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WO2012118495A2 - Supports récepteurs d'impression et procédés associés - Google Patents

Supports récepteurs d'impression et procédés associés Download PDF

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Publication number
WO2012118495A2
WO2012118495A2 PCT/US2011/026724 US2011026724W WO2012118495A2 WO 2012118495 A2 WO2012118495 A2 WO 2012118495A2 US 2011026724 W US2011026724 W US 2011026724W WO 2012118495 A2 WO2012118495 A2 WO 2012118495A2
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WO
WIPO (PCT)
Prior art keywords
print
receptive
microns
value
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2011/026724
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English (en)
Other versions
WO2012118495A3 (fr
Inventor
Haochuan Wang
Thomas Mammen
Arthur G. Castillo
Frank Yen-Jer Shih
Anahit Tataryan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avery Dennison Corp
Original Assignee
Avery Dennison Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avery Dennison Corp filed Critical Avery Dennison Corp
Priority to PCT/US2011/026724 priority Critical patent/WO2012118495A2/fr
Publication of WO2012118495A2 publication Critical patent/WO2012118495A2/fr
Publication of WO2012118495A3 publication Critical patent/WO2012118495A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
    • G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
    • G03G7/0013—Inorganic components thereof
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
    • G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
    • G03G7/002—Organic components thereof
    • G03G7/0026—Organic components thereof being macromolecular
    • G03G7/004—Organic components thereof being macromolecular obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
    • G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
    • G03G7/002—Organic components thereof
    • G03G7/0026—Organic components thereof being macromolecular
    • G03G7/0046—Organic components thereof being macromolecular obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

Definitions

  • the present invention relates generally to electrophotographic printing and relates more particularly to print-receptive media for use in electrophotographic printing.
  • the three principal types of printing devices used for printing text, graphics, or images that are used in the home, at school, or in the workplace are electrophotographic printers, inkjet printers, and hot-melt printers. Of these various types of printers,
  • electrophotographic printers which include, for example, laser printers, LED printers, and copying machines, dominate the market share for office printing/copying, and are also becoming more affordable and attractive to home and school users.
  • the electrophotographic process is typically as follows: First, a negative electrostatic charge is uniformly distributed over the surface of a rotatable cylinder 2, often referred to as "the daini," the daini rotating at the speed of paper output. See Fig. 1.
  • the aforementioned electrostatic charge can be applied to the daini by contacting the daini with a charged contact roller 4.
  • the matter to be printed is imaged onto the surface of the rotating daini usually with a laser 6. Where there is an image on the daini, the charge is dissipated, and where there is no image on the daini, the charge on the daini remains.
  • the rotating daini is brought into contact with a developer roller 8 carrying a negatively charged toner mixture.
  • the developer roller baishes the toner mixture onto the daini, with the toner mixture coating the uncharged areas of the daini through electrostatic attraction.
  • a sheet of print-receptive medium 10 for example, a sheet of paper, coated paper, film, coated film, laminates of paper and film, address labels, file folder labels, stickers, and other labels, business cards, greeting cards, name badges, or tent cards, etc., is typically passed between the daini and a transfer roller 12, the transfer roller applying a charge to the print-receptive niedium that is opposite to that of the toner mixture, whereby the toner image is transferred, through pressure and electrostatic attraction, from the daini to the print-receptive medium.
  • the daini After contacting the print-receptive medium, the daini is typically cleaned of any remaining toner using a rotating baish under suction or a cleaner blade 14.
  • the toner image previously transferred from the daini to the print-receptive medium is then permanently fixed to the print-receptive medium using a heat and pressure mechanism or a radiant fusing technology to melt and to bond the toner particles to the print-receptive medium.
  • the electrophotographic process is also described in U.S. Patent Number 5, 185,496 to Nishimura, et al, which is incorporated herein in its entirety.
  • toner particles tend to accumulate along the entire path taken by the print-receptive medium 10.
  • small toner particles can remain on the daini 2 after passing the baish or cleaner blade 14.
  • some of the accumulated toner particles can transfer to, and eventually become fused with, the print-receptive medium.
  • imprinted areas where imprinted areas are those areas not intended to be printed upon in a given pass through the printer, acquire a grayish or otherwise discolored appearance. This effect is not too noticeable in those instances in which the print-receptive medium passes through the printer only one time.
  • the term plurality means two or more.
  • Multiple passing, also known as re-feeding, of the print-receptive medium can take place, for example, when the print-receptive medium includes a matrix of cards or labels arranged on a common sheet and one wishes to print onto only some of the cards or labels at one time, saving the remainder of the cards or labels for printing in one or more subsequent passes through the printer. Consequently, where, for example, a matrix of labels is arranged on a common sheet, and a user prints onto only one label with each pass through the printer, the discoloration on the imprinted, remaining labels can be quite pronounced after several such passes through the printer.
  • the present invention includes a print-receptive medium including a print- receptive surface.
  • the print-receptive surface having a plurality of peaks and a plurality of valleys.
  • the print-receptive surface also has a primary profile that includes a mean surface.
  • Each of the plurality of peaks has a height measured from the mean surface, and each of the valleys has a depth measured from the mean surface.
  • the plurality of peaks has a mean peak height, Ppni, and the plurality of valleys has a mean valley depth, Pvni.
  • the primary profile of the print-receptive surface has a value of Ppm-Pvm greater than about 0.23 micron.
  • the primary profile of the print-receptive surface has a value of Ppm-Pvm greater than or equal to about 0.51 micron. In other, more detailed features of the invention, the primary profile of the print-receptive surface has a value of Ppm-Pvm ranging from about 0.51 micron to about 6.35 microns.
  • the print-receptive medium includes a print-receptive surface having a primary bearing ratio at threshold 5 microns.
  • the primary bearing ratio at threshold 5 microns of the print-receptive surface has a value less than about 7.1 1%.
  • the primary bearing ratio at threshold 5 microns of the print-receptive surface has a value less than or equal to about 1.51%.
  • the primary bearing ratio at threshold 5 microns of the print-receptive surface has a value less than or equal to about 1.51% and a value of Ppm-Pvm greater than or equal to about 0.96 micron.
  • the primary bearing ratio at threshold 5 microns of the print-receptive surface has a value ranging from about 0.66 % to about 1.51% and a value of Ppm-Pvm ranging from about 0.96 micron to about 4.76 microns.
  • the print-receptive medium includes a print-receptive surface having a AE * a b value.
  • the value of ⁇ is less than about 1.68 after ten passes through an electrophotographic printer.
  • the value of AE * a b is less than or equal to about 1.32 after ten passes through an electrophotographic printer. In other, more detailed features of the invention, the value of AE * a b ranges from about 0.64 to about 1.32 after ten passes through an electrophotographic printer.
  • the print-receptive medium includes a coating.
  • the print-receptive surface is formed on the coating.
  • the coating includes about 100 parts by weight of polyvinyl acetate, up to about 55 parts by weight of polyamide, up to about 105 parts by weight of silica, about 8.75 parts by weight sodium chloride, and up to about 7.25 parts by weight of a thickener.
  • the coating includes about 13.12 parts by weight to about 105 parts by weight of silica.
  • the print-receptive surface has a primary high spot count, PHSC, value, and the PHSC value is less than about 2.71 peaks/mm.
  • the PHSC value is less than or equal to about 1.63 peaks/mm and the value of Ppm-Pvm is greater than or equal to about 0.51 micron.
  • the PHSC ranging from about 0.34 peaks/mm to about 1.63 peaks/mm and the value of Ppm-Pvm ranges from about 0.51 micron to about 6.35 microns.
  • the present invention also includes a method for forming a print-receptive medium including a print-receptive surface.
  • the method includes providing a substrate having a coating surface, providing a coating mixture, coating the mixture onto the coating surface, and drying the coating mixture.
