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WO2013042197A1 - Waste water treatment equipment in flue gas desulfurization facility - Google Patents

Waste water treatment equipment in flue gas desulfurization facility Download PDF

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Publication number
WO2013042197A1
WO2013042197A1 PCT/JP2011/071367 JP2011071367W WO2013042197A1 WO 2013042197 A1 WO2013042197 A1 WO 2013042197A1 JP 2011071367 W JP2011071367 W JP 2011071367W WO 2013042197 A1 WO2013042197 A1 WO 2013042197A1
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WIPO (PCT)
Prior art keywords
seawater
weir
flow
flue gas
channel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2011/071367
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French (fr)
Japanese (ja)
Inventor
憲道 松本
昭浩 本間
昭雄 吉越
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tsukishima Kikai Co Ltd
Original Assignee
Tsukishima Kikai Co Ltd
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Priority to MYPI2014700577A priority Critical patent/MY192539A/en
Priority to PCT/JP2011/071367 priority patent/WO2013042197A1/en
Publication of WO2013042197A1 publication Critical patent/WO2013042197A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/507Sulfur oxides by treating the gases with other liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2252/00Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10Inorganic absorbents
    • B01D2252/103Water
    • B01D2252/1035Sea water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/12Prevention of foaming

Definitions

  • the present invention relates to a facility for efficiently collecting and treating bubbles and scum floating on seawater generated in a flue gas desulfurization facility for exhaust gas discharged from a coal-fired thermal power plant or the like.
  • the SO 2 in the flue gases discharged from the thermal power plant such as those generated upon absorption seawater method flue gas desulfurization, as it can be applied to waste water treatment of the absorbent that has absorbed SO 2 is there.
  • Seawater method flue gas desulfurization equipment is known as equipment that absorbs and removes sulfur oxides in exhaust gas discharged from coal-fired thermal power plants. At this time, the absorbing liquid that has absorbed the sulfur component (hereinafter referred to as “waste water”) is discharged into a water channel into which untreated seawater flows, and is mixed with untreated seawater to further aerate to restore PH. Later, it was released into the sea.
  • scum In the process of aeration of wastewater mixed with untreated seawater, scum floats simultaneously with countless bubbles on the water surface.
  • “scum” refers to an object that is hard to disappear naturally, such as a solid matter such as boiler combustion fly ash that has floated on the surface of the water and a suspended matter containing gaseous substances such as air.
  • a solid matter such as boiler combustion fly ash that has floated on the surface of the water and a suspended matter containing gaseous substances such as air.
  • moisture may scatter from the surface and only solid matter may remain, and this solid matter solidifies so that it cannot be easily broken. Bubbles and scum are thought to be generated by floating on the sea surface together with air entrained in the seawater by aeration bubbles and wastewater turbulence due to the influence of seawater viscosity, ash and marine microorganisms.
  • the bubbles and scum do not easily disappear and may drift to the ocean release location. Discharging them as they are is undesirable because of environmental pollution or the appearance of foreign matter in seawater.
  • Patent Document 1 a foam recovery device having a floating structure in which the entire device is floated in a water channel is provided, the foam is separated from the water channel, stored in the foam recovery device, and the stored foam is stored in an ejector pump. And an apparatus for sucking with a vacuum pump and transferring it to a foam treatment apparatus outside the water channel.
  • Patent Document 2 a recovery pit is provided on the side of the water channel via an overflow weir, and the overflowed foam is temporarily stored in the recovery pit, and the stored foam is sucked with an ejector pump or a vacuum pump, An apparatus for transferring is disclosed.
  • the collected foam is a mixture of gas, liquid and solid, so when transporting with a pump, it will carry air at the same time.
  • a vacuum pump When transporting with a vacuum pump, it is necessary to increase the pump capacity. There was a lot of power needed.
  • the liquid level was not constant due to the sea level, and it was necessary to provide a sufficient amount of suction.
  • An object of the present invention is to provide a wastewater treatment facility in a flue gas desulfurization facility.
  • the present invention that has solved the above problems is as follows.
  • a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas
  • it is a processing facility that collects at least one of bubbles or scum floating on the sea surface of the seawater channel that discharges absorbed seawater.
  • An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway
  • the air lift device with the means Install a weir in the flow of seawater and locate the inflow opening of the weir almost on the sea surface.
  • a flue gas desulfurization facility characterized in that at least one of bubbles and scum floating on the seawater surface is collected by an air lift device from the inflow opening of the weir and led out of the flow of seawater through the pumping channel.
  • the flow rate of seawater is relatively slow, about 0.2 to 1.5 m / second, usually about 0.5 to 1.0 m / second.
  • a guide member that narrows toward the downstream side is provided at a position upstream of the seawater flow with respect to the weir, and a weir is provided at a position where the flow is narrowed by this guide member, bubbles and scum are reliably put into the weir. Can be guided.
  • a guide member that narrows toward the downstream side is provided at a position upstream of the seawater flow with respect to the weir, and a weir is provided at a position where the flow is narrowed by this guide member, bubbles and scum are reliably put into the weir. Can be guided.
  • a means of collecting bubbles and scum it is not forcibly sucked with a rotary vacuum pump, so there is no flow disturbance when guiding bubbles and scum to the weir, and it can be reliably guided to the weir.
  • the weir has a partition wall that extends higher than the upper edge of the inflow opening, and the boundary between the inflow opening and the partition wall is located upstream of the center of the weir from the flow of seawater,
  • Bubbles and scum components pumped along the pumping channel can be supplied to the treatment destination through the drainage channel.
  • a temporary storage unit communicating with the upper portion of the pumping channel is provided, an air exhaust port communicating with the outside air is formed in the temporary storage unit, a collision unit is provided above the upper opening of the pumping channel, and The waste water treatment facility in a flue gas desulfurization facility according to claim 1, wherein a downward sloping drainage channel for allowing a liquid containing foam and scum to flow down is communicated with the temporary storage unit.
  • Defoaming can be achieved by causing the pumped water to collide with a collision portion provided above the pumping path upper end opening.
  • the air exhaust port is for extracting air from bubbles and scum.
  • a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas
  • it is a processing facility that collects bubbles and scum floating on the sea surface of the sea channel that discharges the absorbed sea water
  • An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway
  • a plurality of air lift devices composed of means in the width direction of the flow of seawater, Each weir is installed in the flow of seawater and the inflow opening of the weir is positioned almost on the seawater surface.
  • Wastewater treatment equipment in flue gas desulfurization equipment, wherein bubbles and scum floating on the seawater surface are collected by an air lift device from the inflow opening of the weir and guided out of the flow of seawater through the pumping channel .
  • Mass processing is possible by providing a plurality of air lift devices for processing.
  • a support body extending over the sea surface from the middle of the seawater depth is provided across the width direction, and a plurality of flow openings are formed through the support body at intervals in the width direction.
  • a pair of guide members that narrow toward the downstream are provided on the left and right sides of the seawater flow line passing through each circulation opening.
  • the air lift device when used according to the present invention, it is possible to collect bubbles and scum and lift them to the sea surface with a relatively small amount of air feeding, which is remarkably practical. It was found to be expensive. It is also an advantage of the present invention that there is little accumulation or blockage of bubbles or scum in the airlift device. Furthermore, the equipment cost is extremely low.
  • a sulfur oxide-containing gas such as flue gas discharged from a coal-fired thermal power plant is fed into a desulfurization absorption tower (not shown), and seawater is poured therein.
  • the treated process gas is discharged from the upper part of the desulfurization absorption tower.
  • the sulfur oxide in the sulfur oxide-containing gas is absorbed into the seawater in the desulfurization absorption tower, and the wastewater 10 as the sulfur oxide absorption liquid (SO2 absorption liquid) is pumped from the sea and returned to the sea. It is inserted from an appropriate position.
  • SO2 absorption liquid sulfur oxide absorption liquid
  • waste water 10 As the waste water 10 is introduced, it joins and mixes with seawater, and if necessary, is aerated with a gas supplied from an air diffuser pipe 14 provided in a seawater channel 12 in an appropriate form.
  • a gas supplied from an air diffuser pipe 14 provided in a seawater channel 12 in an appropriate form.
  • the gas supplied here will not be specifically limited if it is a gas containing oxygen, air is desirable economically.
  • the finally treated waste water 10 is discharged from the end of the sea channel 12 to the sea.
  • pH described in FIG. 1 shows the example of seawater pH in a corresponding location.
