WO2013099671A1 - Reflector, method for manufacturing reflector, and backlight panel - Google Patents
Reflector, method for manufacturing reflector, and backlight panel Download PDFInfo
- Publication number
- WO2013099671A1 WO2013099671A1 PCT/JP2012/082630 JP2012082630W WO2013099671A1 WO 2013099671 A1 WO2013099671 A1 WO 2013099671A1 JP 2012082630 W JP2012082630 W JP 2012082630W WO 2013099671 A1 WO2013099671 A1 WO 2013099671A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- reflector
- guide plate
- light guide
- sheet
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/005—Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
- G02B6/0055—Reflecting element, sheet or layer
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
- G02B5/021—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
- G02B5/0221—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures the surface having an irregular structure
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/02—Diffusing elements; Afocal elements
- G02B5/0273—Diffusing elements; Afocal elements characterized by the use
- G02B5/0284—Diffusing elements; Afocal elements characterized by the use used in reflection
Definitions
- the present invention relates to a light guide plate type backlight panel used in a liquid crystal panel.
- a backlight panel that emits light by illuminating light from the back side of a liquid crystal layer is used.
- a reflection plate is installed adjacent to the light guide plate of the edge light type backlight panel. The role of the reflecting plate is to return the light leaked to the reflecting plate side out of the light guided from the light source into the light guiding plate to the liquid crystal layer side to increase the luminance.
- Such an edge light type backlight panel is required to have uniform luminance over the entire light emission surface.
- edge light type backlight panel In the edge light type backlight panel, light emitted to the back side of the light guide plate is reflected by the reflection plate, returns to the inside of the light guide plate, and is emitted from the front side of the light guide plate. Therefore, high brightness can be obtained by reflection of light on the reflecting plate.
- a gap is usually formed between the reflector and the light guide plate. This is because, when the reflecting plate and the light guide plate are brought into close contact with each other, a partially bright portion called a white spot is generated, and there is a risk of unevenness in luminance. For example, when the light guide plate or the like is partially deformed by heat or the like, if the part is strongly pressed against the reflective plate against other parts, the luminance of those parts is not the same as the other parts, and white It can be a factor such as a spot.
- Patent Document 1 As a method of providing a gap between the light guide plate and the reflection plate, there is a method of applying a mixture of crosslinked acrylic beads or the like to a binder on the surface of the reflection plate (Patent Document 1). As another method, there is a method of forming irregularities on the surface of the reflector. (Patent Documents 2 to 5).
- Patent Document 1 in the method of maintaining the gap between the reflection plate and the light guide plate with beads, it is necessary to uniformly disperse and apply the beads. For this reason, it is necessary to use beads separately, and the material cost increases. In addition, since a bead coating step is required, a manufacturing process is required.
- the present invention has been made in view of such problems, and an object of the present invention is to provide a reflector plate that is excellent in manufacturability and can prevent the occurrence of white spots and the like.
- a first invention is a reflector for a backlight panel made of a thermoplastic resin foam, and a plurality of convex portions are formed on at least one surface of the reflector, A durometer A hardness of a surface having a convex portion is 95 or more and less than 100.
- the reflecting plate is characterized in that the arithmetic average roughness Ra of the surface having the convex portion is 6 or more and less than 30.
- the reflecting plate has a first unfoamed layer on at least the surface of the convex forming surface, and the thickness of the first unfoamed layer is 5 to 30 ⁇ m.
- the first unfoamed layer has a foamed layer on the inner side in the thickness direction, and further has a second unfoamed layer on the inner side of the foamed layer.
- the thermoplastic resin is preferably a thermoplastic polyester resin, and is preferably a polyethylene terephthalate resin.
- the gap between the light guide plate is maintained by the convex portions. be able to.
- the reflecting plate is a foam, light can be efficiently diffused inside the reflecting plate and reflected to the front surface.
- the hardness of the convex portion is durometer A hardness 95 or more, the convex portion can be prevented from being crushed, and partial adhesion between the light guide plate and the reflecting plate due to the crushed convex portion can be prevented.
- a certain gap or more can be secured between the light guide plate and the reflection plate without excessively collapsing the convex portion.
- the reflecting plate has the first unfoamed layer on at least the surface of the convex forming surface, the hardness of the convex can be increased efficiently. Further, if the thickness of the first unfoamed layer is 5 to 30 ⁇ m, the effect of improving the hardness is high, and it is possible to suppress a decrease in reflectance due to light absorption in the unfoamed layer.
- first unfoamed layer and the second unfoamed layer and forming the foamed layer therebetween, it is easy to achieve both high reflectivity and the hardness of the surface having the convex portion.
- the total thickness of the reflector is 0.3 mm or more, the occurrence of wrinkles on the reflector can be suppressed.
- the specific gravity of a reflecting plate is 0.7 or less, weight reduction can be achieved and material cost can be reduced.
- a polyethylene terephthalate resin which is a thermoplastic polyester resin, as the thermoplastic resin, a reflector having excellent heat resistance and cost can be obtained.
- 2nd invention is the manufacturing method of the reflecting plate for backlight panels, Comprising: The process a which contains the inert gas in the reflecting plate base material which consists of thermoplastic resin foams, The embossing to the said reflecting plate base material And a step c of heating the reflector substrate and performing a foaming process.
- the surface area of the reflector substrate is increased, so that the gas component inside the convex portion is easily released during foaming. Therefore, it is easy to form an unfoamed layer on the convex portion forming surface, and the hardness of the convex portion can be increased.
- 3rd invention comprises the reflecting plate concerning 1st invention, the light-guide plate provided in the front surface of the said reflecting plate, and the light source provided in the side of the said light-guide plate,
- the said convex part WHEREIN The backlight panel is characterized in that a gap is formed between the reflector and the light guide plate.
- a gap can be maintained between the light guide plate and the reflection plate by the convex portion on the surface of the reflection plate. Moreover, since the convex part on the surface of the reflecting plate has a high hardness, the convex part is not easily crushed. For this reason, it is possible to prevent the light guide plate from being partially adhered to the surface of the reflection plate due to partial deformation of the light guide plate. For this reason, a backlight panel with uniform brightness can be obtained over the entire surface.
- the present invention it is possible to provide a reflector that is excellent in manufacturability and can prevent the occurrence of white spots and the like.
- FIG. 1 is a schematic diagram showing a configuration of a backlight panel 1.
- FIG. It is an enlarged view which shows the boundary part vicinity of the light-guide plate 3 and the reflecting plate 5, and is the A section enlarged view of FIG.
- FIG. 3 is an enlarged view showing the vicinity of the boundary between the light guide plate 3 and the reflective plate 5, and is an enlarged view of a portion B in FIG. (A)-(c) is a figure which shows the manufacturing process of the reflecting plate 5.
- FIG. It is an enlarged view which shows the boundary part vicinity of the light-guide plate 3 and the reflecting plate 5, and is the E section enlarged view of FIG.4 (c). The figure which shows other embodiment of the reflecting plate.
- FIG. 1 is a view showing a backlight panel 1 used in a liquid crystal display device, etc.
- FIG. 2 is an enlarged view of a portion A in FIG. 1
- FIG. 3 is an enlarged view of a portion B in FIG.
- the backlight panel 1 is a so-called edge-light type backlight panel, and mainly includes a light guide plate 3, a reflection plate 5, a light source 9, and the like.
- the light source 9 is disposed on the side (edge) of the light guide plate 3 and surrounded by the reflector 2 and the like.
- LED Light Emitting Diode
- CCFL Cold Cathode Fluorescent Lamp
- EEFL External Electrofluorescent Lamp
- HCFL Hot Cathode Fluorescent LED
- the light guide plate 3 has a flat plate shape, and the light emission surface (the side on which the liquid crystal panel not shown is arranged on the upper surface side in FIG. 1) and the back surface are configured to be smooth.
- a reflector 5 is provided on the back side of the light guide plate 3 through a gap.
- a dot pattern for light diffusion may be printed on the back side of the light guide plate 3.
- an acrylic resin can be used as the light guide plate 3.
- the reflector 5 is a porous body having fine bubbles 7 which are closed cells, and is formed of, for example, a resin foam. More specifically, a thermoplastic resin sheet having fine bubbles or pores having an average cell diameter of 50 nm or more and 50 ⁇ m or less inside can be suitably used.
- the reflecting plate 5 is preferably made of a thermoplastic polyester resin in view of its heat resistance.
- the thermoplastic polyester resin used in the present invention is not limited, but for example, polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, polybutylene naphthalate and the like can be appropriately selected. These may be used individually by 1 type, and may mix and use 2 or more types. Among these, polyethylene terephthalate is preferable in terms of availability, economy, heat resistance, and the like.
- a crystallization nucleating agent, a crystallization accelerator, a bubble nucleating agent, an antioxidant, an antistatic agent are added to the thermoplastic resin sheet before foaming within a range that does not affect the properties of the obtained reflector 5.
- Various additives may be blended. Moreover, you may laminate
- the thickness of the reflecting plate 5 is 0.1 mm or more. If the thickness of the reflecting plate 5 is less than 0.1 mm, the rigidity is low and wrinkles are likely to occur, which is not preferable. From the viewpoint of increasing rigidity, the thickness of the reflector 5 is preferably 0.2 mm or more, and more preferably 0.3 mm or more.
- the specific gravity of the reflector 5 is preferably 0.7 or less, more preferably the specific gravity is less than 0.6, and the specific gravity is more preferably less than 0.5. If the specific gravity is large, the distribution amount of the fine bubbles 7 is not sufficient, and the effect of the fine bubbles is reduced.