  • the dried coating mixture forms the print-receptive surface having a plurality of peaks and a plurality of valleys.
  • the print-receptive surface has a primary profile that includes a mean surface.
  • Each of the plurality of peaks has a height measured from the mean surface, and each of the valleys has a depth measured from the mean surface.
  • the plurality of peaks has a mean peak height, Ppni, and the plurality of valleys has a mean valley depth, Pvni.
  • the primary profile of the print-receptive surface has a value of Ppm-Pvm greater than about 0.23 micron.
  • FIG. 1 is a schematic view of an electrophotographic printer mechanism
  • FIGs. 2(a) and 2(b) are top and side views, respectively, of a first embodiment of a print-receptive medium constaicted according to the present invention
  • FIGs. 3(a) and 3(b) are top and side views, respectively, of a second embodiment of a print-receptive medium constaicted according to the present invention.
  • FIG. 4 is a side view of a third embodiment of a print-receptive medium constaicted according to the present invention.
  • FIG. 5 is a side view of a fourth embodiment of a print-receptive medium constaicted according to the present invention.
  • Fig. 6 is a graph of a primary profile of the print-receptive surface of an embodiment of the present invention.
  • Fig. 7 is a graph of Abbott-Firestone curve of the print-receptive surface of an embodiment of the present invention
  • Fig. 8 is an illustration showing the relationship between a raw surface profile, a primary profile, a roughness profile, and a smoothness profile of a surface
  • Fig. 9 is graph showing the relationship between a mean surface and a surface profile having a sine wave profile
  • Fig. 10 is a graph showing the relationship between a mean surface and a surface profile having a sine wave profile where the valleys of the sine wave have been stretched;
  • Fig. 1 1 is a graph showing the relationship between the mean surface and a surface profile having a sine wave profile where the peaks of the sine wave have been stretched;
  • Fig. 12 is a graph of a primary profile of the print-receptive surface of an embodiment of the present invention showing a bearing ratio at threshold z;
  • Fig. 13 is a schematic view of a sheet of print-receptive medium of the present invention in contact with a printer daini;
  • Fig. 14 is a plot of Pa values against the primary bearing ratio at 5 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 15 is a plot of the average Pa values against the average primary bearing ratio at 5 microns values for Textured Samples, Laser Samples, Inkjet Samples, and
  • Fig. 16 is a plot of the Pa values against the primary bearing ratio at 10 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 17 is a plot of the average Pa values against the average primary bearing ratio at 10 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 18 is a plot of the Ppm-Pvm values against the primary bearing ratio at 5 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 19 is a plot of the average Ppm-Pvm values against the average primary bearing ratio at 5 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 20 is a plot of the Ppm-Pvm values against the primary bearing ratio at 10 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 21 is a plot of the average Ppm-Pvm values against the average primary bearing ratio at 10 microns values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 22 is a plot of the average Ppm-Pvm values against the average Pa values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 23 is a plot of the primary high spot count values against the Ppm-Pvm values for Textured Samples, Laser Samples, Inkjet Samples, and Exemplary Samples;
  • Fig. 24 is a flowchart of a method according to the present invention for forming a print-receptive medium embodiment
  • Fig. 25 is a flowchart of an alternative method according to the present invention for forming a print-receptive medium embodiment
  • Fig. 26 is a plot of the AE * a b values against the average primary bearing ratio at
  • Fig. 27 is a plot of the AE * a b values against the average primary bearing ratio at
  • Fig. 28 is a plot of the AE * a b values against the average Ppm-Pvm values for
  • Fig. 29 is a plot of the AE * a b values against the average Pa values for Textured
  • the present invention is embodied in print-receptive media, and related methods, that include a print-receptive surface.
  • Print-receptive media come in a multitude of configurations. A few non-limiting examples of print-receptive media are discussed below.
  • the present invention is based, at least in part, on the surprising discovery that the undesired graying or other discoloration of print-receptive media in imprinted areas following passage of the print-receptive media through an electrophotographic printer, particularly following multiple passages of the print-receptive media through the
  • electrophotographic printer can be reduced by reducing the surface area of the print-receptive media exposed to the daini 2, based on the surface profile of the print-receiving surface of the print-receptive medium.
  • Print-receptive media can take various physical forms. For example, referring now to Figs. 2(a) and 2(b), there are shown top and side views, respectively, of a first embodiment of a print-receptive medium constaicted according to the teachings of the present invention, the print-receptive medium being represented generally by reference numeral 9. (For simplicity and clarity, only some of the print-receptive surface of print-receptive medium 1 1 is shown in Figs. 2(a) and 2(b).)
  • Print-receptive medium 1 1 can include a unitary sheet of material, which can be, for example, a paper or an opaque, clear, or translucent polymeric film.
  • Print-receptive medium 1 1 can have a top surface 13 and a bottom surface 15.
  • Top surface 13 and bottom surface 15 can be provided with a plurality of peaks 17 and valleys 19, which can be made, for example, by embossing or calendaring. The peaks 17 and valleys 19 endowing top surface 13 and bottom surface 15 with the desired print-receptive surface described below.
  • print-receptive medium 1 1 can be fed into an electrophotographic printer, with either top surface 13 or bottom surface 15 being used as the print-receiving surface.
  • top surface 13 and bottom surface 15 of print-receptive medium 1 1 are constaicted to provide the desired surface roughness, one could modify print-receptive medium 1 1 so that only one of top surface 13 and bottom surface 15 possesses such surface roughness.
  • FIGs. 3(a) and 3(b) there are shown top and side views, respectively, of a second embodiment of a print-receptive medium constaicted according to the teachings of the present invention, said print-receptive medium being represented generally by reference numeral 101.
  • reference numeral 101 For simplicity and clarity, only some of the print- receptive surface of print-receptive medium 101 is shown in Figs. 3(a) and 3(b).
  • Print-receptive medium 101 can include a substrate 103, which can be, for example, a paper or an opaque, clear, or translucent polymeric film. Substrate 103 can have a top surface 105 and a bottom surface 107. Print-receptive medium 101 can further include a coating 109 applied to top surface 105 of substrate 103. Coating 109, which can have a composition as described below and which can be formed as described below, is shaped to include a plurality of peaks 1 1 1 and valleys 1 13 to endow print-receptive medium 101 with the above-described desired surface roughness.
  • print-receptive medium 101 can be fed into an electrophotographic printer, with coating 109 preferably being used as the print-receiving surface.
  • Fig. 4 there is shown a side view of a third embodiment of a print-receptive medium constaicted according to the teachings of the present invention, the print-receptive medium being represented generally by reference numeral 301. (For simplicity and clarity, only some of the print-receptive surface of print-receptive medium 301 is shown in Fig. 4).
  • Print-receptive medium 301 can include a carrier 303 which can be, for example, a paper backing, a polymeric film, or another suitable material.
  • a release coating 305 can be applied to the top surface of carrier 303.
  • Print-receptive medium 301 can further include a plurality of print-receiving members 307 removably positioned on top of release coating 305, the number, size, and shape of print-receiving members 307 shown being merely illustrative.
  • Each member 307 can be a pressure-sensitive adhesive label that can include a substrate 309, a print-receiving coating 31 1, and a pressure-sensitive adhesive 313, coating 31 1 being applied to the top surface of substrate 309 and adhesive 313 being applied to the bottom surface of substrate 309.
  • Substrate 309 can be identical to substrate 103 of print- receptive medium 101
  • coating 31 1 can be identical to coating 109 of print-receptive medium 101.
  • substrate 309 and coating 31 1 can be replaced with a staicture identical to print-receptive medium 1 1.
  • adjacent members 307 can be coupled to one another only through carrier 303; however, print-receptive medium 301 can be modified so as to directly couple together adjacent members 307, for example, through perforations or otherwise.
