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WO2013064403A1 - Agent de nettoyage pour le corps renfermant des systèmes exempts de tensioactifs - Google Patents

Agent de nettoyage pour le corps renfermant des systèmes exempts de tensioactifs Download PDF

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Publication number
WO2013064403A1
WO2013064403A1 PCT/EP2012/071042 EP2012071042W WO2013064403A1 WO 2013064403 A1 WO2013064403 A1 WO 2013064403A1 EP 2012071042 W EP2012071042 W EP 2012071042W WO 2013064403 A1 WO2013064403 A1 WO 2013064403A1
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WIPO (PCT)
Prior art keywords
weight
cleaning agent
agent according
cosmetic
total weight
Prior art date
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German (de)
English (en)
Inventor
Kirsten Sartingen
Barbara Heide
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication of WO2013064403A1 publication Critical patent/WO2013064403A1/fr
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the invention is in the field of cosmetics and relates to mild detergents containing a special surfactant mixture.
  • Cosmetic cleaners such as hair shampoos, shower baths or bath preparations, are based on conventional anionic, amphoteric, zwitterionic, nonionic and / or cationic surfactants.
  • Typical anionic surfactants used in a variety of commercially available shampoos are alkyl sulfates or alkyl ether sulfates.
  • Surfactants soften the skin during the cleaning process and remove lipids from the outer skin layers. As a result, the skin can become dry, brittle and sometimes cracked, especially after frequent cleaning with commercially available cleaning agents, unless they are returned to lipids in the form of creams, lotions and / or care baths after or during cleaning.
  • mild anionic surfactants such as alkyl ether sulfates
  • mild amphoteric and / or mild nonionic surfactants have been combined with mild amphoteric and / or mild nonionic surfactants, and innumerable detergents containing high levels of conditioning and / or restreasing agents have been developed.
  • the present invention therefore an object of the invention to produce mild cosmetic cleanser with good foam properties.
  • the cleaning agents should be stable, have a rich texture and be thickened as possible without the compelling addition of polymeric compounds.
  • the invention relates to a cosmetic cleanser which is in a cosmetic
  • R- (OCH 2 -CH 2 ) x -O-SO 3 " X + in which R is a linear or branched, saturated or unsaturated alkyl group having 8 to 30 C atoms, x is one of the numbers 0 or 1 to and X + an alkali metal or an ammonium ion, and
  • a suitable cosmetic carrier is preferably understood as meaning an aqueous or aqueous-alcoholic carrier.
  • the cosmetic carrier contains at least 50 wt .-%, more preferably at least 60 wt .-% and particularly preferably at least 70 wt .-% water.
  • the cosmetic carrier may contain 0.01 to 40% by weight, preferably 0.05 to 35% by weight and in particular 0.1 to 30% by weight of at least one alcohol which may be selected from ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, diglycerol, triglycerol, 1-butanol, 2-butanol, 1, 2-butanediol, 1, 3-butanediol, 1-pentanol, 2-pentanol, 1, 2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.
  • at least one alcohol which may be selected from ethanol, eth
  • ethanol ethyl diglycol
  • 1-propanol 2-propanol
  • isopropanol 1, 2-propylene glycol
  • glycerol benzyl alcohol and / or phenoxyethanol and mixtures of these alcohols.
  • cleaners according to the invention contain only small amounts of the surfactants (a) and (b) in a specific weight ratio of from 1.5: 1 to 1: 1.2.
  • the cleaning agents according to the invention form a particularly fine and creamy foam when the weight ratio of the surfactants (a) :( b) preferably 1.45: 1 to
  • the total surfactant content in the detergents according to the invention is at most 12% by weight, preferably at most 11% by weight and in particular at most 10% by weight, the quantities given being based on the total weight of the cosmetic cleanser.
  • alkyl sulfate and / or alkylpolyglycol ether sulfate salts (a) which can be used in the cleaning agents according to the invention are straight-chain or branched alkyl ether sulfates which have an alkyl radical having 8 to 18 and in particular 10 to 16 carbon atoms owing to their very good foaming properties and mildness , and 1 to 6 and in particular 2 to 4 ethylene oxide units.