- the reflectance of the reflecting plate 5 is not limited, but when used as a reflecting plate of a liquid crystal panel, the total reflectance of the reflecting plate 5 is desirably 90% or more. Further, from the viewpoint of energy saving, the reflectance is preferably 95% or more, and more preferably 98% or more.
- a plurality of convex portions 11 are formed on the surface of the reflecting plate 5. That is, the light guide plate 3 contacts the convex portion 11 on the surface of the reflective plate 5, and a gap is formed between the light guide plate 3 and the reflective plate 5 by the convex portion 11.
- the shape of the convex portion 11 is not limited to the illustrated example, but may be other shapes, but it is desirable that the convex portion 11 has a circular arc-shaped tip shape so that the tip of the convex portion 11 is not easily crushed.
- the shape of the convex portion 11 needs to have a certain height or higher so that the gap does not collapse even when compressed.
- the arithmetic average roughness Ra is preferably 5 or more. In order to suppress white spots more reliably, Ra is preferably 6 or more, and more preferably Ra is 7 or more. In addition, when Ra exceeds 30, it is not preferable because the convex portion is easily crushed even with a small pressure.
- the convex portions 11 are randomly dispersed without being aligned with the surface of the reflecting plate 5.
- the projections 11 By arranging the projections 11 at random, when the reflector 5 is arranged on the rear surface of the light guide plate 3 and used as a backlight panel unit, there is no occurrence of a striped pattern due to light interference or the like, and it is uniform. Brightness can be obtained.
- the formation method of the convex part 11 is mentioned later.
- FIG. 3 is an enlarged view of part B of FIG.
- the top of the convex portion 11 is in contact with the light guide plate 3.
- the upper part (C in the figure) above the base of the convex part 11 (the bottom part of the convex part 11) is the convex part range
- the lower part (D in the figure) than the base part of the convex part 11 is the range other than the convex part.
- a gap corresponding to the convex portion range C is formed between the light guide plate 3 and the reflection plate 5.
- the surface of the reflecting plate 5 needs to have a hardness that does not crush the gap. Therefore, high hardness is required for the surface having the convex portion 11. Specifically, a durometer A hardness of 95 or more is required. If the durometer A hardness is less than 95, the possibility of white spots is greatly increased. In order to reliably suppress white spots, the durometer A hardness is preferably 96 or more, more preferably 97 or more.
- the non-foamed surface layer 8 is a region that is formed on the surface of the reflecting plate 5 where the convex portions 11 are formed, and in which no fine bubbles are present (or there are only minute portions compared to the inside of the reflecting plate). If the surface unfoamed layer 8 is too thin, the effect of improving the hardness is small. On the other hand, if the thickness is too thick, the specific gravity of the entire reflecting plate 5 is increased, and there is a concern that the reflectance is reduced due to light absorption by the surface unfoamed layer 8. Therefore, the thickness range of the unfoamed surface layer 8 is preferably about 3 to 50 ⁇ m, more preferably 5 to 30 ⁇ m.
- the light emitted from the light source 9 enters the light guide plate 3 directly or by the reflector 2 or the like disposed behind the light source.
- the light beam incident on the inside of the light guide plate 3 is totally reflected at the interface because of the air layer existing on the front surface of the light guide plate 3.
- the light incident on the reflecting plate 5 is reflected by the reflecting plate 5 and returns into the light guide plate 3. A part of the returned light is totally reflected again on the front surface of the light guide plate 3, but the remaining light is emitted to the front surface of the light guide plate 3.
- light can be uniformly emitted from the entire surface of the backlight panel.
- the light guide plate 3 is totally reflected or diffused at the interface with a large number of fine bubbles 7 (the inside is, for example, an air layer and the refractive index is smaller than that of the resin constituting the reflection plate 5). Emitted to the side.
- the light beam diffused by the reflection plate 5 returns into the light guide plate 3, and a part of the light is totally reflected again on the front surface of the light guide plate 3, and the remaining light is emitted to the front surface of the light guide plate 3.
- the reflecting plate 5 for diffusing light is a porous body and absorbs light much less than white paint or the like. Further, the diffusion and reflection of light can be easily controlled by the average hole diameter and density of the reflecting plate 5. In addition, since a predetermined gap is maintained between the reflecting plate 5 and the light guide plate 3, a white spot or the like does not occur due to surface contact between the light guide plate 3 and the reflecting plate 5. That is, uniform brightness can be ensured on the front surface of the light guide plate 3.
- FIG. 4 is a schematic view showing a manufacturing process of the reflector 5.
- the method for introducing bubbles into the sheet is not limited.
- a batch foaming method in which a resin sheet is impregnated with gas in a pressure vessel and then heated and foamed, or a thermoplastic resin sheet is extruded from a die of an extruder.
- foaming is performed, and a stretching method in which a void is formed at the interface between the filler and the resin by extruding a thermoplastic resin sheet containing a filler and then stretching.
- the manufacturing method of the reflecting plate 5 by the batch foaming method is shown as an example.
- the bubbles are more easily refined than the extrusion foaming method, thicker than the stretching method, and easy to reduce the specific gravity.
- the reflector base 13 is manufactured.
- illustration of a separator is abbreviate
- a thermoplastic resin sheet is produced, and a roll is formed by overlapping and winding a thermoplastic resin sheet and a separator.
- the separator used here may be any one as long as it has a void through which an inert gas or an organic solvent used as needed freely enters and exits, and the permeation of the inert gas into itself can be ignored.
- a resin nonwoven fabric or a metal net is particularly suitable.
- thermoplastic resin sheet is preferably unstretched. This is because when the thermoplastic resin sheet is stretched, the gas does not sufficiently permeate into the sheet, and the intended foamed sheet cannot be obtained.
- an organic solvent may be contained in the resin sheet before the roll made of the resin sheet and the separator is held in a pressurized inert gas atmosphere and the resin sheet contains the inert gas.
- the crystallinity of the thermoplastic resin sheet can be increased to 30% or more.
- the rigidity of the sheet is increased and it is difficult for the trace of the separator to remain on the surface of the sheet, and the permeation time of the inert gas can be shortened.
- the trace of the separator may not remain on the surface of the sheet, so that the treatment containing the organic solvent is not necessarily required. However, from the viewpoint of shortening the gas permeation time, it is preferable to carry out a treatment containing an organic solvent.
- Organic solvents used to increase the crystallinity of the resin sheet include benzene, toluene, methyl ethyl ketone, ethyl formate, acetone, acetic acid, dioxane, m-cresol, aniline, acrylonitrile, dimethyl phthalate, nitroethane, nitromethane, benzyl alcohol Etc. Of these, acetone is more preferable from the viewpoints of handleability and economy.
- a large number of convex portions 11 are formed on the surface of the reflector base 13.
- a resin sheet is passed between a pair of embossing rolls having a concave portion corresponding to the convex portion 11, and the convex portion 11 (for example, embossing processing) is formed on the surface of the reflector plate base 13 by the roll. ) May be formed.
- the foamed sheet may be passed between the embossing rolls described above to give irregularities. From the viewpoint of ease of applying unevenness, the sheet before gas permeation has an advantage that unevenness is easily provided because the deformation of the central layer of the sheet is small.
- the reflector base material 13 on which the convex portions 11 are formed is placed in a high-pressure vessel and held in a pressurized inert gas atmosphere so that the thermoplastic sheet contains an inert gas serving as a foaming agent.
- the inert gas include helium, nitrogen, carbon dioxide, and argon. Among these, carbon dioxide is preferable because it can be contained in a large amount in the thermoplastic polyester.
- the osmotic pressure of the inert gas is preferably 30 to 70 kg / cm 2 , more preferably 50 kg / cm 2 or more.
- the infiltration time of the inert gas is 1 hour or more, and more preferably the gas is infiltrated until it becomes saturated.
- the reflector base material 13 is taken out from the high-pressure vessel, and while removing the separator, the reflector base material 13 on which the convex portions 11 are formed is heated to a temperature equal to or higher than the softening temperature of the resin sheet under normal pressure. By doing in this way, as shown in FIG.4 (c), the reflecting plate base material 13 is made to foam. Under the present circumstances, after taking out from a high pressure container, the bulk specific gravity of the foam obtained can be adjusted by adjusting the time until it makes it foam.
- the heating temperature at the time of foaming is set to the melting point or less above the glass transition point of the resin.
- FIG. 5 is an enlarged view of part E in FIG.
- the surface unfoamed layer 8 is usually formed on the surface layer of such a foam.
- the surface unfoamed layer 8 is formed, for example, when gas that has permeated into the inside escapes from the surface of the reflector substrate 13 before foaming (in the direction of arrow F in the figure).
- the fine bubbles 7 are not generated in the vicinity of the surface layer of the reflecting plate substrate 13 during the subsequent foaming process, or the generation amount thereof is reduced. Therefore, in the surface non-foamed layer 8, the fine bubbles 7 are hardly observed and become a solid resin portion.
- the surface area of the convex part 11 increases. For this reason, the amount of escape of this gas increases, and the amount of fine bubbles 7 inside the convex portion 11 becomes smaller than other parts (inside the reflecting plate 5). That is, the volume ratio of the fine bubbles 7 in the convex portion 11 is smaller than the volume ratio of other portions. Therefore, the hardness of the convex part 11 can be made higher than the hardness in parts other than the convex part 11.
- the thickness of the unfoamed surface layer 8 is usually about 5 to 10 ⁇ m, but the thickness of the unfoamed surface layer 8 can be increased by appropriately setting the manufacturing conditions. In the present invention, for example, the thickness of the surface unfoamed layer 8 may be about 30 ⁇ m.