  • print-receptive medium 301 can be fed into an electrophotographic printer, with coatings 31 1 preferably being used as the print-receiving surfaces. If desired, print-receptive medium 301 can be passed through an electrophotographic printer, with printing applied to only some of members 307. Such printed-upon members 307 can then be detached from the remainder of print-receptive medium 301, and the remainder of print- receptive medium 301 can then be passed one or more times through the printer for printing onto some of the remaining members 307. [0058] Referring now to Fig.
  • FIG. 5 there is shown a side view of a fourth embodiment of a print-receptive medium constaicted according to the teachings of the present invention, said print-receptive medium being represented generally by reference numeral 401. (For simplicity and clarity, only some of the print-receptive surface of print-receptive medium 401 is shown in Fig. 5.)
  • Print-receptive medium 401 can include a carrier 403 which can be, for example, a paper backing, a polymeric film, or another suitable material.
  • Print-receptive medium 401 can further include a plurality of print-receiving members 405, the number, size, and shape of print-receiving members 405 shown being merely illustrative.
  • Each member 405 can be a card and can include a substrate 409 and a print-receiving coating 41 1, coating 41 1 being applied to the top surface of substrate 409.
  • Substrate 409 can be identical to substrate 103 of print-receptive medium 101, and coating 41 1 can be identical to coating 109 of print-receptive medium 101.
  • Print-receptive medium 401 can further include a layer of adhesive 413 removably adhering members 405 to carrier 403.
  • Adhesive 413 can be a dry-tack adhesive, i.e., not tacky at room temperature, or a removable or ultraremovable adhesive. In this manner, after a member 405 has been removed from carrier 403, the adhesive will remain with carrier 403, will remain on member 405, or can split, with a portion on carrier 403 and a portion on member 405.
  • the carrier can be a breakable film directly attached, without adhesive 413, to the carrier such that the members can be broken apart.
  • print-receptive medium 401 can be fed into an electrophotographic printer, with coatings 41 1 preferably being used as the print-receiving surfaces. If desired, print-receptive medium 401 can be passed through an electrophotographic printer, with printing applied to only some of members 405. Such printed-upon members 405 can then be detached from the remainder of print-receptive medium 401, and the remainder of print- receptive medium 401 can then be passed one or more times through the printer for printing onto some of the remaining members 405.
  • Fig. 6 is a graph of a primary profile (described below) of the print-receptive surface of an embodiment of the present invention.
  • the print-receptive surface can characterized as including peaks 20, also known as protaisions, and valleys 22.
  • each peak and valley can be further characterized by its height h or depth d as measured from the mean surface 28 (described below), width w, shape, and spacing s. Additional information about the print-receptive surface can be obtained by examining the Abbott- Firestone curve, or bearing ratio curve, (see Fig.
  • Tp% (ASME B46.1-2002), also known as the bearing length ratio) 34 as a function of depth z as measured from the highest peak.
  • One method of characterizing the print-receptive surface profile is by using a surface profilometer.
  • One type of profilometer (DEKTAK 8
  • Spacing of the peaks can be determined by counting the number of peaks that extend above a specified depth as measured from the highest peak.
  • One method of counting the number of peaks is by using the high spot count (HSC).
  • the high spot count is defined as the number of peaks that project through a plane parallel to the mean surface at a selected distance from the mean surface.
  • PHSC is the number of peaks that project through a plane parallel to the mean surface of the primary profile at a distance of 5 microns from the mean surface. Smaller numbers indicate that the projecting peaks are spaced further apart than the peaks of a profile resulting in larger numbers.
  • all of the print-receptive surface parameters can be obtained in varying directions, for example, measurements can be obtained in a direction perpendicular to the leading edge 9 (Fig. 1) of the print-receptive medium.
  • the print-receptive surface parameters can also be obtained in a direction parallel to the leading edge of the print- receptive medium. These directions are orthogonal to one another.
  • the direction perpendicular to the leading edge of the print-receptive medium is referred to as the machine direction or MD.
  • the direction parallel to the leading edge of the print-receptive medium is referred as the cross direction or CD.
  • the surface profile 44 can be broken into two components, specifically, the roughness profile 46 and the waviness profile 48. See Fig. 8.
  • the roughness profile contains short-wavelength, high-frequency deviations from a mean, or average, surface 28.
  • the mean surface is average height value of all the points on the particular profile of interest normalized to 0.
  • the peak heights 24 are deviations from the niean surface in the direction away from the medium and the valley depths 26 are deviations from the mean surface in the direction toward the medium.
  • the waviness profile contains long-wavelength, low-frequency deviations from the mean surface.
  • a cutoff wavelength, or filter specifies the wavelength that separates the roughness profile and the waviness profile. It should be noted that print-receptive surface parameters can be obtained for the primary profile, the roughness profile, and the waviness profile. Parameters that begin with "P,” for example Pp, are derived from the primary profile, while those that begin with "R” or “W” are from the roughness profile or the waviness profile, respectively.
  • Pp 38 is the height, above the mean surface 28, of the highest peak in the primary profile 44.
  • Pv 40 is the depth, below the mean surface, of the deepest valley in the primary profile. Both Pp and Pv are reported as positive numbers.
  • Pa is the arithmetic-mean deviation of the surface from the mean surface 28 in the primary profile 44. It is determined by averaging the absolute value of the difference of each point on the primary profile from the mean surface. Doubling the Pa value provides an estimate of the average depth from a peak to a valley.
  • Ppni and Pvni are parameters determined by TRUESURF (ISO 13565-3 using the primary profile) and are the mean peak height and mean valley depth, respectively, based on the primary profile 44. Both are reported as positive numbers measured from the mean surface 28.
  • a positive value for Ppm-Pvm indicates that the peaks 20 are taller 24 than the valleys 22 are deep 26, and that the peaks are narrower than the valleys.
  • a negative value for Ppm-Pvm indicates that the peaks are shorter than the valleys are deep, and the peaks are wider than the valleys.
  • the value of Ppm-Pvm can be used to determine whether the surface can be thought of as evenly rough, a relatively smooth surface with peaks, or a relatively smooth surface with valleys.
  • the mean surface 50 which is the arithmetic mean of all the points, is the midpoint between the heights 52 of the peaks 54 and the depths 56 of the valleys 58.
  • the peaks are as high above the mean surface as the valleys are deep below the mean surface, resulting in an evenly rough surface.
  • Ppm-Pvm 0.
  • the regular sine wave were stretched such that only the valley portions were widened 61, as shown in Fig. 10, and the distance between the highest peak and the lowest valley is unchanged, the mean surface 60 would shift toward the valleys 68, since now there are more valley surface points.
  • the peaks 64 would be higher 62 above the mean surface and the valleys would be less deep 66 compared to the regular sine wave surface.
  • the surface would appear more like a relatively smooth surface with peaks.
  • the surface can be thought of as having, on average, peaks that are narrower than the valleys. In this instance Ppm-Pvm>0.
  • the regular sine wave were stretched such that only the peak portions were widened 71, as shown in Fig. 1 1, and the distance between the highest peak and the lowest valley is unchanged, the mean surface 70 would shift toward the peaks 74, since now there are more peak surface points.
  • the peaks would be less high 72 above the mean surface and the valleys 78 would be deeper 76 compared to the regular sine wave surface.
  • the surface would appear more like a relatively smooth surface with valleys.
  • the surface can be thought of as having, on average, peaks that are wider than the valleys are narrow. In this instance Ppm-Pvm ⁇ 0.
  • the slicing plane just touches the floor of the deepest valley and the fraction of material at the slicing plane is 100%.
  • the fraction of material at depth z is defined as the bearing ratio at threshold z.
  • a surface with a smaller bearing ratio has narrower peaks on average than a surface with a higher bearing ratio, assuming the number of peaks is approximately the same.
