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WO2012119811A2 - Composition - Google Patents

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Publication number
WO2012119811A2
WO2012119811A2 PCT/EP2012/051262 EP2012051262W WO2012119811A2 WO 2012119811 A2 WO2012119811 A2 WO 2012119811A2 EP 2012051262 W EP2012051262 W EP 2012051262W WO 2012119811 A2 WO2012119811 A2 WO 2012119811A2
Authority
WO
WIPO (PCT)
Prior art keywords
dye
reactive
hair
polymer
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/051262
Other languages
English (en)
Other versions
WO2012119811A3 (fr
Inventor
Stephen Norman Batchelor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hindustan Unilever Ltd
Unilever NV
Original Assignee
Hindustan Unilever Ltd
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hindustan Unilever Ltd, Unilever NV filed Critical Hindustan Unilever Ltd
Publication of WO2012119811A2 publication Critical patent/WO2012119811A2/fr
Publication of WO2012119811A3 publication Critical patent/WO2012119811A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4966—Triazines or their condensed derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/101—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing an anthracene dye
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/106—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing an azo dye
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/108—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing a phthalocyanine dye
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/109—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing other specific dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances

Definitions

  • the present invention relates to a hair care composition comprising a polymer dye, and a method for dying the hair using said composition.
  • FR 2 456 764 discloses quaternary amine polymer linked to dyes for the colouration of hair. The dyes used do not carry negatively charged substituents.
  • US 4 228 259 discloses a dye for keratinic material comprises a water- soluble cationic polymer.
  • WO2008/009579 (Ciba) and WO2009/090121 to WO2009/090125 (BASF) disclose cationic dyes covalently linked to polymers for the colouration of hair.
  • compositions comprising a positively charged polymer covalently bound to a negatively charged reactive dye.
  • the present invention provides a kit for colouring hair comprising at least two parts; i) a first composition comprising an oxidising agent;
  • first composition and/or the second composition and/or an additional third composition further comprises a polymer dye comprising a positively charged polymer covalently bound to a negatively charged reactive dye.
  • the invention provides a method for dying hair comprising the steps of applying to the hair the compositions within the kit as described in any one of the previous claims.
  • composition of the invention comprises a polymer dye comprising a positively charged polymer covalently bound to a negatively charged reactive dye.
  • a hydrolysed reactive dye is one in which the reactive groups has reacted with the hydroxide anion, HO " , rather than the polymer.
  • a reactive dye that has two reactive groups, where one reactive group has reacted with the polymer to form a covalent bond and one reactive group has reacted with HO " is not classed as a hydrolysed reactive dye in the context of the invention.
  • Equally a reactive dye that has three reactive groups where one or two reactive groups have reacted with the polymer to form covalent bonds and one or two reactive groups have reacted with HO " is not classed as a hydrolysed reactive dye in the context of the reaction.
  • a hydrolysed dye has no covalent bond to the polymer.
  • composition of the invention preferably comprise less than 100ppm of hydrolysed reactive dye per l OOOOppm of dye polymer, more preferably less than 50ppm, most preferably less than 5ppm. Most preferably hydrolysed reactive dyes are not present in the composition. Such dyes may be removed by dialysis or careful control of the reactions conditions.