- an intermediate unfoamed layer 10 may be further formed on the inner side in the thickness direction of the surface unfoamed layer 8. That is, the surface unfoamed layer 8, the foamed layer 12, and the intermediate unfoamed layer 10 may be formed in order from the surface on the convex 11 forming surface of the reflector.
- the intermediate non-foamed layer 10 is a region where the fine bubbles 7 are not present (or are present only minutely compared to the inside of the reflector), like the surface unfoamed layer 8.
- the foam layer 12 is a layer in which a predetermined amount of fine bubbles 7 are formed.
- the surface non-foamed layer 8 can improve the hardness of the reflector surface.
- the reflectance is reduced due to light absorption by the unfoamed layer 8.
- a high reflectance is obtained by forming the foamed layer 12 on the inner side of the surface unfoamed layer 8 as shown in FIG. 6 and further forming the intermediate unfoamed layer 10 on the inner side of the foamed layer 12. And the hardness of the convex part are easily compatible.
- the surface unfoamed layer 8 can increase the thickness of the surface unfoamed layer by promoting gas detachment from the surface by heating after removing the resin sheet containing the inert gas. At this time, when heated under appropriate conditions, an intermediate unfoamed layer can also be generated due to the effect of thermal crystallization of the resin.
- the plurality of convex portions 11 are formed on the surface of the reflection plate 5, a gap can be formed between the light guide plate 3 and the reflection plate 5 without applying beads or the like.
- the hardness of the convex part 11 is 95 or more in durometer A hardness, even when a part of the light guide plate 3 is pressed against the reflecting plate 5 due to deformation of the light guide plate 3 or the like, the convex part 11 is crushed. This can be prevented. Therefore, it is possible to prevent the gap between the light guide plate 3 and the reflection plate 5 from being crushed and coming into surface contact with each other. For this reason, formation of a white spot can be suppressed and a backlight panel with high luminance can be obtained.
- Sheet thickness The thickness at the four corners, four sides of the sample and the center of the sheet was measured with a micrometer, and the average value of a total of nine points was taken as the sheet thickness.
- Foaming ratio It calculated as ratio (rho) / rho of the specific gravity ((rho) f) of the foam sheet measured by the underwater substitution method and the specific gravity ((rho) s) of the resin before foaming.
- the reflectance was measured with a spectrophotometer (U-4100, manufactured by Hitachi High-Tech Co., Ltd.) under the condition of a spectral slit of 4 nm and a light wavelength of 550 nm.
- a spectrophotometer U-4100, manufactured by Hitachi High-Tech Co., Ltd.
- an aluminum oxide white plate 210-0740: manufactured by Hitachi High-Tech Fielding Co., Ltd.
- the measured value was a value relative to the reference.
- Durometer A hardness In the present invention, the hardness of the reflective sheet was evaluated by the durometer A hardness based on JIS K 7215 (1986). JIS K 7215 (1986) is a standard corresponding to ISO 868.
- the white spot tolerance evaluation of the reflective sheet was performed as follows. Remove the LCD panel from the commercially available edge light type LCD monitor and take out the backlight. Next, the reflective sheet was taken out from the backlight, and a metal disk having a diameter of 25 mm and a thickness of 1 mm was laid under the reflective sheet, and then the backlight was reassembled as it was. A glass petri dish having a diameter of 50 mm was allowed to stand on the surface of the backlight so that the above-described metal disk was at the center. At the center of the petri dish, a ⁇ 10 mm indenter was set up at a right angle, and the petri dish was compressed while measuring the load.
- the compression was continued until a white spot appeared around the metal disk, and the load (unit N: Newton) when the white spot appeared for the first time was read as white spot resistance.
- the white spot resistance was judged to be acceptable if it was 40N or more, and rejected if it was less than 40N.
- a polyester elastomer grade: Hytrel 2551, manufactured by Toray DuPont
- the roll was put into a pressure vessel, pressurized to 6 MPa with carbon dioxide gas, and carbon dioxide gas was infiltrated into the resin sheet.
- the penetration time was 72 hours.
- the roll was taken out from the pressure vessel, and while removing the separator, only the resin sheet was supplied to a hot air oven set at a temperature lower than the melting point of the resin and foamed.
- Example 2 A foam sheet was obtained by changing only the temperature and pressure conditions for embossing the sheet having the same composition as in Example 1.
- the roll was put into a pressure vessel, pressurized to 6 MPa with carbon dioxide gas, and carbon dioxide gas was infiltrated into the resin sheet.
- the penetration time was 72 hours.
- the roll was taken out from the pressure vessel, and while removing the separator, only the resin sheet was supplied to a hot air oven set at a temperature lower than the melting point of the resin and foamed.
- the foamed sheet thus obtained was passed between rolls heated above the glass transition point of the resin, and a predetermined pressure was applied to make the surface of the sheet uneven.
- Comparative Example 2 A foamed sheet was obtained by changing only the conditions for embossing the sheet having the same composition as Comparative Example 1.
- Example 1 As shown in Table 1, in Example 1, the thickness of the foamed sheet was 0.75 mm, and the specific gravity was 0.35. When the arithmetic average roughness of the surface of the foam sheet having the convex portions was measured, Ra was 7.9, and the durometer A hardness was 96.8. It was a pass level when the white spot tolerance of the obtained reflective sheet was measured.
- Example 2 the thickness of the foam sheet was 0.55 mm, and the specific gravity was 0.35.
- the arithmetic average roughness of the surface of the foam sheet having the convex portions was measured to find 6.4, and the durometer A hardness measured to be 95.8. It was a pass level when the white spot tolerance of the obtained reflective sheet was measured.
- the thickness of the foamed sheet was 0.73 mm, and the specific gravity was 0.36.
- the arithmetic mean roughness of the surface of the foamed sheet having the convex portions was measured and found to be 3.5, and the durometer A hardness was measured to be 92.4. Since the arithmetic average roughness was small and the duro A hardness was low, the white spot resistance of the obtained reflective sheet was measured and found to be a rejected level.
- the thickness of the foam sheet was 0.60 mm, and the specific gravity was 0.35.
- the arithmetic average roughness of the surface of the foam sheet having the convex portions was measured and found to be 5.9, and the durometer A hardness was 92. Since the arithmetic average roughness was small and the duro A hardness was low, the white spot resistance of the obtained reflective sheet was measured and found to be a rejected level.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Planar Illumination Modules (AREA)
- Optical Elements Other Than Lenses (AREA)
Description
本発明は液晶パネルに用いられる導光板式のバックライトパネル等に関するものである。 The present invention relates to a light guide plate type backlight panel used in a liquid crystal panel.
従来、液晶表示装置等において、液晶層の背面側から光を照らして発光させるバックライトパネルが用いられている。近年では特に、光源の数を減らすことができ、省エネルギー化に有利なエッジライト方式のバックライトパネルの採用が増えている。エッジライト式バックライトパネルの導光板には、隣接して反射板が設置される。反射板の役割は、光源から導光板内に導かれた光のうち反射板側に漏れた光を液晶層側に戻して輝度を高めることにある。このようなエッジライト方式のバックライトパネルにおいては、光の出射面全体における均一な輝度が要求される。 Conventionally, in a liquid crystal display device or the like, a backlight panel that emits light by illuminating light from the back side of a liquid crystal layer is used. In recent years, in particular, the use of an edge-light type backlight panel that can reduce the number of light sources and is advantageous for energy saving is increasing. A reflection plate is installed adjacent to the light guide plate of the edge light type backlight panel. The role of the reflecting plate is to return the light leaked to the reflecting plate side out of the light guided from the light source into the light guiding plate to the liquid crystal layer side to increase the luminance. Such an edge light type backlight panel is required to have uniform luminance over the entire light emission surface.
エッジライト方式のバックライトパネルでは、導光板の背面側に出射する光は、反射板で反射されて導光板内部に戻り、導光板の前面側から出射される。したがって、反射板での光の反射により高い輝度を得ることができる。 In the edge light type backlight panel, light emitted to the back side of the light guide plate is reflected by the reflection plate, returns to the inside of the light guide plate, and is emitted from the front side of the light guide plate. Therefore, high brightness can be obtained by reflection of light on the reflecting plate.
反射板と導光板との間には、通常、隙間が形成される。これは、反射板と導光板とを密着させると、ホワイトスポットと呼ばれる部分的に明るい部分が生じ、輝度にムラが生じる恐れがあるためである。例えば、導光板等が熱等で部分的に変形した際に、当該部位が他の部位に対して反射板に強く押しつけられると、それらの部位の輝度が他の部位と同一とならず、ホワイトスポット等の要因となり得る。 A gap is usually formed between the reflector and the light guide plate. This is because, when the reflecting plate and the light guide plate are brought into close contact with each other, a partially bright portion called a white spot is generated, and there is a risk of unevenness in luminance. For example, when the light guide plate or the like is partially deformed by heat or the like, if the part is strongly pressed against the reflective plate against other parts, the luminance of those parts is not the same as the other parts, and white It can be a factor such as a spot.
導光板と反射板の間に空隙を設ける方法として、架橋アクリルビーズ等をバインダーに混合したものを反射板の表面に塗布する方法がある(特許文献1)。
別の方法として、反射板の表面に凹凸を付ける方法がある。(特許文献2~5)。
As a method of providing a gap between the light guide plate and the reflection plate, there is a method of applying a mixture of crosslinked acrylic beads or the like to a binder on the surface of the reflection plate (Patent Document 1).