  • the alkyl sulfate and / or alkyl polyglycol ether sulfate salt (s) (a) of the abovementioned formula is (are) preferably used in the cleaning agents according to the invention in amounts of from 2 to 6% by weight, more preferably from 3 to 6% by weight, particularly preferably from 4 to 6% by weight and in particular from 5 to 6% by weight, the quantities given being based on the total weight of the cleaning agent.
  • Suitable amphoteric and / or zwitterionic surfactants (b) of the formula (I) are (are) in the cleaning agents according to the invention preferably in amounts of from 1 to 5 wt .-%, more preferably from 2 to 5 wt .-%, particularly preferably from 3 used to 5 wt .-% and in particular from 3.5 to 4.5 wt .-%, wherein the amounts are based on the total weight of the cleaning agent.
  • Preferred amphoteric and / or zwitterionic surfactants of the abovementioned formula (I) contain, as radical R, predominantly a straight-chain or branched, saturated, mono- or polyunsaturated alkyl radical having 8 to 20, more preferably 8 to 16 and in particular 8 to 12 ° C - atoms.
  • amphoteric and / or zwitterionic surfactants of the aforementioned formula (I), in which the radical R is derived from coconut oil.
  • amphoteric surfactant known by the INCI name cocamidopropyl betaine and commercially available from several suppliers.
  • cosmetic cleansing compositions according to the invention contain, based on their total weight,
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • weight ratio of the surfactants (a): (b) is 1, 4: 1 to 1, 2: 1.
  • the cleaners according to the invention - based on their total weight - preferably 0.01 to 5 wt .-%, more preferably 0.05 to 4 wt .-%, particularly preferably 0 , 1 to 3 wt .-% and in particular 0.2 to 2 wt .-% of at least one opacifier and / or pearlescing agent (c).
  • Suitable pearlescing agents and opacifiers are - mono- and / or diesters of ethylene glycol, 1, 2-propanediol and / or glycerol with C 8 - C 2 4 fatty acids,
  • Glycol Distearate such as the commercial product Cutina ® AGS Cognis, glycol monostearates, such as the commercial product Cutina ® EGMS from Cognis, PEG-3 Distearate, such as the commercial product Genapol ® TS Clariant, PEG-2 distearate, such as for example the commercial product Kessco ® DEGMS Akzo Nobel, propylene glycol stearates, such as for example the commercial product Tegin ® P Goldschmidt and / or styrene / acrylate copolymers, such as for example the commercial products Joncryl ® 67 from Johnson Polymers, Suprawal ® WS company BASF and / or Acusol ® OP 301 from Rohm & Haas.
  • glycol monostearates such as the commercial product Cutina ® EGMS from Cognis
  • PEG-3 Distearate such as the commercial product Genapol ® TS Clariant
  • Glycol distearate, glycol monostearate, PEG-3 distearate and / or styrene / acrylate copolymer are examples of polystyrene / acrylate copolymer.
  • cosmetic cleansing agents according to the invention contain, based on their total weight,
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • weight ratio of the surfactants (a): (b) is 1, 4: 1 to 1, 2: 1.
  • Suitable cationic polymers (d) are, for example:
  • quaternized cellulose derivatives such as are available under the names of Celquat ® and Polymer JR ® commercially
  • hydrophobically modified cellulose derivatives for example those sold under the trade name SOFTCAT ® cationic polymers,
  • honey for example the commercial product Honeyquat ® 50,
  • cationic guar derivatives such as those under the trade names Cosmedia ® guar
  • polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid Under the names Merquat ® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers, Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are available under the Be drawings Gafquat ® 734 and Gafquat ® 755 commercially
  • Vinylpyrrolidone vinylimidazoliummethochloride copolymers such as those offered under the names Luviquat.RTM ® FC 370, FC 550, FC 905 and HM 552,
  • Polyquaternium 2 Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.
  • Preferred cationic polymers are quaternized cellulosic polymers, cationic guar derivatives and / or acrylic acid (derivative) based cationic polymers, which are more preferably selected from the polymers Guar Hydroxypropyltnmonium Chloride, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10 known under the INCI names , Polyquaternium-37 and / or Polyquaternium-67.
