WO2012123391A1 - Récipients en polyester partiellement cristallisé - Google Patents
Récipients en polyester partiellement cristallisé Download PDFInfo
- Publication number
- WO2012123391A1 WO2012123391A1 PCT/EP2012/054216 EP2012054216W WO2012123391A1 WO 2012123391 A1 WO2012123391 A1 WO 2012123391A1 EP 2012054216 W EP2012054216 W EP 2012054216W WO 2012123391 A1 WO2012123391 A1 WO 2012123391A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- flange
- container
- polyester
- container according
- μιη
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
- B65D85/72—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for edible or potable liquids, semiliquids, or plastic or pasty materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
- B65D77/10—Container closures formed after filling
- B65D77/20—Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
- B65D77/2024—Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers the cover being welded or adhered to the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/04—Combined thermoforming and prestretching, e.g. biaxial stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/003—PET, i.e. poylethylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/02—Open containers
- B32B2439/06—Bags, sacks, sachets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2577/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks, bags
- B65D2577/10—Container closures formed after filling
- B65D2577/20—Container closures formed after filling by applying separate lids or covers
- B65D2577/2025—Multi-layered container, e.g. laminated, coated
Definitions
- the present invention relates to packages for products, preferably food products, comprising in particular clear polyester containers having a crystallized portion of the flange with good sealability to a top web.
- the resultant package has a neat, clear appearance which is more attractive to the final consumer.
- a product support member i.e. a container or a tray
- a cavity formed therein to accomodate the product and a flange around the perimeter of the member to be lidded, and the tray and the lid are not made by the same material causing recycling problems.
- a generally known process to form a polyester tray includes extruding a polyester sheet in amorphous phase and subsequently crystallizing the whole tray by using a two stage mold, one hot for crystallization and the other cold for cooling down the article.
- US 4,374,800 relates to a PAT (Polyalkylene terephthalate) container including a body portion of at least 20% of crystallinity, a flange having a crystallinity lower than that of the body, adjoined to the body portion.
- PAT Polyalkylene terephthalate
- EP 0 605 081 relates to a food package, comprising a crystalline opaque or colored tray thermoformed from a nucleated PET sheet which remains rigid at elevated temperature, and a transparent cover in an amorphous state connected to the tray.
- GB 2 205 063 relates to a PET container having different degrees of crystallization in different regions of the article to ensure best functionality, the different degree of crystallization of the tray is obtained using a special mold at different heating region without using nucleating agents.
- US 2007/0082151 relates to a polyester container with a flange with a projecting portion, which exhibits low-temperature heat sealability.
- object of the present invention is a clear multilayer polyester container comprising a base and upwardly extending side walls terminating in a continuous flange projecting from the side walls, said multilayer container comprising at least an inner layer of an amorphous polyester and a bulk outer layer comprising a polyester in admixture with a nucleating agent, said bulk outer layer being crystallized in at least one portion of said flange.
- the term “inner layer” means the layer of the container that will be in contact with the content of the container or in alternative that part of the container that comes in contact with the forming plug of the mold; in Figure 1 the “inner layer” is indicated by (1.1), the crystallized portion of the flange and the bulk outer layer are indicated by (1.2) and (1.3), respectively.
- a container according to the present invention wherein said bulk outer layer is continuosly crystallized all along the flange is particularly preferred.
- the container is a double-layer or tri-layer container.
- the inner layer is in the amorphous phase and the crystallized portion of the flange is in the other outer layer.
- the inner layer is in the amorphous phase and the crystallized portion of the flange is preferably in the intermediate bulk layer.
- the third outermost layer is preferably amorphous, being the nucleating agent preferably in the second layer.
- the portion of the bulk outer layer of the flange is crystallized while the other parts of the same, i.e. of the side walls and of the bottom part of the container, remain in amorphous phase, i.e. with a crystallinity percentage lower than 10%.
- the polymers used in the present invention are clear amorphous thermoplastic polymers that can be injection molded or sheet extruded.
- polyesters such as, for example polyethylene terephthalate (PET), polylactic acid (PLA), polyethylene terephthalate - glycol (PETG).
- the polymer used in the present invention is PET or PETG.
- the inner layer remains amorphous during the crystallization of the flange so it can easily seal to a top lid using conventional sealing system, such as sealing bars.
- the bulk outer layer(s) comprising the nucleating agent can be crystallized in the flange part of the container, for example by using the mold showed in Figure 2.
- the nucleating agent used to promote crystallization is contained in the bulk outer layer of the container and preferably only the flange portion is crystallized.