  • a reactive dye that has two reactive groups, where one has reacted with the polymer to form a covalently bond and one has reacted with HO " is not classed as a hydrolysed dye in the context of the invention.
  • the total kit comprises from 0.2 to 10wt% of dye polymer, most preferably from 0.5 to 3wt% of the dye polymer.
  • the dye polymer may be present in one or more than one parts of the kit, however it is preferable if the dye polymer is only present in one part of the kit.
  • Reactive dye Reactive dyes are described in Industrial Dyes (K. Hunger ed, Wiley VCH 2003). Many Reactive dyes are listed in the colour index (Society of Dyers and Colourists and American Association of Textile Chemists and Colorists).
  • Reactive groups are preferably selected from heterocyclic reactive groups and, a sulfooxyethylsulfonyl reactive group (-SO 2 CH 2 CH 2 OSO 3 Na), which is converts to a vinylsulfone in alkali.
  • the heterocyclic reactive groups are preferably nitrogen contains aromatic rings bound to a halogen or an ammonium group or a quaternary ammonium group, which react with NH 2 or NH groups of the polymers to form a covalent bonds.
  • the halogen is preferred, most preferably CI or F.
  • the reactive dye comprises a reactive group selected from
  • dichlorotriazinyl difluorochloropynmidine, monofluorotrazinyl, dichloroquinoxahne, vinylsulfone, difluorotriazine, monochlorotriazinyl, bromoacrlyamide and
  • the reactive group may be linked to the dye chromophore via an alkyl spacer for example: dye-NH-CH 2 CH 2 -reactive group.
  • Especially preferred heterocylic reactive groups are
  • Ri is selected from H or alkyl, preferably H.
  • X is selected from F or CI
  • Z 1 is selected from -CI, -NR 2 R 3 , -OR 2 , -S0 3 Na
  • R 2 and R 3 are independently selected from H, alkyl and aryl groups.
  • Aryl groups are preferably phenyl and are preferably substituted by -S0 3 Na or - S0 2 CH 2 CH 2 OS0 3 Na.
  • Alkyl groups are preferably methyl or ethyl.
  • the phenyl groups may be further substituted with suitable uncharged organic groups, preferably with a molecular weight lower than 200.
  • Preferred groups include -CH 3 , -C 2 H 5 , and -OCH 3.
  • the alkyl groups may be further substituted with suitable uncharged organic groups, preferably with a molecular weight lower than 200.
  • Preferred groups include -CH 3 , -C 2 H 5 , -OH, -OCH 3 , -OC 2 H 4 OH.
  • Most preferred heterocylic reactive groups are selected from
  • n 1 or 2, preferably 1 .
  • the reactive dye contains more than one reactive group, preferably two or three.
  • the reactive dye comprises a chromophore selected from azo, anthraquinone, phthalocyanine, formazan and triphendioaxazine.
  • a chromophore selected from azo, anthraquinone, phthalocyanine, formazan and triphendioaxazine.
  • the dye is an azo dye it is preferred that the azo dye is not an azo-metal complex dye.
  • the level of polyamine in the reaction solution is preferable from 2 to 50wt%, more preferably from 5 to 20wt%. These conditions minimise the production of hydrolysed dye.
  • reactive dyes include reactive black 5, reactive blue 19, reactive red 2, reactive blue 171 , reactive blue 269, reactive blue 1 1 , reactive yellow 17, reactive, reactive orange 4, reactive orange 16, reactive green 19, reactive brown 2, reactive brown 50.
  • Reactive blue dyes are preferably selected from anthraquinone, mono azo, bis- azo, triphenodioxazine, and phthalocyanine, more preferably anthraquinone, bis- azo, and triphenodioxazine, most preferably bis-azo and triphenodioxazine.
  • a preferred blue bis-azo dye is of the form
  • a and B rings are substituted by a reactive group.
  • the A and B rings may be further substituted by sulphonate groups (SOsNa).
  • SOsNa sulphonate groups