  • Toner used in electrophotographic printing devices is generally in a dry, particulate form. Toner was obtained from an HP LASERJET 1320 printer cartridge (Hewlett-Packard Company, Palo Alto, California, USA), a Samsung ML-2510 printer cartridge (Samsung Electronics
  • electrophotographic toner has a mean particle size between about 9 microns and about 10 microns.
  • micron means micrometer. The minimum particle size ranges between about 2 microns and about 3 microns, and the maximum particle size ranges between about 15 microns to about 18 microns.
  • An imprinted sheet of print-receptive medium was passed through the HP LASERJET 1320 printer a single time and examined for transfer of stray toner particles.
  • Stray toner particle transfer to a non-printed area of a print-receptive medium can occur because the surface of the print-receptive medium comes into contact with, or sufficiently close to, the daini 2 and rollers of the printer, picking up unwanted, stray toner particles.
  • a print-receptive surface tends to pick up fewer stray toner particles after coming into contact with the rollers of an electrophotographic printer if the contact area of the print- receptive surface is reduced.
  • the profile of the print-receptive surface plays a role in the transfer of stray toner particles. See Fig. 13.
  • a print-receptive surface with relatively tall, narrow peaks 80 reduces the probability that a stray toner particle 82 will come into contact with a peak. With the relatively tall, narrow peaks spaced sufficiently far apart, the probability that a stray toner particle will come into contact with the relatively deep valley floors 84 is reduced. By reducing the probability that stray toner particles will contact the print-receptive surface, the transfer of stray toner particles to the print-receptive medium and subsequent graying of the print-receptive medium is reduced.
  • the bearing ratio at threshold 5 microns and the bearing ratio at threshold 10 microns were determined for a number of print-receptive medium surfaces.
  • Competitive print-receptive media chosen were commercially available textured print-receptive media (including textured writing paper and printer papers modified to appear to have linen texture), commercially available laser print-receptive media, commercially available inkjet print-receptive media, and exemplary embodiments of the invention.
  • Textured Sample 1 is HOWARD LINEN F-650 (Neenah Paper, Inc., Neenah, Wisconsin, USA).
  • Textured Sample 2 (TS2) is NEENAH LINEN 05321 from Neenah Paper, Inc.
  • Textured Sample 3 (TS3) is FOX RIVER 70 IN from Neenah Paper, Inc.
  • Textured Sample 4 (TS4) is SUNDANCE BRIGHT WHITE 04820 from Neenah Paper, Inc.
  • Textured Sample 5 (TS5) is CAPITOL BOND B622 from Neenah Paper, Inc.
  • Textured Sample 6 is BECKET CAMBRIC 1 1395B (Mohawk Fine Papers, Inc., Cohoes, New York, USA).
  • Textured Sample 7 is STRATHMORE WRITING PAPER 1 1758C from Mohawk Fine Papers, Inc.
  • Textured Sample 8 (TS8) is NEENAH LINEN 06051 from Neenah Paper, Inc.
  • Laser Sample 1 (LS I) is 8218 laser grade paper (Donitar Corp., Montreal, Canada).
  • Laser Sample 2 (LS2) is TRIO 134 uncoated laser paper from Donitar Corp.
  • Laser Sample 3 (LS3) is a coated sample of TRIO 134 uncoated laser paper from Donitar Corp.
  • Inkjet Sample 1 I J 1
  • Inkjet Sample 2 (IJ2) is STAPLES BRIGHT WHITE INKJET PAPER 73332 (Staples, Inc., Framingham,
  • Inkjet Sample 3 is FELIX SCHOELLER J80270 (Felix
  • Examples 1-1 1 (EXl-EXl 1) are all coated samples of TRIO 134 uncoated laser paper from Donitar Corp. The coating process used for coating the LS3 and EXl-EXl 1 samples is described below. Surface parameters of all the samples are summarized in TABLE II. Note that in TABLE II, BR( IO) is the bearing ratio at threshold 10 microns and BR(5) is the bearing ratio at threshold 5 microns. Pa Pp Ppm Pvm Pv BR(10) BR(5) Ppm- Pvm PHSC
  • Samples are cut from a random location in the machine direction (MD) or cross direction (CD) of the print-receptive media. Samples are rectangular, measuring 7 cm X 1 cm, with the 7 cm direction aligned with the indicated direction of the web. Each sample is mounted onto a glass microscope slide using SCOTCH 665 permanent double sided tape (3M, St. Paul, Minnesota, USA) in such a way as to avoid bubbles underneath the sample.
  • MD machine direction
  • CD cross direction
  • the raw scan data from DEKTAK 8 profilometer is saved in .dat format.
  • the raw data file is opened using TRUESURF (TaieGage Surface Metrology, North Huntingdon, Pennsylvania, USA) for analysis.
  • TRUESURF TieGage Surface Metrology, North Huntingdon, Pennsylvania, USA
  • the TRUESURF software complies with ASME B46.1, ISO 4287, ISO 4288, ISO 12085, ISO 13565, and ISO 1302 standards.
  • baseline correction was performed to remove the baseline slope. Linear least squares analysis was computed using the raw data.
  • the linear baseline is then subtracted from the raw profile to obtain the primary profile.
  • the TRUESURF software calculates values for Pp, Pv, Pa, Ppni, and Pvni.
  • the TRUESURF software When the TRUESURF software is used to calculate the bearing ratio, the software first calculates the total depth, i.e. Pp+Pv. The material percentage, i.e. the bearing ratio, is then calculated at each 1% increase in depth starting at 0% and ending at 100% of the total depth. The result is a table in which the first column is the depth (in %) and the second column is the percentage of material. The percent depth is manually converted into thetician depth (in microns) based upon Pp+Pv. Linear interpolation is used to determine the bearing ratio at threshold 5 microns and at threshold 10 microns from the purse depth.
  • Mixture II 100 parts by weight of water is added to a mixer capable of medium shear mixing. Under medium shear (the mixer operating at 500 rpni) 80 parts by weight of SYLOID W900 silica (W.R. Grace and Company, Columbia, Maryland, USA) is gradually added. Mixing is continued until the silica is uniformly dispersed. The resulting dispersion is about 20% solids by weight.
  • Mixture III A solution of 1 part by weight TRADEWINDS table salt
  • Mixture IV 1 part by weight POLYPHOBE TR- 115 (Coatex, Inc., Chester,
  • Mixture V 1 part by weight of 28-30% ammonium hydroxide (NH 4 OH)
  • NMP N-methyl-pyrrolidone
  • Coating A roll of TRIO 143 paper is loaded onto a coater such that the outside of the roll will be coated upon.
  • the coater speed (feet per minute), the type of coating method, and coat weight (grams per square meter) for the Laser 3 and Examples 1-1 1 samples is listed in TABLE IV.
  • the coated substrate passed through a convection oven for drying. The oven temperature is adjusted such that the coated substrate is dry after emerging from the oven. The exact temperature will depend on the coat weight of the coating formulation and the speed of the coater.
  • the coated substrate Upon exiting the oven, the coated substrate passes through a steam foil for remoisturization (to ensure the coated substrate lays flat when sheeted into print- receptive media) rolled into a roll and removed from the coater. The finished roll is subsequently converted into the desired print-receptive media.
  • the bearing ratio at threshold 5 microns values for all competitive samples were greater than about 1.83%.
  • EXl -EXl 1 have bearing ratio at 5 microns values of less than or equal to about 1.79% and greater than or equal to about 0.64%.
  • Even at threshold 10 microns the exemplary embodiments EXl, EX2, EX4, EX5, EX8, EX 10, and EXl 1 have bearing ratio values less than or equal to about 5.91% and greater than about 1.95%, while the values of the competitive samples are all greater than about 6.56%.
  • exemplary embodiments EXl -EXl 1 have peaks on the print-receptive surface that are narrower or thinner than peaks on the print-receptive surface of commercially available print-receptive media (TS 1-TS8, LS 1-LS3, and IJ1-IJ3).