- nucleating agents which can be used in the container according to the present application and nucleating agent known in the art and commercially available, are:
- alkali metal salts of organic acids e.g. carboxylic acid; sodium, lithium, potassium benzoates
- organic acids e.g. carboxylic acid
- sodium, lithium, potassium benzoates see D. Garcia, Heterogeneous nucleation of PET, J. of Polymer Science - Polymer physics edition, Vol 22, 2063-2072, 1984 and R. Legras, C. Bailly, M. Daumerie, V.
- the nucleating agent preferably used in the present invention is commercially available as Tna S471 by Sukano ® .
- the amount of nucleating agent generally depends on the type of polyester used. According to the conventional practice, the nucleating agent is generally used in an amount of from 2% to 5%, more preferably from 2.5% to 4%, even more preferably of 3%.
- the nucleating agents have a particle size not higher than 10 microns.
- the containers object of the present invention can be manufactured, for example, according to a process comprising the following steps:
- the crystallization of the flange is therefore selectively guaranteed by the heating provided on the flange using, for instance, a mold similar to the mold showed in Figure 2.
- the heating can be provided using a mold at different heating zones in order to crystallize only a portion of the flange or preferably the entire flange.
- the percentage of crystallization in the bulk outer layer outside the flange remains lower than the percentage of crystallization of the flange or portions of the flange.
- the crystallization of flange may take place, preferably, in a forming mold but also outside a mold.
- the percentage of crystallization of the flange or portion of the flange is equal to or higher than about 10%, preferably higher than 12%, more preferably higher than 15%.
- the crystallization of the flange takes place by heating the bulk outer layer generally at a temperature of from 270°C to 300°C, preferably at 275°C for a time comprised between 5 seconds and 10 seconds, preferably between 6 seconds and 8 seconds.
- the heat transfer takes place by conduction, induction or convection systems.
- the flange, after heating, can be cooled if needed.
- the flange has a thickness ranging from 100 ⁇ to 1000 ⁇ , preferably from 200 ⁇ to 700 ⁇ , more preferably from 300 ⁇ to 600 ⁇ .
- the container object of the present invention having the nucleating agent contained into the whole bulk outer layer, can also be crystallized if needed, in other portions but preferably only the flange is crystallized, thus providing the optical and mechanical properties needed i.e. more rigidity of the flange, transparency of the container and good sealability to the top lid.
- the container of the present invention with the crystallized flange withstands the force imparted by the shrinking of lidding films and resists to deformations .
- the present container is also suitable for tray lidding applications with non shrinkable films.
- the container according to the present invention can be loaded with the product and then closed with a suitable top web by using a lidding machine which is characterized by a sealing bar operating at adequate temperature to get the seal.
- the temperature of the sealing bar depends on the type of lidding film used and the sealing operation can be carried out both under clean and contaminated conditions.
- the packages so obtained, further object of the present invention have a particulary good appearance.
- said packages, having the container and the lid the same polymeric composition are really advantageous in the step of recycling. Furthermore it is possible to manufacture them by using recycled polyester. Examples
- a three-layer container (sample 1) in which the flange has a total thickness of 520 ⁇ is formed using a mold as showed in Figure 2.
- the inner layer is made of 100% PETG 6763 by Eastman Chemical and has a thickness of 100 ⁇ .
- the second layer is made of 97% PETG Ramapet 9921W by Indorama and 3% of nucleating agent Tna S471 by Sukano ® and has a thickness of 320 ⁇ .
- the third layer is made of 97% PETG Ramapet 9921W by Indorama and 3% of nucleating agent Tna S471 by Sukano ® and has a thickness of 100 ⁇ .
- Sample 1 is tested in order to evaluate the variability of crystallinity and is tested after flange conditioning at different temperatures for different times.
- the areas of the flange were selected and submitted to the thermal analysis that showed 12% of crystallinity, by conditioning the sample at 275 °C for 6 seconds.
- the crystallinity of the flange is higher than the crystallinity of the container which is 2.45%.
- Figure 1 represents a two layers container (1.0) according to the present invention.
- the inner layer (1.1) is in the amorphous phase while the bulk outer layer has two portions at different degrees of crystallization: the area of the crystallized flange (1.2) and the remaining area of the polyester in the amorphous state (1.3).
- Figure 2 represents the forming process used to provide the container according to the present invention.