  • the wastewater treatment facility according to the first embodiment of the present invention is provided, for example, at the end portion of the seawater channel 12. That is, for example, as shown in FIG. 3 and FIG. 4, a support 20 made of concrete, for example, made of concrete and extending over the sea surface from the middle of the depth of the seawater 12 across the width direction of the seawater channel 12, It is provided. A plurality of flow openings 21 are formed through the support 20 at intervals in the width direction.
  • a pair of guide members 16 that narrow toward the downstream are provided on the left and right sides of the seawater flow line passing through each circulation opening 21, and the weir 32 of the air lift device 30 is provided at a position downstream of the seawater flow of each circulation opening 21. It is provided.
  • Bubbles and scum floating on the water surface are guided to each flow opening 21 by the guide member 16.
  • the guide member 16 is, for example, a corrosion-resistant plate material, preferably a plastic plate material.
  • the float 16A is fixed by a position fixing member 16B provided on the road bottom. Also good.
  • the opening angle ⁇ in a plan view formed by a pair of opposing guide members is 30 to 90 degrees, more preferably 30 to 60 degrees, which has a high effect of inducing bubbles and scum and efficiently collects bubbles and scum. This is desirable because it can be done.
  • the airlift device 30 has an upper opening weir 32 at the upper end and is connected to the introduction path 34 that is submerged in seawater.
  • An air blowing means 38 (for example, constituted of a compressor 38A and an air conduit 38B) for supplying air to the lower part of the inside 36 is constituted as an element.
  • the introduction channel 34 and the pumping channel 36 are fixed to the bottom of the seawater channel by a support (not shown).
  • a weir 32 is installed in the flow of seawater, and the inflow opening 32A of the weir is positioned substantially on the seawater surface, and bubbles and scum floating on the seawater surface are caused to flow into the inflow opening 32A of the weir.
  • the air is collected by the air lift device 30 and led to a predetermined position such as the collective pit 46 or a foam treatment facility (not shown) outside the seawater channel via the pumping channel 36.
  • the weir 32 is preferably in the form shown in FIG. That is, the entire partition wall is preferably cylindrical with a diameter of 50 to 300 mm (more desirably 100 to 200 mm) and extends higher than the upper edge of the inflow opening 32A (for example, extends higher by about 20 to 80 mm).
  • 32B the boundary between the inflow opening 32A and the partition wall 32B is located on the upstream side of the flow of seawater from the center of the weir, and the opening angle ⁇ in plan view of the line connecting the boundary and the center of the weir is 60 to 180 degrees is desirable. More preferably, it is 60 to 120 degrees. It has been found that bubbles and scum can be efficiently recovered when the opening angle ⁇ is 60 to 120 degrees. If there is no partition wall 32B, since seawater always flows, seawater will be collected behind the weir without collecting bubbles and scum, and foam and scum collection efficiency is reduced.
  • the weir 32 is separated from the introduction path 34, and is structured to be fitted to the outside of the introduction path 34 with play.
  • the weir 32 can be moved up and down along the introduction path 34. In this case, it is desirable that the upper edge of the inflow opening 32A is in a state where it has been sunk by about 20 to 30 mm from the sea surface.
  • Defoaming treatment can be performed on the upper part of the air lift device 30.
  • An example is shown in FIG. That is, the temporary storage part 40 connected to this is provided in the upper part of the pumping path 36, and the temporary storage part 40 is provided with a downward inclined discharge water path 42 through which a liquid containing bubbles and scum flows down. Bubbles and scum components pumped along the pumping channel 36 can be supplied to the processing destination via the discharge channel 42.
  • an air exhaust port 44 communicating with the outside air is formed in the temporary storage unit 40, and a collision unit 48 is provided on the upper side facing the upper end opening of the pumping path. Defoaming can be achieved with any impact force by causing pumped water to collide with the collision portion 48 provided on the upper side facing the upper end opening of the pumping path 36.
  • the air exhaust port is for extracting air from bubbles and scum.
  • the pumping channel has a difference depending on the operation state, but the lift-up seawater and the air volume are almost 1: 1 inside. Therefore, if this separator is provided and air and bubbles or bubbles in scum are separated from seawater, the pipe size after lift-up is sufficient with a small diameter of about 1/4.
  • aeration air used for aeration in the sea channel 12 can be used. By blowing in air, it can be lifted up to about 1.5 times the height H of the underwater part (height from the water surface) to 1.5H, and it can be transported using the slope from that height. . If further lift height is required as required, the height can be held again by adding a similar lift-up operation on the way. At this time, since the bubbles were broken at the first lift-up, gas-liquid separation can be achieved by simply storing them with a soot, and a reduction in power can be expected.
  • the diameter of the weir 32 and the diameter of the flow opening 21 of the narrowest gap (preferably 100 to 500 mm) between the guide members 16 and 16 are substantially coincident with each other. It is desirable that it is within 10%, particularly within 5% of the diameter.
  • the fluid is seawater, so it is very corrosive in terms of environment.
  • metal it is necessary to use a high-grade material such as titanium.
  • the air lift pump does not have a rotating part, it is one of the features that it can be made entirely of resin.
  • the power necessary for operation is air, and in the embodiment, a large amount of air is required in the previous stage.
  • the air lift pump can be operated at a value lower than the air pressure used in the previous stage, and can be operated by using a small part of the previous stage in absolute quantity, and is extremely superior in terms of equipment and power compared to other systems. Is a process.
  • each air lift device 30 is connected to a common discharge water channel 45, the discharged bubbles and scum flow are guided to the collecting pit 46, and the collected bubbles and scum are shown in the shower ring or Batch processing (examples of processing forms are not shown) can be performed by mechanical foam removing means.
  • An opening may be provided below the wall separating the collective pit 46 and the seawater channel so that the seawater in the collective pit is discharged into the seawater channel.
  • a necessary number of similar air lift devices 30 are installed in the collective pit 46 as necessary, and a separate storage tank is provided. It can be transferred to a defoaming device such as a centrifuge and completely separated into seawater and scum or foam, the seawater can be returned to the sea, and the scum or foam can be dried and discarded.
  • the support body 20 can support at least a part of the constituent members of the guide member 16 and the air lift device in addition to the advantage of forming the flow opening 21.
  • the air lift device in this embodiment is the same as that shown in FIGS. 3 and 6, except that the discharge destination of the processing liquid discharged from the air lift device 30 is returned to the seawater channel 12 via the discharge water channel 42A.
  • the return destination may be the upstream seaway 12 or the downstream seaway 12 of the weir 32, but the upstream seaway 12 is particularly preferable in consideration of fluctuations in the amount of scum. Furthermore, it is good to provide the outlet to a sea channel in the position higher than a sea surface.
  • the outflow prevention member 50 is provided on the water surface around the weir 32.
  • the outflow prevention member 50 has a structure like an oil fence, and is opened on the flow opening 21 side. Providing the outflow prevention member 50 has an effect of preventing bubbles and scum that cannot be collected by the weir 32 from flowing out downstream.
  • FIG. 1 A third embodiment is illustrated in FIG.
  • a plurality of air lift devices 30, 30... are provided in series in the water channel width direction.
  • the discharge port of the discharge water passage 42 ⁇ / b> B connected to the discharge passage 42 connected to the air lift device is arranged on the upstream side of the air lift device different from the row of the connection source air lift devices 30.
  • the discharge water channel 42 of the air lift device closest to the water channel wall is connected to the foam treatment facility or the pit 46 through the discharge port 42C for processing. According to this configuration, it is possible to obtain a defoaming effect by the processing liquid and finally discharge bubbles and scum that could not be processed by the air lift device 30 to the outside of the seawater channel.
  • the present invention can be used for wastewater treatment of wastewater generated when SO 2 in flue gas discharged from a thermal power plant is absorbed by a flue gas desulfurization facility.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Removal Of Floating Material (AREA)
  • Physical Water Treatments (AREA)

Abstract

[Problem] To make effective trapping of foam or scum from discharged seawater possible with structurally simple equipment. [Solution] Treatment equipment for trapping foam or scum floating on the surface of seawater in the seawater channel that discharges post-absorption seawater in a flue gas desulfurization facility for absorbing and removing sulfur oxides in exhaust gas into seawater, wherein an air lift device (30) is configured from an introducing channel (34) that has an upper opening dam (32) at the upper end thereof and is submerged in the seawater, a pumping channel (36) that is connected to the introducing channel (34) and spans from within the seawater to above the seawater surface, and an air-blowing means (38) that delivers air into the lower part of the pumping channel (36). The equipment is configured so that the dam (32) is disposed in the flow of the seawater and the inflow opening (32A) of the dam is positioned substantially at the surface of the seawater to trap foam or scum floating on the seawater surface from the inflow opening (32A) of the dam using the air lift device (30) and to conduct same outside of the flow of the seawater via the pumping channel (36).