  • the A and B rings may be further substituted with suitable uncharged organic groups, preferably with a molecular weight lower than 200.
  • Preferred uncharged organic groups are -CH 3 , -C2H5, and -OCH3 .
  • a preferred blue anthraquinone dye is of the form
  • the dye may be further substituted with sulphonate groups (SOsNa) and suitable uncharged organic groups, preferably with a molecular weight lower than 200.
  • SOsNa sulphonate groups
  • suitable uncharged organic groups are-CH 3 , -C2H5, and -OCH3.
  • a preferred blue triphenodioxazine dye is of the form
  • D and E rings are substituted by a reactive groups.
  • D and E rings are further substituted by sulphonate groups (SOsNa).
  • reactive blue dyes are reactive blue 2, reactive blue 4, reactive blue 5, reactive blue 7, reactive blue 15, reactive blue 19, reactive blue 27, reactive blue 29, reactive blue 49, reactive blue 50, reactive blue 74, reactive blue 94, reactive blue 246, reactive blue 247, reactive blue 247, reactive blue 166, reactive blue 109, reactive blue 187, reactive blue 213, reactive blue 225, reactive blue 238, reactive blue 256. Further structures are exemplified below:
  • Reactive Red dyes are preferably selected from mono-azo and bis-azo dyes.
  • a preferred reactive red azo dye is of the form
  • F ring is optionally extended to form a naphthyl group and is optionally substituted by groups selected from sulphonate groups (SOsNa) and a reactive group.
  • SOsNa sulphonate groups
  • G is selected from a reactive group, H, or alky group.
  • a reactive group must be present on the dye.
  • reactive red dyes examples include reactive red 2, reactive red 3, reactive red 4, reactive red 8, reactive red 9, reactive red 12, reactive red 13, reactive red 17, reactive red 22 .reactive red 24, reactive red 29, reactive red 33 reactive red 139, reactive red 198 and reactive red 141 .
  • Reactive yellow and orange dyes are preferably selected from mono-azo dyes.
  • Examples of reactive yellow and orange dyes are reactive yellow 1 , reactive yellow 2, reactive yellow 3, reactive yellow 16, reactive yellow 17, reactive yellow 25 , reactive yellow 39, reactive orange 107, reactive yellow 176 and reactive yellow 135.
  • Combination of reactive dyes may be used to obtain a wide colour palette with use of a limited number of dyes.
  • a trichromate system consisting of a mixture of three reactive dyes.
  • the trichromate system contains a combination of a reactive blue or a reactive black dye, a reactive red and a reactive yellow dye.
  • reactive black 5, reactive yellow 176 and reactive red 239; reactive blue 171 , reactive yellow 176 and reactive red 141 .
  • each polymer molecule should be covalently bound to at least one dye molecule, preferably more than two.
  • if more than one colour is present for example a reactive red and a reactive blue, they are preferably bound to the same polymer backbone.
  • the dye polymer is obtainable by reacting the polymer with from 0.1 to 20wt% reactive dye, most preferably from 1 to 10wt%.
  • the polymer comprises a free -SH, -OH, -NH or -NH 2 group for reaction with the dye. More preferably, the polymer contains at least one -NH or -NH 2 group, most preferably at least five -NH or -NH 2 group.
  • the polymers have an overall cationic charged at pH 5.0.
  • the polymer comprises quaternary amine groups or tertiary amines.
  • polymers examples include polyethyleneimine, polypropylene- imine, polyvinylamine; polyvinylimine, aminosilcone.
  • the polymer before reaction with the dye, has a weight averaged molecular weight of from 500 to 1000 000, preferably from 800 to 60 000, most preferably from 800 to 2500.
  • the molecular weights are determined by dynamic light scattering using a Zetasizer Nano (Malvern).
  • the polymer is a polyamine.
  • the polyamine is selected from polyethyleneimine, polypropylene- imine, polyvinylamine, and polyvinylimine.
  • Polyamines are polyalkyl amines and are generally linear or branched.