- the polyester film (2.1) is inserted into the female mold which comprises the cooled part
- the polyester film (2.1) adheres to the female mold due to the vacuum applied (2.5), while the forming plug (2.4) pushes the polyester film (2.1) in the female mold, providing the final container.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Laminated Bodies (AREA)
Abstract
L'invention porte sur un récipient en polyester transparent (1.0) qui comprend une base et des parois latérales s'étendant vers le haut et se terminant par un rebord continu qui fait saillie à partir des parois latérales. Ledit récipient multicouche comprend une couche intérieure (1.1) dans une phase amorphe et une couche extérieure comprenant un agent de nucléation dans la composition du polymère, de manière à être cristallisé dans au moins une partie du rebord.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12708327.7A EP2686153A1 (fr) | 2011-03-15 | 2012-03-12 | Récipients en polyester partiellement cristallisé |
| NZ615366A NZ615366B2 (en) | 2011-03-15 | 2012-03-12 | Partially crystallized polyester containers |
| US14/005,016 US20140001074A1 (en) | 2011-03-15 | 2012-03-12 | Partially Crystalized Polyester Containers |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11158187.2 | 2011-03-15 | ||
| EP11158187 | 2011-03-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2012123391A1 true WO2012123391A1 (fr) | 2012-09-20 |
Family
ID=44650674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2012/054216 Ceased WO2012123391A1 (fr) | 2011-03-15 | 2012-03-12 | Récipients en polyester partiellement cristallisé |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20140001074A1 (fr) |
| EP (1) | EP2686153A1 (fr) |
| WO (1) | WO2012123391A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140275999A1 (en) * | 2013-03-15 | 2014-09-18 | Devicor Medical Products, Inc. | Biopsy device |
| EP3222405A1 (fr) * | 2016-03-24 | 2017-09-27 | Nakamoto Packs Co., Ltd. | Procédé de fabrication d'un récipient résistant à la chaleur |
| US20210002018A1 (en) * | 2019-06-04 | 2021-01-07 | Silver Plastics Gmbh & Co. Kg | Packaging tray with a profiled sealing edge |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3745979B1 (fr) | 2018-01-29 | 2025-11-19 | Bard Access Systems, Inc. | Système de connexion pour établir une connexion électrique à travers un champ et méthodes associées |
| EP3793464A4 (fr) | 2018-05-18 | 2021-07-21 | Bard Access Systems, Inc. | Systèmes de connexion et procédés associés pour établir une connexion électrique à travers un champ |
| EP3996571A4 (fr) | 2019-07-12 | 2023-06-28 | Bard Access Systems, Inc. | Système de suivi et de positionnement de cathéter comprenant un réseau de diodes électroluminescentes |
| WO2021026502A1 (fr) | 2019-08-08 | 2021-02-11 | Bard Access Systems, Inc. | Modules de connecteur de fibres optiques comprenant des systèmes de détection de forme et procédés associés |
| JP7184469B2 (ja) * | 2020-11-09 | 2022-12-06 | Nissha株式会社 | 紙シートの嵌合方法および紙成形品 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3761450A (en) | 1969-09-11 | 1973-09-25 | Hoechst Ag | Salts of polycarboxylic acids as nucleating agents in polyesters |
| EP0021648A1 (fr) | 1979-06-19 | 1981-01-07 | Imperial Chemical Industries Plc | Compositions de polyester à vitesse de cristallisation élevée |
| US4374800A (en) | 1981-03-18 | 1983-02-22 | The Goodyear Tire & Rubber Company | Method for making an article of partially crystalline organic resin |
| GB2205063A (en) | 1987-05-22 | 1988-11-30 | Clarke R & Co Ltd | Moulded plastics articles |
| EP0605081A1 (fr) | 1992-12-30 | 1994-07-06 | Welex Incorporated | Cuvette pour aliments et méthode de fabrication |
| US5356972A (en) | 1992-07-29 | 1994-10-18 | Istituto Guido Donegani S.P.A. | Nucleating agents for poly(ethylene terephthalate) |
| US20050037168A1 (en) * | 1999-12-02 | 2005-02-17 | Associated Packaging Enterprises, Inc. | Thermoformed food trays having improved toughness |
| US20070082151A1 (en) | 2003-04-11 | 2007-04-12 | Toyo Seikan Kaisha Ltd. | Polyester container, method for manufacturing the same, and method for sealing polyester container |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4545848A (en) * | 1982-11-08 | 1985-10-08 | Mcdonnell Douglas Corporation | HCT Crystal growth method |