As another method, there is a method of forming irregularities on the surface of the reflector. (
しかし、特許文献1のように、ビーズによって反射板と導光板との隙間を維持する方法では、ビーズを均一に分散させて塗布する必要がある。このため、別途ビーズを使用する必要があり、材量費が上昇する。また、ビーズの塗布工程が必要となるため製造工数を要する。
However, as in
また、特許文献2~5のような発泡体の表面に直接凹凸形状を形成する方法では、製造性は優れるものの、任意の凹凸をつけただけではホワイトスポットに対する耐性は十分ではなかった。これに対し、発明者らは特定の条件を満たした凹凸のみがホワイトスポットを抑制しうることを見出した。
Further, in the method of directly forming the uneven shape on the surface of the foam as in
本発明は、このような問題に鑑みてなされたもので、製造性にも優れ、ホワイトスポット等の発生を防止可能な反射板等を提供することを目的とする。 The present invention has been made in view of such problems, and an object of the present invention is to provide a reflector plate that is excellent in manufacturability and can prevent the occurrence of white spots and the like.
前述した目的を達するために第1の発明は、熱可塑性樹脂発泡体からなるバックライトパネル用の反射板であって、前記反射板の少なくとも一方の面に、複数の凸部が形成され、前記凸部を有する表面のデュロメータA硬さが95以上100未満であることを特徴とする反射板である。 In order to achieve the above-mentioned object, a first invention is a reflector for a backlight panel made of a thermoplastic resin foam, and a plurality of convex portions are formed on at least one surface of the reflector, A durometer A hardness of a surface having a convex portion is 95 or more and less than 100.
また、前記凸部を有する表面の算術平均粗さRaが6以上30未満であることを特徴とする反射板であることが望ましい。 Further, it is desirable that the reflecting plate is characterized in that the arithmetic average roughness Ra of the surface having the convex portion is 6 or more and less than 30.
前記反射板は少なくとも前記凸部の形成面の表面に第1の未発泡層を有しており、前記第1の未発泡層の厚さが5~30μmであることが望ましい。 It is desirable that the reflecting plate has a first unfoamed layer on at least the surface of the convex forming surface, and the thickness of the first unfoamed layer is 5 to 30 μm.
前記第1の未発泡層の厚み方向の内部側に発泡層があり、さらに前記発泡層の内部側に第2の未発泡層を有することが望ましい。 It is desirable that the first unfoamed layer has a foamed layer on the inner side in the thickness direction, and further has a second unfoamed layer on the inner side of the foamed layer.
前記反射板の総厚さが0.3mm以上であることが望ましい。前記反射板の比重が0.7以下であることが望ましい。前記熱可塑性樹脂が熱可塑性ポリエステル系樹脂であることが望ましく、ポリエチレンテレフタレート樹脂であることが望ましい。 It is desirable that the total thickness of the reflector is 0.3 mm or more. It is desirable that the specific gravity of the reflector is 0.7 or less. The thermoplastic resin is preferably a thermoplastic polyester resin, and is preferably a polyethylene terephthalate resin.
第1の発明によれば、反射板の表面に複数の凸部が形成されるため、反射板を導光板の後面に配置した際に、導光板との間の隙間を当該凸部で維持することができる。この際、反射板が発泡体であるため、反射板内部で光を効率良く拡散させて、前面に反射させることができる。また、凸部の硬度が、デュロメータA硬さ95以上であるため、凸部の潰れを防止し、凸部の潰れに伴う導光板と反射板との部分的な密着を防止することができる。 According to the first invention, since the plurality of convex portions are formed on the surface of the reflecting plate, when the reflecting plate is disposed on the rear surface of the light guide plate, the gap between the light guide plate is maintained by the convex portions. be able to. At this time, since the reflecting plate is a foam, light can be efficiently diffused inside the reflecting plate and reflected to the front surface. Moreover, since the hardness of the convex portion is durometer A hardness 95 or more, the convex portion can be prevented from being crushed, and partial adhesion between the light guide plate and the reflecting plate due to the crushed convex portion can be prevented.
また、算術平均粗さRaが6以上であれば、凸部が過度につぶれずに、導光板と反射板との間に、一定以上の隙間を確保することができる。 Further, if the arithmetic average roughness Ra is 6 or more, a certain gap or more can be secured between the light guide plate and the reflection plate without excessively collapsing the convex portion.
また、反射板が少なくとも凸部の形成面の表面に第1の未発泡層を有すれば、凸部の硬度を効率良く高めることができる。さらに、第1の未発泡層の厚さが5~30μmであれば、硬度向上の効果が高く、また、未発泡層における光の吸収により反射率が低下することを抑制することができる。 Also, if the reflecting plate has the first unfoamed layer on at least the surface of the convex forming surface, the hardness of the convex can be increased efficiently. Further, if the thickness of the first unfoamed layer is 5 to 30 μm, the effect of improving the hardness is high, and it is possible to suppress a decrease in reflectance due to light absorption in the unfoamed layer.
また、第1の未発泡層と第2の未発泡層を形成し、その間に発泡層を形成することで、高い反射率の確保と、凸部を有する表面の硬度とを両立しやすい。 Further, by forming the first unfoamed layer and the second unfoamed layer and forming the foamed layer therebetween, it is easy to achieve both high reflectivity and the hardness of the surface having the convex portion.
また、反射板の総厚を0.3mm以上とすれば、反射板の波シワの発生を抑制することができる。また、反射板の比重が0.7以下であれば、軽量化を達成することができ、材料費を削減することができる。また、熱可塑性樹脂として熱可塑性ポリエステル系樹脂であるポリエチレンテレフタレート樹脂を適用することで、耐熱性やコストにも優れる反射板を得ることができる。 Also, if the total thickness of the reflector is 0.3 mm or more, the occurrence of wrinkles on the reflector can be suppressed. Moreover, if the specific gravity of a reflecting plate is 0.7 or less, weight reduction can be achieved and material cost can be reduced. In addition, by applying a polyethylene terephthalate resin, which is a thermoplastic polyester resin, as the thermoplastic resin, a reflector having excellent heat resistance and cost can be obtained.
第2の発明は、バックライトパネル用の反射板の製造方法であって、熱可塑性樹脂発泡体からなる反射板基材に不活性ガスを含有させる工程aと、前記反射板基材にエンボス加工を施す工程bと、前記反射板基材を加熱して発泡処理を行う工程cと、を具備することを特徴とする反射板の製造方法である。 2nd invention is the manufacturing method of the reflecting plate for backlight panels, Comprising: The process a which contains the inert gas in the reflecting plate base material which consists of thermoplastic resin foams, The embossing to the said reflecting plate base material And a step c of heating the reflector substrate and performing a foaming process.
第2の発明によれば、凸部を形成する際に、反射板基材の表面積が増大するため、発泡時に、凸部の内部のガス成分が抜けやすくなる。したがって、凸部形成面に未発泡層を形成しやすく、凸部の硬度を高めることができる。 According to the second invention, when the convex portion is formed, the surface area of the reflector substrate is increased, so that the gas component inside the convex portion is easily released during foaming. Therefore, it is easy to form an unfoamed layer on the convex portion forming surface, and the hardness of the convex portion can be increased.
第3の発明は、第1の発明にかかる反射板と、前記反射板の前面に設けられる導光板と、前記導光板の側方に設けられる光源と、を具備し、前記凸部によって、前記反射板と前記導光板との間に隙間が形成されることを特徴とするバックライトパネルである。 3rd invention comprises the reflecting plate concerning 1st invention, the light-guide plate provided in the front surface of the said reflecting plate, and the light source provided in the side of the said light-guide plate, The said convex part WHEREIN: The backlight panel is characterized in that a gap is formed between the reflector and the light guide plate.
第3の発明によれば、反射板表面の凸部によって、導光板と反射板との間に隙間を維持することができる。また、反射板表面の凸部の硬度が高いため、凸部が潰れにくい。このため、導光板の一部の変形等によって、導光板が反射板の表面に部分的に密着することを防止することができる。このため、全面において均一な輝度のバックライトパネルを得ることができる。 According to the third invention, a gap can be maintained between the light guide plate and the reflection plate by the convex portion on the surface of the reflection plate. Moreover, since the convex part on the surface of the reflecting plate has a high hardness, the convex part is not easily crushed. For this reason, it is possible to prevent the light guide plate from being partially adhered to the surface of the reflection plate due to partial deformation of the light guide plate. For this reason, a backlight panel with uniform brightness can be obtained over the entire surface.
本発明によれば、製造性にも優れ、ホワイトスポット等の発生を防止可能な反射板等を提供することができる。 According to the present invention, it is possible to provide a reflector that is excellent in manufacturability and can prevent the occurrence of white spots and the like.