  • exemplary embodiments EX1-EX1 1 have peaks on the print-receptive surface with bearing ratio at threshold 5 microns less than or equal to about 1.79% and greater than or equal to about 0.64%, and/or peaks on the print- receptive surface with bearing ratio at threshold 10 microns of less than or equal to about 5.91% and greater than or equal to about 1.95%.
  • doubling Pa provides an estimate of the average depth from peak-to-valley on the print-receptive surface, since Pa is a measure of the average distance of all points on the print-receptive surface profile from the mean surface profile.
  • TABLE II includes Pa data for a variety of commercially available print-receptive media and exemplary embodiments. The Pa results show that, in general, the Textured Sample print- receptive media (TS 1-TS8) have a greater average depth from peak-to-valley than non- textured print-receptive media (LS 1-LS3, IJ1-IJ3, and EX1-EX1 1).
  • Textured Sample print- receptive media (TS 1-TS8) have Pa values that range from about 4.03 microns to about 8.86 microns.
  • Laser Sample print-receptive media (LS 1-LS3) have Pa values ranging from about 2.99 microns to about 3.62 microns and Inkjet Sample print-receptive media (IJ1-IJ3) have Pa values ranging from about 3.07 microns to about 5.90 microns.
  • the exemplary embodiments (EXl-EXl 1) have Pa values ranging from about 3.63 microns to about 5.14 microns.
  • TABLE II also shows the values of Ppm-Pvm for commercially available samples and exemplary embodiments. In all cases, the values of Ppm-Pvm for the
  • TS 1-TS8, LS 1-LS3, and IJ1-IJ3 are less than about 0.23 micron.
  • the commercially available samples (TS 1-TS8, LS I, LS2, LS3 (CD), and IJ1-IJ3) have Ppm-Pvm values that are less than about -0.12 micron, indicating that these print- receptive surfaces have, on average, relatively wide peaks and narrow valleys.
  • the exemplary embodiments, EXl-EXl 1 have Ppm-Pvm values that are greater than or equal to about 0.51 micron.
  • the exemplary embodiments (EXl-EXl 1) have, relatively narrow peaks and wide valleys.
  • TABLE II also shows the values for PHSC for a variety of commercially available print-receptive media and exemplary embodiments.
  • Textured Sample print- receptive media (TS 1-TS8) have PHSC values that range from about 0.46 peaks/mm to about 3.46 peaks/mm.
  • Laser Sample print-receptive media (LS 1-LS3) have PHSC values ranging from about 1.34 peaks/mm to about 5.92 peaks/mm and
  • Inkjet Sample print-receptive media (IJ1-IJ3) have PHSC values ranging from about 1.50 peaks/mm to about 6.67 peaks/mm.
  • the exemplary embodiments (EXl-EXl 1) have PHSC values ranging from about 0.34 peaks/mm to about 1.63 peaks/mm.
  • TABLE V shows the data from TABLE II wherein the reported values for the print-receptive surface parameters are the average of the CD and MD values.
  • the average bearing ratio at threshold 5 microns values show that all the commercially available print- receptive media (TS 1-TS8, LS 1-LS3, and IJ1-IJ3) have values greater than about 2.18% and all the exemplary embodiments EXl-EXl 1 have values less than or equal to about 1.51% and greater than or equal to about 0.66%.
  • EX1-EX5, EX8, EX10, and EX1 1 have values less than or equal to about 6.54% and greater than or equal to about 2.55%, while all the commercially available print-receptive media (TS 1-TS8, LS 1-LS3, and IJ1-IJ3) have values greater than about 7.23%.
  • Textured Sample print-receptive media (TS 1-TS8) have Pa values that range from about 4.25 microns to about 8.72 microns.
  • Laser Sample print- receptive media (LS 1-LS3) have Pa values that range from about 3.10 microns to about 3.38 microns, and Inkjet Sample print-receptive media (IJ1-IJ3) have Pa values that range from about 3.27 microns to about 5.25 microns.
  • EXl-EXl 1 have Pa values that range from about 3.71 microns to about 4.70 microns.
  • EXl-EXl 1 have values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns.
  • All the commercially available print-receptive media (TS 1-TS8, LS 1-LS3, IJ1-IJ3)) have Ppm-Pvm values that are less than about -1.01 microns.
  • Fig. 14 plots values of Pa from TABLE II (both CD and MD) against the primary bearing ratio at threshold 5 microns (both CD and MD). Specifically, it can be seen that all the exemplary embodiments, EXl-EXl 1, regardless of their Pa values, have primary bearing ratio at threshold 5 microns values less than about 1.83%. Even more specifically all exemplary embodiments, EXl-EXl 1, regardless of their Pa values, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79%. Even more specifically all exemplary embodiments, EXl-EXl 1, regardless of their Pa values, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and greater than or equal to about 0.64%.
  • EX1-EX6 and EX8-EX1 have primary bearing ratio at threshold 5 microns values less than about 4.07% and Pa values less than about 5.12 microns. Even more specifically, all exemplary embodiments, EXl-EXl 1, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and Pa values less than about 5.14 microns. Even more specifically, all exemplary embodiments, EXl-EXl 1, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and greater than or equal to about 0.64%, and Pa values less than or equal to about 5.14 microns and greater than or equal to about 3.63 microns.
  • Fig. 15 is similar to Fig. 14, except that values of Pa and primary bearing ratio at threshold 5 microns are the average of the CD and MD values. Specifically, it can be seen from Fig. 15 and TABLE V that all the exemplary embodiments, EXl-EXl 1, regardless of their average Pa values, have average primary bearing ratios at threshold 5 microns less than about 2.18%. Even more specifically all exemplary embodiments, EXl-EXl 1, regardless of their average Pa values, have average primary bearing ratios at threshold 5 microns less than or equal to about 1.51%. Even more specifically all exemplary embodiments, EXl-EXl 1, regardless of their average Pa values, have average primary bearing ratios at threshold 5 microns less than or equal to about 1.51% and greater than or equal to about 0.66%.
  • EXl-EXl 1 have average primary bearing ratios at threshold 5 microns less than about 4.38% and average Pa values less than about 5.32 microns. Specifically, all exemplary embodiments, EXl-EXl 1, have average primary bearing ratios at threshold 5 microns less than or equal to about 1.51% and average Pa values less than or equal to about 4.70 microns. Even more specifically, all exemplary embodiments, EXl- EXl 1, have average primary bearing ratios at threshold 5 microns less than or equal to about 1.51% and greater than or equal to about 0.66%, and average Pa values less than or equal to about 4.70 microns and greater than or equal to about 3.75 microns.
  • Fig. 16 plots values of Pa (both CD and MD) against the primary bearing ratio at threshold 10 microns (both CD and MD). Specifically, it can be seen from Fig. 16 and TABLE II that the exemplary embodiments, EX1-EX6 and EX8-EX1 1, have values of Pa less than about 5.12 microns and primary bearing ratio at threshold 10 microns values less than about 24.53%. More specifically, the exemplary embodiments, EX1-EX6 and EX8-EX1 1, have values of Pa less than or equal to about 4.93 microns and primary bearing ratio at threshold 10 microns values less than or equal to about 17.38%.
  • the exemplary embodiments, EX1-EX6 and EX8-EX11 have values of Pa less than or equal to about 4.93 microns and greater than or equal to about 3.63 microns, and primary bearing ratio at threshold 10 microns values less than or equal to about 17.38% and greater than or equal to about 1.95%.
  • Fig. 17 is similar to Fig. 16, except that the values of Pa and primary bearing ratio at threshold 10 microns are the average of the CD and MD values.
  • the exemplary embodiments, EX1-EX5, EX8, EX 10, and EXl 1 have average primary bearing ratios at threshold 10 microns less than about 7.23%.