  • the polyamine comprises primary, secondary or tertiary amines or a mixture thereof.
  • the polyamine comprises ethylene alkyl groups and the polymer is formed by ring opening polymerisation of ethyleneimine to provide polyethyleneimine (PEI). PEI is most preferred.
  • the polyamines are alkoxylated to provide alkoxylated PEI's, for example ethoxylated polyethyleneimine (EPEI).
  • EPEI ethoxylated polyethyleneimine
  • a single or a number of amine functions are reacted with one or more alkylene oxide groups to form a polyalkylene oxide side chain.
  • the alkylene oxide can be a homopolymer (for example ethylene oxide) or a random or block copolymer.
  • the PEI's suitable for use in the composition of the invention can have the general formula: (-NHCH2CH2-) X [-N(CH2CH2NH2)CH2CH2-I y wherein x is an integer from about 1 to about 120000, preferably from about 10 to about 20000, more preferably from about 20 to about 10000 and y is an integer from about 1 to about 60000, preferably from about 10 to about 30000, more preferably from about 20 to about 12000.
  • polyethylene imines are PEI-300, PEI-500, PEI 600, PEI- 700, PEI- 800, PEI-1000, PEI-1500, PEI-1800, PEI-2000, PEI-2500, PEI-5000, PEI-10000, PEI-25000, PEI 50000 and PEI-70000, wherein the integer represents the number average molecular weight of the polymer.
  • PEI's which are designated as such are available through Aldrich.
  • the PEI is partially alkoxylated so that at least one NH 2 or NH is available for reaction with the reactive dye, preferably at least one NH 2 .
  • the preferred degree of alkoxylation is from 0.2 to 50% of the primary and secondary amines are alkoxylated.
  • the kit of the invention comprises of a least two parts. It is preferable if the parts of the of kit are mixed on the hair or before shortly (10 minutes or less) application to the head.
  • the pH of the resulting composition is from 6 to 12, preferably from 8 to 10.5 (at 20°C).
  • the present invention provides a kit for colouring hair comprising at least two parts:
  • a first part comprising an oxidising agent compsirinig hydrogen peroxide
  • a second part comprising an alkalinity agent
  • first part and/or the second part and/or an additional third part further comprises a polymer dye comprising a positively charged polymer covalently bound to a negatively charged reactive dye.
  • kits comprising two parts, the first part comprising hydrogen peroxide/hydrogen peroxide generator and the polymer dye, the second part comprising an alkalinity agent.
  • a second preferred embodiment of the invention comprises a kit comprising two parts, the first part comprising alkalinity agent and the polymer dye, the second part comprising hydrogen peroxide/ hydrogen peroxide generator.
  • a third embodiment comprises a kit of three parts; first part comprising an alkalinity agent, the second part the polymer dye, the third part comprising the hydrogen peroxide/ hydrogen peroxide generator.
  • the hydrogen peroxide/hydrogen peroxide generator is not in the same part as the alkalinity agent.
  • At least one composition within the kit further comprises a conditioning active such as a cationic surfactant or silicone, fatty alcohol, fatty acid, fatty ester, fatty amide or mixtures thereof.
  • a conditioning active such as a cationic surfactant or silicone, fatty alcohol, fatty acid, fatty ester, fatty amide or mixtures thereof.
  • the kit of the invention comprises an alkalinity agent.
  • Suitable alkalinity agents include ammonium hydroxide, ethylamine, dipropylamine, triethylamine and alkanediamines such as 1 ,3- diaminopropane, anhydrous alkaline alkanolamines such as, mono or di- ethanolamine, preferably those which are completely substituted on the amine group such as dimethylaminoethanol, polyalkylene polyamines such as diethylenetriamine or a heterocyclic amine such as mocpholine as well as the hydroxides of alkali metals, such as sodium and potassium hydroxide, hydroxides of alkali earth metals, such as magnesium and calcium hydroxide, basic amino acids such as L-alginine, lysine, oxylysine and histidine and alkanolamines such as dimethylaminoethanol and
