[go: up one dir, main page]

WO2013068384A3 - Emulsions containing polymeric cationic emulsifiers, substance and process - Google Patents

Emulsions containing polymeric cationic emulsifiers, substance and process Download PDF

Info

Publication number
WO2013068384A3
WO2013068384A3 PCT/EP2012/072004 EP2012072004W WO2013068384A3 WO 2013068384 A3 WO2013068384 A3 WO 2013068384A3 EP 2012072004 W EP2012072004 W EP 2012072004W WO 2013068384 A3 WO2013068384 A3 WO 2013068384A3
Authority
WO
WIPO (PCT)
Prior art keywords
substance
containing polymeric
emulsions containing
polymeric cationic
cationic emulsifiers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/072004
Other languages
French (fr)
Other versions
WO2013068384A2 (en
Inventor
Rainer Dobrawa
Dieter Boeckh
Aaron FLORES-FIGUEROA
Markus Brym
Rajan K. Panandiker
Frank Huelskoetter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to CN201280055087.1A priority Critical patent/CN103930194B/en
Priority to RU2014123613/04A priority patent/RU2014123613A/en
Priority to IN3626CHN2014 priority patent/IN2014CN03626A/en
Priority to EP12783986.8A priority patent/EP2776149A2/en
Priority to BR112014010971A priority patent/BR112014010971A2/en
Priority to CA2850271A priority patent/CA2850271A1/en
Priority to KR1020147015673A priority patent/KR20140093264A/en
Priority to MX2014004773A priority patent/MX2014004773A/en
Priority to JP2014540430A priority patent/JP2015507520A/en
Publication of WO2013068384A2 publication Critical patent/WO2013068384A2/en
Publication of WO2013068384A3 publication Critical patent/WO2013068384A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
    • C08F226/04—Diallylamine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/16—Amines or polyamines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/34—Higher-molecular-weight carboxylic acid esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/10—General cosmetic use
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Colloid Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Medicinal Preparation (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The present invention is directed to stable emulsions comprising oils and a polymeric cationic emulsifier, the process to obtain said emulsions and the use of said emulsions.
PCT/EP2012/072004 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process Ceased WO2013068384A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CN201280055087.1A CN103930194B (en) 2011-11-11 2012-11-07 Emulsions, materials and methods comprising polymeric cationic emulsifiers
RU2014123613/04A RU2014123613A (en) 2011-11-11 2012-11-07 EMULSIONS CONTAINING POLYMERIC CATION EMULSANERS, SUBSTANCES AND METHOD FOR PRODUCING THEM
IN3626CHN2014 IN2014CN03626A (en) 2011-11-11 2012-11-07
EP12783986.8A EP2776149A2 (en) 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process
BR112014010971A BR112014010971A2 (en) 2011-11-11 2012-11-07 emulsion, process for making an emulsion, use of an emulsion, and polymer
CA2850271A CA2850271A1 (en) 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process
KR1020147015673A KR20140093264A (en) 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process
MX2014004773A MX2014004773A (en) 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process.
JP2014540430A JP2015507520A (en) 2011-11-11 2012-11-07 Emulsions, materials and methods containing polymeric cationic emulsifiers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11188779 2011-11-11
EP11188779.0 2011-11-11

Publications (2)

Publication Number Publication Date
WO2013068384A2 WO2013068384A2 (en) 2013-05-16
WO2013068384A3 true WO2013068384A3 (en) 2013-07-18

Family

ID=47148801

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/072004 Ceased WO2013068384A2 (en) 2011-11-11 2012-11-07 Emulsions containing polymeric cationic emulsifiers, substance and process

Country Status (10)