  • EX1-EX5, EX8, EX10, and EXl 1 have average primary bearing ratios at threshold 10 microns less than or equal to about 6.54%. Even more specifically the exemplary embodiments, EX1-EX5, EX8, EX10, and EXl 1, have average primary bearing ratios at threshold 10 microns less than or equal to about 6.54%, and greater than or equal to about 2.55%. Additionally, all exemplary embodiments, EXl -EXl 1, have average primary bearing ratios at threshold 10 microns less than about 25.28% and average Pa values less than about 5.32 microns.
  • EXl -EXl 1 have average primary bearing ratios at threshold 10 microns less than or equal to about 14.44% and average Pa values less than or equal to about 4.70 microns. Even more specifically, all exemplary embodiments, EXl -EXl 1, have average primary bearing ratios at threshold 10 microns less than or equal to about 14.44% and greater than or equal to about 2.55%, and average Pa values less than or equal to about 4.70 microns and greater than or equal to about 3.75 microns.
  • Fig. 18 plots values of Ppm-Pvm (both CD and MD) against the primary bearing ratio at threshold 5 microns (both CD and MD). Specifically, it can be seen from Fig. 18 and TABLE II that all the exemplary embodiments, EXl -EXl 1, regardless of their Ppm- Pvm values, have primary bearing ratio at threshold 5 microns values less than about 1.83%. Even more specifically all exemplary embodiments, EXl -EXl 1, regardless of their Ppm-Pvm values, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79%.
  • EX1-EX1 regardless of their Ppm-Pvm values, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and greater than or equal to about 0.64%. Additionally, all exemplary embodiments, EXl -EXl 1, regardless of their primary bearing ratio at threshold 5 microns values, have Ppm-Pvm values greater than about 0.23 micron, and specifically, greater than or equal to about 0.51 micron. Even more specifically, all exemplary embodiments, EXl-EXl 1, regardless of their primary bearing ratio at threshold 5 microns values, have Ppm-Pvm values greater than or equal to about 0.51 micron and less than or equal to about 6.35 microns.
  • EXl-EXl 1 have primary bearing ratio at threshold 5 microns values less than about 10.15% and Ppm-Pvm values greater than about - 0.12 micron, specifically, primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and Ppm-Pvm values greater than or equal to about 0.51 micron. Even more specifically, all exemplary embodiments, EXl-EXl 1, have primary bearing ratio at threshold 5 microns values less than or equal to about 1.79% and greater than or equal to about 0.64%, and Ppm-Pvm values greater than or equal to about 0.51 micron and less than or equal to about 6.35 microns.
  • Fig. 19 is similar to Fig. 18, except that values of Ppm-Pvm and primary bearing ratio at threshold 5 microns are the average of the CD and MD values. Specifically, it can be seen from Fig. 19 and TABLE V that all the exemplary embodiments, EXl-EXl 1, regardless of their average Ppm-Pvm values, have average primary bearing ratio at threshold 5 microns values less than about 2.18%. Even more specifically all exemplary embodiments, EXl-EXl 1, regardless of their average Ppm-Pvm values, have average primary bearing ratio at threshold 5 microns values less than or equal to about 1.51%.
  • EXl-EXl 1 regardless of their average Ppm-Pvm values, have average primary bearing ratio at threshold 5 microns values less than or equal to about 1.51% and greater than or equal to about 0.66%. Additionally, all exemplary embodiments, EXl- EXl 1, regardless of their average primary bearing ratio at threshold 5 microns values, have average Ppm-Pvm values greater than about -1.01 microns, and specifically, greater than or equal to about 0.96 micron. More specifically, all exemplary embodiments, EXl-EXl 1, regardless of their average primary bearing ratio at threshold 5 microns values, have average Ppm-Pvm values greater than about 0.96 micron and less than or equal to about 4.76 microns.
  • EX1-EX1 have average primary bearing ratio at threshold 5 microns values less than about 7.1 1% and average Ppm-Pvm values greater than about -1.54 microns, specifically, average primary bearing ratio at threshold 5 microns values less than or equal to about 1.51% and average Ppm-Pvm values greater than or equal to about 0.96 micron. Even more specifically, all exemplary embodiments, EX1-EX1 1, have average primary bearing ratio at threshold 5 microns values less than about 1.51% and greater than or equal to about 0.66%, and average Ppm-Pvm values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns.
  • Fig. 20 plots values of Ppm-Pvm (both CD and MD) against the primary bearing ratio at threshold 10 microns (both CD and MD). Specifically, it can be seen from Fig. 20 and TABLE II that all of the exemplary embodiments, EX1-EX1 1, regardless of their primary bearing ratio at threshold 10 microns values, have Ppm-Pvm values greater than about 0.23 micron. Even more specifically, all of the exemplary embodiments, EX1-EX1 1, regardless of their primary bearing ratio at threshold 10 microns values, have Ppm-Pvm values greater than or equal to about 0.51 micron.
  • EX1-EX1 regardless of their primary bearing ratio at threshold 10 microns values, have Ppm-Pvm values greater than or equal to about 0.51 micron and less than or equal to about 6.35 microns. Additionally, all of the exemplary embodiments, EX1- EX1 1, have Ppm-Pvm values greater than about 0.23 micron and primary bearing ratio at threshold 10 microns values less than about 43.21%. Specifically, all of the exemplary embodiments, EX1-EX1 1, have Ppm-Pvm values greater than or equal to about 0.51 micron and primary bearing ratio at threshold 10 microns values less than or equal to about 17.38%.
  • EX1-EX1 have Ppm-Pvm values greater than or equal to about 0.51 micron and less than or equal to about 6.35 microns, and primary bearing ratio at threshold 10 microns values less than or equal to about 17.38% and greater than or equal to about 1.95%.
  • Fig. 21 is similar to Fig. 20, except that values of Ppm-Pvm and primary bearing ratio at threshold 10 microns are the average of the CD and MD values. Specifically, it can be seen from Fig.
  • EXl-EXl 1 regardless of their average primary bearing ratio at threshold 10 microns values, have average Ppm-Pvm values greater than about -1.01 microns, and specifically, greater than or equal to about 0.96 micron. Even more specifically, all exemplary embodiments, EXl-EXl 1, regardless of their average primary bearing ratio at threshold 10 microns values, have average Ppm-Pvm values greater than about 0.96 micron and less than or equal to about 4.76 microns.
  • EXl-EXl 1 have average primary bearing ratio at threshold 10 microns values less than about 36.09% and average Ppm-Pvm values greater than about -1.54 microns, specifically, average primary bearing ratio at threshold 10 microns values less than or equal to about 14.44% and average Ppm-Pvm values greater than or equal to about 0.96 micron. Even more specifically, average primary bearing ratio at threshold 10 microns values less than or equal to about 14.44% and greater than or equal to about 2.55%, and average Ppm-Pvm values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns.
  • Fig. 22 plots the average of the CD and MD values of Ppm-Pvm against the average of the CD and MD values of the Pa. Specifically, it can be seen in Fig. 22 and TABLE V that all exemplary embodiments, EXl-EXl 1, have average Ppm-Pvm values greater than about -1.01 microns, regardless of the average Pa value. Even more specifically, all exemplary embodiments, EXl-EXl 1, have average Ppm-Pvm values greater than or equal to about 0.96 micron, regardless of the average Pa value.
  • EXl-EXl 1 have average Ppm-Pvm values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns, regardless of the average Pa value. Yet even more specifically, all exemplary embodiments, EXl-EXl 1, have average Ppm-Pvm values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns, and average Pa values greater than or equal to about 3.71 microns and less than or equal to about 4.66 microns.
  • Fig. 23 plots PHSC (both CD and MD) against Ppm-Pvm (both CD and MD).