Description

排煙脱硫設備における廃水処理設備Wastewater treatment equipment in flue gas desulfurization equipment

 本発明は、石炭焚き火力発電所などから排出される排ガスの排煙脱硫設備において生じる海水面に浮遊する泡やスカムを効率的に捕集し、処理する設備に関するものである。例えば、火力発電所から排出される煙道ガス中のSO2を、海水法排煙脱硫設備で吸収した際に発生するような、SO2を吸収した吸収液の廃水処理に適用可能なものである。 The present invention relates to a facility for efficiently collecting and treating bubbles and scum floating on seawater generated in a flue gas desulfurization facility for exhaust gas discharged from a coal-fired thermal power plant or the like. For example, the SO 2 in the flue gases discharged from the thermal power plant, such as those generated upon absorption seawater method flue gas desulfurization, as it can be applied to waste water treatment of the absorbent that has absorbed SO 2 is there.

 海水法排煙脱硫設備は、石炭焚き火力発電所などから排出される排気ガス中の硫黄酸化物を海水に吸収させ、除去する設備として知られている。このとき硫黄成分を吸収した吸収液(以下、「廃水」という)は、未処理の海水が流入する水路に放流され、未処理海水と混合させた上でさらにエアレーションを行い、PHを回復させたのち、海へ放流されている。 Seawater method flue gas desulfurization equipment is known as equipment that absorbs and removes sulfur oxides in exhaust gas discharged from coal-fired thermal power plants. At this time, the absorbing liquid that has absorbed the sulfur component (hereinafter referred to as “waste water”) is discharged into a water channel into which untreated seawater flows, and is mixed with untreated seawater to further aerate to restore PH. Later, it was released into the sea.

 未処理海水と混合された廃水にエアレーションを行う工程において、水面には無数の気泡と同時にスカムが浮遊する。ここで「スカム」とは、水面に浮上したボイラ燃焼飛灰などの固形物と、空気などガス状物質が含まれる浮遊物で自然には消滅しにくい物体を指す。また、浮遊状態を長期間継続した場合、表面から水分が飛散し固形物のみ残ることがあり、この固形物は、容易に破壊ができないほど固化する。泡やスカムは、海水の粘性とアッシュや海洋の微生物なども影響し、曝気の気泡や廃水の乱流により海水中に巻き込まれた空気と一緒に海面上へ浮遊し発生すると考えられている。 In the process of aeration of wastewater mixed with untreated seawater, scum floats simultaneously with countless bubbles on the water surface. Here, “scum” refers to an object that is hard to disappear naturally, such as a solid matter such as boiler combustion fly ash that has floated on the surface of the water and a suspended matter containing gaseous substances such as air. In addition, when the floating state is continued for a long period of time, moisture may scatter from the surface and only solid matter may remain, and this solid matter solidifies so that it cannot be easily broken. Bubbles and scum are thought to be generated by floating on the sea surface together with air entrained in the seawater by aeration bubbles and wastewater turbulence due to the influence of seawater viscosity, ash and marine microorganisms.

 この泡やスカムは容易に消えず、海洋への放流場所に漂う場合があり、そのまま放流することは、環境汚染上、あるいは海水に異物が存在する外観を与え好ましくなかった。 The bubbles and scum do not easily disappear and may drift to the ocean release location. Discharging them as they are is undesirable because of environmental pollution or the appearance of foreign matter in seawater.

 そこで、特許文献1には、装置全体が水路内で浮いた状態の浮体構造の泡回収装置を設け、その水路から泡を分離し、泡回収装置に貯留し、さらに貯留した泡は、エジェクタポンプやバキュームポンプで吸引し、水路外の泡処理装置に移送する装置が開示されている。 Therefore, in Patent Document 1, a foam recovery device having a floating structure in which the entire device is floated in a water channel is provided, the foam is separated from the water channel, stored in the foam recovery device, and the stored foam is stored in an ejector pump. And an apparatus for sucking with a vacuum pump and transferring it to a foam treatment apparatus outside the water channel.

 特許文献2には、水路側面に越流堰を介して回収ピットを設け、越流した泡を回収ピットに一端貯留し、貯留した泡は、エジェクタポンプやバキュームポンプで吸引し、泡処理装置に移送する装置が開示されている。 In Patent Document 2, a recovery pit is provided on the side of the water channel via an overflow weir, and the overflowed foam is temporarily stored in the recovery pit, and the stored foam is sucked with an ejector pump or a vacuum pump, An apparatus for transferring is disclosed.

 またスプレーによる気泡の破壊する方法も知られている。しかし、スプレーはある程度有効であるが、水路の水面高さが変動することで、スプレーの有効噴霧範囲外で気泡が生じたり、時期や運転条件などにより気泡量が多くなったりすると対処ができず、本発明が対象とする排煙脱硫設備において生じる大面積の海水面に浮遊する大量の泡やスカムを処理する設備には、根本的に適しない。 Also known is a method of destroying bubbles by spraying. However, spraying is effective to some extent, but it cannot be dealt with if the water level of the waterway fluctuates, causing bubbles to form outside the effective spraying range of the spray, or if the amount of bubbles increases due to time or operating conditions. The present invention is fundamentally unsuitable for facilities for treating a large amount of bubbles and scum floating on the sea surface of a large area generated in a flue gas desulfurization facility.

特開2008-200620号公報JP 2008-200260 A

特開2009-45614号公報JP 2009-45614 A

 先行例によって、捕集した泡は、気体と液体と個体の混合物のため、ポンプでの搬送の場合、空気を同時に運ぶこととなり、真空ポンプで移送する場合には、ポンプ容量を大きくとる必要があり、多くの動力が必要となっていた。特に運転条件や場合により海水面の干満で液面が一定とならず、吸引量に余裕を持たせなければならなかった。 According to the previous example, the collected foam is a mixture of gas, liquid and solid, so when transporting with a pump, it will carry air at the same time. When transporting with a vacuum pump, it is necessary to increase the pump capacity. There was a lot of power needed. In particular, depending on the operating conditions and circumstances, the liquid level was not constant due to the sea level, and it was necessary to provide a sufficient amount of suction.

 他方、液体と気体とを同時に移送することになるため、回転式真空ポンプで吸引する場合はキャビテーションを強制的に発生させた状態で運転することとなり、装置の振動、腐食などが懸念される。さらに、気体は圧縮性のため配管での流速も遅くなり、その結果、固体物が配管等に堆積し、最終的に配管の閉塞を生じる可能性がある。
 連続運転の必要性から予備機の設置が必要となり、大幅のコストアップが要求される。
On the other hand, since the liquid and the gas are simultaneously transferred, when sucking with the rotary vacuum pump, the operation is performed in a state in which cavitation is forcibly generated, and there is a concern about vibration and corrosion of the apparatus. Further, since the gas is compressible, the flow rate in the pipe is also slowed down. As a result, solid substances may accumulate in the pipe and the like, and finally the pipe may be blocked.
Due to the necessity of continuous operation, it is necessary to install a spare machine, which requires a significant cost increase.

 したがって、本発明の主たる課題は、構造的にシンプルな装置でありながら、排出海水から泡やスカムを効率的に捕集し処理する設備、必要によりその後に脱泡し処理系外に容易に移送できる排煙脱硫設備における廃水処理設備を提供することにある。 Therefore, the main problem of the present invention is that it is a structurally simple device, but equipment that efficiently collects and processes bubbles and scum from the discharged seawater. An object of the present invention is to provide a wastewater treatment facility in a flue gas desulfurization facility.

 上記課題を解決した本発明は次記のとおりである。 The present invention that has solved the above problems is as follows.