Country Link
EP (1) EP2776149A2 (en)
JP (1) JP2015507520A (en)
KR (1) KR20140093264A (en)
CN (1) CN103930194B (en)
BR (1) BR112014010971A2 (en)
CA (1) CA2850271A1 (en)
IN (1) IN2014CN03626A (en)
MX (1) MX2014004773A (en)
RU (1) RU2014123613A (en)
WO (1) WO2013068384A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130118531A1 (en) * 2011-11-11 2013-05-16 The Procter & Gamble Company Emulsions containing polymeric cationic emulsifiers, substance and process
EP3337831B1 (en) 2015-08-21 2024-02-28 G&P Holding, Inc. Silver and copper itaconates and poly itaconates
KR20200123115A (en) * 2018-02-20 2020-10-28 바스프 에스이 Wood fiber board manufacturing method
CN113121744B (en) * 2021-04-02 2023-04-07 浙江凯色丽科技发展有限公司 Rapid crosslinking and curing water-based polyacrylate and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2923701A (en) * 1955-05-02 1960-02-02 American Cyanamid Co Composition comprising a linear copolymer of a quaternary ammonium compound and an ethylenically unsaturated copolymerizable compound
US5686024A (en) * 1995-12-18 1997-11-11 Rhone-Poulenc Surfactants & Specialties, L.P. Aqueous dispersion of a surface active polymer having enhanced performance properties
WO2007014915A1 (en) * 2005-08-04 2007-02-08 Basf Se Aqueous dispersions and their use
WO2011141496A1 (en) * 2010-05-12 2011-11-17 Basf Se Emulsions of polyisobutenes, substance and process

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5486303A (en) 1993-08-27 1996-01-23 The Procter & Gamble Company Process for making high density detergent agglomerates using an anhydrous powder additive
US5879584A (en) 1994-09-10 1999-03-09 The Procter & Gamble Company Process for manufacturing aqueous compositions comprising peracids
US5516448A (en) 1994-09-20 1996-05-14 The Procter & Gamble Company Process for making a high density detergent composition which includes selected recycle streams for improved agglomerate
US5489392A (en) 1994-09-20 1996-02-06 The Procter & Gamble Company Process for making a high density detergent composition in a single mixer/densifier with selected recycle streams for improved agglomerate properties
US5691297A (en) 1994-09-20 1997-11-25 The Procter & Gamble Company Process for making a high density detergent composition by controlling agglomeration within a dispersion index
DE19505100A1 (en) 1995-02-15 1996-08-22 Basf Ag Alk (en) yldicarboxylic acid bisesters, their use and processes for their preparation
US5574005A (en) 1995-03-07 1996-11-12 The Procter & Gamble Company Process for producing detergent agglomerates from high active surfactant pastes having non-linear viscoelastic properties
US5569645A (en) 1995-04-24 1996-10-29 The Procter & Gamble Company Low dosage detergent composition containing optimum proportions of agglomerates and spray dried granules for improved flow properties
DE19520078A1 (en) 1995-06-07 1996-12-12 Basf Ag Process for the production of low molecular weight, highly reactive polyisobutene
US5565422A (en) 1995-06-23 1996-10-15 The Procter & Gamble Company Process for preparing a free-flowing particulate detergent composition having improved solubility
AU5355599A (en) 1998-10-22 2000-05-04 Rohm And Haas Company Polymer compositions and a method of promoting soil release from fabrics using said polymer compositions
DE10035298A1 (en) 2000-07-18 2002-01-31 Basf Ag Highly reactive polyisobutene production involves polymerization of isobutene with boron trifluoride catalyst, using solid amine-type deactivator which is insoluble in reaction mixture
FR2833186B1 (en) * 2001-12-12 2004-01-23 Rhodia Chimie Sa USE OF CATIONIC BLOCK COPOLYMERS AS AID FOR DEPOSITION OF SINGLE OR MULTIPLE EMULSIONS
JP4890027B2 (en) * 2002-12-23 2012-03-07 チバ ホールディング インコーポレーテッド Hydrophobically modified polymers as laundry additives
DE602005026165D1 (en) * 2004-12-07 2011-03-10 Basf Se HYDROPHOBIC MODIFIED CATIONIC POLYMERS AND THEIR USE AS CLEANING AIDS
CN101233187A (en) * 2005-08-04 2008-07-30 巴斯福股份公司 Aqueous dispersions and their use
DE102005049327A1 (en) 2005-10-12 2007-04-19 Basf Ag Process for the preparation of aqueous emulsions and dispersions
CN101365493A (en) * 2005-11-24 2009-02-11 巴斯夫欧洲公司 Keratin-binding effector molecules, and method for the production thereof
JP4944756B2 (en) * 2006-12-28 2012-06-06 花王株式会社 Textile treatment agent
US20130118531A1 (en) * 2011-11-11 2013-05-16 The Procter & Gamble Company Emulsions containing polymeric cationic emulsifiers, substance and process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2923701A (en) * 1955-05-02 1960-02-02 American Cyanamid Co Composition comprising a linear copolymer of a quaternary ammonium compound and an ethylenically unsaturated copolymerizable compound
US5686024A (en) * 1995-12-18 1997-11-11 Rhone-Poulenc Surfactants & Specialties, L.P. Aqueous dispersion of a surface active polymer having enhanced performance properties
WO2007014915A1 (en) * 2005-08-04 2007-02-08 Basf Se Aqueous dispersions and their use
WO2011141496A1 (en) * 2010-05-12 2011-11-17 Basf Se Emulsions of polyisobutenes, substance and process