  • Particularly preferred for use in the cleaning agents according to the invention is a cationic polymer known under the INCI name Polyquaternium-7.
  • cosmetic cleansing compositions according to the invention contain, based on their total weight,
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • weight ratio of the surfactants (a): (b) is 1, 4: 1 to 1, 2: 1.
  • the detergents of the invention may also contain a number of other active ingredients which impart advantageous properties to them.
  • the preferred optional active substances that can be used in the cleaning agents according to the invention include, for example
  • nonionic surfactants and / or nonionic emulsifiers in the detergents according to the invention - based on their total weight - preferably in an amount of 0.01 to 3 wt .-%, more preferably from 0.05 to 2 wt .-% and in particular from 0 , 1 to 1, 5 wt .-% can be used, as well as
  • active ingredients which have a positive influence on the skin moisture and which, in the cleansing compositions according to the invention - based on their total weight - preferably in an amount of 0.001 to 10 wt .-%, more preferably from 0.005 to 7.5 wt .-%, particularly preferably from 0.01 to 5 wt .-% and in particular from 0.02 to 4 wt .-% can be used.
  • nonionic surfactants / emulsifiers examples include
  • alkyl oligoglucosides are alkyl oligoglucosides, in particular alkyl oligoglucosides based on hydrogenated C 12/14 coconut alcohol with a DP of 1-3, as are commercially available, for example, under the INCI name "Coco-Glucoside”.
  • nonionic surfactants / emulsifiers are adducts of 5 to 60 moles of ethylene oxide with castor oil and / or hydrogenated castor oil, such as the known under the INCI names emulsifiers PEG-40 Hydrogenated Castor Oil and / or PEG-60 Hydrogenated Castor Oil.
  • Suitable active ingredients which have a positive influence on the skin moisture are preferably understood as meaning at least one active ingredient selected from the following group:
  • freeze-dried yoghurt powder is meant yoghurt powder which can be obtained from natural yoghurt (after complete fermentation) by freeze-drying.
  • Particularly suitable yoghurt powder which can be used in the cleaning agents according to the invention preferably contains the following main constituents:
  • Freeze-dried yoghurt powder can be present in the cleansing compositions according to the invention, preferably in an amount of from 0.001 to 10% by weight, more preferably from 0.005 to 5% by weight and in particular from 0.01 to 3% by weight, based on their total weight. be used.
  • a known commercially under the name "Yogurtene ®" freeze-dried yogurt powder is suitable.
  • Glycerin can be added separately to the cleaning agents according to the invention in an amount of up to 10% by weight (based on the total weight of the cleaning agent). It may also be part of the aqueous-alcoholic carrier.
  • Suitable vitamins are preferably the following vitamins, provitamins and vitamin precursors and their derivatives:
  • Vitamin A the group of substances called vitamin A includes retinol (vitamin A-1) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A component for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration.
  • Vitamin B belong to the vitamin B group or to the vitamin B complex among others
  • Vitamin B 3 • Vitamin B 3 .
  • the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
  • Vitamin B 5 pantothenic acid and panthenol.
  • panthenol is preferred.
  • Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
  • Vitamin B 6 pyridoxine and pyridoxamine and pyridoxal
  • Vitamin C ascorbic acid: use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, especially a-tocopherol.
  • Vitamin F is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.
  • the cleaning agents according to the invention may preferably contain vitamins, provitamins and vitamin precursors from groups A, B, E and H.
  • nicotinic acid amide particularly preferred are nicotinic acid amide, biotin, pantolactone and / or panthenol.
  • Vitamins, vitamin derivatives and / or vitamin precursors may be present in the cleansing compositions according to the invention (based on their total weight) preferably in an amount of 0.001 to 2 Wt .-%, particularly preferably from 0.005 to 1 wt .-% and in particular from 0.01 to 0.5 wt .-% are used.
