013006781A9 WO2013006781A9 (en) 2013-05-23

Family

ID=47503586

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/045723 Ceased WO2013006781A2 (en) 2011-07-07 2012-07-06 Compostable or biobased foams, method of manufacture and use

Country Status (8)

Country Link
EP (1) EP2729521A4 (en)
JP (1) JP2013018959A (en)
CN (1) CN103890066A (en)
AU (1) AU2012278774A1 (en)
CA (2) CA2778580A1 (en)
MX (2) MX2012003108A (en)
WO (1) WO2013006781A2 (en)
ZA (1) ZA201400868B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3025203B1 (en) 2014-08-26 2016-12-09 Renfortech EPOXY FOAMS DERIVED FROM REACTIVE FORMULATIONS BIOSOURCEES
DE102014216992A1 (en) 2014-08-26 2016-03-03 Adidas Ag Expanded polymer pellets
MX2021002313A (en) * 2018-08-31 2021-04-28 Natureworks Llc Process for forming polylactide expanded bead foam.
KR102515937B1 (en) * 2020-09-03 2023-03-30 한국항공우주산업 주식회사 EMI shielding lightweight conductive foam and manufacturing method of that
US20220323314A1 (en) * 2021-04-05 2022-10-13 Plus Products, Inc. Dissolvable solid foam compositions
DE102021111247A1 (en) * 2021-04-30 2022-11-03 Fox Velution Gmbh Process for the production of cellular plastic particles
CN115181320A (en) * 2022-08-15 2022-10-14 中国科学院宁波材料技术与工程研究所 A kind of degradable PLA/PBAT extruded expanded beads and preparation method thereof
JPWO2024166719A1 (en) * 2023-02-09 2024-08-15
WO2025230974A1 (en) * 2024-04-30 2025-11-06 Cruz Foam, Inc. Expandable beads for biodegradable foamed article and methods thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5766749A (en) * 1994-10-12 1998-06-16 Watanabe-Zo Shoten Co., Ltd. Foam-expanded material
CA2202869C (en) * 1994-10-21 2004-11-23 Per Just Andersen Foamed starch compositions, articles and methods
US20090234035A1 (en) * 2006-12-14 2009-09-17 Yunwa Wilson Cheung Polymer Blends Of Biodegradable Or Bio-Based And Synthetic Polymers And Foams Thereof
US20100056656A1 (en) * 2006-12-22 2010-03-04 Fumio Matsuoka Biodegradable polyester resin composition, and molded body, foamed body and molded container obtained from the biodegradable polyester resin composition
US7863343B2 (en) * 2005-01-25 2011-01-04 Jsp Corporation Expandable polylactic acid resin particles, expanded polylactic acid resin beads and molded article obtained from expanded polylactic acid resin beads
WO2011038081A1 (en) * 2009-09-25 2011-03-31 Arkema Inc. Biodegradable foams with improved dimensional stability

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5589518A (en) * 1994-02-09 1996-12-31 Novamont S.P.A. Biodegradable foamed articles and process for the preparation thereof
JP4104440B2 (en) * 2002-12-03 2008-06-18 アキレス株式会社 Bead cushion
WO2005097878A1 (en) * 2004-03-26 2005-10-20 Natureworks Llc Extruded polylactide foams blown with carbon dioxide
KR101050338B1 (en) * 2007-03-29 2011-07-19 세키스이가세이힝코교가부시키가이샤 Polylactic acid-based resin foamed particles for in-mold foam molding, a method for producing the same, and a method for producing a polylactic acid-based resin foamed molded article
JP5383489B2 (en) * 2007-06-27 2014-01-08 株式会社カネカ Biodegradable aliphatic polyester-based expanded particles and molded articles thereof
JP5027599B2 (en) * 2007-09-10 2012-09-19 株式会社ジェイエスピー Method for producing expandable polylactic acid resin particles

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5766749A (en) * 1994-10-12 1998-06-16 Watanabe-Zo Shoten Co., Ltd. Foam-expanded material
CA2202869C (en) * 1994-10-21 2004-11-23 Per Just Andersen Foamed starch compositions, articles and methods
US7863343B2 (en) * 2005-01-25 2011-01-04 Jsp Corporation Expandable polylactic acid resin particles, expanded polylactic acid resin beads and molded article obtained from expanded polylactic acid resin beads
US20090234035A1 (en) * 2006-12-14 2009-09-17 Yunwa Wilson Cheung Polymer Blends Of Biodegradable Or Bio-Based And Synthetic Polymers And Foams Thereof
US20100056656A1 (en) * 2006-12-22 2010-03-04 Fumio Matsuoka Biodegradable polyester resin composition, and molded body, foamed body and molded container obtained from the biodegradable polyester resin composition
WO2011038081A1 (en) * 2009-09-25 2011-03-31 Arkema Inc. Biodegradable foams with improved dimensional stability

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Enhancing Biopolymers: Additives Are Needed For Toughness", HEAT RESISTANCE & PROCESSABILITY. PLASTIC TECHNOLOGY., 2008, XP008172225, Retrieved from the Internet <URL:http://www.ptonline.com/articles/enhancing-biopolymers-additives-are-needed-for-toughness-heat-resistance-processability> [retrieved on 20121129] *

Also Published As

Publication number Publication date
EP2729521A4 (en) 2016-03-16
CA2778580A1 (en) 2013-01-07
WO2013006781A9 (en) 2013-05-23
JP2013018959A (en) 2013-01-31
AU2012278774A1 (en) 2014-02-27
MX2012003108A (en) 2013-02-07
CA2841130A1 (en) 2013-01-10
WO2013006781A2 (en) 2013-01-10
ZA201400868B (en) 2015-06-24
CN103890066A (en) 2014-06-25
MX2014000279A (en) 2014-09-01
EP2729521A2 (en) 2014-05-14

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