Also Published As

Publication number Publication date
BR112014010971A2 (en) 2017-06-06
CA2850271A1 (en) 2013-05-16
JP2015507520A (en) 2015-03-12
RU2014123613A (en) 2015-12-20
IN2014CN03626A (en) 2015-07-03
CN103930194B (en) 2016-06-22
MX2014004773A (en) 2014-05-27
KR20140093264A (en) 2014-07-25
WO2013068384A2 (en) 2013-05-16
EP2776149A2 (en) 2014-09-17
CN103930194A (en) 2014-07-16

Similar Documents

Publication Publication Date Title
BR112015001577A2 (en) emulsifying agent, food product, method for the manufacture of a food product and emulsifying and stabilizing agent.
MX2014005559A (en) Emulsions containing polymeric cationic emulsifiers, substance and process.
WO2014023640A3 (en) Cosmetic compositions
HK1212701A1 (en) Formulations of enzalutamide
PT2925788T (en) PROCESSES AND APPARATUS FOR THE PRODUCTION OF NANOCELLULOSE, COMPOSITIONS AND PRODUCTS PRODUCED FROM ME
MX348899B (en) Consumer product compositions comprising organopolysiloxane emulsions.
WO2012109678A3 (en) Fluid delivery system
WO2013046060A9 (en) Paper and methods of making paper
BR112015000534A2 (en) Method for the preparation of 2,4-dihydroxybutyrate, microorganism, organism and use
BR112013030517A2 (en) cardboard or paper wrapping, process for producing wrapping, and use of a polymeric aqueous dispersion.
WO2013034979A3 (en) Crystalline forms of cabazitaxel
GB201511405D0 (en) Treatment of crude oil,sludges and emulsions
EA201491689A1 (en) SPRAYED COMPOSITION FOR LOCAL APPLICATION AND SYSTEM FOR ITS DELIVERY
BR112013030513A2 (en) cardboard or paper wrapping, process for producing wrapping, and use of a polymeric aqueous dispersion.
IN2014KN02990A (en)
WO2014091167A3 (en) Cyclopropylboronic compounds, method for preparing same and use thereof
WO2014048776A3 (en) Water-emulsible isocyanates having improved gloss
WO2012167906A3 (en) Cosmetic or dermatological preparations with improved rheological properties
WO2013068384A3 (en) Emulsions containing polymeric cationic emulsifiers, substance and process
BR112015006533A2 (en) method for the manufacture of a polymer product having super or extremely hydrophobic characteristics, a product obtainable from said method and its use
EP2692333A4 (en) Water-in-oil emulsified cosmetic
EP3213741A4 (en) Oil-in-water emulsified sunblock cosmetic
WO2012125468A3 (en) Enhanced seed treatments using oils
EP2682184A3 (en) Catalyst, method for the preparation of the catalyst, use of the catalyst
WO2014100636A3 (en) Methods of treating atherosclerosis or myeloproliferative neoplasms by administering a lyn kinase activator

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12783986

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2850271

Country of ref document: CA

REEP Request for entry into the european phase

Ref document number: 2012783986

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2012783986

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: MX/A/2014/004773

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 2014540430

Country of ref document: JP

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 20147015673

Country of ref document: KR

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2014123613

Country of ref document: RU

Kind code of ref document: A

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112014010971

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112014010971

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20140507