以下、図面を参照しながら、本発明の実施形態について説明する。図1は液晶表示装置等に用いられるバックライトパネル1を示す図であり、図2は、図1のA部拡大図、図3は図2のB部拡大図である。バックライトパネル1は、いわゆるエッジライト方式のバックライトパネルであり、主に、導光板3、反射板5、光源9等から構成される。
Hereinafter, embodiments of the present invention will be described with reference to the drawings. 1 is a view showing a
光源9は、導光板3の側部(エッジ)に配置され、リフレクタ2等により包囲される。光源9としては、例えば、LED(Light Emitting Diode)、CCFL(Cold Cathode Fluorescent Lamp)、EEFL(External Electrode Fluorescent Lamp)、HCFL(Hot Cathode Fluorescent Lamp)等を用いることができ、LEDのような点光源を一列に配置したものも適用することができる。
The light source 9 is disposed on the side (edge) of the
導光板3は、平板状であり、光の出射面(図1の上面側で図示を省略した液晶パネルが配置される側)および背面は平滑に構成される。導光板3の背面側には隙間を介して反射板5が設けられる。導光板3の背面側には光の拡散を目的としたドットパターンが印刷されていてもよい。なお、導光板3としては、例えばアクリル樹脂を使用することができる。
The
図2に示すように、反射板5は独立気泡である微細気泡7を有する多孔質体であり、例えば樹脂発泡体で形成される。より詳細には、平均気泡径が50nm以上で50μm以下の微細な気泡または気孔を内部に有する熱可塑性樹脂シートを好適に用いることができる。
As shown in FIG. 2, the
反射板5は、その耐熱性を考慮すると、熱可塑性ポリエステル系樹脂で構成されることが好ましい。本発明において用いられる熱可塑性ポリエステル樹脂としては、限定されるものではないが、例えば、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンナフタレート等を適宜選択することができ、これらは1種を単独で用いてもよく、2種以上を混合して用いてもよい。中でも、ポリエチレンテレフタレートであれば入手のしやすさ、経済性、耐熱性等の面で好適である。
The reflecting
本発明においては、得られる反射板5の特性に影響を及ぼさない範囲で、発泡前の熱可塑性樹脂シートに、結晶化核剤、結晶化促進剤、気泡化核剤、酸化防止剤、帯電防止剤、紫外線防止剤、光安定剤、蛍光増白剤、顔料、染料、相溶化剤、滑剤、強化剤、難燃剤、架橋剤、架橋助剤、可塑剤、増粘剤、減粘剤などの各種添加剤を配合してもよい。また、得られた反射板に上記添加剤を含有する樹脂を積層してもよいし、上記添加剤を含有する塗料をコーティングしてもよい。紫外線防止剤などを含む層をポリエステル系樹脂発泡体の少なくとも一方の表面に付与することは、熱可塑性ポリエステル樹脂やポリエステル系エラストマーに紫外線劣化しやすいものを用いた場合でも十分な耐紫外線劣化防止能を付与できるので、特に好ましい。
In the present invention, a crystallization nucleating agent, a crystallization accelerator, a bubble nucleating agent, an antioxidant, an antistatic agent are added to the thermoplastic resin sheet before foaming within a range that does not affect the properties of the obtained
なお、反射板5の厚みとしては0.1mm以上であることが望ましい。反射板5の厚みが0.1mm未満では剛性が低く、波シワが発生しやすいため好ましくない。剛性を高める観点でいえば、反射板5の厚みは0.2mm以上が好ましく、0.3mm以上であればさらに好ましい。
In addition, it is desirable that the thickness of the reflecting
また、反射板5の比重としては0.7以下であることが望ましく、より望ましくは比重は0.6未満であり、比重が0.5未満であればさらに好ましい。比重が大きいと、微細気泡7の分布量が十分ではなく、微細気泡による効果が小さくなる。また、反射板5の反射率は限定されないが、液晶パネルの反射板として用いる場合には、反射板5の全反射率は90%以上であることが望ましい。また、省エネルギーの観点でいえば、反射率は95%以上であれば好ましく、98%以上であればさらに好ましい。
The specific gravity of the
反射板5の表面には、複数の凸部11が形成される。すなわち、導光板3は、反射板5表面の凸部11と接触し、凸部11によって、導光板3と反射板5との間には隙間が形成される。なお、凸部11の形状は、図示した例に限られず、他の形状であってもよいが、凸部11の先端が潰れにくいように、断面円弧状の先端形状であることが望ましい。また、凸部11の形状は、圧縮されても隙間がつぶれないようにするため、ある一定以上の高さが必要である。具体的には算術平均粗さRaが5以上であることが好ましい。より確実にホワイトスポットを抑えるためにはRaは6以上が好ましく、Raが7以上であればさらに好ましい。なお、Raが30を超えると、小さい圧力でも凸部が潰れやすくなるので好ましくない。
A plurality of convex portions 11 are formed on the surface of the reflecting
また、凸部11は、反射板5の表面に整列せずに、ランダムに分散されることが望ましい。凸部11をランダムに配置することで、反射板5を導光板3の後面に配置して、バックライトパネルユニットとして用いた際に、光の干渉等に伴う縞模様などの発生がなく、均一な輝度を得ることができる。なお、凸部11の形成方法については後述する。
Further, it is desirable that the convex portions 11 are randomly dispersed without being aligned with the surface of the reflecting
図3は、図2のB部拡大図である。図に示すように、凸部11の頂部が導光板3と接触する。ここで、凸部11の基部(凸部11の最底部)よりも上部(図中C)を凸部範囲とし、凸部11の基部よりも下方(図中D)を凸部以外の範囲とする。すなわち、導光板3と反射板5との間には凸部範囲Cに対応する隙間が形成される。
FIG. 3 is an enlarged view of part B of FIG. As shown in the figure, the top of the convex portion 11 is in contact with the
本発明では、反射板や導光板の熱変形等によって面圧がかかったとしても、隙間が潰れない程度の反射板5表面の硬度が必要である。そのため、凸部11を有する表面には高い硬度が求められる。具体的にはデュロメータA硬さで95以上が要求される。デュロメータA硬さが95未満であるとホワイトスポットが出る可能性が非常に高まる。確実にホワイトスポットを抑えるためにはデュロメータA硬さは96以上が好ましく、97以上であればさらに好ましい。
In the present invention, even if a surface pressure is applied due to thermal deformation or the like of the reflecting plate or the light guide plate, the surface of the reflecting
このような構成とするため、反射板5の表面に表面未発泡層8を形成することが望ましい。表面未発泡層8は、反射板5の凸部11の形成面側に形成され、微細気泡が存在しない(または反射板内部と比較して微小にしか存在しない)領域である。表面未発泡層8は、その厚みが薄すぎると硬度向上の効果が小さい。また、その厚みが厚すぎると、反射板5全体の比重が大きくなるとともに、表面未発泡層8での光の吸収により反射率が低下する懸念がある。このため、表面未発泡層8の厚さの範囲は3~50μm程度であれば好ましく、5~30μmであればさらに好ましい。
In order to obtain such a configuration, it is desirable to form the surface
次に、バックライトパネル1の機能を説明する。光源9から発せられた光は、直接、あるいは光源の後ろに配置されたリフレクタ2等により導光板3内部に入射する。導光板3内部へ入射した光線は、導光板3の前面に存在する空気層のため界面で全反射する。一方、導光板3の背面側では、光の一部が透過し、反射板5内に入射する。反射板5に入射した光は反射板5で反射され、導光板3内に戻る。戻った光の一部は、導光板3の前面で再度全反射するが、残りの光は導光板3の前面に出射する。こうしてバックライトパネルの全面から均一に光を出射することができる。
Next, the function of the
なお、反射板5内では、多数の微細気泡7(内部は例えば空気層であり、屈折率は反射板5を構成する樹脂よりも小さい)との界面で全反射または拡散されて、導光板3側に出射される。反射板5で拡散された光線は導光板3内に戻り、一部は導光板3の前面で再度全反射するとともに、残りの光が導光板3の前面に出射する。
In the
この際、光を拡散させる反射板5は、多孔質体であり、白色塗料等よりも光の吸収が極めて少ない。また、光の拡散および反射を、反射板5の平均孔径および密度等によって容易に制御することが可能である。また、反射板5と導光板3との間には、所定の隙間が維持されるため、導光板3と反射板5との面接触等によってホワイトスポット等が生じることがない。すなわち、導光板3の前面において、均一な輝度を確保することができる。
At this time, the reflecting
次に、反射板5の製造方法について説明する。図4は、反射板5の製造工程を示す概略図である。なお、シート内部に気泡を導入する方法は限定されないが、例えば、圧力容器内で樹脂シートにガスを含浸させてから加熱して発泡させるバッチ発泡法、押出機のダイから熱可塑性樹脂シートを押し出すとともに発泡させる押出発泡法、さらにフィラー入りの熱可塑性樹脂シートを押し出してから延伸してフィラーと樹脂の界面に空洞をつくる延伸法等がある。ここではバッチ発泡法による反射板5の製造方法を一例として示す。バッチ発泡法であれば、押出発泡法より気泡を微細化しやすく、延伸法よりも厚く、かつ比重を小さくしやすいという利点がある。
Next, a method for manufacturing the
まず、図4(a)に示すように反射板基材13を製造する。なお、図4(a)では、セパレータの図示を省略する。まず、熱可塑性樹脂シートを作製し、熱可塑性樹脂シートとセパレータとを重ね合わせて巻くことによりロールを形成する。ここで用いられるセパレータは、不活性ガスや必要に応じて用いられる有機溶剤が自由に出入りする空隙を有し、かつそれ自身への不活性ガスの浸透が無視できるものであればいかなるものでもよい。セパレータとしては、特に樹脂製不織布または金属製の網が好適である。
First, as shown in FIG. 4A, the
一方、熱可塑性樹脂シートは無延伸であることが好ましい。これは、熱可塑性樹脂シートが延伸されていると、ガスが十分にシート内に浸透しないため、目的とする発泡シートが得られなくなるためである。 On the other hand, the thermoplastic resin sheet is preferably unstretched. This is because when the thermoplastic resin sheet is stretched, the gas does not sufficiently permeate into the sheet, and the intended foamed sheet cannot be obtained.