  • aminoalkylpropanediol and mixtures thereof.
  • compounds that form HC03- by dissociation in water hereinafter referred to as 'ion forming compounds'.
  • suitable ion forming compounds are Na2C03, NaHC03, K2C03, (NH4)2C03, NH4HC03, CaC03 and Ca(HC03) and mixtures thereof.
  • the dye polymer may also be used to add alkalinity, an additional alkalinity agent is required.
  • Ammonium hydroxide is highly preferred.
  • the kit comprises an oxidizing agent.
  • the oxidizing agent is preferably in only one composition of the kit.
  • Suitable oxidizing agents include hydrogen peroxide, alkali metal bromate, sodium perborate, urea peroxide, sodium percarbonate, sodium peroxytripolyphosphate, sodium peroxypyrophosphate, sodium peroxyorth ophosphate, sodium silicate/ hydrogen peroxide addition products, sodium sulphate/sodium chloride/ hydrogen peroxide addition products.
  • Hydrogen peroxide and alkali metal bromates are preferred, hydrogen peroxide being particularly preferred.
  • the composition comprising the oxidising agent is present as an aqueous solution.
  • the level of oxidising agent within the composition is from 0.1 to 30wt%, preferably from 2 to 10wt%. These levels are particularly relevant with respect to hydrogen peroxide.
  • the composition comprising hydrogen peroxide has a pH in the range from 2 to 4 at 20°C.
  • the pH adjustment to 2 to 4 can be effected by using acidifying agents such as hydrochloric acid, tartaric acid, citric acid, phosphoric acid and carboxylic or sulphonic acids such as ascorbic acid, acetic acid, lactic acid, sulphuric acid, formic acid, ammonium sulphate and sodium dihydrogenphosphate /phosphoric acid, disodium hydrogenphosphate /phosphoric acid, potassium chloride
  • acidifying agents such as hydrochloric acid, tartaric acid, citric acid, phosphoric acid and carboxylic or sulphonic acids such as ascorbic acid, acetic acid, lactic acid, sulphuric acid, formic acid, ammonium sulphate and sodium dihydrogenphosphate /phosphoric acid, disodium hydrogenphosphate /phosphoric acid, potassium chloride
  • /hydrochloric acid potassium dihydrogen phthalate/ hydrochloric acid, sodium citrate / hydrochloric acid, potassium dihydrogen citrate /hydrochloric acid, potassium dihydrogencitrate/ citric acid, sodium citrate / citric acid, sodium tartarate/ tartaric acid, sodium lactate/ lactic acid, sodium acetate/ acetic acid.
  • Phosphoric acid is a preferred agent for buffering hydrogen peroxide solutions.
  • composition comprising the oxidizing agent particularly if it is hydrogen peroxide further comprises a heavy metal sequestrant.
  • Heavy metal ion sequestrants are preferably present at a level of from about 0.005% to about 20%, preferably from about 0.01 % to about 10%, more preferably from about 0.05% to about 2% by weight of the compositions.
  • compositions of the present invention are formulated into hair colouring compositions which may take a variety of forms, including, for example, mousses, gels, lotions, creams, sprays and tonics. These product forms are well known in the art.
  • the preferred product is a lotion, cream, spray, aerosol mousse or gel.
  • the composition is a rinse off hair treatment composition.
  • a rinse off composition is applied hair preferably to wet hair, and left on the hair for up to I hour, preferably left on the hair for up to 30 minutes before it is removed by rinsing.
  • the method of application is to apply the contents of the kit to hair preferably to wet hair.
  • compositions of the kit may be added sequentially to the hair but are preferably mixed immediately (within 10 minutes) before application to the hair.
  • the composition is left on the hair for up to 60 minutes, more preferably up to 30 minutes before it is removed by rinsing.