 <請求項1記載の発明>
 排気ガス中の硫黄酸化物を海水に吸収させ、除去する排煙脱硫設備において、吸収済み海水を放流する海水路の海水面に浮遊する泡またはスカムのうち少なくとも一方を捕集処理する処理設備であって、
 上方開口の堰を上端部に有し海水中に没する導入路と、この導入路と連結し、海水中と海水面上にわたる揚水路と、揚水路内下部にエアを送給するエア吹込み手段とでエアリフト装置を構成し、
 海水の流れの中に、堰を設置するとともにその堰の流入開口をほぼ海水面に位置させ、
 海水面に浮遊する泡やスカムのうち少なくとも一方を前記堰の流入開口からエアリフト装置に捕集し、前記揚水路を介して海水の流れ外に導くようにしたことを特徴とする排煙脱硫設備における廃水処理設備。
<Invention of Claim 1>
In a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas, it is a processing facility that collects at least one of bubbles or scum floating on the sea surface of the seawater channel that discharges absorbed seawater. There,
An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway The air lift device with the means,
Install a weir in the flow of seawater and locate the inflow opening of the weir almost on the sea surface.
A flue gas desulfurization facility characterized in that at least one of bubbles and scum floating on the seawater surface is collected by an air lift device from the inflow opening of the weir and led out of the flow of seawater through the pumping channel. Wastewater treatment equipment in

 (作用効果)
 特許文献1及び2のように、泡を集め、回転式真空ポンプで処理場所に搬送する場合、大量の空気をも運ぶこととなり、多大な運転コストを要する。また、輸送配管内への堆積及び閉塞も大きな問題となっていた。さらに、捕集のための金属製配管は海水による腐食防止のためにSUSなどを使用せねばならず、コスト高の要因となっていた。
 これに対し、本発明に従ってエアリフト装置を使用すると、比較的少ないエアの送り込みのみで、泡やスカムを捕集し海面上へ揚げることが可能であり、著しく実用性の高いものであることが知見された。エアリフト装置内での泡やスカムの堆積及び閉塞がほとんどないことも本発明の利点である。さらに装置コストは著しく低いものである。
(Function and effect)
As in Patent Documents 1 and 2, when bubbles are collected and transported to a processing place with a rotary vacuum pump, a large amount of air is also transported, which requires a large operating cost. In addition, accumulation and blockage in the transport pipe have also been a serious problem. Furthermore, metal pipes for collection have to use SUS or the like to prevent corrosion due to seawater, which has been a factor of high cost.
On the other hand, using the air lift device according to the present invention, it is found that bubbles and scum can be collected and lifted to the sea surface with only a relatively small amount of air feeding, which is extremely practical. It was done. It is also an advantage of the present invention that there is little accumulation or blockage of bubbles or scum in the airlift device. Furthermore, the equipment cost is extremely low.

 <請求項2記載の発明>
 前記堰に対して海水流れの上流側に位置に、下流に向かって狭まるガイド部材を設け、このガイド部材によって流れが狭まった位置に前記堰が設けられている請求項1記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 2>
The flue gas desulfurization equipment according to claim 1, wherein a guide member that narrows toward the downstream is provided at a position upstream of the seawater flow with respect to the weir, and the weir is provided at a position where the flow is narrowed by the guide member. Wastewater treatment equipment in

 (作用効果)
 海水の流速は、0.2~1.5m/秒程度、通常は、0.5~1.0m/秒程度と比較的遅い。これに対し、堰に対して海水流れの上流側に位置に、下流に向かって狭まるガイド部材を設け、このガイド部材によって流れが狭まった位置に堰を設けると、泡やスカムを確実に堰に誘導できる。そして、泡やスカムの収集手段として、回転式真空ポンプで強引に吸引するものではないので、泡やスカムを堰に誘導する際に流れの乱れがなく、確実に堰に誘導できるようになるのである。
(Function and effect)
The flow rate of seawater is relatively slow, about 0.2 to 1.5 m / second, usually about 0.5 to 1.0 m / second. On the other hand, if a guide member that narrows toward the downstream side is provided at a position upstream of the seawater flow with respect to the weir, and a weir is provided at a position where the flow is narrowed by this guide member, bubbles and scum are reliably put into the weir. Can be guided. And, as a means of collecting bubbles and scum, it is not forcibly sucked with a rotary vacuum pump, so there is no flow disturbance when guiding bubbles and scum to the weir, and it can be reliably guided to the weir. is there.

 <請求項3記載の発明>
 前記堰は、流入開口の上縁より高く延在する仕切り壁を有し、前記流入開口と仕切り壁との境界は、堰の中心より海水の流れの上流側に位置しており、前記境界と堰中心を結ぶ線の平面視での開き角度は、60~120度である請求項1記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 3>
The weir has a partition wall that extends higher than the upper edge of the inflow opening, and the boundary between the inflow opening and the partition wall is located upstream of the center of the weir from the flow of seawater, The wastewater treatment facility in a flue gas desulfurization facility according to claim 1, wherein an opening angle of the line connecting the weir centers in a plan view is 60 to 120 degrees.

 (作用効果)
 開き角度が60~120度であると、効率的に泡やスカムを回収できることを知見している。仮に、仕切り壁がないと、海水が常時流れているので、堰の後方では、泡やスカムを回収することなく、海水を回収することになり、泡やスカム回収効率を低下させる。
(Function and effect)
It has been found that bubbles and scum can be efficiently collected when the opening angle is 60 to 120 degrees. If there is no partition wall, seawater always flows. Therefore, the seawater is collected behind the weir without collecting bubbles and scum, and the foam and scum collection efficiency is lowered.

 <請求項4記載の発明>
 前記堰は導入路と別体であり、前記堰には浮きが一体となり、海水面の上下に応じて前記堰は導入路に沿って上下可能とされている請求項1記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 4>
The flue gas desulfurization equipment according to claim 1, wherein the weir is separate from the introduction path, and the floating is integrated with the weir, and the weir can be moved up and down along the introduction path according to the sea level. Wastewater treatment equipment in

 (作用効果)
 海水面の上下運動に追従して浮きの浮力により堰が昇降するので、海水面の上下運動にかかわらず、泡やスカム回収効率が安定している。
(Function and effect)
Since the weir moves up and down by floating buoyancy following the vertical movement of the sea surface, the foam and scum recovery efficiency is stable regardless of the vertical movement of the sea surface.

 <請求項5記載の発明>
 前記揚水路の上部にこれと連通する一時貯留部を設け、一時貯留部には泡やスカムを含む液を流下させる下り傾斜の排出水路が連通して設けられている請求項1記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 5>
The flue gas according to claim 1, wherein a temporary storage portion communicating with the temporary storage portion is provided at an upper portion of the pumping passage, and a downward inclined discharge water passage for allowing liquid containing bubbles and scum to flow down is provided in communication with the temporary storage portion. Wastewater treatment equipment in desulfurization equipment.

 (作用効果)
 揚水路に沿って揚水した泡やスカム成分を排水水路を介して処理先に送給できる。
(Function and effect)
Bubbles and scum components pumped along the pumping channel can be supplied to the treatment destination through the drainage channel.

 <請求項6記載の発明>
 前記揚水路の上部にこれと連通する一時貯留部を設け、一時貯留部には外気と連通するエア排気口が形成され、前記揚水路上端開口に対向して上方に衝突部が設けられ、さらに前記一時貯留部には泡やスカムを含む液を流下させる下り傾斜の排出水路が連通して設けられている請求項1記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 6>
A temporary storage unit communicating with the upper portion of the pumping channel is provided, an air exhaust port communicating with the outside air is formed in the temporary storage unit, a collision unit is provided above the upper opening of the pumping channel, and The waste water treatment facility in a flue gas desulfurization facility according to claim 1, wherein a downward sloping drainage channel for allowing a liquid containing foam and scum to flow down is communicated with the temporary storage unit.

 (作用効果)
 揚水路上端開口に対向して上方に設けた衝突部に、揚水分を衝突させることにより、脱泡を図ることができる。エア排気口は、泡やスカム中のエア分を抜くためのものである。
(Function and effect)
Defoaming can be achieved by causing the pumped water to collide with a collision portion provided above the pumping path upper end opening. The air exhaust port is for extracting air from bubbles and scum.

 <請求項7記載の発明>
 前記排出水路の出口は、前記堰に対して海水流れの上流側の海水路内または下流側の海水路上に設けられている請求項6記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 7>
The wastewater treatment facility in a flue gas desulfurization facility according to claim 6, wherein an outlet of the discharge channel is provided in a sea channel on the upstream side of the sea water flow or on a sea channel on the downstream side of the weir.

 (作用効果)
 スカム量が少ない場合には、一時貯留部で泡およびスカムが処理しきれるため、本実施形態のようにそのまま海水路に返送することが可能となる。
(Function and effect)
When the amount of scum is small, the foam and scum can be completely processed in the temporary storage unit, so that it can be returned to the seawater channel as it is in this embodiment.

 <請求項8記載の発明>
 排気ガス中の硫黄酸化物を海水に吸収させ、除去する排煙脱硫設備において、吸収済み海水を放流する海水路の海水面に浮遊する泡やスカムを捕集処理する処理設備であって、
 上方開口の堰を上端部に有し海水中に没する導入路と、この導入路と連結し、海水中と海水面上にわたる揚水路と、揚水路内下部にエアを送給するエア吹込み手段とで構成したエアリフト装置を、海水の流れの幅方向に複数設け、
 海水の流れの中に、堰をそれぞれ設置するとともにその堰の流入開口をほぼ海水面に位置させ、
 海水面に浮遊する泡やスカムを前記堰の流入開口からエアリフト装置に捕集し、前記揚水路を介して海水の流れ外に導くようにしたことを特徴とする排煙脱硫設備における廃水処理設備。
<Invention of Claim 8>
In a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas, it is a processing facility that collects bubbles and scum floating on the sea surface of the sea channel that discharges the absorbed sea water,
An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway A plurality of air lift devices composed of means in the width direction of the flow of seawater,
Each weir is installed in the flow of seawater and the inflow opening of the weir is positioned almost on the seawater surface.
Wastewater treatment equipment in flue gas desulfurization equipment, wherein bubbles and scum floating on the seawater surface are collected by an air lift device from the inflow opening of the weir and guided out of the flow of seawater through the pumping channel .