なお、上記方法では、樹脂シートとセパレータとからなるロールを加圧不活性ガス雰囲気中に保持して樹脂シートに不活性ガスを含有させる前に、樹脂シートに有機溶剤を含有させてもよい。シートに有機溶剤を含有させると、熱可塑性樹脂シートの結晶化度を30%以上にすることができる。この結果、シートの剛性が増大してシート表面にセパレータの跡が残存しにくくなるとともに、不活性ガスの浸透時間を短縮できる。なお、セパレータの種類によってはシート表面にセパレータの跡が残存しないこともあるので、有機溶剤を含有させる処理は必ずしも必要なわけではない。ただし、ガス浸透時間の短縮の観点からは有機溶剤を含有させる処理を実施することが好ましい。 In the above method, an organic solvent may be contained in the resin sheet before the roll made of the resin sheet and the separator is held in a pressurized inert gas atmosphere and the resin sheet contains the inert gas. When an organic solvent is contained in the sheet, the crystallinity of the thermoplastic resin sheet can be increased to 30% or more. As a result, the rigidity of the sheet is increased and it is difficult for the trace of the separator to remain on the surface of the sheet, and the permeation time of the inert gas can be shortened. Depending on the type of separator, the trace of the separator may not remain on the surface of the sheet, so that the treatment containing the organic solvent is not necessarily required. However, from the viewpoint of shortening the gas permeation time, it is preferable to carry out a treatment containing an organic solvent.
樹脂シートの結晶化度を上げるために用いられる有機溶剤としては、ベンゼン、トルエン、メチルエチルケトン、ギ酸エチル、アセトン、酢酸、ジオキサン、m-クレゾール、アニリン、アクリロニトリル、フタル酸ジメチル、ニトロエタン、ニトロメタン、ベンジルアルコールなどが挙げられる。これらのうち、取り扱い性および経済性の観点からアセトンがより好ましい。 Organic solvents used to increase the crystallinity of the resin sheet include benzene, toluene, methyl ethyl ketone, ethyl formate, acetone, acetic acid, dioxane, m-cresol, aniline, acrylonitrile, dimethyl phthalate, nitroethane, nitromethane, benzyl alcohol Etc. Of these, acetone is more preferable from the viewpoints of handleability and economy.
次に、図4(b)に示すように、反射板基材13の表面に多数の凸部11を形成する。凸部11の形成には、例えば、樹脂シートを、凸部11に対応する凹部を有する一対のエンボスロールの間に通し、当該ロールによって反射板基材13の表面に凸部11(例えばエンボス加工)を形成すればよい。なお、発泡したシートを前述のエンボスロールの間に通して凹凸を付与してもよい。凹凸のつけやすさの観点でみると、ガス浸透前のシートの方が、シートの中心層の変形が少ない分、凹凸を付けやすいという利点がある。
Next, as shown in FIG. 4B, a large number of convex portions 11 are formed on the surface of the
次に、凸部11が形成された反射板基材13を高圧力容器内に入れ、加圧不活性ガス雰囲気中に保持して熱可塑性シートに発泡剤となる不活性ガスを含有させる。不活性ガスとしては、ヘリウム、窒素、二酸化炭素、アルゴンなどが挙げられる。これらのうち、二酸化炭素は熱可塑性ポリエステル中に多量に含有させることができる点で好ましい。不活性ガスの浸透圧力は30~70kg/cm2、さらに50kg/cm2以上とすることが好ましい。不活性ガスの浸透時間は1時間以上とし、より好ましくは飽和状態になるまでガスを浸透させる。
Next, the
次に、高圧力容器から反射板基材13を取り出し、セパレータを取り除きながら、凸部11が形成された反射板基材13を常圧下で、樹脂シートの軟化温度以上に加熱する。このようにすることで、図4(c)に示すように、反射板基材13を発泡させる。この際、高圧力容器から取り出した後、発泡させるまでの時間を調整することにより、得られる発泡体の嵩比重を調整できる。
Next, the
具体的には、この時間が長いほど嵩比重の大きな発泡体が得られる。なお、発泡時の加熱温度は、その樹脂のガラス転移点以上で融点以下に設定される。 Specifically, the longer this time, the larger the bulk specific gravity. In addition, the heating temperature at the time of foaming is set to the melting point or less above the glass transition point of the resin.
図5は、図4(c)のE部拡大図である。図5に示すように、通常、このような発泡体の表層には、表面未発泡層8が形成される。表面未発泡層8は、例えば、発泡前の反射板基材13の表面から、内部に浸透させたガスが抜けることで(図中矢印F方向)形成される。反射板基材13の表面のガス量が低下することで、その後の発泡処理の際に、反射板基材13表層近傍において微細気泡7が生成されず、または、その生成量が少なくなる。したがって、表面未発泡層8では、微細気泡7がほとんど観察されず、ソリッドな樹脂部となる。
FIG. 5 is an enlarged view of part E in FIG. As shown in FIG. 5, the
反射板基材13の表面に凸部11を形成すると、凸部11では、表面積が増大する。このため、このガスの抜け量が多くなり、凸部11内部の微細気泡7の量が他の部位(反射板5の内部)よりも少なくなる。すなわち、凸部11における微細気泡7の体積割合が、他の部位の体積割合に対して小さくなる。したがって、凸部11の硬度を、凸部11以外の部位における硬度よりも高くすることができる。
When the convex part 11 is formed on the surface of the
なお、通常は表面未発泡層8の厚みは5~10μm程度であるが、製造条件を適宜設定することで、この表面未発泡層8の厚みを厚くすることができる。本発明では、例えば、表面未発泡層8の厚みを30μm程度とすればよい。
Note that the thickness of the
次に、反射板の他の実施形態について説明する。図6に示すように、表面未発泡層8の厚み方向の内部側に、さらに中間未発泡層10を形成してもよい。すなわち、反射板の凸部11形成面において、表面から順に、表面未発泡層8、発泡層12、中間未発泡層10を形成してもよい。中間未発泡層10は、表面未発泡層8と同様に、微細気泡7が存在しない(または反射板内部と比較して微小にしか存在しない)領域である。また、発泡層12は、微細気泡7が所定量形成される層である。
Next, another embodiment of the reflector will be described. As shown in FIG. 6, an
前述の通り、表面未発泡層8によって、反射板表面における硬度を向上させることができる。しかし、表面未発泡層8だけで表面を所定の硬さにするために厚い表面未発泡層8だけを反射板の表面に配置すると、表面未発泡層8による光の吸収により反射率が低下する懸念がある。そこで、図6のような表面未発泡層8の内部側に発泡層12を形成し、さらにその発泡層12の内部側に中間未発泡層10が形成された構造とすることで、高い反射率と凸部の硬度を両立しやすくなる。
As described above, the surface
なお、表面未発泡層8は、不活性ガスを含有させた樹脂シートを取り出してから加熱することで、表面からガスの脱離を促進して表面未発泡層を厚くすることができるが、この際、適切な条件で加熱すると、樹脂が熱結晶化する影響で、中間未発泡層も生じさせることができる。
The
本発明によれば、反射板5の表面に複数の凸部11を形成するため、ビーズ等を塗布することなく、導光板3と反射板5との間に隙間を形成することができる。また、凸部11の硬度が、デュロメータA硬さで95以上であるため、導光板3の変形等によって、導光板3の一部が反射板5に押しつけられた場合でも、凸部11が潰れることを防止することができる。したがって、導光板3と反射板5との隙間が押し潰されて、互いに面接触することを防止することができる。このため、ホワイトスポットの形成を抑制し、高い輝度のバックライトパネルを得ることができる。
According to the present invention, since the plurality of convex portions 11 are formed on the surface of the
(測定評価方法)
以下、実施例により本発明を詳述する。なお、測定、評価は以下の方法で行った。
(Measurement evaluation method)
Hereinafter, the present invention will be described in detail by way of examples. Measurement and evaluation were performed by the following methods.
(1)シート厚
サンプルの4角、4辺及びシートの中心における厚みをマイクロメータにより測定し、合計9点の平均値をシート厚とした。
(1) Sheet thickness The thickness at the four corners, four sides of the sample and the center of the sheet was measured with a micrometer, and the average value of a total of nine points was taken as the sheet thickness.
(2)平均気泡径
ASTMD3576-77に準じて求めた。シートの断面のSEM写真を撮影し、SEM写真上に水平方向と垂直方向に直線を引き、直線が横切る気泡の弦の長さtを平均した。写真の倍率をMとして、下記式に代入して平均気泡径dを求めた(d=t/(0.616×M))。
(2) Average cell diameter It was determined according to ASTM D3576-77. An SEM photograph of the cross section of the sheet was taken, straight lines were drawn in the horizontal direction and the vertical direction on the SEM photograph, and the length t of the bubble chord crossed by the straight line was averaged. Assuming that the magnification of the photograph is M, the average bubble diameter d was determined by substituting it into the following equation (d = t / (0.616 × M)).
(3)発泡倍率
水中置換法により測定された発泡体シートの比重(ρf)と発泡前の樹脂の比重(ρs)との比ρs/ρfとして算出した。
(3) Foaming ratio It calculated as ratio (rho) / rho of the specific gravity ((rho) f) of the foam sheet measured by the underwater substitution method and the specific gravity ((rho) s) of the resin before foaming.
(4)反射率
反射率の測定は、分光光度計(日立ハイテク社製U-4100)にて分光スリット4nmの条件にて光線波長550nmで分光全反射率の測定を行った。リファレンスは酸化アルミニウム白色板(210-0740:(株)日立ハイテクフィールディング製)を使用し、測定値はリファレンスに対する相対値とした。
(4) Reflectance The reflectance was measured with a spectrophotometer (U-4100, manufactured by Hitachi High-Tech Co., Ltd.) under the condition of a spectral slit of 4 nm and a light wavelength of 550 nm. As a reference, an aluminum oxide white plate (210-0740: manufactured by Hitachi High-Tech Fielding Co., Ltd.) was used, and the measured value was a value relative to the reference.
(5)デュロメータA硬さ
本発明において反射シートの硬度は、JIS K 7215(1986)に基づくデュロメータA硬さによって評価した。なお、JIS K 7215(1986)は、ISO 868に対応する規格である。
(5) Durometer A hardness In the present invention, the hardness of the reflective sheet was evaluated by the durometer A hardness based on JIS K 7215 (1986). JIS K 7215 (1986) is a standard corresponding to ISO 868.