  • Particularly preferred abovementioned glycerol esters may be selected from 2 to 30-fold, preferably from 3 to 20-fold and in particular from 5 to 10-fold ethoxylated mono, di- and / or tri-fatty acid esters of saturated and / or unsaturated linear and / or or branched C 8 -C 2 4- fatty acids, preferably C 0 -C 8 fatty acids with glycerol (for example, under the INCI names PEG-10 Olivenfettklastedreglyceride, PEG-9 Kokosfettklastedreglyceride, Glycereth-5 Cocoate, PEG-7 Glyceryl Cocoate , PEG-6 Caprylic / Capric Glyceride known components). Very particular preference is given to PEG-7 glyceryl cocoate.
  • the abovementioned (optionally ethoxylated) mono-, di- and / or triesters of glycerol with at least one C 8 -C 2 -4-fatty acid may preferably be present in the cleaning agents according to the invention in amounts of from 0.01 to 5% by weight, more preferably from 0.025 to 4 wt .-%, particularly preferably from 0.05 to 3 wt .-% and in particular from 0, 1 to 2 wt .-% are used, wherein the amounts are based on the total weight of the detergents.
  • cosmetic cleansing compositions according to the invention contain, based on their total weight,
  • weight ratio of the surfactants (a): (b) is 1, 45: 1 to 1: 1.
  • At least one skin moisture-influencing active ingredient selected from glycerol, freeze-dried yoghurt powder, panthenol, nicotinamide and / or ethoxylated glyceryl monococoate (5-25 EO),
  • weight ratio of the surfactants (a): (b) is 1, 4: 1 to 1, 2: 1.
  • Cosmetic cleaners preferred according to the invention preferably have a viscosity in the range from 5.000 to 15,000 mPas, preferably from 6,000 to 13,000 mPas and in particular from 7,500 to 10,500 mPas (each measured with a Haake VT550 rotational viscometer, 20 ° C, MV measuring device, MV II spindle, 8 rpm).
  • compositions of this viscosity can be conveniently and easily applied from a container to the hand or application surface without passing between the fingers and dripping. At the same time, the viscosity of the composition is low enough to ensure a satisfactory distribution on the surface of the application with the assistance of the hands.
  • Cosmetic detergents preferred according to the invention preferably have a pH in a skin-friendly range of from 4 to 6, preferably from 4 to 5.5 and in particular from 4.5 to 5.0.
  • the cosmetic cleansing compositions according to the invention may also contain a number of other active ingredients which give them advantageous properties.
  • the preferred optional active substances that can be used in the cleansing compositions according to the invention include, for example, oil, wax and / or fat components which are present in the cosmetic cleaners (based on their total weight) preferably in an amount of 0.01-20 wt. -%, particularly preferably from 0.05 to 15 wt.% And in particular from 0, 1 to 10 wt.% Can be used.
  • Suitable oil and / or fat components may preferably be selected from mineral, natural and synthetic oil components and / or fatty substances.
  • natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used.
  • Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, grapeseed oil, Amaranth seed oil, argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and shea butter.
  • mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons.
  • An example of a usable hydrocarbon is for example that available as a commercial product 1, 3-di- (2-ethylhexyl) - cyclohexane (Cetiol ® S).
  • oil component may further serve a dialkyl ether.
  • dialkyl ethers are, in particular, di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular from 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether and di -tert.- butyl ether, di-iso-pentyl ether, di-3-ethyldecyl ether, tert-butyl n-
  • di-n-octyl ether which is commercially available under the name Cetiol ® OE.
  • Suitable synthetic oils are silicone compounds.
  • Silicones have excellent conditioning properties on the hair. In particular, they cause better combability of the hair in the wet and dry state and in many cases have a positive effect on the hair and the softness of the hair.
  • Suitable silicones may be selected from:
  • polyalkyl siloxanes polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;
  • grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;
  • Fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes which may be in solid form as well as liquid in aqueous dispersion.
  • the fatty acids used can be linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ® 871 and Emersol ® 875, and isopalmitic acids such as the commercial product Edenor ® IP 95, and all other products sold under the trade names Edenor ® (Cognis) fatty acids.
  • fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic as well as their technical mixtures.
  • fatty acid cuttings obtainable from coconut oil or palm oil;
  • stearic acid is usually preferred.
  • Fatty alcohols which may be used are saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C 6 - C 30 -, preferably C 0 - C 2 2-, and most preferably C-I2 - C 2 2- carbon atoms.