(作用効果)
 エアリフト装置を複数設けて処理することにより大量処理が可能となる。
(Function and effect)
Mass processing is possible by providing a plurality of air lift devices for processing.

 <請求項9記載の発明>
 各エアリフト装置の揚水路を通して排出する泡やスカム流れを集合ピットに案内して、その集合した泡やスカムを一括処理するように構成した請求項8記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 9>
The wastewater treatment facility in a flue gas desulfurization facility according to claim 8, wherein the foam and scum flow discharged through the pumping path of each airlift device is guided to the collective pit and the collected foam and scum are collectively processed.

(作用効果)
 各エアリフト装置からの泡やスカムを個別に処理するのでなく、集合した泡やスカムを一括処理するように構成したので、処理コストが低減する。
(Function and effect)
Instead of individually processing bubbles and scum from each air lift device, it is configured to collectively process the collected bubbles and scum, thereby reducing processing costs.

 <請求項10記載の発明>
 前記堰に対して海水流れの上流側に位置に、各堰を通る海水流れ線を挟んだ左右に、下流に向かって狭まる一対のガイド部材を設け、この一対のガイド部材によって流れが狭まった位置に前記堰が設けられている請求項8記載の排煙脱硫設備における廃水処理設備。
 (作用効果)
 ガイド部材によって流れが狭まった位置に堰を設けると、泡やスカムを確実に堰に誘導できる。そして、泡やスカムの収集手段として、回転式真空ポンプで強引に吸引するものではないので、泡やスカムを堰に誘導する際に流れの乱れがなく、確実に堰に誘導できるようになるのである。
<Invention of Claim 10>
Positions on the upstream side of the seawater flow with respect to the weir, a pair of guide members that narrow toward the downstream on both sides of the seawater flow line that passes through each weir, and positions where the flow is narrowed by the pair of guide members The wastewater treatment facility in the flue gas desulfurization facility according to claim 8, wherein the weir is provided on the wastewater.
(Function and effect)
If a weir is provided at a position where the flow is narrowed by the guide member, bubbles and scum can be reliably guided to the weir. And, as a means of collecting bubbles and scum, it is not forcibly sucked with a rotary vacuum pump, so there is no flow disturbance when guiding bubbles and scum to the weir, and it can be reliably guided to the weir. is there.

 <請求項11記載の発明>
海水路の途中に、海水深さ途中から海面上に延在する支持体を幅方向に渡って設け、この支持体にこれを貫いて、幅方向に間隔を置いて複数の流通開口を形成し、
 各流通開口の海水流れの上流側に位置に、各流通開口を通る海水流れ線を挟んだ左右に、下流に向かって狭まる一対のガイド部材をそれぞれ設け、
 各流通開口の海水流れの下流側に位置に、前記エアリフト装置の堰を設けてある請求項8記載の排煙脱硫設備における廃水処理設備。
<Invention of Claim 11>
In the middle of the sea channel, a support body extending over the sea surface from the middle of the seawater depth is provided across the width direction, and a plurality of flow openings are formed through the support body at intervals in the width direction. ,
At the upstream side of the seawater flow of each circulation opening, a pair of guide members that narrow toward the downstream are provided on the left and right sides of the seawater flow line passing through each circulation opening,
The wastewater treatment facility in the flue gas desulfurization facility according to claim 8, wherein a weir of the air lift device is provided at a position downstream of the seawater flow of each circulation opening.

 (作用効果)
 海水は支持体の流通開口を通ることになり、その流通開口の下流に堰がそれぞれ設けられているので、泡やスカムの回収が確実になり、回収効率が高まる。
(Function and effect)
Seawater passes through the flow opening of the support, and the weirs are respectively provided downstream of the flow openings. Therefore, the recovery of bubbles and scum is ensured, and the recovery efficiency is increased.

 以上説明したように本発明によれば、本発明に従ってエアリフト装置を使用すると、比較的少ないエアの送り込みのみで、泡やスカムを捕集し海面上へ揚げることが可能であり、著しく実用性の高いものであることが知見された。エアリフト装置内での泡やスカムの堆積及び閉塞がほとんどないことも本発明の利点である。さらに装置コストは著しく低いものである。 As described above, according to the present invention, when the air lift device is used according to the present invention, it is possible to collect bubbles and scum and lift them to the sea surface with a relatively small amount of air feeding, which is remarkably practical. It was found to be expensive. It is also an advantage of the present invention that there is little accumulation or blockage of bubbles or scum in the airlift device. Furthermore, the equipment cost is extremely low.

本発明の廃水処理設備例の処理海水路例の平面図である。It is a top view of the example of the seawater channel of the example of the wastewater treatment facility of this invention. その縦断面図である。It is the longitudinal cross-sectional view. 本発明の廃水処理設備例の概要平面図である。It is a general | schematic top view of the example of the waste water treatment facility of this invention. そのA-A線断面図である。It is the AA sectional view. B-B線縦断面図である。It is a BB line longitudinal cross-sectional view. エアリフト(ポンプ)装置例の概要図である。It is a schematic diagram of an example of an air lift (pump) device. 堰の例の斜視図である。It is a perspective view of the example of a weir. 本発明の廃水処理設備の他の例の概要断面図である。It is an outline sectional view of other examples of the wastewater treatment equipment of the present invention. 本発明の廃水処理設備の他の例の概要平面図である。It is a general | schematic top view of the other example of the wastewater treatment facility of this invention. その縦断面図である。It is the longitudinal cross-sectional view. 本発明の廃水処理設備のさらに別の例の概要平面図である。It is a general | schematic top view of another example of the wastewater treatment facility of this invention.

 本発明の最良の形態に係る廃水処理設備の実施例を図面を参照しながら説明する。
 なお、以下の好ましい実施形態の説明は、本質的な例示に過ぎず、本発明、その適用あるいはその用途を制限することを意図するものではない。
An embodiment of a wastewater treatment facility according to the best mode of the present invention will be described with reference to the drawings.
The following description of the preferred embodiment is merely an exemplification, and is not intended to limit the present invention, its application, or its use.

 図1及び図2は、廃水及び廃水処理系を主に図示している。
 図示しない脱硫吸収塔には、例えば石炭焚き火力発電所から排出される煙道ガスなどの硫黄酸化物含有ガスを送り込むとともに、海水を注ぎ込むようにしてある。脱硫吸収塔の上部からは処理された処理ガスが排出されるようになっている。
1 and 2 mainly illustrate the waste water and the waste water treatment system.
A sulfur oxide-containing gas such as flue gas discharged from a coal-fired thermal power plant is fed into a desulfurization absorption tower (not shown), and seawater is poured therein. The treated process gas is discharged from the upper part of the desulfurization absorption tower.

 脱硫吸収塔内で硫黄酸化物含有ガス中の硫黄酸化物が海水中に吸収され、この硫黄酸化物吸収液(SO2吸収液)たる廃水10は、海から汲み上げ海へと戻す海水の海水路12の適宜の位置から投入される。 The sulfur oxide in the sulfur oxide-containing gas is absorbed into the seawater in the desulfurization absorption tower, and the wastewater 10 as the sulfur oxide absorption liquid (SO2 absorption liquid) is pumped from the sea and returned to the sea. It is inserted from an appropriate position.

 廃水10の投入により、海水との合流・混合が生じ、必要により、海水路12に適宜の形態で設けた散気管14から供給される気体により曝気処理される。ここで供給される気体は、酸素を含む気体であれば特に限定はないが、空気が経済的にも望ましい。最終的に処理された廃水10は、海水路12の終端から海へ放流される。なお、図1中に記載したpHは、該当箇所における海水pHの例を示す。 As the waste water 10 is introduced, it joins and mixes with seawater, and if necessary, is aerated with a gas supplied from an air diffuser pipe 14 provided in a seawater channel 12 in an appropriate form. Although the gas supplied here will not be specifically limited if it is a gas containing oxygen, air is desirable economically. The finally treated waste water 10 is discharged from the end of the sea channel 12 to the sea. In addition, pH described in FIG. 1 shows the example of seawater pH in a corresponding location.