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  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Birds (AREA)
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  • Cosmetics (AREA)

Abstract

Trousse pour colorer les cheveux comprenant au moins deux parties ; iii) une première composition comprenant un agent oxydant ; iv) une deuxième composition comprenant un agent d'alcalinité, la première composition et/ou la deuxième composition et/ou une troisième composition supplémentaire comprenant un colorant polymère constitué d'un polymère à charge positive lié par covalence à un colorant réactif à charge négative.
PCT/EP2012/051262 2011-03-10 2012-01-26 Composition Ceased WO2012119811A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11157580 2011-03-10
EP11157580.9 2011-03-10

Publications (2)

Publication Number Publication Date
WO2012119811A2 true WO2012119811A2 (fr) 2012-09-13
WO2012119811A3 WO2012119811A3 (fr) 2013-08-29

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AR (1) AR085707A1 (fr)
WO (1) WO2012119811A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9949543B2 (en) 2014-10-29 2018-04-24 Noxell Corporation Hair colouration, method and kit thereof
US9949542B2 (en) 2014-10-29 2018-04-24 Noxell Corporation Hair colouration, method and kit thereof
US10689801B2 (en) 2014-04-22 2020-06-23 Millikan & Company Colored coatings and artificial leathers containing colorant complexes
US20220118647A1 (en) * 2019-01-11 2022-04-21 Debal Coatings Method and kit for treating wood with red undertones
WO2022112876A1 (fr) * 2020-11-24 2022-06-02 Agf88 Holding Srl Procédé de coloration/décoloration et traitement général des cheveux

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Publication number Priority date Publication date Assignee Title
US4182612A (en) 1977-01-31 1980-01-08 The Gillette Company Method for dyeing human hair with cationic polymeric dyes
US4228259A (en) 1976-08-12 1980-10-14 L'oreal Water-soluble cationic polymer dye compounds and process for producing the same
FR2456764A2 (fr) 1979-05-18 1980-12-12 Oreal Nouveaux polymeres colorants, leur preparation et leur utilisation
WO2008009579A1 (fr) 2006-07-18 2008-01-24 Ciba Holding Inc. Colorants polymères pour cheveux
WO2009090121A1 (fr) 2008-01-17 2009-07-23 Basf Se Colorants capillaires polymères
WO2009090125A1 (fr) 2008-01-17 2009-07-23 Basf Se Colorants capillaires polymères
WO2011113680A2 (fr) 2010-03-19 2011-09-22 Unilever Plc Composition

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FR2421607A1 (fr) * 1978-04-06 1979-11-02 Oreal Procede de teinture des fibres keratiniques en deux temps par variation de ph
FR2882929B1 (fr) * 2005-03-14 2008-02-22 Oreal Procede de coloration des cheveux a partir d'un polymere colore anionique

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Publication number Priority date Publication date Assignee Title
US4228259A (en) 1976-08-12 1980-10-14 L'oreal Water-soluble cationic polymer dye compounds and process for producing the same
US4182612A (en) 1977-01-31 1980-01-08 The Gillette Company Method for dyeing human hair with cationic polymeric dyes
FR2456764A2 (fr) 1979-05-18 1980-12-12 Oreal Nouveaux polymeres colorants, leur preparation et leur utilisation
WO2008009579A1 (fr) 2006-07-18 2008-01-24 Ciba Holding Inc. Colorants polymères pour cheveux
WO2009090121A1 (fr) 2008-01-17 2009-07-23 Basf Se Colorants capillaires polymères
WO2009090125A1 (fr) 2008-01-17 2009-07-23 Basf Se Colorants capillaires polymères
WO2011113680A2 (fr) 2010-03-19 2011-09-22 Unilever Plc Composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"Industrial Dyes", 2003, WILEY VCH

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10689801B2 (en) 2014-04-22 2020-06-23 Millikan & Company Colored coatings and artificial leathers containing colorant complexes
US9949543B2 (en) 2014-10-29 2018-04-24 Noxell Corporation Hair colouration, method and kit thereof
US9949542B2 (en) 2014-10-29 2018-04-24 Noxell Corporation Hair colouration, method and kit thereof
US10681971B2 (en) 2014-10-29 2020-06-16 Noxell Corporation Hair colouration, method and kit thereof
US10687594B2 (en) 2014-10-29 2020-06-23 Noxell Corporation Hair colouration, method and kit thereof
US20220118647A1 (en) * 2019-01-11 2022-04-21 Debal Coatings Method and kit for treating wood with red undertones
WO2022112876A1 (fr) * 2020-11-24 2022-06-02 Agf88 Holding Srl Procédé de coloration/décoloration et traitement général des cheveux

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