  • the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction.
  • those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols.
  • Such substances are, for example, under the names Stenol ® such as Stenol ® 1618 or Lanette ® such as Lanette ® O or Lorol ®, for example, Lorol ® C8, Lorol C14 ®, Lorol C18 ®, ® Lorol C8-18, HD-Ocenol ®, Crodacol ® such as Crodacol ® CS, Novol ®, Eutanol ® G, Guerbitol ® 16, Guerbitol ® 18, Guerbitol ® 20, Isofol ® 12, Isofol ® 16, lsofol ® 24, Isofol ® 36, Isocarb ® 12, Isocarb ® 16 or acquire Isocarb® ® 24 for sale.
  • Stenol ® such as Stenol ® 1618 or Lanette ® such as Lanette ® O or Lorol ®
  • Lorol ® C8 Lorol C8-18
  • wool wax alcohols as are commercially available, for example under the names of Corona ®, White Swan ®, Coronet ® or Fluilan ® can be used according to the invention.
  • natural or synthetic waxes there may be used solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP.
  • Such waxes are available, for example, from Kahl & Co., Trittau.
  • Other fatty substances are, for example
  • Ester oils are to be understood as meaning the esters of C 6 - C 30 fatty acids with C 2 - C 30 fatty alcohols.
  • the monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • Examples of fatty acid components used in the esters are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic Behenic acid and erucic acid and their technical mixtures.
  • fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol , Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures.
  • isopropyl myristate IPM Rilanit ®
  • isononanoic acid C16-18 alkyl ester Cetiol ® SN
  • 2-ethylhexyl palmitate Cegesoft ® 24
  • stearic acid-2-ethylhexyl ester Cetiol ® 868
  • cetyl oleate glycerol tricaprylate
  • Kokosfettalkohol- caprinatV caprylate (Cetiol ® LC)
  • n-butyl stearate oleyl erucate
  • isopropyl palmitate IPP Rilanit ®
  • oleyl Oleate Cetiol ®
  • hexyl laurate Cetiol ® A
  • di-n-butyl adipate Cetiol ® B
  • myristyl myristate IPM Rilanit ®
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate
  • diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol diisostearate,
  • ethoxylated or non ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol such as Monomuls 90-018 ®, ® Monomuls 90-L12, Cetiol ® HE or Cutina ® MD.
  • Thickening agents such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such.
  • polyvinyl alcohol the Ca, Mg or Zn - soaps, Structurants such as maleic acid and lactic acid,
  • Substances for adjusting the pH for example ⁇ - and ⁇ -hydroxycarboxylic acids such as citric acid, lactic acid, malic acid, glycolic acid,
  • Active ingredients such as bisabolol,
  • Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogs of such lipids (so-called pseudo-ceramides),
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, C0 2 and air,
  • Opacifiers such as those known under the INCI name Styrene / Acrylates copolymer compounds
  • Viscosity regulators such as electrolyte salts (NaCl).
  • the cleaning agents of the invention have excellent properties in the application to the skin.
  • the cosmetic detergents according to the invention despite their low total surfactant content, can be thickened with NaCl, so that the use of additional (polymeric) thickening systems can be dispensed with.
  • the following table contains five examples of cleaning agents according to the invention (shower gel compositions).

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un agent de nettoyage cosmétique comprenant, dans un support cosmétique, (a) entre 1 et 6 % en poids d'au moins un akyl(éther)sulfate de formule générale R-(OCH2-CH2)x-O-SO3 -X+ dans laquelle R représente un groupe alkyle linéaire ou ramifié, saturé ou insaturé comportant entre 8 et 30 atomes C, x désigne le chiffre 0 ou un nombre compris entre 1 et 12 et X+ représente un métal alcalin ou un ion ammonium et (b) entre 0,5 et 5 % d'au moins un tensioactif amphotère de formule générale (I) dans laquelle R désigne un groupe alkyle ou alcényle à chaîne linéaire ou ramifié, saturé ou mono-insaturé ou pluri-insaturé comportant entre 8 et 24 atomes de carbone. Le rapport du poids des tensioactifs (a) : (b) est compris entre 1,5 : 1 et 1 : 1,2, les quantités indiquées se rapportant au poids total de l'agent de nettoyage.