(6)表面粗さ
本発明において反射シートの表面粗さは、JIS B0601(2001)に基づいて算術平均粗Raで評価した。なお、JIS B0601(2001)は、ISO 4287に対応する規格である。
(6) Surface roughness In this invention, the surface roughness of the reflective sheet was evaluated by arithmetic mean roughness Ra based on JIS B0601 (2001). JIS B0601 (2001) is a standard corresponding to ISO 4287.
(7)ホワイトスポット耐性
本発明において、反射シートのホワイトスポット耐性の評価は次のように行った。市販のエッジライト型液晶モニタから液晶パネルを取り外してバックライトを取りだす。次に、前記バックライトから反射シートを取りだし、反射シートの下に直径25mm、厚さ1mmの金属製の円盤を敷いてから、バックライトを元のように組み直した。バックライトの表面に、前述の金属製の円盤が中心に来るように、直径50mmのガラス製のシャーレを静置した。シャーレの中心に、Φ10mmの圧子を直角に立て、荷重を測定しながらシャーレを圧縮した。前述の金属製の円盤の周囲にホワイトスポットが出るまで圧縮を続け、初めてホワイトスポットが出たときの荷重(単位N:ニュートン)をホワイトスポット耐性として読み取った。ホワイトスポット耐性は40N以上あれば合格、40N未満だと不合格と判断した。
(7) White spot tolerance In this invention, the white spot tolerance evaluation of the reflective sheet was performed as follows. Remove the LCD panel from the commercially available edge light type LCD monitor and take out the backlight. Next, the reflective sheet was taken out from the backlight, and a metal disk having a diameter of 25 mm and a thickness of 1 mm was laid under the reflective sheet, and then the backlight was reassembled as it was. A glass petri dish having a diameter of 50 mm was allowed to stand on the surface of the backlight so that the above-described metal disk was at the center. At the center of the petri dish, a Φ10 mm indenter was set up at a right angle, and the petri dish was compressed while measuring the load. The compression was continued until a white spot appeared around the metal disk, and the load (unit N: Newton) when the white spot appeared for the first time was read as white spot resistance. The white spot resistance was judged to be acceptable if it was 40N or more, and rejected if it was less than 40N.
(実施例1)
ポリエチレンテレフタレート(グレード:SA-1206、ユニチカ製、ρs=1.34)100重量部に、ポリエステル系エラストマー(グレード:ハイトレル2551、東レ・デュポン製)2重量部を添加して混練した後、0.5mm厚×250mm幅×60m長さのシートに成形した。こうして得たシートを樹脂のガラス転移点以上に加熱されたロールの間に通し、所定の圧力をかけてシートの表面に凹凸をつけた。このシートにオレフィン系不織布のセパレータを重ねて巻き、ロール状にした。
Example 1
After adding 2 parts by weight of a polyester elastomer (grade: Hytrel 2551, manufactured by Toray DuPont) to 100 parts by weight of polyethylene terephthalate (grade: SA-1206, unitika, ρs = 1.34) The sheet was formed into a sheet of 5 mm thickness × 250 mm width × 60 m length. The sheet thus obtained was passed between rolls heated above the glass transition point of the resin, and a predetermined pressure was applied to make the surface of the sheet uneven. An olefin-based nonwoven fabric separator was stacked on this sheet and wound into a roll shape.
その後、上記ロールを圧力容器に入れ、炭酸ガスで6MPaに加圧し、樹脂シートに炭酸ガスを浸透させた。浸透時間は72時間とした。浸透完了後、圧力容器からロールを取り出し、セパレータを取り除きながら樹脂シートだけを樹脂の融点以下の温度に設定した熱風炉に供給して発泡させた。 Thereafter, the roll was put into a pressure vessel, pressurized to 6 MPa with carbon dioxide gas, and carbon dioxide gas was infiltrated into the resin sheet. The penetration time was 72 hours. After completion of the infiltration, the roll was taken out from the pressure vessel, and while removing the separator, only the resin sheet was supplied to a hot air oven set at a temperature lower than the melting point of the resin and foamed.
(実施例2)
実施例1と同じ組成のシートにエンボスを付与する温度と圧力条件のみを変えて発泡シートを得た。
(Example 2)
A foam sheet was obtained by changing only the temperature and pressure conditions for embossing the sheet having the same composition as in Example 1.
(比較例1)
ポリエチレンテレフタレート(グレード:SA-1206、ユニチカ製、ρs=1.34)100重量部に、ポリエステル系エラストマー(グレード:ハイトレル2551、東レ・デュポン製)2重量部を添加して混練した後、0.5mm厚×250mm幅×60m長さのシートに成形した。このシートにオレフィン系不織布のセパレータ(グレード:FT300、日本バイリーン製)を重ねて巻き、ロール状にした。
(Comparative Example 1)
After adding 2 parts by weight of a polyester elastomer (grade: Hytrel 2551, manufactured by Toray DuPont) to 100 parts by weight of polyethylene terephthalate (grade: SA-1206, unitika, ρs = 1.34) The sheet was formed into a sheet of 5 mm thickness × 250 mm width × 60 m length. An olefin-based nonwoven fabric separator (grade: FT300, manufactured by Japan Vilene) was layered on this sheet and wound into a roll.
その後、上記ロールを圧力容器に入れ、炭酸ガスで6MPaに加圧し、樹脂シートに炭酸ガスを浸透させた。浸透時間は72時間とした。浸透完了後、圧力容器からロールを取り出し、セパレータを取り除きながら樹脂シートだけを樹脂の融点以下の温度に設定した熱風炉に供給して発泡させた。こうして得た発泡シートを樹脂のガラス転移点以上に加熱されたロールの間に通し、所定の圧力をかけてシートの表面に凹凸をつけた。 Thereafter, the roll was put into a pressure vessel, pressurized to 6 MPa with carbon dioxide gas, and carbon dioxide gas was infiltrated into the resin sheet. The penetration time was 72 hours. After completion of the infiltration, the roll was taken out from the pressure vessel, and while removing the separator, only the resin sheet was supplied to a hot air oven set at a temperature lower than the melting point of the resin and foamed. The foamed sheet thus obtained was passed between rolls heated above the glass transition point of the resin, and a predetermined pressure was applied to make the surface of the sheet uneven.
(比較例2)
比較例1と同じ組成のシートにエンボスを付与する条件のみを変えて発泡シートを得た。
(Comparative Example 2)
A foamed sheet was obtained by changing only the conditions for embossing the sheet having the same composition as Comparative Example 1.
結果を表1に示す。 The results are shown in Table 1.
表1に示すように、実施例1では、発泡シートの厚さは0.75mm、比重は0.35であった。この発泡シートの凸部を有する表面の算術平均粗さを測定したところRaは7.9、デュロメータA硬度を測定したところ96.8であった。得られた反射シートのホワイトスポット耐性を測定したところ合格レベルであった。 As shown in Table 1, in Example 1, the thickness of the foamed sheet was 0.75 mm, and the specific gravity was 0.35. When the arithmetic average roughness of the surface of the foam sheet having the convex portions was measured, Ra was 7.9, and the durometer A hardness was 96.8. It was a pass level when the white spot tolerance of the obtained reflective sheet was measured.
また、実施例2では、発泡シートの厚さは0.55mm、比重は0.35であった。発泡シートの凸部を有する表面の算術平均粗さを測定したところ6.4、デュロメータA硬度を測定したところ95.8であった。得られた反射シートのホワイトスポット耐性を測定したところ合格レベルであった。 Moreover, in Example 2, the thickness of the foam sheet was 0.55 mm, and the specific gravity was 0.35. The arithmetic average roughness of the surface of the foam sheet having the convex portions was measured to find 6.4, and the durometer A hardness measured to be 95.8. It was a pass level when the white spot tolerance of the obtained reflective sheet was measured.
一方、比較例1では、発泡シートの厚さは0.73mm、比重は0.36であった。この発泡シートの凸部を有する表面の算術平均粗さを測定したところ3.5、デュロメータA硬度を測定したところ92.4であった。算術平均粗さが小さく、また、デュロA硬度が低いため、得られた反射シートのホワイトスポット耐性を測定したところ不合格レベルであった。 On the other hand, in Comparative Example 1, the thickness of the foamed sheet was 0.73 mm, and the specific gravity was 0.36. The arithmetic mean roughness of the surface of the foamed sheet having the convex portions was measured and found to be 3.5, and the durometer A hardness was measured to be 92.4. Since the arithmetic average roughness was small and the duro A hardness was low, the white spot resistance of the obtained reflective sheet was measured and found to be a rejected level.
また、比較例2では、発泡シートの厚さは0.60mm、比重は0.35であった。発泡シートの凸部を有する表面の算術平均粗さを測定したところ5.9、デュロメータA硬度を測定したところ92であった。算術平均粗さが小さく、また、デュロA硬度が低いため、得られた反射シートのホワイトスポット耐性を測定したところ不合格レベルであった。 In Comparative Example 2, the thickness of the foam sheet was 0.60 mm, and the specific gravity was 0.35. The arithmetic average roughness of the surface of the foam sheet having the convex portions was measured and found to be 5.9, and the durometer A hardness was 92. Since the arithmetic average roughness was small and the duro A hardness was low, the white spot resistance of the obtained reflective sheet was measured and found to be a rejected level.