  • EXl-EXl 1 have PHSC values less than about 2.71 peaks/mm and Ppm-Pvm values greater than about -0.12 micron. More specifically, all exemplary embodiments, EXl-EXl 1, have PHSC values less than or equal to about 1.63 peaks/mm and Ppm-Pvm values greater than or equal to about 0.51 micron.
  • EXl-EXl 1 have PHSC values less than or equal to about 1.63 peaks/mm and greater than or equal to about 0.34 peaks/mm, and Ppm-Pvm values greater than or equal to about 0.51 micron and less than or equal to about 6.35 microns.
  • a print-receptive medium having a print-receptive surface with the above- described surface roughness properties can be prepared by the method outlined in Fig. 24.
  • a roll of substrate material is provided to a roll coater at step 86.
  • the roll is loaded onto the coater to form a web at step 88, and coater is operated under typical coating conditions.
  • a coating material is applied by any method known to one skilled in the art, typically using, for example, slot coating, curtain coating, or gravure coating, at step 90. Alternatively, the material can be sprayed or otherwise applied to the web.
  • the coating material is dried under conditions known to those skilled in the art at step 92. Additionally, after drying, the web can be remoisturized to provide a coated substrate with reduced tendency to curl. Other coatings, for example, adhesives, release agents, etc., can be added to the web either before or after the coating material. After drying, the coated web can be rewound into roll form at step 94. At a later time, the roll of coated substrate can be converted on a converting press to form any number of print-receptive media, for example, address labels, file folder labels, stickers, and other labels, business cards, greeting cards, name badges, tent cards, etc. Alternatively, the dried, coated web can be converted into intermediate or finished print-receptive media directly from the coater without the intermediate roll form.
  • An alternative method of manufacturing a print-receptive medium of the current invention includes embossing the print-receptive surface into a substrate, and is outlined in Fig. 25. Embossing is a process well-known to those skilled in the art.
  • a substrate for example, paper, cardstock, film, or any other material suitable for accepting an embossed pattern, is provided at step 96.
  • An embossed pattern is formed on an embossing roll such that the embossed pattern can be transferred to the substrate to form the peaks and valleys of the print-receptive media at step 98.
  • the pattern is transferred, typically under heat and pressure, by passing the substrate through a nip formed between a backing roll and the embossing roll at step 100.
  • the molten film can be extaided into the nip.
  • the embossing roll and/or the backing roll can be chilled to help solidify and allow release of the film from the rolls.
  • the backing roll can be a second embossing roll.
  • the embossed substrate can be rolled into an embossed roll at step 102, or converted as described above.
  • the embossed substrate can be laminated to a second substrate to form a print-receptive laminate that can be converted as described above.
  • Additional alternative methods of manufacturing the print-receptive medium include printing on a substrate, such as, but not limited to, a paper substrate and a polymeric substrate (which polymeric substrate can be opaque, clear, translucent, or otherwise); and using a size material in forming a substrate, such as, but not limited to, a pulp-based substrate, for example, a paper substrate.
  • a substrate such as, but not limited to, a paper substrate and a polymeric substrate (which polymeric substrate can be opaque, clear, translucent, or otherwise); and using a size material in forming a substrate, such as, but not limited to, a pulp-based substrate, for example, a paper substrate.
  • the print-receptive material is paper or a polymeric film
  • the material can be embossed or calendared, either as part of the paper-making or film-making process or afterwards, so as to have a certain degree and type of desired roughness.
  • the print-receptive surface can be formed directly on the surface of a film, for example, by extaiding the film onto a suitably profiled chill roll.
  • protaisions can be formed in paper by using a calendar roll or a pressing template to emboss a paper substrate with protaiding features.
  • screen printing or UV ink printing can be used to apply resins onto a paper surface, which, after solidifying, become at least a part of the print-receptive surface.
  • by including specifically sized and/or shaped particles in a paper pulp used to make paper one could create paper in which such particles protaide out of the paper to a desired extent, forming the print-receptive surface.
  • the aforementioned particles could be spherical, plate-like, fiber-like, or any other regular or irregular shape.
  • the paper with the particles could experience some heating with temperature above the melting or T g , or glass transition temperature, of the particles, as well as some degree of pressure. After cooling, the particles will solidify and remain as at least a part of the print- receptive surface.
  • a print-receptive medium having one or more of the above- described properties of surface roughness can be made by applying a print-receptive coating to one or more surfaces of a substrate.
  • Suitable materials for use as the substrate include, but are not limited to, paper, polymeric films, and other materials suitable for electrophotographic printers. The only limits on the types of materials that can be used as the substrate are related to printer requirements. For example, certain low softening point films can melt in electrophotographic printers and, therefore, can be unsuitable for use as the substrate.
  • the overall thickness of the substrate can be limited by the useful range of thickness of print- receptive media that can pass through the printer. Materials that are too thin will tend to be too flexible for the media path through the printer while materials that are too thick will not be able to fit through tight tolerances or will be too stiff for the media path.
  • the coating composition of the print-receptive coating can be formulated so that a desired combination of the surface roughness (Pp, Pv, Pa, Ppni, Pvni, and bearing ratios at threshold 5 microns and 10 microns) can be achieved.
  • a suitable coating composition can include one or more polymeric resin binders that can be coated and that can solidify on the substrate surface or, in the case of a paper substrate, that can penetrate inside the paper fibers and one or more particle types that can be dispersed in the resin binder.
  • the polymeric resin binder of the coating composition can be in the form of a water-based polymer solution, a polymeric emulsion, or a water-based polymeric dispersion.
  • An example of a suitable water-based polymeric solution can be an aqueous solution of polyvinyl alcohol.
  • An example of a polymeric emulsion can be an emulsion of polyvinyl acetate.
  • a disadvantage of water-based solutions like the aforementioned polyvinyl alcohol solution is that the resulting coating typically has inferior water resistance as compared to a coating prepared from a polymeric emulsion like polyvinyl acetate.
  • the binder resins have a relatively high T g so as to possess suitably high hardness and non-blocking properties.
  • the dispersed particles of the coating composition can be any of a wide variety of particle material types.
  • the particles can be organic materials including, but not limited to, epoxies, acrylics, polyamides, polypropylenes, polyethylenes, polyurethanes, and the like.
  • the particles can be inorganic materials including, for example, but not limited to, silicates, silica, CaC0 3 , talc, and the like.
  • particle size used in the print-receptive coating in general, as the particle size increases, the discoloration of the print-receptive medium following multiple feedings through the printer decreases.
  • the particles preferably have a particle size of about 10 microns to about 60 microns in diameter, more preferably about 10 microns to about 40 microns in diameter. Also, the particles preferably have a melting temperature higher than about 50°C, more preferably higher than about 100°C, and even more preferably higher than about 150°C.
  • Preferred particle material types can include polyamide particles, particularly polar polyamide particles, such as polyamide-6 particles and polyamide- 6/12 particles.
  • Such polyamide particles can be preferred over less polar polyamide particles, like polyamide- 12 particles, because the more polar polyamide particles can be more easily dispersed in water, because they can have higher melting temperatures to tolerate the heat of electrophotographic printers, and because the more polar particles can adhere better to toner.
  • An example of a suitable particle type includes ORGASOL 1002 D NAT polyamide powder (Arkenia, Inc., Philadelphia, Pennsylvania, USA), a spheroidal powder of polyamide-6, with an average particle diameter of about 20 ⁇ and a melting temperature of 217°C .
  • An example of another suitable particle type includes EPOSTAR MA 1013 cross-linked polymethacrylate powder (Nippon Shokubai Co., Ltd., Osaka, Japan), a spheroidal powder having an average particle size of about 12 microns to about 15 microns.
  • the coating composition can further include one or more of the following: colorants, optical brighteners, whiteners, anti-settling agents, thickeners, and the like.
  • the graying or discoloration of a print-receptive medium can be evaluated objectively by measuring the color difference of the print-receptive medium in one or more imprinted areas before and after passing the print-receptive medium through an electrophotographic printer.