PCT/EP2012/071042 2011-11-02 2012-10-24 Agent de nettoyage pour le corps renfermant des systèmes exempts de tensioactifs Ceased WO2013064403A1 (fr)

Applications Claiming Priority (2)

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DE102011085610.2 2011-11-02
DE201110085610 DE102011085610A1 (de) 2011-11-02 2011-11-02 Körperreinigung mit tensidarmen Systemen

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015189049A1 (fr) * 2014-06-12 2015-12-17 Henkel Ag & Co. Kgaa Utilisation d'une composition de nettoyage cosmétique comme probiotique

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102015201862A1 (de) 2015-02-03 2016-08-04 Henkel Ag & Co. Kgaa Körperreinigungs- und Pflegemittel
US12059485B2 (en) 2018-06-21 2024-08-13 Conopco, Inc. Personal cleansing compositions comprising a surfactant system consisting of an alkyl ether sulfate and betaine

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0417501A1 (fr) * 1989-09-14 1991-03-20 Joh. A. Benckiser GmbH Composition gel de douche et shampooing pour cheveur extra douche à basse concentration de tensides
WO1995015150A2 (fr) * 1993-11-24 1995-06-08 The Procter & Gamble Company Composition nettoyante moussante ultra-douce pour la peau
EP0834307A2 (fr) * 1996-10-04 1998-04-08 Unilever Plc Compositions liquides comprenant des tensioactifs chélatants dérivés d'edta
US5908617A (en) * 1994-08-24 1999-06-01 The Procter & Gamble Company Mild shower gel composition comprising unique thickener system which imparts improved lathering properties and modified rinse feel
US5985809A (en) * 1995-05-27 1999-11-16 The Procter & Gamble Company Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester
WO2002062936A1 (fr) * 2001-02-06 2002-08-15 Playtex Products, Inc. Composition moussante de nettoyeur doux
US20020177535A1 (en) * 2001-02-06 2002-11-28 Playtex Products, Inc. Cleansing compositions with milk protein and aromatherapy
US20040022818A1 (en) * 2002-07-31 2004-02-05 Cho Suk H. Skin care compositions
GB2455404A (en) * 2007-12-06 2009-06-10 Pz Cussons Mild cleansing composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0417501A1 (fr) * 1989-09-14 1991-03-20 Joh. A. Benckiser GmbH Composition gel de douche et shampooing pour cheveur extra douche à basse concentration de tensides
WO1995015150A2 (fr) * 1993-11-24 1995-06-08 The Procter & Gamble Company Composition nettoyante moussante ultra-douce pour la peau
US5908617A (en) * 1994-08-24 1999-06-01 The Procter & Gamble Company Mild shower gel composition comprising unique thickener system which imparts improved lathering properties and modified rinse feel
US5985809A (en) * 1995-05-27 1999-11-16 The Procter & Gamble Company Aqueous personal cleansing compositions comprising specific nonocclusive liquid polyol fatty acid polyester
EP0834307A2 (fr) * 1996-10-04 1998-04-08 Unilever Plc Compositions liquides comprenant des tensioactifs chélatants dérivés d'edta
WO2002062936A1 (fr) * 2001-02-06 2002-08-15 Playtex Products, Inc. Composition moussante de nettoyeur doux
US20020177535A1 (en) * 2001-02-06 2002-11-28 Playtex Products, Inc. Cleansing compositions with milk protein and aromatherapy
US20040022818A1 (en) * 2002-07-31 2004-02-05 Cho Suk H. Skin care compositions
GB2455404A (en) * 2007-12-06 2009-06-10 Pz Cussons Mild cleansing composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015189049A1 (fr) * 2014-06-12 2015-12-17 Henkel Ag & Co. Kgaa Utilisation d'une composition de nettoyage cosmétique comme probiotique
US10085934B2 (en) 2014-06-12 2018-10-02 Henkel Ag & Co. Kgaa Use of cosmetic cleaning compositions as a prebiotic

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