以上、添付図を参照しながら、本発明の実施の形態を説明したが、本発明の技術的範囲は、前述した実施の形態に左右されない。当業者であれば、特許請求の範囲に記載された技術的思想の範疇内において各種の変更例または修正例に想到し得ることは明らかであり、それらについても当然に本発明の技術的範囲に属するものと了解される。 The embodiment of the present invention has been described above with reference to the accompanying drawings, but the technical scope of the present invention is not affected by the above-described embodiment. It is obvious for those skilled in the art that various modifications or modifications can be conceived within the scope of the technical idea described in the claims, and these are naturally within the technical scope of the present invention. It is understood that it belongs.
1………バックライトパネル
3………導光板
5………反射板
7………微細気泡
9………光源
11………凸部
13………反射板基材
15………スキン層
17………溶融部
19………非溶融部
1 ...
Claims (10)
前記反射板の少なくとも一方の面に、複数の凸部が形成され、
前記凸部を有する表面のデュロメータA硬さが95以上100未満であることを特徴とする反射板。 A reflector for a backlight panel made of a thermoplastic resin foam,
A plurality of convex portions are formed on at least one surface of the reflecting plate,
A reflector having a durometer A hardness of 95 to less than 100 on the surface having the convex portion.
熱可塑性樹脂の発泡体からなる反射板基材に不活性ガスを含有させる工程aと、
前記反射板基材にエンボス加工を施す工程bと、
前記反射板基材を加熱して発泡処理を行う工程cと、
を具備することを特徴とする反射板の製造方法。 A method of manufacturing a reflector for a backlight panel,
A step a of incorporating an inert gas into the reflector substrate made of a thermoplastic resin foam;
B) embossing the reflector substrate;
A step c of heating the reflector substrate to perform a foaming treatment;
The manufacturing method of the reflecting plate characterized by comprising.
前記反射板の前面に設けられる導光板と、
前記導光板の側方に設けられる光源と、
を具備し、
前記凸部によって、前記反射板と前記導光板との間に隙間が形成されることを特徴とするバックライトパネル。
The reflector according to any one of claims 1 to 8,
A light guide plate provided in front of the reflector;
A light source provided on a side of the light guide plate;
Comprising
The backlight panel is characterized in that a gap is formed between the reflection plate and the light guide plate by the convex portion.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012800077587A CN103339434A (en) | 2011-12-26 | 2012-12-17 | Reflective plate, preparation method of reflective plate and backlight panel |
| KR1020137020709A KR101506832B1 (en) | 2011-12-26 | 2012-12-17 | Reflector, and backlight panel |
| JP2013524675A JP5416317B2 (en) | 2011-12-26 | 2012-12-17 | Reflector and backlight panel |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-283247 | 2011-12-26 | ||
| JP2011283247 | 2011-12-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2013099671A1 true WO2013099671A1 (en) | 2013-07-04 |
Family
ID=48697163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2012/082630 Ceased WO2013099671A1 (en) | 2011-12-26 | 2012-12-17 | Reflector, method for manufacturing reflector, and backlight panel |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5416317B2 (en) |
| KR (1) | KR101506832B1 (en) |
| CN (1) | CN103339434A (en) |
| TW (1) | TW201333541A (en) |
| WO (1) | WO2013099671A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL2013949B1 (en) * | 2014-12-10 | 2016-10-11 | Buyink Pleunie | Flexible material with the property of a multiple light reflection, and a method for manufacturing it according to a casting process. |
| US9949732B2 (en) | 2005-02-07 | 2018-04-24 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
| US10548590B2 (en) | 2005-02-07 | 2020-02-04 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
| US10932769B2 (en) | 2016-05-26 | 2021-03-02 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108469647A (en) * | 2018-03-03 | 2018-08-31 | 苏州茂立光电科技有限公司 | Light guide plate, backlight module with optical performance protective film and its assemble method |
| CN111045123A (en) * | 2019-12-25 | 2020-04-21 | 合肥乐凯科技产业有限公司 | Reflecting film and composite light guide structure |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006233180A (en) * | 2005-01-28 | 2006-09-07 | Tosoh Corp | Thermoplastic resin composition |
| JP2006249158A (en) * | 2005-03-09 | 2006-09-21 | Furukawa Electric Co Ltd:The | Thermoplastic resin foam |
| WO2008053740A1 (en) * | 2006-10-27 | 2008-05-08 | Toray Industries, Inc. | White polyester film for liquid crystal display reflector |
| JP2009235312A (en) * | 2008-03-28 | 2009-10-15 | Furukawa Electric Co Ltd:The | Thermoplastic resin foam |
| JP2010253696A (en) * | 2009-04-21 | 2010-11-11 | Idemitsu Unitech Co Ltd | Embossed transfer thermoplastic resin sheet, thermoplastic resin embossed sheet, and thermoplastic resin embossed sheet manufacturing method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000066013A (en) * | 1998-08-25 | 2000-03-03 | Dainippon Printing Co Ltd | Light reflecting optical sheet and surface light source device |
| US6906761B2 (en) * | 2001-09-19 | 2005-06-14 | Keiwa Inc. | Reflection sheet and backlight unit using the same |
| CN100543500C (en) * | 2005-04-19 | 2009-09-23 | 积水化成品工业株式会社 | Foamed sheet for reflector, and method for producing foamed sheet for reflector |
-
2012
- 2012-12-17 WO PCT/JP2012/082630 patent/WO2013099671A1/en not_active Ceased
- 2012-12-17 JP JP2013524675A patent/JP5416317B2/en active Active
- 2012-12-17 CN CN2012800077587A patent/CN103339434A/en active Pending
- 2012-12-17 KR KR1020137020709A patent/KR101506832B1/en active Active
- 2012-12-22 TW TW101149303A patent/TW201333541A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006233180A (en) * | 2005-01-28 | 2006-09-07 | Tosoh Corp | Thermoplastic resin composition |
| JP2006249158A (en) * | 2005-03-09 | 2006-09-21 | Furukawa Electric Co Ltd:The | Thermoplastic resin foam |
| WO2008053740A1 (en) * | 2006-10-27 | 2008-05-08 | Toray Industries, Inc. | White polyester film for liquid crystal display reflector |
| JP2009235312A (en) * | 2008-03-28 | 2009-10-15 | Furukawa Electric Co Ltd:The | Thermoplastic resin foam |
| JP2010253696A (en) * | 2009-04-21 | 2010-11-11 | Idemitsu Unitech Co Ltd | Embossed transfer thermoplastic resin sheet, thermoplastic resin embossed sheet, and thermoplastic resin embossed sheet manufacturing method |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9949732B2 (en) | 2005-02-07 | 2018-04-24 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
| US10548590B2 (en) | 2005-02-07 | 2020-02-04 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
| NL2013949B1 (en) * | 2014-12-10 | 2016-10-11 | Buyink Pleunie | Flexible material with the property of a multiple light reflection, and a method for manufacturing it according to a casting process. |
| US10932769B2 (en) | 2016-05-26 | 2021-03-02 | Ivy Sports Medicine, Llc | System and method for all-inside suture fixation for implant attachment and soft tissue repair |
| US11696752B2 (en) | 2016-05-26 | 2023-07-11 | Stryker Corporation | Systems and methods for all-inside suture fixation for implant attachment and soft tissue repair |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5416317B2 (en) | 2014-02-12 |
| JPWO2013099671A1 (en) | 2015-05-07 |
| TW201333541A (en) | 2013-08-16 |
| KR20130111628A (en) | 2013-10-10 |
| CN103339434A (en) | 2013-10-02 |
| KR101506832B1 (en) | 2015-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5416317B2 (en) | Reflector and backlight panel | |
| CN103797386B (en) | Foamed sheet and the light reflecting board and the backlight panel that use this foamed sheet | |
| JP5469290B1 (en) | Edge light type backlight light reflector, liquid crystal display backlight, and manufacturing method of edge light type backlight light reflector | |
| JP6355204B2 (en) | White reflective film for edge light type backlight of liquid crystal display and backlight using the same | |
| KR20080025057A (en) | Foamed resin sheet and liquid crystal display | |
| JP2010026222A (en) | Base sheet for optical sheet | |
| JP5367367B2 (en) | Thermoplastic resin foam | |
| TW201410465A (en) | White polyester film for liquid crystal display | |
| JP2010005829A (en) | Optical sheet and its manufacturing method | |
| JP2004309804A (en) | Light reflector | |
| CN102203640B (en) | Optical sheet and surface light source for liquid crystal display device | |
| JP5503815B1 (en) | Foam sheet | |
| JP5184183B2 (en) | Manufacturing method of light reflector | |
| TW201235709A (en) | Light reflecting body and planar light source device employing same | |
| JP2014237267A (en) | Foam sheet, light reflection plate, back light panel, resin sheet for production of foam sheet and method of producing foam sheet | |
| JP5817165B2 (en) | White laminated polyester film for reflector and backlight device | |
| JP2013133368A (en) | Reflector | |
| JP2012084473A (en) | Reflective base material and backlight unit | |
| TW201518783A (en) | Light reflection plate for edge light-type backlight, backlight source for liquid crystal display, and manufacturing method for light reflection plate for edge light-type backlight | |
| JP2012212000A (en) | Light reflection plate and backlight unit | |
| JP2012155125A (en) | Light reflection plate for liquid crystal backlight and method for manufacturing the same | |
| JP2010249898A (en) | Light diffusion film and surface light source using the same | |
| JP2010117394A (en) | Lens sheet and surface light source for liquid crystal display device | |
| JP2010511188A (en) | Reflector and method of manufacturing reflector | |
| JP2011069988A (en) | Reflection sheet |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ENP | Entry into the national phase |
Ref document number: 2013524675 Country of ref document: JP Kind code of ref document: A |
|
| ENP | Entry into the national phase |
Ref document number: 20137020709 Country of ref document: KR Kind code of ref document: A |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12861112 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 12861112 Country of ref document: EP Kind code of ref document: A1 |