 前述のように、海水とのエアレーション(曝気処理)を行う工程において、水面には無数の気泡と同時に泡やスカムが浮遊する。
 本発明は、これを効率的かつ確実に処理するものである。
As described above, in the process of performing aeration (aeration treatment) with seawater, bubbles and scum float on the water surface simultaneously with countless bubbles.
The present invention handles this efficiently and reliably.

 本発明の第1の実施形態に係る廃水処理設備は、たとえば海水路12の終端部に設けられる。すなわち、海水路12の終端部に、たとえば図3及び図4に示すように、海水深さ途中から海面上に延在する、たとえばコンクリート製の支持体20を海水路12の幅方向に渡って設けてある。この支持体20にこれを貫いて、幅方向に間隔を置いて複数の流通開口21が形成してある。 The wastewater treatment facility according to the first embodiment of the present invention is provided, for example, at the end portion of the seawater channel 12. That is, for example, as shown in FIG. 3 and FIG. 4, a support 20 made of concrete, for example, made of concrete and extending over the sea surface from the middle of the depth of the seawater 12 across the width direction of the seawater channel 12, It is provided. A plurality of flow openings 21 are formed through the support 20 at intervals in the width direction.

 各流通開口21を通る海水流れ線を挟んだ左右に、下流に向かって狭まる一対のガイド部材16をそれぞれ設け、各流通開口21の海水流れの下流側に位置に、エアリフト装置30の堰32を設けてある。 A pair of guide members 16 that narrow toward the downstream are provided on the left and right sides of the seawater flow line passing through each circulation opening 21, and the weir 32 of the air lift device 30 is provided at a position downstream of the seawater flow of each circulation opening 21. It is provided.

 水面に浮遊する泡やスカムは、ガイド部材16によって、各流通開口21に導かれる。ここでガイド部材16は、たとえば耐食性の板材、好適にはプラスチック板材であり、他の形態として、図8のように、路底に設けた位置固定部材16Bによりフロート16Aを固定した形態などであてもよい。対向する一対のガイド部材がなす平面視での開き角度θは、30~90度、より好ましくは30~60度であるのが泡やスカムの誘導効果が高く、効率的に泡やスカムを回収できる点で望ましい。 Bubbles and scum floating on the water surface are guided to each flow opening 21 by the guide member 16. Here, the guide member 16 is, for example, a corrosion-resistant plate material, preferably a plastic plate material. As another form, as shown in FIG. 8, the float 16A is fixed by a position fixing member 16B provided on the road bottom. Also good. The opening angle θ in a plan view formed by a pair of opposing guide members is 30 to 90 degrees, more preferably 30 to 60 degrees, which has a high effect of inducing bubbles and scum and efficiently collects bubbles and scum. This is desirable because it can be done.

次にエアリフト装置30の詳細例を図6に示す。すなわち、エアリフト装置30は、上方開口の堰32を上端部に有し海水中に没する導入路34と、この導入路34と連結し、海水中と海水面上にわたる揚水路36と、揚水路36内下部にエアを送給するエア吹込み手段38(たとえばコンプレッサー38Aとエア導管38Bで構成されている)とを要素として構成している。エアリフト装置30は、導入路34と揚水路36を図示しないサポートによって海水路底部と固定されている。 Next, a detailed example of the air lift device 30 is shown in FIG. That is, the airlift device 30 has an upper opening weir 32 at the upper end and is connected to the introduction path 34 that is submerged in seawater. An air blowing means 38 (for example, constituted of a compressor 38A and an air conduit 38B) for supplying air to the lower part of the inside 36 is constituted as an element. In the air lift device 30, the introduction channel 34 and the pumping channel 36 are fixed to the bottom of the seawater channel by a support (not shown).

 かかるエアリフト装置30を使用し、海水の流れの中に、堰32を設置するとともにその堰の流入開口32Aをほぼ海水面に位置させ、海水面に浮遊する泡やスカムを前記堰の流入開口32Aからエアリフト装置30に捕集し、揚水路36を介して、集合ピット46や海水路外の泡処理設備(図示せず)など所定の位置まで導くようにしたものである。  Using such an air lift device 30, a weir 32 is installed in the flow of seawater, and the inflow opening 32A of the weir is positioned substantially on the seawater surface, and bubbles and scum floating on the seawater surface are caused to flow into the inflow opening 32A of the weir. The air is collected by the air lift device 30 and led to a predetermined position such as the collective pit 46 or a foam treatment facility (not shown) outside the seawater channel via the pumping channel 36. *

 堰32は、たとえば図7に示す形態が望ましい。すなわち、全体が好ましくは直径が50~300mm(より望ましくは、100~200mm)の円筒状であり、流入開口32Aの上縁より高く延在する(たとえば20~80mm程度高く延在する)仕切り壁32Bを有し、流入開口32Aと仕切り壁32Bとの境界は、堰の中心より海水の流れの上流側に位置しており、前記境界と堰中心を結ぶ線の平面視での開き角度αは、60~180度であるのが望ましい。より望ましくは60~120度である。開き角度αが60~120度であると、効率的に泡やスカムを回収できることを知見している。仮に、仕切り壁32Bがないと、海水が常時流れているので、堰の後方では、泡やスカムを回収することなく、海水を回収することになり、泡やスカム回収効率を低下させる。 The weir 32 is preferably in the form shown in FIG. That is, the entire partition wall is preferably cylindrical with a diameter of 50 to 300 mm (more desirably 100 to 200 mm) and extends higher than the upper edge of the inflow opening 32A (for example, extends higher by about 20 to 80 mm). 32B, the boundary between the inflow opening 32A and the partition wall 32B is located on the upstream side of the flow of seawater from the center of the weir, and the opening angle α in plan view of the line connecting the boundary and the center of the weir is 60 to 180 degrees is desirable. More preferably, it is 60 to 120 degrees. It has been found that bubbles and scum can be efficiently recovered when the opening angle α is 60 to 120 degrees. If there is no partition wall 32B, since seawater always flows, seawater will be collected behind the weir without collecting bubbles and scum, and foam and scum collection efficiency is reduced.

 図6に示すように、堰32は導入路34と別体とし、導入路34の外方に遊びをもって嵌合する構造とし、堰32には浮き33を一体とし、海水面の上下に応じて堰32は導入路34に沿って上下可能とさせることができる。この場合、流入開口32Aの上縁は、海水面から20~30mm程度沈んだ状態になることが望ましい。 As shown in FIG. 6, the weir 32 is separated from the introduction path 34, and is structured to be fitted to the outside of the introduction path 34 with play. The weir 32 can be moved up and down along the introduction path 34. In this case, it is desirable that the upper edge of the inflow opening 32A is in a state where it has been sunk by about 20 to 30 mm from the sea surface.

 エアリフト装置30の上部において、脱泡処理することができる。その例を図6に示した。すなわち、揚水路36の上部にこれと連通する一時貯留部40を設け、一時貯留部40には泡やスカムを含む液を流下させる下り傾斜の排出水路42が連通して設けられてある。揚水路36に沿って揚水した泡やスカム成分を、排出水路42を介して処理先に送給できる。 Defoaming treatment can be performed on the upper part of the air lift device 30. An example is shown in FIG. That is, the temporary storage part 40 connected to this is provided in the upper part of the pumping path 36, and the temporary storage part 40 is provided with a downward inclined discharge water path 42 through which a liquid containing bubbles and scum flows down. Bubbles and scum components pumped along the pumping channel 36 can be supplied to the processing destination via the discharge channel 42.

 また、一時貯留部40には外気と連通するエア排気口44が形成され、揚水路上端開口に対向して上方に衝突部48が設けられている。揚水路36上端開口に対向して上方に設けた衝突部48に、揚水分を衝突させどの衝撃力により、脱泡を図ることができる。エア排気口は、泡やスカム中のエア分を抜くためのものである。
 揚水路は、運転状態により違いはあるが、その内部において、リフトアップ海水とエアーボリュームはほぼ1:1となる。したがって、このセパレータを設け、エア及び泡やスカム中の気泡と海水を分離すると、リフトアップ後の配管サイズは1/4程度の小径のもので足りるものとなる。
In addition, an air exhaust port 44 communicating with the outside air is formed in the temporary storage unit 40, and a collision unit 48 is provided on the upper side facing the upper end opening of the pumping path. Defoaming can be achieved with any impact force by causing pumped water to collide with the collision portion 48 provided on the upper side facing the upper end opening of the pumping path 36. The air exhaust port is for extracting air from bubbles and scum.
The pumping channel has a difference depending on the operation state, but the lift-up seawater and the air volume are almost 1: 1 inside. Therefore, if this separator is provided and air and bubbles or bubbles in scum are separated from seawater, the pipe size after lift-up is sufficient with a small diameter of about 1/4.