| US4540038A (en) * | 1984-06-05 | 1985-09-10 | Westinghouse Electric Corp. | Method for production of combustion turbine blade having a hybrid structure |
| US4803088A (en) * | 1985-05-01 | 1989-02-07 | House Food Industrial Company Limited | Container packed with instant food for use in microwave oven |
| US5039001A (en) * | 1990-06-18 | 1991-08-13 | Kraft General Foods, Inc. | Microwavable package and process |
| US6429402B1 (en) * | 1997-01-24 | 2002-08-06 | The Regents Of The University Of California | Controlled laser production of elongated articles from particulates |
| US20050131522A1 (en) * | 2003-12-10 | 2005-06-16 | Stinson Jonathan S. | Medical devices and methods of making the same |
| US8129007B2 (en) * | 2006-02-16 | 2012-03-06 | Cryovac, Inc. | Coextruded heat-shrinkable polyester film |
| JP5465239B2 (ja) * | 2008-05-29 | 2014-04-09 | シーメンス アクチエンゲゼルシヤフト | 耐熱超合金から成るワークを溶接する方法と装置 |
-
2012
- 2012-03-12 WO PCT/EP2012/054216 patent/WO2012123391A1/fr not_active Ceased
- 2012-03-12 EP EP12708327.7A patent/EP2686153A1/fr not_active Withdrawn
- 2012-03-12 US US14/005,016 patent/US20140001074A1/en not_active Abandoned
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3761450A (en) | 1969-09-11 | 1973-09-25 | Hoechst Ag | Salts of polycarboxylic acids as nucleating agents in polyesters |
| EP0021648A1 (fr) | 1979-06-19 | 1981-01-07 | Imperial Chemical Industries Plc | Compositions de polyester à vitesse de cristallisation élevée |
| US4374800A (en) | 1981-03-18 | 1983-02-22 | The Goodyear Tire & Rubber Company | Method for making an article of partially crystalline organic resin |
| GB2205063A (en) | 1987-05-22 | 1988-11-30 | Clarke R & Co Ltd | Moulded plastics articles |
| US5356972A (en) | 1992-07-29 | 1994-10-18 | Istituto Guido Donegani S.P.A. | Nucleating agents for poly(ethylene terephthalate) |
| EP0605081A1 (fr) | 1992-12-30 | 1994-07-06 | Welex Incorporated | Cuvette pour aliments et méthode de fabrication |
| US20050037168A1 (en) * | 1999-12-02 | 2005-02-17 | Associated Packaging Enterprises, Inc. | Thermoformed food trays having improved toughness |
| US20070082151A1 (en) | 2003-04-11 | 2007-04-12 | Toyo Seikan Kaisha Ltd. | Polyester container, method for manufacturing the same, and method for sealing polyester container |
Non-Patent Citations (4)
| Title |
|---|
| D. GARCIA: "Heterogeneous nucleation of PET", J. OF POLYMER SCIENCE - POLYMER PHYSICS EDITION, vol. 22, 1984, pages 2063 - 2072 |
| J. OF APPLIED POLYMER SCIENCE, vol. 36, 1988, pages 387 - 402 |
| R. LEGRAS; C. BAILLY; M. DAUMERIE; V. ZICHY: "Chemical nucleation, a new concept applied to mechanism of action of organic acid salts on the crystallization of PET and bisphenol-A-polycarbonate", POLYMER, vol. 25, 1984, pages 835 - 844 |
| See also references of EP2686153A1 |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140275999A1 (en) * | 2013-03-15 | 2014-09-18 | Devicor Medical Products, Inc. | Biopsy device |
| JP2016515872A (ja) * | 2013-03-15 | 2016-06-02 | デヴィコア メディカル プロダクツ, インク.Devicor Medical Products, Inc. | バイオプシー装置 |
| US9877706B2 (en) * | 2013-03-15 | 2018-01-30 | Devicor Medical Products, Inc. | Biopsy device |
| US10413280B2 (en) | 2013-03-15 | 2019-09-17 | Devicor Medical Products, Inc. | Biopsy device |
| KR102057322B1 (ko) * | 2013-03-15 | 2019-12-19 | 데비코어 메디컬 프로덕츠, 인코포레이티드 | 생검 디바이스 |
| EP3222405A1 (fr) * | 2016-03-24 | 2017-09-27 | Nakamoto Packs Co., Ltd. | Procédé de fabrication d'un récipient résistant à la chaleur |
| CN107225783A (zh) * | 2016-03-24 | 2017-10-03 | 中本包装株式会社 | 制造耐热的容器的方法 |
| KR20170113261A (ko) * | 2016-03-24 | 2017-10-12 | 나카모토팍쿠스가부시키가이샤 | 내열 용기의 제조 방법 |
| TWI705927B (zh) * | 2016-03-24 | 2020-10-01 | 日商中本包裝股份有限公司 | 製造耐熱性容器之方法 |
| KR102270904B1 (ko) | 2016-03-24 | 2021-07-01 | 나카모토팍쿠스가부시키가이샤 | 내열 용기의 제조 방법 |
| US20210002018A1 (en) * | 2019-06-04 | 2021-01-07 | Silver Plastics Gmbh & Co. Kg | Packaging tray with a profiled sealing edge |
| US12319465B2 (en) * | 2019-06-04 | 2025-06-03 | Silver Plastics Gmbh | Packaging tray with a profiled sealing edge |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ615366A (en) | 2015-04-24 |
| US20140001074A1 (en) | 2014-01-02 |
| EP2686153A1 (fr) | 2014-01-22 |
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