  • the aforementioned color difference or ⁇ a b can be determined using the industry standard CLE L*a*b* measurement, wherein
  • ⁇ 3 ⁇ 4 (3 ⁇ 4 - 3 ⁇ 4) a + (aS - fl » 2 + (3 ⁇ 4 - 3 ⁇ 4 ) 2
  • L * 2 and ⁇ represent lightness of color in an unprinted area after and before, respectively, one or more feedings through the electrophotographic printer
  • b * 2 and b ⁇ represent position between yellow and blue in an unprinted area after and before, respectively, one or more passes through the electrophotographic printer.
  • TABLE V includes AE* a b for commercially available samples (TS 1-TS8, LS 1-
  • exemplary embodiments (EXl-EXl 1) have AE* a b values less than about 1.68. More specifically, the exemplary embodiments (EXl-EXl 1) have AE*ab values less than or equal to about 1.32.
  • Fig. 26 illustrates the relationship between AE*ab and the average primary bearing ratio at threshold 5 microns from TABLE V.
  • the exemplary embodiments (EXl-EXl 1) have AE* a b values less than about 2.41 and average primary bearing ratio at threshold 5 microns values less than about 2.67%.
  • exemplary embodiments (EXl-EXl 1) have AE* a b values less than or equal to about 1.32 and average primary bearing ratio at threshold 5 microns values less than or equal to about 1.51%.
  • FIG. 27 illustrates the relationship between AE* a b and the average primary bearing ratio at threshold 10 microns from TABLE V.
  • Exemplary embodiments (EX1-EX5, EX8, EX10, and EX1 1) have AE* a b values less than about 2.41 and average primary bearing ratio at threshold 10 microns values less than about 7.23%.
  • exemplary embodiments (EX1-EX5, EX8, EX10, and EX1 1) have AE* a b values less than or equal to about 1.27 and average primary bearing ratio at 10 microns values less than or equal to about 6.54%.
  • exemplary embodiments (EX1-EX5, EX8, EX10, and EX1 1) have AE*ab values less than or equal to about 1.27 and greater than or equal to about 0.64, and average primary bearing ratio at 10 microns values less than or equal to about 6.54% and greater than or equal to about 2.88%.
  • Exemplary embodiments (EXl-EXl 1) regardless of the average primary bearing ratio at 10 microns value, have AE* a b values less than about 1.68.
  • exemplary embodiments (EXl-EXl 1), regardless of the average primary bearing ratio at 10 microns value have AE* a b values less than about 1.32.
  • exemplary embodiments (EXl-EXl 1), regardless of the average primary bearing ratio at 10 microns value have AE* a b values less than about 1.32 and greater than or equal to about 0.64.
  • Fig. 28 illustrates the relationship between AE* a b and average Ppm-Pvm from
  • the exemplary embodiments (EXl-EXl 1) have AE* a b values less than about 2.96 and average Ppm-Pvm values greater than about -2.75 microns. Specifically, exemplary embodiments (EXl-EXl 1) have AE* a b less than or equal to about 1.32 and average Ppm-Pvm values greater than or equal to about 0.96 micron. Even more specifically, exemplary embodiments (EXl-EXl 1) have AE* a b less than or equal to about 1.32 and greater than or equal to about 0.64, and average Ppm-Pvm values greater than or equal to about 0.96 micron and less than or equal to about 4.76 microns.
  • Fig. 29 illustrates the relationship between AE* a b and average Pa from TABLE
  • the exemplary embodiments (EXl-EXl 1) have AE* a b values less than about 2.78 and average Pa values less than about 6.59 microns. Specifically, exemplary embodiments (EXl- EXl 1) have AE* a b values less than or equal to about 1.32 and average Pa values less than or equal to about 4.70 microns. More specifically, exemplary embodiments (EXl-EXl 1) have AE*ab values less than or equal to about 1.32 and greater than or equal to about 0.64, and average Pa values less than or equal to about 4.70 microns and greater than or equal to about 3.71 microns.
  • Roughness average R a is the arithmetic average of the
  • Root mean square (RMS) roughness R q is the root mean square average of the roughness profile ordinates.
  • the Mean Roughness Depth R z is the mean of five roughness depths of five successive sample lengths I of the roughness
  • the Maximum Roughness Depth Rmax is the largest of five roughness depths.
  • R z and R max are used together to monitor the variations of surface finish in a production process. Similar values of R z and R max indicate a consistent surface finish, while a significant difference indicates a surface defect in an otherwise consistent surface.
  • the Mean Leveling Depth R pm is the mean of five leveling depths of five
  • R pm 1/5 (R p1 + R p2 + R p3 + R p4 + R p5 )
  • the Leveling Depth R p is also the largest of the five leveling depths.
  • Maximum Roughness Depth R t (peak to valley height) is the vertical distance between the highest peak and the lowest valley of the roughness profile R within the evaluation length L.
  • R p per ISO 4287, is the max height of any peak to the mean line within one sampling length.
  • R pm the mean leveling depth - per rules of ISO 4288, is an averaging of R p over 5 cutoffs; according to ASME B46.1 -2002, R p calculated over the evaluation length is R pm .
  • R pm is useful in predicting bearing characteristics of a surface.
  • the ratio R pm /R z quantifies the asymmetry of profile.
  • R pm is recommended for bearing and sliding surfaces and surface substrates prior to coating.
  • R v is a good parameter where stress is a major factor.
  • R p is a good parameter to control coating quality.
  • R 3z - mean third highest N pea3k-t1o-0va0lley7 he:1igh9t o8ve3r 5 sampling length.
  • R 3z disregards the 2 highest peaks and deepest valleys that have little effect on the surface performance, with the intent to reduce the instability of peak parameters (such as R z ), by ignoring profile extremes.
  • the peak count is the number of local roughness peaks which project through a selectable band centered about the mean line. The count is determined over the evaluation length and is reported in peaks per cm or inch.
  • Nr HSC Nr HSC
  • Multiprocessed, multipurpose surfaces such as plateau honed

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  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
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Abstract

La présente invention comprend un support récepteur d'impression comprenant une surface réceptrice d'impression. La surface réceptrice d'impression comporte une pluralité de crêtes et une pluralité de creux. La surface réceptrice d'impression comporte également un profilé primaire qui comprend une surface moyenne. Chaque crête de la pluralité de crêtes a une hauteur mesurée depuis la surface moyenne, et chacun des creux a une profondeur mesurée depuis la surface moyenne. La pluralité de crêtes ont une hauteur de crête moyenne, Ppm, et la pluralité de creux ont une profondeur de creux moyenne, Pvm. Le profilé primaire de la surface réceptrice d'impression a une valeur de Ppm-Pvm supérieure à environ 0,23 micron.
PCT/US2011/026724 2011-03-01 2011-03-01 Supports récepteurs d'impression et procédés associés Ceased WO2012118495A2 (fr)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185496A (en) 1990-03-02 1993-02-09 Canon Kabushiki Kaisha Electrostatic latent image device having a coating layer provided on a developer carrying member

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Publication number Priority date Publication date Assignee Title
JP2833071B2 (ja) * 1989-11-20 1998-12-09 ミノルタ株式会社 複写方法
WO1995011655A1 (fr) * 1993-10-29 1995-05-04 Minnesota Mining And Manufacturing Company Systemes de fermeture adhesifs structures
WO2004092293A1 (fr) * 2003-04-10 2004-10-28 Yupo Corporation Feuille convertie adhesive
US20050095401A1 (en) * 2003-11-04 2005-05-05 Fuji Photo Film Co., Ltd. Image recording material and depression-and-protrusion forming method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5185496A (en) 1990-03-02 1993-02-09 Canon Kabushiki Kaisha Electrostatic latent image device having a coating layer provided on a developer carrying member

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