 エア導管38Bから吹出すエアとしては、海水路12内の曝気に使用するエアレーションエアーを利用することができる。エアの吹込みによって、水中部分の高さHの約1.5倍(水面からの高さ)1.5Hまでリフトアップすることができ、そこの高さから傾斜を利用し搬送することができる。必要に応じて、さらにリフト高さを必要とする場合は、途中にて同様のリフトアップ操作をくわえることで再度高さの保持が可能となる。またこの時は、1回目のリフトアップ時に気泡を壊していることからも、単なる舛にて貯留することで気液分離も可能となり、動力の削減も期待できる。 As the air blown out from the air conduit 38B, aeration air used for aeration in the sea channel 12 can be used. By blowing in air, it can be lifted up to about 1.5 times the height H of the underwater part (height from the water surface) to 1.5H, and it can be transported using the slope from that height. . If further lift height is required as required, the height can be held again by adding a similar lift-up operation on the way. At this time, since the bubbles were broken at the first lift-up, gas-liquid separation can be achieved by simply storing them with a soot, and a reduction in power can be expected.

 堰32の直径と、ガイド部材16、16の最狭間隔(100~500mmが望ましい)の流通開口21径とはほぼ一致しているのが望ましく、長さの差異があるとしても、堰32の直径に対し10%以内、特に5%以内であるのが望ましい。 It is desirable that the diameter of the weir 32 and the diameter of the flow opening 21 of the narrowest gap (preferably 100 to 500 mm) between the guide members 16 and 16 are substantially coincident with each other. It is desirable that it is within 10%, particularly within 5% of the diameter.

 実施例は流体が海水であることから、環境面において非常に腐食性が高い。金属の場合は、チタンなどの高級材質を使う必要がある。エアリフトポンプは回転部が無いため、すべて樹脂製で対応が可能であることも特徴の一つである。また、稼働に必要な動力はエアであり、実施例では前段で大量のエアを必要とする。エアリフトポンプは、前段で使うエアの圧力よりも低い値で対応できる、また、絶対量においても前段のごく一部を使うことで運転でき、設備面・動力面でも他の方式に比べ大変優位なプロセスである。 In the example, the fluid is seawater, so it is very corrosive in terms of environment. In the case of metal, it is necessary to use a high-grade material such as titanium. Since the air lift pump does not have a rotating part, it is one of the features that it can be made entirely of resin. Further, the power necessary for operation is air, and in the embodiment, a large amount of air is required in the previous stage. The air lift pump can be operated at a value lower than the air pressure used in the previous stage, and can be operated by using a small part of the previous stage in absolute quantity, and is extremely superior in terms of equipment and power compared to other systems. Is a process.

 他方、エアリフト装置を、海水の流れの幅方向に複数設けるのが処理量を多くするために望ましい。 On the other hand, it is desirable to provide a plurality of air lift devices in the width direction of the seawater flow in order to increase the processing amount.

 この場合、図3に示すように、各エアリフト装置30の排出を共通排出水路45に連結し、排出する泡やスカム流れを集合ピット46に案内して、その集合した泡やスカムをシャワーリングや機械的な泡除去手段により一括処理する(処理形態例は図示していない)ことができる。なお、集合ピット46と海水路を隔てる壁の下方には、開口を設け、集合ピット内の海水を海水路内に放流するようにしてもよい。また、集合ピット46には、必要に応じて同様のエアリフト装置30を必要台数設置し、別途設けられた貯留槽や。遠心分離機などの脱泡装置に移送し、完全に海水とスカムまたは泡分とに分離し、海水を海に戻し、スカムまたは泡分を乾燥し、廃棄することができる。 In this case, as shown in FIG. 3, the discharge of each air lift device 30 is connected to a common discharge water channel 45, the discharged bubbles and scum flow are guided to the collecting pit 46, and the collected bubbles and scum are shown in the shower ring or Batch processing (examples of processing forms are not shown) can be performed by mechanical foam removing means. An opening may be provided below the wall separating the collective pit 46 and the seawater channel so that the seawater in the collective pit is discharged into the seawater channel. In addition, a necessary number of similar air lift devices 30 are installed in the collective pit 46 as necessary, and a separate storage tank is provided. It can be transferred to a defoaming device such as a centrifuge and completely separated into seawater and scum or foam, the seawater can be returned to the sea, and the scum or foam can be dried and discarded.

 支持体20は、流通開口21を形成する利点に加えて、ガイド部材16及びエアリフト装置の構成部材の少なくとも一部を支持することができる。 The support body 20 can support at least a part of the constituent members of the guide member 16 and the air lift device in addition to the advantage of forming the flow opening 21.

 次に第2の実施形態を図9、10に図示する。
この実施形態におけるエアリフト装置は図3及び図6と同様であるが、エアリフト装置30から排出される処理液の排出先を、排出水路42Aを介して、海水路12に返送する点が異なる。スカム量が少ない場合には、一時貯留部40で泡およびスカムが処理しきれるため、本実施形態のようにそのまま海水路に返送することが可能となる。返送先としては、堰32の上流側海水路12でも下流側海水路12でも良いが、スカム量の変動を考慮すると上流側海水路12が特に好ましい。さらに、海水路への放流口を海水面より高い位置に設けるとよい。このような構造にすることで、水面上に浮遊する泡やスカム上に処理液が放流されるため、消泡効果を得ることが可能となる。ところで本実施形態では、堰32周囲の水面に流出防止部材50設けた。流出防止部材50は、オイルフェンスのような構造であり、流通開口21側に開口されている。流出防止部材50を設けることで、堰32で回収しきれなかった泡やスカムが下流に流出することを防ぐ効果がある。
Next, a second embodiment is illustrated in FIGS.
The air lift device in this embodiment is the same as that shown in FIGS. 3 and 6, except that the discharge destination of the processing liquid discharged from the air lift device 30 is returned to the seawater channel 12 via the discharge water channel 42A. When the amount of scum is small, since the bubbles and scum can be completely processed by the temporary storage unit 40, it can be returned as it is to the seawater channel as in this embodiment. The return destination may be the upstream seaway 12 or the downstream seaway 12 of the weir 32, but the upstream seaway 12 is particularly preferable in consideration of fluctuations in the amount of scum. Furthermore, it is good to provide the outlet to a sea channel in the position higher than a sea surface. By adopting such a structure, since the treatment liquid is discharged onto bubbles or scum floating on the water surface, an antifoaming effect can be obtained. By the way, in this embodiment, the outflow prevention member 50 is provided on the water surface around the weir 32. The outflow prevention member 50 has a structure like an oil fence, and is opened on the flow opening 21 side. Providing the outflow prevention member 50 has an effect of preventing bubbles and scum that cannot be collected by the weir 32 from flowing out downstream.

 第3の実施形態を図11に図示する。
 この実施形態では、水路幅方向に直列に複数のエアリフト装置30,30・・・が設けられている。エアリフト装置と接続された排出路42に連結された排出水路42Bの排出口を、接続元のエアリフト装置30の列とは異なるエアリフト装置の上流側に配置したことを特徴とする。さらに最も水路壁側のエアリフト装置の排出水路42を、排出口42Cを介して泡処理設備やピット46に連結して処理することが好ましい。この構成によれば、処理液による消泡効果を得られるとともに、エアリフト装置30で処理しきれなかった泡やスカムを最終的に海水路外へ排出することが可能となる。
A third embodiment is illustrated in FIG.
In this embodiment, a plurality of air lift devices 30, 30... Are provided in series in the water channel width direction. The discharge port of the discharge water passage 42 </ b> B connected to the discharge passage 42 connected to the air lift device is arranged on the upstream side of the air lift device different from the row of the connection source air lift devices 30. Furthermore, it is preferable that the discharge water channel 42 of the air lift device closest to the water channel wall is connected to the foam treatment facility or the pit 46 through the discharge port 42C for processing. According to this configuration, it is possible to obtain a defoaming effect by the processing liquid and finally discharge bubbles and scum that could not be processed by the air lift device 30 to the outside of the seawater channel.

 本発明は、火力発電所から排出される煙道ガス中のSO2を、排煙脱硫設備で吸収した際に発生するような廃水の廃水処理に利用することができる。 INDUSTRIAL APPLICABILITY The present invention can be used for wastewater treatment of wastewater generated when SO 2 in flue gas discharged from a thermal power plant is absorbed by a flue gas desulfurization facility.

10 廃水
12 海水路
14 散気管
20 支持体
21 流通開口
30 エアリフト装置
32 堰
34 導入路
36 揚水路
38 エア吹込み手段
40 一時貯留部
42 排水水路
DESCRIPTION OF SYMBOLS 10 Wastewater 12 Seawater channel 14 Aeration pipe 20 Support body 21 Distribution opening 30 Air lift device 32 Weir 34 Introduction channel 36 Pumping channel 38 Air blowing means 40 Temporary storage part 42 Drainage channel

Claims (11)

 排気ガス中の硫黄酸化物を海水に吸収させ、除去する排煙脱硫設備において、吸収済み海水を放流する海水路の海水面に浮遊する泡またはスカムのうち少なくとも一方を捕集処理する処理設備であって、
 上方開口の堰を上端部に有し海水中に没する導入路と、この導入路と連結し、海水中と海水面上にわたる揚水路と、揚水路内下部にエアを送給するエア吹込み手段とでエアリフト装置を構成し、
 海水の流れの中に、堰を設置するとともにその堰の流入開口をほぼ海水面に位置させ、
 海水面に浮遊する泡やスカムのうち少なくとも一方を前記堰の流入開口からエアリフト装置に捕集し、前記揚水路を介して海水の流れ外に導くようにしたことを特徴とする排煙脱硫設備における廃水処理設備。
In a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas, it is a processing facility that collects at least one of bubbles or scum floating on the sea surface of the seawater channel that discharges absorbed seawater. There,
An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway The air lift device with the means,
Install a weir in the flow of seawater and locate the inflow opening of the weir almost on the sea surface.
A flue gas desulfurization facility characterized in that at least one of bubbles and scum floating on the seawater surface is collected by an air lift device from the inflow opening of the weir and led out of the flow of seawater through the pumping channel. Wastewater treatment equipment in
 前記堰に対して海水流れの上流側に位置に、下流に向かって狭まるガイド部材を設け、このガイド部材によって流れが狭まった位置に前記堰が設けられている請求項1記載の排煙脱硫設備における廃水処理設備。 The flue gas desulfurization equipment according to claim 1, wherein a guide member that narrows toward the downstream is provided at a position upstream of the seawater flow with respect to the weir, and the weir is provided at a position where the flow is narrowed by the guide member. Wastewater treatment equipment in  前記堰は、流入開口の上縁より高く延在する仕切り壁を有し、前記流入開口と仕切り壁との境界は、堰の中心より海水の流れの上流側に位置しており、前記境界と堰中心を結ぶ線の平面視での開き角度は、60~120度である請求項1記載の排煙脱硫設備における廃水処理設備。 The weir has a partition wall that extends higher than the upper edge of the inflow opening, and the boundary between the inflow opening and the partition wall is located upstream of the center of the weir from the flow of seawater, The wastewater treatment facility in a flue gas desulfurization facility according to claim 1, wherein an opening angle of the line connecting the weir centers in a plan view is 60 to 120 degrees.  前記堰は導入路と別体であり、前記堰には浮きが一体となり、海水面の上下に応じて前記堰は導入路に沿って上下可能とされている請求項1記載の排煙脱硫設備における廃水処理設備。 The flue gas desulfurization equipment according to claim 1, wherein the weir is separate from the introduction path, and the floating is integrated with the weir, and the weir can be moved up and down along the introduction path according to the sea level. Wastewater treatment equipment in  前記揚水路の上部にこれと連通する一時貯留部を設け、一時貯留部には泡やスカムを含む液を流下させる下り傾斜の排出水路が連通して設けられている請求項1記載の排煙脱硫設備における廃水処理設備。 The flue gas according to claim 1, wherein a temporary storage portion communicating with the temporary storage portion is provided at an upper portion of the pumping passage, and a downward inclined discharge water passage for allowing liquid containing bubbles and scum to flow down is provided in communication with the temporary storage portion. Wastewater treatment equipment in desulfurization equipment.  前記揚水路の上部にこれと連通する一時貯留部を設け、一時貯留部には外気と連通するエア排気口が形成され、前記揚水路上端開口に対向して上方に衝突部が設けられ、さらに前記一時貯留部には泡やスカムを含む液を流下させる下り傾斜の排出水路が連通して設けられている請求項1記載の排煙脱硫設備における廃水処理設備。 A temporary storage unit communicating with the upper portion of the pumping channel is provided, an air exhaust port communicating with the outside air is formed in the temporary storage unit, a collision unit is provided above the upper opening of the pumping channel, and The waste water treatment facility in a flue gas desulfurization facility according to claim 1, wherein a downward sloping drainage channel for allowing a liquid containing foam and scum to flow down is communicated with the temporary storage unit.  前記排出水路の出口は、前記堰に対して海水流れの上流側の海水路内または下流側の海水路上に設けられている請求項6記載の排煙脱硫設備における廃水処理設備。 The wastewater treatment facility in the flue gas desulfurization facility according to claim 6, wherein the outlet of the discharge channel is provided in the sea channel on the upstream side of the sea water flow or on the downstream sea channel with respect to the weir.  排気ガス中の硫黄酸化物を海水に吸収させ、除去する排煙脱硫設備において、吸収済み海水を放流する海水路の海水面に浮遊する泡やスカムを捕集処理する処理設備であって、
 上方開口の堰を上端部に有し海水中に没する導入路と、この導入路と連結し、海水中と海水面上にわたる揚水路と、揚水路内下部にエアを送給するエア吹込み手段とで構成したエアリフト装置を、海水の流れの幅方向に複数設け、
 海水の流れの中に、堰をそれぞれ設置するとともにその堰の流入開口をほぼ海水面に位置させ、
 海水面に浮遊する泡やスカムを前記堰の流入開口からエアリフト装置に捕集し、前記揚水路を介して海水の流れ外に導くようにしたことを特徴とする排煙脱硫設備における廃水処理設備。
In a flue gas desulfurization facility that absorbs and removes sulfur oxides in exhaust gas, it is a processing facility that collects bubbles and scum floating on the sea surface of the sea channel that discharges the absorbed sea water,
An inlet passage that has an upper opening weir at the upper end and is submerged in seawater, and an air blower that is connected to this introduction passage and feeds air into the seawater and the seawater surface, and to the lower part of the waterway A plurality of air lift devices composed of means in the width direction of the flow of seawater,
Each weir is installed in the flow of seawater and the inflow opening of the weir is positioned almost on the seawater surface.
Wastewater treatment equipment in flue gas desulfurization equipment, wherein bubbles and scum floating on the seawater surface are collected by an air lift device from the inflow opening of the weir and guided out of the flow of seawater through the pumping channel .
 各エアリフト装置の揚水路を通して排出する泡やスカム流れを集合ピットに案内して、その集合した泡やスカムを一括処理するように構成した請求項8記載の排煙脱硫設備における廃水処理設備。 The wastewater treatment facility in the flue gas desulfurization facility according to claim 8, wherein the foam and scum flow discharged through the pumping path of each airlift device is guided to the collective pit and the collected foam and scum are collectively processed.  前記堰に対して海水流れの上流側に位置に、各堰を通る海水流れ線を挟んだ左右に、下流に向かって狭まる一対のガイド部材を設け、この一対のガイド部材によって流れが狭まった位置に前記堰が設けられている請求項8記載の排煙脱硫設備における廃水処理設備。 Positions on the upstream side of the seawater flow with respect to the weir, a pair of guide members that narrow toward the downstream on both sides of the seawater flow line that passes through each weir, and positions where the flow is narrowed by the pair of guide members The wastewater treatment facility in the flue gas desulfurization facility according to claim 8, wherein the weir is provided in the wastewater desulfurization facility.  海水路の途中に、海水深さ途中から海面上に延在する支持体を幅方向に渡って設け、この支持体にこれを貫いて、幅方向に間隔を置いて複数の流通開口を形成し、
 各流通開口の海水流れの上流側に位置に、各流通開口を通る海水流れ線を挟んだ左右に、下流に向かって狭まる一対のガイド部材をそれぞれ設け、
 各流通開口の海水流れの下流側に位置に、前記エアリフト装置の堰を設けてある請求項8記載の排煙脱硫設備における廃水処理設備。
 
In the middle of the sea channel, a support body extending over the sea surface from the middle of the seawater depth is provided across the width direction, and a plurality of flow openings are formed through the support body at intervals in the width direction. ,
At the upstream side of the seawater flow of each circulation opening, a pair of guide members that narrow toward the downstream are provided on the left and right sides of the seawater flow line passing through each circulation opening,
The wastewater treatment facility in the flue gas desulfurization facility according to claim 8, wherein a weir of the air lift device is provided at a position downstream of the seawater flow of each circulation opening.
PCT/JP2011/071367 2011-09-20 2011-09-20 Waste water treatment equipment in flue gas desulfurization facility Ceased WO2013042197A1 (en)

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